#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:32:07 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180043 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/37/7033792.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7033792
loop_
_publ_author_name
'Sgro, Michael J.'
'Piers, Warren E.'
'Romero, Patricio E.'
_publ_section_title
;
 Synthesis, structural characterization and thermal properties of copper
 and silver silyl complexes.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3817
_journal_page_last               3828
_journal_paper_doi               10.1039/c4dt03770g
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C20 H47 Cu N2 Si4'
_chemical_formula_weight         491.50
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-12-04 deposited with the CCDC.
2015-01-12 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 118.196(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.7847(4)
_cell_length_b                   16.8005(7)
_cell_length_c                   20.3185(8)
_cell_measurement_reflns_used    9951
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      67.29
_cell_measurement_theta_min      3.61
_cell_volume                     2943.8(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0219
_diffrn_reflns_av_sigmaI/netI    0.0164
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            24130
_diffrn_reflns_theta_full        67.83
_diffrn_reflns_theta_max         67.83
_diffrn_reflns_theta_min         3.61
_exptl_absorpt_coefficient_mu    2.653
_exptl_absorpt_correction_T_max  0.7773
_exptl_absorpt_correction_T_min  0.6762
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.109
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1064
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.436
_refine_diff_density_min         -0.147
_refine_diff_density_rms         0.047
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     259
_refine_ls_number_reflns         5299
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0345
_refine_ls_R_factor_gt           0.0301
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0533P)²+0.5129P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0805
_refine_ls_wR_factor_ref         0.0839
_reflns_number_gt                4724
_reflns_number_total             5299
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt03770g2.cif
_cod_data_source_block           compound3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 7033789--7033802.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7033792
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.98018(3) 0.891363(14) 0.842350(13) 0.03600(9) Uani 1 1 d .
Si1 Si 0.95824(5) 0.98174(2) 0.75526(2) 0.03031(11) Uani 1 1 d .
Si3 Si 0.73196(5) 0.97132(3) 0.64147(2) 0.03675(12) Uani 1 1 d .
Si4 Si 1.16168(5) 0.97927(3) 0.72501(3) 0.03529(12) Uani 1 1 d .
Si2 Si 0.95425(6) 1.11027(3) 0.79870(3) 0.03960(12) Uani 1 1 d .
N1 N 1.13925(15) 0.78908(8) 0.97661(8) 0.0360(3) Uani 1 1 d .
N2 N 0.89298(15) 0.77033(8) 0.92243(8) 0.0343(3) Uani 1 1 d .
C15 C 0.5559(2) 0.95469(16) 0.65459(13) 0.0611(6) Uani 1 1 d .
H15A H 0.4644 0.9553 0.6068 0.092 Uiso 1 1 calc R
H15B H 0.5492 0.9962 0.6854 0.092 Uiso 1 1 calc R
H15C H 0.5643 0.9041 0.6782 0.092 Uiso 1 1 calc R
C16 C 0.7462(3) 0.88425(15) 0.58713(13) 0.0678(7) Uani 1 1 d .
H16A H 0.6521 0.8799 0.5407 0.102 Uiso 1 1 calc R
H16B H 0.7616 0.8364 0.6156 0.102 Uiso 1 1 calc R
H16C H 0.8321 0.8919 0.5773 0.102 Uiso 1 1 calc R
C17 C 0.6900(3) 1.06241(14) 0.58112(12) 0.0639(6) Uani 1 1 d .
H17A H 0.7767 1.0734 0.5727 0.096 Uiso 1 1 calc R
H17B H 0.6726 1.1070 0.6057 0.096 Uiso 1 1 calc R
H17C H 0.5992 1.0533 0.5342 0.096 Uiso 1 1 calc R
C18 C 1.2142(2) 0.87475(11) 0.71200(12) 0.0482(4) Uani 1 1 d .
H18A H 1.2994 0.8762 0.7010 0.072 Uiso 1 1 calc R
H18B H 1.1265 0.8499 0.6714 0.072 Uiso 1 1 calc R
H18C H 1.2435 0.8448 0.7570 0.072 Uiso 1 1 calc R
C20 C 1.1209(3) 1.03336(14) 0.63642(13) 0.0593(5) Uani 1 1 d .
H20A H 1.0905 1.0871 0.6390 0.089 Uiso 1 1 calc R
H20B H 1.0387 1.0068 0.5946 0.089 Uiso 1 1 calc R
H20C H 1.2126 1.0337 0.6305 0.089 Uiso 1 1 calc R
C19 C 1.3415(2) 1.02463(13) 0.80233(13) 0.0569(5) Uani 1 1 d .
H19A H 1.4246 1.0215 0.7899 0.085 Uiso 1 1 calc R
H19B H 1.3696 0.9962 0.8479 0.085 Uiso 1 1 calc R
H19C H 1.3220 1.0794 0.8086 0.085 Uiso 1 1 calc R
C12 C 1.1017(3) 1.12018(15) 0.90001(14) 0.0820(8) Uani 1 1 d .
H12A H 1.2008 1.1022 0.9070 0.123 Uiso 1 1 calc R
H12B H 1.0704 1.0884 0.9299 0.123 Uiso 1 1 calc R
H12C H 1.1092 1.1749 0.9148 0.123 Uiso 1 1 calc R
C13 C 0.7601(3) 1.13226(14) 0.79251(15) 0.0669(6) Uani 1 1 d .
H13A H 0.7634 1.1833 0.8145 0.100 Uiso 1 1 calc R
H13B H 0.7357 1.0920 0.8188 0.100 Uiso 1 1 calc R
H13C H 0.6820 1.1328 0.7411 0.100 Uiso 1 1 calc R
C14 C 0.9951(3) 1.19149(12) 0.74723(15) 0.0681(6) Uani 1 1 d .
H14A H 0.9928 1.2420 0.7687 0.102 Uiso 1 1 calc R
H14B H 0.9178 1.1907 0.6956 0.102 Uiso 1 1 calc R
H14C H 1.0956 1.1834 0.7510 0.102 Uiso 1 1 calc R
C1 C 1.00427(18) 0.81471(9) 0.91828(9) 0.0334(3) Uani 1 1 d .
C4 C 1.29424(19) 0.82523(11) 0.99707(10) 0.0426(4) Uani 1 1 d .
C6 C 1.2892(3) 0.91305(13) 1.01382(13) 0.0613(6) Uani 1 1 d .
H6A H 1.2135 0.9395 0.9697 0.092 Uiso 1 1 calc R
H6B H 1.3893 0.9364 1.0292 0.092 Uiso 1 1 calc R
H6C H 1.2615 0.9187 1.0531 0.092 Uiso 1 1 calc R
C5 C 1.3277(2) 0.81479(15) 0.93181(13) 0.0601(6) Uani 1 1 d .
H5A H 1.3263 0.7592 0.9207 0.090 Uiso 1 1 calc R
H5B H 1.4280 0.8365 0.9446 0.090 Uiso 1 1 calc R
H5C H 1.2501 0.8421 0.8889 0.090 Uiso 1 1 calc R
C7 C 1.4182(2) 0.78314(16) 1.06614(14) 0.0698(7) Uani 1 1 d .
H7A H 1.3961 0.7902 1.1071 0.105 Uiso 1 1 calc R
H7B H 1.5180 0.8054 1.0790 0.105 Uiso 1 1 calc R
H7C H 1.4182 0.7274 1.0558 0.105 Uiso 1 1 calc R
C2 C 1.1112(2) 0.72964(11) 1.01511(10) 0.0447(4) Uani 1 1 d .
H2 H 1.1850 0.7028 1.0568 0.054 Uiso 1 1 calc R
C3 C 0.9576(2) 0.71762(11) 0.98124(11) 0.0447(4) Uani 1 1 d .
H3 H 0.9047 0.6807 0.9949 0.054 Uiso 1 1 calc R
C8 C 0.72260(19) 0.78102(10) 0.87163(10) 0.0388(4) Uani 1 1 d .
C10 C 0.6317(2) 0.72553(13) 0.89575(13) 0.0565(5) Uani 1 1 d .
H10A H 0.6599 0.6714 0.8929 0.085 Uiso 1 1 calc R
H10B H 0.5227 0.7326 0.8634 0.085 Uiso 1 1 calc R
H10C H 0.6552 0.7376 0.9462 0.085 Uiso 1 1 calc R
C9 C 0.6867(2) 0.76166(13) 0.79181(11) 0.0518(5) Uani 1 1 d .
H9A H 0.7479 0.7951 0.7776 0.078 Uiso 1 1 calc R
H9B H 0.5786 0.7708 0.7588 0.078 Uiso 1 1 calc R
H9C H 0.7110 0.7069 0.7888 0.078 Uiso 1 1 calc R
C11 C 0.6802(2) 0.86727(12) 0.87772(12) 0.0495(5) Uani 1 1 d .
H11A H 0.7085 0.8791 0.9288 0.074 Uiso 1 1 calc R
H11B H 0.5705 0.8746 0.8473 0.074 Uiso 1 1 calc R
H11C H 0.7348 0.9023 0.8609 0.074 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1 Cu1 Si1 178.60(5)
Cu1 Si1 Si3 114.80(2)
Cu1 Si1 Si2 109.66(2)
Si3 Si1 Si2 105.42(2)
Cu1 Si1 Si4 114.48(2)
Si3 Si1 Si4 105.35(2)
Si2 Si1 Si4 106.42(2)
C16 Si3 C17 107.73(12)
C16 Si3 C15 107.13(12)
C17 Si3 C15 106.28(11)
C16 Si3 Si1 110.00(7)
C17 Si3 Si1 113.44(7)
C15 Si3 Si1 111.96(7)
C19 Si4 C18 106.60(9)
C19 Si4 C20 107.18(11)
C18 Si4 C20 105.34(10)
C19 Si4 Si1 110.43(7)
C18 Si4 Si1 112.03(6)
C20 Si4 Si1 114.78(7)
C14 Si2 C13 107.15(11)
C14 Si2 C12 106.90(13)
C13 Si2 C12 106.50(13)
C14 Si2 Si1 114.56(8)
C13 Si2 Si1 110.63(8)
C12 Si2 Si1 110.69(8)
C1 N1 C2 110.66(14)
C1 N1 C4 123.46(14)
C2 N1 C4 125.79(14)
C1 N2 C3 110.78(14)
C1 N2 C8 123.76(14)
C3 N2 C8 125.39(14)
Si3 C15 H15A 109.5
Si3 C15 H15B 109.5
H15A C15 H15B 109.5
Si3 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
Si3 C16 H16A 109.5
Si3 C16 H16B 109.5
H16A C16 H16B 109.5
Si3 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
Si3 C17 H17A 109.5
Si3 C17 H17B 109.5
H17A C17 H17B 109.5
Si3 C17 H17C 109.5
H17A C17 H17C 109.5
H17B C17 H17C 109.5
Si4 C18 H18A 109.5
Si4 C18 H18B 109.5
H18A C18 H18B 109.5
Si4 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
Si4 C20 H20A 109.5
Si4 C20 H20B 109.5
H20A C20 H20B 109.5
Si4 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
Si4 C19 H19A 109.5
Si4 C19 H19B 109.5
H19A C19 H19B 109.5
Si4 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
Si2 C12 H12A 109.5
Si2 C12 H12B 109.5
H12A C12 H12B 109.5
Si2 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
Si2 C13 H13A 109.5
Si2 C13 H13B 109.5
H13A C13 H13B 109.5
Si2 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
Si2 C14 H14A 109.5
Si2 C14 H14B 109.5
H14A C14 H14B 109.5
Si2 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
N2 C1 N1 104.44(13)
N2 C1 Cu1 128.08(12)
N1 C1 Cu1 127.33(12)
N1 C4 C5 108.58(15)
N1 C4 C6 108.64(15)
C5 C4 C6 110.54(18)
N1 C4 C7 109.10(16)
C5 C4 C7 110.11(18)
C6 C4 C7 109.84(18)
C4 C6 H6A 109.5
C4 C6 H6B 109.5
H6A C6 H6B 109.5
C4 C6 H6C 109.5
H6A C6 H6C 109.5
H6B C6 H6C 109.5
C4 C5 H5A 109.5
C4 C5 H5B 109.5
H5A C5 H5B 109.5
C4 C5 H5C 109.5
H5A C5 H5C 109.5
H5B C5 H5C 109.5
C4 C7 H7A 109.5
C4 C7 H7B 109.5
H7A C7 H7B 109.5
C4 C7 H7C 109.5
H7A C7 H7C 109.5
H7B C7 H7C 109.5
C3 C2 N1 107.12(15)
C3 C2 H2 126.4
N1 C2 H2 126.4
C2 C3 N2 106.99(15)
C2 C3 H3 126.5
N2 C3 H3 126.5
N2 C8 C10 109.50(15)
N2 C8 C9 109.22(14)
C10 C8 C9 109.67(16)
N2 C8 C11 108.28(14)
C10 C8 C11 109.42(15)
C9 C8 C11 110.72(16)
C8 C10 H10A 109.5
C8 C10 H10B 109.5
H10A C10 H10B 109.5
C8 C10 H10C 109.5
H10A C10 H10C 109.5
H10B C10 H10C 109.5
C8 C9 H9A 109.5
C8 C9 H9B 109.5
H9A C9 H9B 109.5
C8 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
C8 C11 H11A 109.5
C8 C11 H11B 109.5
H11A C11 H11B 109.5
C8 C11 H11C 109.5
H11A C11 H11C 109.5
H11B C11 H11C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Cu1 C1 1.9366(16)
Cu1 Si1 2.2636(5)
Si1 Si3 2.3326(6)
Si1 Si2 2.3401(6)
Si1 Si4 2.3449(6)
Si3 C16 1.877(2)
Si3 C17 1.881(2)
Si3 C15 1.884(2)
Si4 C19 1.879(2)
Si4 C18 1.8830(19)
Si4 C20 1.883(2)
Si2 C14 1.873(2)
Si2 C13 1.880(2)
Si2 C12 1.882(2)
N1 C1 1.362(2)
N1 C2 1.374(2)
N1 C4 1.499(2)
N2 C1 1.355(2)
N2 C3 1.378(2)
N2 C8 1.500(2)
C15 H15A 0.9600
C15 H15B 0.9600
C15 H15C 0.9600
C16 H16A 0.9600
C16 H16B 0.9600
C16 H16C 0.9600
C17 H17A 0.9600
C17 H17B 0.9600
C17 H17C 0.9600
C18 H18A 0.9600
C18 H18B 0.9600
C18 H18C 0.9600
C20 H20A 0.9600
C20 H20B 0.9600
C20 H20C 0.9600
C19 H19A 0.9600
C19 H19B 0.9600
C19 H19C 0.9600
C12 H12A 0.9600
C12 H12B 0.9600
C12 H12C 0.9600
C13 H13A 0.9600
C13 H13B 0.9600
C13 H13C 0.9600
C14 H14A 0.9600
C14 H14B 0.9600
C14 H14C 0.9600
C4 C5 1.519(3)
C4 C6 1.520(3)
C4 C7 1.527(3)
C6 H6A 0.9600
C6 H6B 0.9600
C6 H6C 0.9600
C5 H5A 0.9600
C5 H5B 0.9600
C5 H5C 0.9600
C7 H7A 0.9600
C7 H7B 0.9600
C7 H7C 0.9600
C2 C3 1.340(3)
C2 H2 0.9300
C3 H3 0.9300
C8 C10 1.521(2)
C8 C9 1.523(2)
C8 C11 1.529(2)
C10 H10A 0.9600
C10 H10B 0.9600
C10 H10C 0.9600
C9 H9A 0.9600
C9 H9B 0.9600
C9 H9C 0.9600
C11 H11A 0.9600
C11 H11B 0.9600
C11 H11C 0.9600
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 Cu1 Si1 Si3 166(2)
C1 Cu1 Si1 Si2 -75(2)
C1 Cu1 Si1 Si4 44(2)
Cu1 Si1 Si3 C16 -75.58(10)
Si2 Si1 Si3 C16 163.62(10)
Si4 Si1 Si3 C16 51.30(10)
Cu1 Si1 Si3 C17 163.69(9)
Si2 Si1 Si3 C17 42.89(9)
Si4 Si1 Si3 C17 -69.43(9)
Cu1 Si1 Si3 C15 43.41(9)
Si2 Si1 Si3 C15 -77.39(9)
Si4 Si1 Si3 C15 170.29(9)
Cu1 Si1 Si4 C19 -74.24(8)
Si3 Si1 Si4 C19 158.68(8)
Si2 Si1 Si4 C19 47.07(8)
Cu1 Si1 Si4 C18 44.42(8)
Si3 Si1 Si4 C18 -82.66(8)
Si2 Si1 Si4 C18 165.72(7)
Cu1 Si1 Si4 C20 164.49(9)
Si3 Si1 Si4 C20 37.41(9)
Si2 Si1 Si4 C20 -74.20(9)
Cu1 Si1 Si2 C14 162.88(10)
Si3 Si1 Si2 C14 -73.01(10)
Si4 Si1 Si2 C14 38.55(10)
Cu1 Si1 Si2 C13 -75.89(9)
Si3 Si1 Si2 C13 48.22(9)
Si4 Si1 Si2 C13 159.78(9)
Cu1 Si1 Si2 C12 41.94(12)
Si3 Si1 Si2 C12 166.04(12)
Si4 Si1 Si2 C12 -82.40(12)
C3 N2 C1 N1 -0.89(18)
C8 N2 C1 N1 176.29(14)
C3 N2 C1 Cu1 174.70(13)
C8 N2 C1 Cu1 -8.1(2)
C2 N1 C1 N2 0.68(18)
C4 N1 C1 N2 -176.14(14)
C2 N1 C1 Cu1 -174.96(13)
C4 N1 C1 Cu1 8.2(2)
Si1 Cu1 C1 N2 175(29)
Si1 Cu1 C1 N1 -11(2)
C1 N1 C4 C5 -61.4(2)
C2 N1 C4 C5 122.25(19)
C1 N1 C4 C6 58.8(2)
C2 N1 C4 C6 -117.49(19)
C1 N1 C4 C7 178.56(17)
C2 N1 C4 C7 2.2(3)
C1 N1 C2 C3 -0.2(2)
C4 N1 C2 C3 176.51(16)
N1 C2 C3 N2 -0.3(2)
C1 N2 C3 C2 0.8(2)
C8 N2 C3 C2 -176.34(16)
C1 N2 C8 C10 -175.89(16)
C3 N2 C8 C10 0.9(2)
C1 N2 C8 C9 64.0(2)
C3 N2 C8 C9 -119.23(19)
C1 N2 C8 C11 -56.6(2)
C3 N2 C8 C11 120.12(18)
