#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:51:44 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180017 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/11/7031112.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7031112
loop_
_publ_author_name
'Zhang, Kou-Lin'
'Zhong, Zhao-Yin'
'Zhang, Lei'
'Jing, Chu-Yue'
'Daniels, Luke M.'
'Walton, Richard I.'
_publ_section_title
;
 Synthesis, characterization and properties of a family of
 lead(ii)-organic frameworks based on a multi-functional ligand
 2-amino-4-sulfobenzoic acid exhibiting auxiliary ligand-dependent
 dehydration-rehydration behaviours.
;
_journal_issue                   30
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11597
_journal_page_last               11610
_journal_paper_doi               10.1039/c4dt00659c
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C28 H28 N6 O12 Pb2 S2'
_chemical_formula_weight         1119.06
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.0520(10)
_cell_angle_beta                 92.705(2)
_cell_angle_gamma                93.508(2)
_cell_formula_units_Z            2
_cell_length_a                   5.9314(7)
_cell_length_b                   11.0291(13)
_cell_length_c                   24.939(3)
_cell_measurement_reflns_used    5028
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.4362
_cell_measurement_theta_min      2.2061
_cell_volume                     1595.3(3)
_computing_cell_refinement       'SAINT (Bruker, 2005)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'SAINT (Bruker, 2005)'
_computing_molecular_graphics    'Diamond (CRYSTAL IMPACT, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 8.3
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker APEXII area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0436
_diffrn_reflns_av_unetI/netI     0.0652
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            14086
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         1.67
_exptl_absorpt_coefficient_mu    10.745
_exptl_absorpt_correction_T_max  0.2956
_exptl_absorpt_correction_T_min  0.1169
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            YELLOW
_exptl_crystal_density_diffrn    2.330
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             1060
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.826
_refine_diff_density_min         -1.643
_refine_diff_density_rms         0.211
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         7182
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0527
_refine_ls_R_factor_gt           0.0394
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0335P)²+8.4058P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0963
_refine_ls_wR_factor_ref         0.1085
_reflns_number_gt                5774
_reflns_number_total             7182
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt00659c2.cif
_cod_data_source_block           6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'TRICLINIC' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed
to 'constr' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7031110--7031114.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7031112
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.7160(13) 0.1780(7) 0.8239(3) 0.0272(17) Uani 1 1 d .
C2 C 0.9971(13) 0.3678(7) 0.8571(3) 0.0270(17) Uani 1 1 d .
C3 C 1.0507(13) 0.4933(7) 0.8573(3) 0.0292(17) Uani 1 1 d .
H3 H 1.1903 0.5304 0.8725 0.035 Uiso 1 1 calc R
C4 C 0.8982(12) 0.5623(7) 0.8354(3) 0.0213(15) Uani 1 1 d .
C5 C 0.6846(14) 0.5120(7) 0.8126(3) 0.0298(18) Uani 1 1 d .
H5 H 0.5801 0.5605 0.7995 0.036 Uiso 1 1 calc R
C6 C 0.6362(14) 0.3869(7) 0.8103(3) 0.0298(18) Uani 1 1 d .
H6 H 0.4980 0.3505 0.7939 0.036 Uiso 1 1 calc R
C7 C 0.7858(13) 0.3128(7) 0.8316(3) 0.0248(16) Uani 1 1 d .
C8 C 0.6883(15) 0.4388(9) 0.9833(4) 0.040(2) Uani 1 1 d .
H8 H 0.8143 0.3973 0.9715 0.048 Uiso 1 1 calc R
C9 C 0.3510(16) 0.4496(9) 1.0319(4) 0.041(2) Uani 1 1 d .
H9 H 0.2491 0.4153 1.0530 0.049 Uiso 1 1 calc R
C10 C 0.5408(15) 0.3890(8) 1.0158(3) 0.0329(18) Uani 1 1 d .
C11 C 0.5743(17) 0.2631(8) 1.0307(4) 0.041(2) Uani 1 1 d .
H11A H 0.7349 0.2540 1.0364 0.050 Uiso 1 1 calc R
H11B H 0.5043 0.2590 1.0648 0.050 Uiso 1 1 calc R
C12 C 0.5733(14) 0.1115(8) 0.9421(4) 0.0343(19) Uani 1 1 d .
H12 H 0.7211 0.1328 0.9346 0.041 Uiso 1 1 calc R
C13 C 0.2601(13) 0.1064(7) 0.9842(3) 0.0304(18) Uani 1 1 d .
H13 H 0.1522 0.1223 1.0100 0.037 Uiso 1 1 calc R
C14 C 0.2336(16) 0.0247(8) 0.9358(4) 0.038(2) Uani 1 1 d .
H14 H 0.1032 -0.0255 0.9227 0.046 Uiso 1 1 calc R
C15 C 0.6143(14) 0.7047(8) 0.6578(3) 0.0303(18) Uani 1 1 d .
C16 C 0.7499(14) 0.6136(8) 0.6350(4) 0.037(2) Uani 1 1 d .
H16 H 0.8777 0.6330 0.6173 0.044 Uiso 1 1 calc R
C17 C 0.6906(15) 0.4911(9) 0.6394(4) 0.039(2) Uani 1 1 d .
H17 H 0.7793 0.4283 0.6241 0.047 Uiso 1 1 calc R
C18 C 0.4983(15) 0.4624(7) 0.6665(4) 0.0326(18) Uani 1 1 d .
C19 C 0.3568(13) 0.5565(8) 0.6881(4) 0.0313(18) Uani 1 1 d .
C20 C 0.4206(14) 0.6774(8) 0.6823(3) 0.0323(18) Uani 1 1 d .
H20 H 0.3293 0.7409 0.6954 0.039 Uiso 1 1 calc R
C21 C 0.1960(16) 0.5509(9) 0.5301(4) 0.040(2) Uani 1 1 d .
H21 H 0.3296 0.5840 0.5500 0.048 Uiso 1 1 calc R
C22 C 0.1273(17) 0.4281(9) 0.5272(4) 0.045(2) Uani 1 1 d .
H22 H 0.2129 0.3805 0.5462 0.054 Uiso 1 1 calc R
C23 C -0.0673(15) 0.3736(8) 0.4964(3) 0.0341(19) Uani 1 1 d .
C24 C -0.1495(17) 0.2395(8) 0.4911(4) 0.042(2) Uani 1 1 d .
H24A H -0.2993 0.2348 0.5050 0.051 Uiso 1 1 calc R
H24B H -0.1614 0.1999 0.4527 0.051 Uiso 1 1 calc R
C25 C 0.2026(14) 0.1246(8) 0.5038(4) 0.0336(19) Uani 1 1 d .
H25 H 0.2601 0.1217 0.4695 0.040 Uiso 1 1 calc R
C26 C -0.0181(14) 0.1561(8) 0.5723(4) 0.0330(18) Uani 1 1 d .
H26 H -0.1396 0.1790 0.5933 0.040 Uiso 1 1 calc R
C27 C 0.2970(17) 0.0832(9) 0.5458(3) 0.040(2) Uani 1 1 d .
H27 H 0.4347 0.0472 0.5460 0.048 Uiso 1 1 calc R
C28 C 0.4527(14) 0.3318(7) 0.6725(3) 0.0297(18) Uani 1 1 d .
N1 N 0.4761(11) 0.1612(6) 0.9879(3) 0.0315(15) Uani 1 1 d .
N2 N 0.4344(11) 0.0282(6) 0.9086(3) 0.0298(15) Uani 1 1 d .
N3 N 1.1456(13) 0.3042(7) 0.8828(3) 0.044(2) Uani 1 1 d .
H3A H 1.2696 0.3414 0.8987 0.053 Uiso 1 1 calc R
H3B H 1.1150 0.2271 0.8830 0.053 Uiso 1 1 calc R
N4 N 0.0019(12) 0.1729(6) 0.5211(3) 0.0318(15) Uani 1 1 d .
N5 N 0.1579(13) 0.1024(7) 0.5891(3) 0.0357(17) Uani 1 1 d .
N6 N 0.1745(13) 0.5360(8) 0.7166(4) 0.049(2) Uani 1 1 d .
H6A H 0.0989 0.5969 0.7309 0.059 Uiso 1 1 calc R
H6B H 0.1341 0.4620 0.7204 0.059 Uiso 1 1 calc R
O1 O 0.8362(11) 0.7919(6) 0.8791(3) 0.0411(15) Uani 1 1 d .
O2 O 1.2133(9) 0.7448(5) 0.8491(2) 0.0317(13) Uani 1 1 d .
O3 O 0.8971(9) 0.7448(5) 0.7833(2) 0.0322(13) Uani 1 1 d .
O4 O 0.8507(10) 0.1041(5) 0.8409(3) 0.0355(14) Uani 1 1 d .
O5 O 0.5220(10) 0.1378(5) 0.8031(3) 0.0372(14) Uani 1 1 d .
O6 O 0.5917(11) 0.2515(6) 0.6571(3) 0.0435(16) Uani 1 1 d .
O7 O 0.2710(11) 0.3016(6) 0.6928(3) 0.0400(15) Uani 1 1 d .
O8 O 0.5421(11) 0.8977(6) 0.6154(3) 0.0435(16) Uani 1 1 d .
O9 O 0.6612(10) 0.9325(5) 0.7113(2) 0.0367(14) Uani 1 1 d .
O10 O 0.9281(10) 0.8701(6) 0.6428(3) 0.0439(16) Uani 1 1 d .
O1W O 0.1453(9) -0.0379(5) 0.7770(2) 0.0333(13) Uani 1 1 d D
H1WA H 0.0820 0.0211 0.7965 0.040 Uiso 1 1 d RD
H1WB H 0.0540 -0.1024 0.7705 0.040 Uiso 1 1 d RD
O2W O -0.0874(10) 0.1483(6) 0.7136(3) 0.0420(15) Uani 1 1 d D
H2WA H -0.1819 0.1925 0.7010 0.050 Uiso 1 1 d RD
H2WB H -0.1155 0.0728 0.6983 0.050 Uiso 1 1 d RD
Pb1 Pb 0.27223(5) 0.08053(3) 0.681053(13) 0.03061(10) Uani 1 1 d .
Pb2 Pb 0.52787(5) -0.07767(3) 0.816879(11) 0.02319(9) Uani 1 1 d .
S1 S 0.6941(3) 0.86158(19) 0.65565(8) 0.0286(4) Uani 1 1 d .
S2 S 0.9701(3) 0.72317(17) 0.83740(8) 0.0245(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 C1 O4 120.3(7) . .
O5 C1 C7 119.8(7) . .
O4 C1 C7 119.9(7) . .
N3 C2 C3 119.0(7) . .
N3 C2 C7 122.7(7) . .
C3 C2 C7 118.3(7) . .
C4 C3 C2 120.5(7) . .
C3 C4 C5 122.3(7) . .
C3 C4 S2 119.3(6) . .
C5 C4 S2 118.3(6) . .
C6 C5 C4 117.0(7) . .
C5 C6 C7 122.8(7) . .
C6 C7 C2 119.0(7) . .
C6 C7 C1 117.0(7) . .
C2 C7 C1 123.9(7) . .
C10 C8 C9 120.1(8) . 2_667
C10 C9 C8 120.4(8) . 2_667
C8 C10 C9 119.5(8) . .
C8 C10 C11 121.0(9) . .
C9 C10 C11 119.3(8) . .
N1 C11 C10 111.7(7) . .
N2 C12 N1 112.3(7) . .
C14 C13 N1 107.2(7) . .
C13 C14 N2 108.9(8) . .
C20 C15 C16 121.7(8) . .
C20 C15 S1 119.2(7) . .
C16 C15 S1 119.1(6) . .
C15 C16 C17 118.4(8) . .
C16 C17 C18 120.6(8) . .
C17 C18 C19 120.3(8) . .
C17 C18 C28 117.8(8) . .
C19 C18 C28 121.9(8) . .
N6 C19 C20 119.4(8) . .
N6 C19 C18 123.3(8) . .
C20 C19 C18 117.2(7) . .
C15 C20 C19 121.7(8) . .
C22 C21 C23 120.8(8) . 2_566
C21 C22 C23 121.6(8) . .
C22 C23 C21 117.6(8) . 2_566
C22 C23 C24 124.0(8) . .
C21 C23 C24 118.4(8) 2_566 .
N4 C24 C23 112.0(7) . .
C27 C25 N4 106.6(8) . .
N5 C26 N4 110.9(7) . .
C25 C27 N5 109.2(9) . .
O6 C28 O7 120.4(8) . .
O6 C28 C18 120.7(8) . .
O7 C28 C18 118.9(7) . .
C12 N1 C13 106.8(7) . .
C12 N1 C11 126.2(8) . .
C13 N1 C11 126.7(7) . .
C12 N2 C14 104.8(7) . .
C12 N2 Pb2 124.2(6) . .
C14 N2 Pb2 130.9(5) . .
C26 N4 C25 107.1(7) . .
C26 N4 C24 126.0(8) . .
C25 N4 C24 126.7(8) . .
C26 N5 C27 106.2(7) . .
C26 N5 Pb1 128.8(6) . .
C27 N5 Pb1 123.7(6) . .
C1 O4 Pb2 89.7(5) . .
C1 O5 Pb2 98.9(5) . .
C28 O6 Pb1 86.3(5) . .
C28 O7 Pb1 103.3(5) . .
O7 Pb1 N5 79.2(2) . .
O7 Pb1 O2W 69.9(2) . .
N5 Pb1 O2W 90.8(2) . .
O7 Pb1 O6 49.8(2) . .
N5 Pb1 O6 75.8(2) . .
O2W Pb1 O6 119.5(2) . .
N2 Pb2 O5 79.4(2) . .
N2 Pb2 O1W 90.7(2) . .
O5 Pb2 O1W 69.01(18) . .
N2 Pb2 O4 77.8(2) . .
O5 Pb2 O4 51.02(18) . .
O1W Pb2 O4 119.99(18) . .
O10 S1 O8 113.4(4) . .
O10 S1 O9 111.3(4) . .
O8 S1 O9 110.8(4) . .
O10 S1 C15 108.3(4) . .
O8 S1 C15 107.1(4) . .
O9 S1 C15 105.4(4) . .
O2 S2 O1 114.0(4) . .
O2 S2 O3 112.9(3) . .
O1 S2 O3 109.9(4) . .
O2 S2 C4 107.4(3) . .
O1 S2 C4 106.6(3) . .
O3 S2 C4 105.4(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O5 1.258(10) .
C1 O4 1.289(10) .
C1 C7 1.493(10) .
C2 N3 1.368(10) .
C2 C3 1.400(10) .
C2 C7 1.424(11) .
C3 C4 1.376(11) .
C4 C5 1.401(10) .
C4 S2 1.790(7) .
C5 C6 1.382(10) .
C6 C7 1.395(11) .
C8 C10 1.380(12) .
C8 C9 1.384(13) 2_667
C9 C10 1.381(13) .
C9 C8 1.384(13) 2_667
C10 C11 1.528(12) .
C11 N1 1.464(11) .
C12 N2 1.330(11) .
C12 N1 1.340(11) .
C13 C14 1.358(12) .
C13 N1 1.374(10) .
C14 N2 1.400(11) .
C15 C20 1.371(11) .
C15 C16 1.379(12) .
C15 S1 1.777(8) .
C16 C17 1.400(12) .
C17 C18 1.404(12) .
C18 C19 1.416(12) .
C18 C28 1.487(11) .
C19 N6 1.352(11) .
C19 C20 1.400(11) .
C21 C22 1.377(13) .
C21 C23 1.398(12) 2_566
C22 C23 1.392(12) .
C23 C21 1.398(12) 2_566
C23 C24 1.508(12) .
C24 N4 1.461(11) .
C25 C27 1.335(13) .
C25 N4 1.387(11) .
C26 N5 1.321(11) .
C26 N4 1.334(11) .
C27 N5 1.381(11) .
C28 O6 1.265(10) .
C28 O7 1.265(10) .
N2 Pb2 2.466(7) .
N5 Pb1 2.422(7) .
O1 S2 1.462(6) .
O2 S2 1.454(5) .
O3 S2 1.464(6) .
O4 Pb2 2.647(6) .
O5 Pb2 2.468(6) .
O6 Pb1 2.758(6) .
O7 Pb1 2.400(6) .
O8 S1 1.445(6) .
O9 S1 1.486(6) .
O10 S1 1.440(6) .
O1W Pb2 2.531(5) .
O2W Pb1 2.428(6) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N3 C2 C3 C4 -175.4(8) . .
C7 C2 C3 C4 2.6(12) . .
C2 C3 C4 C5 0.7(12) . .
C2 C3 C4 S2 178.9(6) . .
C3 C4 C5 C6 -3.3(12) . .
S2 C4 C5 C6 178.4(6) . .
C4 C5 C6 C7 2.7(12) . .
C5 C6 C7 C2 0.5(13) . .
C5 C6 C7 C1 -177.1(8) . .
N3 C2 C7 C6 174.7(8) . .
C3 C2 C7 C6 -3.2(12) . .
N3 C2 C7 C1 -7.8(13) . .
C3 C2 C7 C1 174.3(7) . .
O5 C1 C7 C6 -5.6(11) . .
O4 C1 C7 C6 177.5(7) . .
O5 C1 C7 C2 176.9(8) . .
O4 C1 C7 C2 0.0(12) . .
C9 C8 C10 C9 1.7(15) 2_667 .
C9 C8 C10 C11 177.0(8) 2_667 .
C8 C9 C10 C8 -1.7(15) 2_667 .
C8 C9 C10 C11 -177.1(8) 2_667 .
C8 C10 C11 N1 -84.1(11) . .
C9 C10 C11 N1 91.2(10) . .
N1 C13 C14 N2 -0.1(10) . .
C20 C15 C16 C17 -2.5(14) . .
S1 C15 C16 C17 177.0(7) . .
C15 C16 C17 C18 -0.4(14) . .
C16 C17 C18 C19 2.5(14) . .
C16 C17 C18 C28 -176.4(8) . .
C17 C18 C19 N6 -177.3(9) . .
C28 C18 C19 N6 1.6(14) . .
C17 C18 C19 C20 -1.6(13) . .
C28 C18 C19 C20 177.3(8) . .
C16 C15 C20 C19 3.5(13) . .
S1 C15 C20 C19 -176.1(7) . .
N6 C19 C20 C15 174.6(8) . .
C18 C19 C20 C15 -1.3(12) . .
C23 C21 C22 C23 2.3(17) 2_566 .
C21 C22 C23 C21 -2.2(17) . 2_566
C21 C22 C23 C24 179.3(10) . .
C22 C23 C24 N4 -1.4(14) . .
C21 C23 C24 N4 -179.8(8) 2_566 .
N4 C25 C27 N5 1.1(10) . .
C17 C18 C28 O6 5.0(12) . .
C19 C18 C28 O6 -173.9(8) . .
C17 C18 C28 O7 -174.3(8) . .
C19 C18 C28 O7 6.9(12) . .
N2 C12 N1 C13 0.3(10) . .
N2 C12 N1 C11 -174.1(8) . .
C14 C13 N1 C12 -0.1(9) . .
C14 C13 N1 C11 174.3(8) . .
C10 C11 N1 C12 82.3(11) . .
C10 C11 N1 C13 -91.0(10) . .
N1 C12 N2 C14 -0.4(10) . .
N1 C12 N2 Pb2 175.7(5) . .
C13 C14 N2 C12 0.3(9) . .
C13 C14 N2 Pb2 -175.4(6) . .
N5 C26 N4 C25 1.1(10) . .
N5 C26 N4 C24 -174.0(8) . .
C27 C25 N4 C26 -1.3(10) . .
C27 C25 N4 C24 173.7(8) . .
C23 C24 N4 C26 93.5(10) . .
C23 C24 N4 C25 -80.7(11) . .
N4 C26 N5 C27 -0.5(10) . .
N4 C26 N5 Pb1 166.7(5) . .
C25 C27 N5 C26 -0.4(10) . .
C25 C27 N5 Pb1 -168.4(6) . .
O5 C1 O4 Pb2 -3.8(8) . .
C7 C1 O4 Pb2 173.0(6) . .
O4 C1 O5 Pb2 4.1(8) . .
C7 C1 O5 Pb2 -172.7(6) . .
O7 C28 O6 Pb1 5.3(8) . .
C18 C28 O6 Pb1 -173.9(7) . .
O6 C28 O7 Pb1 -6.3(9) . .
C18 C28 O7 Pb1 173.0(6) . .
C28 O7 Pb1 N5 -77.3(5) . .
C28 O7 Pb1 O2W -172.2(6) . .
C28 O7 Pb1 O6 3.3(5) . .
C26 N5 Pb1 O7 -57.9(7) . .
C27 N5 Pb1 O7 107.2(7) . .
C26 N5 Pb1 O2W 11.4(8) . .
C27 N5 Pb1 O2W 176.5(7) . .
C26 N5 Pb1 O6 -108.9(8) . .
C27 N5 Pb1 O6 56.2(7) . .
C28 O6 Pb1 O7 -3.2(5) . .
C28 O6 Pb1 N5 84.5(5) . .
C28 O6 Pb1 O2W 1.8(6) . .
C12 N2 Pb2 O5 -65.6(7) . .
C14 N2 Pb2 O5 109.5(7) . .
C12 N2 Pb2 O1W -134.0(7) . .
C14 N2 Pb2 O1W 41.0(7) . .
C12 N2 Pb2 O4 -13.5(6) . .
C14 N2 Pb2 O4 161.6(7) . .
C1 O5 Pb2 N2 80.6(5) . .
C1 O5 Pb2 O1W 175.5(5) . .
C1 O5 Pb2 O4 -2.2(5) . .
C1 O4 Pb2 N2 -84.0(5) . .
C1 O4 Pb2 O5 2.1(4) . .
C1 O4 Pb2 O1W -0.3(5) . .
C20 C15 S1 O10 163.7(7) . .
C16 C15 S1 O10 -15.8(8) . .
C20 C15 S1 O8 -73.6(8) . .
C16 C15 S1 O8 106.9(8) . .
C20 C15 S1 O9 44.4(8) . .
C16 C15 S1 O9 -135.1(7) . .
C3 C4 S2 O2 16.2(7) . .
C5 C4 S2 O2 -165.5(6) . .
C3 C4 S2 O1 -106.4(7) . .
C5 C4 S2 O1 71.9(7) . .
C3 C4 S2 O3 136.9(6) . .
C5 C4 S2 O3 -44.8(7) . .
