#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:13:35 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180030 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/24/7032485.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7032485
loop_
_publ_author_name
'Han, Min-Le'
'Duan, Ya-Ping'
'Li, Dong-Sheng'
'Xu, Guo-Wang'
'Wu, Ya-Pan'
'Zhao, Jun'
_publ_section_title
;
 A series of divalent metal coordination polymers based on isomeric
 tetracarboxylic acids: synthesis, structures and magnetic properties.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17519
_journal_page_last               17527
_journal_paper_doi               10.1039/c4dt01946f
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C27 H23 Co N2 O10'
_chemical_formula_weight         594.40
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.196(19)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   28.550(2)
_cell_length_b                   7.7222(7)
_cell_length_c                   24.645(2)
_cell_measurement_reflns_used    6236
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      2.6
_cell_volume                     5217.8(9)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0873
_diffrn_reflns_av_sigmaI/netI    0.0678
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            22653
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.57
_exptl_absorpt_coefficient_mu    0.720
_exptl_absorpt_correction_T_max  0.8813
_exptl_absorpt_correction_T_min  0.8634
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.513
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    NONE
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2448
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.284
_refine_diff_density_min         -0.468
_refine_diff_density_rms         0.060
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     363
_refine_ls_number_reflns         4849
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.076
_refine_ls_R_factor_all          0.0578
_refine_ls_R_factor_gt           0.0443
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0401P)²+4.9602P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1014
_refine_ls_wR_factor_ref         0.1106
_reflns_number_gt                4024
_reflns_number_total             4849
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt01946f2.cif
_cod_data_source_block           z
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed
to 'constr' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7032483--7032487.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        5217.8(7)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7032485
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.223812(13) 0.35221(5) 0.662454(15) 0.02505(12) Uani 1 1 d .
O1 O 0.16937(7) 0.4394(2) 0.59403(8) 0.0309(5) Uani 1 1 d .
O2 O 0.17015(7) 0.7234(2) 0.61127(9) 0.0362(5) Uani 1 1 d .
O3 O 0.13830(8) 0.0406(3) 0.28359(12) 0.0543(7) Uani 1 1 d .
O4 O 0.09616(9) -0.1652(3) 0.31243(12) 0.0500(6) Uani 1 1 d .
H4A H 0.1150 -0.2280 0.3018 0.075 Uiso 1 1 calc R
O5 O -0.16031(7) 0.6408(3) 0.21281(9) 0.0406(5) Uani 1 1 d .
O6 O -0.19299(7) 0.5400(3) 0.27833(8) 0.0327(5) Uani 1 1 d .
O7 O -0.17903(6) 0.8770(2) 0.33338(9) 0.0327(5) Uani 1 1 d .
O8 O -0.11441(7) 1.0455(3) 0.36984(10) 0.0431(6) Uani 1 1 d .
H8A H -0.1352 1.1094 0.3763 0.065 Uiso 1 1 calc R
O9 O 0.26117(7) 0.5918(3) 0.66057(9) 0.0372(5) Uani 1 1 d .
H9A H 0.2384 0.6662 0.6516 0.056 Uiso 1 1 d R
H9B H 0.2818 0.6339 0.6893 0.056 Uiso 1 1 d R
O10 O 0.27950(7) 0.2747(3) 0.73273(9) 0.0436(6) Uani 1 1 d .
H10B H 0.2834 0.1664 0.7382 0.065 Uiso 1 1 d R
H10A H 0.3052 0.3351 0.7370 0.065 Uiso 1 1 d R
N1 N 0.25821(9) 0.2230(3) 0.60972(11) 0.0340(6) Uani 1 1 d .
N2 N 0.29091(9) 0.0096(3) 0.57283(11) 0.0370(6) Uani 1 1 d .
C1 C 0.15211(10) 0.5901(3) 0.58308(11) 0.0267(6) Uani 1 1 d .
C2 C 0.10846(10) 0.6073(3) 0.53251(11) 0.0263(6) Uani 1 1 d .
C3 C 0.08248(10) 0.4598(4) 0.51000(11) 0.0287(6) Uani 1 1 d .
H3 H 0.0924 0.3526 0.5264 0.034 Uiso 1 1 calc R
C4 C 0.04188(10) 0.4699(4) 0.46345(12) 0.0300(6) Uani 1 1 d .
H4 H 0.0243 0.3700 0.4499 0.036 Uiso 1 1 calc R
C5 C 0.02708(9) 0.6286(3) 0.43668(11) 0.0252(6) Uani 1 1 d .
C6 C 0.05368(10) 0.7766(4) 0.45876(12) 0.0321(6) Uani 1 1 d .
H6 H 0.0447 0.8830 0.4413 0.039 Uiso 1 1 calc R
C7 C 0.09358(10) 0.7671(4) 0.50667(12) 0.0321(7) Uani 1 1 d .
H7 H 0.1104 0.8674 0.5215 0.039 Uiso 1 1 calc R
C8 C -0.01762(9) 0.6350(3) 0.38803(11) 0.0254(6) Uani 1 1 d .
C9 C -0.02858(9) 0.5039(4) 0.34620(11) 0.0268(6) Uani 1 1 d .
C10 C 0.00716(10) 0.3704(4) 0.33954(11) 0.0275(6) Uani 1 1 d .
C11 C 0.05339(10) 0.4193(4) 0.33612(12) 0.0305(6) Uani 1 1 d .
H11 H 0.0629 0.5348 0.3410 0.037 Uiso 1 1 calc R
C12 C 0.08509(10) 0.2972(4) 0.32555(12) 0.0312(6) Uani 1 1 d .
H12 H 0.1156 0.3314 0.3229 0.037 Uiso 1 1 calc R
C13 C 0.07175(10) 0.1239(4) 0.31881(12) 0.0293(6) Uani 1 1 d .
C14 C 0.02611(10) 0.0732(4) 0.32336(12) 0.0334(7) Uani 1 1 d .
H14 H 0.0172 -0.0431 0.3199 0.040 Uiso 1 1 calc R
C15 C -0.00612(10) 0.1961(4) 0.33311(13) 0.0325(7) Uani 1 1 d .
H15 H -0.0368 0.1621 0.3354 0.039 Uiso 1 1 calc R
C16 C 0.10518(10) -0.0023(4) 0.30324(13) 0.0350(7) Uani 1 1 d .
C17 C -0.07458(10) 0.5036(4) 0.30719(12) 0.0293(6) Uani 1 1 d .
H17 H -0.0820 0.4165 0.2801 0.035 Uiso 1 1 calc R
C18 C -0.10975(9) 0.6279(3) 0.30714(11) 0.0248(6) Uani 1 1 d .
C19 C -0.09819(9) 0.7639(3) 0.34618(11) 0.0246(6) Uani 1 1 d .
C20 C -0.05214(9) 0.7657(4) 0.38550(11) 0.0261(6) Uani 1 1 d .
H20 H -0.0442 0.8572 0.4109 0.031 Uiso 1 1 calc R
C21 C -0.15816(10) 0.6065(3) 0.26285(12) 0.0251(6) Uani 1 1 d .
C22 C -0.13463(10) 0.8991(3) 0.34886(12) 0.0268(6) Uani 1 1 d .
C23 C 0.26241(12) 0.0532(4) 0.60576(14) 0.0392(7) Uani 1 1 d .
H23 H 0.2474 -0.0266 0.6237 0.047 Uiso 1 1 calc R
C24 C 0.28615(13) 0.2905(4) 0.57782(15) 0.0484(9) Uani 1 1 d .
H24 H 0.2906 0.4080 0.5727 0.058 Uiso 1 1 calc R
C25 C 0.30631(14) 0.1607(4) 0.55488(16) 0.0528(9) Uani 1 1 d .
H25 H 0.3267 0.1723 0.5315 0.063 Uiso 1 1 calc R
C26 C 0.30498(13) -0.1676(4) 0.56116(15) 0.0466(8) Uani 1 1 d .
H26A H 0.2993 -0.2456 0.5895 0.056 Uiso 1 1 calc R
H26B H 0.3396 -0.1696 0.5642 0.056 Uiso 1 1 calc R
C27 C 0.27681(12) -0.2328(4) 0.50270(14) 0.0453(8) Uani 1 1 d .
H27A H 0.2792 -0.1476 0.4747 0.054 Uiso 1 1 calc R
H27B H 0.2918 -0.3389 0.4947 0.054 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Co1 O6 94.21(8) . 5_566
O1 Co1 O10 177.62(8) . .
O6 Co1 O10 84.60(8) 5_566 .
O1 Co1 N1 91.43(9) . .
O6 Co1 N1 173.61(9) 5_566 .
O10 Co1 N1 89.88(9) . .
O1 Co1 O9 88.09(8) . .
O6 Co1 O9 88.86(8) 5_566 .
O10 Co1 O9 89.83(8) . .
N1 Co1 O9 94.35(9) . .
O1 Co1 O7 89.17(7) . 5_566
O6 Co1 O7 85.65(8) 5_566 5_566
O10 Co1 O7 92.79(8) . 5_566
N1 Co1 O7 91.43(9) . 5_566
O9 Co1 O7 173.66(7) . 5_566
C1 O1 Co1 129.48(17) . .
C16 O4 H4A 109.5 . .
C21 O6 Co1 124.77(17) . 5_566
C22 O7 Co1 131.21(18) . 5_566
C22 O8 H8A 109.5 . .
Co1 O9 H9A 103.9 . .
Co1 O9 H9B 123.0 . .
H9A O9 H9B 105.1 . .
Co1 O10 H10B 116.8 . .
Co1 O10 H10A 112.2 . .
H10B O10 H10A 116.7 . .
C23 N1 C24 104.8(3) . .
C23 N1 Co1 126.0(2) . .
C24 N1 Co1 128.7(2) . .
C23 N2 C25 106.6(3) . .
C23 N2 C26 126.4(3) . .
C25 N2 C26 126.9(3) . .
O1 C1 O2 123.8(2) . .
O1 C1 C2 116.3(2) . .
O2 C1 C2 119.9(2) . .
C3 C2 C7 118.8(2) . .
C3 C2 C1 119.1(2) . .
C7 C2 C1 122.1(2) . .
C4 C3 C2 121.0(3) . .
C4 C3 H3 119.5 . .
C2 C3 H3 119.5 . .
C3 C4 C5 120.7(3) . .
C3 C4 H4 119.6 . .
C5 C4 H4 119.6 . .
C6 C5 C4 118.2(2) . .
C6 C5 C8 122.5(2) . .
C4 C5 C8 119.1(2) . .
C7 C6 C5 120.9(3) . .
C7 C6 H6 119.5 . .
C5 C6 H6 119.5 . .
C6 C7 C2 120.3(3) . .
C6 C7 H7 119.9 . .
C2 C7 H7 119.9 . .
C20 C8 C9 118.2(2) . .
C20 C8 C5 119.7(2) . .
C9 C8 C5 121.9(2) . .
C17 C9 C8 118.5(2) . .
C17 C9 C10 117.7(2) . .
C8 C9 C10 123.7(2) . .
C15 C10 C11 119.0(3) . .
C15 C10 C9 120.4(2) . .
C11 C10 C9 120.4(2) . .
C12 C11 C10 120.4(3) . .
C12 C11 H11 119.8 . .
C10 C11 H11 119.8 . .
C11 C12 C13 120.6(3) . .
C11 C12 H12 119.7 . .
C13 C12 H12 119.7 . .
C12 C13 C14 119.5(3) . .
C12 C13 C16 119.2(3) . .
C14 C13 C16 121.2(3) . .
C15 C14 C13 120.1(3) . .
C15 C14 H14 120.0 . .
C13 C14 H14 120.0 . .
C14 C15 C10 120.5(3) . .
C14 C15 H15 119.8 . .
C10 C15 H15 119.8 . .
O3 C16 O4 122.5(3) . .
O3 C16 C13 123.2(3) . .
O4 C16 C13 114.3(3) . .
C18 C17 C9 122.8(3) . .
C18 C17 H17 118.6 . .
C9 C17 H17 118.6 . .
C17 C18 C19 119.1(2) . .
C17 C18 C21 116.1(2) . .
C19 C18 C21 124.8(2) . .
C20 C19 C18 118.6(2) . .
C20 C19 C22 119.7(2) . .
C18 C19 C22 121.5(2) . .
C19 C20 C8 122.5(2) . .
C19 C20 H20 118.7 . .
C8 C20 H20 118.7 . .
O5 C21 O6 123.9(2) . .
O5 C21 C18 118.3(2) . .
O6 C21 C18 117.5(2) . .
O7 C22 O8 123.1(2) . .
O7 C22 C19 124.2(2) . .
O8 C22 C19 112.8(2) . .
N1 C23 N2 112.1(3) . .
N1 C23 H23 124.0 . .
N2 C23 H23 124.0 . .
C25 C24 N1 109.9(3) . .
C25 C24 H24 125.0 . .
N1 C24 H24 125.0 . .
C24 C25 N2 106.5(3) . .
C24 C25 H25 126.7 . .
N2 C25 H25 126.7 . .
N2 C26 C27 112.9(3) . .
N2 C26 H26A 109.0 . .
C27 C26 H26A 109.0 . .
N2 C26 H26B 109.0 . .
C27 C26 H26B 109.0 . .
H26A C26 H26B 107.8 . .
C27 C27 C26 113.1(3) 7_546 .
C27 C27 H27A 109.0 7_546 .
C26 C27 H27A 109.0 . .
C27 C27 H27B 109.0 7_546 .
C26 C27 H27B 109.0 . .
H27A C27 H27B 107.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O1 2.0615(19) .
Co1 O6 2.0768(19) 5_566
Co1 O10 2.086(2) .
Co1 N1 2.088(2) .
Co1 O9 2.143(2) .
Co1 O7 2.2025(19) 5_566
O1 C1 1.263(3) .
O2 C1 1.268(3) .
O3 C16 1.222(4) .
O4 C16 1.316(4) .
O4 H4A 0.8200 .
O5 C21 1.246(3) .
O6 C21 1.269(3) .
O6 Co1 2.0768(19) 5_566
O7 C22 1.230(3) .
O7 Co1 2.2025(19) 5_566
O8 C22 1.308(3) .
O8 H8A 0.8200 .
O9 H9A 0.8501 .
O9 H9B 0.8499 .
O10 H10B 0.8499 .
O10 H10A 0.8499 .
N1 C23 1.323(4) .
N1 C24 1.370(4) .
N2 C23 1.343(4) .
N2 C25 1.363(4) .
N2 C26 1.477(4) .
C1 C2 1.502(4) .
C2 C3 1.388(4) .
C2 C7 1.399(4) .
C3 C4 1.387(4) .
C3 H3 0.9300 .
C4 C5 1.400(4) .
C4 H4 0.9300 .
C5 C6 1.396(4) .
C5 C8 1.488(4) .
C6 C7 1.395(4) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C20 1.399(4) .
C8 C9 1.416(4) .
C9 C17 1.395(4) .
C9 C10 1.491(4) .
C10 C15 1.395(4) .
C10 C11 1.398(4) .
C11 C12 1.381(4) .
C11 H11 0.9300 .
C12 C13 1.389(4) .
C12 H12 0.9300 .
C13 C14 1.395(4) .
C13 C16 1.487(4) .
C14 C15 1.389(4) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C17 C18 1.389(4) .
C17 H17 0.9300 .
C18 C19 1.400(4) .
C18 C21 1.512(4) .
C19 C20 1.399(4) .
C19 C22 1.488(4) .
C20 H20 0.9300 .
C23 H23 0.9300 .
C24 C25 1.356(5) .
C24 H24 0.9300 .
C25 H25 0.9300 .
C26 C27 1.526(5) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 C27 1.522(6) 7_546
C27 H27A 0.9700 .
C27 H27B 0.9700 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O10 H10A O3 0.85 2.06 2.869(3) 158.8 7_556
O10 H10B O6 0.85 1.90 2.701(3) 157.2 8_556
O9 H9B O3 0.85 2.57 2.996(3) 112.0 7_556
O9 H9B O5 0.85 2.36 3.056(3) 139.6 8_566
O9 H9A O2 0.85 1.97 2.739(3) 149.2 .
O8 H8A O2 0.82 1.71 2.519(3) 167.9 5_576
O4 H4A O5 0.82 1.76 2.573(3) 173.0 2_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O6 Co1 O1 C1 51.2(2) 5_566 .
O10 Co1 O1 C1 -9(2) . .
N1 Co1 O1 C1 -131.8(2) . .
O9 Co1 O1 C1 -37.5(2) . .
O7 Co1 O1 C1 136.8(2) 5_566 .
O1 Co1 N1 C23 -112.7(3) . .
O6 Co1 N1 C23 39.2(9) 5_566 .
O10 Co1 N1 C23 69.3(3) . .
O9 Co1 N1 C23 159.1(3) . .
O7 Co1 N1 C23 -23.5(3) 5_566 .
O1 Co1 N1 C24 76.5(3) . .
O6 Co1 N1 C24 -131.6(7) 5_566 .
O10 Co1 N1 C24 -101.5(3) . .
O9 Co1 N1 C24 -11.7(3) . .
O7 Co1 N1 C24 165.7(3) 5_566 .
Co1 O1 C1 O2 8.2(4) . .
Co1 O1 C1 C2 -173.41(17) . .
O1 C1 C2 C3 16.1(4) . .
O2 C1 C2 C3 -165.4(3) . .
O1 C1 C2 C7 -162.7(3) . .
O2 C1 C2 C7 15.7(4) . .
C7 C2 C3 C4 -1.3(4) . .
C1 C2 C3 C4 179.8(2) . .
C2 C3 C4 C5 2.3(4) . .
C3 C4 C5 C6 -1.3(4) . .
C3 C4 C5 C8 -178.0(2) . .
C4 C5 C6 C7 -0.8(4) . .
C8 C5 C6 C7 175.8(3) . .
C5 C6 C7 C2 1.8(5) . .
C3 C2 C7 C6 -0.7(4) . .
C1 C2 C7 C6 178.1(3) . .
C6 C5 C8 C20 -42.6(4) . .
C4 C5 C8 C20 134.0(3) . .
C6 C5 C8 C9 142.9(3) . .
C4 C5 C8 C9 -40.5(4) . .
C20 C8 C9 C17 -4.8(4) . .
C5 C8 C9 C17 169.8(3) . .
C20 C8 C9 C10 172.0(3) . .
C5 C8 C9 C10 -13.4(4) . .
C17 C9 C10 C15 -50.2(4) . .
C8 C9 C10 C15 133.0(3) . .
C17 C9 C10 C11 125.8(3) . .
C8 C9 C10 C11 -51.0(4) . .
C15 C10 C11 C12 1.1(4) . .
C9 C10 C11 C12 -174.9(3) . .
C10 C11 C12 C13 -0.7(4) . .
C11 C12 C13 C14 -0.7(4) . .
C11 C12 C13 C16 175.5(3) . .
C12 C13 C14 C15 1.7(4) . .
C16 C13 C14 C15 -174.4(3) . .
C13 C14 C15 C10 -1.3(5) . .
C11 C10 C15 C14 -0.1(4) . .
C9 C10 C15 C14 175.9(3) . .
C12 C13 C16 O3 -17.2(5) . .
C14 C13 C16 O3 158.9(3) . .
C12 C13 C16 O4 162.8(3) . .
C14 C13 C16 O4 -21.1(4) . .
C8 C9 C17 C18 1.0(4) . .
C10 C9 C17 C18 -176.0(3) . .
C9 C17 C18 C19 2.8(4) . .
C9 C17 C18 C21 -178.6(3) . .
C17 C18 C19 C20 -2.6(4) . .
C21 C18 C19 C20 178.9(3) . .
C17 C18 C19 C22 -178.9(3) . .
C21 C18 C19 C22 2.6(4) . .
C18 C19 C20 C8 -1.3(4) . .
C22 C19 C20 C8 175.0(3) . .
C9 C8 C20 C19 5.1(4) . .
C5 C8 C20 C19 -169.6(3) . .
Co1 O6 C21 O5 -123.8(2) 5_566 .
Co1 O6 C21 C18 62.7(3) 5_566 .
C17 C18 C21 O5 -73.5(3) . .
C19 C18 C21 O5 105.0(3) . .
C17 C18 C21 O6 100.4(3) . .
C19 C18 C21 O6 -81.1(3) . .
Co1 O7 C22 O8 -144.6(2) 5_566 .
Co1 O7 C22 C19 35.0(4) 5_566 .
C20 C19 C22 O7 -150.6(3) . .
C18 C19 C22 O7 25.6(4) . .
C20 C19 C22 O8 29.1(4) . .
C18 C19 C22 O8 -154.7(3) . .
C24 N1 C23 N2 -0.6(4) . .
Co1 N1 C23 N2 -173.3(2) . .
C25 N2 C23 N1 0.5(4) . .
C26 N2 C23 N1 177.3(3) . .
C23 N1 C24 C25 0.5(4) . .
Co1 N1 C24 C25 172.9(2) . .
N1 C24 C25 N2 -0.2(4) . .
C23 N2 C25 C24 -0.2(4) . .
C26 N2 C25 C24 -177.0(3) . .
C23 N2 C26 C27 103.5(4) . .
C25 N2 C26 C27 -80.3(4) . .
N2 C26 C27 C27 -69.6(5) . 7_546
