#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:27:44 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180040 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/34/7033405.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7033405
loop_
_publ_author_name
'Wei, Yongqin'
'Sa, Rongjian'
'Li, Qiaohong'
'Wu, Kechen'
_publ_section_title
;
 Highly stable and sensitive LnMOF ratiometric thermometers constructed
 with mixed ligands.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3067
_journal_page_last               3074
_journal_paper_doi               10.1039/c4dt03421j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C25 H19 Eu N3 O10 S2'
_chemical_formula_weight         737.51
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-12-04 deposited with the CCDC.
2014-12-15 downloaded from the CCDC.
;
_cell_angle_alpha                109.677(3)
_cell_angle_beta                 103.108(2)
_cell_angle_gamma                109.545(2)
_cell_formula_units_Z            2
_cell_length_a                   10.826(4)
_cell_length_b                   12.044(4)
_cell_length_c                   12.046(4)
_cell_measurement_reflns_used    4063
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4739
_cell_measurement_theta_min      2.0087
_cell_volume                     1287.7(8)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.962
_diffrn_measurement_device_type  'Rigaku Mercury CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0246
_diffrn_reflns_av_unetI/netI     0.0426
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9953
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         2.01
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.663
_exptl_absorpt_correction_T_max  0.974
_exptl_absorpt_correction_T_min  0.888
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.902
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             730
_exptl_crystal_size_max          0.088
_exptl_crystal_size_mid          0.037
_exptl_crystal_size_min          0.010
_refine_diff_density_max         1.349
_refine_diff_density_min         -1.632
_refine_diff_density_rms         0.362
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     371
_refine_ls_number_reflns         5517
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0442
_refine_ls_R_factor_gt           0.0359
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1200P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1069
_refine_ls_wR_factor_ref         0.1543
_reflns_number_gt                5053
_reflns_number_total             5517
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt03421j2.cif
_cod_data_source_block           Eu-BDC-DSTP
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 

 Adding full bibliography for 7033405--7033408.cif.
;
_cod_original_cell_volume        1287.7(7)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7033405
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.53201(3) 0.96421(2) 0.68210(2) 0.01387(13) Uani 1 1 d .
S1 S 0.33905(15) 1.71535(13) 1.35417(14) 0.0182(3) Uani 1 1 d .
S2 S 0.30490(17) 1.23452(15) 1.24847(16) 0.0239(3) Uani 1 1 d .
O1W O -0.0966(10) 0.6159(9) 0.2779(9) 0.099(3) Uani 1 1 d .
O1 O 0.3988(5) 1.8221(5) 1.3220(5) 0.0318(11) Uani 1 1 d .
O2W O 0.7590(13) 0.5534(10) 0.4389(10) 0.114(4) Uani 1 1 d .
O2 O 0.1867(5) 1.6457(5) 1.2984(5) 0.0390(13) Uani 1 1 d .
O3 O 0.3970(5) 1.7573(5) 1.4904(4) 0.0289(10) Uani 1 1 d .
O4 O 0.2896(7) 1.2811(5) 1.3705(5) 0.0430(14) Uani 1 1 d .
O5 O 0.1722(5) 1.1466(5) 1.1388(6) 0.0426(13) Uani 1 1 d .
O6 O 0.4084(5) 1.1815(4) 1.2508(5) 0.0258(10) Uani 1 1 d .
O7 O 0.6869(5) 0.9654(4) 0.5784(4) 0.0266(10) Uani 1 1 d .
O8 O 0.6690(5) 1.0231(5) 0.4205(5) 0.0333(11) Uani 1 1 d .
N1 N 0.7734(5) 1.1382(5) 0.8694(5) 0.0200(10) Uani 1 1 d .
N2 N 0.5273(5) 1.1003(5) 0.8915(5) 0.0191(10) Uani 1 1 d .
N3 N 0.3243(5) 0.8553(5) 0.7434(5) 0.0187(10) Uani 1 1 d .
C1 C 0.8958(7) 1.1450(7) 0.8590(7) 0.0312(15) Uani 1 1 d .
H1A H 0.8956 1.0719 0.7993 0.037 Uiso 1 1 calc R
C2 C 1.0242(7) 1.2591(7) 0.9353(7) 0.0331(15) Uani 1 1 d .
H2A H 1.1081 1.2609 0.9271 0.040 Uiso 1 1 calc R
C3 C 1.0255(7) 1.3673(7) 1.0216(7) 0.0329(16) Uani 1 1 d .
H3A H 1.1097 1.4446 1.0711 0.039 Uiso 1 1 calc R
C4 C 0.8984(7) 1.3606(7) 1.0351(7) 0.0317(15) Uani 1 1 d .
H4A H 0.8970 1.4336 1.0934 0.038 Uiso 1 1 calc R
C5 C 0.7739(6) 1.2429(6) 0.9597(6) 0.0198(12) Uani 1 1 d .
C6 C 0.6366(6) 1.2192(5) 0.9700(5) 0.0168(11) Uani 1 1 d .
C7 C 0.6222(7) 1.3213(6) 1.0642(6) 0.0220(13) Uani 1 1 d .
H7A H 0.6993 1.4032 1.1185 0.026 Uiso 1 1 calc R
C8 C 0.4906(7) 1.2933(6) 1.0710(6) 0.0215(12) Uani 1 1 d .
C9 C 0.3778(7) 1.1647(6) 0.9894(6) 0.0247(13) Uani 1 1 d .
H9A H 0.2884 1.1429 0.9932 0.030 Uiso 1 1 calc R
C10 C 0.4013(6) 1.0764(6) 0.9077(6) 0.0217(13) Uani 1 1 d .
C11 C 0.2905(6) 0.9375(6) 0.8268(6) 0.0194(12) Uani 1 1 d .
C12 C 0.1575(7) 0.8905(7) 0.8363(6) 0.0241(13) Uani 1 1 d .
H12A H 0.1346 0.9467 0.8931 0.029 Uiso 1 1 calc R
C13 C 0.0608(7) 0.7586(7) 0.7595(7) 0.0304(15) Uani 1 1 d .
H13A H -0.0280 0.7262 0.7639 0.036 Uiso 1 1 calc R
C14 C 0.0967(7) 0.6750(8) 0.6761(7) 0.0367(17) Uani 1 1 d .
H14A H 0.0345 0.5861 0.6251 0.044 Uiso 1 1 calc R
C15 C 0.2297(7) 0.7303(6) 0.6723(6) 0.0282(14) Uani 1 1 d .
H15A H 0.2540 0.6756 0.6157 0.034 Uiso 1 1 calc R
C16 C 0.4647(7) 1.3975(6) 1.1555(6) 0.0221(12) Uani 1 1 d .
C17 C 0.3808(6) 1.3809(6) 1.2289(6) 0.0192(11) Uani 1 1 d .
C18 C 0.3497(6) 1.4813(5) 1.2920(5) 0.0196(11) Uani 1 1 d .
H18A H 0.2941 1.4686 1.3394 0.024 Uiso 1 1 calc R
C19 C 0.3997(6) 1.6002(6) 1.2857(6) 0.0219(13) Uani 1 1 d .
C20 C 0.4884(7) 1.6221(6) 1.2214(6) 0.0236(13) Uani 1 1 d U
H20A H 0.5266 1.7032 1.2204 0.028 Uiso 1 1 calc R
C21 C 0.5212(8) 1.5201(6) 1.1567(7) 0.0276(14) Uani 1 1 d .
H21A H 0.5820 1.5356 1.1142 0.033 Uiso 1 1 calc R
C22 C 0.7322(6) 0.9938(6) 0.4987(6) 0.0204(12) Uani 1 1 d .
C23 C 0.8710(6) 0.9968(7) 0.5002(6) 0.0232(13) Uani 1 1 d .
C24 C 0.9233(7) 0.9259(6) 0.5510(6) 0.0239(13) Uani 1 1 d .
H24A H 0.8708 0.8738 0.5815 0.029 Uiso 1 1 calc R
C25 C 0.9452(7) 1.0652(6) 0.4450(6) 0.0247(13) Uani 1 1 d .
H25A H 0.9054 1.1057 0.4046 0.030 Uiso 1 1 calc R
H4 H 0.8094 0.6331 0.4952 0.1123(14) Uiso 1 1 d R
H2 H -0.1639 0.5916 0.3029 0.1234(12) Uiso 1 1 d R
H1 H -0.0427 0.5902 0.3136 0.1325(16) Uiso 1 1 d R
H3 H 0.6700 0.5280 0.4080 0.1401(17) Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu1 O8 114.83(17) . 2_676
O7 Eu1 O6 88.32(16) . 2_677
O8 Eu1 O6 139.13(16) 2_676 2_677
O7 Eu1 O3 77.25(16) . 1_544
O8 Eu1 O3 75.11(18) 2_676 1_544
O6 Eu1 O3 78.28(17) 2_677 1_544
O7 Eu1 O1 77.51(17) . 2_687
O8 Eu1 O1 70.30(17) 2_676 2_687
O6 Eu1 O1 150.37(17) 2_677 2_687
O3 Eu1 O1 122.46(16) 1_544 2_687
O7 Eu1 N2 139.47(16) . .
O8 Eu1 N2 87.82(17) 2_676 .
O6 Eu1 N2 95.46(16) 2_677 .
O3 Eu1 N2 143.03(16) 1_544 .
O1 Eu1 N2 79.75(16) 2_687 .
O7 Eu1 N3 155.17(17) . .
O8 Eu1 N3 69.77(16) 2_676 .
O6 Eu1 N3 75.84(16) 2_677 .
O3 Eu1 N3 80.82(15) 1_544 .
O1 Eu1 N3 124.90(16) 2_687 .
N2 Eu1 N3 62.42(15) . .
O7 Eu1 N1 78.87(16) . .
O8 Eu1 N1 133.32(17) 2_676 .
O6 Eu1 N1 81.94(16) 2_677 .
O3 Eu1 N1 149.25(17) 1_544 .
O1 Eu1 N1 69.94(16) 2_687 .
N2 Eu1 N1 61.89(16) . .
N3 Eu1 N1 116.76(16) . .
O2 S1 O3 113.1(3) . .
O2 S1 O1 114.3(3) . .
O3 S1 O1 112.0(3) . .
O2 S1 C19 106.1(3) . .
O3 S1 C19 105.4(3) . .
O1 S1 C19 105.0(3) . .
O5 S2 O4 114.7(4) . .
O5 S2 O6 112.4(3) . .
O4 S2 O6 112.3(3) . .
O5 S2 C17 106.2(3) . .
O4 S2 C17 104.6(3) . .
O6 S2 C17 105.6(3) . .
H2 O1W H1 99.4 . .
S1 O1 Eu1 160.8(3) . 2_687
H4 O2W H3 116.5 . .
S1 O3 Eu1 136.7(3) . 1_566
S2 O6 Eu1 139.6(3) . 2_677
C22 O7 Eu1 148.3(4) . .
C22 O8 Eu1 150.4(4) . 2_676
C1 N1 C5 119.3(5) . .
C1 N1 Eu1 120.6(4) . .
C5 N1 Eu1 117.4(4) . .
C6 N2 C10 117.1(5) . .
C6 N2 Eu1 119.1(4) . .
C10 N2 Eu1 120.4(4) . .
C15 N3 C11 118.6(5) . .
C15 N3 Eu1 121.5(4) . .
C11 N3 Eu1 117.2(4) . .
N1 C1 C2 121.9(7) . .
N1 C1 H1A 119.1 . .
C2 C1 H1A 119.1 . .
C3 C2 C1 119.6(7) . .
C3 C2 H2A 120.2 . .
C1 C2 H2A 120.2 . .
C2 C3 C4 119.1(6) . .
C2 C3 H3A 120.5 . .
C4 C3 H3A 120.5 . .
C5 C4 C3 119.1(7) . .
C5 C4 H4A 120.5 . .
C3 C4 H4A 120.5 . .
N1 C5 C4 120.8(6) . .
N1 C5 C6 114.3(5) . .
C4 C5 C6 124.9(6) . .
N2 C6 C7 122.0(5) . .
N2 C6 C5 117.7(5) . .
C7 C6 C5 120.2(5) . .
C8 C7 C6 117.9(5) . .
C8 C7 H7A 121.0 . .
C6 C7 H7A 121.0 . .
C7 C8 C9 118.7(5) . .
C7 C8 C16 120.7(6) . .
C9 C8 C16 120.5(6) . .
C10 C9 C8 119.3(6) . .
C10 C9 H9A 120.4 . .
C8 C9 H9A 120.4 . .
C9 C10 N2 124.8(6) . .
C9 C10 C11 121.6(6) . .
N2 C10 C11 113.6(6) . .
N3 C11 C12 120.7(6) . .
N3 C11 C10 116.9(5) . .
C12 C11 C10 122.4(6) . .
C13 C12 C11 119.0(6) . .
C13 C12 H12A 120.5 . .
C11 C12 H12A 120.5 . .
C14 C13 C12 120.0(6) . .
C14 C13 H13A 120.0 . .
C12 C13 H13A 120.0 . .
C15 C14 C13 117.0(7) . .
C15 C14 H14A 121.5 . .
C13 C14 H14A 121.5 . .
N3 C15 C14 124.8(7) . .
N3 C15 H15A 117.6 . .
C14 C15 H15A 117.6 . .
C21 C16 C17 117.5(6) . .
C21 C16 C8 116.7(5) . .
C17 C16 C8 125.7(5) . .
C18 C17 C16 120.4(5) . .
C18 C17 S2 114.3(4) . .
C16 C17 S2 125.3(5) . .
C19 C18 C17 121.4(6) . .
C19 C18 H18A 119.3 . .
C17 C18 H18A 119.3 . .
C20 C19 C18 119.5(6) . .
C20 C19 S1 122.2(5) . .
C18 C19 S1 118.2(5) . .
C19 C20 C21 119.6(6) . .
C19 C20 H20A 120.2 . .
C21 C20 H20A 120.2 . .
C16 C21 C20 121.5(6) . .
C16 C21 H21A 119.3 . .
C20 C21 H21A 119.3 . .
O8 C22 O7 124.1(6) . .
O8 C22 C23 117.7(5) . .
O7 C22 C23 118.2(5) . .
C25 C23 C24 120.0(6) . .
C25 C23 C22 119.8(5) . .
C24 C23 C22 120.2(5) . .
C25 C24 C23 118.6(6) 2_776 .
C25 C24 H24A 120.7 2_776 .
C23 C24 H24A 120.7 . .
C24 C25 C23 121.2(6) 2_776 .
C24 C25 H25A 119.4 2_776 .
C23 C25 H25A 119.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O7 2.306(4) .
Eu1 O8 2.327(4) 2_676
Eu1 O6 2.371(4) 2_677
Eu1 O3 2.416(5) 1_544
Eu1 O1 2.450(4) 2_687
Eu1 N2 2.526(5) .
Eu1 N3 2.599(5) .
Eu1 N1 2.606(5) .
S1 O2 1.438(5) .
S1 O3 1.451(5) .
S1 O1 1.454(5) .
S1 C19 1.766(7) .
S2 O5 1.452(6) .
S2 O4 1.456(5) .
S2 O6 1.464(4) .
S2 C17 1.799(6) .
O1W H2 0.8498 .
O1W H1 0.8482 .
O1 Eu1 2.450(4) 2_687
O2W H4 0.8495 .
O2W H3 0.8511 .
O3 Eu1 2.416(5) 1_566
O6 Eu1 2.371(4) 2_677
O7 C22 1.265(7) .
O8 C22 1.254(7) .
O8 Eu1 2.327(4) 2_676
N1 C1 1.337(8) .
N1 C5 1.358(8) .
N2 C6 1.339(7) .
N2 C10 1.371(7) .
N3 C15 1.323(8) .
N3 C11 1.365(8) .
C1 C2 1.399(9) .
C1 H1A 0.9300 .
C2 C3 1.359(10) .
C2 H2A 0.9300 .
C3 C4 1.401(10) .
C3 H3A 0.9300 .
C4 C5 1.397(9) .
C4 H4A 0.9300 .
C5 C6 1.459(8) .
C6 C7 1.447(8) .
C7 C8 1.378(9) .
C7 H7A 0.9300 .
C8 C9 1.421(9) .
C8 C16 1.482(8) .
C9 C10 1.324(10) .
C9 H9A 0.9300 .
C10 C11 1.489(9) .
C11 C12 1.406(8) .
C12 C13 1.391(9) .
C12 H12A 0.9300 .
C13 C14 1.390(11) .
C13 H13A 0.9300 .
C14 C15 1.387(9) .
C14 H14A 0.9300 .
C15 H15A 0.9300 .
C16 C21 1.390(9) .
C16 C17 1.417(8) .
C17 C18 1.387(8) .
C18 C19 1.386(8) .
C18 H18A 0.9300 .
C19 C20 1.377(8) .
C20 C21 1.420(9) .
C20 H20A 0.9300 .
C21 H21A 0.9300 .
C22 C23 1.487(8) .
C23 C25 1.391(8) .
C23 C24 1.393(8) .
C24 C25 1.380(8) 2_776
C24 H24A 0.9300 .
C25 C24 1.380(8) 2_776
C25 H25A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 S1 O1 Eu1 73.4(10) . 2_687
O3 S1 O1 Eu1 -56.9(10) . 2_687
C19 S1 O1 Eu1 -170.8(9) . 2_687
O2 S1 O3 Eu1 -116.3(4) . 1_566
O1 S1 O3 Eu1 14.5(5) . 1_566
C19 S1 O3 Eu1 128.2(4) . 1_566
O5 S2 O6 Eu1 -84.1(5) . 2_677
O4 S2 O6 Eu1 47.1(5) . 2_677
C17 S2 O6 Eu1 160.6(4) . 2_677
O8 Eu1 O7 C22 21.5(8) 2_676 .
O6 Eu1 O7 C22 166.6(8) 2_677 .
O3 Eu1 O7 C22 88.2(8) 1_544 .
O1 Eu1 O7 C22 -39.6(8) 2_687 .
N2 Eu1 O7 C22 -97.0(8) . .
N3 Eu1 O7 C22 116.8(8) . .
N1 Eu1 O7 C22 -111.3(8) . .
O7 Eu1 N1 C1 -17.6(5) . .
O8 Eu1 N1 C1 -131.3(5) 2_676 .
O6 Eu1 N1 C1 72.3(5) 2_677 .
O3 Eu1 N1 C1 22.0(7) 1_544 .
O1 Eu1 N1 C1 -98.2(5) 2_687 .
N2 Eu1 N1 C1 172.9(5) . .
N3 Eu1 N1 C1 141.9(5) . .
O7 Eu1 N1 C5 144.0(4) . .
O8 Eu1 N1 C5 30.3(5) 2_676 .
O6 Eu1 N1 C5 -126.1(4) 2_677 .
O3 Eu1 N1 C5 -176.3(4) 1_544 .
O1 Eu1 N1 C5 63.4(4) 2_687 .
N2 Eu1 N1 C5 -25.5(4) . .
N3 Eu1 N1 C5 -56.5(4) . .
O7 Eu1 N2 C6 9.5(5) . .
O8 Eu1 N2 C6 -117.5(4) 2_676 .
O6 Eu1 N2 C6 103.3(4) 2_677 .
O3 Eu1 N2 C6 -178.9(4) 1_544 .
O1 Eu1 N2 C6 -47.1(4) 2_687 .
N3 Eu1 N2 C6 174.3(5) . .
N1 Eu1 N2 C6 25.5(4) . .
O7 Eu1 N2 C10 168.3(4) . .
O8 Eu1 N2 C10 41.3(4) 2_676 .
O6 Eu1 N2 C10 -97.9(4) 2_677 .
O3 Eu1 N2 C10 -20.2(6) 1_544 .
O1 Eu1 N2 C10 111.7(4) 2_687 .
N3 Eu1 N2 C10 -27.0(4) . .
N1 Eu1 N2 C10 -175.7(5) . .
O7 Eu1 N3 C15 -19.5(7) . .
O8 Eu1 N3 C15 86.2(5) 2_676 .
O6 Eu1 N3 C15 -71.4(5) 2_677 .
O3 Eu1 N3 C15 8.7(5) 1_544 .
O1 Eu1 N3 C15 132.1(5) 2_687 .
N2 Eu1 N3 C15 -175.4(5) . .
N1 Eu1 N3 C15 -144.6(5) . .
O7 Eu1 N3 C11 179.6(4) . .
O8 Eu1 N3 C11 -74.8(4) 2_676 .
O6 Eu1 N3 C11 127.7(4) 2_677 .
O3 Eu1 N3 C11 -152.2(4) 1_544 .
O1 Eu1 N3 C11 -28.8(5) 2_687 .
N2 Eu1 N3 C11 23.7(4) . .
N1 Eu1 N3 C11 54.5(4) . .
C5 N1 C1 C2 -2.6(10) . .
Eu1 N1 C1 C2 158.7(5) . .
N1 C1 C2 C3 -0.9(11) . .
C1 C2 C3 C4 2.0(11) . .
C2 C3 C4 C5 0.2(11) . .
C1 N1 C5 C4 4.9(9) . .
Eu1 N1 C5 C4 -157.0(5) . .
C1 N1 C5 C6 -174.4(6) . .
Eu1 N1 C5 C6 23.8(6) . .
C3 C4 C5 N1 -3.7(9) . .
C3 C4 C5 C6 175.4(6) . .
C10 N2 C6 C7 -3.0(8) . .
Eu1 N2 C6 C7 156.4(4) . .
C10 N2 C6 C5 175.8(5) . .
Eu1 N2 C6 C5 -24.7(7) . .
N1 C5 C6 N2 -0.2(7) . .
C4 C5 C6 N2 -179.4(6) . .
N1 C5 C6 C7 178.7(5) . .
C4 C5 C6 C7 -0.5(9) . .
N2 C6 C7 C8 -0.4(9) . .
C5 C6 C7 C8 -179.2(5) . .
C6 C7 C8 C9 2.5(9) . .
C6 C7 C8 C16 -173.4(5) . .
C7 C8 C9 C10 -1.1(9) . .
C16 C8 C9 C10 174.8(6) . .
C8 C9 C10 N2 -2.6(10) . .
C8 C9 C10 C11 175.3(5) . .
C6 N2 C10 C9 4.7(9) . .
Eu1 N2 C10 C9 -154.5(5) . .
C6 N2 C10 C11 -173.4(5) . .
Eu1 N2 C10 C11 27.4(6) . .
C15 N3 C11 C12 -0.5(9) . .
Eu1 N3 C11 C12 161.0(5) . .
C15 N3 C11 C10 178.3(6) . .
Eu1 N3 C11 C10 -20.2(6) . .
C9 C10 C11 N3 178.2(6) . .
N2 C10 C11 N3 -3.6(7) . .
C9 C10 C11 C12 -3.1(9) . .
N2 C10 C11 C12 175.1(6) . .
N3 C11 C12 C13 0.2(9) . .
C10 C11 C12 C13 -178.5(6) . .
C11 C12 C13 C14 0.8(10) . .
C12 C13 C14 C15 -1.4(11) . .
C11 N3 C15 C14 -0.2(10) . .
Eu1 N3 C15 C14 -160.9(6) . .
C13 C14 C15 N3 1.1(11) . .
C7 C8 C16 C21 42.7(9) . .
C9 C8 C16 C21 -133.1(6) . .
C7 C8 C16 C17 -141.1(7) . .
C9 C8 C16 C17 43.0(9) . .
C21 C16 C17 C18 4.2(9) . .
C8 C16 C17 C18 -171.9(6) . .
C21 C16 C17 S2 -176.5(5) . .
C8 C16 C17 S2 7.4(9) . .
O5 S2 C17 C18 94.9(5) . .
O4 S2 C17 C18 -26.8(6) . .
O6 S2 C17 C18 -145.5(5) . .
O5 S2 C17 C16 -84.4(6) . .
O4 S2 C17 C16 154.0(6) . .
O6 S2 C17 C16 35.2(6) . .
C16 C17 C18 C19 -0.3(9) . .
S2 C17 C18 C19 -179.6(5) . .
C17 C18 C19 C20 -3.6(9) . .
C17 C18 C19 S1 173.2(5) . .
O2 S1 C19 C20 123.1(6) . .
O3 S1 C19 C20 -116.6(6) . .
O1 S1 C19 C20 1.8(6) . .
O2 S1 C19 C18 -53.5(6) . .
O3 S1 C19 C18 66.7(5) . .
O1 S1 C19 C18 -174.8(5) . .
C18 C19 C20 C21 3.4(10) . .
S1 C19 C20 C21 -173.2(5) . .
C17 C16 C21 C20 -4.4(10) . .
C8 C16 C21 C20 172.1(7) . .
C19 C20 C21 C16 0.7(11) . .
Eu1 O8 C22 O7 -11.4(14) 2_676 .
Eu1 O8 C22 C23 170.5(6) 2_676 .
Eu1 O7 C22 O8 -13.9(12) . .
Eu1 O7 C22 C23 164.2(6) . .
O8 C22 C23 C25 18.1(10) . .
O7 C22 C23 C25 -160.1(6) . .
O8 C22 C23 C24 -158.6(6) . .
O7 C22 C23 C24 23.2(10) . .
C25 C23 C24 C25 5.6(11) . 2_776
C22 C23 C24 C25 -177.7(6) . 2_776
C24 C23 C25 C24 -5.7(12) . 2_776
C22 C23 C25 C24 177.5(6) . 2_776
