#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:27:44 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180040 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/34/7033420.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7033420
loop_
_publ_author_name
'Lin, Yu-Mei'
'Guan, Zong-Jie'
'Liu, Kuan-Guan'
'Jiang, Zhan-Guo'
'Wang, Quan-Ming'
_publ_section_title
;
 Assembly of silver alkynyl compounds with various nuclearities.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2439
_journal_page_last               2446
_journal_paper_doi               10.1039/c4dt03394a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C78 H82 Ag10 F12 N2 O8 P2'
_chemical_formula_weight         2544.10
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-11-03 deposited with the CCDC.
2014-12-17 downloaded from the CCDC.
;
_cell_angle_alpha                90.077(2)
_cell_angle_beta                 92.357(2)
_cell_angle_gamma                104.900(2)
_cell_formula_units_Z            2
_cell_length_a                   12.7629(3)
_cell_length_b                   15.3551(3)
_cell_length_c                   23.4186(4)
_cell_measurement_reflns_used    20286
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.7155
_cell_measurement_theta_min      2.3989
_cell_volume                     4431.07(16)
_computing_cell_refinement       RED
_computing_data_collection       CCD
_computing_data_reduction        RED
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Oxford Gemini S Ultra'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0322
_diffrn_reflns_av_sigmaI/netI    0.0417
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            39978
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.40
_exptl_absorpt_coefficient_mu    2.270
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.65915
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.907
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2472
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.666
_refine_diff_density_min         -1.261
_refine_diff_density_rms         0.168
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1009
_refine_ls_number_reflns         15412
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.060
_refine_ls_R_factor_all          0.0585
_refine_ls_R_factor_gt           0.0391
_refine_ls_shift/su_max          0.017
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0891P)²+4.8874P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1138
_refine_ls_wR_factor_ref         0.1406
_reflns_number_gt                11618
_reflns_number_total             15412
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt03394a2.cif
_cod_data_source_block           6
_cod_depositor_comments
'Adding full bibliography for 7033415--7033423.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7033420
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.44790(5) 0.69756(3) 0.39853(2) 0.04208(15) Uani 1 1 d .
Ag2 Ag -0.42062(4) 0.53715(3) 0.34711(2) 0.03179(13) Uani 1 1 d .
Ag3 Ag -0.38549(4) 0.43363(3) 0.44931(2) 0.03687(14) Uani 1 1 d .
Ag4 Ag -0.57953(4) 0.51843(3) 0.43499(2) 0.03115(13) Uani 1 1 d .
Ag5 Ag -0.61251(5) 0.34682(3) 0.48860(2) 0.03926(14) Uani 1 1 d .
Ag6 Ag -0.05695(6) 0.82814(4) 0.12123(2) 0.05105(18) Uani 1 1 d .
Ag7 Ag -0.07770(5) 0.83902(4) 0.00149(2) 0.04399(15) Uani 1 1 d .
Ag8 Ag 0.06509(4) 1.00302(3) 0.06904(2) 0.03103(13) Uani 1 1 d .
Ag9 Ag -0.10745(4) 0.99366(3) 0.14724(2) 0.03391(13) Uani 1 1 d .
Ag10 Ag -0.14564(5) 1.05527(4) 0.03214(2) 0.03937(14) Uani 1 1 d .
P1 P -0.51663(14) 0.59292(11) 0.27062(7) 0.0304(4) Uani 1 1 d .
P2 P -0.01832(14) 0.96799(11) 0.23680(7) 0.0284(4) Uani 1 1 d .
N1 N -0.4383(4) 0.7633(3) 0.3081(2) 0.0329(13) Uani 1 1 d .
N2 N -0.0816(5) 0.7898(3) 0.2173(2) 0.0349(13) Uani 1 1 d .
C1 C -0.2872(6) 0.8520(4) 0.4765(3) 0.0369(16) Uani 1 1 d .
C2 C -0.2155(8) 0.9475(5) 0.4827(4) 0.061(2) Uani 1 1 d .
C3 C -0.2594(6) 0.4109(4) 0.3406(3) 0.0346(16) Uani 1 1 d .
C4 C -0.1727(7) 0.3775(5) 0.3084(4) 0.051(2) Uani 1 1 d .
C5 C -0.2848(6) 1.1036(5) 0.1301(3) 0.0395(17) Uani 1 1 d .
C6 C -0.3735(8) 1.1449(7) 0.1502(4) 0.061(2) Uani 1 1 d .
C7 C -0.1436(6) 0.6440(5) 0.0512(3) 0.0389(16) Uani 1 1 d .
C8 C -0.1756(9) 0.5399(5) 0.0445(4) 0.060(2) Uani 1 1 d .
C11 C -0.5943(6) 0.6418(4) 0.4644(3) 0.0335(15) Uani 1 1 d .
C12 C -0.6161(6) 0.7141(5) 0.4653(3) 0.0401(17) Uani 1 1 d .
C13 C -0.6542(7) 0.7974(5) 0.4695(4) 0.051(2) Uani 1 1 d .
C14 C -0.7574(12) 0.7759(9) 0.4905(7) 0.118(5) Uani 1 1 d U
H14A H -0.8071 0.7379 0.4633 0.177 Uiso 1 1 calc R
H14B H -0.7797 0.8301 0.4967 0.177 Uiso 1 1 calc R
H14C H -0.7570 0.7447 0.5259 0.177 Uiso 1 1 calc R
C15 C -0.6107(17) 0.8618(12) 0.4304(9) 0.156(7) Uani 1 1 d U
H15A H -0.6438 0.8436 0.3932 0.234 Uiso 1 1 calc R
H15B H -0.5339 0.8685 0.4295 0.234 Uiso 1 1 calc R
H15C H -0.6241 0.9182 0.4411 0.234 Uiso 1 1 calc R
C16 C -0.5806(18) 0.8589(14) 0.5173(9) 0.185(9) Uani 1 1 d U
H16A H -0.6028 0.9137 0.5212 0.278 Uiso 1 1 calc R
H16B H -0.5062 0.8729 0.5069 0.278 Uiso 1 1 calc R
H16C H -0.5880 0.8276 0.5530 0.278 Uiso 1 1 calc R
C21 C -0.3218(5) 0.5976(4) 0.4257(3) 0.0265(13) Uani 1 1 d .
C22 C -0.2378(6) 0.6066(4) 0.4539(3) 0.0344(15) Uani 1 1 d .
C23 C -0.1279(6) 0.6219(5) 0.4800(4) 0.0475(19) Uani 1 1 d .
C24 C -0.0616(7) 0.5741(7) 0.4424(4) 0.069(3) Uani 1 1 d .
H24A H -0.0952 0.5105 0.4411 0.103 Uiso 1 1 calc R
H24B H 0.0110 0.5846 0.4585 0.103 Uiso 1 1 calc R
H24C H -0.0596 0.5977 0.4044 0.103 Uiso 1 1 calc R
C25 C -0.1318(9) 0.5858(9) 0.5412(5) 0.091(4) Uani 1 1 d .
H25A H -0.1726 0.6164 0.5639 0.137 Uiso 1 1 calc R
H25B H -0.0593 0.5962 0.5575 0.137 Uiso 1 1 calc R
H25C H -0.1659 0.5223 0.5405 0.137 Uiso 1 1 calc R
C26 C -0.0708(8) 0.7240(6) 0.4817(5) 0.081(3) Uani 1 1 d .
H26A H -0.1102 0.7548 0.5051 0.121 Uiso 1 1 calc R
H26B H -0.0688 0.7473 0.4436 0.121 Uiso 1 1 calc R
H26C H 0.0019 0.7331 0.4974 0.121 Uiso 1 1 calc R
C31 C -0.5667(5) 0.3979(4) 0.3982(3) 0.0311(14) Uani 1 1 d .
C32 C -0.5759(6) 0.3357(4) 0.3660(3) 0.0343(15) Uani 1 1 d .
C33 C -0.5966(8) 0.2590(5) 0.3220(3) 0.054(2) Uani 1 1 d .
C34 C -0.5564(12) 0.2884(9) 0.2666(6) 0.111(4) Uani 1 1 d U
H34A H -0.5982 0.3265 0.2499 0.166 Uiso 1 1 calc R
H34B H -0.5626 0.2369 0.2422 0.166 Uiso 1 1 calc R
H34C H -0.4816 0.3215 0.2709 0.166 Uiso 1 1 calc R
C35 C -0.7078(13) 0.2077(10) 0.3247(7) 0.128(5) Uani 1 1 d U
H35A H -0.7547 0.2424 0.3092 0.193 Uiso 1 1 calc R
H35B H -0.7243 0.1934 0.3637 0.193 Uiso 1 1 calc R
H35C H -0.7185 0.1529 0.3028 0.193 Uiso 1 1 calc R
C36 C -0.5239(15) 0.1968(11) 0.3493(8) 0.140(6) Uani 1 1 d U
H36A H -0.5306 0.1449 0.3252 0.210 Uiso 1 1 calc R
H36B H -0.5484 0.1778 0.3866 0.210 Uiso 1 1 calc R
H36C H -0.4493 0.2307 0.3523 0.210 Uiso 1 1 calc R
C41 C 0.1110(5) 0.8834(4) 0.0585(3) 0.0331(15) Uani 1 1 d .
C42 C 0.1497(6) 0.8225(5) 0.0706(3) 0.0404(17) Uani 1 1 d .
C43 C 0.2074(7) 0.7528(6) 0.0844(4) 0.057(2) Uani 1 1 d .
C44 C 0.3206(9) 0.7991(8) 0.1123(6) 0.097(4) Uani 1 1 d .
H44A H 0.3117 0.8282 0.1474 0.146 Uiso 1 1 calc R
H44B H 0.3603 0.8431 0.0867 0.146 Uiso 1 1 calc R
H44C H 0.3600 0.7545 0.1201 0.146 Uiso 1 1 calc R
C45 C 0.2319(13) 0.7092(9) 0.0283(6) 0.116(5) Uani 1 1 d U
H45A H 0.1649 0.6797 0.0084 0.174 Uiso 1 1 calc R
H45B H 0.2724 0.6659 0.0374 0.174 Uiso 1 1 calc R
H45C H 0.2736 0.7551 0.0046 0.174 Uiso 1 1 calc R
C46 C 0.1420(13) 0.6853(10) 0.1232(7) 0.127(5) Uani 1 1 d U
H46A H 0.0734 0.6569 0.1045 0.191 Uiso 1 1 calc R
H46B H 0.1303 0.7149 0.1576 0.191 Uiso 1 1 calc R
H46C H 0.1803 0.6406 0.1325 0.191 Uiso 1 1 calc R
C51 C -0.1886(5) 0.9011(4) 0.0733(3) 0.0283(14) Uani 1 1 d .
C52 C -0.2572(6) 0.8734(5) 0.0392(3) 0.0378(16) Uani 1 1 d .
C53 C -0.3597(6) 0.8361(5) 0.0036(3) 0.0449(18) Uani 1 1 d .
C54 C -0.4211(8) 0.7470(7) 0.0302(4) 0.071(3) Uani 1 1 d .
H54A H -0.3777 0.7045 0.0292 0.107 Uiso 1 1 calc R
H54B H -0.4884 0.7232 0.0089 0.107 Uiso 1 1 calc R
H54C H -0.4358 0.7577 0.0691 0.107 Uiso 1 1 calc R
C55 C -0.3363(8) 0.8146(8) -0.0569(4) 0.079(3) Uani 1 1 d .
H55A H -0.2918 0.7728 -0.0561 0.119 Uiso 1 1 calc R
H55B H -0.2989 0.8690 -0.0752 0.119 Uiso 1 1 calc R
H55C H -0.4034 0.7884 -0.0778 0.119 Uiso 1 1 calc R
C56 C -0.4314(8) 0.9036(7) 0.0063(5) 0.073(3) Uani 1 1 d .
H56A H -0.3949 0.9594 -0.0108 0.109 Uiso 1 1 calc R
H56B H -0.4443 0.9144 0.0455 0.109 Uiso 1 1 calc R
H56C H -0.4994 0.8789 -0.0141 0.109 Uiso 1 1 calc R
C61 C 0.0327(5) 1.1246(4) 0.0917(3) 0.0289(14) Uani 1 1 d .
C62 C 0.0348(5) 1.1950(4) 0.1153(3) 0.0315(14) Uani 1 1 d .
C63 C 0.0407(6) 1.2807(4) 0.1467(3) 0.0399(17) Uani 1 1 d .
C64 C 0.0057(9) 1.2604(6) 0.2075(4) 0.068(3) Uani 1 1 d .
H64A H 0.0537 1.2301 0.2268 0.102 Uiso 1 1 calc R
H64B H -0.0670 1.2225 0.2067 0.102 Uiso 1 1 calc R
H64C H 0.0083 1.3157 0.2273 0.102 Uiso 1 1 calc R
C65 C -0.0352(9) 1.3311(6) 0.1152(5) 0.073(3) Uani 1 1 d .
H65A H -0.0124 1.3439 0.0769 0.109 Uiso 1 1 calc R
H65B H -0.0317 1.3866 0.1351 0.109 Uiso 1 1 calc R
H65C H -0.1084 1.2941 0.1142 0.109 Uiso 1 1 calc R
C66 C 0.1580(8) 1.3394(6) 0.1461(4) 0.068(3) Uani 1 1 d .
H66A H 0.2055 1.3091 0.1659 0.103 Uiso 1 1 calc R
H66B H 0.1627 1.3961 0.1648 0.103 Uiso 1 1 calc R
H66C H 0.1791 1.3498 0.1074 0.103 Uiso 1 1 calc R
C101 C -0.4549(5) 0.7139(5) 0.2604(3) 0.0354(15) Uani 1 1 d .
C102 C -0.4302(6) 0.7494(5) 0.2060(3) 0.0460(19) Uani 1 1 d .
H10A H -0.4420 0.7127 0.1735 0.055 Uiso 1 1 calc R
C103 C -0.3865(7) 0.8435(5) 0.2028(3) 0.050(2) Uani 1 1 d .
H10B H -0.3678 0.8705 0.1678 0.060 Uiso 1 1 calc R
C104 C -0.3720(6) 0.8949(5) 0.2526(4) 0.052(2) Uani 1 1 d .
H10C H -0.3444 0.9571 0.2518 0.062 Uiso 1 1 calc R
C105 C -0.3994(6) 0.8518(5) 0.3027(3) 0.0422(17) Uani 1 1 d .
H10D H -0.3901 0.8870 0.3358 0.051 Uiso 1 1 calc R
C201 C -0.6585(6) 0.5915(5) 0.2827(3) 0.0376(16) Uani 1 1 d .
C202 C -0.7009(7) 0.6623(5) 0.2749(4) 0.059(2) Uani 1 1 d .
H20A H -0.6568 0.7169 0.2631 0.071 Uiso 1 1 calc R
C203 C -0.8104(8) 0.6554(7) 0.2841(5) 0.079(3) Uani 1 1 d .
H20B H -0.8396 0.7043 0.2776 0.095 Uiso 1 1 calc R
C204 C -0.8731(7) 0.5764(7) 0.3026(5) 0.072(3) Uani 1 1 d .
H20C H -0.9449 0.5726 0.3106 0.086 Uiso 1 1 calc R
C205 C -0.8342(7) 0.5020(7) 0.3099(4) 0.062(2) Uani 1 1 d .
H20D H -0.8800 0.4474 0.3204 0.074 Uiso 1 1 calc R
C206 C -0.7258(6) 0.5090(6) 0.3014(3) 0.0482(19) Uani 1 1 d .
H20E H -0.6972 0.4598 0.3080 0.058 Uiso 1 1 calc R
C301 C -0.5231(6) 0.5407(4) 0.1998(3) 0.0363(16) Uani 1 1 d .
C302 C -0.6008(7) 0.5436(5) 0.1590(3) 0.053(2) Uani 1 1 d .
H30A H -0.6545 0.5723 0.1672 0.063 Uiso 1 1 calc R
C303 C -0.6019(9) 0.5057(7) 0.1066(4) 0.070(3) Uani 1 1 d .
H30B H -0.6565 0.5074 0.0794 0.084 Uiso 1 1 calc R
C304 C -0.5219(9) 0.4649(7) 0.0940(4) 0.073(3) Uani 1 1 d .
H30C H -0.5218 0.4392 0.0580 0.088 Uiso 1 1 calc R
C305 C -0.4404(9) 0.4619(7) 0.1352(4) 0.072(3) Uani 1 1 d .
H30D H -0.3856 0.4349 0.1264 0.086 Uiso 1 1 calc R
C306 C -0.4409(7) 0.4983(6) 0.1884(3) 0.052(2) Uani 1 1 d .
H30E H -0.3881 0.4951 0.2163 0.063 Uiso 1 1 calc R
C401 C -0.0791(5) 0.8519(4) 0.2579(3) 0.0308(14) Uani 1 1 d .
C402 C -0.1215(6) 0.8291(5) 0.3115(3) 0.0427(18) Uani 1 1 d .
H40A H -0.1186 0.8733 0.3391 0.051 Uiso 1 1 calc R
C403 C -0.1684(6) 0.7381(5) 0.3228(3) 0.0480(19) Uani 1 1 d .
H40B H -0.1993 0.7208 0.3577 0.058 Uiso 1 1 calc R
C404 C -0.1676(7) 0.6744(5) 0.2809(4) 0.049(2) Uani 1 1 d .
H40C H -0.1954 0.6133 0.2875 0.059 Uiso 1 1 calc R
C405 C -0.1246(7) 0.7039(5) 0.2290(3) 0.0459(19) Uani 1 1 d .
H40D H -0.1258 0.6610 0.2007 0.055 Uiso 1 1 calc R
C501 C 0.1242(5) 0.9709(4) 0.2366(3) 0.0312(14) Uani 1 1 d .
C502 C 0.1923(6) 1.0350(4) 0.2019(3) 0.0347(15) Uani 1 1 d .
H50A H 0.1635 1.0741 0.1796 0.042 Uiso 1 1 calc R
C503 C 0.3032(6) 1.0393(5) 0.2011(3) 0.0410(17) Uani 1 1 d .
H50B H 0.3482 1.0815 0.1784 0.049 Uiso 1 1 calc R
C504 C 0.3454(7) 0.9820(5) 0.2334(4) 0.050(2) Uani 1 1 d .
H50C H 0.4192 0.9856 0.2328 0.060 Uiso 1 1 calc R
C505 C 0.2819(7) 0.9203(5) 0.2661(4) 0.055(2) Uani 1 1 d .
H50D H 0.3120 0.8809 0.2873 0.066 Uiso 1 1 calc R
C506 C 0.1723(6) 0.9145(5) 0.2689(3) 0.0452(18) Uani 1 1 d .
H50E H 0.1302 0.8723 0.2927 0.054 Uiso 1 1 calc R
C601 C -0.0311(6) 1.0379(4) 0.2969(3) 0.0341(15) Uani 1 1 d .
C602 C -0.1211(6) 1.0753(5) 0.2949(3) 0.0389(16) Uani 1 1 d .
H60A H -0.1705 1.0628 0.2638 0.047 Uiso 1 1 calc R
C603 C -0.1366(7) 1.1295(5) 0.3379(3) 0.050(2) Uani 1 1 d .
H60B H -0.1967 1.1532 0.3368 0.060 Uiso 1 1 calc R
C604 C -0.0597(8) 1.1493(6) 0.3844(4) 0.061(2) Uani 1 1 d .
H60C H -0.0701 1.1854 0.4145 0.073 Uiso 1 1 calc R
C605 C 0.0280(9) 1.1164(6) 0.3855(4) 0.067(3) Uani 1 1 d .
H60D H 0.0801 1.1325 0.4153 0.081 Uiso 1 1 calc R
C606 C 0.0416(7) 1.0584(5) 0.3424(3) 0.052(2) Uani 1 1 d .
H60E H 0.1007 1.0334 0.3446 0.063 Uiso 1 1 calc R
O1 O -0.3287(5) 0.8334(3) 0.4275(3) 0.0610(16) Uani 1 1 d .
O2 O -0.2990(5) 0.8062(3) 0.5201(2) 0.0557(15) Uani 1 1 d .
O3 O -0.3026(4) 0.4589(3) 0.3130(2) 0.0388(11) Uani 1 1 d .
O4 O -0.2716(5) 0.3818(3) 0.3899(2) 0.0477(13) Uani 1 1 d .
O5 O -0.2709(4) 1.1159(3) 0.0773(2) 0.0457(12) Uani 1 1 d .
O6 O -0.2452(4) 1.0631(4) 0.1649(2) 0.0438(12) Uani 1 1 d .
O7 O -0.1445(6) 0.6840(4) 0.0048(3) 0.0610(16) Uani 1 1 d .
O8 O -0.1197(5) 0.6744(3) 0.0990(2) 0.0561(15) Uani 1 1 d .
F1 F -0.2110(7) 0.9801(4) 0.5359(3) 0.105(2) Uani 1 1 d .
F2 F -0.1136(5) 0.9496(4) 0.4727(4) 0.107(2) Uani 1 1 d .
F3 F -0.2464(6) 1.0070(3) 0.4512(3) 0.092(2) Uani 1 1 d .
F4 F -0.1241(5) 0.4379(4) 0.2702(3) 0.094(2) Uani 1 1 d .
F5 F -0.0942(5) 0.3623(4) 0.3424(3) 0.0855(18) Uani 1 1 d .
F6 F -0.2167(5) 0.3038(4) 0.2798(3) 0.091(2) Uani 1 1 d .
F7 F -0.4708(6) 1.0902(8) 0.1377(4) 0.155(4) Uani 1 1 d .
F8 F -0.3790(8) 1.2171(6) 0.1284(4) 0.151(4) Uani 1 1 d .
F9 F -0.3774(8) 1.1452(7) 0.2074(3) 0.141(4) Uani 1 1 d .
F10 F -0.1707(6) 0.4994(4) 0.0932(3) 0.111(3) Uani 1 1 d .
F11 F -0.2779(6) 0.5104(4) 0.0261(2) 0.087(2) Uani 1 1 d .
F12 F -0.1165(8) 0.5131(4) 0.0089(5) 0.150(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Ag1 N1 84.40(19) . .
O1 Ag1 C11 113.7(2) . .
N1 Ag1 C11 134.4(2) . .
O1 Ag1 C21 96.5(2) . .
N1 Ag1 C21 119.4(2) . .
C11 Ag1 C21 100.5(2) . .
O1 Ag1 Ag2 133.76(18) . .
N1 Ag1 Ag2 88.95(14) . .
C11 Ag1 Ag2 103.37(16) . .
C21 Ag1 Ag2 48.73(14) . .
O1 Ag1 Ag5 79.56(14) . 2_466
N1 Ag1 Ag5 161.00(13) . 2_466
C11 Ag1 Ag5 62.64(16) . 2_466
C21 Ag1 Ag5 53.28(14) . 2_466
Ag2 Ag1 Ag5 94.79(2) . 2_466
O1 Ag1 Ag4 146.08(14) . .
N1 Ag1 Ag4 129.44(13) . .
C11 Ag1 Ag4 43.50(16) . .
C21 Ag1 Ag4 70.59(13) . .
Ag2 Ag1 Ag4 59.930(16) . .
Ag5 Ag1 Ag4 67.502(18) 2_466 .
C21 Ag2 O3 98.0(2) . .
C21 Ag2 P1 135.32(15) . .
O3 Ag2 P1 111.93(13) . .
C21 Ag2 Ag1 58.88(16) . .
O3 Ag2 Ag1 147.81(13) . .
P1 Ag2 Ag1 79.32(4) . .
C21 Ag2 Ag4 75.96(16) . .
O3 Ag2 Ag4 138.53(12) . .
P1 Ag2 Ag4 99.35(5) . .
Ag1 Ag2 Ag4 62.258(17) . .
C21 Ag2 Ag3 55.65(14) . .
O3 Ag2 Ag3 79.08(12) . .
P1 Ag2 Ag3 158.95(5) . .
Ag1 Ag2 Ag3 101.02(2) . .
Ag4 Ag2 Ag3 63.482(17) . .
C11 Ag3 O4 111.9(2) 2_466 .
C11 Ag3 C31 107.5(2) 2_466 .
O4 Ag3 C31 105.9(2) . .
C11 Ag3 C21 132.2(2) 2_466 .
O4 Ag3 C21 97.31(19) . .
C31 Ag3 C21 99.2(2) . .
C11 Ag3 Ag4 45.22(17) 2_466 2_466
O4 Ag3 Ag4 145.54(14) . 2_466
C31 Ag3 Ag4 106.17(15) . 2_466
C21 Ag3 Ag4 89.86(14) . 2_466
C11 Ag3 Ag2 163.66(17) 2_466 .
O4 Ag3 Ag2 82.95(13) . .
C31 Ag3 Ag2 60.17(14) . .
C21 Ag3 Ag2 47.64(15) . .
Ag4 Ag3 Ag2 124.55(2) 2_466 .
C11 Ag3 Ag5 60.71(18) 2_466 .
O4 Ag3 Ag5 131.99(13) . .
C31 Ag3 Ag5 47.97(14) . .
C21 Ag3 Ag5 123.08(15) . .
Ag4 Ag3 Ag5 66.214(18) 2_466 .
Ag2 Ag3 Ag5 104.59(2) . .
C11 Ag3 Ag4 106.21(17) 2_466 .
O4 Ag3 Ag4 137.16(14) . .
C31 Ag3 Ag4 42.30(16) . .
C21 Ag3 Ag4 69.28(15) . .
Ag4 Ag3 Ag4 76.79(2) 2_466 .
Ag2 Ag3 Ag4 57.537(16) . .
Ag5 Ag3 Ag4 55.621(16) . .
C11 Ag4 C31 175.0(2) . .
C11 Ag4 Ag5 131.82(17) . .
C31 Ag4 Ag5 52.76(17) . .
C11 Ag4 Ag3 52.73(17) . 2_466
C31 Ag4 Ag3 132.07(17) . 2_466
Ag5 Ag4 Ag3 79.50(2) . 2_466
C11 Ag4 Ag2 112.40(17) . .
C31 Ag4 Ag2 64.59(17) . .
Ag5 Ag4 Ag2 110.66(2) . .
Ag3 Ag4 Ag2 144.93(2) 2_466 .
C11 Ag4 Ag1 54.67(17) . .
C31 Ag4 Ag1 122.39(17) . .
Ag5 Ag4 Ag1 154.73(3) . .
Ag3 Ag4 Ag1 98.38(2) 2_466 .
Ag2 Ag4 Ag1 57.812(17) . .
C11 Ag4 Ag3 129.2(2) . .
C31 Ag4 Ag3 53.38(18) . .
Ag5 Ag4 Ag3 61.387(18) . .
Ag3 Ag4 Ag3 103.21(2) 2_466 .
Ag2 Ag4 Ag3 58.980(16) . .
Ag1 Ag4 Ag3 95.22(2) . .
C11 Ag4 Ag5 58.2(2) . 2_466
C31 Ag4 Ag5 124.25(18) . 2_466
Ag5 Ag4 Ag5 105.29(2) . 2_466
Ag3 Ag4 Ag5 59.162(17) 2_466 2_466
Ag2 Ag4 Ag5 85.832(19) . 2_466
Ag1 Ag4 Ag5 54.456(16) . 2_466
Ag3 Ag4 Ag5 70.964(18) . 2_466
C31 Ag5 O2 107.2(2) . 2_466
C31 Ag5 C21 137.5(2) . 2_466
O2 Ag5 C21 106.65(19) 2_466 2_466
C31 Ag5 C22 123.4(2) . 2_466
O2 Ag5 C22 96.5(2) 2_466 2_466
C21 Ag5 C22 27.4(2) 2_466 2_466
C31 Ag5 Ag1 150.63(16) . 2_466
O2 Ag5 Ag1 84.85(14) 2_466 2_466
C21 Ag5 Ag1 57.10(15) 2_466 2_466
C22 Ag5 Ag1 80.11(15) 2_466 2_466
C31 Ag5 Ag4 46.16(17) . .
O2 Ag5 Ag4 144.70(15) 2_466 .
C21 Ag5 Ag4 91.89(13) 2_466 .
C22 Ag5 Ag4 86.33(14) 2_466 .
Ag1 Ag5 Ag4 130.06(2) 2_466 .
C31 Ag5 Ag3 53.37(16) . .
O2 Ag5 Ag3 125.26(16) 2_466 .
C21 Ag5 Ag3 120.40(15) 2_466 .
C22 Ag5 Ag3 138.01(15) 2_466 .
Ag1 Ag5 Ag3 97.64(2) 2_466 .
Ag4 Ag5 Ag3 62.992(17) . .
C31 Ag5 Ag4 100.53(16) . 2_466
O2 Ag5 Ag4 140.03(15) 2_466 2_466
C21 Ag5 Ag4 67.23(15) 2_466 2_466
C22 Ag5 Ag4 91.53(16) 2_466 2_466
Ag1 Ag5 Ag4 58.042(17) 2_466 2_466
Ag4 Ag5 Ag4 74.71(2) . 2_466
Ag3 Ag5 Ag4 54.625(16) . 2_466
O8 Ag6 N2 87.58(19) . .
O8 Ag6 C51 105.8(2) . .
N2 Ag6 C51 117.5(2) . .
O8 Ag6 C41 104.1(2) . .
N2 Ag6 C41 134.9(2) . .
C51 Ag6 C41 101.2(2) . .
O8 Ag6 Ag7 80.87(14) . .
N2 Ag6 Ag7 165.12(14) . .
C51 Ag6 Ag7 57.74(14) . .
C41 Ag6 Ag7 57.98(15) . .
O8 Ag6 Ag9 148.07(17) . .
N2 Ag6 Ag9 87.87(14) . .
C51 Ag6 Ag9 49.98(14) . .
C41 Ag6 Ag9 101.39(15) . .
Ag7 Ag6 Ag9 96.95(2) . .
O8 Ag6 Ag8 140.51(14) . .
N2 Ag6 Ag8 129.87(13) . .
C51 Ag6 Ag8 70.80(14) . .
C41 Ag6 Ag8 42.63(14) . .
Ag7 Ag6 Ag8 63.820(19) . .
Ag9 Ag6 Ag8 59.024(17) . .
C61 Ag7 O7 107.4(2) 2_575 .
C61 Ag7 C51 133.0(2) 2_575 .
O7 Ag7 C51 104.8(2) . .
C61 Ag7 C41 103.4(2) 2_575 .
O7 Ag7 C41 108.2(2) . .
C51 Ag7 C41 98.0(2) . .
C61 Ag7 C52 118.4(2) 2_575 .
O7 Ag7 C52 94.5(2) . .
C51 Ag7 C52 25.4(2) . .
C41 Ag7 C52 123.4(2) . .
C61 Ag7 Ag6 160.07(16) 2_575 .
O7 Ag7 Ag6 84.51(15) . .
C51 Ag7 Ag6 54.59(14) . .
C41 Ag7 Ag6 57.06(15) . .
C52 Ag7 Ag6 75.31(16) . .
C61 Ag7 Ag8 45.33(16) 2_575 2_575
O7 Ag7 Ag8 144.34(15) . 2_575
C51 Ag7 Ag8 89.71(13) . 2_575
C41 Ag7 Ag8 101.61(14) . 2_575
C52 Ag7 Ag8 84.84(15) . 2_575
Ag6 Ag7 Ag8 129.06(3) . 2_575
C61 Ag7 Ag10 56.24(15) 2_575 2_575
O7 Ag7 Ag10 127.72(17) . 2_575
C51 Ag7 Ag10 122.27(14) . 2_575
C41 Ag7 Ag10 48.08(14) . 2_575
C52 Ag7 Ag10 137.76(15) . 2_575
Ag6 Ag7 Ag10 103.83(3) . 2_575
Ag8 Ag7 Ag10 62.620(18) 2_575 2_575
C61 Ag7 Ag8 102.12(16) 2_575 .
O7 Ag7 Ag8 142.80(16) . .
C51 Ag7 Ag8 68.55(14) . .
C41 Ag7 Ag8 41.72(15) . .
C52 Ag7 Ag8 90.91(16) . .
Ag6 Ag7 Ag8 61.382(19) . .
Ag8 Ag7 Ag8 72.79(2) 2_575 .
Ag10 Ag7 Ag8 55.537(17) 2_575 .
C41 Ag8 C61 171.1(3) . .
C41 Ag8 Ag10 53.80(18) . 2_575
C61 Ag8 Ag10 132.21(17) . 2_575
C41 Ag8 Ag9 115.07(18) . .
C61 Ag8 Ag9 63.14(17) . .
Ag10 Ag8 Ag9 151.06(2) 2_575 .
C41 Ag8 Ag7 133.91(18) . 2_575
C61 Ag8 Ag7 52.00(17) . 2_575
Ag10 Ag8 Ag7 80.33(2) 2_575 2_575
Ag9 Ag8 Ag7 107.37(2) . 2_575
C41 Ag8 Ag6 57.94(18) . .
C61 Ag8 Ag6 120.54(17) . .
Ag10 Ag8 Ag6 103.08(2) 2_575 .
Ag9 Ag8 Ag6 57.473(19) . .
Ag7 Ag8 Ag6 152.75(3) 2_575 .
C41 Ag8 Ag10 131.16(19) . .
C61 Ag8 Ag10 56.31(17) . .
Ag10 Ag8 Ag10 106.41(2) 2_575 .
Ag9 Ag8 Ag10 58.307(16) . .
Ag7 Ag8 Ag10 60.612(19) 2_575 .
Ag6 Ag8 Ag10 92.96(2) . .
C41 Ag8 Ag7 57.30(19) . .
C61 Ag8 Ag7 130.18(17) . .
Ag10 Ag8 Ag7 61.163(18) 2_575 .
Ag9 Ag8 Ag7 90.10(2) . .
Ag7 Ag8 Ag7 107.21(2) 2_575 .
Ag6 Ag8 Ag7 54.798(17) . .
Ag10 Ag8 Ag7 73.94(2) . .
C51 Ag9 O6 99.5(2) . .
C51 Ag9 P2 132.98(16) . .
O6 Ag9 P2 109.77(13) . .
C51 Ag9 C61 101.2(2) . .
O6 Ag9 C61 101.40(19) . .
P2 Ag9 C61 107.73(14) . .
C51 Ag9 Ag6 56.56(16) . .
O6 Ag9 Ag6 145.61(13) . .
P2 Ag9 Ag6 79.61(4) . .
C61 Ag9 Ag6 107.06(14) . .
C51 Ag9 Ag8 75.90(17) . .
O6 Ag9 Ag8 140.20(12) . .
P2 Ag9 Ag8 100.80(4) . .
C61 Ag9 Ag8 43.60(14) . .
Ag6 Ag9 Ag8 63.503(19) . .
C51 Ag9 Ag10 55.69(15) . .
O6 Ag9 Ag10 80.47(12) . .
P2 Ag9 Ag10 162.08(5) . .
C61 Ag9 Ag10 54.88(13) . .
Ag6 Ag9 Ag10 100.39(2) . .
Ag8 Ag9 Ag10 64.140(18) . .
C41 Ag10 O5 111.0(2) 2_575 .
C41 Ag10 C51 136.0(2) 2_575 .
O5 Ag10 C51 100.5(2) . .
C41 Ag10 C61 103.8(2) 2_575 .
O5 Ag10 C61 102.3(2) . .
C51 Ag10 C61 98.4(2) . .
C41 Ag10 Ag8 46.01(17) 2_575 2_575
O5 Ag10 Ag8 150.48(13) . 2_575
C51 Ag10 Ag8 92.64(15) . 2_575
C61 Ag10 Ag8 101.75(14) . 2_575
C41 Ag10 Ag9 160.20(16) 2_575 .
O5 Ag10 Ag9 82.94(13) . .
C51 Ag10 Ag9 48.93(14) . .
C61 Ag10 Ag9 58.20(13) . .
Ag8 Ag10 Ag9 124.68(2) 2_575 .
C41 Ag10 Ag7 57.03(17) 2_575 2_575
O5 Ag10 Ag7 125.14(13) . 2_575
C51 Ag10 Ag7 125.00(16) . 2_575
C61 Ag10 Ag7 47.74(14) . 2_575
Ag8 Ag10 Ag7 63.299(18) 2_575 2_575
Ag9 Ag10 Ag7 103.63(2) . 2_575
C41 Ag10 Ag8 103.99(16) 2_575 .
O5 Ag10 Ag8 135.81(13) . .
C51 Ag10 Ag8 69.48(16) . .
C61 Ag10 Ag8 41.94(14) . .
Ag8 Ag10 Ag8 73.59(2) 2_575 .
Ag9 Ag10 Ag8 57.552(17) . .
Ag7 Ag10 Ag8 56.768(17) 2_575 .
C301 P1 C101 105.5(3) . .
C301 P1 C201 103.7(3) . .
C101 P1 C201 101.8(3) . .
C301 P1 Ag2 117.8(2) . .
C101 P1 Ag2 110.0(2) . .
C201 P1 Ag2 116.3(2) . .
C501 P2 C601 105.3(3) . .
C501 P2 C401 102.0(3) . .
C601 P2 C401 105.8(3) . .
C501 P2 Ag9 118.0(2) . .
C601 P2 Ag9 116.5(2) . .
C401 P2 Ag9 107.7(2) . .
C101 N1 C105 117.0(6) . .
C101 N1 Ag1 121.7(4) . .
C105 N1 Ag1 120.4(5) . .
C405 N2 C401 118.5(6) . .
C405 N2 Ag6 117.5(5) . .
C401 N2 Ag6 121.9(4) . .
O2 C1 O1 129.9(7) . .
O2 C1 C2 116.6(7) . .
O1 C1 C2 113.5(7) . .
F3 C2 F2 109.6(8) . .
F3 C2 F1 104.1(7) . .
F2 C2 F1 104.2(9) . .
F3 C2 C1 115.0(8) . .
F2 C2 C1 110.6(7) . .
F1 C2 C1 112.6(8) . .
O3 C3 O4 132.2(6) . .
O3 C3 C4 114.5(7) . .
O4 C3 C4 113.3(7) . .
F6 C4 F5 107.9(7) . .
F6 C4 F4 106.3(8) . .
F5 C4 F4 106.1(7) . .
F6 C4 C3 111.1(7) . .
F5 C4 C3 113.7(7) . .
F4 C4 C3 111.4(6) . .
O6 C5 O5 132.0(7) . .
O6 C5 C6 116.6(7) . .
O5 C5 C6 111.3(7) . .
F8 C6 F7 103.5(9) . .
F8 C6 F9 113.3(9) . .
F7 C6 F9 98.8(9) . .
F8 C6 C5 117.0(8) . .
F7 C6 C5 110.4(8) . .
F9 C6 C5 111.9(7) . .
O8 C7 O7 129.7(7) . .
O8 C7 C8 116.9(7) . .
O7 C7 C8 113.4(7) . .
F12 C8 F10 109.3(9) . .
F12 C8 F11 107.8(9) . .
F10 C8 F11 104.4(8) . .
F12 C8 C7 111.7(8) . .
F10 C8 C7 112.5(7) . .
F11 C8 C7 110.7(8) . .
C12 C11 Ag4 160.5(6) . .
C12 C11 Ag3 114.3(5) . 2_466
Ag4 C11 Ag3 82.1(2) . 2_466
C12 C11 Ag1 91.7(5) . .
Ag4 C11 Ag1 81.8(2) . .
Ag3 C11 Ag1 136.8(3) 2_466 .
C11 C12 C13 173.6(7) . .
C15 C13 C14 128.7(12) . .
C15 C13 C12 114.0(10) . .
C14 C13 C12 109.1(8) . .
C15 C13 C16 88.3(12) . .
C14 C13 C16 104.8(12) . .
C12 C13 C16 107.1(11) . .
C13 C15 C16 49.9(9) . .
C13 C16 C15 41.8(8) . .
C22 C21 Ag2 146.8(5) . .
C22 C21 Ag5 84.7(4) . 2_466
Ag2 C21 Ag5 127.1(3) . 2_466
C22 C21 Ag3 92.5(4) . .
Ag2 C21 Ag3 76.71(17) . .
Ag5 C21 Ag3 95.9(2) 2_466 .
C22 C21 Ag1 135.9(5) . .
Ag2 C21 Ag1 72.39(19) . .
Ag5 C21 Ag1 69.63(16) 2_466 .
Ag3 C21 Ag1 124.3(3) . .
C21 C22 C23 171.3(7) . .
C21 C22 Ag5 67.9(4) . 2_466
C23 C22 Ag5 118.9(5) . 2_466
C22 C23 C25 110.7(7) . .
C22 C23 C26 110.1(7) . .
C25 C23 C26 108.8(8) . .
C22 C23 C24 108.5(7) . .
C25 C23 C24 110.6(8) . .
C26 C23 C24 108.1(8) . .
C32 C31 Ag4 162.6(6) . .
C32 C31 Ag5 110.3(5) . .
Ag4 C31 Ag5 81.1(2) . .
C32 C31 Ag3 110.4(5) . .
Ag4 C31 Ag3 84.3(2) . .
Ag5 C31 Ag3 78.65(19) . .
C31 C32 C33 174.6(8) . .
C34 C33 C35 117.9(11) . .
C34 C33 C32 112.9(7) . .
C35 C33 C32 108.5(9) . .
C34 C33 C36 108.3(11) . .
C35 C33 C36 106.3(10) . .
C32 C33 C36 101.4(9) . .
C42 C41 Ag8 158.2(6) . .
C42 C41 Ag10 116.4(5) . 2_575
Ag8 C41 Ag10 80.2(2) . 2_575
C42 C41 Ag6 94.8(5) . .
Ag8 C41 Ag6 79.4(2) . .
Ag10 C41 Ag6 137.2(3) 2_575 .
C42 C41 Ag7 115.8(6) . .
Ag8 C41 Ag7 81.0(2) . .
Ag10 C41 Ag7 74.89(18) 2_575 .
Ag6 C41 Ag7 64.96(16) . .
C41 C42 C43 174.7(8) . .
C42 C43 C46 109.8(9) . .
C42 C43 C45 109.6(8) . .
C46 C43 C45 112.3(10) . .
C42 C43 C44 108.8(7) . .
C46 C43 C44 111.3(10) . .
C45 C43 C44 104.8(10) . .
C52 C51 Ag9 153.8(6) . .
C52 C51 Ag6 130.6(5) . .
Ag9 C51 Ag6 73.46(19) . .
C52 C51 Ag10 92.7(5) . .
Ag9 C51 Ag10 75.37(17) . .
Ag6 C51 Ag10 126.1(3) . .
C52 C51 Ag7 81.7(5) . .
Ag9 C51 Ag7 121.8(3) . .
Ag6 C51 Ag7 67.67(17) . .
Ag10 C51 Ag7 94.4(2) . .
C51 C52 C53 169.8(8) . .
C51 C52 Ag7 72.9(5) . .
C53 C52 Ag7 116.2(5) . .
C52 C53 C55 111.9(7) . .
C52 C53 C54 108.1(6) . .
C55 C53 C54 107.0(8) . .
C52 C53 C56 108.4(7) . .
C55 C53 C56 112.9(8) . .
C54 C53 C56 108.3(8) . .
C62 C61 Ag8 163.1(5) . .
C62 C61 Ag7 105.8(5) . 2_575
Ag8 C61 Ag7 82.7(2) . 2_575
C62 C61 Ag10 114.2(5) . .
Ag8 C61 Ag10 81.7(2) . .
Ag7 C61 Ag10 76.02(18) 2_575 .
C62 C61 Ag9 107.0(5) . .
Ag8 C61 Ag9 73.26(18) . .
Ag7 C61 Ag9 137.9(3) 2_575 .
Ag10 C61 Ag9 66.92(14) . .
C61 C62 C63 177.2(7) . .
C62 C63 C64 109.8(6) . .
C62 C63 C66 108.3(6) . .
C64 C63 C66 110.9(7) . .
C62 C63 C65 108.9(7) . .
C64 C63 C65 110.0(7) . .
C66 C63 C65 108.8(7) . .
N1 C101 C102 123.8(6) . .
N1 C101 P1 114.6(5) . .
C102 C101 P1 121.6(6) . .
C101 C102 C103 116.9(7) . .
C104 C103 C102 118.9(7) . .
C105 C104 C103 118.2(7) . .
N1 C105 C104 125.1(7) . .
C202 C201 C206 119.2(7) . .
C202 C201 P1 124.5(6) . .
C206 C201 P1 116.3(6) . .
C201 C202 C203 121.1(8) . .
C204 C203 C202 118.9(9) . .
C203 C204 C205 122.0(8) . .
C204 C205 C206 119.1(8) . .
C205 C206 C201 119.7(8) . .
C302 C301 C306 120.3(7) . .
C302 C301 P1 123.1(6) . .
C306 C301 P1 116.6(6) . .
C301 C302 C303 121.5(9) . .
C302 C303 C304 119.4(10) . .
C303 C304 C305 120.1(9) . .
C306 C305 C304 120.3(10) . .
C305 C306 C301 118.3(8) . .
N2 C401 C402 122.2(6) . .
N2 C401 P2 114.6(4) . .
C402 C401 P2 123.3(5) . .
C401 C402 C403 118.7(7) . .
C404 C403 C402 118.4(7) . .
C405 C404 C403 118.5(7) . .
N2 C405 C404 123.6(7) . .
C506 C501 C502 117.3(7) . .
C506 C501 P2 124.3(5) . .
C502 C501 P2 118.4(5) . .
C503 C502 C501 119.8(7) . .
C504 C503 C502 120.2(7) . .
C505 C504 C503 120.9(8) . .
C504 C505 C506 121.0(7) . .
C505 C506 C501 120.9(7) . .
C606 C601 C602 118.8(7) . .
C606 C601 P2 124.4(6) . .
C602 C601 P2 116.7(5) . .
C603 C602 C601 120.8(7) . .
C602 C603 C604 119.0(8) . .
C605 C604 C603 120.5(8) . .
C604 C605 C606 120.4(9) . .
C601 C606 C605 120.5(9) . .
C1 O1 Ag1 125.8(4) . .
C1 O2 Ag5 118.4(5) . 2_466
C3 O3 Ag2 126.0(4) . .
C3 O4 Ag3 119.4(4) . .
C5 O5 Ag10 119.9(4) . .
C5 O6 Ag9 124.5(5) . .
C7 O7 Ag7 120.1(5) . .
C7 O8 Ag6 124.5(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O1 2.325(5) .
Ag1 N1 2.342(5) .
Ag1 C11 2.454(6) .
Ag1 C21 2.557(6) .
Ag1 Ag2 2.8471(7) .
Ag1 Ag5 2.8554(8) 2_466
Ag1 Ag4 2.9774(7) .
Ag2 C21 2.245(6) .
Ag2 O3 2.319(5) .
Ag2 P1 2.4098(17) .
Ag2 Ag4 2.9113(7) .
Ag2 Ag3 2.9571(7) .
Ag3 C11 2.321(6) 2_466
Ag3 O4 2.333(5) .
Ag3 C31 2.490(6) .
Ag3 C21 2.508(6) .
Ag3 Ag4 2.8890(7) 2_466
Ag3 Ag5 3.0422(8) .
Ag3 Ag4 3.0875(7) .
Ag4 C11 2.071(7) .
Ag4 C31 2.088(7) .
Ag4 Ag5 2.8601(7) .
Ag4 Ag3 2.8890(7) 2_466
Ag4 Ag5 3.2422(8) 2_466
Ag5 C31 2.305(6) .
Ag5 O2 2.335(5) 2_466
Ag5 C21 2.441(6) 2_466
Ag5 C22 2.624(7) 2_466
Ag5 Ag1 2.8554(8) 2_466
Ag5 Ag4 3.2422(8) 2_466
Ag6 O8 2.340(5) .
Ag6 N2 2.340(5) .
Ag6 C51 2.480(7) .
Ag6 C41 2.607(7) .
Ag6 Ag7 2.8150(8) .
Ag6 Ag9 2.8490(8) .
Ag6 Ag8 3.0241(7) .
Ag7 C61 2.312(6) 2_575
Ag7 O7 2.315(5) .
Ag7 C51 2.573(6) .
Ag7 C41 2.634(7) .
Ag7 C52 2.664(7) .
Ag7 Ag8 2.9101(7) 2_575
Ag7 Ag10 3.0314(8) 2_575
Ag7 Ag8 3.0915(8) .
Ag8 C41 2.083(7) .
Ag8 C61 2.087(7) .
Ag8 Ag10 2.8532(7) 2_575
Ag8 Ag9 2.8971(7) .
Ag8 Ag7 2.9101(7) 2_575
Ag8 Ag10 3.0893(8) .
Ag9 C51 2.276(6) .
Ag9 O6 2.329(5) .
Ag9 P2 2.4260(17) .
Ag9 C61 2.699(6) .
Ag9 Ag10 2.9212(7) .
Ag10 C41 2.337(6) 2_575
Ag10 O5 2.332(5) .
Ag10 C51 2.494(6) .
Ag10 C61 2.597(6) .
Ag10 Ag8 2.8531(7) 2_575
Ag10 Ag7 3.0313(8) 2_575
P1 C301 1.830(7) .
P1 C101 1.841(7) .
P1 C201 1.839(7) .
P2 C501 1.808(7) .
P2 C601 1.807(7) .
P2 C401 1.829(6) .
N1 C101 1.328(9) .
N1 C105 1.329(9) .
N2 C405 1.327(8) .
N2 C401 1.338(9) .
C1 O2 1.232(9) .
C1 O1 1.246(9) .
C1 C2 1.519(10) .
C2 F3 1.304(10) .
C2 F2 1.322(11) .
C2 F1 1.335(11) .
C3 O3 1.201(9) .
C3 O4 1.240(9) .
C3 C4 1.553(9) .
C4 F6 1.298(10) .
C4 F5 1.321(11) .
C4 F4 1.341(10) .
C5 O6 1.199(9) .
C5 O5 1.264(9) .
C5 C6 1.522(10) .
C6 F8 1.238(11) .
C6 F7 1.329(13) .
C6 F9 1.343(11) .
C7 O8 1.209(9) .
C7 O7 1.249(9) .
C7 C8 1.551(10) .
C8 F12 1.283(11) .
C8 F10 1.306(11) .
C8 F11 1.322(12) .
C11 C12 1.212(9) .
C11 Ag3 2.321(6) 2_466
C12 C13 1.486(10) .
C13 C15 1.372(17) .
C13 C14 1.385(15) .
C13 C16 1.58(2) .
C15 C16 2.06(3) .
C21 C22 1.212(10) .
C21 Ag5 2.441(6) 2_466
C22 C23 1.469(11) .
C22 Ag5 2.624(7) 2_466
C23 C25 1.536(13) .
C23 C26 1.549(12) .
C23 C24 1.550(11) .
C31 C32 1.195(9) .
C32 C33 1.526(9) .
C33 C34 1.446(14) .
C33 C35 1.439(16) .
C33 C36 1.609(19) .
C41 C42 1.194(10) .
C41 Ag10 2.337(6) 2_575
C42 C43 1.476(10) .
C43 C46 1.489(16) .
C43 C45 1.553(16) .
C43 C44 1.554(13) .
C51 C52 1.155(10) .
C52 C53 1.503(10) .
C53 C55 1.514(12) .
C53 C54 1.538(12) .
C53 C56 1.552(12) .
C61 C62 1.207(9) .
C61 Ag7 2.312(6) 2_575
C62 C63 1.490(9) .
C63 C64 1.518(11) .
C63 C66 1.537(11) .
C63 C65 1.552(12) .
C101 C102 1.403(9) .
C102 C103 1.411(11) .
C103 C104 1.387(12) .
C104 C105 1.362(10) .
C201 C202 1.343(11) .
C201 C206 1.416(10) .
C202 C203 1.400(12) .
C203 C204 1.354(13) .
C204 C205 1.365(13) .
C205 C206 1.383(12) .
C301 C302 1.359(11) .
C301 C306 1.404(11) .
C302 C303 1.356(11) .
C303 C304 1.369(15) .
C304 C305 1.400(15) .
C305 C306 1.365(12) .
C401 C402 1.396(9) .
C402 C403 1.402(10) .
C403 C404 1.387(12) .
C404 C405 1.382(11) .
C501 C506 1.391(10) .
C501 C502 1.417(9) .
C502 C503 1.401(10) .
C503 C504 1.359(11) .
C504 C505 1.342(11) .
C505 C506 1.382(11) .
C601 C606 1.366(11) .
C601 C602 1.410(10) .
C602 C603 1.358(10) .
C603 C604 1.414(13) .
C604 C605 1.341(14) .
C605 C606 1.392(11) .
O2 Ag5 2.335(5) 2_466
