#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/29/7032929.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7032929
loop_
_publ_author_name
'Feng, Xun'
'Feng, Yu-Quan'
'Chen, Jun Jing'
'Ng, Seik-Weng'
'Wang, Li-Ya'
'Guo, Jin-Zhong'
_publ_section_title
;
 Reticular three-dimensional 3d-4f frameworks constructed through
 substituted imidazole-dicarboxylate: syntheses, luminescence and magnetic
 properties study.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              804
_journal_page_last               816
_journal_paper_doi               10.1039/c4dt02047b
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety
'Er Zn (H2 O)2 (C6 H3 N2 O4) (C6 H4 N2 O4), 2.5H2 O'
_chemical_formula_sum            'C12 H16 N4 O12.5 Yb Zn'
_chemical_formula_weight         654.70
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.0500(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   24.1744(13)
_cell_length_b                   9.1789(5)
_cell_length_c                   18.9734(10)
_cell_measurement_reflns_used    9226
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.2398
_cell_measurement_theta_min      2.3229
_cell_volume                     3844.6(4)
_computing_cell_refinement       'SAINT (Bruker, 2011)'
_computing_data_collection       'APEX2 (Bruker, 2011)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'X-Seed (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART APEX diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0221
_diffrn_reflns_av_sigmaI/netI    0.0208
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            15582
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.32
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.158
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.724373
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.262
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2528
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_refine_diff_density_max         2.185
_refine_diff_density_min         -1.085
_refine_diff_density_rms         0.137
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     280
_refine_ls_number_reflns         4399
_refine_ls_number_restraints     24
_refine_ls_restrained_S_all      1.058
_refine_ls_R_factor_all          0.0272
_refine_ls_R_factor_gt           0.0248
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0461P)²+13.5489P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0719
_refine_ls_wR_factor_ref         0.0733
_reflns_number_gt                4075
_reflns_number_total             4399
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c4dt02047b3.cif
_cod_data_source_block           yb
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2827 2014-09-09 07:05:25Z andrius 

 Adding full bibliography for 7032926--7032931.cif.
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C12 H16 N4 O12.50 Yb Zn'
_cod_database_code               7032929
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Yb1 Yb 0.542120(6) 0.693092(16) 0.495871(9) 0.01795(7) Uani 1 1 d .
Zn1 Zn 0.712595(19) 0.49132(5) 0.33675(2) 0.02123(10) Uani 1 1 d .
O1 O 0.61579(15) 0.6496(3) 0.4596(2) 0.0360(7) Uani 1 1 d .
O2 O 0.66533(15) 0.6360(3) 0.38426(19) 0.0349(7) Uani 1 1 d .
O3 O 0.54675(11) 0.4330(3) 0.49615(15) 0.0237(6) Uani 1 1 d .
O4 O 0.53977(14) 0.1968(3) 0.4806(2) 0.0303(7) Uani 1 1 d .
O5 O 0.60706(13) 0.8756(3) 0.55526(17) 0.0314(6) Uani 1 1 d .
O6 O 0.69424(13) 0.9804(3) 0.57288(16) 0.0278(6) Uani 1 1 d .
O7 O 0.57670(12) 0.6293(3) 0.62139(16) 0.0292(6) Uani 1 1 d .
O8 O 0.62069(13) 0.5411(3) 0.73975(17) 0.0309(6) Uani 1 1 d .
O1w O 0.51907(15) 0.9074(3) 0.41891(18) 0.0362(7) Uani 1 1 d .
H11 H 0.5435 0.9734 0.4430 0.054 Uiso 1 1 d R
H12 H 0.4836 0.9343 0.4097 0.054 Uiso 1 1 d R
O2w O 0.48243(14) 0.6311(3) 0.37021(17) 0.0414(8) Uani 1 1 d .
H21 H 0.4620 0.5570 0.3701 0.062 Uiso 1 1 d R
H22 H 0.5040 0.6129 0.3461 0.062 Uiso 1 1 d R
O3w O 0.43679(14) 1.0543(3) 0.29896(17) 0.132(3) Uani 1 1 d RU
H31 H 0.4266 1.0033 0.2590 0.198 Uiso 1 1 d R
H32 H 0.4514 1.1340 0.2926 0.198 Uiso 1 1 d R
O4w O 0.4003(4) 0.8875(9) 0.1634(5) 0.135(3) Uani 1 1 d U
H41 H 0.3758 0.8184 0.1453 0.202 Uiso 1 1 d R
H42 H 0.4036 0.9339 0.1274 0.202 Uiso 1 1 d R
O5w O 0.5000 0.7285(16) 0.2500 0.074(4) Uani 0.50 2 d SPU
H51 H 0.4703 0.7843 0.2286 0.112 Uiso 0.50 1 d PR
O6w O 0.5000 1.3153(17) 0.2500 0.086(5) Uani 0.50 2 d SPU
H61 H 0.5230 1.3666 0.2869 0.129 Uiso 0.50 1 d PR
N1 N 0.68517(15) 0.3504(4) 0.40524(19) 0.0247(7) Uani 1 1 d .
N2 N 0.64286(18) 0.1830(4) 0.4495(2) 0.0312(8) Uani 1 1 d .
H2 H 0.6340 0.0968 0.4625 0.037 Uiso 1 1 calc R
N3 N 0.75706(15) 0.8301(4) 0.70335(19) 0.0226(6) Uani 1 1 d .
N4 N 0.72864(15) 0.6618(4) 0.76654(19) 0.0237(7) Uani 1 1 d .
C1 C 0.64129(17) 0.5787(4) 0.4240(2) 0.0247(8) Uani 1 1 d .
C2 C 0.64540(16) 0.4172(4) 0.4304(2) 0.0223(7) Uani 1 1 d .
C3 C 0.61803(19) 0.3130(4) 0.4578(2) 0.0243(8) Uani 1 1 d .
C4 C 0.56592(18) 0.3155(4) 0.4793(2) 0.0218(8) Uani 1 1 d .
C5 C 0.6831(2) 0.2088(4) 0.4183(3) 0.0279(9) Uani 1 1 d .
C6 C 0.7187(2) 0.0932(6) 0.4006(3) 0.0427(11) Uani 1 1 d .
H6A H 0.7573 0.1317 0.4069 0.064 Uiso 1 1 calc R
H6B H 0.6971 0.0608 0.3484 0.064 Uiso 1 1 calc R
H6C H 0.7245 0.0127 0.4352 0.064 Uiso 1 1 calc R
C7 C 0.66376(17) 0.8894(4) 0.5913(2) 0.0213(7) Uani 1 1 d .
C8 C 0.69667(17) 0.8012(4) 0.6613(2) 0.0205(7) Uani 1 1 d .
C9 C 0.67933(17) 0.6960(4) 0.7009(2) 0.0206(7) Uani 1 1 d .
C10 C 0.62204(17) 0.6186(4) 0.6866(2) 0.0212(7) Uani 1 1 d .
C11 C 0.77447(17) 0.7429(4) 0.7654(2) 0.0237(7) Uani 1 1 d .
C12 C 0.8370(2) 0.7411(7) 0.8265(3) 0.0480(13) Uani 1 1 d .
H12A H 0.8654 0.7313 0.8032 0.072 Uiso 1 1 calc R
H12B H 0.8414 0.6604 0.8606 0.072 Uiso 1 1 calc R
H12C H 0.8446 0.8304 0.8553 0.072 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Yb1 O7 106.58(12) . .
O1 Yb1 O5 78.66(12) . .
O7 Yb1 O5 77.45(10) . .
O1 Yb1 O2w 82.87(13) . .
O7 Yb1 O2w 146.74(11) . .
O5 Yb1 O2w 135.73(11) . .
O1 Yb1 O1w 88.56(12) . .
O7 Yb1 O1w 139.17(11) . .
O5 Yb1 O1w 68.53(10) . .
O2w Yb1 O1w 71.15(11) . .
O1 Yb1 O3 77.02(10) . .
O7 Yb1 O3 75.01(10) . .
O5 Yb1 O3 135.85(10) . .
O2w Yb1 O3 76.35(10) . .
O1w Yb1 O3 145.80(10) . .
O1 Yb1 O4 164.60(11) . 5_666
O7 Yb1 O4 83.86(11) . 5_666
O5 Yb1 O4 93.02(11) . 5_666
O2w Yb1 O4 94.57(12) . 5_666
O1w Yb1 O4 76.29(11) . 5_666
O3 Yb1 O4 117.25(9) . 5_666
O1 Yb1 O3 139.75(10) . 5_666
O7 Yb1 O3 76.91(9) . 5_666
O5 Yb1 O3 138.90(10) . 5_666
O2w Yb1 O3 75.90(10) . 5_666
O1w Yb1 O3 115.38(10) . 5_666
O3 Yb1 O3 65.02(10) . 5_666
O4 Yb1 O3 52.73(10) 5_666 5_666
N3 Zn1 N4 96.54(14) 7_666 6_565
N3 Zn1 N1 163.05(13) 7_666 .
N4 Zn1 N1 99.59(14) 6_565 .
N3 Zn1 O2 89.62(12) 7_666 .
N4 Zn1 O2 161.10(13) 6_565 .
N1 Zn1 O2 76.72(12) . .
N3 Zn1 O6 77.92(12) 7_666 7_666
N4 Zn1 O6 100.28(12) 6_565 7_666
N1 Zn1 O6 94.02(11) . 7_666
O2 Zn1 O6 98.48(12) . 7_666
N3 Zn1 O8 100.61(12) 7_666 6_565
N4 Zn1 O8 76.51(11) 6_565 6_565
N1 Zn1 O8 88.25(12) . 6_565
O2 Zn1 O8 84.81(12) . 6_565
O6 Zn1 O8 176.36(11) 7_666 6_565
C1 O1 Yb1 153.8(3) . .
C1 O2 Zn1 116.7(3) . .
C4 O3 Yb1 150.7(2) . .
C4 O3 Yb1 91.9(2) . 5_666
Yb1 O3 Yb1 114.98(10) . 5_666
C4 O4 Yb1 95.6(2) . 5_666
C7 O5 Yb1 136.4(3) . .
C7 O6 Zn1 112.9(2) . 7_666
C10 O7 Yb1 147.5(2) . .
C10 O8 Zn1 113.2(2) . 6_566
Yb1 O1w H11 109.0 . .
Yb1 O1w H12 109.6 . .
H11 O1w H12 109.4 . .
Yb1 O2w H21 108.8 . .
Yb1 O2w H22 110.3 . .
H21 O2w H22 109.5 . .
H31 O3w H32 110.0 . .
H41 O4w H42 109.6 . .
C5 N1 C2 106.6(3) . .
C5 N1 Zn1 139.1(3) . .
C2 N1 Zn1 112.2(3) . .
C5 N2 C3 108.9(3) . .
C5 N2 H2 125.5 . .
C3 N2 H2 125.5 . .
C11 N3 C8 105.9(3) . .
C11 N3 Zn1 140.0(3) . 7_666
C8 N3 Zn1 113.1(2) . 7_666
C11 N4 C9 106.1(3) . .
C11 N4 Zn1 139.1(3) . 6_566
C9 N4 Zn1 114.8(2) . 6_566
O2 C1 O1 123.9(4) . .
O2 C1 C2 116.1(3) . .
O1 C1 C2 120.0(3) . .
C3 C2 N1 109.3(3) . .
C3 C2 C1 134.1(3) . .
N1 C2 C1 116.6(3) . .
C2 C3 N2 105.1(3) . .
C2 C3 C4 133.5(3) . .
N2 C3 C4 120.5(3) . .
O3 C4 O4 119.4(4) . .
O3 C4 C3 121.7(3) . .
O4 C4 C3 118.8(3) . .
N1 C5 N2 110.0(3) . .
N1 C5 C6 125.9(4) . .
N2 C5 C6 124.1(4) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
O6 C7 O5 123.1(4) . .
O6 C7 C8 116.9(3) . .
O5 C7 C8 119.9(3) . .
N3 C8 C9 107.7(3) . .
N3 C8 C7 118.1(3) . .
C9 C8 C7 134.0(4) . .
N4 C9 C8 108.0(3) . .
N4 C9 C10 117.5(3) . .
C8 C9 C10 134.5(4) . .
O8 C10 O7 122.1(3) . .
O8 C10 C9 117.2(3) . .
O7 C10 C9 120.6(3) . .
N4 C11 N3 112.3(3) . .
N4 C11 C12 124.5(4) . .
N3 C11 C12 123.2(4) . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Yb1 O1 2.192(3) .
Yb1 O3 2.390(3) .
Yb1 O3 2.499(3) 5_666
Yb1 O4 2.420(3) 5_666
Yb1 O5 2.258(3) .
Yb1 O7 2.256(3) .
Yb1 O1w 2.376(3) .
Yb1 O2w 2.299(3) .
Zn1 O2 2.173(3) .
Zn1 O6 2.221(3) 7_666
Zn1 O8 2.254(3) 6_565
Zn1 N1 2.122(3) .
Zn1 N3 2.064(3) 7_666
Zn1 N4 2.079(3) 6_565
O1 C1 1.263(5) .
O2 C1 1.242(5) .
O3 C4 1.265(5) .
O3 Yb1 2.499(3) 5_666
O4 C4 1.266(5) .
O4 Yb1 2.420(3) 5_666
O5 C7 1.264(5) .
O6 C7 1.255(5) .
O6 Zn1 2.221(3) 7_666
O7 C10 1.279(5) .
O8 C10 1.245(5) .
O8 Zn1 2.254(3) 6_566
O1w H11 0.8389 .
O1w H12 0.8390 .
O2w H21 0.8399 .
O2w H22 0.8397 .
O3w H31 0.8390 .
O3w H32 0.8415 .
O4w H41 0.8397 .
O4w H42 0.8370 .
O5w H51 0.8389 .
O6w H61 0.8381 .
N1 C5 1.328(5) .
N1 C2 1.379(5) .
N2 C5 1.350(5) .
N2 C3 1.373(5) .
N2 H2 0.8800 .
N3 C11 1.342(5) .
N3 C8 1.374(5) .
N3 Zn1 2.064(3) 7_666
N4 C11 1.342(5) .
N4 C9 1.364(5) .
N4 Zn1 2.079(3) 6_566
C1 C2 1.488(6) .
C2 C3 1.379(5) .
C3 C4 1.474(5) .
C5 C6 1.487(6) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 C8 1.479(5) .
C8 C9 1.389(5) .
C9 C10 1.480(5) .
C11 C12 1.483(6) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1w H11 O4 0.84 2.19 2.864(4) 138.0 1_565
O1w H12 O3w 0.84 2.23 2.696(4) 115.2 .
O2w H21 O7 0.84 1.99 2.822(4) 172.9 5_666
O2w H22 O5w 0.84 2.08 2.641(6) 124.0 .
O3w H31 O4w 0.84 1.97 2.808(8) 178.1 .
O3w H32 O6w 0.84 2.36 3.177(12) 163.2 .
O4w H41 O2 0.84 1.91 2.737(9) 167.9 2_655
O4w H42 O1w 0.84 2.38 2.960(8) 127.0 2_655
O5w H51 O4w 0.84 1.89 2.723(12) 169.0 .
N2 H2 O6 0.88 2.27 2.848(5) 122.9 1_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O7 Yb1 O1 C1 106.8(7) . .
O5 Yb1 O1 C1 179.9(7) . .
O2w Yb1 O1 C1 -40.6(7) . .
O1w Yb1 O1 C1 -111.7(7) . .
O3 Yb1 O1 C1 37.0(7) . .
O4 Yb1 O1 C1 -121.8(7) 5_666 .
O3 Yb1 O1 C1 17.6(8) 5_666 .
N3 Zn1 O2 C1 -173.7(3) 7_666 .
N4 Zn1 O2 C1 76.9(5) 6_565 .
N1 Zn1 O2 C1 -3.9(3) . .
O6 Zn1 O2 C1 -96.0(3) 7_666 .
O8 Zn1 O2 C1 85.6(3) 6_565 .
O1 Yb1 O3 C4 -11.3(5) . .
O7 Yb1 O3 C4 -122.7(5) . .
O5 Yb1 O3 C4 -69.5(6) . .
O2w Yb1 O3 C4 74.4(5) . .
O1w Yb1 O3 C4 56.1(6) . .
O4 Yb1 O3 C4 162.5(5) 5_666 .
O3 Yb1 O3 C4 155.0(6) 5_666 .
O1 Yb1 O3 Yb1 -166.29(15) . 5_666
O7 Yb1 O3 Yb1 82.31(12) . 5_666
O5 Yb1 O3 Yb1 135.53(13) . 5_666
O2w Yb1 O3 Yb1 -80.59(13) . 5_666
O1w Yb1 O3 Yb1 -98.95(19) . 5_666
O4 Yb1 O3 Yb1 7.52(16) 5_666 5_666
O3 Yb1 O3 Yb1 0.0 5_666 5_666
O1 Yb1 O5 C7 -41.1(4) . .
O7 Yb1 O5 C7 68.9(4) . .
O2w Yb1 O5 C7 -108.3(4) . .
O1w Yb1 O5 C7 -134.0(4) . .
O3 Yb1 O5 C7 16.5(5) . .
O4 Yb1 O5 C7 152.0(4) 5_666 .
O3 Yb1 O5 C7 121.5(4) 5_666 .
O1 Yb1 O7 C10 32.0(5) . .
O5 Yb1 O7 C10 -41.9(5) . .
O2w Yb1 O7 C10 134.6(5) . .
O1w Yb1 O7 C10 -75.7(5) . .
O3 Yb1 O7 C10 103.2(5) . .
O4 Yb1 O7 C10 -136.4(5) 5_666 .
O3 Yb1 O7 C10 170.5(5) 5_666 .
N3 Zn1 N1 C5 -152.6(5) 7_666 .
N4 Zn1 N1 C5 9.3(5) 6_565 .
O2 Zn1 N1 C5 170.4(5) . .
O6 Zn1 N1 C5 -91.8(4) 7_666 .
O8 Zn1 N1 C5 85.3(4) 6_565 .
N3 Zn1 N1 C2 47.2(6) 7_666 .
N4 Zn1 N1 C2 -150.9(3) 6_565 .
O2 Zn1 N1 C2 10.2(3) . .
O6 Zn1 N1 C2 108.0(3) 7_666 .
O8 Zn1 N1 C2 -74.9(3) 6_565 .
Zn1 O2 C1 O1 175.1(3) . .
Zn1 O2 C1 C2 -3.1(5) . .
Yb1 O1 C1 O2 134.0(6) . .
Yb1 O1 C1 C2 -47.8(9) . .
C5 N1 C2 C3 -1.2(5) . .
Zn1 N1 C2 C3 165.4(3) . .
C5 N1 C2 C1 178.1(4) . .
Zn1 N1 C2 C1 -15.3(4) . .
O2 C1 C2 C3 -168.4(4) . .
O1 C1 C2 C3 13.4(7) . .
O2 C1 C2 N1 12.6(5) . .
O1 C1 C2 N1 -165.7(4) . .
N1 C2 C3 N2 0.9(5) . .
C1 C2 C3 N2 -178.2(4) . .
N1 C2 C3 C4 -168.2(4) . .
C1 C2 C3 C4 12.8(8) . .
C5 N2 C3 C2 -0.2(5) . .
C5 N2 C3 C4 170.5(4) . .
Yb1 O3 C4 O4 -163.6(3) . .
Yb1 O3 C4 O4 -6.1(4) 5_666 .
Yb1 O3 C4 C3 16.2(8) . .
Yb1 O3 C4 C3 173.7(3) 5_666 .
Yb1 O4 C4 O3 6.4(4) 5_666 .
Yb1 O4 C4 C3 -173.4(3) 5_666 .
C2 C3 C4 O3 -20.8(7) . .
N2 C3 C4 O3 171.5(4) . .
C2 C3 C4 O4 159.0(5) . .
N2 C3 C4 O4 -8.7(6) . .
C2 N1 C5 N2 1.0(5) . .
Zn1 N1 C5 N2 -159.9(3) . .
C2 N1 C5 C6 -179.8(5) . .
Zn1 N1 C5 C6 19.3(8) . .
C3 N2 C5 N1 -0.5(5) . .
C3 N2 C5 C6 -179.7(4) . .
Zn1 O6 C7 O5 167.0(3) 7_666 .
Zn1 O6 C7 C8 -9.8(4) 7_666 .
Yb1 O5 C7 O6 124.5(4) . .
Yb1 O5 C7 C8 -58.9(5) . .
C11 N3 C8 C9 0.5(4) . .
Zn1 N3 C8 C9 -170.2(2) 7_666 .
C11 N3 C8 C7 176.0(3) . .
Zn1 N3 C8 C7 5.3(4) 7_666 .
O6 C7 C8 N3 3.5(5) . .
O5 C7 C8 N3 -173.4(4) . .
O6 C7 C8 C9 177.5(4) . .
O5 C7 C8 C9 0.7(6) . .
C11 N4 C9 C8 -1.0(4) . .
Zn1 N4 C9 C8 178.6(2) 6_566 .
C11 N4 C9 C10 178.7(3) . .
Zn1 N4 C9 C10 -1.7(4) 6_566 .
N3 C8 C9 N4 0.3(4) . .
C7 C8 C9 N4 -174.2(4) . .
N3 C8 C9 C10 -179.3(4) . .
C7 C8 C9 C10 6.2(7) . .
Zn1 O8 C10 O7 168.0(3) 6_566 .
Zn1 O8 C10 C9 -10.4(4) 6_566 .
Yb1 O7 C10 O8 -162.5(4) . .
Yb1 O7 C10 C9 15.9(7) . .
N4 C9 C10 O8 8.7(5) . .
C8 C9 C10 O8 -171.7(4) . .
N4 C9 C10 O7 -169.8(4) . .
C8 C9 C10 O7 9.8(7) . .
C9 N4 C11 N3 1.4(5) . .
Zn1 N4 C11 N3 -178.1(3) 6_566 .
C9 N4 C11 C12 179.6(5) . .
Zn1 N4 C11 C12 0.1(8) 6_566 .
C8 N3 C11 N4 -1.2(5) . .
Zn1 N3 C11 N4 165.4(3) 7_666 .
C8 N3 C11 C12 -179.4(4) . .
Zn1 N3 C11 C12 -12.8(7) 7_666 .
