#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:42:20 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180050 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/44/7034494.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034494
loop_
_publ_author_name
'Dinca, Alina S.'
'Shova, Sergiu'
'Ion, Adrian E.'
'Maxim, Catalin'
'Lloret, Francesc'
'Julve, Miguel'
'Andruh, Marius'
_publ_section_title
;
 Ascorbic acid decomposition into oxalate ions: a simple synthetic route
 towards oxalato-bridged heterometallic 3d-4f clusters.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7148
_journal_page_last               7151
_journal_paper_doi               10.1039/c5dt00778j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C138 H134 Cu6 Eu6 N12 O60, 2(H2 O)'
_chemical_formula_sum            'C138 H138 Cu6 Eu6 N12 O62'
_chemical_formula_weight         4249.60
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2015-03-15
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_audit_update_record
;
2015-03-19 deposited with the CCDC.
2015-03-20 downloaded from the CCDC.
;
_cell_angle_alpha                116.336(6)
_cell_angle_beta                 100.484(6)
_cell_angle_gamma                93.871(6)
_cell_formula_units_Z            1
_cell_length_a                   15.1982(12)
_cell_length_b                   18.9472(12)
_cell_length_c                   19.5041(13)
_cell_measurement_reflns_used    6513
_cell_measurement_temperature    173.00(14)
_cell_measurement_theta_max      26.0830
_cell_measurement_theta_min      1.6850
_cell_volume                     4879.0(7)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_diffrn_ambient_temperature      173.00(14)
_diffrn_detector_area_resol_mean 16.1593
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_details
;
  1 omega  -25.00   20.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
    -      -13.9352  -99.0000  -60.0000 45

  2 omega  -16.00   22.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
    -      -13.9352  -99.0000   60.0000 38

  3 omega  -18.00   51.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
    -       16.5133  -99.0000  -90.0000 69

  4 omega    6.00   42.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
    -       16.5133  -77.0000  150.0000 36

  5 omega  -43.00   78.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
    -       16.5133    0.0000 -120.0000 121

  6 omega  -49.00   30.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
    -       16.5133  -57.0000   30.0000 79
;
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0210435000
_diffrn_orient_matrix_UB_12      -0.0342474000
_diffrn_orient_matrix_UB_13      -0.0360538000
_diffrn_orient_matrix_UB_21      -0.0427900000
_diffrn_orient_matrix_UB_22      0.0050115000
_diffrn_orient_matrix_UB_23      0.0095243000
_diffrn_orient_matrix_UB_31      -0.0066688000
_diffrn_orient_matrix_UB_32      0.0244465000
_diffrn_orient_matrix_UB_33      -0.0188150000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0711
_diffrn_reflns_av_unetI/netI     0.1670
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            42206
_diffrn_reflns_theta_full        23.26
_diffrn_reflns_theta_max         23.26
_diffrn_reflns_theta_min         2.07
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.611
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.63088
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear dark green'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.446
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2098
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         2.469
_refine_diff_density_min         -1.355
_refine_diff_density_rms         0.182
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1021
_refine_ls_number_reflns         13870
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.1129
_refine_ls_R_factor_gt           0.0766
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1180P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1928
_refine_ls_wR_factor_ref         0.2144
_reflns_number_gt                9061
_reflns_number_total             13870
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt00778j2.cif
_cod_data_source_block           shi_2412_maan
_cod_depositor_comments
'Adding full bibliography for 7034494--7034500.cif.'
_cod_original_cell_volume        4879.0(6)
_cod_database_code               7034494
#BEGIN Tags that were not found in dictionaries:
_chemical_oxdiff_formula         'C100 H100 N12 O65 Cu6 Eu6'
_chemical_oxdiff_usercomment     '_885'
_reflns_odcompleteness_completeness 99.60
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, {H3WA,H3WB} of O3W, {H1WA,H1WB} of O1W, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, {H2WA,H2WB} of O2W
2. Uiso/Uaniso restraints and constraints
Uanis(C4) \\sim Ueq, Uanis(C11) \\sim Ueq, Uanis(C30) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
3. Others
 Fixed Sof: O1W(0.25) H1WA(0.25) H1WB(0.25) O3W(0.25) H3WA(0.25) H3WB(0.25)
 O2W(0.5) H2WA(0.5) H2WB(0.5)
4.a Riding coordinates:
 O1W(H1WA,H1WB), O3W(H3WA,H3WB), O2W(H2WA,H2WB)
4.b Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C10(H10A,H10B), C11(H11A,H11B), C34(H34A,H34B), C35(H35A,H35B),
 C36(H36A,H36B), C53(H53A,H53B)
4.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C8(H8), C12(H12), C14(H14), C15(H15), C16(H16),
 C28(H28), C29(H29), C30(H30), C33(H33), C37(H37), C39(H39), C40(H40), C41(H41),
  C47(H47), C48(H48), C49(H49), C52(H52), C54(H54), C55(H55), C56(H56),
 C58(H58), C59(H59), C60(H60)
4.d Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C19(H19A,H19B,H19C), C26(H26A,H26B,H26C), C44(H44A,H44B,
 H44C), C45(H45A,H45B,H45C), C63(H63A,H63B,H63C), C65(H65A,H65B,H65C), C67(H67A,
 H67B,H67C), C69(H69A,H69B,H69C)
;
_olex2_submission_special_instructions 'No special instructions were received'
#END Tags that were not found in dictionaries
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.8804(11) -0.2144(10) 0.1973(8) 0.062(4) Uani 1 d . . . .
H1A H 0.8352 -0.1813 0.2128 0.093 Uiso 1 calc . . GR .
H1B H 0.8624 -0.2649 0.1953 0.093 Uiso 1 calc . . GR .
H1C H 0.8865 -0.2226 0.1462 0.093 Uiso 1 calc . . GR .
C2 C 0.9649(11) -0.1531(9) 0.3318(8) 0.047(4) Uani 1 d . . . .
C3 C 0.8896(13) -0.1615(10) 0.3586(9) 0.068(5) Uani 1 d . . . .
H3 H 0.8327 -0.1825 0.3240 0.081 Uiso 1 calc . . R .
C4 C 0.8992(14) -0.1387(11) 0.4374(10) 0.075(5) Uani 1 d . . . U
H4 H 0.8477 -0.1418 0.4561 0.090 Uiso 1 calc . . R .
C5 C 0.9847(14) -0.1109(11) 0.4902(9) 0.078(6) Uani 1 d . . . .
H5 H 0.9902 -0.0987 0.5427 0.094 Uiso 1 calc . . R .
C6 C 1.0614(12) -0.1017(10) 0.4631(9) 0.058(4) Uani 1 d . . . .
C7 C 1.0513(12) -0.1225(7) 0.3798(8) 0.047(4) Uani 1 d . . . .
C8 C 1.1485(12) -0.0786(10) 0.5171(8) 0.056(4) Uani 1 d . . . .
H8 H 1.1488 -0.0776 0.5653 0.067 Uiso 1 calc . . R .
C9 C 1.3096(17) -0.0438(15) 0.5699(10) 0.108(8) Uani 1 d . . . .
H9A H 1.2940 -0.0533 0.6114 0.129 Uiso 1 calc . . R .
H9B H 1.3484 -0.0815 0.5457 0.129 Uiso 1 calc . . R .
C10 C 1.3591(13) 0.0348(13) 0.6039(10) 0.082(6) Uani 1 d . . . .
H10A H 1.4091 0.0405 0.6458 0.099 Uiso 1 calc . . R .
H10B H 1.3197 0.0718 0.6282 0.099 Uiso 1 calc . . R .
C11 C 1.3977(12) 0.0608(12) 0.5508(10) 0.082(5) Uani 1 d . . . U
H11A H 1.4348 0.1133 0.5823 0.098 Uiso 1 calc . . R .
H11B H 1.4359 0.0237 0.5243 0.098 Uiso 1 calc . . R .
C12 C 1.3192(12) 0.1324(14) 0.4929(8) 0.077(6) Uani 1 d . . . .
H12 H 1.3601 0.1755 0.5340 0.092 Uiso 1 calc . . R .
C13 C 1.2571(11) 0.1492(11) 0.4360(7) 0.061(5) Uani 1 d . . . .
C14 C 1.2512(12) 0.2267(11) 0.4527(9) 0.074(6) Uani 1 d . . . .
H14 H 1.2807 0.2676 0.5021 0.088 Uiso 1 calc . . R .
C15 C 1.2010(13) 0.2459(10) 0.3960(10) 0.070(5) Uani 1 d . . . .
H15 H 1.1954 0.2983 0.4075 0.084 Uiso 1 calc . . R .
C16 C 1.1604(10) 0.1819(10) 0.3222(8) 0.050(4) Uani 1 d . . . .
H16 H 1.1288 0.1921 0.2829 0.060 Uiso 1 calc . . R .
C17 C 1.1659(9) 0.1066(10) 0.3067(7) 0.045(4) Uani 1 d . . . .
C18 C 1.2092(9) 0.0855(9) 0.3620(7) 0.040(3) Uani 1 d . . . .
C19 C 1.1059(9) 0.0558(7) 0.1681(7) 0.039(3) Uani 1 d . . . .
H19A H 1.0934 0.0063 0.1201 0.059 Uiso 1 calc . . GR .
H19B H 1.1549 0.0907 0.1683 0.059 Uiso 1 calc . . GR .
H19C H 1.0527 0.0806 0.1715 0.059 Uiso 1 calc . . GR .
C20 C 0.9444(10) 0.0071(8) 0.2771(6) 0.035(3) Uani 1 d . . . .
C21 C 0.9208(9) -0.0381(7) 0.1854(7) 0.030(3) Uani 1 d . . . .
C22 C 1.1134(9) -0.1794(8) 0.0546(7) 0.040(3) Uani 1 d . . . .
C23 C 1.0592(9) -0.2443(7) 0.0632(7) 0.031(3) Uani 1 d . . . .
C24 C 0.9262(9) 0.1991(8) 0.1959(7) 0.038(3) Uani 1 d . . . .
C25 C 0.8405(9) 0.2381(7) 0.1956(6) 0.031(3) Uani 1 d . . . .
C26 C 0.9504(10) 0.2406(8) 0.3998(8) 0.049(4) Uani 1 d . . . .
H26A H 0.9829 0.2074 0.3631 0.073 Uiso 1 calc . . GR .
H26B H 0.9686 0.2388 0.4487 0.073 Uiso 1 calc . . GR .
H26C H 0.9639 0.2946 0.4087 0.073 Uiso 1 calc . . GR .
C27 C 0.7954(10) 0.2444(9) 0.4127(8) 0.052(4) Uani 1 d . . . .
C28 C 0.8227(12) 0.3085(11) 0.4863(11) 0.078(5) Uani 1 d . . . .
H28 H 0.8838 0.3312 0.5070 0.094 Uiso 1 calc . . R .
C29 C 0.7568(14) 0.3414(11) 0.5322(10) 0.098(7) Uani 1 d . . . .
H29 H 0.7735 0.3851 0.5821 0.118 Uiso 1 calc . . R .
C30 C 0.6660(14) 0.3029(12) 0.4962(11) 0.088(6) Uani 1 d . . . U
H30 H 0.6208 0.3250 0.5213 0.106 Uiso 1 calc . . R .
C31 C 0.6407(12) 0.2320(9) 0.4237(9) 0.071(5) Uani 1 d . . . .
C32 C 0.7050(9) 0.2036(8) 0.3795(7) 0.044(4) Uani 1 d . . . .
C33 C 0.5482(12) 0.1893(13) 0.4006(9) 0.095(7) Uani 1 d . . . .
H33 H 0.5128 0.2067 0.4373 0.114 Uiso 1 calc . . R .
C34 C 0.4217(11) 0.0903(12) 0.3241(10) 0.083(6) Uani 1 d . . . .
H34A H 0.3888 0.1303 0.3549 0.100 Uiso 1 calc . . R .
H34B H 0.4267 0.0520 0.3443 0.100 Uiso 1 calc . . R .
C35 C 0.3693(11) 0.0479(12) 0.2383(9) 0.080(6) Uani 1 d . . . .
H35A H 0.3965 0.0019 0.2100 0.096 Uiso 1 calc . . R .
H35B H 0.3075 0.0284 0.2358 0.096 Uiso 1 calc . . R .
C36 C 0.3665(11) 0.0989(11) 0.1974(10) 0.070(5) Uani 1 d . . . .
H36A H 0.3159 0.0766 0.1515 0.084 Uiso 1 calc . . R .
H36B H 0.3591 0.1525 0.2326 0.084 Uiso 1 calc . . R .
C37 C 0.4484(11) 0.1016(9) 0.1071(11) 0.064(5) Uani 1 d . . . .
H37 H 0.3915 0.1028 0.0808 0.077 Uiso 1 calc . . R .
C38 C 0.5238(10) 0.1003(7) 0.0690(8) 0.043(4) Uani 1 d . . . .
C39 C 0.5064(11) 0.1091(8) -0.0005(8) 0.052(4) Uani 1 d . . . .
H39 H 0.4495 0.1178 -0.0192 0.063 Uiso 1 calc . . R .
C40 C 0.5701(10) 0.1050(8) -0.0385(7) 0.044(4) Uani 1 d . . . .
H40 H 0.5569 0.1110 -0.0839 0.053 Uiso 1 calc . . R .
C41 C 0.6554(10) 0.0923(8) -0.0143(7) 0.048(4) Uani 1 d . . . .
H41 H 0.6993 0.0905 -0.0423 0.057 Uiso 1 calc . . R .
C42 C 0.6749(9) 0.0821(8) 0.0528(6) 0.037(3) Uani 1 d . . . .
C43 C 0.6096(9) 0.0874(8) 0.0961(7) 0.040(3) Uani 1 d . . . .
C44 C 0.8151(10) 0.0388(8) 0.0278(7) 0.047(4) Uani 1 d . . . .
H44A H 0.8270 0.0800 0.0131 0.070 Uiso 1 calc . . GR .
H44B H 0.7879 -0.0104 -0.0186 0.070 Uiso 1 calc . . GR .
H44C H 0.8711 0.0319 0.0542 0.070 Uiso 1 calc . . GR .
C45 C 0.9271(10) -0.1371(6) -0.0337(7) 0.044(4) Uani 1 d . . . .
H45A H 0.9358 -0.1132 0.0225 0.066 Uiso 1 calc . . GR .
H45B H 0.8748 -0.1216 -0.0556 0.066 Uiso 1 calc . . GR .
H45C H 0.9797 -0.1194 -0.0463 0.066 Uiso 1 calc . . GR .
C46 C 0.8356(11) -0.2558(8) -0.0625(8) 0.047(4) Uani 1 d . . . .
C47 C 0.7712(13) -0.2186(10) -0.0215(10) 0.069(5) Uani 1 d . . . .
H47 H 0.7862 -0.1646 0.0143 0.083 Uiso 1 calc . . R .
C48 C 0.6862(15) -0.2588(10) -0.0316(11) 0.085(6) Uani 1 d . . . .
H48 H 0.6440 -0.2308 -0.0064 0.102 Uiso 1 calc . . R .
C49 C 0.6648(14) -0.3394(11) -0.0789(12) 0.080(6) Uani 1 d . . . .
H49 H 0.6091 -0.3670 -0.0837 0.096 Uiso 1 calc . . R .
C50 C 0.7289(14) -0.3819(10) -0.1215(8) 0.070(5) Uani 1 d . . . .
C51 C 0.8157(11) -0.3361(11) -0.1097(9) 0.056(4) Uani 1 d . . . .
C52 C 0.6964(11) -0.4661(10) -0.1770(9) 0.056(4) Uani 1 d . . . .
H52 H 0.6348 -0.4856 -0.1889 0.067 Uiso 1 calc . . R .
C53 C 0.7052(14) -0.6001(10) -0.2671(10) 0.086(6) Uani 1 d . . . .
H53A H 0.6404 -0.6052 -0.2705 0.103 Uiso 1 calc . . R .
H53B H 0.7135 -0.6108 -0.3188 0.103 Uiso 1 calc . . R .
C54 C 0.7378(16) -0.6595(11) -0.2498(13) 0.096(7) Uani 1 d . . . .
H54 H 0.7010 -0.6909 -0.2371 0.115 Uiso 1 calc . . R .
C55 C 0.8310(15) -0.6698(11) -0.2527(15) 0.112(8) Uani 1 d . . . .
H55 H 0.8468 -0.7165 -0.2881 0.135 Uiso 1 calc . . R .
C56 C 0.9675(14) -0.6019(10) -0.1441(12) 0.072(5) Uani 1 d . . . .
H56 H 0.9637 -0.6510 -0.1440 0.086 Uiso 1 calc . . R .
C57 C 1.0458(12) -0.5452(8) -0.0916(9) 0.055(4) Uani 1 d . . . .
C58 C 1.1047(15) -0.5622(12) -0.0429(11) 0.071(5) Uani 1 d . . . .
H58 H 1.0892 -0.6088 -0.0397 0.085 Uiso 1 calc . . R .
C59 C 1.1835(15) -0.5161(9) 0.0008(11) 0.071(5) Uani 1 d . . . .
H59 H 1.2213 -0.5309 0.0336 0.085 Uiso 1 calc . . R .
C60 C 1.2109(11) -0.4454(9) -0.0016(7) 0.057(4) Uani 1 d . . . .
H60 H 1.2656 -0.4121 0.0297 0.069 Uiso 1 calc . . R .
C61 C 1.1516(11) -0.4269(9) -0.0539(8) 0.050(4) Uani 1 d . . . .
C62 C 1.0652(10) -0.4746(8) -0.0977(8) 0.043(4) Uani 1 d . . . .
C63 C 1.2565(11) -0.3141(12) -0.0269(12) 0.085(6) Uani 1 d . . . .
H63A H 1.2643 -0.2722 -0.0413 0.128 Uiso 1 calc . . GR .
H63B H 1.3028 -0.3465 -0.0402 0.128 Uiso 1 calc . . GR .
H63C H 1.2612 -0.2911 0.0288 0.128 Uiso 1 calc . . GR .
C64 C 1.3135(11) -0.1387(9) 0.2867(8) 0.046(4) Uani 1 d . . . .
C65 C 1.3937(10) -0.1681(10) 0.2522(10) 0.064(5) Uani 1 d . . . .
H65A H 1.3724 -0.2155 0.2027 0.097 Uiso 1 calc . . GR .
H65B H 1.4347 -0.1800 0.2878 0.097 Uiso 1 calc . . GR .
H65C H 1.4247 -0.1274 0.2443 0.097 Uiso 1 calc . . GR .
C66 C 0.6285(12) -0.0600(9) 0.2084(8) 0.048(4) Uani 1 d . . . .
C67 C 0.6150(11) -0.1470(9) 0.1828(9) 0.059(4) Uani 1 d . . . .
H67A H 0.5747 -0.1593 0.2102 0.089 Uiso 1 calc . . GR .
H67B H 0.6724 -0.1625 0.1946 0.089 Uiso 1 calc . . GR .
H67C H 0.5891 -0.1756 0.1271 0.089 Uiso 1 calc . . GR .
C68 C 0.9348(15) -0.4602(11) -0.3158(10) 0.075(6) Uani 1 d . . . .
C69 C 0.9325(19) -0.4750(14) -0.3982(10) 0.151(12) Uani 1 d . . . .
H69A H 0.9390 -0.4250 -0.3996 0.227 Uiso 1 calc . . GR .
H69B H 0.8756 -0.5073 -0.4323 0.227 Uiso 1 calc . . GR .
H69C H 0.9813 -0.5024 -0.4155 0.227 Uiso 1 calc . . GR .
Cu1 Cu 1.23372(13) -0.03349(12) 0.42060(9) 0.0528(5) Uani 1 d . . . .
Cu2 Cu 0.56498(11) 0.09575(10) 0.24093(9) 0.0421(4) Uani 1 d . . . .
Cu3 Cu 0.88274(13) -0.49221(10) -0.18845(11) 0.0526(5) Uani 1 d . . . .
Eu1 Eu 1.10288(5) -0.09757(4) 0.23557(3) 0.0339(2) Uani 1 d . . . .
Eu2 Eu 0.78562(5) 0.08988(4) 0.22605(3) 0.0327(2) Uani 1 d . . . .
Eu3 Eu 1.02977(5) -0.31772(4) -0.12488(4) 0.0387(2) Uani 1 d . . . .
N1 N 1.3219(9) 0.0634(12) 0.4906(7) 0.076(5) Uani 1 d . . . .
N2 N 1.2223(11) -0.0600(9) 0.5078(7) 0.067(4) Uani 1 d . . . .
N3 N 0.5117(9) 0.1284(8) 0.3324(7) 0.061(4) Uani 1 d . . . .
N4 N 0.4541(8) 0.1011(6) 0.1732(7) 0.045(3) Uani 1 d . . . .
N5 N 0.7480(9) -0.5144(7) -0.2099(7) 0.060(4) Uani 1 d . . . .
N6 N 0.9014(12) -0.5961(7) -0.1915(10) 0.080(5) Uani 1 d . . . .
O1 O 1.2105(6) 0.0092(6) 0.3432(4) 0.038(2) Uani 1 d . . . .
O2 O 1.1224(6) -0.1123(5) 0.3539(5) 0.043(2) Uani 1 d . . . .
O3 O 1.1307(6) 0.0404(5) 0.2339(5) 0.041(2) Uani 1 d . . . .
O4 O 0.9661(7) -0.1756(6) 0.2537(5) 0.048(2) Uani 1 d . . . .
O5 O 1.0131(6) -0.0059(5) 0.3116(4) 0.035(2) Uani 1 d . . . .
O6 O 0.9678(6) -0.0897(5) 0.1540(4) 0.034(2) Uani 1 d . . . .
O7 O 0.8950(6) 0.0576(5) 0.3076(5) 0.037(2) Uani 1 d . . . .
O8 O 0.8570(6) -0.0194(5) 0.1509(4) 0.037(2) Uani 1 d . . . .
O9 O 1.1456(6) -0.1172(5) 0.1137(4) 0.031(2) Uani 1 d . . . .
O10 O 1.0572(6) -0.2312(5) 0.1323(5) 0.040(2) Uani 1 d . . . .
O11 O 1.1169(6) -0.1979(5) -0.0166(5) 0.042(2) Uani 1 d . . . .
O12 O 1.0206(7) -0.3072(5) 0.0020(5) 0.046(2) Uani 1 d . . . .
O13 O 0.9254(6) 0.1460(5) 0.2159(5) 0.036(2) Uani 1 d . . . .
O14 O 0.7797(6) 0.2152(5) 0.2170(5) 0.045(2) Uani 1 d . . . .
O15 O 1.1597(6) -0.2907(5) -0.1706(5) 0.045(2) Uani 1 d . . . .
O16 O 1.0086(6) -0.2248(5) -0.1759(5) 0.042(2) Uani 1 d . . . .
O17 O 0.6881(6) 0.1421(5) 0.3118(4) 0.042(2) Uani 1 d . . . .
O18 O 0.6325(6) 0.0768(5) 0.1593(4) 0.038(2) Uani 1 d . . . .
O19 O 0.8549(6) 0.2121(5) 0.3685(5) 0.039(2) Uani 1 d . . . .
O20 O 0.7543(6) 0.0610(6) 0.0795(5) 0.043(2) Uani 1 d . . . .
O21 O 1.0117(6) -0.4529(5) -0.1448(5) 0.045(2) Uani 1 d . . . .
O22 O 0.8750(6) -0.3769(5) -0.1485(5) 0.042(2) Uani 1 d . . . .
O23 O 1.1705(7) -0.3616(6) -0.0677(5) 0.049(3) Uani 1 d . . . .
O24 O 0.9139(7) -0.2221(5) -0.0658(5) 0.048(3) Uani 1 d . . . .
O25 O 1.2388(7) -0.1477(6) 0.2419(5) 0.046(2) Uani 1 d . . . .
O26 O 1.3305(7) -0.1040(7) 0.3626(6) 0.069(3) Uani 1 d . . . .
O27 O 0.7063(7) -0.0267(5) 0.2167(5) 0.046(2) Uani 1 d . . . .
O28 O 0.5602(7) -0.0276(6) 0.2219(5) 0.044(2) Uani 1 d . . . .
O29 O 0.9871(8) -0.3983(5) -0.2621(5) 0.054(3) Uani 1 d . . . .
O30 O 0.8876(8) -0.5103(6) -0.3066(6) 0.069(3) Uani 1 d . . . .
O1W O 0.559(3) -0.404(3) 0.095(2) 0.077(13) Uiso 0.25 d . . . .
H1WA H 0.5099 -0.4312 0.0893 0.092 Uiso 0.25 d . . R .
H1WB H 0.5997 -0.4316 0.0962 0.092 Uiso 0.25 d . . R .
O3W O 0.871(3) -0.395(2) 0.322(2) 0.057(10) Uiso 0.25 d A 2 . .
H3WA H 0.8328 -0.4311 0.2823 0.069 Uiso 0.25 d A 2 R .
H3WB H 0.8448 -0.3555 0.3358 0.069 Uiso 0.25 d A 2 R .
O2W O 0.5564(15) 0.1730(13) 0.5531(12) 0.075(6) Uiso 0.50 d . . . .
H2WA H 0.5708 0.1444 0.5765 0.113 Uiso 0.50 d . . R .
H2WB H 0.5982 0.2134 0.5810 0.113 Uiso 0.50 d . . R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
H1A C1 H1B 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O4 C1 H1A 109.5 . .
O4 C1 H1B 109.5 . .
O4 C1 H1C 109.5 . .
C3 C2 C7 123.5(13) . .
C3 C2 O4 125.7(14) . .
C7 C2 O4 110.8(12) . .
C2 C3 H3 120.4 . .
C2 C3 C4 119.2(17) . .
C4 C3 H3 120.4 . .
C3 C4 H4 119.2 . .
C3 C4 C5 121.5(15) . .
C5 C4 H4 119.2 . .
C4 C5 H5 120.4 . .
C6 C5 C4 119.3(13) . .
C6 C5 H5 120.4 . .
C5 C6 C7 119.5(16) . .
C5 C6 C8 118.0(14) . .
C8 C6 C7 122.3(14) . .
C2 C7 C6 116.9(13) . .
C2 C7 Eu1 85.7(8) . .
C6 C7 Eu1 153.5(11) . .
O2 C7 C2 122.9(12) . .
O2 C7 C6 120.2(15) . .
O2 C7 Eu1 39.9(6) . .
C6 C8 H8 115.9 . .
N2 C8 C6 128.2(14) . .
N2 C8 H8 115.9 . .
H9A C9 H9B 107.6 . .
C10 C9 H9A 108.7 . .
C10 C9 H9B 108.7 . .
C10 C9 N2 114.3(17) . .
N2 C9 H9A 108.7 . .
N2 C9 H9B 108.7 . .
C9 C10 H10A 107.8 . .
C9 C10 H10B 107.8 . .
C9 C10 C11 118.2(16) . .
H10A C10 H10B 107.1 . .
C11 C10 H10A 107.8 . .
C11 C10 H10B 107.8 . .
C10 C11 H11A 109.6 . .
C10 C11 H11B 109.6 . .
H11A C11 H11B 108.1 . .
N1 C11 C10 110.2(14) . .
N1 C11 H11A 109.6 . .
N1 C11 H11B 109.6 . .
C13 C12 H12 117.0 . .
N1 C12 H12 117.0 . .
N1 C12 C13 126.1(17) . .
C14 C13 C12 119.5(16) . .
C14 C13 C18 120.3(15) . .
C18 C13 C12 120.0(17) . .
C13 C14 H14 119.3 . .
C13 C14 C15 121.4(14) . .
C15 C14 H14 119.3 . .
C14 C15 H15 121.7 . .
C16 C15 C14 116.6(15) . .
C16 C15 H15 121.7 . .
C15 C16 H16 119.2 . .
C17 C16 C15 121.6(14) . .
C17 C16 H16 119.2 . .
C16 C17 C18 123.3(13) . .
C16 C17 O3 124.8(12) . .
C18 C17 O3 111.9(13) . .
C17 C18 C13 116.5(14) . .
O1 C18 C13 123.0(13) . .
O1 C18 C17 120.2(12) . .
H19A C19 H19B 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O3 C19 H19A 109.5 . .
O3 C19 H19B 109.5 . .
O3 C19 H19C 109.5 . .
O5 C20 C21 116.8(12) . .
O5 C20 O7 127.1(10) . .
O7 C20 C21 115.8(12) . .
O6 C21 C20 116.8(11) . .
O8 C21 C20 116.6(11) . .
O8 C21 O6 126.6(10) . .
C23 C22 Eu1 75.3(7) . .
C23 C22 Eu3 75.6(7) . .
Eu1 C22 Eu3 148.7(5) . .
O9 C22 C23 117.6(10) . .
O9 C22 Eu1 42.6(6) . .
O9 C22 Eu3 165.7(9) . .
O9 C22 O11 128.2(13) . .
O11 C22 C23 114.2(12) . .
O11 C22 Eu1 168.3(9) . .
O11 C22 Eu3 38.9(6) . .
C22 C23 Eu1 77.1(7) . .
C22 C23 Eu3 77.2(7) . .
Eu1 C23 Eu3 151.8(4) . .
O10 C23 C22 117.1(11) . .
O10 C23 Eu1 41.3(6) . .
O10 C23 Eu3 165.6(8) . .
O12 C23 C22 118.5(10) . .
O12 C23 Eu1 161.9(9) . .
O12 C23 Eu3 41.3(5) . .
O12 C23 O10 124.4(10) . .
C25 C24 Eu2 76.9(7) . .
C25 C24 Eu3 77.2(7) . 2_755
Eu2 C24 Eu3 151.0(5) . 2_755
O13 C24 C25 116.9(11) . .
O13 C24 Eu2 40.8(6) . .
O13 C24 Eu3 165.2(9) . 2_755
O13 C24 O16 125.9(12) . 2_755
O16 C24 C25 117.2(12) 2_755 .
O16 C24 Eu2 164.0(9) 2_755 .
O16 C24 Eu3 40.3(6) 2_755 2_755
C24 C25 Eu2 75.2(7) . .
C24 C25 Eu3 75.2(7) . 2_755
Eu2 C25 Eu3 147.7(4) . 2_755
O14 C25 C24 117.0(11) . .
O14 C25 Eu2 43.0(6) . .
O14 C25 Eu3 167.5(9) . 2_755
O14 C25 O15 126.7(12) . 2_755
O15 C25 C24 116.3(11) 2_755 .
O15 C25 Eu2 164.1(9) 2_755 .
O15 C25 Eu3 41.1(6) 2_755 2_755
H26A C26 H26B 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
O19 C26 H26A 109.5 . .
O19 C26 H26B 109.5 . .
O19 C26 H26C 109.5 . .
C28 C27 C32 123.1(12) . .
O19 C27 C28 121.9(15) . .
O19 C27 C32 114.8(13) . .
C27 C28 H28 119.8 . .
C27 C28 C29 120.3(16) . .
C29 C28 H28 119.8 . .
C28 C29 H29 122.1 . .
C30 C29 C28 115.8(16) . .
C30 C29 H29 122.1 . .
C29 C30 H30 118.6 . .
C29 C30 C31 122.8(16) . .
C31 C30 H30 118.6 . .
C30 C31 C33 117.3(14) . .
C32 C31 C30 119.8(15) . .
C32 C31 C33 122.8(13) . .
C31 C32 C27 117.7(12) . .
O17 C32 C27 117.8(12) . .
O17 C32 C31 124.6(13) . .
C31 C33 H33 117.7 . .
N3 C33 C31 124.6(14) . .
N3 C33 H33 117.7 . .
H34A C34 H34B 108.0 . .
C35 C34 H34A 109.4 . .
C35 C34 H34B 109.4 . .
N3 C34 H34A 109.4 . .
N3 C34 H34B 109.4 . .
N3 C34 C35 111.2(13) . .
C34 C35 H35A 108.6 . .
C34 C35 H35B 108.6 . .
H35A C35 H35B 107.6 . .
C36 C35 C34 114.5(16) . .
C36 C35 H35A 108.6 . .
C36 C35 H35B 108.6 . .
C35 C36 H36A 110.2 . .
C35 C36 H36B 110.2 . .
H36A C36 H36B 108.5 . .
N4 C36 C35 107.7(14) . .
N4 C36 H36A 110.2 . .
N4 C36 H36B 110.2 . .
C38 C37 H37 117.0 . .
N4 C37 H37 117.0 . .
N4 C37 C38 125.9(14) . .
C39 C38 C37 117.9(14) . .
C43 C38 C37 123.0(13) . .
C43 C38 C39 119.0(13) . .
C38 C39 H39 119.8 . .
C40 C39 C38 120.3(13) . .
C40 C39 H39 119.8 . .
C39 C40 H40 118.6 . .
C39 C40 C41 122.9(12) . .
C41 C40 H40 118.6 . .
C40 C41 H41 120.6 . .
C40 C41 C42 118.8(13) . .
C42 C41 H41 120.6 . .
C41 C42 C43 120.4(13) . .
O20 C42 C41 125.1(12) . .
O20 C42 C43 114.3(10) . .
C38 C43 C42 118.6(12) . .
O18 C43 C38 124.1(12) . .
O18 C43 C42 117.3(12) . .
H44A C44 H44B 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
O20 C44 H44A 109.5 . .
O20 C44 H44B 109.5 . .
O20 C44 H44C 109.5 . .
H45A C45 H45B 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
O24 C45 H45A 109.5 . .
O24 C45 H45B 109.5 . .
O24 C45 H45C 109.5 . .
C51 C46 C47 117.8(16) . .
O24 C46 C47 128.6(13) . .
O24 C46 C51 113.5(13) . .
C46 C47 H47 118.4 . .
C48 C47 C46 123.2(16) . .
C48 C47 H47 118.4 . .
C47 C48 H48 120.1 . .
C49 C48 C47 119.8(17) . .
C49 C48 H48 120.1 . .
C48 C49 H49 120.1 . .
C48 C49 C50 119.8(18) . .
C50 C49 H49 120.1 . .
C49 C50 C51 117.5(16) . .
C49 C50 C52 115.9(17) . .
C51 C50 C52 126.4(17) . .
C46 C51 C50 121.7(15) . .
O22 C51 C46 121.7(14) . .
O22 C51 C50 116.6(15) . .
C50 C52 H52 118.3 . .
N5 C52 C50 123.4(16) . .
N5 C52 H52 118.3 . .
H53A C53 H53B 107.3 . .
C54 C53 H53A 108.1 . .
C54 C53 H53B 108.1 . .
C54 C53 N5 116.8(16) . .
N5 C53 H53A 108.1 . .
N5 C53 H53B 108.1 . .
C53 C54 H54 121.3 . .
C53 C54 C55 117.3(19) . .
C55 C54 H54 121.3 . .
C54 C55 H55 123.2 . .
C54 C55 N6 113.7(18) . .
N6 C55 H55 123.2 . .
C57 C56 H56 114.8 . .
N6 C56 H56 114.8 . .
N6 C56 C57 130.5(16) . .
C58 C57 C56 120.6(15) . .
C58 C57 C62 120.6(17) . .
C62 C57 C56 118.4(15) . .
C57 C58 H58 118.3 . .
C59 C58 C57 123.5(16) . .
C59 C58 H58 118.3 . .
C58 C59 H59 119.5 . .
C58 C59 C60 121.0(15) . .
C60 C59 H59 119.5 . .
C59 C60 H60 121.5 . .
C59 C60 C61 116.9(15) . .
C61 C60 H60 121.5 . .
C60 C61 C62 121.7(12) . .
O23 C61 C60 124.7(14) . .
O23 C61 C62 113.6(11) . .
C57 C62 C61 116.1(13) . .
O21 C62 C57 125.2(14) . .
O21 C62 C61 118.6(11) . .
H63A C63 H63B 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
O23 C63 H63A 109.5 . .
O23 C63 H63B 109.5 . .
O23 C63 H63C 109.5 . .
O25 C64 C65 119.7(13) . .
O25 C64 O26 125.3(13) . .
O26 C64 C65 115.0(13) . .
C64 C65 H65A 109.5 . .
C64 C65 H65B 109.5 . .
C64 C65 H65C 109.5 . .
H65A C65 H65B 109.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
O27 C66 C67 117.4(14) . .
O27 C66 O28 127.3(14) . .
O28 C66 C67 115.3(14) . .
C66 C67 H67A 109.5 . .
C66 C67 H67B 109.5 . .
C66 C67 H67C 109.5 . .
H67A C67 H67B 109.5 . .
H67A C67 H67C 109.5 . .
H67B C67 H67C 109.5 . .
O29 C68 C69 115.7(16) . .
O30 C68 C69 117.9(18) . .
O30 C68 O29 126.3(13) . .
C68 C69 H69A 109.5 . .
C68 C69 H69B 109.5 . .
C68 C69 H69C 109.5 . .
H69A C69 H69B 109.5 . .
H69A C69 H69C 109.5 . .
H69B C69 H69C 109.5 . .
N1 Cu1 N2 93.2(6) . .
N1 Cu1 O1 88.3(5) . .
N1 Cu1 O2 165.4(5) . .
N1 Cu1 O26 96.0(5) . .
N2 Cu1 O26 106.0(5) . .
O1 Cu1 N2 161.5(5) . .
O1 Cu1 O26 92.1(4) . .
O2 Cu1 N2 88.9(5) . .
O2 Cu1 O1 85.3(3) . .
O2 Cu1 O26 97.3(4) . .
N3 Cu2 N4 93.2(5) . .
N3 Cu2 O17 90.2(5) . .
N3 Cu2 O18 171.5(5) . .
N3 Cu2 O28 93.4(5) . .
N4 Cu2 O17 152.1(4) . .
N4 Cu2 O28 108.4(4) . .
O17 Cu2 O28 99.0(4) . .
O18 Cu2 N4 91.3(4) . .
O18 Cu2 O17 82.5(3) . .
O18 Cu2 O28 91.9(3) . .
N5 Cu3 Eu3 131.0(4) . .
N5 Cu3 O30 95.7(5) . .
N6 Cu3 Eu3 132.2(5) . .
N6 Cu3 N5 95.4(6) . .
N6 Cu3 O22 161.5(6) . .
N6 Cu3 O30 104.0(6) . .
O21 Cu3 Eu3 42.6(2) . .
O21 Cu3 N5 167.2(5) . .
O21 Cu3 N6 89.7(5) . .
O21 Cu3 O22 83.5(4) . .
O21 Cu3 O30 94.4(4) . .
O22 Cu3 Eu3 43.1(3) . .
O22 Cu3 N5 88.1(5) . .
O22 Cu3 O30 93.6(4) . .
O30 Cu3 Eu3 84.7(3) . .
C22 Eu1 C7 147.1(3) . .
C23 Eu1 C7 119.8(3) . .
C23 Eu1 C22 27.6(3) . .
O1 Eu1 C7 81.2(3) . .
O1 Eu1 C22 126.3(3) . .
O1 Eu1 C23 148.9(3) . .
O1 Eu1 O2 68.2(3) . .
O1 Eu1 O3 61.4(3) . .
O1 Eu1 O4 123.3(3) . .
O1 Eu1 O5 74.7(3) . .
O1 Eu1 O6 128.4(3) . .
O1 Eu1 O9 107.7(3) . .
O2 Eu1 C7 20.4(4) . .
O2 Eu1 C22 145.3(3) . .
O2 Eu1 C23 123.6(3) . .
O2 Eu1 O3 124.2(3) . .
O2 Eu1 O4 61.7(3) . .
O2 Eu1 O5 76.4(3) . .
O2 Eu1 O6 130.2(3) . .
O2 Eu1 O9 152.0(3) . .
O3 Eu1 C7 125.4(3) . .
O3 Eu1 C22 86.7(3) . .
O3 Eu1 C23 111.9(3) . .
O3 Eu1 O4 133.9(3) . .
O4 Eu1 C7 43.9(4) . .
O4 Eu1 C22 110.1(3) . .
O4 Eu1 C23 84.2(3) . .
O5 Eu1 C7 63.5(3) . .
O5 Eu1 C22 135.1(3) . .
O5 Eu1 C23 133.8(3) . .
O5 Eu1 O3 68.9(3) . .
O5 Eu1 O4 69.3(3) . .
O5 Eu1 O9 130.5(2) . .
O6 Eu1 C7 109.9(4) . .
O6 Eu1 C22 69.5(3) . .
O6 Eu1 C23 69.2(3) . .
O6 Eu1 O3 72.7(3) . .
O6 Eu1 O4 73.9(3) . .
O6 Eu1 O5 67.4(3) . .
O6 Eu1 O9 75.1(3) . .
O9 Eu1 C7 164.4(3) . .
O9 Eu1 C22 19.5(3) . .
O9 Eu1 C23 47.0(3) . .
O9 Eu1 O3 70.0(2) . .
O9 Eu1 O4 129.0(3) . .
O10 Eu1 C7 99.4(3) . .
O10 Eu1 C22 47.7(3) . .
O10 Eu1 C23 20.5(2) . .
O10 Eu1 O1 153.2(3) . .
O10 Eu1 O2 103.7(3) . .
O10 Eu1 O3 132.0(2) . .
O10 Eu1 O4 67.4(3) . .
O10 Eu1 O5 129.7(3) . .
O10 Eu1 O6 76.9(3) . .
O10 Eu1 O9 66.8(3) . .
O25 Eu1 C7 94.8(3) . .
O25 Eu1 C22 78.3(3) . .
O25 Eu1 C23 80.6(3) . .
O25 Eu1 O1 74.6(3) . .
O25 Eu1 O2 76.3(3) . .
O25 Eu1 O3 110.0(3) . .
O25 Eu1 O4 115.3(3) . .
O25 Eu1 O5 144.7(3) . .
O25 Eu1 O6 147.6(3) . .
O25 Eu1 O9 75.9(3) . .
O25 Eu1 O10 78.7(3) . .
C24 Eu2 C25 27.9(3) . .
O7 Eu2 C24 96.4(3) . .
O7 Eu2 C25 119.4(3) . .
O7 Eu2 O8 67.4(3) . .
O7 Eu2 O13 78.1(3) . .
O7 Eu2 O14 130.2(3) . .
O7 Eu2 O18 150.5(3) . .
O7 Eu2 O19 66.7(3) . .
O7 Eu2 O20 134.4(3) . .
O8 Eu2 C24 86.0(3) . .
O8 Eu2 C25 108.9(3) . .
O8 Eu2 O14 126.7(3) . .
O8 Eu2 O19 128.1(3) . .
O8 Eu2 O20 69.1(3) . .
O13 Eu2 C24 19.6(3) . .
O13 Eu2 C25 47.3(3) . .
O13 Eu2 O8 72.6(3) . .
O13 Eu2 O14 66.0(3) . .
O13 Eu2 O19 75.4(3) . .
O13 Eu2 O20 76.3(3) . .
O14 Eu2 C24 47.1(3) . .
O14 Eu2 C25 19.6(3) . .
O14 Eu2 O19 71.4(3) . .
O14 Eu2 O20 69.7(3) . .
O17 Eu2 C24 123.2(3) . .
O17 Eu2 C25 101.1(3) . .
O17 Eu2 O7 99.2(3) . .
O17 Eu2 O8 149.9(3) . .
O17 Eu2 O13 133.0(3) . .
O17 Eu2 O14 82.9(3) . .
O17 Eu2 O18 66.3(3) . .
O17 Eu2 O19 61.3(3) . .
O17 Eu2 O20 125.8(3) . .
O18 Eu2 C24 113.0(3) . .
O18 Eu2 C25 89.3(3) . .
O18 Eu2 O8 111.7(3) . .
O18 Eu2 O13 130.8(3) . .
O18 Eu2 O14 75.4(3) . .
O18 Eu2 O19 120.1(3) . .
O18 Eu2 O20 62.0(3) . .
O19 Eu2 C24 76.2(3) . .
O19 Eu2 C25 74.8(3) . .
O20 Eu2 C24 67.2(3) . .
O20 Eu2 C25 63.8(3) . .
O20 Eu2 O19 138.6(3) . .
O27 Eu2 C24 159.1(3) . .
O27 Eu2 C25 162.2(3) . .
O27 Eu2 O7 78.1(3) . .
O27 Eu2 O8 73.3(3) . .
O27 Eu2 O13 143.8(3) . .
O27 Eu2 O14 148.3(3) . .
O27 Eu2 O17 77.7(3) . .
O27 Eu2 O18 73.9(3) . .
O27 Eu2 O19 118.5(3) . .
O27 Eu2 O20 102.2(3) . .
C23 Eu3 C25 119.3(3) . 2_755
C24 Eu3 C23 118.4(3) 2_755 .
C24 Eu3 C25 27.6(3) 2_755 2_755
O11 Eu3 C23 46.9(3) . .
O11 Eu3 C24 73.9(3) . 2_755
O11 Eu3 C25 73.2(3) . 2_755
O11 Eu3 O12 66.8(3) . .
O11 Eu3 O15 75.8(3) . .
O11 Eu3 O16 79.1(3) . .
O11 Eu3 O21 130.7(3) . .
O11 Eu3 O22 129.4(3) . .
O11 Eu3 O23 74.9(3) . .
O11 Eu3 O24 72.8(3) . .
O12 Eu3 C23 20.0(3) . .
O12 Eu3 C24 137.5(3) . 2_755
O12 Eu3 C25 138.2(3) . 2_755
O12 Eu3 O23 70.1(3) . .
O12 Eu3 O24 69.7(3) . .
O15 Eu3 C23 115.9(3) . .
O15 Eu3 C24 48.1(3) . 2_755
O15 Eu3 C25 20.5(3) . 2_755
O15 Eu3 O12 130.3(3) . .
O15 Eu3 O23 69.4(3) . .
O15 Eu3 O24 128.6(3) . .
O16 Eu3 C23 115.6(3) . .
O16 Eu3 C24 20.2(3) . 2_755
O16 Eu3 C25 47.7(3) . 2_755
O16 Eu3 O12 130.6(3) . .
O16 Eu3 O15 68.1(3) . .
O16 Eu3 O21 149.7(3) . .
O16 Eu3 O22 100.9(3) . .
O16 Eu3 O23 134.3(3) . .
O16 Eu3 O24 66.7(3) . .
O21 Eu3 C23 92.9(3) . .
O21 Eu3 C24 146.8(3) . 2_755
O21 Eu3 C25 127.5(3) . 2_755
O21 Eu3 O12 75.0(3) . .
O21 Eu3 O15 109.9(3) . .
O21 Eu3 O22 65.9(3) . .
O21 Eu3 O23 63.3(3) . .
O21 Eu3 O24 121.4(3) . .
O22 Eu3 C23 92.4(3) . .
O22 Eu3 C24 119.6(3) . 2_755
O22 Eu3 C25 141.6(3) . 2_755
O22 Eu3 O12 77.0(3) . .
O22 Eu3 O15 151.7(3) . .
O22 Eu3 O23 124.6(3) . .
O22 Eu3 O24 61.7(3) . .
O23 Eu3 C23 69.9(3) . .
O23 Eu3 C24 114.8(3) . 2_755
O23 Eu3 C25 88.6(3) . 2_755
O23 Eu3 O24 135.7(3) . .
O24 Eu3 C23 65.9(3) . .
O24 Eu3 C24 84.2(3) . 2_755
O24 Eu3 C25 109.8(3) . 2_755
O29 Eu3 C23 165.7(3) . .
O29 Eu3 C24 75.4(3) . 2_755
O29 Eu3 C25 74.5(3) . 2_755
O29 Eu3 O11 147.4(3) . .
O29 Eu3 O12 145.7(3) . .
O29 Eu3 O15 75.7(3) . .
O29 Eu3 O16 75.9(3) . .
O29 Eu3 O21 74.5(3) . .
O29 Eu3 O22 76.4(3) . .
O29 Eu3 O23 109.0(3) . .
O29 Eu3 O24 114.7(3) . .
C11 N1 Cu1 118.8(14) . .
C12 N1 C11 115.6(17) . .
C12 N1 Cu1 125.5(12) . .
C8 N2 C9 120.6(14) . .
C8 N2 Cu1 121.9(11) . .
C9 N2 Cu1 116.8(13) . .
C33 N3 C34 115.7(12) . .
C33 N3 Cu2 123.8(11) . .
C34 N3 Cu2 120.1(10) . .
C36 N4 Cu2 118.1(9) . .
C37 N4 C36 115.5(13) . .
C37 N4 Cu2 126.2(10) . .
C52 N5 C53 118.0(15) . .
C52 N5 Cu3 127.0(11) . .
C53 N5 Cu3 114.8(12) . .
C55 N6 Cu3 116.7(14) . .
C56 N6 C55 121.3(16) . .
C56 N6 Cu3 122.0(13) . .
C18 O1 Cu1 124.7(7) . .
C18 O1 Eu1 123.1(7) . .
Cu1 O1 Eu1 101.7(4) . .
C7 O2 Cu1 124.0(8) . .
C7 O2 Eu1 119.8(8) . .
Cu1 O2 Eu1 101.3(4) . .
C17 O3 C19 116.4(10) . .
C17 O3 Eu1 115.9(7) . .
C19 O3 Eu1 127.4(7) . .
C1 O4 Eu1 126.0(7) . .
C2 O4 C1 115.5(10) . .
C2 O4 Eu1 114.4(9) . .
C20 O5 Eu1 119.4(7) . .
C21 O6 Eu1 118.8(7) . .
C20 O7 Eu2 119.9(7) . .
C21 O8 Eu2 119.5(7) . .
C22 O9 Eu1 117.9(8) . .
C23 O10 Eu1 118.1(7) . .
C22 O11 Eu3 121.3(8) . .
C23 O12 Eu3 118.7(7) . .
C24 O13 Eu2 119.6(8) . .
C25 O14 Eu2 117.4(8) . .
C25 O15 Eu3 118.4(8) 2_755 .
C24 O16 Eu3 119.5(8) 2_755 .
C32 O17 Cu2 124.1(9) . .
C32 O17 Eu2 129.1(8) . .
Cu2 O17 Eu2 103.3(3) . .
C43 O18 Cu2 127.5(8) . .
C43 O18 Eu2 124.0(8) . .
Cu2 O18 Eu2 103.3(3) . .
C26 O19 Eu2 122.8(7) . .
C27 O19 C26 120.5(11) . .
C27 O19 Eu2 116.6(9) . .
C42 O20 C44 115.9(9) . .
C42 O20 Eu2 115.1(6) . .
C44 O20 Eu2 128.1(8) . .
C62 O21 Cu3 124.8(8) . .
C62 O21 Eu3 121.7(8) . .
Cu3 O21 Eu3 104.3(4) . .
C51 O22 Cu3 128.7(9) . .
C51 O22 Eu3 122.6(9) . .
Cu3 O22 Eu3 102.5(4) . .
C61 O23 C63 115.3(11) . .
C61 O23 Eu3 115.2(9) . .
C63 O23 Eu3 126.2(8) . .
C45 O24 Eu3 127.0(8) . .
C46 O24 C45 115.6(11) . .
C46 O24 Eu3 117.4(7) . .
C64 O25 Eu1 143.4(9) . .
C64 O26 Cu1 118.7(9) . .
C66 O27 Eu2 142.4(9) . .
C66 O28 Cu2 118.5(9) . .
C68 O29 Eu3 143.0(9) . .
C68 O30 Cu3 120.8(10) . .
H1WA O1W H1WB 106.3 . .
H3WA O3W H3WB 104.4 . .
H2WA O2W H2WB 98.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C1 O4 1.441(17) .
C2 C3 1.37(2) .
C2 C7 1.38(2) .
C2 O4 1.392(15) .
C3 H3 0.9300 .
C3 C4 1.37(2) .
C4 H4 0.9300 .
C4 C5 1.40(2) .
C5 H5 0.9300 .
C5 C6 1.39(2) .
C6 C7 1.467(18) .
C6 C8 1.43(2) .
C7 Eu1 3.269(12) .
C7 O2 1.310(16) .
C8 H8 0.9300 .
C8 N2 1.223(19) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C9 C10 1.42(3) .
C9 N2 1.53(2) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C10 C11 1.51(2) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C11 N1 1.51(2) .
C12 H12 0.9300 .
C12 C13 1.48(3) .
C12 N1 1.29(2) .
C13 C14 1.37(2) .
C13 C18 1.422(19) .
C14 H14 0.9300 .
C14 C15 1.42(2) .
C15 H15 0.9300 .
C15 C16 1.40(2) .
C16 H16 0.9300 .
C16 C17 1.334(19) .
C17 C18 1.385(18) .
C17 O3 1.388(16) .
C18 O1 1.326(15) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C19 O3 1.431(13) .
C20 C21 1.557(15) .
C20 O5 1.237(15) .
C20 O7 1.261(15) .
C21 O6 1.252(14) .
C21 O8 1.241(14) .
C22 C23 1.522(18) .
C22 Eu1 3.205(13) .
C22 Eu3 3.245(14) .
C22 O9 1.212(15) .
C22 O11 1.285(14) .
C23 Eu1 3.181(12) .
C23 Eu3 3.222(12) .
C23 O10 1.265(13) .
C23 O12 1.256(14) .
C24 C25 1.540(18) .
C24 Eu2 3.182(14) .
C24 Eu3 3.213(15) 2_755
C24 O13 1.228(15) .
C24 O16 1.273(15) 2_755
C25 Eu2 3.206(12) .
C25 Eu3 3.240(12) 2_755
C25 O14 1.209(13) .
C25 O15 1.291(14) 2_755
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C26 O19 1.432(16) .
C27 C28 1.37(2) .
C27 C32 1.411(19) .
C27 O19 1.352(15) .
C28 H28 0.9300 .
C28 C29 1.45(2) .
C29 H29 0.9300 .
C29 C30 1.41(2) .
C30 H30 0.9300 .
C30 C31 1.41(2) .
C31 C32 1.398(19) .
C31 C33 1.46(2) .
C32 O17 1.278(14) .
C33 H33 0.9300 .
C33 N3 1.300(19) .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C34 C35 1.52(2) .
C34 N3 1.449(19) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C35 C36 1.50(2) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C36 N4 1.495(18) .
C37 H37 0.9300 .
C37 C38 1.47(2) .
C37 N4 1.279(19) .
C38 C39 1.419(18) .
C38 C43 1.395(18) .
C39 H39 0.9300 .
C39 C40 1.308(19) .
C40 H40 0.9300 .
C40 C41 1.372(18) .
C41 H41 0.9300 .
C41 C42 1.389(17) .
C42 C43 1.399(18) .
C42 O20 1.381(15) .
C43 O18 1.323(14) .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C44 O20 1.438(14) .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
C45 O24 1.429(13) .
C46 C47 1.40(2) .
C46 C51 1.36(2) .
C46 O24 1.336(17) .
C47 H47 0.9300 .
C47 C48 1.39(2) .
C48 H48 0.9300 .
C48 C49 1.37(2) .
C49 H49 0.9300 .
C49 C50 1.45(2) .
C50 C51 1.45(2) .
C50 C52 1.46(2) .
C51 O22 1.344(17) .
C52 H52 0.9300 .
C52 N5 1.274(18) .
C53 H53A 0.9700 .
C53 H53B 0.9700 .
C53 C54 1.41(2) .
C53 N5 1.514(19) .
C54 H54 0.9300 .
C54 C55 1.45(3) .
C55 H55 0.9300 .
C55 N6 1.54(2) .
C56 H56 0.9300 .
C56 C57 1.42(2) .
C56 N6 1.28(2) .
C57 C58 1.34(2) .
C57 C62 1.411(18) .
C58 H58 0.9300 .
C58 C59 1.32(2) .
C59 H59 0.9300 .
C59 C60 1.40(2) .
C60 H60 0.9300 .
C60 C61 1.414(19) .
C61 C62 1.42(2) .
C61 O23 1.400(15) .
C62 O21 1.336(16) .
C63 H63A 0.9600 .
C63 H63B 0.9600 .
C63 H63C 0.9600 .
C63 O23 1.408(18) .
C64 C65 1.518(18) .
C64 O25 1.250(16) .
C64 O26 1.291(16) .
C65 H65A 0.9600 .
C65 H65B 0.9600 .
C65 H65C 0.9600 .
C66 C67 1.48(2) .
C66 O27 1.250(16) .
C66 O28 1.251(17) .
C67 H67A 0.9600 .
C67 H67B 0.9600 .
C67 H67C 0.9600 .
C68 C69 1.50(2) .
C68 O29 1.26(2) .
C68 O30 1.247(19) .
C69 H69A 0.9600 .
C69 H69B 0.9600 .
C69 H69C 0.9600 .
Cu1 N1 1.952(18) .
Cu1 N2 2.007(12) .
Cu1 O1 1.997(8) .
Cu1 O2 1.980(10) .
Cu1 O26 2.181(10) .
Cu2 N3 1.959(11) .
Cu2 N4 1.983(12) .
Cu2 O17 1.985(9) .
Cu2 O18 1.964(8) .
Cu2 O28 2.191(9) .
Cu3 Eu3 3.4378(18) .
Cu3 N5 1.990(14) .
Cu3 N6 1.984(14) .
Cu3 O21 1.937(10) .
Cu3 O22 1.988(8) .
Cu3 O30 2.191(10) .
Eu1 O1 2.390(9) .
Eu1 O2 2.414(7) .
Eu1 O3 2.635(8) .
Eu1 O4 2.635(9) .
Eu1 O5 2.419(9) .
Eu1 O6 2.414(8) .
Eu1 O9 2.454(7) .
Eu1 O10 2.383(8) .
Eu1 O25 2.338(9) .
Eu2 O7 2.388(8) .
Eu2 O8 2.408(8) .
Eu2 O13 2.391(8) .
Eu2 O14 2.464(8) .
Eu2 O17 2.369(9) .
Eu2 O18 2.388(9) .
Eu2 O19 2.662(8) .
Eu2 O20 2.603(7) .
Eu2 O27 2.359(9) .
Eu3 C24 3.213(15) 2_755
Eu3 C25 3.240(12) 2_755
Eu3 O11 2.385(8) .
Eu3 O12 2.424(8) .
Eu3 O15 2.421(9) .
Eu3 O16 2.389(8) .
Eu3 O21 2.401(8) .
Eu3 O22 2.407(9) .
Eu3 O23 2.590(10) .
Eu3 O24 2.651(9) .
Eu3 O29 2.350(9) .
O15 C25 1.290(14) 2_755
O16 C24 1.273(15) 2_755
O1W H1WA 0.8360 .
O1W H1WB 0.8486 .
O3W H3WA 0.8448 .
O3W H3WB 0.8252 .
O2W H2WA 0.8662 .
O2W H2WB 0.8508 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C2 C3 C4 C5 -3(3) . .
C2 C7 Eu1 C22 -59.5(11) . .
C2 C7 Eu1 C23 -53.5(9) . .
C2 C7 Eu1 O1 151.1(8) . .
C2 C7 Eu1 O2 -160.3(14) . .
C2 C7 Eu1 O3 105.9(8) . .
C2 C7 Eu1 O4 -13.3(7) . .
C2 C7 Eu1 O5 73.8(8) . .
C2 C7 Eu1 O6 23.3(9) . .
C2 C7 Eu1 O9 -82.8(16) . .
C2 C7 Eu1 O10 -56.1(8) . .
C2 C7 Eu1 O25 -135.4(8) . .
C2 C7 O2 Cu1 154.9(10) . .
C2 C7 O2 Eu1 23.7(16) . .
C3 C2 C7 C6 3(2) . .
C3 C2 C7 Eu1 -162.8(14) . .
C3 C2 C7 O2 -177.8(13) . .
C3 C2 O4 C1 -3(2) . .
C3 C2 O4 Eu1 155.7(13) . .
C3 C4 C5 C6 4(3) . .
C4 C5 C6 C7 -1(2) . .
C4 C5 C6 C8 -175.6(16) . .
C5 C6 C7 C2 -2(2) . .
C5 C6 C7 Eu1 143.8(19) . .
C5 C6 C7 O2 178.3(13) . .
C5 C6 C8 N2 -172.3(17) . .
C6 C7 Eu1 C22 151(2) . .
C6 C7 Eu1 C23 157(2) . .
C6 C7 Eu1 O1 1(2) . .
C6 C7 Eu1 O2 50(2) . .
C6 C7 Eu1 O3 -44(2) . .
C6 C7 Eu1 O4 -163(2) . .
C6 C7 Eu1 O5 -76(2) . .
C6 C7 Eu1 O6 -127(2) . .
C6 C7 Eu1 O9 127(2) . .
C6 C7 Eu1 O10 154(2) . .
C6 C7 Eu1 O25 75(2) . .
C6 C7 O2 Cu1 -25.6(16) . .
C6 C7 O2 Eu1 -156.8(9) . .
C6 C8 N2 C9 -174.8(17) . .
C6 C8 N2 Cu1 15(3) . .
C7 C2 C3 C4 0(2) . .
C7 C2 O4 C1 175.2(12) . .
C7 C2 O4 Eu1 -26.0(14) . .
C7 C6 C8 N2 13(3) . .
C7 Eu1 O1 C18 -116.1(9) . .
C7 Eu1 O1 Cu1 29.8(4) . .
C7 Eu1 O2 Cu1 -140.5(10) . .
C7 Eu1 O3 C17 30.4(10) . .
C7 Eu1 O3 C19 -143.3(9) . .
C7 Eu1 O4 C1 170.7(12) . .
C7 Eu1 O4 C2 14.5(8) . .
C7 Eu1 O5 C20 -131.9(10) . .
C7 Eu1 O6 C21 56.1(9) . .
C7 Eu1 O9 C22 40.1(18) . .
C7 Eu1 O10 C23 173.5(9) . .
C7 Eu1 O25 C64 -57.0(15) . .
C8 C6 C7 C2 172.3(14) . .
C8 C6 C7 Eu1 -42(3) . .
C8 C6 C7 O2 -7(2) . .
C9 C10 C11 N1 65(2) . .
C10 C9 N2 C8 -119(2) . .
C10 C9 N2 Cu1 52(2) . .
C10 C11 N1 C12 119.4(18) . .
C10 C11 N1 Cu1 -57.5(18) . .
C12 C13 C14 C15 172.4(14) . .
C12 C13 C18 C17 -168.4(13) . .
C12 C13 C18 O1 6(2) . .
C13 C12 N1 C11 174.1(13) . .
C13 C12 N1 Cu1 -9(2) . .
C13 C14 C15 C16 -2(2) . .
C13 C18 O1 Cu1 25.5(17) . .
C13 C18 O1 Eu1 163.7(10) . .
C14 C13 C18 C17 7(2) . .
C14 C13 C18 O1 -178.4(13) . .
C14 C15 C16 C17 2(2) . .
C15 C16 C17 C18 2(2) . .
C15 C16 C17 O3 -177.2(13) . .
C16 C17 C18 C13 -6(2) . .
C16 C17 C18 O1 178.5(12) . .
C16 C17 O3 C19 15.0(19) . .
C16 C17 O3 Eu1 -159.4(11) . .
C17 C18 O1 Cu1 -159.8(9) . .
C17 C18 O1 Eu1 -21.7(16) . .
C18 C13 C14 C15 -3(2) . .
C18 C17 O3 C19 -164.3(11) . .
C18 C17 O3 Eu1 21.3(13) . .
C20 C21 O6 Eu1 -10.3(13) . .
C20 C21 O8 Eu2 5.1(14) . .
C21 C20 O5 Eu1 0.3(14) . .
C21 C20 O7 Eu2 -7.2(14) . .
C22 C23 Eu1 C7 -172.9(7) . .
C22 C23 Eu1 O1 -45.6(9) . .
C22 C23 Eu1 O2 -149.4(6) . .
C22 C23 Eu1 O3 25.1(7) . .
C22 C23 Eu1 O4 160.3(7) . .
C22 C23 Eu1 O5 106.4(7) . .
C22 C23 Eu1 O6 85.4(7) . .
C22 C23 Eu1 O9 -3.3(6) . .
C22 C23 Eu1 O10 -165.6(13) . .
C22 C23 Eu1 O25 -82.8(7) . .
C22 C23 Eu3 C24 -17.2(8) . 2_755
C22 C23 Eu3 C25 14.4(8) . 2_755
C22 C23 Eu3 O11 3.0(6) . .
C22 C23 Eu3 O12 177.6(14) . .
C22 C23 Eu3 O15 37.2(7) . .
C22 C23 Eu3 O16 -39.7(8) . .
C22 C23 Eu3 O21 151.1(7) . .
C22 C23 Eu3 O22 -143.0(7) . .
C22 C23 Eu3 O23 90.9(7) . .
C22 C23 Eu3 O24 -85.6(7) . .
C22 C23 Eu3 O29 179.0(13) . .
C22 C23 O10 Eu1 15.8(14) . .
C22 C23 O12 Eu3 -2.7(15) . .
C22 Eu1 O1 C18 83.9(9) . .
C22 Eu1 O1 Cu1 -130.1(3) . .
C22 Eu1 O2 C7 -110.2(9) . .
C22 Eu1 O2 Cu1 109.2(6) . .
C22 Eu1 O3 C17 -157.6(8) . .
C22 Eu1 O3 C19 28.8(9) . .
C22 Eu1 O4 C1 -34.0(11) . .
C22 Eu1 O4 C2 169.8(8) . .
C22 Eu1 O5 C20 14.0(11) . .
C22 Eu1 O6 C21 -159.1(9) . .
C22 Eu1 O10 C23 -9.0(8) . .
C22 Eu1 O25 C64 155.5(15) . .
C23 C22 Eu1 C7 11.3(11) . .
C23 C22 Eu1 O1 152.7(6) . .
C23 C22 Eu1 O2 48.2(10) . .
C23 C22 Eu1 O3 -156.8(7) . .
C23 C22 Eu1 O4 -20.9(7) . .
C23 C22 Eu1 O5 -101.4(7) . .
C23 C22 Eu1 O6 -84.0(7) . .
C23 C22 Eu1 O9 172.8(13) . .
C23 C22 Eu1 O10 6.8(6) . .
C23 C22 Eu1 O25 92.0(7) . .
C23 C22 O9 Eu1 -7.9(15) . .
C23 C22 O11 Eu3 7.0(14) . .
C23 Eu1 O1 C18 108.2(9) . .
C23 Eu1 O1 Cu1 -105.9(5) . .
C23 Eu1 O2 C7 -85.8(9) . .
C23 Eu1 O2 Cu1 133.7(4) . .
C23 Eu1 O3 C17 -168.9(8) . .
C23 Eu1 O3 C19 17.4(10) . .
C23 Eu1 O4 C1 -43.6(10) . .
C23 Eu1 O4 C2 160.2(9) . .
C23 Eu1 O5 C20 -25.0(10) . .
C23 Eu1 O6 C21 171.4(9) . .
C23 Eu1 O9 C22 4.6(8) . .
C23 Eu1 O25 C64 -176.5(15) . .
C23 Eu3 O11 C22 -4.1(8) . .
C23 Eu3 O15 C25 -105.0(8) . 2_755
C23 Eu3 O16 C24 103.1(9) . 2_755
C23 Eu3 O21 C62 -42.5(9) . .
C23 Eu3 O21 Cu3 105.7(4) . .
C23 Eu3 O22 C51 48.4(9) . .
C23 Eu3 O22 Cu3 -105.9(3) . .
C23 Eu3 O23 C61 81.6(8) . .
C23 Eu3 O23 C63 -76.6(11) . .
C23 Eu3 O24 C45 86.0(9) . .
C23 Eu3 O24 C46 -91.3(9) . .
C23 Eu3 O29 C68 12(3) . .
C24 C25 Eu2 O7 37.8(7) . .
C24 C25 Eu2 O8 -36.4(7) . .
C24 C25 Eu2 O13 5.2(6) . .
C24 C25 Eu2 O14 166.5(12) . .
C24 C25 Eu2 O17 145.1(6) . .
C24 C25 Eu2 O18 -149.2(6) . .
C24 C25 Eu2 O19 89.3(6) . .
C24 C25 Eu2 O20 -90.3(6) . .
C24 C25 Eu2 O27 -130.5(10) . .
C24 C25 O14 Eu2 -14.7(13) . .
C24 Eu2 O7 C20 -75.9(9) . .
C24 Eu2 O8 C21 92.4(9) . .
C24 Eu2 O14 C25 8.6(8) . .
C24 Eu2 O17 C32 -41.0(12) . .
C24 Eu2 O17 Cu2 118.3(4) . .
C24 Eu2 O18 C43 23.0(9) . .
C24 Eu2 O18 Cu2 -133.2(3) . .
C24 Eu2 O19 C26 -48.1(8) . .
C24 Eu2 O19 C27 135.4(9) . .
C24 Eu2 O20 C42 -112.4(8) . .
C24 Eu2 O20 C44 56.3(10) . .
C24 Eu2 O27 C66 -135.5(14) . .
C24 Eu3 O11 C22 157.4(10) 2_755 .
C24 Eu3 O12 C23 -19.5(12) 2_755 .
C24 Eu3 O15 C25 1.0(7) 2_755 2_755
C24 Eu3 O21 C62 118.5(9) 2_755 .
C24 Eu3 O21 Cu3 -93.3(6) 2_755 .
C24 Eu3 O22 C51 -76.5(9) 2_755 .
C24 Eu3 O22 Cu3 129.2(3) 2_755 .
C24 Eu3 O23 C61 -165.5(8) 2_755 .
C24 Eu3 O23 C63 36.3(12) 2_755 .
C24 Eu3 O24 C45 -38.7(9) 2_755 .
C24 Eu3 O24 C46 144.0(9) 2_755 .
C24 Eu3 O29 C68 -153.4(19) 2_755 .
C25 C24 Eu2 O7 -147.5(6) . .
C25 C24 Eu2 O8 145.8(6) . .
C25 C24 Eu2 O13 -168.5(12) . .
C25 C24 Eu2 O14 -6.1(5) . .
C25 C24 Eu2 O17 -42.1(7) . .
C25 C24 Eu2 O18 33.8(7) . .
C25 C24 Eu2 O19 -83.4(6) . .
C25 C24 Eu2 O20 76.8(6) . .
C25 C24 Eu2 O27 139.3(9) . .
C25 C24 O13 Eu2 12.5(14) . .
C25 Eu2 O7 C20 -92.7(9) . .
C25 Eu2 O8 C21 108.6(9) . .
C25 Eu2 O13 C24 -7.3(8) . .
C25 Eu2 O17 C32 -59.7(11) . .
C25 Eu2 O17 Cu2 99.7(4) . .
C25 Eu2 O18 C43 38.2(9) . .
C25 Eu2 O18 Cu2 -118.1(4) . .
C25 Eu2 O19 C26 -76.9(8) . .
C25 Eu2 O19 C27 106.6(9) . .
C25 Eu2 O20 C42 -81.9(8) . .
C25 Eu2 O20 C44 86.8(10) . .
C25 Eu2 O27 C66 -42(2) . .
C25 Eu3 O11 C22 -173.8(10) 2_755 .
C25 Eu3 O12 C23 22.2(12) 2_755 .
C25 Eu3 O16 C24 -4.3(8) 2_755 2_755
C25 Eu3 O21 C62 88.5(9) 2_755 .
C25 Eu3 O21 Cu3 -123.2(4) 2_755 .
C25 Eu3 O22 C51 -99.0(9) 2_755 .
C25 Eu3 O22 Cu3 106.7(5) 2_755 .
C25 Eu3 O23 C61 -156.4(9) 2_755 .
C25 Eu3 O23 C63 45.4(11) 2_755 .
C25 Eu3 O24 C45 -28.1(10) 2_755 .
C25 Eu3 O24 C46 154.5(8) 2_755 .
C25 Eu3 O29 C68 178.0(19) 2_755 .
C27 C28 C29 C30 0(3) . .
C27 C32 O17 Cu2 -161.0(10) . .
C27 C32 O17 Eu2 -5.5(19) . .
C28 C27 C32 C31 2(2) . .
C28 C27 C32 O17 -176.8(15) . .
C28 C27 O19 C26 5(2) . .
C28 C27 O19 Eu2 -178.6(12) . .
C28 C29 C30 C31 6(3) . .
C29 C30 C31 C32 -9(3) . .
C29 C30 C31 C33 168(2) . .
C30 C31 C32 C27 5(3) . .
C30 C31 C32 O17 -177.0(16) . .
C30 C31 C33 N3 172(2) . .
C31 C32 O17 Cu2 21(2) . .
C31 C32 O17 Eu2 176.2(12) . .
C31 C33 N3 C34 174.8(19) . .
C31 C33 N3 Cu2 -13(3) . .
C32 C27 C28 C29 -4(3) . .
C32 C27 O19 C26 -171.2(11) . .
C32 C27 O19 Eu2 5.4(15) . .
C32 C31 C33 N3 -11(3) . .
C33 C31 C32 C27 -171.7(17) . .
C33 C31 C32 O17 7(3) . .
C34 C35 C36 N4 80.8(17) . .
C35 C34 N3 C33 154.5(18) . .
C35 C34 N3 Cu2 -18(2) . .
C35 C36 N4 C37 143.5(14) . .
C35 C36 N4 Cu2 -32.4(16) . .
C37 C38 C39 C40 -177.1(14) . .
C37 C38 C43 C42 175.8(13) . .
C37 C38 C43 O18 -2(2) . .
C38 C37 N4 C36 -177.3(14) . .
C38 C37 N4 Cu2 -2(2) . .
C38 C39 C40 C41 0(2) . .
C38 C43 O18 Cu2 -12.4(18) . .
C38 C43 O18 Eu2 -162.7(9) . .
C39 C38 C43 C42 -1.1(19) . .
C39 C38 C43 O18 -178.6(12) . .
C39 C40 C41 C42 1(2) . .
C40 C41 C42 C43 -2.1(19) . .
C40 C41 C42 O20 173.2(12) . .
C41 C42 C43 C38 2.2(19) . .
C41 C42 C43 O18 179.8(11) . .
C41 C42 O20 C44 -8.0(18) . .
C41 C42 O20 Eu2 162.1(10) . .
C42 C43 O18 Cu2 170.1(9) . .
C42 C43 O18 Eu2 19.8(15) . .
C43 C38 C39 C40 0(2) . .
C43 C42 O20 C44 167.5(11) . .
C43 C42 O20 Eu2 -22.3(13) . .
C46 C47 C48 C49 5(3) . .
C46 C51 O22 Cu3 156.4(10) . .
C46 C51 O22 Eu3 9.3(17) . .
C47 C46 C51 C50 4(2) . .
C47 C46 C51 O22 -177.1(12) . .
C47 C46 O24 C45 -11(2) . .
C47 C46 O24 Eu3 166.8(12) . .
C47 C48 C49 C50 -3(3) . .
C48 C49 C50 C51 2(2) . .
C48 C49 C50 C52 -173.5(16) . .
C49 C50 C51 C46 -2(2) . .
C49 C50 C51 O22 178.6(12) . .
C49 C50 C52 N5 -169.0(14) . .
C50 C51 O22 Cu3 -24.3(17) . .
C50 C51 O22 Eu3 -171.5(9) . .
C50 C52 N5 C53 -179.3(13) . .
C50 C52 N5 Cu3 6(2) . .
C51 C46 C47 C48 -5(2) . .
C51 C46 O24 C45 164.9(11) . .
C51 C46 O24 Eu3 -17.4(15) . .
C51 C50 C52 N5 16(2) . .
C52 C50 C51 C46 172.8(14) . .
C52 C50 C51 O22 -6(2) . .
C53 C54 C55 N6 63(3) . .
C54 C53 N5 C52 -121(2) . .
C54 C53 N5 Cu3 54(2) . .
C54 C55 N6 C56 127(2) . .
C54 C55 N6 Cu3 -52(2) . .
C56 C57 C58 C59 172.2(17) . .
C56 C57 C62 C61 -169.4(14) . .
C56 C57 C62 O21 6(2) . .
C57 C56 N6 C55 170.1(18) . .
C57 C56 N6 Cu3 -11(3) . .
C57 C58 C59 C60 0(3) . .
C57 C62 O21 Cu3 21.0(18) . .
C57 C62 O21 Eu3 162.6(10) . .
C58 C57 C62 C61 4(2) . .
C58 C57 C62 O21 179.3(13) . .
C58 C59 C60 C61 -1(3) . .
C59 C60 C61 C62 5(2) . .
C59 C60 C61 O23 -175.8(14) . .
C60 C61 C62 C57 -6(2) . .
C60 C61 C62 O21 178.6(13) . .
C60 C61 O23 C63 2(2) . .
C60 C61 O23 Eu3 -158.8(12) . .
C61 C62 O21 Cu3 -163.9(9) . .
C61 C62 O21 Eu3 -22.3(16) . .
C62 C57 C58 C59 -1(3) . .
C62 C61 O23 C63 -178.5(14) . .
C62 C61 O23 Eu3 20.9(14) . .
C65 C64 O25 Eu1 -156.1(11) . .
C65 C64 O26 Cu1 165.0(10) . .
C67 C66 O27 Eu2 162.1(10) . .
C67 C66 O28 Cu2 -170.0(9) . .
C69 C68 O29 Eu3 172.2(16) . .
C69 C68 O30 Cu3 -178.0(16) . .
Eu1 C7 O2 Cu1 131.2(11) . .
Eu1 C22 C23 Eu3 168.3(3) . .
Eu1 C22 C23 O10 -10.6(9) . .
Eu1 C22 C23 O12 170.1(12) . .
Eu1 C22 O11 Eu3 -136(4) . .
Eu1 C23 Eu3 C24 7.5(11) . 2_755
Eu1 C23 Eu3 C25 39.1(11) . 2_755
Eu1 C23 Eu3 O11 27.7(8) . .
Eu1 C23 Eu3 O12 -157.7(17) . .
Eu1 C23 Eu3 O15 61.9(10) . .
Eu1 C23 Eu3 O16 -15.0(11) . .
Eu1 C23 Eu3 O21 175.8(9) . .
Eu1 C23 Eu3 O22 -118.3(9) . .
Eu1 C23 Eu3 O23 115.6(10) . .
Eu1 C23 Eu3 O24 -60.9(9) . .
Eu1 C23 Eu3 O29 -156.3(11) . .
Eu1 C23 O12 Eu3 145(2) . .
Eu2 C24 C25 Eu3 -167.0(3) . 2_755
Eu2 C24 C25 O14 10.3(9) . .
Eu2 C24 C25 O15 -168.2(10) . 2_755
Eu3 C22 C23 Eu1 -168.3(3) . .
Eu3 C22 C23 O10 -179.0(11) . .
Eu3 C22 C23 O12 1.8(10) . .
Eu3 C22 Eu1 C7 33.5(12) . .
Eu3 C22 Eu1 C23 22.2(7) . .
Eu3 C22 Eu1 O1 174.9(7) . .
Eu3 C22 Eu1 O2 70.4(11) . .
Eu3 C22 Eu1 O3 -134.6(8) . .
Eu3 C22 Eu1 O4 1.3(9) . .
Eu3 C22 Eu1 O5 -79.2(9) . .
Eu3 C22 Eu1 O6 -61.8(8) . .
Eu3 C22 Eu1 O9 -165.1(15) . .
Eu3 C22 Eu1 O10 28.9(7) . .
Eu3 C22 Eu1 O25 114.2(8) . .
Eu3 C22 O9 Eu1 147(3) . .
Eu3 C23 Eu1 C7 162.3(9) . .
Eu3 C23 Eu1 C22 -24.7(7) . .
Eu3 C23 Eu1 O1 -70.4(12) . .
Eu3 C23 Eu1 O2 -174.1(8) . .
Eu3 C23 Eu1 O3 0.4(10) . .
Eu3 C23 Eu1 O4 135.6(10) . .
Eu3 C23 Eu1 O5 81.7(10) . .
Eu3 C23 Eu1 O6 60.7(9) . .
Eu3 C23 Eu1 O9 -28.0(8) . .
Eu3 C23 Eu1 O10 169.7(16) . .
Eu3 C23 Eu1 O25 -107.5(10) . .
Eu3 C23 O10 Eu1 -160(3) . .
Eu3 C24 C25 Eu2 167.0(3) 2_755 .
Eu3 C24 C25 O14 177.3(10) 2_755 .
Eu3 C24 C25 O15 -1.2(9) 2_755 2_755
Eu3 C24 Eu2 C25 -27.0(7) 2_755 .
Eu3 C24 Eu2 O7 -174.5(9) 2_755 .
Eu3 C24 Eu2 O8 118.7(9) 2_755 .
Eu3 C24 Eu2 O13 164.4(16) 2_755 .
Eu3 C24 Eu2 O14 -33.2(8) 2_755 .
Eu3 C24 Eu2 O17 -69.1(9) 2_755 .
Eu3 C24 Eu2 O18 6.8(10) 2_755 .
Eu3 C24 Eu2 O19 -110.4(9) 2_755 .
Eu3 C24 Eu2 O20 49.7(8) 2_755 .
Eu3 C24 Eu2 O27 112.3(11) 2_755 .
Eu3 C24 O13 Eu2 -149(3) 2_755 .
Eu3 C25 Eu2 C24 24.1(6) 2_755 .
Eu3 C25 Eu2 O7 62.0(8) 2_755 .
Eu3 C25 Eu2 O8 -12.3(8) 2_755 .
Eu3 C25 Eu2 O13 29.3(6) 2_755 .
Eu3 C25 Eu2 O14 -169.4(14) 2_755 .
Eu3 C25 Eu2 O17 169.2(7) 2_755 .
Eu3 C25 Eu2 O18 -125.0(8) 2_755 .
Eu3 C25 Eu2 O19 113.4(8) 2_755 .
Eu3 C25 Eu2 O20 -66.2(7) 2_755 .
Eu3 C25 Eu2 O27 -106.4(12) 2_755 .
Eu3 C25 O14 Eu2 153(3) 2_755 .
Eu3 Cu3 N5 C52 -29.3(15) . .
Eu3 Cu3 N5 C53 155.9(9) . .
Eu3 Cu3 N6 C55 -155.7(12) . .
Eu3 Cu3 N6 C56 25.5(18) . .
Eu3 Cu3 O21 C62 146.9(11) . .
Eu3 Cu3 O22 C51 -152.1(12) . .
Eu3 Cu3 O30 C68 0.0(13) . .
N1 C12 C13 C14 169.1(16) . .
N1 C12 C13 C18 -16(2) . .
N1 Cu1 N2 C8 132.3(15) . .
N1 Cu1 N2 C9 -38.7(13) . .
N1 Cu1 O1 C18 -37.1(10) . .
N1 Cu1 O1 Eu1 177.8(5) . .
N1 Cu1 O2 C7 -59(2) . .
N1 Cu1 O2 Eu1 79.2(18) . .
N1 Cu1 O26 C64 -127.1(12) . .
N2 C9 C10 C11 -63(2) . .
N2 Cu1 N1 C11 43.5(11) . .
N2 Cu1 N1 C12 -133.1(14) . .
N2 Cu1 O1 C18 58(2) . .
N2 Cu1 O1 Eu1 -87.3(17) . .
N2 Cu1 O2 C7 39.4(10) . .
N2 Cu1 O2 Eu1 177.6(5) . .
N2 Cu1 O26 C64 137.8(11) . .
N3 C34 C35 C36 -52(2) . .
N3 Cu2 N4 C36 -19.4(11) . .
N3 Cu2 N4 C37 165.1(13) . .
N3 Cu2 O17 C32 -32.4(10) . .
N3 Cu2 O17 Eu2 166.9(5) . .
N3 Cu2 O18 C43 -108(3) . .
N3 Cu2 O18 Eu2 47(3) . .
N3 Cu2 O28 C66 -134.7(10) . .
N4 C37 C38 C39 -173.8(14) . .
N4 C37 C38 C43 9(2) . .
N4 Cu2 N3 C33 -124.4(16) . .
N4 Cu2 N3 C34 47.9(14) . .
N4 Cu2 O17 C32 64.8(13) . .
N4 Cu2 O17 Eu2 -95.9(9) . .
N4 Cu2 O18 C43 14.8(10) . .
N4 Cu2 O18 Eu2 169.9(4) . .
N4 Cu2 O28 C66 130.7(9) . .
N5 C53 C54 C55 -66(3) . .
N5 Cu3 N6 C55 37.2(14) . .
N5 Cu3 N6 C56 -141.6(15) . .
N5 Cu3 O21 C62 82(2) . .
N5 Cu3 O21 Eu3 -65.4(19) . .
N5 Cu3 O22 C51 34.1(11) . .
N5 Cu3 O22 Eu3 -173.8(4) . .
N5 Cu3 O30 C68 130.7(14) . .
N6 C56 C57 C58 175.7(18) . .
N6 C56 C57 C62 -11(3) . .
N6 Cu3 N5 C52 138.1(13) . .
N6 Cu3 N5 C53 -36.7(12) . .
N6 Cu3 O21 C62 -31.9(10) . .
N6 Cu3 O21 Eu3 -178.8(5) . .
N6 Cu3 O22 C51 -67(2) . .
N6 Cu3 O22 Eu3 84.8(17) . .
N6 Cu3 O30 C68 -132.3(14) . .
O1 Cu1 N1 C11 -154.9(11) . .
O1 Cu1 N1 C12 28.5(14) . .
O1 Cu1 N2 C8 38(3) . .
O1 Cu1 N2 C9 -132.8(16) . .
O1 Cu1 O2 C7 -123.1(10) . .
O1 Cu1 O2 Eu1 15.2(3) . .
O1 Cu1 O26 C64 -38.6(11) . .
O1 Eu1 O2 C7 127.0(9) . .
O1 Eu1 O2 Cu1 -13.6(3) . .
O1 Eu1 O3 C17 -22.6(8) . .
O1 Eu1 O3 C19 163.7(10) . .
O1 Eu1 O4 C1 152.1(10) . .
O1 Eu1 O4 C2 -4.1(9) . .
O1 Eu1 O5 C20 140.5(9) . .
O1 Eu1 O6 C21 -38.4(9) . .
O1 Eu1 O9 C22 163.1(9) . .
O1 Eu1 O10 C23 -97.4(10) . .
O1 Eu1 O25 C64 22.4(14) . .
O2 C7 Eu1 C22 100.7(11) . .
O2 C7 Eu1 C23 106.7(9) . .
O2 C7 Eu1 O1 -48.7(9) . .
O2 C7 Eu1 O3 -93.9(9) . .
O2 C7 Eu1 O4 147.0(10) . .
O2 C7 Eu1 O5 -126.0(9) . .
O2 C7 Eu1 O6 -176.4(8) . .
O2 C7 Eu1 O9 77.4(17) . .
O2 C7 Eu1 O10 104.1(9) . .
O2 C7 Eu1 O25 24.9(9) . .
O2 Cu1 N1 C11 141.3(17) . .
O2 Cu1 N1 C12 -35(3) . .
O2 Cu1 N2 C8 -33.2(14) . .
O2 Cu1 N2 C9 155.8(13) . .
O2 Cu1 O1 C18 129.8(10) . .
O2 Cu1 O1 Eu1 -15.3(3) . .
O2 Cu1 O26 C64 46.9(11) . .
O2 Eu1 O1 C18 -132.5(9) . .
O2 Eu1 O1 Cu1 13.5(3) . .
O2 Eu1 O3 C17 5.5(9) . .
O2 Eu1 O3 C19 -168.2(9) . .
O2 Eu1 O4 C1 -176.9(11) . .
O2 Eu1 O4 C2 26.9(8) . .
O2 Eu1 O5 C20 -148.8(9) . .
O2 Eu1 O6 C21 54.4(9) . .
O2 Eu1 O9 C22 86.4(11) . .
O2 Eu1 O10 C23 -166.1(9) . .
O2 Eu1 O25 C64 -48.4(14) . .
O3 C17 C18 C13 172.8(11) . .
O3 C17 C18 O1 -2.2(17) . .
O3 Eu1 O1 C18 22.7(8) . .
O3 Eu1 O1 Cu1 168.6(4) . .
O3 Eu1 O2 C7 100.5(9) . .
O3 Eu1 O2 Cu1 -40.1(5) . .
O3 Eu1 O4 C1 71.4(11) . .
O3 Eu1 O4 C2 -84.8(9) . .
O3 Eu1 O5 C20 75.7(9) . .
O3 Eu1 O6 C21 -66.2(8) . .
O3 Eu1 O9 C22 -147.4(9) . .
O3 Eu1 O10 C23 13.4(10) . .
O3 Eu1 O25 C64 73.5(14) . .
O4 C2 C3 C4 178.1(14) . .
O4 C2 C7 C6 -175.7(11) . .
O4 C2 C7 Eu1 18.9(10) . .
O4 C2 C7 O2 3.9(18) . .
O4 Eu1 O1 C18 -103.2(8) . .
O4 Eu1 O1 Cu1 42.7(5) . .
O4 Eu1 O2 C7 -25.4(8) . .
O4 Eu1 O2 Cu1 -165.9(5) . .
O4 Eu1 O3 C17 87.5(9) . .
O4 Eu1 O3 C19 -86.2(10) . .
O4 Eu1 O5 C20 -84.2(9) . .
O4 Eu1 O6 C21 81.6(8) . .
O4 Eu1 O9 C22 -16.6(10) . .
O4 Eu1 O10 C23 142.9(9) . .
O4 Eu1 O25 C64 -97.6(14) . .
O5 C20 C21 O6 6.8(17) . .
O5 C20 C21 O8 -173.4(11) . .
O5 C20 O7 Eu2 166.9(10) . .
O5 Eu1 O1 C18 -51.3(8) . .
O5 Eu1 O1 Cu1 94.6(3) . .
O5 Eu1 O2 C7 48.2(9) . .
O5 Eu1 O2 Cu1 -92.3(4) . .
O5 Eu1 O3 C17 61.0(8) . .
O5 Eu1 O3 C19 -112.7(10) . .
O5 Eu1 O4 C1 97.8(11) . .
O5 Eu1 O4 C2 -58.4(8) . .
O5 Eu1 O6 C21 7.7(8) . .
O5 Eu1 O9 C22 -112.0(9) . .
O5 Eu1 O10 C23 110.3(9) . .
O5 Eu1 O25 C64 -8.0(17) . .
O6 C21 O8 Eu2 -175.1(9) . .
O6 Eu1 O1 C18 -7.7(9) . .
O6 Eu1 O1 Cu1 138.3(3) . .
O6 Eu1 O2 C7 4.4(10) . .
O6 Eu1 O2 Cu1 -136.1(3) . .
O6 Eu1 O3 C17 132.9(8) . .
O6 Eu1 O3 C19 -40.8(9) . .
O6 Eu1 O4 C1 26.4(10) . .
O6 Eu1 O4 C2 -129.8(9) . .
O6 Eu1 O5 C20 -3.7(8) . .
O6 Eu1 O9 C22 -70.7(9) . .
O6 Eu1 O10 C23 65.1(9) . .
O6 Eu1 O25 C64 162.6(13) . .
O7 C20 C21 O6 -178.5(11) . .
O7 C20 C21 O8 1.3(16) . .
O7 C20 O5 Eu1 -173.7(10) . .
O7 Eu2 O8 C21 -6.2(8) . .
O7 Eu2 O13 C24 -158.6(9) . .
O7 Eu2 O14 C25 62.9(9) . .
O7 Eu2 O17 C32 62.9(11) . .
O7 Eu2 O17 Cu2 -137.7(4) . .
O7 Eu2 O18 C43 -154.3(8) . .
O7 Eu2 O18 Cu2 49.5(7) . .
O7 Eu2 O19 C26 55.3(8) . .
O7 Eu2 O19 C27 -121.2(9) . .
O7 Eu2 O20 C42 171.6(7) . .
O7 Eu2 O20 C44 -19.7(11) . .
O7 Eu2 O27 C66 148.0(14) . .
O8 C21 O6 Eu1 169.9(9) . .
O8 Eu2 O7 C20 7.0(9) . .
O8 Eu2 O13 C24 131.6(9) . .
O8 Eu2 O14 C25 -27.3(10) . .
O8 Eu2 O17 C32 123.2(11) . .
O8 Eu2 O17 Cu2 -77.5(6) . .
O8 Eu2 O18 C43 -72.0(9) . .
O8 Eu2 O18 Cu2 131.8(3) . .
O8 Eu2 O19 C26 25.5(9) . .
O8 Eu2 O19 C27 -151.0(8) . .
O8 Eu2 O20 C42 153.0(9) . .
O8 Eu2 O20 C44 -38.3(9) . .
O8 Eu2 O27 C66 -142.2(15) . .
O9 C22 C23 Eu1 5.5(10) . .
O9 C22 C23 Eu3 173.8(12) . .
O9 C22 C23 O10 -5.1(17) . .
O9 C22 C23 O12 175.6(12) . .
O9 C22 Eu1 C7 -161.4(9) . .
O9 C22 Eu1 C23 -172.8(13) . .
O9 C22 Eu1 O1 -20.0(10) . .
O9 C22 Eu1 O2 -124.6(9) . .
O9 C22 Eu1 O3 30.4(9) . .
O9 C22 Eu1 O4 166.4(8) . .
O9 C22 Eu1 O5 85.8(10) . .
O9 C22 Eu1 O6 103.3(9) . .
O9 C22 Eu1 O10 -166.0(11) . .
O9 C22 Eu1 O25 -80.8(9) . .
O9 C22 O11 Eu3 -171.2(11) . .
O9 Eu1 O1 C18 77.0(8) . .
O9 Eu1 O1 Cu1 -137.0(3) . .
O9 Eu1 O2 C7 -146.1(8) . .
O9 Eu1 O2 Cu1 73.4(7) . .
O9 Eu1 O3 C17 -147.2(9) . .
O9 Eu1 O3 C19 39.1(9) . .
O9 Eu1 O4 C1 -28.2(11) . .
O9 Eu1 O4 C2 175.6(8) . .
O9 Eu1 O5 C20 40.0(10) . .
O9 Eu1 O6 C21 -139.4(9) . .
O9 Eu1 O10 C23 -14.0(8) . .
O9 Eu1 O25 C64 135.7(15) . .
O10 C23 Eu1 C7 -7.4(10) . .
O10 C23 Eu1 C22 165.6(13) . .
O10 C23 Eu1 O1 120.0(9) . .
O10 C23 Eu1 O2 16.2(10) . .
O10 C23 Eu1 O3 -169.3(8) . .
O10 C23 Eu1 O4 -34.1(9) . .
O10 C23 Eu1 O5 -88.0(9) . .
O10 C23 Eu1 O6 -109.0(9) . .
O10 C23 Eu1 O9 162.3(10) . .
O10 C23 Eu1 O25 82.8(9) . .
O10 C23 Eu3 C24 159(3) . 2_755
O10 C23 Eu3 C25 -169(3) . 2_755
O10 C23 Eu3 O11 179(4) . .
O10 C23 Eu3 O12 -6(3) . .
O10 C23 Eu3 O15 -146(3) . .
O10 C23 Eu3 O16 137(3) . .
O10 C23 Eu3 O21 -33(3) . .
O10 C23 Eu3 O22 33(3) . .
O10 C23 Eu3 O23 -93(3) . .
O10 C23 Eu3 O24 91(4) . .
O10 C23 Eu3 O29 -5(4) . .
O10 C23 O12 Eu3 178.2(9) . .
O10 Eu1 O1 C18 150.4(8) . .
O10 Eu1 O1 Cu1 -63.6(6) . .
O10 Eu1 O2 C7 -80.0(9) . .
O10 Eu1 O2 Cu1 139.5(3) . .
O10 Eu1 O3 C17 -173.9(8) . .
O10 Eu1 O3 C19 12.4(11) . .
O10 Eu1 O4 C1 -55.9(10) . .
O10 Eu1 O4 C2 147.9(9) . .
O10 Eu1 O5 C20 -52.1(10) . .
O10 Eu1 O6 C21 151.5(9) . .
O10 Eu1 O9 C22 11.2(9) . .
O10 Eu1 O25 C64 -155.7(15) . .
O11 C22 C23 Eu1 -172.8(11) . .
O11 C22 C23 Eu3 -4.5(9) . .
O11 C22 C23 O10 176.5(11) . .
O11 C22 C23 O12 -2.7(17) . .
O11 C22 Eu1 C7 157(4) . .
O11 C22 Eu1 C23 146(5) . .
O11 C22 Eu1 O1 -61(5) . .
O11 C22 Eu1 O2 -166(4) . .
O11 C22 Eu1 O3 -11(5) . .
O11 C22 Eu1 O4 125(5) . .
O11 C22 Eu1 O5 44(5) . .
O11 C22 Eu1 O6 62(5) . .
O11 C22 Eu1 O9 -41(4) . .
O11 C22 Eu1 O10 153(5) . .
O11 C22 Eu1 O25 -122(5) . .
O11 C22 O9 Eu1 170.2(10) . .
O11 Eu3 O12 C23 4.3(9) . .
O11 Eu3 O15 C25 -79.9(8) . 2_755
O11 Eu3 O16 C24 72.8(9) . 2_755
O11 Eu3 O21 C62 -11.8(11) . .
O11 Eu3 O21 Cu3 136.4(4) . .
O11 Eu3 O22 C51 16.5(10) . .
O11 Eu3 O22 Cu3 -137.7(3) . .
O11 Eu3 O23 C61 130.7(9) . .
O11 Eu3 O23 C63 -27.5(11) . .
O11 Eu3 O24 C45 36.2(9) . .
O11 Eu3 O24 C46 -141.1(9) . .
O11 Eu3 O29 C68 -173.6(17) . .
O12 C23 Eu1 C7 36(3) . .
O12 C23 Eu1 C22 -151(3) . .
O12 C23 Eu1 O1 163(2) . .
O12 C23 Eu1 O2 60(3) . .
O12 C23 Eu1 O3 -126(3) . .
O12 C23 Eu1 O4 9(3) . .
O12 C23 Eu1 O5 -44(3) . .
O12 C23 Eu1 O6 -66(3) . .
O12 C23 Eu1 O9 -154(3) . .
O12 C23 Eu1 O10 44(2) . .
O12 C23 Eu1 O25 126(3) . .
O12 C23 Eu3 C24 165.2(9) . 2_755
O12 C23 Eu3 C25 -163.2(9) . 2_755
O12 C23 Eu3 O11 -174.6(11) . .
O12 C23 Eu3 O15 -140.4(9) . .
O12 C23 Eu3 O16 142.7(9) . .
O12 C23 Eu3 O21 -26.5(10) . .
O12 C23 Eu3 O22 39.4(10) . .
O12 C23 Eu3 O23 -86.7(10) . .
O12 C23 Eu3 O24 96.8(10) . .
O12 C23 Eu3 O29 1(2) . .
O12 C23 O10 Eu1 -165.0(10) . .
O12 Eu3 O11 C22 -6.1(9) . .
O12 Eu3 O15 C25 -121.6(8) . 2_755
O12 Eu3 O16 C24 118.9(8) . 2_755
O12 Eu3 O21 C62 -51.6(9) . .
O12 Eu3 O21 Cu3 96.6(4) . .
O12 Eu3 O22 C51 61.2(9) . .
O12 Eu3 O22 Cu3 -93.0(4) . .
O12 Eu3 O23 C61 60.3(8) . .
O12 Eu3 O23 C63 -97.9(12) . .
O12 Eu3 O24 C45 107.3(9) . .
O12 Eu3 O24 C46 -70.1(9) . .
O12 Eu3 O29 C68 13(2) . .
O13 C24 C25 Eu2 -8.4(9) . .
O13 C24 C25 Eu3 -175.3(11) . 2_755
O13 C24 C25 O14 1.9(16) . .
O13 C24 C25 O15 -176.5(10) . 2_755
O13 C24 Eu2 C25 168.5(12) . .
O13 C24 Eu2 O7 21.1(9) . .
O13 C24 Eu2 O8 -45.7(9) . .
O13 C24 Eu2 O14 162.4(10) . .
O13 C24 Eu2 O17 126.5(8) . .
O13 C24 Eu2 O18 -157.6(8) . .
O13 C24 Eu2 O19 85.2(9) . .
O13 C24 Eu2 O20 -114.7(9) . .
O13 C24 Eu2 O27 -52.1(13) . .
O13 Eu2 O7 C20 -68.8(9) . .
O13 Eu2 O8 C21 77.9(9) . .
O13 Eu2 O14 C25 15.0(8) . .
O13 Eu2 O17 C32 -19.4(12) . .
O13 Eu2 O17 Cu2 140.0(3) . .
O13 Eu2 O18 C43 13.3(10) . .
O13 Eu2 O18 Cu2 -142.9(3) . .
O13 Eu2 O19 C26 -27.8(8) . .
O13 Eu2 O19 C27 155.6(9) . .
O13 Eu2 O20 C42 -130.7(8) . .
O13 Eu2 O20 C44 38.0(10) . .
O13 Eu2 O27 C66 -162.1(13) . .
O14 C25 Eu2 C24 -166.5(12) . .
O14 C25 Eu2 O7 -128.6(9) . .
O14 C25 Eu2 O8 157.1(8) . .
O14 C25 Eu2 O13 -161.3(10) . .
O14 C25 Eu2 O17 -21.4(9) . .
O14 C25 Eu2 O18 44.4(9) . .
O14 C25 Eu2 O19 -77.2(9) . .
O14 C25 Eu2 O20 103.2(9) . .
O14 C25 Eu2 O27 63.0(13) . .
O14 Eu2 O7 C20 -112.7(9) . .
O14 Eu2 O8 C21 117.9(8) . .
O14 Eu2 O13 C24 -14.0(8) . .
O14 Eu2 O17 C32 -66.7(11) . .
O14 Eu2 O17 Cu2 92.6(4) . .
O14 Eu2 O18 C43 52.1(9) . .
O14 Eu2 O18 Cu2 -104.1(4) . .
O14 Eu2 O19 C26 -97.0(8) . .
O14 Eu2 O19 C27 86.5(9) . .
O14 Eu2 O20 C42 -61.6(8) . .
O14 Eu2 O20 C44 107.2(10) . .
O14 Eu2 O27 C66 -7.8(17) . .
O15 C25 Eu2 C24 138(3) 2_755 .
O15 C25 Eu2 O7 176(3) 2_755 .
O15 C25 Eu2 O8 102(3) 2_755 .
O15 C25 Eu2 O13 143(3) 2_755 .
O15 C25 Eu2 O14 -56(3) 2_755 .
O15 C25 Eu2 O17 -77(3) 2_755 .
O15 C25 Eu2 O18 -11(3) 2_755 .
O15 C25 Eu2 O19 -133(3) 2_755 .
O15 C25 Eu2 O20 48(3) 2_755 .
O15 C25 Eu2 O27 7(3) 2_755 .
O15 C25 O14 Eu2 163.6(9) 2_755 .
O15 Eu3 O11 C22 -152.6(10) . .
O15 Eu3 O12 C23 48.8(11) . .
O15 Eu3 O16 C24 -6.1(8) . 2_755
O15 Eu3 O21 C62 76.4(9) . .
O15 Eu3 O21 Cu3 -135.4(4) . .
O15 Eu3 O22 C51 -132.1(9) . .
O15 Eu3 O22 Cu3 73.6(6) . .
O15 Eu3 O23 C61 -149.1(9) . .
O15 Eu3 O23 C63 52.7(11) . .
O15 Eu3 O24 C45 -18.7(10) . .
O15 Eu3 O24 C46 164.0(8) . .
O15 Eu3 O29 C68 156.8(19) . .
O16 C24 C25 Eu2 171.9(10) 2_755 .
O16 C24 C25 Eu3 5.0(9) 2_755 2_755
O16 C24 C25 O14 -177.8(10) 2_755 .
O16 C24 C25 O15 3.8(16) 2_755 2_755
O16 C24 Eu2 C25 -153(3) 2_755 .
O16 C24 Eu2 O7 59(3) 2_755 .
O16 C24 Eu2 O8 -7(3) 2_755 .
O16 C24 Eu2 O13 38(3) 2_755 .
O16 C24 Eu2 O14 -159(3) 2_755 .
O16 C24 Eu2 O17 165(3) 2_755 .
O16 C24 Eu2 O18 -119(3) 2_755 .
O16 C24 Eu2 O19 124(3) 2_755 .
O16 C24 Eu2 O20 -76(3) 2_755 .
O16 C24 Eu2 O27 -14(4) 2_755 .
O16 C24 O13 Eu2 -167.8(9) 2_755 .
O16 Eu3 O11 C22 137.4(9) . .
O16 Eu3 O12 C23 -46.0(11) . .
O16 Eu3 O15 C25 3.8(8) . 2_755
O16 Eu3 O21 C62 156.9(9) . .
O16 Eu3 O21 Cu3 -54.9(7) . .
O16 Eu3 O22 C51 -68.3(9) . .
O16 Eu3 O22 Cu3 137.5(3) . .
O16 Eu3 O23 C61 -171.8(8) . .
O16 Eu3 O23 C63 30.0(13) . .
O16 Eu3 O24 C45 -49.0(9) . .
O16 Eu3 O24 C46 133.6(9) . .
O16 Eu3 O29 C68 -132.6(19) . .
O17 Cu2 N3 C33 27.8(16) . .
O17 Cu2 N3 C34 -159.8(13) . .
O17 Cu2 N4 C36 -115.9(12) . .
O17 Cu2 N4 C37 68.6(16) . .
O17 Cu2 O18 C43 -137.8(10) . .
O17 Cu2 O18 Eu2 17.2(4) . .
O17 Cu2 O28 C66 -44.0(10) . .
O17 Eu2 O7 C20 158.9(9) . .
O17 Eu2 O8 C21 -74.4(11) . .
O17 Eu2 O13 C24 -67.1(9) . .
O17 Eu2 O14 C25 158.9(9) . .
O17 Eu2 O18 C43 140.6(9) . .
O17 Eu2 O18 Cu2 -15.6(3) . .
O17 Eu2 O19 C26 171.0(9) . .
O17 Eu2 O19 C27 -5.5(8) . .
O17 Eu2 O20 C42 3.0(9) . .
O17 Eu2 O20 C44 171.7(9) . .
O17 Eu2 O27 C66 45.7(14) . .
O18 Cu2 N3 C33 -2(4) . .
O18 Cu2 N3 C34 170(3) . .
O18 Cu2 N4 C36 167.7(10) . .
O18 Cu2 N4 C37 -7.7(12) . .
O18 Cu2 O17 C32 143.3(10) . .
O18 Cu2 O17 Eu2 -17.4(3) . .
O18 Cu2 O28 C66 38.6(9) . .
O18 Eu2 O7 C20 101.6(10) . .
O18 Eu2 O8 C21 -154.4(8) . .
O18 Eu2 O13 C24 27.6(10) . .
O18 Eu2 O14 C25 -133.8(9) . .
O18 Eu2 O17 C32 -143.9(11) . .
O18 Eu2 O17 Cu2 15.4(3) . .
O18 Eu2 O19 C26 -156.9(8) . .
O18 Eu2 O19 C27 26.6(9) . .
O18 Eu2 O20 C42 22.3(7) . .
O18 Eu2 O20 C44 -169.0(11) . .
O18 Eu2 O27 C66 -22.9(14) . .
O19 C27 C28 C29 -179.9(16) . .
O19 C27 C32 C31 177.5(14) . .
O19 C27 C32 O17 -0.9(19) . .
O19 Eu2 O7 C20 -147.9(9) . .
O19 Eu2 O8 C21 23.4(10) . .
O19 Eu2 O13 C24 -89.8(9) . .
O19 Eu2 O14 C25 96.9(9) . .
O19 Eu2 O17 C32 5.9(10) . .
O19 Eu2 O17 Cu2 165.3(5) . .
O19 Eu2 O18 C43 110.0(9) . .
O19 Eu2 O18 Cu2 -46.2(4) . .
O19 Eu2 O20 C42 -82.5(9) . .
O19 Eu2 O20 C44 86.2(10) . .
O19 Eu2 O27 C66 93.0(14) . .
O20 C42 C43 C38 -173.6(11) . .
O20 C42 C43 O18 4.0(17) . .
O20 Eu2 O7 C20 -11.8(11) . .
O20 Eu2 O8 C21 159.5(9) . .
O20 Eu2 O13 C24 59.5(9) . .
O20 Eu2 O14 C25 -68.7(8) . .
O20 Eu2 O17 C32 -125.3(11) . .
O20 Eu2 O17 Cu2 34.1(5) . .
O20 Eu2 O18 C43 -22.3(8) . .
O20 Eu2 O18 Cu2 -178.5(5) . .
O20 Eu2 O19 C26 -76.3(9) . .
O20 Eu2 O19 C27 107.2(9) . .
O20 Eu2 O27 C66 -78.7(14) . .
O21 Cu3 N5 C52 25(3) . .
O21 Cu3 N5 C53 -149.6(16) . .
O21 Cu3 N6 C55 -154.6(14) . .
O21 Cu3 N6 C56 26.7(15) . .
O21 Cu3 O22 C51 -136.3(11) . .
O21 Cu3 O22 Eu3 15.8(3) . .
O21 Cu3 O30 C68 -41.5(14) . .
O21 Eu3 O11 C22 -48.4(10) . .
O21 Eu3 O12 C23 152.5(10) . .
O21 Eu3 O15 C25 151.4(8) . 2_755
O21 Eu3 O16 C24 -98.5(10) . 2_755
O21 Eu3 O22 C51 140.4(9) . .
O21 Eu3 O22 Cu3 -13.9(3) . .
O21 Eu3 O23 C61 -22.5(8) . .
O21 Eu3 O23 C63 179.3(12) . .
O21 Eu3 O24 C45 163.9(9) . .
O21 Eu3 O24 C46 -13.4(10) . .
O21 Eu3 O29 C68 40.9(18) . .
O22 Cu3 N5 C52 -23.7(12) . .
O22 Cu3 N5 C53 161.5(10) . .
O22 Cu3 N6 C55 137.4(17) . .
O22 Cu3 N6 C56 -41(3) . .
O22 Cu3 O21 C62 130.9(10) . .
O22 Cu3 O21 Eu3 -16.0(3) . .
O22 Cu3 O30 C68 42.2(14) . .
O22 Eu3 O11 C22 42.1(10) . .
O22 Eu3 O12 C23 -139.4(10) . .
O22 Eu3 O15 C25 75.6(10) . 2_755
O22 Eu3 O16 C24 -158.8(8) . 2_755
O22 Eu3 O21 C62 -133.9(10) . .
O22 Eu3 O21 Cu3 14.3(3) . .
O22 Eu3 O23 C61 3.0(9) . .
O22 Eu3 O23 C63 -155.2(11) . .
O22 Eu3 O24 C45 -166.9(10) . .
O22 Eu3 O24 C46 15.8(8) . .
O22 Eu3 O29 C68 -27.4(18) . .
O23 C61 C62 C57 174.5(12) . .
O23 C61 C62 O21 -1.1(18) . .
O23 Eu3 O11 C22 -80.6(9) . .
O23 Eu3 O12 C23 85.9(10) . .
O23 Eu3 O15 C25 -158.9(9) . 2_755
O23 Eu3 O16 C24 16.8(10) . 2_755
O23 Eu3 O21 C62 23.3(9) . .
O23 Eu3 O21 Cu3 171.5(5) . .
O23 Eu3 O22 C51 115.6(9) . .
O23 Eu3 O22 Cu3 -38.7(5) . .
O23 Eu3 O24 C45 81.3(10) . .
O23 Eu3 O24 C46 -96.0(9) . .
O23 Eu3 O29 C68 94.9(19) . .
O24 C46 C47 C48 170.3(16) . .
O24 C46 C51 C50 -172.6(12) . .
O24 C46 C51 O22 6.6(19) . .
O24 Eu3 O11 C22 68.6(9) . .
O24 Eu3 O12 C23 -75.1(10) . .
O24 Eu3 O15 C25 -26.2(10) . 2_755
O24 Eu3 O16 C24 148.7(9) . 2_755
O24 Eu3 O21 C62 -105.8(9) . .
O24 Eu3 O21 Cu3 42.4(5) . .
O24 Eu3 O22 C51 -12.4(8) . .
O24 Eu3 O22 Cu3 -166.7(4) . .
O24 Eu3 O23 C61 86.2(9) . .
O24 Eu3 O23 C63 -72.0(12) . .
O24 Eu3 O29 C68 -77.0(19) . .
O25 C64 O26 Cu1 -14(2) . .
O25 Eu1 O1 C18 146.3(9) . .
O25 Eu1 O1 Cu1 -67.7(4) . .
O25 Eu1 O2 C7 -154.5(9) . .
O25 Eu1 O2 Cu1 65.0(4) . .
O25 Eu1 O3 C17 -81.2(8) . .
O25 Eu1 O3 C19 105.1(9) . .
O25 Eu1 O4 C1 -120.3(10) . .
O25 Eu1 O4 C2 83.5(9) . .
O25 Eu1 O5 C20 170.8(8) . .
O25 Eu1 O6 C21 -166.5(8) . .
O25 Eu1 O9 C22 94.8(9) . .
O25 Eu1 O10 C23 -93.4(9) . .
O26 C64 O25 Eu1 22(2) . .
O26 Cu1 N1 C11 -63.0(11) . .
O26 Cu1 N1 C12 120.4(14) . .
O26 Cu1 N2 C8 -130.5(14) . .
O26 Cu1 N2 C9 58.6(13) . .
O26 Cu1 O1 C18 -133.1(10) . .
O26 Cu1 O1 Eu1 81.8(4) . .
O26 Cu1 O2 C7 145.4(9) . .
O26 Cu1 O2 Eu1 -76.4(4) . .
O27 C66 O28 Cu2 12.4(18) . .
O27 Eu2 O7 C20 83.7(9) . .
O27 Eu2 O8 C21 -90.0(9) . .
O27 Eu2 O13 C24 151.6(8) . .
O27 Eu2 O14 C25 -148.8(8) . .
O27 Eu2 O17 C32 138.5(11) . .
O27 Eu2 O17 Cu2 -62.2(4) . .
O27 Eu2 O18 C43 -136.0(9) . .
O27 Eu2 O18 Cu2 67.8(4) . .
O27 Eu2 O19 C26 116.0(8) . .
O27 Eu2 O19 C27 -60.5(9) . .
O27 Eu2 O20 C42 86.5(8) . .
O27 Eu2 O20 C44 -104.8(10) . .
O28 C66 O27 Eu2 -20(2) . .
O28 Cu2 N3 C33 126.9(16) . .
O28 Cu2 N3 C34 -60.8(14) . .
O28 Cu2 N4 C36 75.2(11) . .
O28 Cu2 N4 C37 -100.2(12) . .
O28 Cu2 O17 C32 -125.9(10) . .
O28 Cu2 O17 Eu2 73.4(4) . .
O28 Cu2 O18 C43 123.3(10) . .
O28 Cu2 O18 Eu2 -81.6(4) . .
O29 C68 O30 Cu3 4(3) . .
O29 Eu3 O11 C22 177.7(9) . .
O29 Eu3 O12 C23 -179.4(9) . .
O29 Eu3 O15 C25 84.1(8) . 2_755
O29 Eu3 O16 C24 -86.1(9) . 2_755
O29 Eu3 O21 C62 144.4(10) . .
O29 Eu3 O21 Cu3 -67.4(4) . .
O29 Eu3 O22 C51 -140.6(9) . .
O29 Eu3 O22 Cu3 65.1(4) . .
O29 Eu3 O23 C61 -83.2(9) . .
O29 Eu3 O23 C63 118.6(11) . .
O29 Eu3 O24 C45 -109.7(9) . .
O29 Eu3 O24 C46 73.0(9) . .
O30 C68 O29 Eu3 -10(3) . .
O30 Cu3 N5 C52 -117.2(13) . .
O30 Cu3 N5 C53 68.0(11) . .
O30 Cu3 N6 C55 -60.1(14) . .
O30 Cu3 N6 C56 121.2(15) . .
O30 Cu3 O21 C62 -135.9(9) . .
O30 Cu3 O21 Eu3 77.2(4) . .
O30 Cu3 O22 C51 129.7(11) . .
O30 Cu3 O22 Eu3 -78.2(4) . .
#BEGIN Loops that were not found in dictionaries:
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
1 -0.045 0.296 0.624 21.8 0.0
2 0.500 0.500 -0.275 1304.1 381.6
3 0.045 0.704 0.376 21.8 0.0
#END Loops that were not found in dictionaries
