#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:59:02 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180021 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/15/7031569.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7031569
loop_
_publ_author_name
'Liao, Jian-Hong'
'Chang, Hao-Wei'
'Li, Yi-Juan'
'Fang, Ching-Shiang'
'Sarkar, Bijay'
'van Zyl, Werner E.'
'Liu, C. W.'
_publ_section_title
;
 Anion templating from a silver(i) dithiophosphate 1D polymer forming
 discrete cationic and neutral octa- and decanuclear silver(i) clusters.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12380
_journal_page_last               12389
_journal_paper_doi               10.1039/c4dt00691g
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C36 H84 Ag8 O12 P6 S13'
_chemical_formula_weight         2174.59
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                117.1860(10)
_cell_angle_beta                 99.3420(10)
_cell_angle_gamma                95.4300(10)
_cell_formula_units_Z            1
_cell_length_a                   12.8486(12)
_cell_length_b                   12.9911(6)
_cell_length_c                   13.7516(6)
_cell_measurement_reflns_used    6518
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.09
_cell_measurement_theta_min      2.18
_cell_volume                     1977.1(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0227
_diffrn_reflns_av_sigmaI/netI    0.0327
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            13120
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.64
_exptl_absorpt_coefficient_mu    2.444
_exptl_absorpt_correction_T_max  0.8672
_exptl_absorpt_correction_T_min  0.3746
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.826
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       thin
_exptl_crystal_F_000             1070
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.833
_refine_diff_density_min         -0.963
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     333
_refine_ls_number_reflns         6878
_refine_ls_number_restraints     28
_refine_ls_restrained_S_all      1.094
_refine_ls_R_factor_all          0.0462
_refine_ls_R_factor_gt           0.0358
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0531P)²+1.6595P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1007
_refine_ls_wR_factor_ref         0.1062
_reflns_number_gt                5434
_reflns_number_total             6878
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt00691g2.cif
_cod_data_source_block           6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7031565--7031570.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7031569
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.50069(3) 0.79267(3) 0.52799(3) 0.05742(12) Uani 1 1 d . . .
Ag2 Ag 0.36371(3) 0.79898(3) 0.29889(3) 0.06101(13) Uani 1 1 d . . .
Ag3 Ag 0.28452(3) 1.03896(4) 0.46667(3) 0.06240(13) Uani 1 1 d . . .
Ag4 Ag 0.41709(4) 1.03759(3) 0.68983(3) 0.06000(13) Uani 1 1 d . . .
S1 S 0.34133(10) 0.82137(10) 0.61558(9) 0.0481(3) Uani 1 1 d . . .
S2 S 0.19861(10) 0.82425(11) 0.37681(11) 0.0543(3) Uani 1 1 d . . .
S3 S 0.40156(12) 0.88060(11) 0.17233(10) 0.0612(3) Uani 1 1 d . . .
S4 S 0.31261(11) 1.13490(11) 0.34759(11) 0.0596(3) Uani 1 1 d . . .
S5 S 0.29575(11) 1.17211(10) 0.67228(11) 0.0554(3) Uani 1 1 d . . .
S6 S 0.47176(10) 0.65524(10) 0.32018(10) 0.0518(3) Uani 1 1 d . . .
S7 S 0.5000 1.0000 0.5000 0.0391(3) Uani 1 2 d S . .
P1 P 0.31931(15) 1.01042(12) 0.19534(12) 0.0753(5) Uani 1 1 d DU . .
P2 P 0.61904(10) 0.67146(9) 0.29108(9) 0.0448(3) Uani 1 1 d . . .
P3 P 0.21491(9) 0.75698(10) 0.48329(10) 0.0461(3) Uani 1 1 d . . .
O1 O 0.3290(9) 1.0637(8) 0.1184(7) 0.0912(15) Uani 0.50 1 d PDU A 1
O2 O 0.1893(6) 0.9538(8) 0.1561(7) 0.0912(15) Uani 0.50 1 d PDU A 1
O1' O 0.3980(8) 1.0789(8) 0.1502(7) 0.0912(15) Uani 0.50 1 d PDU A 2
O2' O 0.2196(8) 0.9625(8) 0.1025(7) 0.0912(15) Uani 0.50 1 d PD A 2
O3 O 0.6007(3) 0.5833(3) 0.1629(3) 0.0592(8) Uani 1 1 d . . .
O4 O 0.6963(3) 0.6283(3) 0.3589(3) 0.0570(8) Uani 1 1 d . . .
O5 O 0.1095(3) 0.7575(3) 0.5264(3) 0.0671(9) Uani 1 1 d . . .
O6 O 0.2173(3) 0.6229(3) 0.4176(3) 0.0605(9) Uani 1 1 d . . .
C1 C 0.3471(14) 1.1682(16) 0.1178(14) 0.117(3) Uani 0.50 1 d PDU A 1
H1 H 0.3105 1.2257 0.1684 0.140 Uiso 0.50 1 calc PR A 1
C2 C 0.290(2) 1.120(2) -0.0052(14) 0.159(3) Uani 0.50 1 d PDU A 1
H2A H 0.3094 1.0461 -0.0502 0.239 Uiso 0.50 1 calc PR A 1
H2B H 0.3121 1.1752 -0.0302 0.239 Uiso 0.50 1 calc PR A 1
H2C H 0.2140 1.1096 -0.0126 0.239 Uiso 0.50 1 calc PR A 1
C3 C 0.4634(16) 1.226(2) 0.1277(19) 0.159(3) Uani 0.50 1 d PDU A 1
H3A H 0.4983 1.2762 0.2055 0.239 Uiso 0.50 1 calc PR A 1
H3B H 0.4597 1.2726 0.0896 0.239 Uiso 0.50 1 calc PR A 1
H3C H 0.5037 1.1658 0.0939 0.239 Uiso 0.50 1 calc PR A 1
C4 C 0.1370(17) 0.8332(12) 0.0793(14) 0.117(3) Uani 0.50 1 d PDU A 1
H4 H 0.1774 0.7755 0.0859 0.140 Uiso 0.50 1 calc PR A 1
C5 C 0.0195(17) 0.811(2) 0.0851(19) 0.159(3) Uani 0.50 1 d PDU A 1
H5A H 0.0165 0.8271 0.1600 0.239 Uiso 0.50 1 calc PR A 1
H5B H -0.0129 0.7300 0.0333 0.239 Uiso 0.50 1 calc PR A 1
H5C H -0.0186 0.8614 0.0658 0.239 Uiso 0.50 1 calc PR A 1
C6 C 0.102(2) 0.811(3) -0.0410(17) 0.159(3) Uani 0.50 1 d PDU A 1
H6A H 0.0426 0.8489 -0.0470 0.239 Uiso 0.50 1 calc PR A 1
H6B H 0.0811 0.7278 -0.0911 0.239 Uiso 0.50 1 calc PR A 1
H6C H 0.1611 0.8427 -0.0606 0.239 Uiso 0.50 1 calc PR A 1
C1' C 0.4106(17) 1.1083(14) 0.0903(13) 0.117(3) Uani 0.50 1 d PDU A 2
H1' H 0.4863 1.1033 0.0905 0.140 Uiso 0.50 1 calc PR A 2
C2' C 0.365(2) 1.070(2) -0.0338(13) 0.159(3) Uani 0.50 1 d PDU A 2
H2D H 0.3979 1.0076 -0.0798 0.239 Uiso 0.50 1 calc PR A 2
H2E H 0.3787 1.1356 -0.0471 0.239 Uiso 0.50 1 calc PR A 2
H2F H 0.2884 1.0419 -0.0522 0.239 Uiso 0.50 1 calc PR A 2
C3' C 0.420(2) 1.2445(16) 0.1677(18) 0.159(3) Uani 0.50 1 d PDU A 2
H3D H 0.3957 1.2578 0.2341 0.239 Uiso 0.50 1 calc PR A 2
H3E H 0.3767 1.2755 0.1277 0.239 Uiso 0.50 1 calc PR A 2
H3F H 0.4938 1.2834 0.1886 0.239 Uiso 0.50 1 calc PR A 2
C4' C 0.1406(17) 0.8584(14) 0.0710(16) 0.117(3) Uani 0.50 1 d PD A 2
H4' H 0.1823 0.8172 0.1029 0.140 Uiso 0.50 1 calc PR A 2
C5' C 0.0490(18) 0.878(2) 0.1327(18) 0.159(3) Uani 0.50 1 d PD A 2
H5D H 0.0772 0.9339 0.2107 0.239 Uiso 0.50 1 calc PR A 2
H5E H 0.0166 0.8045 0.1258 0.239 Uiso 0.50 1 calc PR A 2
H5F H -0.0040 0.9078 0.1003 0.239 Uiso 0.50 1 calc PR A 2
C6' C 0.145(2) 0.792(3) -0.0515(17) 0.159(3) Uani 0.50 1 d PD A 2
H6D H 0.1202 0.8347 -0.0892 0.239 Uiso 0.50 1 calc PR A 2
H6E H 0.1010 0.7151 -0.0865 0.239 Uiso 0.50 1 calc PR A 2
H6F H 0.2184 0.7847 -0.0562 0.239 Uiso 0.50 1 calc PR A 2
C7 C 0.6873(5) 0.5609(5) 0.1019(5) 0.0746(16) Uani 1 1 d . . .
H7A H 0.7575 0.5908 0.1551 0.090 Uiso 1 1 calc R . .
C8 C 0.6706(7) 0.4305(6) 0.0307(7) 0.114(3) Uani 1 1 d . . .
H8A H 0.6789 0.3943 0.0780 0.171 Uiso 1 1 calc R . .
H8B H 0.7226 0.4115 -0.0146 0.171 Uiso 1 1 calc R . .
H8C H 0.5995 0.4015 -0.0171 0.171 Uiso 1 1 calc R . .
C9 C 0.6776(10) 0.6224(8) 0.0326(7) 0.137(4) Uani 1 1 d . . .
H9A H 0.6907 0.7061 0.0813 0.205 Uiso 1 1 calc R . .
H9B H 0.6065 0.5971 -0.0148 0.205 Uiso 1 1 calc R . .
H9C H 0.7292 0.6035 -0.0131 0.205 Uiso 1 1 calc R . .
C10 C 0.0701(6) 0.8608(7) 0.5920(7) 0.105(2) Uani 1 1 d U . .
H10A H 0.1202 0.9301 0.6053 0.126 Uiso 1 1 calc R . .
C11 C 0.0678(15) 0.8663(16) 0.6998(12) 0.251(10) Uani 1 1 d U . .
H11A H 0.0428 0.9360 0.7459 0.376 Uiso 1 1 calc R . .
H11B H 0.1388 0.8687 0.7367 0.376 Uiso 1 1 calc R . .
H11C H 0.0202 0.7979 0.6878 0.376 Uiso 1 1 calc R . .
C12 C -0.0322(10) 0.8604(15) 0.5357(12) 0.221(8) Uani 1 1 d U . .
H12A H -0.0276 0.8576 0.4656 0.331 Uiso 1 1 calc R . .
H12B H -0.0565 0.9308 0.5815 0.331 Uiso 1 1 calc R . .
H12C H -0.0821 0.7926 0.5217 0.331 Uiso 1 1 calc R . .
C13 C 0.1438(5) 0.5393(5) 0.3082(5) 0.0847(19) Uani 1 1 d U . .
H13A H 0.1164 0.5793 0.2667 0.102 Uiso 1 1 calc R . .
C14 C 0.0560(8) 0.4796(9) 0.3331(10) 0.195(5) Uani 1 1 d . . .
H14A H 0.0055 0.4249 0.2643 0.293 Uiso 1 1 calc R . .
H14B H 0.0203 0.5373 0.3813 0.293 Uiso 1 1 calc R . .
H14C H 0.0855 0.4379 0.3700 0.293 Uiso 1 1 calc R . .
C15 C 0.2044(8) 0.4501(9) 0.2454(9) 0.195(5) Uani 1 1 d U . .
H15A H 0.1596 0.3944 0.1732 0.293 Uiso 1 1 calc R . .
H15B H 0.2265 0.4098 0.2865 0.293 Uiso 1 1 calc R . .
H15C H 0.2667 0.4880 0.2357 0.293 Uiso 1 1 calc R . .
C16 C 0.6718(5) 0.5105(5) 0.3519(6) 0.0710(15) Uani 1 1 d . . .
H16A H 0.6127 0.4605 0.2862 0.085 Uiso 1 1 calc R . .
C17 C 0.6382(7) 0.5233(7) 0.4530(7) 0.104(2) Uani 1 1 d . . .
H17A H 0.5742 0.5563 0.4582 0.156 Uiso 1 1 calc R . .
H17B H 0.6944 0.5747 0.5181 0.156 Uiso 1 1 calc R . .
H17C H 0.6240 0.4474 0.4490 0.156 Uiso 1 1 calc R . .
C18 C 0.7706(7) 0.4594(8) 0.3341(9) 0.122(3) Uani 1 1 d . . .
H18A H 0.7589 0.3824 0.3280 0.182 Uiso 1 1 calc R . .
H18B H 0.8297 0.5094 0.3967 0.182 Uiso 1 1 calc R . .
H18C H 0.7870 0.4535 0.2663 0.182 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
S1 Ag1 S4 119.46(4) . 2_676
S1 Ag1 S6 119.15(4) . .
S4 Ag1 S6 120.09(5) 2_676 .
S1 Ag1 S7 93.64(3) . .
S4 Ag1 S7 94.29(3) 2_676 .
S6 Ag1 S7 93.44(3) . .
S1 Ag1 Ag3 137.41(3) . 2_676
S4 Ag1 Ag3 48.68(3) 2_676 2_676
S6 Ag1 Ag3 92.72(3) . 2_676
S7 Ag1 Ag3 54.320(10) . 2_676
S1 Ag1 Ag4 48.76(3) . .
S4 Ag1 Ag4 92.82(3) 2_676 .
S6 Ag1 Ag4 136.38(3) . .
S7 Ag1 Ag4 53.449(10) . .
Ag3 Ag1 Ag4 88.789(14) 2_676 .
S3 Ag2 S2 121.63(5) . .
S3 Ag2 S6 119.71(5) . .
S2 Ag2 S6 117.59(4) . .
S3 Ag2 S7 93.74(3) . .
S2 Ag2 S7 93.68(3) . .
S6 Ag2 S7 92.85(3) . .
S3 Ag2 Ag3 92.46(3) . .
S2 Ag2 Ag3 49.18(3) . .
S6 Ag2 Ag3 136.89(3) . .
S7 Ag2 Ag3 54.471(11) . .
S3 Ag2 Ag4 49.43(3) . 2_676
S2 Ag2 Ag4 139.19(3) . 2_676
S6 Ag2 Ag4 90.77(3) . 2_676
S7 Ag2 Ag4 53.798(10) . 2_676
Ag3 Ag2 Ag4 90.015(14) . 2_676
S4 Ag3 S2 120.61(5) . .
S4 Ag3 S5 117.60(4) . .
S2 Ag3 S5 119.65(4) . .
S4 Ag3 S7 94.95(3) . .
S2 Ag3 S7 94.75(3) . .
S5 Ag3 S7 94.90(3) . .
S4 Ag3 Ag4 138.08(3) . .
S2 Ag3 Ag4 92.66(3) . .
S5 Ag3 Ag4 49.45(3) . .
S7 Ag3 Ag4 54.557(10) . .
S4 Ag3 Ag2 92.53(3) . .
S2 Ag3 Ag2 48.94(3) . .
S5 Ag3 Ag2 140.95(3) . .
S7 Ag3 Ag2 55.959(10) . .
Ag4 Ag3 Ag2 91.618(14) . .
S4 Ag3 Ag1 48.68(3) . 2_676
S2 Ag3 Ag1 139.67(3) . 2_676
S5 Ag3 Ag1 91.67(3) . 2_676
S7 Ag3 Ag1 55.088(11) . 2_676
Ag4 Ag3 Ag1 89.588(14) . 2_676
Ag2 Ag3 Ag1 90.761(15) . 2_676
S5 Ag4 S3 121.09(5) . 2_676
S5 Ag4 S1 120.04(4) . .
S3 Ag4 S1 116.46(4) 2_676 .
S5 Ag4 S7 95.81(3) . .
S3 Ag4 S7 95.08(3) 2_676 .
S1 Ag4 S7 94.60(3) . .
S5 Ag4 Ag3 49.64(3) . .
S3 Ag4 Ag3 141.13(4) 2_676 .
S1 Ag4 Ag3 92.81(3) . .
S7 Ag4 Ag3 55.426(11) . .
S5 Ag4 Ag2 94.22(3) . 2_676
S3 Ag4 Ag2 48.62(3) 2_676 2_676
S1 Ag4 Ag2 138.27(3) . 2_676
S7 Ag4 Ag2 56.142(10) . 2_676
Ag3 Ag4 Ag2 92.533(14) . 2_676
S5 Ag4 Ag1 139.99(3) . .
S3 Ag4 Ag1 91.06(3) 2_676 .
S1 Ag4 Ag1 48.25(3) . .
S7 Ag4 Ag1 55.048(10) . .
Ag3 Ag4 Ag1 90.494(14) . .
Ag2 Ag4 Ag1 90.356(15) 2_676 .
P3 S1 Ag1 103.75(6) . .
P3 S1 Ag4 113.10(6) . .
Ag1 S1 Ag4 82.99(4) . .
P3 S2 Ag2 105.27(6) . .
P3 S2 Ag3 113.68(6) . .
Ag2 S2 Ag3 81.88(4) . .
P1 S3 Ag2 108.81(8) . .
P1 S3 Ag4 110.10(7) . 2_676
Ag2 S3 Ag4 81.95(4) . 2_676
P1 S4 Ag1 108.33(8) . 2_676
P1 S4 Ag3 108.74(7) . .
Ag1 S4 Ag3 82.64(4) 2_676 .
P2 S5 Ag4 111.26(7) 2_676 .
P2 S5 Ag3 105.47(6) 2_676 .
Ag4 S5 Ag3 80.91(4) . .
P2 S6 Ag2 113.93(6) . .
P2 S6 Ag1 103.63(6) . .
Ag2 S6 Ag1 84.47(4) . .
Ag4 S7 Ag4 179.999(1) . 2_676
Ag4 S7 Ag3 109.983(13) . 2_676
Ag4 S7 Ag3 70.016(13) 2_676 2_676
Ag4 S7 Ag3 70.018(13) . .
Ag4 S7 Ag3 109.983(13) 2_676 .
Ag3 S7 Ag3 180.0 2_676 .
Ag4 S7 Ag1 71.503(11) . .
Ag4 S7 Ag1 108.497(11) 2_676 .
Ag3 S7 Ag1 70.592(12) 2_676 .
Ag3 S7 Ag1 109.408(12) . .
Ag4 S7 Ag1 108.496(11) . 2_676
Ag4 S7 Ag1 71.503(11) 2_676 2_676
Ag3 S7 Ag1 109.408(12) 2_676 2_676
Ag3 S7 Ag1 70.592(12) . 2_676
Ag1 S7 Ag1 180.0 . 2_676
Ag4 S7 Ag2 109.940(12) . .
Ag4 S7 Ag2 70.061(12) 2_676 .
Ag3 S7 Ag2 110.429(12) 2_676 .
Ag3 S7 Ag2 69.570(12) . .
Ag1 S7 Ag2 71.458(11) . .
Ag1 S7 Ag2 108.542(11) 2_676 .
Ag4 S7 Ag2 70.060(12) . 2_676
Ag4 S7 Ag2 109.939(13) 2_676 2_676
Ag3 S7 Ag2 69.571(12) 2_676 2_676
Ag3 S7 Ag2 110.430(12) . 2_676
Ag1 S7 Ag2 108.542(11) . 2_676
Ag1 S7 Ag2 71.458(12) 2_676 2_676
Ag2 S7 Ag2 180.0 . 2_676
O2' P1 O1 70.5(5) . .
O2' P1 O2 33.9(4) . .
O1 P1 O2 101.2(5) . .
O2' P1 O1' 100.8(5) . .
O1 P1 O1' 31.9(4) . .
O2 P1 O1' 133.0(4) . .
O2' P1 S4 118.3(4) . .
O1 P1 S4 110.4(4) . .
O2 P1 S4 94.6(3) . .
O1' P1 S4 104.7(3) . .
O2' P1 S3 108.7(4) . .
O1 P1 S3 114.8(4) . .
O2 P1 S3 108.7(3) . .
O1' P1 S3 96.1(4) . .
S4 P1 S3 122.82(8) . .
O3 P2 O4 108.68(19) . .
O3 P2 S6 103.16(15) . .
O4 P2 S6 109.61(15) . .
O3 P2 S5 110.02(15) . 2_676
O4 P2 S5 102.80(14) . 2_676
S6 P2 S5 122.19(7) . 2_676
O6 P3 O5 102.8(2) . .
O6 P3 S1 104.08(14) . .
O5 P3 S1 108.53(16) . .
O6 P3 S2 109.94(15) . .
O5 P3 S2 108.50(16) . .
S1 P3 S2 121.41(7) . .
C1 O1 P1 142.8(10) . .
C4 O2 P1 127.9(11) . .
C1' O1' P1 150.6(13) . .
C4' O2' P1 125.3(11) . .
C7 O3 P2 123.7(3) . .
C16 O4 P2 123.1(3) . .
C10 O5 P3 125.1(4) . .
C13 O6 P3 124.1(4) . .
O1 C1 C2 96.0(15) . .
O1 C1 C3 120.4(19) . .
C2 C1 C3 104.5(17) . .
O2 C4 C6 112.2(16) . .
O2 C4 C5 111.5(16) . .
C6 C4 C5 90.9(17) . .
O1' C1' C2' 137.6(18) . .
O1' C1' C3' 98.6(17) . .
C2' C1' C3' 112.2(17) . .
O2' C4' C6' 97.1(15) . .
O2' C4' C5' 116.3(16) . .
C6' C4' C5' 134.2(18) . .
O3 C7 C8 106.3(5) . .
O3 C7 C9 107.8(6) . .
C8 C7 C9 111.9(6) . .
C12 C10 O5 111.3(8) . .
C12 C10 C11 111.6(10) . .
O5 C10 C11 108.0(9) . .
C15 C13 O6 106.9(6) . .
C15 C13 C14 107.8(8) . .
O6 C13 C14 106.4(7) . .
C17 C16 O4 109.7(5) . .
C17 C16 C18 114.6(6) . .
O4 C16 C18 105.9(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 S1 2.5135(13) .
Ag1 S4 2.5171(14) 2_676
Ag1 S6 2.5218(13) .
Ag1 S7 2.8902(4) .
Ag1 Ag3 3.3242(6) 2_676
Ag1 Ag4 3.3440(5) .
Ag2 S3 2.5007(14) .
Ag2 S2 2.5109(14) .
Ag2 S6 2.5215(13) .
Ag2 S7 2.9151(4) .
Ag2 Ag3 3.2966(6) .
Ag2 Ag4 3.3000(6) 2_676
Ag3 S4 2.5174(14) .
Ag3 S2 2.5201(13) .
Ag3 S5 2.5217(13) .
Ag3 S7 2.8629(5) .
Ag3 Ag4 3.2677(6) .
Ag3 Ag1 3.3242(6) 2_676
Ag4 S5 2.5143(13) .
Ag4 S3 2.5314(15) 2_676
Ag4 S1 2.5336(12) .
Ag4 S7 2.8327(4) .
Ag4 Ag2 3.3000(6) 2_676
S1 P3 2.0101(16) .
S2 P3 2.0138(17) .
S3 P1 2.005(2) .
S3 Ag4 2.5315(15) 2_676
S4 P1 1.999(2) .
S4 Ag1 2.5172(14) 2_676
S5 P2 2.0117(17) 2_676
S6 P2 2.0082(17) .
S7 Ag4 2.8327(4) 2_676
S7 Ag3 2.8629(5) 2_676
S7 Ag1 2.8902(4) 2_676
S7 Ag2 2.9151(4) 2_676
P1 O2' 1.501(9) .
P1 O1 1.519(7) .
P1 O2 1.653(8) .
P1 O1' 1.654(8) .
P2 O3 1.564(3) .
P2 O4 1.565(3) .
P2 S5 2.0118(17) 2_676
P3 O6 1.559(3) .
P3 O5 1.563(4) .
O1 C1 1.360(18) .
O2 C4 1.442(9) .
O1' C1' 1.082(18) .
O2' C4' 1.452(9) .
O3 C7 1.472(7) .
O4 C16 1.490(6) .
O5 C10 1.428(8) .
O6 C13 1.479(6) .
C1 C2 1.527(10) .
C1 C3 1.565(10) .
C4 C6 1.523(10) .
C4 C5 1.532(10) .
C1' C2' 1.532(10) .
C1' C3' 1.574(10) .
C4' C6' 1.517(10) .
C4' C5' 1.534(10) .
C7 C8 1.491(9) .
C7 C9 1.496(10) .
C10 C12 1.412(13) .
C10 C11 1.457(15) .
C13 C15 1.473(12) .
C13 C14 1.482(13) .
C16 C17 1.464(9) .
C16 C18 1.492(9) .
