#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:27:44 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180040 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/34/7033425.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7033425
loop_
_publ_author_name
'Ku, Hsiao-Yun'
'Tong, Bihai'
'Chi, Yun'
'Kao, Hao-Che'
'Yeh, Chia-Chi'
'Chang, Chih-Hao'
'Lee, Gene-Hsiang'
_publ_section_title
;
 Luminescent Pt(ii) complexes bearing dual isoquinolinyl pyrazolates:
 fundamentals and applications.
;
_journal_issue                   18
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8552
_journal_page_last               8563
_journal_paper_doi               10.1039/c4dt03028a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C110 H100 F18 N18 Pt3'
_chemical_formula_weight         2601.35
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-10-02 deposited with the CCDC.
2014-12-16 downloaded from the CCDC.
;
_cell_angle_alpha                94.811(2)
_cell_angle_beta                 99.629(2)
_cell_angle_gamma                94.980(2)
_cell_formula_units_Z            1
_cell_length_a                   11.0996(7)
_cell_length_b                   15.0849(10)
_cell_length_c                   15.1862(10)
_cell_measurement_reflns_used    2282
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      20.35
_cell_measurement_theta_min      2.42
_cell_volume                     2484.9(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'BRUKER SMART APEXCCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0715
_diffrn_reflns_av_sigmaI/netI    0.1130
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            24310
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.36
_exptl_absorpt_coefficient_mu    4.306
_exptl_absorpt_correction_T_max  0.8135
_exptl_absorpt_correction_T_min  0.3582
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2001)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.738
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1282
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.991
_refine_diff_density_min         -2.254
_refine_diff_density_rms         0.327
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     668
_refine_ls_number_reflns         11405
_refine_ls_number_restraints     50
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0934
_refine_ls_R_factor_gt           0.0597
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0577P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1244
_refine_ls_wR_factor_ref         0.1491
_reflns_number_gt                8149
_reflns_number_total             11405
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt03028a2.cif
_cod_data_source_block           ic16315
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not_measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 7033425--7033426.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7033425
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.23308(3) 0.54006(2) 0.06123(2) 0.01971(10) Uani 1 1 d . . .
N1 N 0.1216(6) 0.5183(5) -0.0614(5) 0.0222(16) Uani 1 1 d . . .
N2 N 0.1811(6) 0.4084(5) 0.0548(5) 0.0236(16) Uani 1 1 d . . .
N3 N 0.2066(7) 0.3496(5) 0.1133(5) 0.0249(17) Uani 1 1 d . . .
N4 N 0.3479(6) 0.5613(5) 0.1819(5) 0.0214(16) Uani 1 1 d . . .
N5 N 0.2746(6) 0.6733(5) 0.0723(5) 0.0217(16) Uani 1 1 d . . .
N6 N 0.2368(6) 0.7345(5) 0.0175(5) 0.0252(17) Uani 1 1 d . . .
C1 C 0.1055(7) 0.5835(6) -0.1175(6) 0.025(2) Uani 1 1 d . . .
H1 H 0.1408 0.6429 -0.0973 0.030 Uiso 1 1 calc R . .
C2 C 0.0409(8) 0.5656(6) -0.2008(6) 0.031(2) Uani 1 1 d . . .
H2 H 0.0304 0.6126 -0.2384 0.037 Uiso 1 1 calc R . .
C3 C -0.0118(8) 0.4781(6) -0.2339(6) 0.030(2) Uani 1 1 d . . .
C4 C -0.0703(8) 0.4556(6) -0.3235(6) 0.029(2) Uani 1 1 d . . .
H4 H -0.0758 0.5011 -0.3631 0.034 Uiso 1 1 calc R . .
C5 C -0.1198(8) 0.3697(7) -0.3559(6) 0.030(2) Uani 1 1 d . A .
C6 C -0.1149(8) 0.3064(7) -0.2927(7) 0.037(2) Uani 1 1 d . . .
H6 H -0.1533 0.2477 -0.3122 0.044 Uiso 1 1 calc R . .
C7 C -0.0594(8) 0.3236(6) -0.2067(7) 0.029(2) Uani 1 1 d . . .
H7 H -0.0589 0.2782 -0.1670 0.035 Uiso 1 1 calc R . .
C8 C -0.0011(7) 0.4115(6) -0.1759(6) 0.0208(18) Uani 1 1 d U . .
C9 C 0.0725(7) 0.4335(6) -0.0837(6) 0.0216(18) Uani 1 1 d U . .
C10 C 0.1016(8) 0.3725(6) -0.0200(6) 0.0223(19) Uani 1 1 d . . .
C11 C 0.0727(8) 0.2834(7) -0.0077(7) 0.031(2) Uani 1 1 d . . .
H11 H 0.0187 0.2395 -0.0472 0.037 Uiso 1 1 calc R . .
C12 C 0.1396(8) 0.2733(6) 0.0744(6) 0.028(2) Uani 1 1 d . . .
C13 C 0.1431(11) 0.1921(7) 0.1233(8) 0.043(3) Uani 1 1 d . . .
C14 C -0.1715(9) 0.3443(7) -0.4554(7) 0.035(2) Uani 1 1 d . . .
C15 C -0.0693(19) 0.3342(16) -0.5008(14) 0.062(5) Uani 0.642(7) 1 d PU A 1
H15A H -0.0171 0.2922 -0.4715 0.093 Uiso 0.642(7) 1 calc PR A 1
H15B H -0.0215 0.3924 -0.4982 0.093 Uiso 0.642(7) 1 calc PR A 1
H15C H -0.0996 0.3112 -0.5636 0.093 Uiso 0.642(7) 1 calc PR A 1
C16 C -0.2550(15) 0.4120(11) -0.4905(10) 0.042(4) Uani 0.642(7) 1 d PU A 1
H16A H -0.3227 0.4140 -0.4567 0.062 Uiso 0.642(7) 1 calc PR A 1
H16B H -0.2882 0.3949 -0.5542 0.062 Uiso 0.642(7) 1 calc PR A 1
H16C H -0.2083 0.4711 -0.4834 0.062 Uiso 0.642(7) 1 calc PR A 1
C17 C -0.249(2) 0.2487(15) -0.4736(16) 0.065(6) Uani 0.642(7) 1 d PU A 1
H17A H -0.3132 0.2469 -0.4362 0.098 Uiso 0.642(7) 1 calc PR A 1
H17B H -0.1949 0.2023 -0.4588 0.098 Uiso 0.642(7) 1 calc PR A 1
H17C H -0.2878 0.2381 -0.5371 0.098 Uiso 0.642(7) 1 calc PR A 1
C15' C -0.089(4) 0.274(3) -0.495(3) 0.062(5) Uani 0.358(7) 1 d P A 2
H15D H -0.0578 0.2369 -0.4483 0.093 Uiso 0.358(7) 1 calc PR A 2
H15E H -0.0195 0.3069 -0.5148 0.093 Uiso 0.358(7) 1 calc PR A 2
H15F H -0.1386 0.2366 -0.5461 0.093 Uiso 0.358(7) 1 calc PR A 2
C16' C -0.135(3) 0.421(2) -0.5191(18) 0.042(4) Uani 0.358(7) 1 d P A 2
H16D H -0.0462 0.4371 -0.5062 0.062 Uiso 0.358(7) 1 calc PR A 2
H16E H -0.1775 0.4737 -0.5071 0.062 Uiso 0.358(7) 1 calc PR A 2
H16F H -0.1602 0.3973 -0.5823 0.062 Uiso 0.358(7) 1 calc PR A 2
C17' C -0.294(4) 0.288(3) -0.468(3) 0.065(6) Uani 0.358(7) 1 d P A 2
H17D H -0.2982 0.2559 -0.4153 0.098 Uiso 0.358(7) 1 calc PR A 2
H17E H -0.3026 0.2456 -0.5216 0.098 Uiso 0.358(7) 1 calc PR A 2
H17F H -0.3602 0.3274 -0.4756 0.098 Uiso 0.358(7) 1 calc PR A 2
C18 C 0.3874(8) 0.4955(6) 0.2312(6) 0.025(2) Uani 1 1 d . . .
H18 H 0.3570 0.4354 0.2098 0.030 Uiso 1 1 calc R . .
C19 C 0.4681(8) 0.5110(6) 0.3094(6) 0.029(2) Uani 1 1 d . . .
H19 H 0.4959 0.4621 0.3398 0.035 Uiso 1 1 calc R . .
C20 C 0.5116(7) 0.5998(6) 0.3466(6) 0.0212(18) Uani 1 1 d . . .
C21 C 0.5872(8) 0.6202(6) 0.4302(6) 0.027(2) Uani 1 1 d . . .
H21 H 0.6137 0.5728 0.4635 0.033 Uiso 1 1 calc R . .
C22 C 0.6245(8) 0.7071(6) 0.4659(6) 0.028(2) Uani 1 1 d . . .
C23 C 0.5863(9) 0.7766(6) 0.4148(7) 0.034(2) Uani 1 1 d . . .
H23 H 0.6127 0.8371 0.4374 0.041 Uiso 1 1 calc R . .
C24 C 0.5127(9) 0.7579(6) 0.3345(7) 0.036(2) Uani 1 1 d . . .
H24 H 0.4880 0.8066 0.3025 0.043 Uiso 1 1 calc R . .
C25 C 0.4695(8) 0.6701(6) 0.2942(6) 0.026(2) Uani 1 1 d . . .
C26 C 0.3941(8) 0.6493(6) 0.2147(6) 0.025(2) Uani 1 1 d . . .
C27 C 0.3484(8) 0.7097(6) 0.1492(6) 0.0236(19) Uani 1 1 d . . .
C28 C 0.3624(8) 0.8012(6) 0.1434(6) 0.027(2) Uani 1 1 d . . .
H28 H 0.4096 0.8460 0.1860 0.033 Uiso 1 1 calc R . .
C29 C 0.2923(9) 0.8123(6) 0.0622(7) 0.033(2) Uani 1 1 d . A .
C30 C 0.2711(10) 0.8975(7) 0.0222(7) 0.039(3) Uani 1 1 d . . .
C31 C 0.6991(9) 0.7310(7) 0.5608(7) 0.034(2) Uani 1 1 d . . .
C32 C 0.6074(10) 0.7565(8) 0.6207(7) 0.048(3) Uani 1 1 d . . .
H32A H 0.5641 0.8058 0.5971 0.072 Uiso 1 1 calc R . .
H32B H 0.6513 0.7754 0.6818 0.072 Uiso 1 1 calc R . .
H32C H 0.5479 0.7048 0.6216 0.072 Uiso 1 1 calc R . .
C33 C 0.7645(9) 0.6530(6) 0.5980(7) 0.038(3) Uani 1 1 d . . .
H33A H 0.8112 0.6724 0.6582 0.058 Uiso 1 1 calc R . .
H33B H 0.8205 0.6339 0.5583 0.058 Uiso 1 1 calc R . .
H33C H 0.7034 0.6030 0.6012 0.058 Uiso 1 1 calc R . .
C34 C 0.7963(9) 0.8102(7) 0.5635(8) 0.045(3) Uani 1 1 d . . .
H34A H 0.7559 0.8626 0.5453 0.068 Uiso 1 1 calc R . .
H34B H 0.8523 0.7950 0.5223 0.068 Uiso 1 1 calc R . .
H34C H 0.8429 0.8236 0.6246 0.068 Uiso 1 1 calc R . .
F1 F 0.2550(6) 0.1707(4) 0.1517(5) 0.061(2) Uani 1 1 d . . .
F2 F 0.0907(7) 0.1999(4) 0.1965(5) 0.0599(19) Uani 1 1 d . . .
F3 F 0.0830(7) 0.1208(4) 0.0713(4) 0.061(2) Uani 1 1 d . . .
F4 F 0.1771(13) 0.9333(8) 0.0454(10) 0.073(3) Uani 0.642(7) 1 d PU A 1
F5 F 0.2410(14) 0.8868(8) -0.0660(8) 0.073(3) Uani 0.642(7) 1 d PU A 1
F6 F 0.3696(12) 0.9552(8) 0.0426(11) 0.081(4) Uani 0.642(7) 1 d PU A 1
F4' F 0.299(3) 0.9688(14) 0.0842(16) 0.073(3) Uani 0.358(7) 1 d P A 2
F5' F 0.154(2) 0.9060(14) -0.0174(17) 0.073(3) Uani 0.358(7) 1 d P A 2
F6' F 0.334(2) 0.9152(15) -0.042(2) 0.081(4) Uani 0.358(7) 1 d P A 2
Pt2 Pt 0.5000 0.5000 0.0000 0.01960(12) Uani 1 2 d S . .
N7 N 0.6044(6) 0.5974(4) 0.0880(5) 0.0183(15) Uani 1 1 d . . .
N8 N 0.4720(6) 0.6098(5) -0.0634(5) 0.0211(16) Uani 1 1 d . . .
N9 N 0.3991(7) 0.6201(5) -0.1403(5) 0.0264(17) Uani 1 1 d . . .
C35 C 0.6708(7) 0.5805(6) 0.1672(6) 0.0211(19) Uani 1 1 d . . .
H35 H 0.6691 0.5208 0.1829 0.025 Uiso 1 1 calc R . .
C36 C 0.7392(8) 0.6467(6) 0.2243(6) 0.024(2) Uani 1 1 d . . .
H36 H 0.7806 0.6330 0.2807 0.029 Uiso 1 1 calc R . .
C37 C 0.7505(8) 0.7341(6) 0.2024(6) 0.0217(18) Uani 1 1 d . . .
C38 C 0.8257(8) 0.8052(6) 0.2574(6) 0.027(2) Uani 1 1 d . . .
H38 H 0.8661 0.7936 0.3150 0.032 Uiso 1 1 calc R . .
C39 C 0.8432(8) 0.8886(6) 0.2324(6) 0.030(2) Uani 1 1 d . . .
C40 C 0.7761(10) 0.9058(7) 0.1479(7) 0.047(3) Uani 1 1 d . . .
H40 H 0.7853 0.9641 0.1290 0.056 Uiso 1 1 calc R . .
C41 C 0.6994(9) 0.8409(6) 0.0938(7) 0.039(3) Uani 1 1 d . . .
H41 H 0.6559 0.8549 0.0381 0.047 Uiso 1 1 calc R . .
C42 C 0.6830(7) 0.7523(6) 0.1189(6) 0.025(2) Uani 1 1 d . . .
C43 C 0.6081(7) 0.6823(6) 0.0633(6) 0.0218(19) Uani 1 1 d . . .
C44 C 0.5324(8) 0.6891(6) -0.0212(6) 0.026(2) Uani 1 1 d . . .
C45 C 0.4939(8) 0.7539(6) -0.0769(6) 0.027(2) Uani 1 1 d . . .
H45 H 0.5182 0.8164 -0.0676 0.032 Uiso 1 1 calc R . .
C46 C 0.4142(8) 0.7087(6) -0.1474(6) 0.0247(19) Uani 1 1 d . . .
C47 C 0.3425(9) 0.7443(6) -0.2246(7) 0.033(2) Uani 1 1 d . . .
C48 C 0.9343(9) 0.9632(6) 0.2861(7) 0.035(2) Uani 1 1 d . . .
C49 C 0.8774(11) 1.0504(8) 0.2927(10) 0.065(4) Uani 1 1 d . . .
H49A H 0.8451 1.0653 0.2323 0.097 Uiso 1 1 calc R . .
H49B H 0.9400 1.0980 0.3230 0.097 Uiso 1 1 calc R . .
H49C H 0.8104 1.0444 0.3271 0.097 Uiso 1 1 calc R . .
C50 C 0.9822(11) 0.9409(8) 0.3807(7) 0.057(3) Uani 1 1 d . . .
H50A H 1.0421 0.9896 0.4120 0.085 Uiso 1 1 calc R . .
H50B H 1.0216 0.8853 0.3776 0.085 Uiso 1 1 calc R . .
H50C H 0.9136 0.9333 0.4135 0.085 Uiso 1 1 calc R . .
C51 C 1.0418(10) 0.9755(8) 0.2359(8) 0.058(4) Uani 1 1 d . . .
H51A H 1.0147 1.0012 0.1797 0.087 Uiso 1 1 calc R . .
H51B H 1.0715 0.9174 0.2227 0.087 Uiso 1 1 calc R . .
H51C H 1.1083 1.0159 0.2733 0.087 Uiso 1 1 calc R . .
F7 F 0.3859(6) 0.8272(4) -0.2341(5) 0.061(2) Uani 1 1 d . . .
F8 F 0.2247(5) 0.7488(5) -0.2189(5) 0.0552(18) Uani 1 1 d . . .
F9 F 0.3423(7) 0.6963(5) -0.3021(4) 0.068(2) Uani 1 1 d . . .
C52 C 0.5291(7) 0.9980(5) 0.5926(4) 0.150 Uiso 0.50 1 d PRD B -1
C53 C 0.4117(7) 0.9675(5) 0.5469(4) 0.150 Uiso 0.50 1 d PR B -1
H53A H 0.3510 0.9447 0.5788 0.180 Uiso 0.50 1 calc PR B -1
C54 C 0.3829(7) 0.9706(5) 0.4546(4) 0.150 Uiso 0.50 1 d PR B -1
H54A H 0.3026 0.9498 0.4234 0.180 Uiso 0.50 1 calc PR B -1
C55 C 0.4716(7) 1.0040(5) 0.4080(4) 0.150 Uiso 0.50 1 d PRD B -1
C56 C 0.5891(7) 1.0345(5) 0.4537(4) 0.150 Uiso 0.50 1 d PR B -1
H56A H 0.6497 1.0573 0.4219 0.180 Uiso 0.50 1 calc PR B -1
C57 C 0.6178(7) 1.0314(5) 0.5460(4) 0.150 Uiso 0.50 1 d PR B -1
H57A H 0.6981 1.0522 0.5772 0.180 Uiso 0.50 1 calc PR B -1
C58 C 0.5344(7) 0.9882(5) 0.6890(4) 0.200 Uiso 0.50 1 d PRD B -1
H58A H 0.4544 0.9619 0.6988 0.300 Uiso 0.50 1 calc PR B -1
H58B H 0.5546 1.0471 0.7234 0.300 Uiso 0.50 1 calc PR B -1
H58C H 0.5976 0.9492 0.7089 0.300 Uiso 0.50 1 calc PR B -1
C59 C 0.4664(7) 1.0138(5) 0.3116(4) 0.200 Uiso 0.50 1 d PRD B -1
H59A H 0.5463 1.0401 0.3018 0.300 Uiso 0.50 1 calc PR B -1
H59B H 0.4032 1.0528 0.2918 0.300 Uiso 0.50 1 calc PR B -1
H59C H 0.4461 0.9549 0.2772 0.300 Uiso 0.50 1 calc PR B -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N5 Pt1 N2 175.8(3) . .
N5 Pt1 N4 78.5(3) . .
N2 Pt1 N4 101.4(3) . .
N5 Pt1 N1 101.5(3) . .
N2 Pt1 N1 78.7(3) . .
N4 Pt1 N1 178.6(3) . .
C9 N1 C1 123.3(8) . .
C9 N1 Pt1 114.2(6) . .
C1 N1 Pt1 122.4(6) . .
N3 N2 C10 112.7(7) . .
N3 N2 Pt1 131.1(6) . .
C10 N2 Pt1 116.1(6) . .
N2 N3 C12 104.2(7) . .
C18 N4 C26 117.3(7) . .
C18 N4 Pt1 124.3(6) . .
C26 N4 Pt1 118.4(6) . .
N6 N5 C27 113.1(7) . .
N6 N5 Pt1 130.8(6) . .
C27 N5 Pt1 116.0(6) . .
N5 N6 C29 103.3(7) . .
C2 C1 N1 121.2(8) . .
C1 C2 C3 121.3(9) . .
C8 C3 C4 119.2(9) . .
C8 C3 C2 118.2(9) . .
C4 C3 C2 122.6(9) . .
C5 C4 C3 122.4(9) . .
C4 C5 C6 116.0(9) . .
C4 C5 C14 121.7(9) . .
C6 C5 C14 122.2(9) . .
C7 C6 C5 124.2(9) . .
C6 C7 C8 118.9(9) . .
C3 C8 C7 119.0(8) . .
C3 C8 C9 119.1(8) . .
C7 C8 C9 121.9(8) . .
N1 C9 C10 116.8(7) . .
N1 C9 C8 116.9(8) . .
C10 C9 C8 126.2(8) . .
N2 C10 C11 106.2(8) . .
N2 C10 C9 114.1(7) . .
C11 C10 C9 139.7(9) . .
C12 C11 C10 104.3(8) . .
N3 C12 C11 112.6(9) . .
N3 C12 C13 119.2(9) . .
C11 C12 C13 128.2(9) . .
F1 C13 F3 106.3(9) . .
F1 C13 F2 105.5(9) . .
F3 C13 F2 106.5(9) . .
F1 C13 C12 114.2(9) . .
F3 C13 C12 111.1(9) . .
F2 C13 C12 112.7(9) . .
C15 C14 C16 114.7(13) . .
C15 C14 C5 107.4(11) . .
C16 C14 C5 110.1(9) . .
C15 C14 C17' 130(2) . .
C16 C14 C17' 80.4(18) . .
C5 C14 C17' 111.1(18) . .
C15 C14 C15' 34.9(15) . .
C16 C14 C15' 137.5(17) . .
C5 C14 C15' 108.7(16) . .
C17' C14 C15' 101(2) . .
C15 C14 C17 104.6(14) . .
C16 C14 C17 107.6(12) . .
C5 C14 C17 112.4(11) . .
C17' C14 C17 30.4(16) . .
C15' C14 C17 72.0(17) . .
C15 C14 C16' 61.3(14) . .
C16 C14 C16' 55.4(12) . .
C5 C14 C16' 113.2(12) . .
C17' C14 C16' 125(2) . .
C15' C14 C16' 93.5(19) . .
C17 C14 C16' 134.4(15) . .
C19 C18 N4 123.2(8) . .
C18 C19 C20 120.6(8) . .
C21 C20 C19 123.2(8) . .
C21 C20 C25 120.6(8) . .
C19 C20 C25 116.2(8) . .
C22 C21 C20 121.9(9) . .
C21 C22 C23 118.3(9) . .
C21 C22 C31 122.6(9) . .
C23 C22 C31 119.0(8) . .
C24 C23 C22 120.4(9) . .
C23 C24 C25 124.3(9) . .
C26 C25 C24 125.7(9) . .
C26 C25 C20 119.8(8) . .
C24 C25 C20 114.5(8) . .
C25 C26 N4 122.7(8) . .
C25 C26 C27 128.2(8) . .
N4 C26 C27 109.1(8) . .
N5 C27 C28 106.3(8) . .
N5 C27 C26 117.9(8) . .
C28 C27 C26 135.8(9) . .
C29 C28 C27 104.4(8) . .
N6 C29 C28 112.9(8) . .
N6 C29 C30 119.4(9) . .
C28 C29 C30 127.7(9) . .
F4 C30 F6' 130.2(14) . .
F4 C30 F6 110.0(12) . .
F6' C30 F6 61.7(13) . .
F4 C30 F5 102.1(11) . .
F6' C30 F5 48.0(11) . .
F6 C30 F5 107.3(12) . .
F4 C30 F4' 64.9(12) . .
F6' C30 F4' 105.6(17) . .
F6 C30 F4' 49.3(11) . .
F5 C30 F4' 134.7(13) . .
F4 C30 F5' 43.6(11) . .
F6' C30 F5' 102.3(17) . .
F6 C30 F5' 131.9(13) . .
F5 C30 F5' 60.4(12) . .
F4' C30 F5' 103.7(16) . .
F4 C30 C29 112.8(11) . .
F6' C30 C29 115.6(13) . .
F6 C30 C29 111.1(10) . .
F5 C30 C29 113.0(10) . .
F4' C30 C29 111.9(12) . .
F5' C30 C29 116.4(13) . .
C32 C31 C34 109.5(9) . .
C32 C31 C22 106.3(8) . .
C34 C31 C22 111.2(8) . .
C32 C31 C33 108.7(9) . .
C34 C31 C33 107.9(8) . .
C22 C31 C33 113.2(8) . .
N8 Pt2 N8 179.999(1) . 2_665
N8 Pt2 N7 102.0(3) . 2_665
N8 Pt2 N7 78.0(3) 2_665 2_665
N8 Pt2 N7 78.0(3) . .
N8 Pt2 N7 102.0(3) 2_665 .
N7 Pt2 N7 180.0(3) 2_665 .
C35 N7 C43 120.0(7) . .
C35 N7 Pt2 122.9(6) . .
C43 N7 Pt2 117.0(6) . .
N9 N8 C44 112.6(7) . .
N9 N8 Pt2 130.5(6) . .
C44 N8 Pt2 116.8(6) . .
N8 N9 C46 104.2(7) . .
C36 C35 N7 121.5(8) . .
C35 C36 C37 121.6(9) . .
C36 C37 C38 124.1(8) . .
C36 C37 C42 117.3(8) . .
C38 C37 C42 118.6(8) . .
C39 C38 C37 123.5(9) . .
C38 C39 C40 117.3(8) . .
C38 C39 C48 124.2(9) . .
C40 C39 C48 118.4(8) . .
C41 C40 C39 121.6(9) . .
C40 C41 C42 121.3(9) . .
C43 C42 C37 119.3(8) . .
C43 C42 C41 123.0(9) . .
C37 C42 C41 117.6(8) . .
N7 C43 C42 120.1(8) . .
N7 C43 C44 113.2(8) . .
C42 C43 C44 126.7(8) . .
N8 C44 C45 105.2(8) . .
N8 C44 C43 114.9(8) . .
C45 C44 C43 139.9(9) . .
C46 C45 C44 105.5(8) . .
N9 C46 C45 112.6(8) . .
N9 C46 C47 118.6(8) . .
C45 C46 C47 128.8(8) . .
F7 C47 F9 106.4(9) . .
F7 C47 F8 105.2(8) . .
F9 C47 F8 105.6(8) . .
F7 C47 C46 111.8(8) . .
F9 C47 C46 113.1(8) . .
F8 C47 C46 114.0(8) . .
C49 C48 C50 108.4(10) . .
C49 C48 C39 111.4(9) . .
C50 C48 C39 112.3(8) . .
C49 C48 C51 108.4(9) . .
C50 C48 C51 109.1(9) . .
C39 C48 C51 107.2(9) . .
C53 C52 C57 120.0 . .
C53 C52 C58 108.9 . .
C57 C52 C58 131.1 . .
C52 C53 C54 120.0 . .
C55 C54 C53 120.0 . .
C54 C55 C56 120.0 . .
C54 C55 C59 131.1 . .
C56 C55 C59 108.9 . .
C57 C56 C55 120.0 . .
C56 C57 C52 120.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N5 2.009(7) .
Pt1 N2 2.010(7) .
Pt1 N4 2.033(7) .
Pt1 N1 2.041(7) .
N1 C9 1.339(11) .
N1 C1 1.358(11) .
N2 N3 1.322(10) .
N2 C10 1.357(11) .
N3 C12 1.348(11) .
N4 C18 1.353(11) .
N4 C26 1.399(11) .
N5 N6 1.341(10) .
N5 C27 1.354(11) .
N6 C29 1.348(11) .
C1 C2 1.339(12) .
C2 C3 1.411(12) .
C3 C8 1.391(12) .
C3 C4 1.406(12) .
C4 C5 1.379(12) .
C5 C6 1.408(14) .
C5 C14 1.528(13) .
C6 C7 1.341(13) .
C7 C8 1.428(12) .
C8 C9 1.493(11) .
C9 C10 1.408(12) .
C10 C11 1.390(12) .
C11 C12 1.368(13) .
C12 C13 1.485(14) .
C13 F1 1.322(13) .
C13 F3 1.334(12) .
C13 F2 1.339(12) .
C14 C15 1.43(2) .
C14 C16 1.509(17) .
C14 C17' 1.51(4) .
C14 C15' 1.60(4) .
C14 C17 1.59(2) .
C14 C16' 1.63(3) .
C18 C19 1.352(12) .
C19 C20 1.419(12) .
C20 C21 1.394(12) .
C20 C25 1.441(12) .
C21 C22 1.377(12) .
C22 C23 1.408(13) .
C22 C31 1.534(13) .
C23 C24 1.344(13) .
C24 C25 1.419(12) .
C25 C26 1.344(13) .
C26 C27 1.462(12) .
C27 C28 1.387(12) .
C28 C29 1.376(13) .
C29 C30 1.487(13) .
C30 F4 1.301(15) .
C30 F6' 1.32(3) .
C30 F6 1.314(15) .
C30 F5 1.319(15) .
C30 F4' 1.35(3) .
C30 F5' 1.36(3) .
C31 C32 1.526(14) .
C31 C34 1.532(13) .
C31 C33 1.533(13) .
Pt2 N8 2.005(7) .
Pt2 N8 2.005(7) 2_665
Pt2 N7 2.035(7) 2_665
Pt2 N7 2.035(7) .
N7 C35 1.357(11) .
N7 C43 1.364(10) .
N8 N9 1.334(10) .
N8 C44 1.372(11) .
N9 C46 1.349(11) .
C35 C36 1.352(12) .
C36 C37 1.387(12) .
C37 C38 1.416(11) .
C37 C42 1.422(12) .
C38 C39 1.351(12) .
C39 C40 1.429(13) .
C39 C48 1.525(12) .
C40 C41 1.358(13) .
C41 C42 1.426(12) .
C42 C43 1.407(12) .
C43 C44 1.428(12) .
C44 C45 1.394(12) .
C45 C46 1.360(12) .
C46 C47 1.472(13) .
C47 F7 1.328(10) .
C47 F9 1.328(12) .
C47 F8 1.332(11) .
C48 C49 1.511(15) .
C48 C50 1.522(14) .
C48 C51 1.526(15) .
C52 C53 1.3900 .
C52 C57 1.3901 .
C52 C58 1.4758 .
C53 C54 1.3901 .
C54 C55 1.3899 .
C55 C56 1.3900 .
C55 C59 1.4756 .
C56 C57 1.3899 .
