#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:33:23 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180044 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/38/7033800.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7033800
loop_
_publ_author_name
'Sgro, Michael J.'
'Piers, Warren E.'
'Romero, Patricio E.'
_publ_section_title
;
 Synthesis, structural characterization and thermal properties of copper
 and silver silyl complexes.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3817
_journal_page_last               3828
_journal_paper_doi               10.1039/c4dt03770g
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C32 H74 Ag2 N4 Si8'
_chemical_formula_weight         955.41
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-12-04 deposited with the CCDC.
2015-01-12 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 121.6380(14)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.0170(4)
_cell_length_b                   21.7790(5)
_cell_length_c                   19.3560(6)
_cell_measurement_reflns_used    17980
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      0.998
_cell_volume                     5030.7(3)
_computing_cell_refinement       'HKL DENZO (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT (Hooft, 1998)'
_computing_data_reduction        'SCALEPACK (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare et al., 1991)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0729
_diffrn_reflns_av_sigmaI/netI    0.0576
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            36692
_diffrn_reflns_theta_full        27.68
_diffrn_reflns_theta_max         27.68
_diffrn_reflns_theta_min         1.55
_exptl_absorpt_coefficient_mu    0.993
_exptl_absorpt_correction_T_max  0.9248
_exptl_absorpt_correction_T_min  0.8901
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SORTAV: (Blessing, 1997)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.261
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             2000
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.658
_refine_diff_density_min         -0.407
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.195
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     437
_refine_ls_number_reflns         11588
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.195
_refine_ls_R_factor_all          0.1020
_refine_ls_R_factor_gt           0.0683
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+13.0796P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1051
_refine_ls_wR_factor_ref         0.1159
_reflns_number_gt                8446
_reflns_number_total             11588
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt03770g2.cif
_cod_data_source_block           compound13
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 7033789--7033802.cif.
;
_cod_original_cell_volume        5030.7(2)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7033800
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.42499(3) 0.15325(2) 0.73076(3) 0.05134(12) Uani 1 1 d .
Ag2 Ag 0.59913(3) 0.179158(18) 0.71351(2) 0.04347(11) Uani 1 1 d .
Si1 Si 0.42906(11) 0.25116(7) 0.66924(9) 0.0409(3) Uani 1 1 d .
Si2 Si 0.54993(13) 0.33316(7) 0.73860(11) 0.0560(4) Uani 1 1 d .
Si3 Si 0.26623(12) 0.27388(8) 0.67140(10) 0.0499(4) Uani 1 1 d .
Si4 Si 0.37539(13) 0.24999(8) 0.53278(10) 0.0539(4) Uani 1 1 d .
Si5 Si 0.76955(11) 0.12889(7) 0.74102(9) 0.0427(3) Uani 1 1 d .
Si6 Si 0.86730(13) 0.10052(8) 0.87715(10) 0.0556(4) Uani 1 1 d .
Si7 Si 0.72396(14) 0.03951(8) 0.66546(12) 0.0619(5) Uani 1 1 d .
Si8 Si 0.89457(13) 0.18380(8) 0.71980(11) 0.0554(4) Uani 1 1 d .
N1 N 0.5092(4) 0.1206(2) 0.8628(3) 0.0589(13) Uani 1 1 d .
N2 N 0.7452(5) 0.0490(3) 1.0899(3) 0.0778(17) Uani 1 1 d .
N3 N 0.2997(4) 0.0734(2) 0.6761(3) 0.0521(12) Uani 1 1 d .
N4 N 0.0782(4) -0.0740(2) 0.5714(3) 0.0693(15) Uani 1 1 d .
C1 C 0.5923(6) 0.1539(3) 0.9213(4) 0.0705(19) Uani 1 1 d .
H1 H 0.5976 0.1947 0.9096 0.085 Uiso 1 1 calc R
C2 C 0.6695(6) 0.1333(3) 0.9962(4) 0.075(2) Uani 1 1 d .
H2 H 0.7245 0.1598 1.0336 0.090 Uiso 1 1 calc R
C3 C 0.6668(5) 0.0729(3) 1.0171(4) 0.0594(16) Uani 1 1 d .
C4 C 0.5798(5) 0.0373(3) 0.9581(4) 0.0568(15) Uani 1 1 d .
H4 H 0.5720 -0.0034 0.9686 0.068 Uiso 1 1 calc R
C5 C 0.5056(5) 0.0631(3) 0.8845(4) 0.0612(16) Uani 1 1 d .
H5 H 0.4479 0.0382 0.8464 0.073 Uiso 1 1 calc R
C6 C 0.8409(7) 0.0859(4) 1.1460(4) 0.104(3) Uani 1 1 d .
H6A H 0.8765 0.1019 1.1189 0.157 Uiso 1 1 calc R
H6B H 0.8932 0.0610 1.1911 0.157 Uiso 1 1 calc R
H6C H 0.8163 0.1193 1.1653 0.157 Uiso 1 1 calc R
C7 C 0.7483(6) -0.0160(4) 1.1046(5) 0.095(3) Uani 1 1 d .
H7A H 0.6798 -0.0283 1.1004 0.142 Uiso 1 1 calc R
H7B H 0.8104 -0.0251 1.1580 0.142 Uiso 1 1 calc R
H7C H 0.7570 -0.0378 1.0651 0.142 Uiso 1 1 calc R
C8 C 0.2207(5) 0.0610(3) 0.6923(4) 0.0558(15) Uani 1 1 d .
H8 H 0.2162 0.0865 0.7290 0.067 Uiso 1 1 calc R
C9 C 0.1460(4) 0.0142(3) 0.6595(4) 0.0537(14) Uani 1 1 d .
H9 H 0.0927 0.0090 0.6738 0.064 Uiso 1 1 calc R
C10 C 0.1486(4) -0.0259(3) 0.6047(3) 0.0500(14) Uani 1 1 d .
C11 C 0.2310(5) -0.0133(3) 0.5879(4) 0.0612(16) Uani 1 1 d .
H11 H 0.2385 -0.0381 0.5519 0.073 Uiso 1 1 calc R
C12 C 0.3009(5) 0.0350(3) 0.6235(4) 0.0604(16) Uani 1 1 d .
H12 H 0.3545 0.0419 0.6098 0.072 Uiso 1 1 calc R
C13 C -0.0072(6) -0.0851(3) 0.5894(5) 0.092(2) Uani 1 1 d .
H13A H 0.0270 -0.0938 0.6462 0.138 Uiso 1 1 calc R
H13B H -0.0518 -0.1196 0.5584 0.138 Uiso 1 1 calc R
H13C H -0.0540 -0.0495 0.5758 0.138 Uiso 1 1 calc R
C14 C 0.0859(6) -0.1157(3) 0.5167(5) 0.098(3) Uani 1 1 d .
H14A H 0.0661 -0.0945 0.4674 0.146 Uiso 1 1 calc R
H14B H 0.0356 -0.1495 0.5046 0.146 Uiso 1 1 calc R
H14C H 0.1612 -0.1308 0.5416 0.146 Uiso 1 1 calc R
C15 C 0.5609(7) 0.3439(4) 0.8385(4) 0.098(3) Uani 1 1 d .
H15A H 0.6014 0.3810 0.8635 0.147 Uiso 1 1 calc R
H15B H 0.5999 0.3096 0.8731 0.147 Uiso 1 1 calc R
H15C H 0.4872 0.3466 0.8300 0.147 Uiso 1 1 calc R
C16 C 0.5002(7) 0.4070(3) 0.6844(5) 0.112(3) Uani 1 1 d .
H16A H 0.5476 0.4396 0.7186 0.168 Uiso 1 1 calc R
H16B H 0.4247 0.4142 0.6705 0.168 Uiso 1 1 calc R
H16C H 0.5027 0.4056 0.6357 0.168 Uiso 1 1 calc R
C17 C 0.6932(5) 0.3228(3) 0.7592(6) 0.108(3) Uani 1 1 d .
H17A H 0.6907 0.3198 0.7088 0.162 Uiso 1 1 calc R
H17B H 0.7250 0.2860 0.7902 0.162 Uiso 1 1 calc R
H17C H 0.7385 0.3574 0.7894 0.162 Uiso 1 1 calc R
C18 C 0.2217(5) 0.3556(3) 0.6467(5) 0.083(2) Uani 1 1 d .
H18A H 0.2164 0.3665 0.5968 0.125 Uiso 1 1 calc R
H18B H 0.2758 0.3815 0.6896 0.125 Uiso 1 1 calc R
H18C H 0.1500 0.3608 0.6411 0.125 Uiso 1 1 calc R
C19 C 0.1461(4) 0.2261(3) 0.5955(4) 0.0633(17) Uani 1 1 d .
H19A H 0.0808 0.2355 0.5977 0.095 Uiso 1 1 calc R
H19B H 0.1643 0.1834 0.6075 0.095 Uiso 1 1 calc R
H19C H 0.1313 0.2348 0.5421 0.095 Uiso 1 1 calc R
C20 C 0.2820(5) 0.2570(4) 0.7714(4) 0.083(2) Uani 1 1 d .
H20A H 0.3423 0.2810 0.8129 0.125 Uiso 1 1 calc R
H20B H 0.2979 0.2142 0.7837 0.125 Uiso 1 1 calc R
H20C H 0.2137 0.2672 0.7690 0.125 Uiso 1 1 calc R
C21 C 0.2951(7) 0.1790(4) 0.4828(4) 0.097(3) Uani 1 1 d .
H21A H 0.2313 0.1765 0.4886 0.146 Uiso 1 1 calc R
H21B H 0.3422 0.1439 0.5077 0.146 Uiso 1 1 calc R
H21C H 0.2703 0.1801 0.4262 0.146 Uiso 1 1 calc R
C22 C 0.5000(6) 0.2486(5) 0.5231(4) 0.111(3) Uani 1 1 d .
H22A H 0.4764 0.2452 0.4669 0.166 Uiso 1 1 calc R
H22B H 0.5462 0.2140 0.5524 0.166 Uiso 1 1 calc R
H22C H 0.5420 0.2858 0.5450 0.166 Uiso 1 1 calc R
C23 C 0.2878(7) 0.3166(4) 0.4739(4) 0.113(3) Uani 1 1 d .
H23A H 0.2650 0.3121 0.4180 0.169 Uiso 1 1 calc R
H23B H 0.3304 0.3537 0.4951 0.169 Uiso 1 1 calc R
H23C H 0.2227 0.3185 0.4782 0.169 Uiso 1 1 calc R
C24 C 0.8867(6) 0.1681(4) 0.9426(4) 0.091(2) Uani 1 1 d .
H24A H 0.8148 0.1835 0.9293 0.137 Uiso 1 1 calc R
H24B H 0.9268 0.1997 0.9336 0.137 Uiso 1 1 calc R
H24C H 0.9286 0.1560 0.9986 0.137 Uiso 1 1 calc R
C25 C 0.7863(5) 0.0409(3) 0.8944(4) 0.0670(17) Uani 1 1 d .
H25A H 0.8205 0.0340 0.9516 0.100 Uiso 1 1 calc R
H25B H 0.7861 0.0033 0.8684 0.100 Uiso 1 1 calc R
H25C H 0.7106 0.0547 0.8721 0.100 Uiso 1 1 calc R
C26 C 1.0108(5) 0.0689(4) 0.9156(4) 0.092(3) Uani 1 1 d .
H26A H 1.0529 0.0974 0.9040 0.138 Uiso 1 1 calc R
H26B H 1.0049 0.0305 0.8893 0.138 Uiso 1 1 calc R
H26C H 1.0483 0.0627 0.9731 0.138 Uiso 1 1 calc R
C27 C 0.6077(6) -0.0014(3) 0.6647(5) 0.089(2) Uani 1 1 d .
H27A H 0.5405 0.0227 0.6359 0.133 Uiso 1 1 calc R
H27B H 0.6262 -0.0076 0.7195 0.133 Uiso 1 1 calc R
H27C H 0.5961 -0.0404 0.6384 0.133 Uiso 1 1 calc R
C28 C 0.8410(6) -0.0184(4) 0.7043(6) 0.131(4) Uani 1 1 d .
H28A H 0.8732 -0.0243 0.7615 0.197 Uiso 1 1 calc R
H28B H 0.8976 -0.0037 0.6946 0.197 Uiso 1 1 calc R
H28C H 0.8120 -0.0567 0.6765 0.197 Uiso 1 1 calc R
C29 C 0.6766(9) 0.0568(5) 0.5588(5) 0.146(4) Uani 1 1 d .
H29A H 0.6641 0.0191 0.5295 0.219 Uiso 1 1 calc R
H29B H 0.7330 0.0804 0.5568 0.219 Uiso 1 1 calc R
H29C H 0.6082 0.0799 0.5346 0.219 Uiso 1 1 calc R
C30 C 1.0100(5) 0.1350(3) 0.7275(4) 0.073(2) Uani 1 1 d .
H30A H 0.9784 0.1031 0.6874 0.110 Uiso 1 1 calc R
H30B H 1.0518 0.1170 0.7806 0.110 Uiso 1 1 calc R
H30C H 1.0589 0.1600 0.7185 0.110 Uiso 1 1 calc R
C31 C 0.8228(6) 0.2190(3) 0.6167(5) 0.088(2) Uani 1 1 d .
H31A H 0.8766 0.2406 0.6095 0.132 Uiso 1 1 calc R
H31B H 0.7664 0.2471 0.6111 0.132 Uiso 1 1 calc R
H31C H 0.7883 0.1873 0.5764 0.132 Uiso 1 1 calc R
C32 C 0.9655(5) 0.2472(3) 0.7952(5) 0.087(2) Uani 1 1 d .
H32A H 1.0129 0.2698 0.7823 0.130 Uiso 1 1 calc R
H32B H 1.0100 0.2300 0.8487 0.130 Uiso 1 1 calc R
H32C H 0.9100 0.2741 0.7934 0.130 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N1 Ag1 N3 95.78(18)
N1 Ag1 Si1 132.81(14)
N3 Ag1 Si1 129.79(12)
N1 Ag1 Ag2 103.47(13)
N3 Ag1 Ag2 128.70(12)
Si1 Ag1 Ag2 60.32(3)
Si5 Ag2 Si1 167.45(5)
Si5 Ag2 Ag1 137.12(4)
Si1 Ag2 Ag1 55.37(3)
Si4 Si1 Si2 111.33(9)
Si4 Si1 Si3 106.37(7)
Si2 Si1 Si3 104.24(8)
Si4 Si1 Ag1 117.57(7)
Si2 Si1 Ag1 125.31(7)
Si3 Si1 Ag1 84.53(6)
Si4 Si1 Ag2 93.55(6)
Si2 Si1 Ag2 90.49(6)
Si3 Si1 Ag2 148.36(8)
Ag1 Si1 Ag2 64.30(4)
C17 Si2 C16 105.8(4)
C17 Si2 C15 107.5(4)
C16 Si2 C15 106.3(4)
C17 Si2 Si1 114.2(2)
C16 Si2 Si1 113.3(3)
C15 Si2 Si1 109.3(2)
C18 Si3 C20 107.2(3)
C18 Si3 C19 106.7(3)
C20 Si3 C19 105.9(3)
C18 Si3 Si1 113.2(2)
C20 Si3 Si1 112.9(2)
C19 Si3 Si1 110.6(2)
C22 Si4 C23 107.8(4)
C22 Si4 C21 106.2(4)
C23 Si4 C21 107.8(4)
C22 Si4 Si1 110.7(2)
C23 Si4 Si1 113.7(3)
C21 Si4 Si1 110.2(2)
Si7 Si5 Si6 107.20(9)
Si7 Si5 Si8 107.72(9)
Si6 Si5 Si8 106.58(8)
Si7 Si5 Ag2 109.15(7)
Si6 Si5 Ag2 107.23(7)
Si8 Si5 Ag2 118.43(7)
C25 Si6 C24 108.2(3)
C25 Si6 C26 107.5(3)
C24 Si6 C26 106.1(3)
C25 Si6 Si5 109.6(2)
C24 Si6 Si5 110.4(3)
C26 Si6 Si5 114.8(2)
C29 Si7 C27 106.9(4)
C29 Si7 C28 108.0(5)
C27 Si7 C28 105.1(4)
C29 Si7 Si5 110.7(3)
C27 Si7 Si5 111.1(3)
C28 Si7 Si5 114.6(3)
C31 Si8 C32 107.4(4)
C31 Si8 C30 106.1(3)
C32 Si8 C30 105.8(3)
C31 Si8 Si5 111.5(2)
C32 Si8 Si5 112.5(2)
C30 Si8 Si5 113.1(2)
C5 N1 C1 113.9(5)
C5 N1 Ag1 124.1(4)
C1 N1 Ag1 119.1(4)
C3 N2 C7 120.5(6)
C3 N2 C6 119.5(6)
C7 N2 C6 118.6(6)
C12 N3 C8 113.7(5)
C12 N3 Ag1 121.2(4)
C8 N3 Ag1 125.1(4)
C10 N4 C13 120.8(6)
C10 N4 C14 121.4(6)
C13 N4 C14 117.8(6)
N1 C1 C2 125.5(6)
N1 C1 H1 117.2
C2 C1 H1 117.2
C1 C2 C3 120.0(6)
C1 C2 H2 120.0
C3 C2 H2 120.0
N2 C3 C2 122.5(7)
N2 C3 C4 121.6(6)
C2 C3 C4 115.9(6)
C5 C4 C3 119.2(6)
C5 C4 H4 120.4
C3 C4 H4 120.4
N1 C5 C4 125.5(6)
N1 C5 H5 117.3
C4 C5 H5 117.3
N2 C6 H6A 109.5
N2 C6 H6B 109.5
H6A C6 H6B 109.5
N2 C6 H6C 109.5
H6A C6 H6C 109.5
H6B C6 H6C 109.5
N2 C7 H7A 109.5
N2 C7 H7B 109.5
H7A C7 H7B 109.5
N2 C7 H7C 109.5
H7A C7 H7C 109.5
H7B C7 H7C 109.5
N3 C8 C9 125.3(6)
N3 C8 H8 117.4
C9 C8 H8 117.4
C8 C9 C10 120.4(5)
C8 C9 H9 119.8
C10 C9 H9 119.8
N4 C10 C11 122.4(6)
N4 C10 C9 123.2(6)
C11 C10 C9 114.5(5)
C12 C11 C10 120.3(6)
C12 C11 H11 119.8
C10 C11 H11 119.8
N3 C12 C11 125.8(6)
N3 C12 H12 117.1
C11 C12 H12 117.1
N4 C13 H13A 109.5
N4 C13 H13B 109.5
H13A C13 H13B 109.5
N4 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
N4 C14 H14A 109.5
N4 C14 H14B 109.5
H14A C14 H14B 109.5
N4 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
Si2 C15 H15A 109.5
Si2 C15 H15B 109.5
H15A C15 H15B 109.5
Si2 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
Si2 C16 H16A 109.5
Si2 C16 H16B 109.5
H16A C16 H16B 109.5
Si2 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
Si2 C17 H17A 109.5
Si2 C17 H17B 109.5
H17A C17 H17B 109.5
Si2 C17 H17C 109.5
H17A C17 H17C 109.5
H17B C17 H17C 109.5
Si3 C18 H18A 109.5
Si3 C18 H18B 109.5
H18A C18 H18B 109.5
Si3 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
Si3 C19 H19A 109.5
Si3 C19 H19B 109.5
H19A C19 H19B 109.5
Si3 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
Si3 C20 H20A 109.5
Si3 C20 H20B 109.5
H20A C20 H20B 109.5
Si3 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
Si4 C21 H21A 109.5
Si4 C21 H21B 109.5
H21A C21 H21B 109.5
Si4 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
Si4 C22 H22A 109.5
Si4 C22 H22B 109.5
H22A C22 H22B 109.5
Si4 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
Si4 C23 H23A 109.5
Si4 C23 H23B 109.5
H23A C23 H23B 109.5
Si4 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
Si6 C24 H24A 109.5
Si6 C24 H24B 109.5
H24A C24 H24B 109.5
Si6 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
Si6 C25 H25A 109.5
Si6 C25 H25B 109.5
H25A C25 H25B 109.5
Si6 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
Si6 C26 H26A 109.5
Si6 C26 H26B 109.5
H26A C26 H26B 109.5
Si6 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
Si7 C27 H27A 109.5
Si7 C27 H27B 109.5
H27A C27 H27B 109.5
Si7 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
Si7 C28 H28A 109.5
Si7 C28 H28B 109.5
H28A C28 H28B 109.5
Si7 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
Si7 C29 H29A 109.5
Si7 C29 H29B 109.5
H29A C29 H29B 109.5
Si7 C29 H29C 109.5
H29A C29 H29C 109.5
H29B C29 H29C 109.5
Si8 C30 H30A 109.5
Si8 C30 H30B 109.5
H30A C30 H30B 109.5
Si8 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
Si8 C31 H31A 109.5
Si8 C31 H31B 109.5
H31A C31 H31B 109.5
Si8 C31 H31C 109.5
H31A C31 H31C 109.5
H31B C31 H31C 109.5
Si8 C32 H32A 109.5
Si8 C32 H32B 109.5
H32A C32 H32B 109.5
Si8 C32 H32C 109.5
H32A C32 H32C 109.5
H32B C32 H32C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ag1 N1 2.295(5)
Ag1 N3 2.297(5)
Ag1 Si1 2.4577(15)
Ag1 Ag2 2.6913(6)
Ag2 Si5 2.4195(14)
Ag2 Si1 2.5949(14)
Si1 Si4 2.336(2)
Si1 Si2 2.340(2)
Si1 Si3 2.357(2)
Si2 C17 1.845(7)
Si2 C16 1.845(7)
Si2 C15 1.871(8)
Si3 C18 1.863(6)
Si3 C20 1.866(6)
Si3 C19 1.866(6)
Si4 C22 1.853(7)
Si4 C23 1.856(7)
Si4 C21 1.857(7)
Si5 Si7 2.314(2)
Si5 Si6 2.327(2)
Si5 Si8 2.329(2)
Si6 C25 1.867(6)
Si6 C24 1.867(7)
Si6 C26 1.872(6)
Si7 C29 1.845(8)
Si7 C27 1.850(7)
Si7 C28 1.886(7)
Si8 C31 1.865(7)
Si8 C32 1.871(7)
Si8 C30 1.875(6)
N1 C5 1.330(7)
N1 C1 1.335(8)
N2 C3 1.356(7)
N2 C7 1.438(9)
N2 C6 1.449(9)
N3 C12 1.323(7)
N3 C8 1.328(7)
N4 C10 1.348(7)
N4 C13 1.432(8)
N4 C14 1.442(8)
C1 C2 1.351(8)
C1 H1 0.9300
C2 C3 1.383(9)
C2 H2 0.9300
C3 C4 1.389(8)
C4 C5 1.368(8)
C4 H4 0.9300
C5 H5 0.9300
C6 H6A 0.9600
C6 H6B 0.9600
C6 H6C 0.9600
C7 H7A 0.9600
C7 H7B 0.9600
C7 H7C 0.9600
C8 C9 1.357(7)
C8 H8 0.9300
C9 C10 1.390(8)
C9 H9 0.9300
C10 C11 1.382(8)
C11 C12 1.354(8)
C11 H11 0.9300
C12 H12 0.9300
C13 H13A 0.9600
C13 H13B 0.9600
C13 H13C 0.9600
C14 H14A 0.9600
C14 H14B 0.9600
C14 H14C 0.9600
C15 H15A 0.9600
C15 H15B 0.9600
C15 H15C 0.9600
C16 H16A 0.9600
C16 H16B 0.9600
C16 H16C 0.9600
C17 H17A 0.9600
C17 H17B 0.9600
C17 H17C 0.9600
C18 H18A 0.9600
C18 H18B 0.9600
C18 H18C 0.9600
C19 H19A 0.9600
C19 H19B 0.9600
C19 H19C 0.9600
C20 H20A 0.9600
C20 H20B 0.9600
C20 H20C 0.9600
C21 H21A 0.9600
C21 H21B 0.9600
C21 H21C 0.9600
C22 H22A 0.9600
C22 H22B 0.9600
C22 H22C 0.9600
C23 H23A 0.9600
C23 H23B 0.9600
C23 H23C 0.9600
C24 H24A 0.9600
C24 H24B 0.9600
C24 H24C 0.9600
C25 H25A 0.9600
C25 H25B 0.9600
C25 H25C 0.9600
C26 H26A 0.9600
C26 H26B 0.9600
C26 H26C 0.9600
C27 H27A 0.9600
C27 H27B 0.9600
C27 H27C 0.9600
C28 H28A 0.9600
C28 H28B 0.9600
C28 H28C 0.9600
C29 H29A 0.9600
C29 H29B 0.9600
C29 H29C 0.9600
C30 H30A 0.9600
C30 H30B 0.9600
C30 H30C 0.9600
C31 H31A 0.9600
C31 H31B 0.9600
C31 H31C 0.9600
C32 H32A 0.9600
C32 H32B 0.9600
C32 H32C 0.9600
