#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:27:44 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180040 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/34/7033419.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7033419
loop_
_publ_author_name
'Lin, Yu-Mei'
'Guan, Zong-Jie'
'Liu, Kuan-Guan'
'Jiang, Zhan-Guo'
'Wang, Quan-Ming'
_publ_section_title
;
 Assembly of silver alkynyl compounds with various nuclearities.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2439
_journal_page_last               2446
_journal_paper_doi               10.1039/c4dt03394a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C78 H50 Ag8 F30 N8 O12'
_chemical_formula_weight         2724.22
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 111.372(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.2589(8)
_cell_length_b                   15.9256(4)
_cell_length_c                   25.5945(9)
_cell_measurement_reflns_used    7281
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.7153
_cell_measurement_theta_min      2.1677
_cell_volume                     8828.6(5)
_computing_cell_refinement       RED
_computing_data_collection       CCD
_computing_data_reduction        RED
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Oxford, CCD'
_diffrn_measurement_method       '/w scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_av_sigmaI/netI    0.0486
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            22839
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.56
_exptl_absorpt_coefficient_mu    1.862
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.89935
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.050
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5264
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.571
_refine_diff_density_min         -0.678
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     613
_refine_ls_number_reflns         8532
_refine_ls_number_restraints     30
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0808
_refine_ls_R_factor_gt           0.0485
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0815P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1294
_refine_ls_wR_factor_ref         0.1449
_reflns_number_gt                5451
_reflns_number_total             8532
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt03394a2.cif
_cod_data_source_block           5
_cod_depositor_comments
'Adding full bibliography for 7033415--7033423.cif.'
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7033419
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.16190(2) 1.45169(4) 0.28611(2) 0.05896(18) Uani 1 1 d .
Ag2 Ag 0.03156(2) 1.45797(4) 0.21138(3) 0.05996(18) Uani 1 1 d .
Ag3 Ag 0.07463(2) 1.59323(3) 0.29545(2) 0.05391(17) Uani 1 1 d .
Ag4 Ag 0.16548(3) 1.53514(4) 0.39773(2) 0.05851(18) Uani 1 1 d .
C1 C 0.0785(3) 1.4646(4) 0.3181(3) 0.0456(15) Uani 1 1 d .
C2 C 0.0948(3) 1.4046(4) 0.3493(3) 0.0499(16) Uani 1 1 d .
C3 C 0.1074(3) 1.3259(5) 0.3829(3) 0.0602(19) Uani 1 1 d .
C4 C 0.1767(4) 1.3163(8) 0.4156(6) 0.123(5) Uani 1 1 d .
H4A H 0.1984 1.3131 0.3892 0.185 Uiso 1 1 calc R
H4B H 0.1843 1.2649 0.4381 0.185 Uiso 1 1 calc R
H4C H 0.1919 1.3649 0.4403 0.185 Uiso 1 1 calc R
C5 C 0.0734(5) 1.3311(6) 0.4247(4) 0.092(3) Uani 1 1 d .
H5A H 0.0289 1.3362 0.4038 0.139 Uiso 1 1 calc R
H5B H 0.0880 1.3803 0.4489 0.139 Uiso 1 1 calc R
H5C H 0.0817 1.2802 0.4477 0.139 Uiso 1 1 calc R
C6 C 0.0842(5) 1.2525(6) 0.3444(5) 0.095(3) Uani 1 1 d .
H6A H 0.0399 1.2591 0.3232 0.143 Uiso 1 1 calc R
H6B H 0.0914 1.2007 0.3665 0.143 Uiso 1 1 calc R
H6C H 0.1062 1.2496 0.3183 0.143 Uiso 1 1 calc R
N1 N 0.1075(2) 1.6063(4) 0.4444(2) 0.0516(14) Uani 1 1 d .
N2 N 0.1964(2) 1.6762(4) 0.4120(2) 0.0521(14) Uani 1 1 d .
N3 N 0.0320(2) 1.7109(3) 0.31987(19) 0.0393(11) Uani 1 1 d .
N4 N 0.1233(2) 1.7088(4) 0.2757(2) 0.0484(13) Uani 1 1 d .
C101 C 0.0621(4) 1.5738(5) 0.4583(3) 0.065(2) Uani 1 1 d .
H10A H 0.0505 1.5170 0.4486 0.078 Uiso 1 1 calc R
C102 C 0.0309(4) 1.6188(7) 0.4861(4) 0.074(2) Uani 1 1 d .
H10B H -0.0004 1.5927 0.4961 0.089 Uiso 1 1 calc R
C103 C 0.0457(4) 1.7000(6) 0.4987(3) 0.071(2) Uani 1 1 d .
H10C H 0.0243 1.7315 0.5174 0.085 Uiso 1 1 calc R
C104 C 0.0922(3) 1.7385(5) 0.4844(3) 0.0547(18) Uani 1 1 d .
C105 C 0.1214(3) 1.6882(4) 0.4565(3) 0.0458(15) Uani 1 1 d .
C106 C 0.1088(4) 1.8239(6) 0.4954(3) 0.068(2) Uani 1 1 d .
H10D H 0.0882 1.8574 0.5139 0.081 Uiso 1 1 calc R
C201 C 0.2400(3) 1.7105(6) 0.3973(3) 0.065(2) Uani 1 1 d .
H20A H 0.2597 1.6762 0.3785 0.078 Uiso 1 1 calc R
C202 C 0.2585(3) 1.7918(6) 0.4075(3) 0.071(2) Uani 1 1 d .
H20B H 0.2905 1.8129 0.3964 0.085 Uiso 1 1 calc R
C203 C 0.2299(4) 1.8438(6) 0.4343(3) 0.070(2) Uani 1 1 d .
H20C H 0.2408 1.9014 0.4409 0.085 Uiso 1 1 calc R
C204 C 0.1841(3) 1.8083(5) 0.4514(3) 0.0549(17) Uani 1 1 d .
C205 C 0.1693(3) 1.7256(5) 0.4398(3) 0.0473(15) Uani 1 1 d .
C206 C 0.1523(4) 1.8583(5) 0.4808(3) 0.072(2) Uani 1 1 d .
H20D H 0.1630 1.9156 0.4893 0.087 Uiso 1 1 calc R
C301 C -0.0108(3) 1.7109(4) 0.3426(3) 0.0472(15) Uani 1 1 d .
H30A H -0.0280 1.6590 0.3480 0.057 Uiso 1 1 calc R
C302 C -0.0315(3) 1.7855(6) 0.3588(3) 0.063(2) Uani 1 1 d .
H30B H -0.0627 1.7839 0.3746 0.076 Uiso 1 1 calc R
C303 C -0.0071(3) 1.8594(5) 0.3520(3) 0.065(2) Uani 1 1 d .
H30C H -0.0206 1.9102 0.3634 0.078 Uiso 1 1 calc R
C304 C 0.0380(3) 1.8612(4) 0.3283(3) 0.0538(17) Uani 1 1 d .
C305 C 0.0572(3) 1.7847(4) 0.3131(2) 0.0423(14) Uani 1 1 d .
C306 C 0.0675(4) 1.9376(5) 0.3205(4) 0.076(2) Uani 1 1 d .
H30D H 0.0550 1.9898 0.3308 0.091 Uiso 1 1 calc R
C401 C 0.1677(3) 1.7094(5) 0.2553(3) 0.0604(19) Uani 1 1 d .
H40A H 0.1808 1.6569 0.2460 0.072 Uiso 1 1 calc R
C402 C 0.1968(4) 1.7817(6) 0.2466(3) 0.072(2) Uani 1 1 d .
H40B H 0.2288 1.7782 0.2319 0.086 Uiso 1 1 calc R
C403 C 0.1783(4) 1.8573(6) 0.2596(3) 0.072(2) Uani 1 1 d .
H40C H 0.1970 1.9077 0.2537 0.086 Uiso 1 1 calc R
C404 C 0.1305(3) 1.8605(5) 0.2823(3) 0.0582(18) Uani 1 1 d .
C405 C 0.1047(3) 1.7840(4) 0.2896(2) 0.0407(13) Uani 1 1 d .
C406 C 0.1114(4) 1.9364(5) 0.2993(4) 0.067(2) Uani 1 1 d .
H40D H 0.1304 1.9876 0.2954 0.080 Uiso 1 1 calc R
O11 O 0.2632(3) 1.4512(6) 0.3442(3) 0.102(3) Uani 1 1 d .
O12 O 0.2663(2) 1.4874(4) 0.4297(3) 0.0842(19) Uani 1 1 d .
C11 C 0.2866(3) 1.4598(5) 0.3942(4) 0.061(2) Uani 1 1 d .
C12 C 0.3535(4) 1.4334(7) 0.4197(4) 0.080(3) Uani 1 1 d .
F11 F 0.3746(3) 1.4043(5) 0.3820(3) 0.136(3) Uani 1 1 d .
F12 F 0.3918(3) 1.5027(5) 0.4394(3) 0.137(3) Uani 1 1 d .
C13 C 0.3712(7) 1.3769(11) 0.4664(7) 0.130(5) Uani 1 1 d .
F13 F 0.3348(4) 1.3108(6) 0.4511(6) 0.217(6) Uani 1 1 d .
F14 F 0.3658(5) 1.4082(9) 0.5115(3) 0.213(6) Uani 1 1 d .
F15 F 0.4291(3) 1.3488(6) 0.4830(3) 0.154(3) Uani 1 1 d .
O21 O 0.1594(3) 1.3164(4) 0.2463(3) 0.0850(18) Uani 1 1 d .
O22 O 0.0614(3) 1.3273(4) 0.1901(3) 0.097(2) Uani 1 1 d .
C21 C 0.1126(5) 1.2941(5) 0.2086(4) 0.070(2) Uani 1 1 d .
C22 C 0.1161(6) 1.2110(7) 0.1798(5) 0.100(3) Uani 1 1 d .
F21 F 0.1580(5) 1.2054(7) 0.1598(5) 0.181(3) Uani 1 1 d U
F22 F 0.0615(8) 1.1989(8) 0.1258(3) 0.306(10) Uani 1 1 d .
C23 C 0.0971(9) 1.1392(13) 0.1966(8) 0.164(6) Uani 1 1 d U
F23 F 0.1573(6) 1.1370(9) 0.2474(6) 0.243(5) Uani 1 1 d U
F24 F 0.0577(4) 1.1384(6) 0.2185(4) 0.161(3) Uani 1 1 d U
F25 F 0.1044(4) 1.0648(5) 0.1727(4) 0.146(3) Uani 1 1 d U
O31 O 0.1743(3) 1.5098(5) 0.2081(3) 0.0856(18) Uani 1 1 d .
O32 O 0.0743(3) 1.5224(4) 0.1521(3) 0.0819(18) Uani 1 1 d .
C31 C 0.1296(5) 1.5242(5) 0.1631(4) 0.070(2) Uani 1 1 d .
C32 C 0.1523(5) 1.5452(10) 0.1148(4) 0.107(4) Uani 1 1 d .
F31 F 0.1315(7) 1.4942(12) 0.0754(4) 0.277(9) Uani 1 1 d .
F32 F 0.1154(5) 1.6247(12) 0.0877(6) 0.284(10) Uani 1 1 d .
C33 C 0.2065(11) 1.5847(12) 0.1207(7) 0.176(9) Uani 1 1 d .
F33 F 0.2382(8) 1.5055(11) 0.1390(6) 0.275(9) Uani 1 1 d .
F34 F 0.2218(6) 1.6430(8) 0.1540(4) 0.220(6) Uani 1 1 d .
F35 F 0.2102(4) 1.6045(7) 0.0718(3) 0.167(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Ag1 O31 98.0(2) . .
O11 Ag1 C1 123.8(2) . .
O31 Ag1 C1 129.6(2) . .
O11 Ag1 O21 97.7(3) . .
O31 Ag1 O21 89.1(3) . .
C1 Ag1 O21 109.4(2) . .
O11 Ag1 Ag2 178.2(2) . .
O31 Ag1 Ag2 81.26(17) . .
C1 Ag1 Ag2 56.12(16) . .
O21 Ag1 Ag2 83.91(15) . .
O11 Ag1 Ag3 120.1(2) . .
O31 Ag1 Ag3 93.83(18) . .
C1 Ag1 Ag3 43.11(16) . .
O21 Ag1 Ag3 141.13(14) . .
Ag2 Ag1 Ag3 58.416(18) . .
O11 Ag1 Ag4 74.28(18) . .
O31 Ag1 Ag4 130.49(18) . .
C1 Ag1 Ag4 53.17(16) . .
O21 Ag1 Ag4 140.02(17) . .
Ag2 Ag1 Ag4 104.96(2) . .
Ag3 Ag1 Ag4 54.572(17) . .
O22 Ag2 O32 90.4(3) . .
O22 Ag2 C1 110.0(2) . 2
O32 Ag2 C1 115.9(2) . 2
O22 Ag2 C1 104.0(2) . .
O32 Ag2 C1 124.1(2) . .
C1 Ag2 C1 109.12(18) 2 .
O22 Ag2 Ag2 115.8(2) . 2
O32 Ag2 Ag2 153.81(16) . 2
C1 Ag2 Ag2 57.18(16) 2 2
C1 Ag2 Ag2 52.17(14) . 2
O22 Ag2 Ag1 78.27(15) . .
O32 Ag2 Ag1 81.66(16) . .
C1 Ag2 Ag1 159.74(16) 2 .
C1 Ag2 Ag1 50.63(14) . .
Ag2 Ag2 Ag1 102.58(3) 2 .
O22 Ag2 Ag3 140.83(16) . .
O32 Ag2 Ag3 92.36(18) . .
C1 Ag2 Ag3 103.73(17) 2 .
C1 Ag2 Ag3 44.66(15) . .
Ag2 Ag2 Ag3 67.62(2) 2 .
Ag1 Ag2 Ag3 63.542(19) . .
O22 Ag2 Ag3 150.75(15) . 2
O32 Ag2 Ag3 99.80(15) . 2
C1 Ag2 Ag3 40.99(16) 2 2
C1 Ag2 Ag3 92.93(15) . 2
Ag2 Ag2 Ag3 57.515(16) 2 2
Ag1 Ag2 Ag3 130.12(2) . 2
Ag3 Ag2 Ag3 66.59(2) . 2
C1 Ag3 N4 148.5(2) . .
C1 Ag3 N3 133.6(2) . .
N4 Ag3 N3 72.89(18) . .
C1 Ag3 Ag4 59.52(18) . .
N4 Ag3 Ag4 101.61(13) . .
N3 Ag3 Ag4 105.19(12) . .
C1 Ag3 Ag2 57.55(18) . .
N4 Ag3 Ag2 119.00(13) . .
N3 Ag3 Ag2 136.44(12) . .
Ag4 Ag3 Ag2 111.93(2) . .
C1 Ag3 Ag1 49.83(17) . .
N4 Ag3 Ag1 100.11(14) . .
N3 Ag3 Ag1 165.51(12) . .
Ag4 Ag3 Ag1 63.142(18) . .
Ag2 Ag3 Ag1 58.043(18) . .
C1 Ag3 Ag2 47.75(17) . 2
N4 Ag3 Ag2 160.71(13) . 2
N3 Ag3 Ag2 99.23(12) . 2
Ag4 Ag3 Ag2 97.43(2) . 2
Ag2 Ag3 Ag2 54.86(2) . 2
Ag1 Ag3 Ag2 91.16(2) . 2
O12 Ag4 N2 92.7(2) . .
O12 Ag4 N1 131.6(2) . .
N2 Ag4 N1 70.42(19) . .
O12 Ag4 C1 123.0(2) . .
N2 Ag4 C1 130.9(2) . .
N1 Ag4 C1 100.4(2) . .
O12 Ag4 C2 106.4(2) . .
N2 Ag4 C2 157.3(2) . .
N1 Ag4 C2 103.8(2) . .
C1 Ag4 C2 26.8(2) . .
O12 Ag4 Ag3 138.39(17) . .
N2 Ag4 Ag3 85.10(13) . .
N1 Ag4 Ag3 86.59(13) . .
C1 Ag4 Ag3 45.81(15) . .
C2 Ag4 Ag3 72.55(16) . .
O12 Ag4 Ag1 82.50(15) . .
N2 Ag4 Ag1 117.00(13) . .
N1 Ag4 Ag1 145.82(13) . .
C1 Ag4 Ag1 48.12(14) . .
C2 Ag4 Ag1 55.62(14) . .
Ag3 Ag4 Ag1 62.285(19) . .
C2 C1 Ag3 155.7(6) . .
C2 C1 Ag1 93.5(5) . .
Ag3 C1 Ag1 87.1(2) . .
C2 C1 Ag2 102.3(5) . 2
Ag3 C1 Ag2 91.3(2) . 2
Ag1 C1 Ag2 143.4(3) . 2
C2 C1 Ag4 81.7(4) . .
Ag3 C1 Ag4 74.67(19) . .
Ag1 C1 Ag4 78.71(19) . .
Ag2 C1 Ag4 135.8(3) 2 .
C2 C1 Ag2 125.6(5) . .
Ag3 C1 Ag2 77.8(2) . .
Ag1 C1 Ag2 73.25(18) . .
Ag2 C1 Ag2 70.65(18) 2 .
Ag4 C1 Ag2 141.3(3) . .
C1 C2 C3 172.8(7) . .
C1 C2 Ag4 71.5(4) . .
C3 C2 Ag4 115.5(5) . .
C2 C3 C6 109.3(7) . .
C2 C3 C4 110.3(6) . .
C6 C3 C4 109.7(8) . .
C2 C3 C5 108.2(6) . .
C6 C3 C5 110.2(7) . .
C4 C3 C5 109.3(8) . .
C101 N1 C105 117.5(6) . .
C101 N1 Ag4 126.5(5) . .
C105 N1 Ag4 116.0(4) . .
C201 N2 C205 117.3(7) . .
C201 N2 Ag4 125.1(5) . .
C205 N2 Ag4 117.5(4) . .
C301 N3 C305 119.1(5) . .
C301 N3 Ag3 125.8(4) . .
C305 N3 Ag3 115.0(4) . .
C401 N4 C405 117.8(6) . .
C401 N4 Ag3 127.6(5) . .
C405 N4 Ag3 114.5(4) . .
N1 C101 C102 123.3(8) . .
C103 C102 C101 118.9(8) . .
C102 C103 C104 120.7(7) . .
C103 C104 C105 116.5(7) . .
C103 C104 C106 123.3(7) . .
C105 C104 C106 120.2(7) . .
N1 C105 C104 123.1(6) . .
N1 C105 C205 118.2(6) . .
C104 C105 C205 118.7(7) . .
C206 C106 C104 121.7(7) . .
N2 C201 C202 124.2(8) . .
C203 C202 C201 119.1(7) . .
C202 C203 C204 117.8(8) . .
C205 C204 C203 118.6(7) . .
C205 C204 C206 120.1(7) . .
C203 C204 C206 121.3(8) . .
N2 C205 C204 123.0(6) . .
N2 C205 C105 117.8(6) . .
C204 C205 C105 119.3(6) . .
C106 C206 C204 120.1(8) . .
N3 C301 C302 121.7(7) . .
C303 C302 C301 119.8(7) . .
C302 C303 C304 119.7(7) . .
C303 C304 C305 118.1(7) . .
C303 C304 C306 123.3(7) . .
C305 C304 C306 118.5(7) . .
N3 C305 C304 121.6(6) . .
N3 C305 C405 118.7(5) . .
C304 C305 C405 119.7(6) . .
C406 C306 C304 121.5(7) . .
N4 C401 C402 124.6(8) . .
C403 C402 C401 118.4(7) . .
C402 C403 C404 119.5(7) . .
C405 C404 C406 120.3(7) . .
C405 C404 C403 117.3(7) . .
C406 C404 C403 122.3(7) . .
N4 C405 C404 122.4(6) . .
N4 C405 C305 118.8(6) . .
C404 C405 C305 118.8(6) . .
C306 C406 C404 121.1(7) . .
C11 O11 Ag1 130.7(5) . .
C11 O12 Ag4 117.6(5) . .
O11 C11 O12 132.2(7) . .
O11 C11 C12 115.0(8) . .
O12 C11 C12 112.8(7) . .
F11 C12 F12 100.6(8) . .
F11 C12 C13 108.6(9) . .
F12 C12 C13 104.1(10) . .
F11 C12 C11 112.6(8) . .
F12 C12 C11 111.0(8) . .
C13 C12 C11 118.2(9) . .
F14 C13 F15 105.0(13) . .
F14 C13 F13 108.1(15) . .
F15 C13 F13 107.0(13) . .
F14 C13 C12 114.0(13) . .
F15 C13 C12 115.3(12) . .
F13 C13 C12 107.1(13) . .
C21 O21 Ag1 118.6(5) . .
C21 O22 Ag2 128.7(6) . .
O22 C21 O21 130.1(8) . .
O22 C21 C22 113.6(9) . .
O21 C21 C22 116.3(9) . .
F21 C22 C23 117.4(13) . .
F21 C22 F22 97.8(10) . .
C23 C22 F22 85.4(13) . .
F21 C22 C21 116.3(10) . .
C23 C22 C21 119.7(11) . .
F22 C22 C21 112.1(10) . .
C22 F22 C23 43.9(7) . .
F24 C23 F25 115.1(18) . .
F24 C23 C22 122.4(17) . .
F25 C23 C22 118.8(15) . .
F24 C23 F23 102.4(15) . .
F25 C23 F23 97.8(14) . .
C22 C23 F23 89.3(15) . .
F24 C23 F22 107.1(14) . .
F25 C23 F22 94.9(11) . .
C22 C23 F22 50.7(11) . .
F23 C23 F22 138.9(16) . .
C31 O31 Ag1 122.8(6) . .
C31 O32 Ag2 121.8(6) . .
O32 C31 O31 131.3(8) . .
O32 C31 C32 117.5(9) . .
O31 C31 C32 111.2(8) . .
F31 C32 C33 117.4(12) . .
F31 C32 C31 111.1(11) . .
C33 C32 C31 125.5(11) . .
F31 C32 F32 100.5(12) . .
C33 C32 F32 90.7(14) . .
C31 C32 F32 103.8(9) . .
F34 C33 F35 112.1(13) . .
F34 C33 C32 116.6(14) . .
F35 C33 C32 112.4(17) . .
F34 C33 F33 117(2) . .
F35 C33 F33 108.3(14) . .
C32 C33 F33 88.5(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O11 2.283(6) .
Ag1 O31 2.311(6) .
Ag1 C1 2.372(6) .
Ag1 O21 2.375(6) .
Ag1 Ag2 2.9380(8) .
Ag1 Ag3 3.1002(8) .
Ag1 Ag4 3.1242(8) .
Ag2 O22 2.321(6) .
Ag2 O32 2.332(6) .
Ag2 C1 2.394(6) 2
Ag2 C1 2.547(7) .
Ag2 Ag2 2.8597(11) 2
Ag2 Ag3 2.9499(8) .
Ag2 Ag3 3.2336(8) 2
Ag3 C1 2.121(7) .
Ag3 N4 2.311(5) .
Ag3 N3 2.310(5) .
Ag3 Ag4 2.8535(8) .
Ag3 Ag2 3.2335(8) 2
Ag4 O12 2.313(5) .
Ag4 N2 2.346(6) .
Ag4 N1 2.389(5) .
Ag4 C1 2.550(7) .
Ag4 C2 2.660(7) .
C1 C2 1.213(9) .
C1 Ag2 2.394(6) 2
C2 C3 1.488(10) .
C3 C6 1.497(12) .
C3 C4 1.531(12) .
C3 C5 1.546(11) .
N1 C101 1.335(9) .
N1 C105 1.353(9) .
N2 C201 1.322(9) .
N2 C205 1.361(8) .
N3 C301 1.324(7) .
N3 C305 1.353(8) .
N4 C401 1.315(8) .
N4 C405 1.364(8) .
C101 C102 1.386(11) .
C102 C103 1.347(13) .
C103 C104 1.404(11) .
C104 C105 1.403(9) .
C104 C106 1.415(11) .
C105 C205 1.456(9) .
C106 C206 1.318(12) .
C201 C202 1.359(12) .
C202 C203 1.390(12) .
C203 C204 1.409(11) .
C204 C205 1.365(10) .
C204 C206 1.467(11) .
C301 C302 1.400(10) .
C302 C303 1.346(12) .
C303 C304 1.390(10) .
C304 C305 1.400(9) .
C304 C306 1.445(11) .
C305 C405 1.437(9) .
C306 C406 1.319(12) .
C401 C402 1.395(12) .
C402 C403 1.362(13) .
C403 C404 1.428(11) .
C404 C405 1.402(10) .
C404 C406 1.411(11) .
O11 C11 1.203(10) .
O12 C11 1.247(9) .
C11 C12 1.509(11) .
C12 F11 1.315(10) .
C12 F12 1.392(12) .
C12 C13 1.433(16) .
C13 F14 1.304(16) .
C13 F15 1.333(13) .
C13 F13 1.319(18) .
O21 C21 1.217(10) .
O22 C21 1.229(10) .
C21 C22 1.532(12) .
C22 F21 1.258(11) .
C22 C23 1.35(2) .
C22 F22 1.510(17) .
F22 C23 1.94(2) .
C23 F24 1.236(17) .
C23 F25 1.373(19) .
C23 F23 1.52(2) .
O31 C31 1.260(11) .
O32 C31 1.212(11) .
C31 C32 1.549(13) .
C32 F31 1.246(15) .
C32 C33 1.368(19) .
C32 F32 1.545(18) .
C33 F34 1.222(16) .
C33 F35 1.323(13) .
C33 F33 1.45(2) .
