#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:39:32 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180048 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/42/7034250.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034250
loop_
_publ_author_name
'Icsel, Ceyda'
'Yilmaz, Veysel T.'
'Kaya, Yunus'
'Samli, Hale'
'Harrison, William T. A.'
'Buyukgungor, Orhan'
_publ_section_title
;
 New palladium(ii) and platinum(ii) 5,5-diethylbarbiturate complexes with
 2-phenylpyridine, 2,2'-bipyridine and 2,2'-dipyridylamine: synthesis,
 structures, DNA binding, molecular docking, cellular uptake, antioxidant
 activity and cytotoxicity.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6880
_journal_page_last               6895
_journal_paper_doi               10.1039/c5dt00728c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         '2(C16 H22 Ag N4 O6), C20 H18 N6 Pt, 4(H2 O)'
_chemical_formula_sum            'C52 H70 Ag2 N14 O16 Pt'
_chemical_formula_weight         1558.05
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-11-13 deposited with the CCDC.
2015-03-02 downloaded from the CCDC.
;
_cell_angle_alpha                72.852(3)
_cell_angle_beta                 86.993(3)
_cell_angle_gamma                84.128(3)
_cell_formula_units_Z            1
_cell_length_a                   11.0480(4)
_cell_length_b                   11.4890(4)
_cell_length_c                   12.7247(5)
_cell_measurement_reflns_used    28112
_cell_measurement_temperature    296
_cell_measurement_theta_max      28.06
_cell_measurement_theta_min      1.85
_cell_volume                     1534.83(10)
_computing_cell_refinement       X-AREA
_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2002)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0326
_diffrn_reflns_av_sigmaI/netI    0.0231
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            28112
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    2.981
_exptl_absorpt_correction_T_max  0.7362
_exptl_absorpt_correction_T_min  0.3298
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   '(X-RED32, Stoe & Cie, 2002)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.686
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             780
_exptl_crystal_size_max          0.64
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.540
_refine_diff_density_min         -0.391
_refine_diff_density_rms         0.054
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.998
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     405
_refine_ls_number_reflns         6026
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      0.999
_refine_ls_R_factor_all          0.0226
_refine_ls_R_factor_gt           0.0204
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0263P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0435
_refine_ls_wR_factor_ref         0.0440
_reflns_number_gt                5603
_reflns_number_total             6026
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c5dt00728c2.cif
_cod_data_source_block           Compound_VI
_cod_depositor_comments
'Adding full bibliography for 7034246--7034250.cif.'
_cod_database_code               7034250
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.0766(3) 0.1095(3) 0.8580(3) 0.0586(8) Uani 1 1 d .
C2 C 0.2659(3) -0.0210(2) 0.9066(2) 0.0494(7) Uani 1 1 d .
C3 C 0.3309(2) 0.0645(2) 0.8136(2) 0.0450(6) Uani 1 1 d .
C4 C 0.2500(2) 0.1774(2) 0.7504(2) 0.0417(6) Uani 1 1 d .
C5 C 0.3827(5) -0.0067(3) 0.7354(3) 0.0947(15) Uani 1 1 d .
H5A H 0.4209 0.0491 0.6729 0.114 Uiso 1 1 calc R
H5B H 0.4457 -0.0678 0.7728 0.114 Uiso 1 1 calc R
C6 C 0.2920(7) -0.0688(5) 0.6942(4) 0.151(3) Uani 1 1 d .
H6A H 0.3316 -0.1105 0.6449 0.227 Uiso 1 1 calc R
H6B H 0.2297 -0.0091 0.6561 0.227 Uiso 1 1 calc R
H6C H 0.2560 -0.1269 0.7552 0.227 Uiso 1 1 calc R
C7 C 0.4341(3) 0.1113(3) 0.8627(3) 0.0697(10) Uani 1 1 d .
H7A H 0.4898 0.0421 0.8995 0.084 Uiso 1 1 calc R
H7B H 0.4791 0.1643 0.8032 0.084 Uiso 1 1 calc R
C8 C 0.3901(4) 0.1807(4) 0.9434(4) 0.0978(15) Uani 1 1 d .
H8A H 0.4588 0.2042 0.9730 0.147 Uiso 1 1 calc R
H8B H 0.3444 0.1295 1.0021 0.147 Uiso 1 1 calc R
H8C H 0.3393 0.2525 0.9066 0.147 Uiso 1 1 calc R
C9 C -0.1481(2) 0.5533(2) 0.5768(2) 0.0400(5) Uani 1 1 d .
C10 C -0.2267(3) 0.7563(2) 0.5888(2) 0.0580(8) Uani 1 1 d .
C11 C -0.1473(3) 0.7388(2) 0.6860(2) 0.0500(6) Uani 1 1 d .
C12 C -0.0823(2) 0.6108(2) 0.7271(2) 0.0425(6) Uani 1 1 d .
C13 C -0.2253(3) 0.7707(3) 0.7782(3) 0.0589(8) Uani 1 1 d .
H13A H -0.1730 0.7683 0.8379 0.071 Uiso 1 1 calc R
H13B H -0.2632 0.8535 0.7508 0.071 Uiso 1 1 calc R
C14 C -0.3230(4) 0.6854(3) 0.8225(3) 0.0818(11) Uani 1 1 d .
H14A H -0.3654 0.7067 0.8830 0.123 Uiso 1 1 calc R
H14B H -0.2865 0.6028 0.8473 0.123 Uiso 1 1 calc R
H14C H -0.3792 0.6925 0.7655 0.123 Uiso 1 1 calc R
C15 C -0.0475(4) 0.8296(3) 0.6478(4) 0.0787(11) Uani 1 1 d .
H15A H -0.0865 0.9124 0.6289 0.094 Uiso 1 1 calc R
H15B H 0.0053 0.8196 0.7090 0.094 Uiso 1 1 calc R
C16 C 0.0301(4) 0.8140(4) 0.5503(4) 0.1008(15) Uani 1 1 d .
H16A H 0.0931 0.8688 0.5356 0.151 Uiso 1 1 calc R
H16B H -0.0198 0.8322 0.4869 0.151 Uiso 1 1 calc R
H16C H 0.0662 0.7313 0.5666 0.151 Uiso 1 1 calc R
N1 N 0.1308(2) 0.19212(19) 0.77512(18) 0.0471(5) Uani 1 1 d .
N2 N 0.1462(2) 0.0072(2) 0.9209(2) 0.0639(7) Uani 1 1 d D
N3 N -0.0839(2) 0.52867(17) 0.67101(16) 0.0394(5) Uani 1 1 d .
N4 N -0.2168(2) 0.6643(2) 0.54022(18) 0.0524(6) Uani 1 1 d .
H4 H -0.2571 0.6766 0.4813 0.063 Uiso 1 1 calc R
O1 O -0.0321(2) 0.1219(2) 0.8805(2) 0.0868(9) Uani 1 1 d .
O2 O 0.3190(2) -0.11300(19) 0.96682(19) 0.0709(7) Uani 1 1 d .
O3 O 0.29850(18) 0.25493(16) 0.67717(15) 0.0539(5) Uani 1 1 d .
O4 O -0.14756(19) 0.47960(16) 0.52545(16) 0.0533(5) Uani 1 1 d .
O5 O -0.2931(3) 0.8480(2) 0.5527(2) 0.1001(10) Uani 1 1 d .
O6 O -0.0255(2) 0.5846(2) 0.81324(17) 0.0631(6) Uani 1 1 d .
Ag1 Ag 0.025560(18) 0.360864(15) 0.712766(15) 0.04749(6) Uani 1 1 d .
H2 H 0.110(3) -0.039(3) 0.975(2) 0.079(11) Uiso 1 1 d D
C17 C 0.6481(2) 0.3293(2) 0.67333(19) 0.0370(5) Uani 1 1 d .
C18 C 0.7317(3) 0.2307(2) 0.7184(2) 0.0462(6) Uani 1 1 d .
H18 H 0.7778 0.2295 0.7778 0.055 Uiso 1 1 calc R
C19 C 0.7450(3) 0.1357(2) 0.6738(3) 0.0561(8) Uani 1 1 d .
H19 H 0.8010 0.0689 0.7025 0.067 Uiso 1 1 calc R
C20 C 0.6748(3) 0.1389(2) 0.5857(2) 0.0550(7) Uani 1 1 d .
H20 H 0.6789 0.0722 0.5579 0.066 Uiso 1 1 calc R
C21 C 0.5998(3) 0.2411(2) 0.5405(2) 0.0472(6) Uani 1 1 d .
H21 H 0.5546 0.2442 0.4800 0.057 Uiso 1 1 calc R
C22 C 0.3157(2) 0.5468(2) 0.6632(2) 0.0439(6) Uani 1 1 d .
H22 H 0.2635 0.5646 0.6044 0.053 Uiso 1 1 calc R
C23 C 0.2714(3) 0.5629(3) 0.7601(2) 0.0545(7) Uani 1 1 d .
H23 H 0.1904 0.5911 0.7675 0.065 Uiso 1 1 calc R
C24 C 0.3491(3) 0.5363(3) 0.8475(2) 0.0562(7) Uani 1 1 d .
H24 H 0.3218 0.5497 0.9137 0.067 Uiso 1 1 calc R
C25 C 0.4658(3) 0.4904(2) 0.8356(2) 0.0473(6) Uani 1 1 d .
H25 H 0.5184 0.4709 0.8943 0.057 Uiso 1 1 calc R
C26 C 0.5065(2) 0.4725(2) 0.73591(19) 0.0365(5) Uani 1 1 d .
N5 N 0.58890(19) 0.33911(17) 0.58115(16) 0.0365(4) Uani 1 1 d .
N6 N 0.43320(18) 0.50585(16) 0.64900(15) 0.0351(4) Uani 1 1 d .
N7 N 0.6234(2) 0.42003(18) 0.72520(17) 0.0397(5) Uani 1 1 d D
Pt1 Pt 0.5000 0.5000 0.5000 0.03147(4) Uani 1 2 d S
H7 H 0.660(2) 0.406(2) 0.7822(16) 0.035(7) Uiso 1 1 d D
O1W O 0.2596(2) 0.64979(19) 0.06817(19) 0.0648(6) Uani 1 1 d D
H11W H 0.188(2) 0.648(3) 0.055(4) 0.097 Uiso 1 1 d D
H12W H 0.275(3) 0.722(2) 0.046(3) 0.097 Uiso 1 1 d D
O2W O 0.0223(5) 0.6414(4) 0.0118(3) 0.1425(15) Uani 1 1 d D
H21W H 0.026(8) 0.565(3) 0.051(5) 0.214 Uiso 1 1 d D
H22W H -0.014(7) 0.645(6) -0.049(4) 0.214 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 N1 122.2(2) . .
O1 C1 N2 118.4(3) . .
N1 C1 N2 119.3(3) . .
O2 C2 N2 121.1(3) . .
O2 C2 C3 121.6(3) . .
N2 C2 C3 117.3(2) . .
C2 C3 C5 108.0(3) . .
C2 C3 C4 113.8(2) . .
C5 C3 C4 109.7(2) . .
C2 C3 C7 107.8(2) . .
C5 C3 C7 110.5(3) . .
C4 C3 C7 106.9(2) . .
O3 C4 N1 121.0(2) . .
O3 C4 C3 117.5(2) . .
N1 C4 C3 121.4(2) . .
C6 C5 C3 114.7(4) . .
C6 C5 H5A 108.6 . .
C3 C5 H5A 108.6 . .
C6 C5 H5B 108.6 . .
C3 C5 H5B 108.6 . .
H5A C5 H5B 107.6 . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C8 C7 C3 113.8(3) . .
C8 C7 H7A 108.8 . .
C3 C7 H7A 108.8 . .
C8 C7 H7B 108.8 . .
C3 C7 H7B 108.8 . .
H7A C7 H7B 107.7 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
O4 C9 N3 121.7(2) . .
O4 C9 N4 119.2(2) . .
N3 C9 N4 119.1(2) . .
O5 C10 N4 121.0(3) . .
O5 C10 C11 122.3(3) . .
N4 C10 C11 116.6(2) . .
C10 C11 C12 113.9(2) . .
C10 C11 C13 108.6(3) . .
C12 C11 C13 110.5(2) . .
C10 C11 C15 107.0(3) . .
C12 C11 C15 107.2(3) . .
C13 C11 C15 109.4(2) . .
O6 C12 N3 120.3(2) . .
O6 C12 C11 118.1(2) . .
N3 C12 C11 121.6(2) . .
C14 C13 C11 113.2(3) . .
C14 C13 H13A 108.9 . .
C11 C13 H13A 108.9 . .
C14 C13 H13B 108.9 . .
C11 C13 H13B 108.9 . .
H13A C13 H13B 107.7 . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 C11 114.7(3) . .
C16 C15 H15A 108.6 . .
C11 C15 H15A 108.6 . .
C16 C15 H15B 108.6 . .
C11 C15 H15B 108.6 . .
H15A C15 H15B 107.6 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C4 N1 C1 121.8(2) . .
C4 N1 Ag1 121.99(16) . .
C1 N1 Ag1 114.82(18) . .
C2 N2 C1 126.1(2) . .
C2 N2 H2 117(2) . .
C1 N2 H2 117(3) . .
C12 N3 C9 121.9(2) . .
C12 N3 Ag1 122.40(16) . .
C9 N3 Ag1 115.38(15) . .
C10 N4 C9 126.1(2) . .
C10 N4 H4 116.9 . .
C9 N4 H4 116.9 . .
N5 C17 C18 121.9(2) . .
N5 C17 N7 118.7(2) . .
C18 C17 N7 119.4(2) . .
C19 C18 C17 118.7(3) . .
C19 C18 H18 120.6 . .
C17 C18 H18 120.6 . .
C18 C19 C20 119.7(3) . .
C18 C19 H19 120.1 . .
C20 C19 H19 120.1 . .
C21 C20 C19 118.9(3) . .
C21 C20 H20 120.5 . .
C19 C20 H20 120.5 . .
C20 C21 N5 122.1(3) . .
C20 C21 H21 119.0 . .
N5 C21 H21 119.0 . .
N6 C22 C23 122.5(2) . .
N6 C22 H22 118.8 . .
C23 C22 H22 118.8 . .
C22 C23 C24 118.7(3) . .
C22 C23 H23 120.6 . .
C24 C23 H23 120.6 . .
C25 C24 C23 119.3(3) . .
C25 C24 H24 120.3 . .
C23 C24 H24 120.3 . .
C24 C25 C26 120.0(2) . .
C24 C25 H25 120.0 . .
C26 C25 H25 120.0 . .
N6 C26 N7 119.4(2) . .
N6 C26 C25 120.5(2) . .
N7 C26 C25 120.1(2) . .
C17 N5 C21 118.0(2) . .
C17 N5 Pt1 119.93(15) . .
C21 N5 Pt1 121.85(17) . .
C26 N6 C22 118.7(2) . .
C26 N6 Pt1 119.98(16) . .
C22 N6 Pt1 121.25(16) . .
C26 N7 C17 122.3(2) . .
C26 N7 H7 110.6(19) . .
C17 N7 H7 113.4(18) . .
H11W O1W H12W 108(3) . .
H21W O2W H22W 106(3) . .
N3 Ag1 N1 172.91(8) . .
N5 Pt1 N5 180.00(11) . 2_666
N5 Pt1 N6 85.76(8) . .
N5 Pt1 N6 94.24(8) 2_666 .
N5 Pt1 N6 94.24(8) . 2_666
N5 Pt1 N6 85.76(8) 2_666 2_666
N6 Pt1 N6 180.0 . 2_666
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.224(4) .
C1 N1 1.353(4) .
C1 N2 1.392(3) .
C2 O2 1.221(3) .
C2 N2 1.345(4) .
C2 C3 1.501(4) .
C3 C5 1.520(4) .
C3 C4 1.533(3) .
C3 C7 1.542(4) .
C4 O3 1.227(3) .
C4 N1 1.344(3) .
C5 C6 1.487(8) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 C8 1.509(6) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 O4 1.212(3) .
C9 N3 1.367(3) .
C9 N4 1.381(3) .
C10 O5 1.204(3) .
C10 N4 1.366(4) .
C10 C11 1.507(4) .
C11 C12 1.524(3) .
C11 C13 1.529(4) .
C11 C15 1.556(4) .
C12 O6 1.235(3) .
C12 N3 1.342(3) .
C13 C14 1.505(5) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C16 1.514(5) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
N2 H2 0.848(18) .
N4 H4 0.8600 .
C17 N5 1.343(3) .
C17 C18 1.387(3) .
C17 N7 1.388(3) .
C18 C19 1.363(4) .
C18 H18 0.9300 .
C19 C20 1.387(4) .
C19 H19 0.9300 .
C20 C21 1.359(4) .
C20 H20 0.9300 .
C21 N5 1.364(3) .
C21 H21 0.9300 .
C22 N6 1.356(3) .
C22 C23 1.358(4) .
C22 H22 0.9300 .
C23 C24 1.384(4) .
C23 H23 0.9300 .
C24 C25 1.361(4) .
C24 H24 0.9300 .
C25 C26 1.389(3) .
C25 H25 0.9300 .
C26 N6 1.344(3) .
C26 N7 1.386(3) .
N7 H7 0.817(16) .
O1W H11W 0.818(18) .
O1W H12W 0.827(18) .
O2W H21W 0.874(19) .
O2W H22W 0.87(2) .
N5 Pt1 2.0143(18) .
N6 Pt1 2.0155(19) .
Pt1 N5 2.0143(18) 2_666
Pt1 N6 2.0155(19) 2_666
N1 Ag1 2.114(2) .
N3 Ag1 2.109(2) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2 O1 0.848(18) 2.00(2) 2.831(3) 168(4) 2_557
N4 H4 O3 0.86 2.00 2.812(3) 158.0 2_566
N7 H7 O1W 0.817(16) 2.040(17) 2.851(3) 172(2) 2_666
O1W H11W O2W 0.818(18) 1.956(19) 2.772(5) 175(5) .
O1W H12W O2 0.827(18) 1.963(19) 2.780(3) 169(4) 1_564
O2W H21W O6 0.874(19) 2.04(3) 2.878(5) 159(7) 2_566
O2W H22W O6 0.87(2) 2.09(4) 2.876(4) 150(7) 1_554
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
O2 C2 C3 C5 60.3(4) .
N2 C2 C3 C5 -119.4(3) .
O2 C2 C3 C4 -177.6(3) .
N2 C2 C3 C4 2.7(4) .
O2 C2 C3 C7 -59.2(4) .
N2 C2 C3 C7 121.1(3) .
C2 C3 C4 O3 176.0(2) .
C5 C3 C4 O3 -62.8(4) .
C7 C3 C4 O3 57.0(3) .
C2 C3 C4 N1 -3.0(4) .
C5 C3 C4 N1 118.2(3) .
C7 C3 C4 N1 -122.0(3) .
C2 C3 C5 C6 55.1(4) .
C4 C3 C5 C6 -69.6(4) .
C7 C3 C5 C6 172.8(3) .
C2 C3 C7 C8 -60.8(3) .
C5 C3 C7 C8 -178.7(3) .
C4 C3 C7 C8 62.0(3) .
O5 C10 C11 C12 172.9(3) .
N4 C10 C11 C12 -9.5(4) .
O5 C10 C11 C13 49.2(4) .
N4 C10 C11 C13 -133.1(3) .
O5 C10 C11 C15 -68.8(4) .
N4 C10 C11 C15 108.8(3) .
C10 C11 C12 O6 -172.6(3) .
C13 C11 C12 O6 -50.0(4) .
C15 C11 C12 O6 69.2(3) .
C10 C11 C12 N3 8.7(4) .
C13 C11 C12 N3 131.3(3) .
C15 C11 C12 N3 -109.5(3) .
C10 C11 C13 C14 64.9(4) .
C12 C11 C13 C14 -60.8(4) .
C15 C11 C13 C14 -178.6(3) .
C10 C11 C15 C16 -57.9(4) .
C12 C11 C15 C16 64.6(4) .
C13 C11 C15 C16 -175.4(3) .
O3 C4 N1 C1 -177.8(3) .
C3 C4 N1 C1 1.2(4) .
O3 C4 N1 Ag1 -11.7(4) .
C3 C4 N1 Ag1 167.28(18) .
O1 C1 N1 C4 -179.5(3) .
N2 C1 N1 C4 1.1(5) .
O1 C1 N1 Ag1 13.5(5) .
N2 C1 N1 Ag1 -165.9(3) .
O2 C2 N2 C1 179.6(3) .
C3 C2 N2 C1 -0.7(5) .
O1 C1 N2 C2 179.2(4) .
N1 C1 N2 C2 -1.4(5) .
O6 C12 N3 C9 178.5(3) .
C11 C12 N3 C9 -2.9(4) .
O6 C12 N3 Ag1 -7.8(4) .
C11 C12 N3 Ag1 170.79(19) .
O4 C9 N3 C12 178.7(3) .
N4 C9 N3 C12 -2.3(4) .
O4 C9 N3 Ag1 4.6(3) .
N4 C9 N3 Ag1 -176.43(19) .
O5 C10 N4 C9 -177.0(3) .
C11 C10 N4 C9 5.3(5) .
O4 C9 N4 C10 180.0(3) .
N3 C9 N4 C10 1.0(4) .
N5 C17 C18 C19 -6.6(4) .
N7 C17 C18 C19 172.7(3) .
C17 C18 C19 C20 -0.5(4) .
C18 C19 C20 C21 4.5(5) .
C19 C20 C21 N5 -1.9(5) .
N6 C22 C23 C24 0.0(5) .
C22 C23 C24 C25 -2.7(5) .
C23 C24 C25 C26 1.1(5) .
C24 C25 C26 N6 3.3(4) .
C24 C25 C26 N7 -176.8(3) .
C18 C17 N5 C21 9.1(4) .
N7 C17 N5 C21 -170.2(2) .
C18 C17 N5 Pt1 -165.5(2) .
N7 C17 N5 Pt1 15.2(3) .
C20 C21 N5 C17 -4.8(4) .
C20 C21 N5 Pt1 169.7(2) .
N7 C26 N6 C22 174.1(2) .
C25 C26 N6 C22 -5.9(3) .
N7 C26 N6 Pt1 -8.0(3) .
C25 C26 N6 Pt1 171.98(18) .
C23 C22 N6 C26 4.3(4) .
C23 C22 N6 Pt1 -173.5(2) .
N6 C26 N7 C17 -44.9(3) .
C25 C26 N7 C17 135.2(2) .
N5 C17 N7 C26 40.6(3) .
C18 C17 N7 C26 -138.7(3) .
C17 N5 Pt1 N6 -45.94(19) .
C21 N5 Pt1 N6 139.7(2) .
C17 N5 Pt1 N6 134.06(19) 2_666
C21 N5 Pt1 N6 -40.3(2) 2_666
C26 N6 Pt1 N5 42.10(17) .
C22 N6 Pt1 N5 -140.09(19) .
C26 N6 Pt1 N5 -137.90(17) 2_666
C22 N6 Pt1 N5 39.91(19) 2_666
