#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:48:39 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180016 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/10/7031089.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7031089
loop_
_publ_author_name
'Zhao, Xiao-Li'
'Mak, Thomas C. W.'
_publ_section_title
;
 Silver cages with encapsulated acetylenediide as building blocks for
 hydrothermal synthesis of supramolecular complexes with n-cyanopyridine
 and pyridine-n-carboxamide (n=3, 4).
;
_journal_issue                   20
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3212
_journal_page_last               3217
_journal_paper_doi               10.1039/B406711H
_journal_year                    2004
_chemical_formula_sum            'C16 H10 Ag6 F12 N2 O11'
_chemical_formula_weight         1281.45
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 128.0610(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   20.1547(10)
_cell_length_b                   24.0752(12)
_cell_length_c                   15.3635(8)
_cell_measurement_temperature    293(2)
_cell_volume                     5869.6(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0298
_diffrn_reflns_av_sigmaI/netI    0.0240
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            20199
_diffrn_reflns_theta_full        28.01
_diffrn_reflns_theta_max         28.01
_diffrn_reflns_theta_min         1.59
_exptl_absorpt_coefficient_mu    4.057
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.530587
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.891
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4752
_exptl_crystal_size_max          0.56
_exptl_crystal_size_mid          0.46
_exptl_crystal_size_min          0.38
_refine_diff_density_max         1.551
_refine_diff_density_min         -1.606
_refine_diff_density_rms         0.153
_refine_ls_extinction_coef       0.00082(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     454
_refine_ls_number_reflns         7080
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0515
_refine_ls_R_factor_gt           0.0422
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
calc w=1/[σ²(Fo²)+(0.0629P)²+34.4806P] where
P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1096
_refine_ls_wR_factor_ref         0.1165
_reflns_number_gt                5923
_reflns_number_total             7080
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b406711h.txt
_cod_data_source_block           compound_2
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7031089
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.58387(2) 0.00880(2) 0.35038(3) 0.04238(13) Uani 1 1 d .
Ag2 Ag 0.58822(2) 0.00729(2) 0.53756(3) 0.04363(13) Uani 1 1 d .
Ag4 Ag 0.29247(3) -0.051717(19) 0.19634(4) 0.04883(14) Uani 1 1 d .
Ag3 Ag 0.47994(3) -0.085618(18) 0.35074(5) 0.05828(16) Uani 1 1 d .
Ag6 Ag 0.48803(4) 0.103567(19) 0.34711(5) 0.06445(17) Uani 1 1 d .
Ag5 Ag 0.28542(3) 0.05910(2) 0.23398(5) 0.05706(16) Uani 1 1 d .
C1 C 0.3950(3) 0.00877(19) 0.2961(4) 0.0298(9) Uani 1 1 d .
C2 C 0.4730(3) 0.0125(2) 0.3534(4) 0.0306(9) Uani 1 1 d .
O1 O 0.3229(3) -0.14326(18) 0.2751(4) 0.0562(11) Uani 1 1 d .
O2 O 0.4309(3) -0.13102(18) 0.4521(3) 0.0516(10) Uani 1 1 d .
C3 C 0.3631(3) -0.1520(2) 0.3747(5) 0.0469(13) Uani 1 1 d .
C4 C 0.3272(5) -0.1965(4) 0.4063(8) 0.078(2) Uani 1 1 d .
F11 F 0.2533(4) -0.2119(4) 0.3278(7) 0.185(5) Uani 1 1 d .
F12 F 0.3250(6) -0.1783(3) 0.4868(8) 0.143(3) Uani 1 1 d .
F13 F 0.3756(4) -0.2397(2) 0.4515(6) 0.112(2) Uani 1 1 d .
O3 O 0.7064(3) 0.0566(2) 0.4586(4) 0.0656(13) Uani 1 1 d .
O4 O 0.7241(2) 0.0363(2) 0.6135(3) 0.0524(10) Uani 1 1 d .
C5 C 0.7464(4) 0.0529(2) 0.5599(5) 0.0450(12) Uani 1 1 d .
C6 C 0.8402(5) 0.0687(4) 0.6270(6) 0.072(2) Uani 1 1 d .
F21 F 0.8842(4) 0.0276(5) 0.6378(9) 0.181(5) Uani 1 1 d .
F22 F 0.8729(3) 0.0863(3) 0.7270(4) 0.114(2) Uani 1 1 d .
F23 F 0.8520(4) 0.1082(4) 0.5804(5) 0.159(4) Uani 1 1 d .
O5 O 0.6629(3) -0.0760(2) 0.4221(4) 0.0620(12) Uani 1 1 d .
O6 O 0.6416(3) -0.09436(17) 0.5450(3) 0.0493(9) Uani 1 1 d .
C7 C 0.6763(3) -0.1010(2) 0.5019(5) 0.0419(11) Uani 1 1 d .
C8 C 0.7449(5) -0.1459(3) 0.5522(7) 0.0663(19) Uani 1 1 d .
F31 F 0.7353(5) -0.1773(3) 0.4771(5) 0.122(2) Uani 1 1 d .
F32 F 0.8189(3) -0.1241(3) 0.6032(6) 0.124(2) Uani 1 1 d .
F33 F 0.7496(5) -0.1770(3) 0.6250(6) 0.131(3) Uani 1 1 d .
O7 O 0.4821(4) 0.1908(2) 0.3049(5) 0.0801(16) Uani 1 1 d .
C9 C 0.5000 0.2114(3) 0.2500 0.055(2) Uani 1 2 d S
C10 C 0.5000 0.2753(4) 0.2500 0.112(7) Uani 1 2 d S
F41 F 0.4069(19) 0.2870(7) 0.157(2) 0.208(12) Uani 0.50 1 d P
F42 F 0.488(2) 0.2981(7) 0.172(2) 0.108(10) Uani 0.50 1 d P
F43 F 0.535(3) 0.2981(11) 0.216(3) 0.167(18) Uani 0.50 1 d P
O8 O 0.5121(3) -0.17117(17) 0.3317(4) 0.0592(11) Uani 1 1 d .
C11 C 0.5000 -0.1921(3) 0.2500 0.0480(19) Uani 1 2 d S
C12 C 0.5000 -0.2564(5) 0.2500 0.106(6) Uani 1 2 d S
F51 F 0.564(2) -0.2705(7) 0.236(3) 0.163(9) Uani 0.50 1 d P
F52 F 0.565(2) -0.2754(11) 0.338(3) 0.149(17) Uani 0.50 1 d P
F53 F 0.526(4) -0.2792(10) 0.335(3) 0.17(2) Uani 0.50 1 d P
N1 N -0.1540(3) -0.08090(19) -0.1533(4) 0.0437(10) Uani 1 1 d .
N2 N 0.1424(3) -0.1594(2) 0.0890(4) 0.0501(12) Uani 1 1 d .
H2A H 0.1960 -0.1644 0.1345 0.060 Uiso 1 1 calc R
H2B H 0.1088 -0.1871 0.0686 0.060 Uiso 1 1 calc R
O9 O 0.1553(2) -0.06773(17) 0.0752(4) 0.0514(10) Uani 1 1 d .
C13 C -0.0364(3) -0.1398(2) -0.0327(5) 0.0470(13) Uani 1 1 d .
H13A H -0.0160 -0.1732 0.0057 0.056 Uiso 1 1 calc R
C14 C -0.1220(3) -0.1275(2) -0.0978(6) 0.0519(14) Uani 1 1 d .
H14A H -0.1581 -0.1534 -0.1021 0.062 Uiso 1 1 calc R
C15 C -0.1017(4) -0.0445(3) -0.1482(6) 0.0545(16) Uani 1 1 d .
H15A H -0.1237 -0.0115 -0.1878 0.065 Uiso 1 1 calc R
C16 C -0.0153(3) -0.0541(2) -0.0854(5) 0.0515(15) Uani 1 1 d .
H16A H 0.0194 -0.0281 -0.0842 0.062 Uiso 1 1 calc R
C17 C 0.0176(3) -0.1017(2) -0.0260(4) 0.0353(10) Uani 1 1 d .
C18 C 0.1119(3) -0.1095(2) 0.0505(4) 0.0396(11) Uani 1 1 d .
O1W O 0.3256(4) 0.1572(3) 0.2538(7) 0.103(2) Uani 1 1 d .
O2W O 0.0679(3) -0.2722(2) 0.0476(5) 0.0757(15) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Ag1 C2 127.45(18) . .
O3 Ag1 O5 88.92(19) . .
C2 Ag1 O5 114.08(17) . .
O3 Ag1 C1 87.00(16) . 2_655
C2 Ag1 C1 136.54(15) . 2_655
O5 Ag1 C1 88.88(15) . 2_655
O3 Ag1 C2 109.85(16) . 2_655
C2 Ag1 C2 108.45(13) . 2_655
O5 Ag1 C2 105.00(15) . 2_655
C1 Ag1 C2 28.09(14) 2_655 2_655
O3 Ag1 Ag2 85.64(12) . .
C2 Ag1 Ag2 52.49(11) . .
O5 Ag1 Ag2 85.76(11) . .
C1 Ag1 Ag2 170.97(10) 2_655 .
C2 Ag1 Ag2 160.94(10) 2_655 .
O3 Ag1 Ag1 145.65(13) . 2_655
C2 Ag1 Ag1 59.61(11) . 2_655
O5 Ag1 Ag1 120.44(13) . 2_655
C1 Ag1 Ag1 77.01(10) 2_655 2_655
C2 Ag1 Ag1 49.01(10) 2_655 2_655
Ag2 Ag1 Ag1 111.99(2) . 2_655
O3 Ag1 Ag6 91.46(15) . .
C2 Ag1 Ag6 47.95(12) . .
O5 Ag1 Ag6 154.45(11) . .
C1 Ag1 Ag6 116.66(11) 2_655 .
C2 Ag1 Ag6 98.88(10) 2_655 .
Ag2 Ag1 Ag6 68.807(16) . .
Ag1 Ag1 Ag6 69.859(16) 2_655 .
O3 Ag1 Ag3 143.69(12) . .
C2 Ag1 Ag3 49.58(12) . .
O5 Ag1 Ag3 68.40(12) . .
C1 Ag1 Ag3 119.07(10) 2_655 .
C2 Ag1 Ag3 103.43(11) 2_655 .
Ag2 Ag1 Ag3 65.452(17) . .
Ag1 Ag1 Ag3 69.412(15) 2_655 .
Ag6 Ag1 Ag3 97.498(18) . .
O3 Ag1 Ag4 75.98(15) . 2_655
C2 Ag1 Ag4 154.43(12) . 2_655
O5 Ag1 Ag4 49.66(11) . 2_655
C1 Ag1 Ag4 41.39(10) 2_655 2_655
C2 Ag1 Ag4 65.55(10) 2_655 2_655
Ag2 Ag1 Ag4 131.122(18) . 2_655
Ag1 Ag1 Ag4 108.299(18) 2_655 2_655
Ag6 Ag1 Ag4 154.07(2) . 2_655
Ag3 Ag1 Ag4 106.072(18) . 2_655
O3 Ag1 Ag6 89.17(13) . 2_655
C2 Ag1 Ag6 96.36(12) . 2_655
O5 Ag1 Ag6 142.60(11) . 2_655
C1 Ag1 Ag6 53.72(10) 2_655 2_655
C2 Ag1 Ag6 41.80(10) 2_655 2_655
Ag2 Ag1 Ag6 131.28(2) . 2_655
Ag1 Ag1 Ag6 56.848(14) 2_655 2_655
Ag6 Ag1 Ag6 62.94(2) . 2_655
Ag3 Ag1 Ag6 126.174(19) . 2_655
Ag4 Ag1 Ag6 93.818(16) 2_655 2_655
C2 Ag2 O4 125.64(16) . .
C2 Ag2 C1 133.77(16) . 5_656
O4 Ag2 C1 99.54(15) . 5_656
C2 Ag2 C2 105.95(12) . 5_656
O4 Ag2 C2 126.66(14) . 5_656
C1 Ag2 C2 27.82(14) 5_656 5_656
C2 Ag2 Ag1 51.22(12) . .
O4 Ag2 Ag1 78.12(10) . .
C1 Ag2 Ag1 170.06(11) 5_656 .
C2 Ag2 Ag1 155.07(10) 5_656 .
C2 Ag2 Ag2 58.48(12) . 5_656
O4 Ag2 Ag2 167.40(12) . 5_656
C1 Ag2 Ag2 75.29(11) 5_656 5_656
C2 Ag2 Ag2 47.47(10) 5_656 5_656
Ag1 Ag2 Ag2 108.90(2) . 5_656
C2 Ag2 Ag3 47.53(12) . .
O4 Ag2 Ag3 126.82(12) . .
C1 Ag2 Ag3 114.40(11) 5_656 .
C2 Ag2 Ag3 96.55(10) 5_656 .
Ag1 Ag2 Ag3 61.347(16) . .
Ag2 Ag2 Ag3 65.399(18) 5_656 .
C2 Ag2 Ag5 152.60(12) . 5_656
O4 Ag2 Ag5 72.94(11) . 5_656
C1 Ag2 Ag5 42.16(11) 5_656 5_656
C2 Ag2 Ag5 65.61(10) 5_656 5_656
Ag1 Ag2 Ag5 128.66(2) . 5_656
Ag2 Ag2 Ag5 108.32(2) 5_656 5_656
Ag3 Ag2 Ag5 105.921(19) . 5_656
C2 Ag2 Ag6 42.67(12) . .
O4 Ag2 Ag6 97.02(11) . .
C1 Ag2 Ag6 132.20(11) 5_656 .
C2 Ag2 Ag6 114.76(10) 5_656 .
Ag1 Ag2 Ag6 57.719(15) . .
Ag2 Ag2 Ag6 78.92(2) 5_656 .
Ag3 Ag2 Ag6 89.396(16) . .
Ag5 Ag2 Ag6 164.63(2) 5_656 .
C2 Ag2 Ag3 100.16(12) . 5_656
O4 Ag2 Ag3 107.54(12) . 5_656
C1 Ag2 Ag3 51.59(11) 5_656 5_656
C2 Ag2 Ag3 44.47(10) 5_656 5_656
Ag1 Ag2 Ag3 138.35(2) . 5_656
Ag2 Ag2 Ag3 60.164(17) 5_656 5_656
Ag3 Ag2 Ag3 125.563(16) . 5_656
Ag5 Ag2 Ag3 91.119(17) 5_656 5_656
Ag6 Ag2 Ag3 80.686(18) . 5_656
C1 Ag4 O9 148.24(16) . .
C1 Ag4 O1 114.70(15) . .
O9 Ag4 O1 93.55(15) . .
C1 Ag4 O5 93.22(15) . 2_655
O9 Ag4 O5 99.63(17) . 2_655
O1 Ag4 O5 93.24(17) . 2_655
C1 Ag4 Ag5 50.17(12) . .
O9 Ag4 Ag5 98.39(11) . .
O1 Ag4 Ag5 144.36(12) . .
O5 Ag4 Ag5 117.38(11) 2_655 .
C1 Ag4 Ag3 57.33(12) . .
O9 Ag4 Ag3 154.43(11) . .
O1 Ag4 Ag3 63.86(11) . .
O5 Ag4 Ag3 71.56(12) 2_655 .
Ag5 Ag4 Ag3 106.999(17) . .
C1 Ag4 Ag1 49.68(12) . 2_655
O9 Ag4 Ag1 127.43(12) . 2_655
O1 Ag4 Ag1 121.21(12) . 2_655
O5 Ag4 Ag1 45.91(10) 2_655 2_655
Ag5 Ag4 Ag1 76.308(17) . 2_655
Ag3 Ag4 Ag1 63.656(15) . 2_655
O8 Ag3 C2 161.38(18) . .
O8 Ag3 O2 86.43(17) . .
C2 Ag3 O2 111.60(15) . .
O8 Ag3 C1 158.84(15) . .
C2 Ag3 C1 27.99(15) . .
O2 Ag3 C1 98.23(14) . .
O8 Ag3 Ag4 117.41(13) . .
C2 Ag3 Ag4 72.07(11) . .
O2 Ag3 Ag4 80.26(9) . .
C1 Ag3 Ag4 44.28(10) . .
O8 Ag3 Ag1 115.22(14) . .
C2 Ag3 Ag1 46.70(11) . .
O2 Ag3 Ag1 146.56(10) . .
C1 Ag3 Ag1 71.06(10) . .
Ag4 Ag3 Ag1 108.294(18) . .
O8 Ag3 Ag2 131.97(12) . .
C2 Ag3 Ag2 45.85(11) . .
O2 Ag3 Ag2 93.36(10) . .
C1 Ag3 Ag2 68.63(10) . .
Ag4 Ag3 Ag2 109.802(18) . .
Ag1 Ag3 Ag2 53.201(13) . .
O8 Ag3 Ag2 145.89(14) . 5_656
C2 Ag3 Ag2 52.01(11) . 5_656
O2 Ag3 Ag2 59.61(10) . 5_656
C1 Ag3 Ag2 45.02(10) . 5_656
Ag4 Ag3 Ag2 63.370(15) . 5_656
Ag1 Ag3 Ag2 94.532(16) . 5_656
Ag2 Ag3 Ag2 54.437(16) . 5_656
O7 Ag6 C2 168.3(2) . .
O7 Ag6 O2 89.24(19) . 5_656
C2 Ag6 O2 101.95(15) . 5_656
O7 Ag6 Ag1 131.41(16) . .
C2 Ag6 Ag1 49.19(12) . .
O2 Ag6 Ag1 104.81(10) 5_656 .
O7 Ag6 Ag2 146.96(18) . .
C2 Ag6 Ag2 44.66(11) . .
O2 Ag6 Ag2 61.11(10) 5_656 .
Ag1 Ag6 Ag2 53.474(14) . .
O7 Ag6 Ag6 75.12(15) . 2_655
C2 Ag6 Ag6 97.99(12) . 2_655
O2 Ag6 Ag6 139.20(10) 5_656 2_655
Ag1 Ag6 Ag6 63.870(16) . 2_655
Ag2 Ag6 Ag6 117.01(2) . 2_655
O7 Ag6 Ag1 118.42(17) . 2_655
C2 Ag6 Ag1 50.93(11) . 2_655
O2 Ag6 Ag1 151.71(10) 5_656 2_655
Ag1 Ag6 Ag1 53.292(16) . 2_655
Ag2 Ag6 Ag1 90.657(16) . 2_655
Ag6 Ag6 Ag1 53.189(14) 2_655 2_655
C1 Ag5 N1 159.61(17) . 5
C1 Ag5 O1W 108.4(2) . .
N1 Ag5 O1W 91.8(2) 5 .
C1 Ag5 Ag4 51.49(12) . .
N1 Ag5 Ag4 108.37(12) 5 .
O1W Ag5 Ag4 154.59(18) . .
C1 Ag5 Ag2 48.10(12) . 5_656
N1 Ag5 Ag2 127.27(14) 5 5_656
O1W Ag5 Ag2 111.38(19) . 5_656
Ag4 Ag5 Ag2 68.822(16) . 5_656
C2 C1 Ag5 140.7(4) . .
C2 C1 Ag4 140.9(4) . .
Ag5 C1 Ag4 78.34(15) . .
C2 C1 Ag2 88.4(3) . 5_656
Ag5 C1 Ag2 89.74(16) . 5_656
Ag4 C1 Ag2 95.21(17) . 5_656
C2 C1 Ag1 78.3(3) . 2_655
Ag5 C1 Ag1 107.06(17) . 2_655
Ag4 C1 Ag1 88.93(15) . 2_655
Ag2 C1 Ag1 163.2(2) 5_656 2_655
C2 C1 Ag3 63.3(3) . .
Ag5 C1 Ag3 155.0(2) . .
Ag4 C1 Ag3 78.40(14) . .
Ag2 C1 Ag3 83.39(14) 5_656 .
Ag1 C1 Ag3 81.49(13) 2_655 .
C1 C2 Ag6 100.8(3) . .
C1 C2 Ag1 144.6(4) . .
Ag6 C2 Ag1 82.87(16) . .
C1 C2 Ag2 137.9(4) . .
Ag6 C2 Ag2 92.66(17) . .
Ag1 C2 Ag2 76.29(14) . .
C1 C2 Ag3 88.7(3) . .
Ag6 C2 Ag3 166.3(2) . .
Ag1 C2 Ag3 83.71(16) . .
Ag2 C2 Ag3 86.62(16) . .
C1 C2 Ag1 73.6(3) . 2_655
Ag6 C2 Ag1 87.26(15) . 2_655
Ag1 C2 Ag1 71.38(13) . 2_655
Ag2 C2 Ag1 147.4(2) . 2_655
Ag3 C2 Ag1 86.05(15) . 2_655
C1 C2 Ag2 63.8(3) . 5_656
Ag6 C2 Ag2 109.41(18) . 5_656
Ag1 C2 Ag2 148.3(2) . 5_656
Ag2 C2 Ag2 74.05(12) . 5_656
Ag3 C2 Ag2 83.52(14) . 5_656
Ag1 C2 Ag2 136.25(18) 2_655 5_656
C3 O1 Ag4 123.5(4) . .
C3 O2 Ag6 141.0(4) . 5_656
C3 O2 Ag3 101.7(4) . .
Ag6 O2 Ag3 115.52(16) 5_656 .
O1 C3 O2 128.0(6) . .
O1 C3 C4 115.9(6) . .
O2 C3 C4 116.1(6) . .
F11 C4 F13 109.3(9) . .
F11 C4 F12 106.7(10) . .
F13 C4 F12 102.1(8) . .
F11 C4 C3 114.4(7) . .
F13 C4 C3 112.6(7) . .
F12 C4 C3 110.8(7) . .
C5 O3 Ag1 117.2(4) . .
C5 O4 Ag2 124.6(4) . .
O4 C5 O3 130.1(5) . .
O4 C5 C6 116.0(5) . .
O3 C5 C6 113.8(6) . .
F21 C6 F23 107.0(9) . .
F21 C6 F22 107.1(9) . .
F23 C6 F22 106.1(7) . .
F21 C6 C5 111.4(7) . .
F23 C6 C5 112.2(7) . .
F22 C6 C5 112.7(6) . .
C7 O5 Ag1 123.1(4) . .
C7 O5 Ag4 149.6(4) . 2_655
Ag1 O5 Ag4 84.43(14) . 2_655
O6 C7 O5 128.2(5) . .
O6 C7 C8 116.9(5) . .
O5 C7 C8 114.8(5) . .
F31 C8 F32 105.1(7) . .
F31 C8 F33 108.9(8) . .
F32 C8 F33 105.5(8) . .
F31 C8 C7 111.7(6) . .
F32 C8 C7 111.3(7) . .
F33 C8 C7 113.9(6) . .
C9 O7 Ag6 128.1(5) . .
O7 C9 O7 131.5(9) 2_655 .
O7 C9 C10 114.2(4) 2_655 .
O7 C9 C10 114.2(4) . .
F42 C10 F42 125(2) 2_655 .
F42 C10 F43 113.6(14) 2_655 .
F42 C10 F43 36(2) . .
F42 C10 F43 36(2) 2_655 2_655
F42 C10 F43 113.6(14) . 2_655
F43 C10 F43 127(3) . 2_655
F42 C10 F41 66.4(16) 2_655 2_655
F42 C10 F41 103.4(15) . 2_655
F43 C10 F41 68.0(15) . 2_655
F43 C10 F41 102.1(17) 2_655 2_655
F42 C10 F41 103.4(15) 2_655 .
F42 C10 F41 66.4(16) . .
F43 C10 F41 102.1(17) . .
F43 C10 F41 68.0(15) 2_655 .
F41 C10 F41 158.8(17) 2_655 .
F42 C10 C9 117.4(11) 2_655 .
F42 C10 C9 117.4(11) . .
F43 C10 C9 116.4(17) . .
F43 C10 C9 116.4(17) 2_655 .
F41 C10 C9 100.6(8) 2_655 .
F41 C10 C9 100.6(8) . .
F42 F41 C10 46.2(9) . .
F42 F41 F43 82.5(19) . 2_655
C10 F41 F43 47.1(14) . 2_655
F43 F42 C10 75(3) . .
F43 F42 F41 142(5) . .
C10 F42 F41 67.4(16) . .
F42 F43 C10 69(4) . .
F42 F43 F41 132(5) . 2_655
C10 F43 F41 64.9(15) . 2_655
C11 O8 Ag3 128.4(4) . .
O8 C11 O8 131.6(8) . 2_655
O8 C11 C12 114.2(4) . .
O8 C11 C12 114.2(4) 2_655 .
F53 C12 F53 125(3) 2_655 .
F53 C12 F52 36(3) 2_655 2_655
F53 C12 F52 118(2) . 2_655
F53 C12 F52 118(2) 2_655 .
F53 C12 F52 36(3) . .
F52 C12 F52 137(3) 2_655 .
F53 C12 F51 102(2) 2_655 2_655
F53 C12 F51 65(2) . 2_655
F52 C12 F51 69.5(16) 2_655 2_655
F52 C12 F51 100.5(18) . 2_655
F53 C12 F51 65(2) 2_655 .
F53 C12 F51 102(2) . .
F52 C12 F51 100.5(18) 2_655 .
F52 C12 F51 69.5(16) . .
F51 C12 F51 153.3(19) 2_655 .
F53 C12 C11 117.4(13) 2_655 .
F53 C12 C11 117.4(13) . .
F52 C12 C11 111.4(16) 2_655 .
F52 C12 C11 111.4(16) . .
F51 C12 C11 103.4(9) 2_655 .
F51 C12 C11 103.4(9) . .
F53 F51 C12 48.5(13) 2_655 .
F53 F51 F52 88.8(19) 2_655 .
C12 F51 F52 48.8(11) . .
F53 F52 C12 68(4) . .
F53 F52 F51 124(5) . .
C12 F52 F51 61.7(15) . .
F52 F53 C12 76(4) . .
F52 F53 F51 143(4) . 2_655
C12 F53 F51 67(2) . 2_655
C14 N1 C15 118.0(5) . .
C14 N1 Ag5 120.8(4) . 5
C15 N1 Ag5 120.8(4) . 5
C18 O9 Ag4 133.1(4) . .
C17 C13 C14 119.0(5) . .
N1 C14 C13 122.9(5) . .
N1 C15 C16 122.4(5) . .
C17 C16 C15 119.3(5) . .
C16 C17 C13 118.4(5) . .
C16 C17 C18 119.2(5) . .
C13 C17 C18 122.3(5) . .
O9 C18 N2 124.2(5) . .
O9 C18 C17 117.0(5) . .
N2 C18 C17 118.7(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O3 2.264(4) .
Ag1 C2 2.265(5) .
Ag1 O5 2.400(4) .
Ag1 C1 2.536(4) 2_655
Ag1 C2 2.588(4) 2_655
Ag1 Ag2 2.8227(5) .
Ag1 Ag1 2.8436(7) 2_655
Ag1 Ag6 2.9697(7) .
Ag1 Ag3 3.0934(6) .
Ag1 Ag4 3.3249(6) 2_655
Ag1 Ag6 3.3301(7) 2_655
Ag2 C2 2.305(4) .
Ag2 O4 2.327(4) .
Ag2 C1 2.393(4) 5_656
Ag2 C2 2.666(5) 5_656
Ag2 Ag2 3.0069(8) 5_656
Ag2 Ag3 3.2065(7) .
Ag2 Ag5 3.2153(6) 5_656
Ag2 Ag6 3.2750(7) .
Ag2 Ag3 3.3609(7) 5_656
Ag4 C1 2.199(5) .
Ag4 O9 2.216(4) .
Ag4 O1 2.405(4) .
Ag4 O5 2.546(5) 2_655
Ag4 Ag5 2.7520(7) .
Ag4 Ag3 3.0851(7) .
Ag4 Ag1 3.3249(6) 2_655
Ag3 O8 2.232(4) .
Ag3 C2 2.369(5) .
Ag3 O2 2.548(4) .
Ag3 C1 2.651(5) .
Ag3 Ag2 3.3609(7) 5_656
Ag6 O7 2.178(5) .
Ag6 C2 2.222(5) .
Ag6 O2 2.532(4) 5_656
Ag6 Ag6 3.3032(11) 2_655
Ag6 Ag1 3.3301(7) 2_655
Ag5 C1 2.158(5) .
Ag5 N1 2.187(4) 5
Ag5 O1W 2.455(6) .
Ag5 Ag2 3.2153(6) 5_656
C1 C2 1.245(6) .
C1 Ag2 2.393(4) 5_656
C1 Ag1 2.536(4) 2_655
C2 Ag1 2.588(4) 2_655
C2 Ag2 2.666(5) 5_656
O1 C3 1.230(7) .
O2 C3 1.238(7) .
O2 Ag6 2.532(4) 5_656
C3 C4 1.529(10) .
C4 F11 1.264(10) .
C4 F13 1.296(10) .
C4 F12 1.338(12) .
O3 C5 1.238(7) .
O4 C5 1.223(7) .
C5 C6 1.542(9) .
C6 F21 1.270(12) .
C6 F23 1.298(10) .
C6 F22 1.314(9) .
O5 C7 1.236(7) .
O5 Ag4 2.546(5) 2_655
O6 C7 1.233(7) .
C7 C8 1.536(8) .
C8 F31 1.291(10) .
C8 F32 1.294(10) .
C8 F33 1.299(9) .
O7 C9 1.211(6) .
C9 O7 1.211(6) 2_655
C9 C10 1.537(13) .
C10 F42 1.19(2) 2_655
C10 F42 1.19(2) .
C10 F43 1.24(3) .
C10 F43 1.24(3) 2_655
C10 F41 1.53(2) 2_655
C10 F41 1.53(2) .
F41 F42 1.52(4) .
F41 F43 1.57(3) 2_655
F42 F43 0.75(5) .
F43 F41 1.57(3) 2_655
O8 C11 1.229(5) .
C11 O8 1.229(5) 2_655
C11 C12 1.549(13) .
C12 F53 1.19(2) 2_655
C12 F53 1.19(2) .
C12 F52 1.25(3) 2_655
C12 F52 1.25(3) .
C12 F51 1.46(2) 2_655
C12 F51 1.46(2) .
F51 F53 1.44(5) 2_655
F51 F52 1.56(3) .
F52 F53 0.75(7) .
F53 F51 1.44(5) 2_655
N1 C14 1.313(7) .
N1 C15 1.335(8) .
N1 Ag5 2.187(4) 5
N2 C18 1.312(7) .
O9 C18 1.230(6) .
C13 C17 1.377(7) .
C13 C14 1.392(7) .
C15 C16 1.396(8) .
C16 C17 1.358(8) .
C17 C18 1.507(6) .
