#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/44/7034497.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034497
loop_
_publ_author_name
'Dinca, Alina S.'
'Shova, Sergiu'
'Ion, Adrian E.'
'Maxim, Catalin'
'Lloret, Francesc'
'Julve, Miguel'
'Andruh, Marius'
_publ_section_title
;
 Ascorbic acid decomposition into oxalate ions: a simple synthetic route
 towards oxalato-bridged heterometallic 3d-4f clusters.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7148
_journal_page_last               7151
_journal_paper_doi               10.1039/c5dt00778j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C138 H138 Eu6 N12 O60 Zn6'
_chemical_formula_sum            'C141 H165.6 Eu6 N13 O71.3 Zn6'
_chemical_formula_weight         4487.25
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2015-03-16
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_audit_update_record
;
2015-03-19 deposited with the CCDC.
2015-03-20 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 91.157(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   15.3521(11)
_cell_length_b                   26.8468(17)
_cell_length_c                   24.981(2)
_cell_measurement_reflns_used    3494
_cell_measurement_temperature    173.00(14)
_cell_measurement_theta_max      18.4030
_cell_measurement_theta_min      1.5300
_cell_volume                     10293.9(13)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_diffrn_ambient_temperature      173.00(14)
_diffrn_detector_area_resol_mean 16.1593
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_details
;
  1 omega  -23.00   25.00   1.0000  160.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1690  -99.0000  -30.0000 48

  2 omega  -53.00   34.00   1.0000  160.0000
omega____ theta____ kappa____ phi______ frames
    -       19.6690  -38.0000   30.0000 87

  3 omega  -49.00  -13.00   1.0000  160.0000
omega____ theta____ kappa____ phi______ frames
    -       19.6690  -57.0000  150.0000 36

  4 omega   12.00   38.00   1.0000  160.0000
omega____ theta____ kappa____ phi______ frames
    -       19.6690  -57.0000  150.0000 26

  5 omega   -6.00   23.00   1.0000  160.0000
omega____ theta____ kappa____ phi______ frames
    -       19.6690  102.0000  174.0838 29
;
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0339840000
_diffrn_orient_matrix_UB_12      0.0178737000
_diffrn_orient_matrix_UB_13      0.0005802000
_diffrn_orient_matrix_UB_21      0.0090451000
_diffrn_orient_matrix_UB_22      -0.0054102000
_diffrn_orient_matrix_UB_23      -0.0271291000
_diffrn_orient_matrix_UB_31      -0.0299813000
_diffrn_orient_matrix_UB_32      0.0186929000
_diffrn_orient_matrix_UB_33      -0.0083673000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1549
_diffrn_reflns_av_unetI/netI     0.3470
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            47068
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.56
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.562
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.66048
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.448
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4462
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.035
_refine_diff_density_min         -1.132
_refine_diff_density_rms         0.123
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.824
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     927
_refine_ls_number_reflns         20931
_refine_ls_number_restraints     58
_refine_ls_restrained_S_all      0.824
_refine_ls_R_factor_all          0.2110
_refine_ls_R_factor_gt           0.0864
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0083P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1145
_refine_ls_wR_factor_ref         0.1376
_reflns_number_gt                6731
_reflns_number_total             20931
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt00778j2.cif
_cod_data_source_block           shi_2428_maan
_cod_depositor_comments
'Adding full bibliography for 7034494--7034500.cif.'
_cod_original_cell_volume        10293.7(13)
_cod_original_formula_sum        'C141 H165.60 Eu6 N13 O71.30 Zn6'
_cod_database_code               7034497
#BEGIN Tags that were not found in dictionaries:
_chemical_oxdiff_formula         'C100 H40 N4 O30 Zn6 Eu6'
_chemical_oxdiff_usercomment     Zn_Eu
_reflns_odcompleteness_completeness 99.93
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 H8-H9A
 2 with sigma of 0.01
 O25-C64 \\sim O26-C64 \\sim O29-C68 \\sim O30-C68 \\sim O28-C66 \\sim O27-C66
 with sigma of 0.01
 C67-C66 \\sim C69-C68 \\sim C65-C64
 with sigma of 0.01
 C11-C10 \\sim C9-C10
 with sigma of 0.01
 N2-C11 \\sim N1-C9
 with sigma of 0.01
 C13-C12 \\sim C8-C6
 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
C8 \\sim C9 \\sim C10 \\sim C11 \\sim N1: within 1.7A with sigma of 0.04 and
sigma for terminal atoms of 0.08
Uanis(C20) \\sim Ueq, Uanis(O12) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
4.a Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C10(H10A,H10B), C11(H11A,H11B), C34(H34A,H34B), C35(H35A,H35B),
 C36(H36A,H36B), C53(H53A,H53B), C54(H54A,H54B), C55(H55A,H55B)
4.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C8(H8), C12(H12), C14(H14), C15(H15), C16(H16),
 C30(H30), C29(H29), C28(H28), C33(H33), C37(H37), C41(H41), C40(H40), C39(H39),
  C47(H47), C48(H48), C49(H49), C52(H52), C56(H56), C58(H58), C59(H59), C60(H60)
4.c Fitted hexagon refined as free rotating group:
 C6(C7,C2,C3,C4,C5), C14(C15,C16,C17,C18,C13), C30(C29,C28,C27,C32,C31),
 C38(C43,C42,C41,C40,C39), C51(C46,C47,C48,C49,C50), C62(C57,C58,C59,C60,C61)
4.d Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C19(H19A,H19B,H19C), C26(H26A,H26B,H26C), C44(H44A,H44B,
 H44C), C45(H45A,H45B,H45C), C63(H63A,H63B,H63C), C65(H65A,H65B,H65C), C67(H67A,
 H67B,H67C), C69(H69A,H69B,H69C)
;
_olex2_submission_special_instructions 'No special instructions were received'
#END Tags that were not found in dictionaries
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x+1/2, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 1.0805(6) 0.5386(3) 0.4072(4) 0.060(3) Uani 1 d . .
H1A H 1.1122 0.5570 0.4342 0.091 Uiso 1 calc GR .
H1B H 1.1095 0.5075 0.4008 0.091 Uiso 1 calc GR .
H1C H 1.0225 0.5322 0.4192 0.091 Uiso 1 calc GR .
C6 C 1.2237(8) 0.6299(3) 0.2717(3) 0.082(5) Uani 1 d D .
C7 C 1.1491(5) 0.6150(3) 0.2979(4) 0.076(5) Uani 1 d G .
C2 C 1.1529(6) 0.5757(3) 0.3341(3) 0.073(4) Uani 1 d G .
C3 C 1.2313(9) 0.5513(3) 0.3441(3) 0.086(5) Uani 1 d G .
H3 H 1.2339 0.5250 0.3684 0.104 Uiso 1 calc R .
C4 C 1.3060(6) 0.5661(4) 0.3179(4) 0.105(5) Uani 1 d G .
H4 H 1.3585 0.5498 0.3246 0.126 Uiso 1 calc R .
C5 C 1.3022(6) 0.6054(4) 0.2817(4) 0.095(5) Uani 1 d G .
H5 H 1.3522 0.6154 0.2642 0.114 Uiso 1 calc R .
C8 C 1.2291(10) 0.6728(4) 0.2313(5) 0.090(5) Uani 1 d D U
H8 H 1.2836 0.6833 0.2203 0.108 Uiso 1 calc DR .
C9 C 1.1862(10) 0.7397(4) 0.1794(6) 0.121(6) Uani 1 d D U
H9A H 1.2491 0.7431 0.1797 0.146 Uiso 1 calc DR .
H9B H 1.1614 0.7698 0.1942 0.146 Uiso 1 calc R .
C10 C 1.1516(10) 0.7313(5) 0.1220(6) 0.124(6) Uani 1 d D U
H10A H 1.1663 0.6978 0.1108 0.148 Uiso 1 calc R .
H10B H 1.1799 0.7544 0.0982 0.148 Uiso 1 calc R .
C11 C 1.0521(11) 0.7384(5) 0.1171(7) 0.174(9) Uani 1 d D U
H11A H 1.0351 0.7689 0.1348 0.209 Uiso 1 calc R .
H11B H 1.0344 0.7406 0.0796 0.209 Uiso 1 calc R .
C12 C 0.9463(8) 0.6754(5) 0.1138(7) 0.103(6) Uani 1 d D .
H12 H 0.9350 0.6901 0.0807 0.124 Uiso 1 calc R .
C14 C 0.8369(7) 0.6110(4) 0.0882(3) 0.107(5) Uani 1 d . .
H14 H 0.8422 0.6218 0.0530 0.129 Uiso 1 calc R .
C15 C 0.7766(6) 0.5743(3) 0.1005(4) 0.110(6) Uani 1 d G .
H15 H 0.7417 0.5605 0.0736 0.132 Uiso 1 calc R .
C16 C 0.7687(5) 0.5583(3) 0.1531(4) 0.094(5) Uani 1 d G .
H16 H 0.7284 0.5338 0.1613 0.112 Uiso 1 calc R .
C17 C 0.8210(6) 0.5790(3) 0.1934(3) 0.086(5) Uani 1 d G .
C18 C 0.8812(5) 0.6157(3) 0.1811(3) 0.060(4) Uani 1 d G .
C13 C 0.8892(5) 0.6317(3) 0.1285(4) 0.069(4) Uani 1 d DG .
C19 C 0.7450(7) 0.5342(3) 0.2605(4) 0.070(4) Uani 1 d . .
H19A H 0.7614 0.5005 0.2527 0.105 Uiso 1 calc GR .
H19B H 0.6926 0.5424 0.2409 0.105 Uiso 1 calc GR .
H19C H 0.7351 0.5374 0.2982 0.105 Uiso 1 calc GR .
C20 C 0.9935(7) 0.4908(4) 0.2728(4) 0.051(3) Uani 1 d . U
C21 C 0.9306(7) 0.4817(5) 0.3215(4) 0.046(3) Uani 1 d . .
C22 C 0.8706(9) 0.6307(3) 0.4288(5) 0.055(4) Uani 1 d . .
C23 C 0.7834(8) 0.6294(3) 0.3931(5) 0.047(3) Uani 1 d . .
C24 C 1.1582(9) 0.3956(4) 0.3935(5) 0.057(4) Uani 1 d . .
C25 C 1.1574(8) 0.3389(4) 0.3831(6) 0.056(4) Uani 1 d . .
C26 C 1.2257(9) 0.4194(4) 0.2568(5) 0.110(6) Uani 1 d . .
H26A H 1.2505 0.4261 0.2225 0.165 Uiso 1 calc GR .
H26B H 1.2710 0.4095 0.2816 0.165 Uiso 1 calc GR .
H26C H 1.1978 0.4489 0.2698 0.165 Uiso 1 calc GR .
C30 C 1.2324(8) 0.2535(3) 0.1682(3) 0.093(5) Uani 1 d . .
H30 H 1.2466 0.2251 0.1489 0.111 Uiso 1 calc R .
C29 C 1.2962(5) 0.2887(4) 0.1804(3) 0.095(5) Uani 1 d G .
H29 H 1.3530 0.2838 0.1693 0.113 Uiso 1 calc R .
C28 C 1.2750(6) 0.3311(3) 0.2093(3) 0.090(5) Uani 1 d G .
H28 H 1.3177 0.3546 0.2175 0.108 Uiso 1 calc R .
C27 C 1.1901(7) 0.3384(3) 0.2258(3) 0.064(4) Uani 1 d G .
C32 C 1.1263(5) 0.3032(4) 0.2136(3) 0.058(3) Uani 1 d G .
C31 C 1.1474(6) 0.2608(3) 0.1848(3) 0.075(4) Uani 1 d G .
C33 C 1.0858(10) 0.2248(5) 0.1696(5) 0.077(4) Uani 1 d . .
H33 H 1.1065 0.2000 0.1471 0.092 Uiso 1 calc R .
C34 C 0.9505(10) 0.1799(4) 0.1578(5) 0.110(6) Uani 1 d . .
H34A H 0.9054 0.1951 0.1356 0.132 Uiso 1 calc R .
H34B H 0.9861 0.1595 0.1347 0.132 Uiso 1 calc R .
C35 C 0.9082(9) 0.1467(4) 0.1977(5) 0.083(4) Uani 1 d . .
H35A H 0.9523 0.1352 0.2232 0.099 Uiso 1 calc R .
H35B H 0.8851 0.1177 0.1791 0.099 Uiso 1 calc R .
C36 C 0.8330(8) 0.1718(4) 0.2292(6) 0.095(5) Uani 1 d . .
H36A H 0.7919 0.1868 0.2040 0.114 Uiso 1 calc R .
H36B H 0.8022 0.1466 0.2492 0.114 Uiso 1 calc R .
C37 C 0.8494(9) 0.2002(4) 0.3179(6) 0.089(5) Uani 1 d . .
H37 H 0.8187 0.1714 0.3259 0.107 Uiso 1 calc R .
C38 C 0.8750(6) 0.2304(4) 0.3609(4) 0.098(6) Uani 1 d . .
C43 C 0.9088(6) 0.2783(4) 0.3572(4) 0.087(5) Uani 1 d G .
C42 C 0.9242(5) 0.3062(3) 0.4033(5) 0.090(5) Uani 1 d G .
C41 C 0.9057(6) 0.2862(4) 0.4531(4) 0.109(6) Uani 1 d G .
H41 H 0.9160 0.3049 0.4840 0.131 Uiso 1 calc R .
C40 C 0.8719(6) 0.2384(5) 0.4569(4) 0.131(7) Uani 1 d G .
H40 H 0.8595 0.2250 0.4902 0.157 Uiso 1 calc R .
C39 C 0.8565(6) 0.2104(3) 0.4108(6) 0.154(9) Uani 1 d G .
H39 H 0.8339 0.1784 0.4133 0.185 Uiso 1 calc R .
C44 C 0.9566(7) 0.3880(4) 0.4418(5) 0.081(4) Uani 1 d . .
H44A H 0.9860 0.3723 0.4716 0.121 Uiso 1 calc GR .
H44B H 0.8977 0.3954 0.4512 0.121 Uiso 1 calc GR .
H44C H 0.9862 0.4183 0.4330 0.121 Uiso 1 calc GR .
C45 C 0.8261(7) 0.5229(3) 0.4727(4) 0.061(4) Uani 1 d . .
H45A H 0.8554 0.5300 0.4400 0.092 Uiso 1 calc GR .
H45B H 0.8151 0.4878 0.4752 0.092 Uiso 1 calc GR .
H45C H 0.8620 0.5333 0.5026 0.092 Uiso 1 calc GR .
C51 C 0.5914(6) 0.5503(2) 0.4593(3) 0.057(3) Uani 1 d . .
C46 C 0.6725(5) 0.5316(3) 0.4460(3) 0.049(3) Uani 1 d G .
C47 C 0.6786(5) 0.4932(3) 0.4089(3) 0.079(4) Uani 1 d G .
H47 H 0.7329 0.4806 0.4001 0.095 Uiso 1 calc R .
C48 C 0.6035(7) 0.4736(2) 0.3851(3) 0.103(5) Uani 1 d G .
H48 H 0.6076 0.4479 0.3603 0.124 Uiso 1 calc R .
C49 C 0.5224(5) 0.4924(3) 0.3984(3) 0.093(5) Uani 1 d G .
H49 H 0.4722 0.4793 0.3824 0.111 Uiso 1 calc R .
C50 C 0.5163(4) 0.5307(3) 0.4355(4) 0.060(4) Uani 1 d G .
C52 C 0.4327(8) 0.5464(4) 0.4488(5) 0.064(4) Uani 1 d . .
H52 H 0.3880 0.5251 0.4377 0.077 Uiso 1 calc R .
C53 C 0.3167(8) 0.5937(4) 0.4833(5) 0.071(4) Uani 1 d . .
H53A H 0.3076 0.5951 0.5216 0.085 Uiso 1 calc R .
H53B H 0.2842 0.5655 0.4692 0.085 Uiso 1 calc R .
C54 C 0.2807(8) 0.6410(5) 0.4579(5) 0.085(4) Uani 1 d . .
H54A H 0.3012 0.6435 0.4216 0.102 Uiso 1 calc R .
H54B H 0.2176 0.6390 0.4563 0.102 Uiso 1 calc R .
C55 C 0.3070(9) 0.6867(5) 0.4880(6) 0.101(6) Uani 1 d . .
H55A H 0.2929 0.6826 0.5255 0.121 Uiso 1 calc R .
H55B H 0.2740 0.7149 0.4742 0.121 Uiso 1 calc R .
C56 C 0.4238(8) 0.7411(4) 0.4707(5) 0.066(4) Uani 1 d . .
H56 H 0.3784 0.7627 0.4618 0.079 Uiso 1 calc R .
C62 C 0.5909(8) 0.7366(3) 0.4778(3) 0.077(5) Uani 1 d . .
C57 C 0.5126(6) 0.7612(5) 0.4681(4) 0.104(6) Uani 1 d G .
C58 C 0.5125(7) 0.8118(5) 0.4561(4) 0.131(7) Uani 1 d G .
H58 H 0.4601 0.8283 0.4497 0.158 Uiso 1 calc R .
C59 C 0.5908(9) 0.8377(3) 0.4539(4) 0.181(9) Uani 1 d G .
H59 H 0.5907 0.8716 0.4460 0.217 Uiso 1 calc R .
C60 C 0.6691(7) 0.8130(4) 0.4636(4) 0.109(6) Uani 1 d G .
H60 H 0.7215 0.8304 0.4621 0.131 Uiso 1 calc R .
C61 C 0.6692(6) 0.7625(4) 0.4755(4) 0.077(4) Uani 1 d G .
C63 C 0.8201(8) 0.7581(4) 0.4885(5) 0.106(5) Uani 1 d . .
H63A H 0.8337 0.7686 0.4529 0.159 Uiso 1 calc GR .
H63B H 0.8650 0.7363 0.5019 0.159 Uiso 1 calc GR .
H63C H 0.8163 0.7867 0.5113 0.159 Uiso 1 calc GR .
C64 C 0.9392(10) 0.7336(4) 0.2992(5) 0.107(6) Uani 1 d D .
C65 C 0.9001(12) 0.7792(4) 0.3269(6) 0.221(12) Uani 1 d D .
H65A H 0.9001 0.8071 0.3028 0.331 Uiso 1 calc GR .
H65B H 0.9342 0.7871 0.3584 0.331 Uiso 1 calc GR .
H65C H 0.8414 0.7719 0.3369 0.331 Uiso 1 calc GR .
C66 C 0.8478(8) 0.3538(4) 0.2025(5) 0.084(5) Uani 1 d D .
C67 C 0.7777(9) 0.3811(4) 0.1693(5) 0.121(6) Uani 1 d D .
H67A H 0.7874 0.4164 0.1715 0.182 Uiso 1 calc GR .
H67B H 0.7213 0.3733 0.1828 0.182 Uiso 1 calc GR .
H67C H 0.7807 0.3707 0.1326 0.182 Uiso 1 calc GR .
C68 C 0.5564(6) 0.6348(4) 0.6104(5) 0.065(4) Uani 1 d D .
C69 C 0.5442(8) 0.6294(4) 0.6711(5) 0.114(6) Uani 1 d D .
H69A H 0.5718 0.5993 0.6834 0.171 Uiso 1 calc GR .
H69B H 0.4832 0.6281 0.6785 0.171 Uiso 1 calc GR .
H69C H 0.5702 0.6575 0.6892 0.171 Uiso 1 calc GR .
Eu1 Eu 0.93517(4) 0.60186(2) 0.31010(2) 0.0575(2) Uani 1 d . .
Eu2 Eu 1.01226(4) 0.37425(2) 0.29903(3) 0.0664(2) Uani 1 d . .
Eu3 Eu 0.71767(4) 0.63988(2) 0.51308(2) 0.0573(2) Uani 1 d . .
N1 N 1.1600(8) 0.6950(4) 0.2119(5) 0.098(5) Uani 1 d D U
N2 N 1.0098(9) 0.6948(4) 0.1426(6) 0.122(6) Uani 1 d D .
N3 N 1.0067(7) 0.2206(4) 0.1815(4) 0.074(3) Uani 1 d . .
N4 N 0.8653(7) 0.2091(3) 0.2652(5) 0.078(3) Uani 1 d . .
N5 N 0.4073(7) 0.5859(3) 0.4742(4) 0.063(3) Uani 1 d . .
N6 N 0.4029(8) 0.6974(3) 0.4836(4) 0.077(3) Uani 1 d . .
O1 O 1.0708(6) 0.6366(3) 0.2864(3) 0.084(3) Uani 1 d . .
O2 O 0.9298(5) 0.6323(3) 0.2228(3) 0.081(3) Uani 1 d . .
O3 O 1.0765(5) 0.5662(2) 0.3600(3) 0.065(2) Uiso 1 d . .
O4 O 0.8136(5) 0.5674(2) 0.2454(3) 0.064(2) Uiso 1 d . .
O5 O 0.9983(5) 0.5350(2) 0.2579(3) 0.063(2) Uani 1 d . .
O6 O 0.8992(4) 0.5204(2) 0.3427(3) 0.056(2) Uani 1 d . .
O7 O 1.0315(5) 0.4550(2) 0.2551(3) 0.064(2) Uani 1 d . .
O8 O 0.9157(5) 0.4378(3) 0.3349(3) 0.074(3) Uani 1 d . .
O9 O 0.9426(5) 0.6212(2) 0.4060(3) 0.062(2) Uani 1 d . .
O10 O 0.7932(5) 0.6132(3) 0.3463(3) 0.066(2) Uani 1 d . .
O11 O 0.8633(5) 0.6410(2) 0.4771(3) 0.060(2) Uani 1 d . .
O12 O 0.7174(5) 0.6424(2) 0.4181(3) 0.063(2) Uani 1 d . U
O13 O 1.1078(5) 0.4186(2) 0.3612(3) 0.062(2) Uani 1 d . .
O14 O 1.1125(6) 0.3199(3) 0.3471(3) 0.070(3) Uani 1 d . .
O15 O 0.8018(5) 0.6850(2) 0.5827(3) 0.058(2) Uani 1 d . .
O16 O 0.7961(5) 0.5849(2) 0.5728(3) 0.062(3) Uani 1 d . .
O17 O 0.9263(5) 0.3002(3) 0.3108(3) 0.073(3) Uani 1 d . .
O18 O 1.0492(5) 0.3116(2) 0.2337(3) 0.061(2) Uani 1 d . .
O19 O 0.9564(5) 0.3545(3) 0.3958(4) 0.087(3) Uani 1 d . .
O20 O 1.1621(5) 0.3797(3) 0.2514(3) 0.071(3) Uani 1 d . .
O21 O 0.5950(5) 0.5908(2) 0.4919(3) 0.063(2) Uani 1 d . .
O22 O 0.5889(5) 0.6896(2) 0.4923(3) 0.068(3) Uani 1 d . .
O23 O 0.7451(5) 0.5494(2) 0.4733(3) 0.056(2) Uani 1 d . .
O24 O 0.7399(6) 0.7328(2) 0.4876(3) 0.068(3) Uani 1 d . .
O25 O 0.9174(5) 0.6912(3) 0.3160(3) 0.085(3) Uani 1 d D .
O26 O 0.9857(6) 0.7411(3) 0.2593(4) 0.095(3) Uani 1 d D .
O27 O 0.8521(6) 0.3071(3) 0.1962(4) 0.097(3) Uani 1 d D .
O28 O 0.8955(6) 0.3786(3) 0.2334(4) 0.089(3) Uani 1 d D .
O29 O 0.4868(5) 0.6377(3) 0.5834(3) 0.070(2) Uani 1 d D .
O30 O 0.6334(5) 0.6364(2) 0.5944(3) 0.065(2) Uani 1 d D .
Zn1 Zn 1.03401(11) 0.68204(5) 0.22249(7) 0.0830(5) Uani 1 d . .
Zn2 Zn 0.94200(11) 0.26577(5) 0.23728(6) 0.0795(5) Uani 1 d . .
Zn3 Zn 0.49127(9) 0.64006(5) 0.50458(6) 0.0666(4) Uani 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
H1A C1 H1B 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O3 C1 H1A 109.5 . .
O3 C1 H1B 109.5 . .
O3 C1 H1C 109.5 . .
C7 C6 C5 120.0 . .
C7 C6 C8 125.5(10) . .
C5 C6 C8 114.5(10) . .
C6 C7 C2 120.0 . .
O1 C7 C6 120.7(9) . .
O1 C7 C2 119.2(9) . .
C3 C2 C7 120.0 . .
O3 C2 C7 115.0(10) . .
O3 C2 C3 124.9(10) . .
C2 C3 H3 120.0 . .
C4 C3 C2 120.0 . .
C4 C3 H3 120.0 . .
C3 C4 H4 120.0 . .
C3 C4 C5 120.0 . .
C5 C4 H4 120.0 . .
C6 C5 H5 120.0 . .
C4 C5 C6 120.0 . .
C4 C5 H5 120.0 . .
C6 C8 H8 118.9 . .
N1 C8 C6 122.3(13) . .
N1 C8 H8 118.9 . .
H9A C9 H9B 108.5 . .
C10 C9 H9A 110.3 . .
C10 C9 H9B 110.3 . .
N1 C9 H9A 110.3 . .
N1 C9 H9B 110.3 . .
N1 C9 C10 107.2(11) . .
C9 C10 H10A 109.1 . .
C9 C10 H10B 109.1 . .
C9 C10 C11 112.4(15) . .
H10A C10 H10B 107.9 . .
C11 C10 H10A 109.1 . .
C11 C10 H10B 109.1 . .
C10 C11 H11A 110.1 . .
C10 C11 H11B 110.1 . .
H11A C11 H11B 108.4 . .
N2 C11 C10 108.0(13) . .
N2 C11 H11A 110.1 . .
N2 C11 H11B 110.1 . .
C13 C12 H12 116.4 . .
N2 C12 H12 116.4 . .
N2 C12 C13 127.2(14) . .
C15 C14 H14 120.0 . .
C15 C14 C13 120.0 . .
C13 C14 H14 120.0 . .
C14 C15 H15 120.0 . .
C16 C15 C14 120.0 . .
C16 C15 H15 120.0 . .
C15 C16 H16 120.0 . .
C15 C16 C17 120.0 . .
C17 C16 H16 120.0 . .
C18 C17 C16 120.0 . .
O4 C17 C16 123.3(8) . .
O4 C17 C18 116.6(8) . .
C17 C18 C13 120.0 . .
O2 C18 C17 115.1(8) . .
O2 C18 C13 124.9(8) . .
C14 C13 C12 117.6(9) . .
C18 C13 C12 122.0(10) . .
C18 C13 C14 120.0 . .
H19A C19 H19B 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O4 C19 H19A 109.5 . .
O4 C19 H19B 109.5 . .
O4 C19 H19C 109.5 . .
O5 C20 C21 114.6(10) . .
O7 C20 C21 117.5(10) . .
O7 C20 O5 127.9(11) . .
C20 C21 Eu2 76.0(6) . .
O6 C21 C20 116.0(10) . .
O6 C21 Eu2 165.2(8) . .
O8 C21 C20 118.0(10) . .
O8 C21 Eu2 43.1(6) . .
O8 C21 O6 126.1(10) . .
O9 C22 C23 118.0(10) . .
O11 C22 C23 117.1(11) . .
O11 C22 O9 124.9(13) . .
O10 C23 C22 114.3(10) . .
O12 C23 C22 113.3(11) . .
O12 C23 O10 132.3(12) . .
C25 C24 Eu3 80.1(7) . 3_766
O13 C24 C25 111.8(12) . .
O13 C24 Eu3 167.8(9) . 3_766
O16 C24 C25 123.2(12) 3_766 .
O16 C24 Eu3 43.5(6) 3_766 3_766
O16 C24 O13 124.9(12) 3_766 .
C24 C25 Eu3 72.0(7) . 3_766
O14 C25 C24 122.2(12) . .
O14 C25 Eu3 165.6(9) . 3_766
O15 C25 C24 113.3(12) 3_766 .
O15 C25 Eu3 41.6(6) 3_766 3_766
O15 C25 O14 124.0(12) 3_766 .
H26A C26 H26B 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
O20 C26 H26A 109.5 . .
O20 C26 H26B 109.5 . .
O20 C26 H26C 109.5 . .
C29 C30 H30 120.0 . .
C29 C30 C31 120.0 . .
C31 C30 H30 120.0 . .
C30 C29 H29 120.0 . .
C30 C29 C28 120.0 . .
C28 C29 H29 120.0 . .
C29 C28 H28 120.0 . .
C27 C28 C29 120.0 . .
C27 C28 H28 120.0 . .
C32 C27 C28 120.0 . .
O20 C27 C28 124.3(8) . .
O20 C27 C32 115.6(8) . .
C27 C32 C31 120.0 . .
O18 C32 C27 115.8(8) . .
O18 C32 C31 124.1(8) . .
C30 C31 C33 117.1(9) . .
C32 C31 C30 120.0 . .
C32 C31 C33 122.8(9) . .
C31 C33 H33 114.8 . .
N3 C33 C31 130.4(12) . .
N3 C33 H33 114.8 . .
H34A C34 H34B 107.5 . .
C35 C34 H34A 108.5 . .
C35 C34 H34B 108.5 . .
C35 C34 N3 115.1(11) . .
N3 C34 H34A 108.5 . .
N3 C34 H34B 108.5 . .
C34 C35 H35A 108.7 . .
C34 C35 H35B 108.7 . .
C34 C35 C36 114.4(10) . .
H35A C35 H35B 107.6 . .
C36 C35 H35A 108.7 . .
C36 C35 H35B 108.7 . .
C35 C36 H36A 109.3 . .
C35 C36 H36B 109.3 . .
H36A C36 H36B 108.0 . .
N4 C36 C35 111.6(11) . .
N4 C36 H36A 109.3 . .
N4 C36 H36B 109.3 . .
C38 C37 H37 117.0 . .
N4 C37 H37 117.0 . .
N4 C37 C38 126.0(12) . .
C43 C38 C37 125.8(11) . .
C43 C38 C39 120.0 . .
C39 C38 C37 114.0(11) . .
C38 C43 C42 120.0 . .
O17 C43 C38 123.3(9) . .
O17 C43 C42 116.6(9) . .
C43 C42 O19 116.3(10) . .
C41 C42 C43 120.0 . .
C41 C42 O19 123.7(10) . .
C42 C41 H41 120.0 . .
C40 C41 C42 120.0 . .
C40 C41 H41 120.0 . .
C41 C40 H40 120.0 . .
C41 C40 C39 120.0 . .
C39 C40 H40 120.0 . .
C38 C39 H39 120.0 . .
C40 C39 C38 120.0 . .
C40 C39 H39 120.0 . .
H44A C44 H44B 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
O19 C44 H44A 109.5 . .
O19 C44 H44B 109.5 . .
O19 C44 H44C 109.5 . .
H45A C45 H45B 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
O23 C45 H45A 109.5 . .
O23 C45 H45B 109.5 . .
O23 C45 H45C 109.5 . .
C46 C51 C50 120.0 . .
O21 C51 C46 114.0(7) . .
O21 C51 C50 125.7(7) . .
C47 C46 C51 120.0 . .
O23 C46 C51 118.3(7) . .
O23 C46 C47 121.5(7) . .
C46 C47 H47 120.0 . .
C46 C47 C48 120.0 . .
C48 C47 H47 120.0 . .
C47 C48 H48 120.0 . .
C47 C48 C49 120.0 . .
C49 C48 H48 120.0 . .
C48 C49 H49 120.0 . .
C50 C49 C48 120.0 . .
C50 C49 H49 120.0 . .
C51 C50 C52 122.8(9) . .
C49 C50 C51 120.0 . .
C49 C50 C52 117.1(9) . .
C50 C52 H52 114.8 . .
N5 C52 C50 130.4(11) . .
N5 C52 H52 114.8 . .
H53A C53 H53B 107.7 . .
C54 C53 H53A 108.8 . .
C54 C53 H53B 108.8 . .
N5 C53 H53A 108.8 . .
N5 C53 H53B 108.8 . .
N5 C53 C54 113.8(10) . .
C53 C54 H54A 109.1 . .
C53 C54 H54B 109.1 . .
H54A C54 H54B 107.8 . .
C55 C54 C53 112.7(12) . .
C55 C54 H54A 109.1 . .
C55 C54 H54B 109.1 . .
C54 C55 H55A 109.2 . .
C54 C55 H55B 109.2 . .
C54 C55 N6 112.0(10) . .
H55A C55 H55B 107.9 . .
N6 C55 H55A 109.2 . .
N6 C55 H55B 109.2 . .
C57 C56 H56 116.7 . .
N6 C56 H56 116.7 . .
N6 C56 C57 126.5(12) . .
C57 C62 C61 120.0 . .
O22 C62 C57 118.7(10) . .
O22 C62 C61 121.1(10) . .
C62 C57 C56 128.1(10) . .
C58 C57 C56 111.9(10) . .
C58 C57 C62 120.0 . .
C57 C58 H58 120.0 . .
C57 C58 C59 120.0 . .
C59 C58 H58 120.0 . .
C58 C59 H59 120.0 . .
C58 C59 C60 120.0 . .
C60 C59 H59 120.0 . .
C59 C60 H60 120.0 . .
C59 C60 C61 120.0 . .
C61 C60 H60 120.0 . .
C60 C61 C62 120.0 . .
O24 C61 C62 112.4(9) . .
O24 C61 C60 127.6(9) . .
H63A C63 H63B 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
O24 C63 H63A 109.5 . .
O24 C63 H63B 109.5 . .
O24 C63 H63C 109.5 . .
O25 C64 C65 117.4(9) . .
O26 C64 C65 117.8(10) . .
O26 C64 O25 124.6(11) . .
C64 C65 H65A 109.5 . .
C64 C65 H65B 109.5 . .
C64 C65 H65C 109.5 . .
H65A C65 H65B 109.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
O27 C66 C67 116.3(9) . .
O28 C66 C67 118.6(10) . .
O28 C66 O27 125.1(12) . .
C66 C67 H67A 109.5 . .
C66 C67 H67B 109.5 . .
C66 C67 H67C 109.5 . .
H67A C67 H67B 109.5 . .
H67A C67 H67C 109.5 . .
H67B C67 H67C 109.5 . .
O29 C68 C69 114.7(9) . .
O29 C68 O30 128.5(11) . .
O30 C68 C69 116.8(9) . .
C68 C69 H69A 109.5 . .
C68 C69 H69B 109.5 . .
C68 C69 H69C 109.5 . .
H69A C69 H69B 109.5 . .
H69A C69 H69C 109.5 . .
H69B C69 H69C 109.5 . .
O1 Eu1 O3 63.0(3) . .
O1 Eu1 O4 127.3(3) . .
O1 Eu1 O5 78.2(2) . .
O1 Eu1 O6 130.8(3) . .
O1 Eu1 O9 97.9(3) . .
O1 Eu1 O10 148.8(2) . .
O1 Eu1 O25 74.1(3) . .
O2 Eu1 O1 69.0(3) . .
O2 Eu1 O3 125.4(3) . .
O2 Eu1 O4 62.2(3) . .
O2 Eu1 O5 76.3(2) . .
O2 Eu1 O6 129.3(2) . .
O2 Eu1 O9 147.3(2) . .
O2 Eu1 O10 107.1(3) . .
O2 Eu1 O25 73.0(3) . .
O4 Eu1 O3 136.7(2) . .
O5 Eu1 O3 69.8(2) . .
O5 Eu1 O4 72.2(2) . .
O5 Eu1 O9 132.0(2) . .
O6 Eu1 O3 72.8(2) . .
O6 Eu1 O4 73.8(2) . .
O6 Eu1 O5 66.9(2) . .
O6 Eu1 O9 82.4(2) . .
O6 Eu1 O25 148.8(2) . .
O9 Eu1 O3 66.2(2) . .
O9 Eu1 O4 134.3(2) . .
O10 Eu1 O3 127.5(2) . .
O10 Eu1 O4 68.6(2) . .
O10 Eu1 O5 132.2(2) . .
O10 Eu1 O6 76.7(2) . .
O10 Eu1 O9 68.2(3) . .
O10 Eu1 O25 75.3(3) . .
O25 Eu1 O3 114.9(3) . .
O25 Eu1 O4 108.0(3) . .
O25 Eu1 O5 144.2(2) . .
O25 Eu1 O9 74.6(2) . .
O7 Eu2 C21 48.1(2) . .
O7 Eu2 O19 129.3(2) . .
O7 Eu2 O20 68.4(2) . .
O8 Eu2 C21 20.4(2) . .
O8 Eu2 O7 68.0(2) . .
O8 Eu2 O19 66.0(2) . .
O8 Eu2 O20 132.4(2) . .
O13 Eu2 C21 71.3(3) . .
O13 Eu2 O7 77.0(2) . .
O13 Eu2 O8 77.7(2) . .
O13 Eu2 O19 73.5(2) . .
O13 Eu2 O20 74.8(2) . .
O14 Eu2 C21 134.7(3) . .
O14 Eu2 O7 132.4(3) . .
O14 Eu2 O8 128.6(3) . .
O14 Eu2 O13 67.0(2) . .
O14 Eu2 O19 68.9(3) . .
O14 Eu2 O20 72.7(3) . .
O17 Eu2 C21 120.4(3) . .
O17 Eu2 O7 149.0(3) . .
O17 Eu2 O8 101.2(2) . .
O17 Eu2 O13 130.7(3) . .
O17 Eu2 O14 77.6(3) . .
O17 Eu2 O18 69.2(2) . .
O17 Eu2 O19 62.1(2) . .
O17 Eu2 O20 126.2(2) . .
O17 Eu2 O28 73.8(3) . .
O18 Eu2 C21 147.5(3) . .
O18 Eu2 O7 106.3(2) . .
O18 Eu2 O8 152.3(3) . .
O18 Eu2 O13 128.8(2) . .
O18 Eu2 O14 76.1(3) . .
O18 Eu2 O19 124.3(2) . .
O18 Eu2 O20 60.8(2) . .
O19 Eu2 C21 83.4(2) . .
O20 Eu2 C21 112.4(2) . .
O20 Eu2 O19 137.2(3) . .
O28 Eu2 C21 77.7(3) . .
O28 Eu2 O7 75.3(3) . .
O28 Eu2 O8 76.5(3) . .
O28 Eu2 O13 147.6(3) . .
O28 Eu2 O14 145.5(3) . .
O28 Eu2 O18 75.9(3) . .
O28 Eu2 O19 112.5(3) . .
O28 Eu2 O20 109.7(3) . .
C24 Eu3 C25 27.9(3) 3_766 3_766
O11 Eu3 C24 74.2(3) . 3_766
O11 Eu3 C25 76.1(3) . 3_766
O11 Eu3 O15 77.4(2) . .
O11 Eu3 O22 131.6(2) . .
O11 Eu3 O23 73.7(2) . .
O11 Eu3 O24 76.7(2) . .
O11 Eu3 O30 145.1(3) . .
O12 Eu3 C24 137.9(3) . 3_766
O12 Eu3 C25 141.5(3) . 3_766
O12 Eu3 O11 67.2(2) . .
O12 Eu3 O15 133.0(2) . .
O12 Eu3 O16 128.9(2) . .
O12 Eu3 O22 77.6(2) . .
O12 Eu3 O23 69.5(2) . .
O12 Eu3 O24 74.1(2) . .
O12 Eu3 O30 147.7(3) . .
O15 Eu3 C24 47.2(3) . 3_766
O15 Eu3 C25 19.3(2) . 3_766
O15 Eu3 O23 128.9(2) . .
O15 Eu3 O24 68.4(3) . .
O16 Eu3 C24 20.2(2) . 3_766
O16 Eu3 C25 48.0(2) . 3_766
O16 Eu3 O11 77.5(2) . .
O16 Eu3 O15 67.4(2) . .
O16 Eu3 O22 149.8(2) . .
O16 Eu3 O23 65.8(2) . .
O16 Eu3 O24 132.4(3) . .
O16 Eu3 O30 74.1(3) . .
O21 Eu3 C24 118.1(3) . 3_766
O21 Eu3 C25 137.4(3) . 3_766
O21 Eu3 O11 131.6(2) . .
O21 Eu3 O12 78.8(2) . .
O21 Eu3 O15 147.3(2) . .
O21 Eu3 O16 100.6(2) . .
O21 Eu3 O22 67.4(2) . .
O21 Eu3 O23 62.4(2) . .
O21 Eu3 O24 126.3(3) . .
O21 Eu3 O30 74.3(2) . .
O22 Eu3 C24 143.7(3) . 3_766
O22 Eu3 C25 122.6(3) . 3_766
O22 Eu3 O15 107.1(2) . .
O22 Eu3 O23 123.7(2) . .
O22 Eu3 O24 62.0(2) . .
O22 Eu3 O30 75.9(2) . .
O23 Eu3 C24 84.4(3) . 3_766
O23 Eu3 C25 111.3(3) . 3_766
O24 Eu3 C24 113.2(3) . 3_766
O24 Eu3 C25 87.1(3) . 3_766
O24 Eu3 O23 139.6(2) . .
O30 Eu3 C24 72.1(3) . 3_766
O30 Eu3 C25 69.8(3) . 3_766
O30 Eu3 O15 73.1(2) . .
O30 Eu3 O23 111.6(2) . .
O30 Eu3 O24 108.5(2) . .
C8 N1 C9 109.9(12) . .
C8 N1 Zn1 131.1(10) . .
C9 N1 Zn1 118.8(8) . .
C11 N2 Zn1 118.4(10) . .
C12 N2 C11 113.9(14) . .
C12 N2 Zn1 126.0(10) . .
C33 N3 C34 121.3(12) . .
C33 N3 Zn2 124.9(9) . .
C34 N3 Zn2 113.8(8) . .
C36 N4 Zn2 120.0(9) . .
C37 N4 C36 114.7(11) . .
C37 N4 Zn2 124.9(9) . .
C52 N5 C53 120.0(10) . .
C52 N5 Zn3 124.0(8) . .
C53 N5 Zn3 115.9(7) . .
C55 N6 Zn3 117.9(8) . .
C56 N6 C55 116.7(11) . .
C56 N6 Zn3 125.3(9) . .
C7 O1 Eu1 123.8(6) . .
C7 O1 Zn1 129.7(6) . .
Zn1 O1 Eu1 101.3(4) . .
C18 O2 Eu1 128.2(6) . .
C18 O2 Zn1 128.5(6) . .
Zn1 O2 Eu1 102.4(4) . .
C1 O3 Eu1 127.6(6) . .
C2 O3 C1 118.3(9) . .
C2 O3 Eu1 114.1(7) . .
C17 O4 C19 118.4(9) . .
C17 O4 Eu1 116.3(6) . .
C19 O4 Eu1 125.1(7) . .
C20 O5 Eu1 121.1(7) . .
C21 O6 Eu1 120.8(7) . .
C20 O7 Eu2 118.4(7) . .
C21 O8 Eu2 116.4(7) . .
C22 O9 Eu1 117.0(8) . .
C23 O10 Eu1 121.4(8) . .
C22 O11 Eu3 117.3(8) . .
C23 O12 Eu3 120.4(8) . .
C24 O13 Eu2 121.4(8) . .
C25 O14 Eu2 116.9(8) . .
C25 O15 Eu3 119.1(8) 3_766 .
C24 O16 Eu3 116.4(8) 3_766 .
C43 O17 Eu2 126.3(7) . .
C43 O17 Zn2 127.1(6) . .
Zn2 O17 Eu2 100.7(3) . .
C32 O18 Eu2 127.0(6) . .
C32 O18 Zn2 129.9(6) . .
Zn2 O18 Eu2 100.8(3) . .
C42 O19 C44 117.4(9) . .
C42 O19 Eu2 115.5(7) . .
C44 O19 Eu2 127.1(6) . .
C26 O20 Eu2 126.6(6) . .
C27 O20 C26 115.2(8) . .
C27 O20 Eu2 117.3(6) . .
C51 O21 Eu3 127.3(6) . .
C51 O21 Zn3 124.9(6) . .
Zn3 O21 Eu3 102.7(2) . .
C62 O22 Eu3 124.2(7) . .
C62 O22 Zn3 133.9(7) . .
Zn3 O22 Eu3 101.9(3) . .
C45 O23 Eu3 126.9(6) . .
C46 O23 C45 121.0(8) . .
C46 O23 Eu3 111.7(5) . .
C61 O24 C63 114.2(9) . .
C61 O24 Eu3 120.2(6) . .
C63 O24 Eu3 125.5(7) . .
C64 O25 Eu1 147.5(7) . .
C64 O26 Zn1 117.8(7) . .
C66 O27 Zn2 120.9(8) . .
C66 O28 Eu2 144.7(8) . .
C68 O29 Zn3 119.6(7) . .
C68 O30 Eu3 142.0(8) . .
N1 Zn1 N2 90.0(5) . .
N1 Zn1 O1 87.4(4) . .
N1 Zn1 O2 149.5(4) . .
N1 Zn1 O26 107.2(4) . .
O1 Zn1 N2 152.4(4) . .
O1 Zn1 O2 79.5(3) . .
O2 Zn1 N2 89.2(4) . .
O26 Zn1 N2 104.8(5) . .
O26 Zn1 O1 102.2(3) . .
O26 Zn1 O2 102.5(3) . .
N4 Zn2 N3 94.5(4) . .
N4 Zn2 O17 87.2(4) . .
N4 Zn2 O18 157.2(4) . .
O17 Zn2 N3 154.8(4) . .
O18 Zn2 N3 85.8(3) . .
O18 Zn2 O17 83.1(3) . .
O27 Zn2 N3 107.7(4) . .
O27 Zn2 N4 100.8(4) . .
O27 Zn2 O17 96.6(3) . .
O27 Zn2 O18 100.8(3) . .
N5 Zn3 N6 91.7(4) . .
N5 Zn3 O21 88.3(3) . .
O21 Zn3 N6 155.2(3) . .
O22 Zn3 N5 149.0(3) . .
O22 Zn3 N6 87.5(4) . .
O22 Zn3 O21 80.0(3) . .
O29 Zn3 N5 107.9(3) . .
O29 Zn3 N6 103.7(3) . .
O29 Zn3 O21 99.9(3) . .
O29 Zn3 O22 102.3(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C1 O3 1.393(10) .
C6 C7 1.3900 .
C6 C5 1.3900 .
C6 C8 1.536(10) .
C7 C2 1.3900 .
C7 O1 1.360(10) .
C2 C3 1.3900 .
C2 O3 1.374(9) .
C3 H3 0.9300 .
C3 C4 1.3900 .
C4 H4 0.9300 .
C4 C5 1.3900 .
C5 H5 0.9300 .
C8 H8 0.9300 .
C8 N1 1.302(15) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C9 C10 1.535(12) .
C9 N1 1.508(11) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C10 C11 1.541(13) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C11 N2 1.489(11) .
C12 H12 0.9300 .
C12 C13 1.514(11) .
C12 N2 1.306(17) .
C14 H14 0.9300 .
C14 C15 1.3900 .
C14 C13 1.3900 .
C15 H15 0.9300 .
C15 C16 1.3900 .
C16 H16 0.9300 .
C16 C17 1.3900 .
C17 C18 1.3900 .
C17 O4 1.343(9) .
C18 C13 1.3900 .
C18 O2 1.345(10) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C19 O4 1.436(10) .
C20 C21 1.587(13) .
C20 O5 1.247(10) .
C20 O7 1.211(10) .
C21 Eu2 3.198(12) .
C21 O6 1.268(11) .
C21 O8 1.247(10) .
C22 C23 1.594(15) .
C22 O9 1.279(12) .
C22 O11 1.245(11) .
C23 O10 1.261(12) .
C23 O12 1.250(11) .
C24 C25 1.543(15) .
C24 Eu3 3.132(14) 3_766
C24 O13 1.267(12) .
C24 O16 1.205(14) 3_766
C25 Eu3 3.244(15) 3_766
C25 O14 1.234(14) .
C25 O15 1.229(12) 3_766
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C26 O20 1.451(11) .
C30 H30 0.9300 .
C30 C29 1.3900 .
C30 C31 1.3900 .
C29 H29 0.9300 .
C29 C28 1.3900 .
C28 H28 0.9300 .
C28 C27 1.3900 .
C27 C32 1.3900 .
C27 O20 1.355(8) .
C32 C31 1.3900 .
C32 O18 1.315(8) .
C31 C33 1.399(14) .
C33 H33 0.9300 .
C33 N3 1.261(13) .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C34 C35 1.495(14) .
C34 N3 1.506(13) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C35 C36 1.564(14) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C36 N4 1.428(13) .
C37 H37 0.9300 .
C37 C38 1.396(14) .
C37 N4 1.365(14) .
C38 C43 1.3900 .
C38 C39 1.3900 .
C43 C42 1.3900 .
C43 O17 1.331(9) .
C42 C41 1.3900 .
C42 O19 1.402(9) .
C41 H41 0.9300 .
C41 C40 1.3900 .
C40 H40 0.9300 .
C40 C39 1.3900 .
C39 H39 0.9300 .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C44 O19 1.459(11) .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
C45 O23 1.433(10) .
C51 C46 1.3900 .
C51 C50 1.3900 .
C51 O21 1.357(8) .
C46 C47 1.3900 .
C46 O23 1.380(9) .
C47 H47 0.9300 .
C47 C48 1.3900 .
C48 H48 0.9300 .
C48 C49 1.3900 .
C49 H49 0.9300 .
C49 C50 1.3900 .
C50 C52 1.398(12) .
C52 H52 0.9300 .
C52 N5 1.299(12) .
C53 H53A 0.9700 .
C53 H53B 0.9700 .
C53 C54 1.518(13) .
C53 N5 1.430(12) .
C54 H54A 0.9700 .
C54 H54B 0.9700 .
C54 C55 1.490(14) .
C55 H55A 0.9700 .
C55 H55B 0.9700 .
C55 N6 1.507(13) .
C56 H56 0.9300 .
C56 C57 1.470(13) .
C56 N6 1.260(12) .
C62 C57 1.3900 .
C62 C61 1.3900 .
C62 O22 1.311(8) .
C57 C58 1.3900 .
C58 H58 0.9300 .
C58 C59 1.3900 .
C59 H59 0.9300 .
C59 C60 1.3900 .
C60 H60 0.9300 .
C60 C61 1.3900 .
C61 O24 1.376(10) .
C63 H63A 0.9600 .
C63 H63B 0.9600 .
C63 H63C 0.9600 .
C63 O24 1.405(12) .
C64 C65 1.534(11) .
C64 O25 1.262(7) .
C64 O26 1.252(7) .
C65 H65A 0.9600 .
C65 H65B 0.9600 .
C65 H65C 0.9600 .
C66 C67 1.532(11) .
C66 O27 1.266(7) .
C66 O28 1.245(7) .
C67 H67A 0.9600 .
C67 H67B 0.9600 .
C67 H67C 0.9600 .
C68 C69 1.537(10) .
C68 O29 1.254(7) .
C68 O30 1.257(7) .
C69 H69A 0.9600 .
C69 H69B 0.9600 .
C69 H69C 0.9600 .
Eu1 O1 2.369(8) .
Eu1 O2 2.329(8) .
Eu1 O3 2.659(8) .
Eu1 O4 2.614(8) .
Eu1 O5 2.432(6) .
Eu1 O6 2.402(6) .
Eu1 O9 2.451(7) .
Eu1 O10 2.396(7) .
Eu1 O25 2.419(8) .
Eu2 O7 2.450(7) .
Eu2 O8 2.442(8) .
Eu2 O13 2.427(8) .
Eu2 O14 2.422(8) .
Eu2 O17 2.408(7) .
Eu2 O18 2.419(6) .
Eu2 O19 2.635(9) .
Eu2 O20 2.614(7) .
Eu2 O28 2.408(9) .
Eu3 C24 3.132(14) 3_766
Eu3 C25 3.244(15) 3_766
Eu3 O11 2.427(7) .
Eu3 O12 2.374(7) .
Eu3 O15 2.463(8) .
Eu3 O16 2.405(8) .
Eu3 O21 2.350(7) .
Eu3 O22 2.434(7) .
Eu3 O23 2.661(6) .
Eu3 O24 2.598(7) .
Eu3 O30 2.432(7) .
N1 Zn1 1.989(13) .
N2 Zn1 2.052(14) .
N3 Zn2 2.112(10) .
N4 Zn2 2.054(10) .
N5 Zn3 2.077(10) .
N6 Zn3 2.110(10) .
O1 Zn1 2.078(8) .
O2 Zn1 2.085(8) .
O15 C25 1.229(12) 3_766
O16 C24 1.205(14) 3_766
O17 Zn2 2.075(8) .
O18 Zn2 2.057(7) .
O21 Zn3 2.099(6) .
O22 Zn3 2.033(7) .
O26 Zn1 1.984(8) .
O27 Zn2 2.033(8) .
O29 Zn3 1.972(8) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C7 C2 C3 0.0 . .
C6 C7 C2 O3 176.2(7) . .
C6 C7 O1 Eu1 163.4(4) . .
C6 C7 O1 Zn1 13.8(10) . .
C6 C8 N1 C9 172.4(10) . .
C6 C8 N1 Zn1 -3(2) . .
C7 C6 C5 C4 0.0 . .
C7 C6 C8 N1 -10.2(17) . .
C7 C2 C3 C4 0.0 . .
C7 C2 O3 C1 -161.0(7) . .
C7 C2 O3 Eu1 20.8(7) . .
C7 O1 Zn1 N1 -19.3(8) . .
C7 O1 Zn1 N2 65.6(13) . .
C7 O1 Zn1 O2 133.0(8) . .
C7 O1 Zn1 O26 -126.3(8) . .
C2 C7 O1 Eu1 -13.0(9) . .
C2 C7 O1 Zn1 -162.6(5) . .
C2 C3 C4 C5 0.0 . .
C3 C2 O3 C1 15.0(11) . .
C3 C2 O3 Eu1 -163.2(4) . .
C3 C4 C5 C6 0.0 . .
C5 C6 C7 C2 0.0 . .
C5 C6 C7 O1 -176.3(8) . .
C5 C6 C8 N1 170.4(11) . .
C8 C6 C7 C2 -179.4(9) . .
C8 C6 C7 O1 4.3(10) . .
C8 C6 C5 C4 179.5(8) . .
C8 N1 Zn1 N2 -139.0(14) . .
C8 N1 Zn1 O1 13.5(14) . .
C8 N1 Zn1 O2 -50.7(19) . .
C8 N1 Zn1 O26 115.4(14) . .
C9 C10 C11 N2 -73.1(16) . .
C9 N1 Zn1 N2 45.7(10) . .
C9 N1 Zn1 O1 -161.7(10) . .
C9 N1 Zn1 O2 134.1(10) . .
C9 N1 Zn1 O26 -59.8(11) . .
C10 C9 N1 C8 119.6(14) . .
C10 C9 N1 Zn1 -64.3(15) . .
C10 C11 N2 C12 -133.3(16) . .
C10 C11 N2 Zn1 61.0(17) . .
C11 N2 Zn1 N1 -44.4(12) . .
C11 N2 Zn1 O1 -128.7(12) . .
C11 N2 Zn1 O2 166.1(12) . .
C11 N2 Zn1 O26 63.4(12) . .
C12 N2 Zn1 N1 151.9(15) . .
C12 N2 Zn1 O1 68(2) . .
C12 N2 Zn1 O2 2.4(15) . .
C12 N2 Zn1 O26 -100.4(14) . .
C14 C15 C16 C17 0.0 . .
C15 C14 C13 C12 -173.3(8) . .
C15 C14 C13 C18 0.0 . .
C15 C16 C17 C18 0.0 . .
C15 C16 C17 O4 176.2(8) . .
C16 C17 C18 C13 0.0 . .
C16 C17 C18 O2 -178.5(8) . .
C16 C17 O4 C19 -3.8(11) . .
C16 C17 O4 Eu1 171.2(4) . .
C17 C18 C13 C12 173.0(9) . .
C17 C18 C13 C14 0.0 . .
C17 C18 O2 Eu1 6.8(10) . .
C17 C18 O2 Zn1 174.4(5) . .
C18 C17 O4 C19 172.5(6) . .
C18 C17 O4 Eu1 -12.5(7) . .
C18 O2 Zn1 N1 -81.9(12) . .
C18 O2 Zn1 N2 6.6(9) . .
C18 O2 Zn1 O1 -148.0(8) . .
C18 O2 Zn1 O26 111.7(8) . .
C13 C12 N2 C11 -178.8(12) . .
C13 C12 N2 Zn1 -14(2) . .
C13 C14 C15 C16 0.0 . .
C13 C18 O2 Eu1 -171.6(4) . .
C13 C18 O2 Zn1 -4.0(11) . .
C20 C21 Eu2 O7 -1.1(5) . .
C20 C21 Eu2 O8 -166.7(11) . .
C20 C21 Eu2 O13 88.0(6) . .
C20 C21 Eu2 O14 111.6(6) . .
C20 C21 Eu2 O17 -145.1(5) . .
C20 C21 Eu2 O18 -46.3(8) . .
C20 C21 Eu2 O19 162.8(6) . .
C20 C21 Eu2 O20 24.1(6) . .
C20 C21 Eu2 O28 -82.4(6) . .
C20 C21 O6 Eu1 -0.3(12) . .
C20 C21 O8 Eu2 14.6(12) . .
C21 C20 O5 Eu1 9.8(12) . .
C21 C20 O7 Eu2 -2.7(13) . .
C21 Eu2 O7 C20 1.6(8) . .
C21 Eu2 O13 C24 154.7(9) . .
C21 Eu2 O14 C25 -17.4(11) . .
C21 Eu2 O17 C43 -78.4(8) . .
C21 Eu2 O17 Zn2 127.5(3) . .
C21 Eu2 O18 C32 99.8(8) . .
C21 Eu2 O18 Zn2 -96.1(5) . .
C21 Eu2 O19 C42 143.5(7) . .
C21 Eu2 O19 C44 -37.4(8) . .
C21 Eu2 O20 C26 30.4(10) . .
C21 Eu2 O20 C27 -160.8(6) . .
C21 Eu2 O28 C66 -162.0(17) . .
C22 C23 O10 Eu1 -11.8(11) . .
C22 C23 O12 Eu3 -20.5(11) . .
C23 C22 O9 Eu1 -0.2(11) . .
C23 C22 O11 Eu3 12.8(11) . .
C24 C25 O14 Eu2 -6.7(15) . .
C24 Eu3 O11 C22 146.5(8) 3_766 .
C24 Eu3 O12 C23 -5.1(9) 3_766 .
C24 Eu3 O15 C25 -3.9(8) 3_766 3_766
C24 Eu3 O21 C51 -84.7(7) 3_766 .
C24 Eu3 O21 Zn3 119.8(3) 3_766 .
C24 Eu3 O22 C62 93.2(8) 3_766 .
C24 Eu3 O22 Zn3 -86.2(5) 3_766 .
C24 Eu3 O23 C45 -41.1(7) 3_766 .
C24 Eu3 O23 C46 146.6(5) 3_766 .
C24 Eu3 O24 C61 -139.8(7) 3_766 .
C24 Eu3 O24 C63 35.1(9) 3_766 .
C24 Eu3 O30 C68 -161.8(12) 3_766 .
C25 C24 O13 Eu2 6.6(12) . .
C25 Eu3 O11 C22 175.3(8) 3_766 .
C25 Eu3 O12 C23 38.4(9) 3_766 .
C25 Eu3 O16 C24 -4.2(8) 3_766 3_766
C25 Eu3 O21 C51 -110.6(7) 3_766 .
C25 Eu3 O21 Zn3 93.9(4) 3_766 .
C25 Eu3 O22 C62 67.4(7) 3_766 .
C25 Eu3 O22 Zn3 -112.0(3) 3_766 .
C25 Eu3 O23 C45 -33.4(7) 3_766 .
C25 Eu3 O23 C46 154.3(5) 3_766 .
C25 Eu3 O24 C61 -129.6(7) 3_766 .
C25 Eu3 O24 C63 45.4(9) 3_766 .
C25 Eu3 O30 C68 168.7(12) 3_766 .
C30 C29 C28 C27 0.0 . .
C30 C31 C33 N3 175.4(13) . .
C29 C30 C31 C32 0.0 . .
C29 C30 C31 C33 177.9(9) . .
C29 C28 C27 C32 0.0 . .
C29 C28 C27 O20 -176.1(8) . .
C28 C27 C32 C31 0.0 . .
C28 C27 C32 O18 175.9(8) . .
C28 C27 O20 C26 5.3(12) . .
C28 C27 O20 Eu2 -164.8(4) . .
C27 C32 C31 C30 0.0 . .
C27 C32 C31 C33 -177.8(10) . .
C27 C32 O18 Eu2 -9.3(9) . .
C27 C32 O18 Zn2 -168.8(5) . .
C32 C27 O20 C26 -171.0(8) . .
C32 C27 O20 Eu2 18.9(8) . .
C32 C31 C33 N3 -7(2) . .
C32 O18 Zn2 N3 -13.7(9) . .
C32 O18 Zn2 N4 78.1(12) . .
C32 O18 Zn2 O17 143.6(9) . .
C32 O18 Zn2 O27 -121.0(8) . .
C31 C30 C29 C28 0.0 . .
C31 C32 O18 Eu2 166.4(4) . .
C31 C32 O18 Zn2 6.9(11) . .
C31 C33 N3 C34 176.5(12) . .
C31 C33 N3 Zn2 -6(2) . .
C33 N3 Zn2 N4 -144.1(12) . .
C33 N3 Zn2 O17 -51.0(17) . .
C33 N3 Zn2 O18 13.0(12) . .
C33 N3 Zn2 O27 113.0(12) . .
C34 C35 C36 N4 -69.2(15) . .
C34 N3 Zn2 N4 33.2(9) . .
C34 N3 Zn2 O17 126.3(10) . .
C34 N3 Zn2 O18 -169.7(9) . .
C34 N3 Zn2 O27 -69.7(9) . .
C35 C34 N3 C33 123.2(14) . .
C35 C34 N3 Zn2 -54.2(14) . .
C35 C36 N4 C37 -118.6(12) . .
C35 C36 N4 Zn2 54.4(14) . .
C36 N4 Zn2 N3 -36.4(10) . .
C36 N4 Zn2 O17 168.8(10) . .
C36 N4 Zn2 O18 -126.4(11) . .
C36 N4 Zn2 O27 72.7(10) . .
C37 C38 C43 C42 174.0(11) . .
C37 C38 C43 O17 -4.5(11) . .
C37 C38 C39 C40 -174.7(10) . .
C37 N4 Zn2 N3 135.9(11) . .
C37 N4 Zn2 O17 -19.0(11) . .
C37 N4 Zn2 O18 45.9(16) . .
C37 N4 Zn2 O27 -115.1(11) . .
C38 C37 N4 C36 179.2(12) . .
C38 C37 N4 Zn2 7(2) . .
C38 C43 C42 C41 0.0 . .
C38 C43 C42 O19 -178.5(8) . .
C38 C43 O17 Eu2 -165.9(4) . .
C38 C43 O17 Zn2 -18.3(11) . .
C43 C38 C39 C40 0.0 . .
C43 C42 C41 C40 0.0 . .
C43 C42 O19 C44 168.0(7) . .
C43 C42 O19 Eu2 -12.8(8) . .
C43 O17 Zn2 N3 -69.4(12) . .
C43 O17 Zn2 N4 25.3(8) . .
C43 O17 Zn2 O18 -134.0(8) . .
C43 O17 Zn2 O27 125.9(8) . .
C42 C43 O17 Eu2 15.6(9) . .
C42 C43 O17 Zn2 163.1(5) . .
C42 C41 C40 C39 0.0 . .
C41 C42 O19 C44 -10.4(12) . .
C41 C42 O19 Eu2 168.7(4) . .
C41 C40 C39 C38 0.0 . .
C39 C38 C43 C42 0.0 . .
C39 C38 C43 O17 -178.5(9) . .
C51 C46 C47 C48 0.0 . .
C51 C46 O23 C45 162.6(6) . .
C51 C46 O23 Eu3 -24.5(6) . .
C51 C50 C52 N5 16.2(16) . .
C51 O21 Zn3 N5 17.8(7) . .
C51 O21 Zn3 N6 -72.4(11) . .
C51 O21 Zn3 O22 -133.4(7) . .
C51 O21 Zn3 O29 125.8(6) . .
C46 C51 C50 C49 0.0 . .
C46 C51 C50 C52 177.0(8) . .
C46 C51 O21 Eu3 13.0(8) . .
C46 C51 O21 Zn3 163.4(4) . .
C46 C47 C48 C49 0.0 . .
C47 C46 O23 C45 -12.7(10) . .
C47 C46 O23 Eu3 160.2(3) . .
C47 C48 C49 C50 0.0 . .
C48 C49 C50 C51 0.0 . .
C48 C49 C50 C52 -177.2(8) . .
C49 C50 C52 N5 -166.6(10) . .
C50 C51 C46 C47 0.0 . .
C50 C51 C46 O23 -175.4(7) . .
C50 C51 O21 Eu3 -160.5(4) . .
C50 C51 O21 Zn3 -10.1(9) . .
C50 C52 N5 C53 -179.7(10) . .
C50 C52 N5 Zn3 -0.5(17) . .
C52 N5 Zn3 N6 142.2(9) . .
C52 N5 Zn3 O21 -12.9(9) . .
C52 N5 Zn3 O22 54.3(12) . .
C52 N5 Zn3 O29 -112.8(9) . .
C53 C54 C55 N6 69.3(15) . .
C53 N5 Zn3 N6 -38.5(8) . .
C53 N5 Zn3 O21 166.3(8) . .
C53 N5 Zn3 O22 -126.5(9) . .
C53 N5 Zn3 O29 66.4(8) . .
C54 C53 N5 C52 -119.2(11) . .
C54 C53 N5 Zn3 61.6(12) . .
C54 C55 N6 C56 130.3(12) . .
C54 C55 N6 Zn3 -53.8(14) . .
C55 N6 Zn3 N5 35.4(9) . .
C55 N6 Zn3 O21 125.0(11) . .
C55 N6 Zn3 O22 -175.6(9) . .
C55 N6 Zn3 O29 -73.5(9) . .
C56 C57 C58 C59 177.7(9) . .
C56 N6 Zn3 N5 -149.2(10) . .
C56 N6 Zn3 O21 -59.6(15) . .
C56 N6 Zn3 O22 -0.1(10) . .
C56 N6 Zn3 O29 101.9(10) . .
C62 C57 C58 C59 0.0 . .
C62 C61 O24 C63 -176.9(8) . .
C62 C61 O24 Eu3 -1.4(9) . .
C62 O22 Zn3 N5 89.4(10) . .
C62 O22 Zn3 N6 0.3(9) . .
C62 O22 Zn3 O21 158.7(9) . .
C62 O22 Zn3 O29 -103.2(9) . .
C57 C56 N6 C55 174.7(11) . .
C57 C56 N6 Zn3 -0.8(18) . .
C57 C62 C61 C60 0.0 . .
C57 C62 C61 O24 178.3(8) . .
C57 C62 O22 Eu3 -178.6(4) . .
C57 C62 O22 Zn3 0.5(11) . .
C57 C58 C59 C60 0.0 . .
C58 C59 C60 C61 0.0 . .
C59 C60 C61 C62 0.0 . .
C59 C60 C61 O24 -178.0(10) . .
C60 C61 O24 C63 1.3(12) . .
C60 C61 O24 Eu3 176.8(4) . .
C61 C62 C57 C56 -177.3(10) . .
C61 C62 C57 C58 0.0 . .
C61 C62 O22 Eu3 -3.0(9) . .
C61 C62 O22 Zn3 176.1(5) . .
C64 O26 Zn1 N1 -132.1(12) . .
C64 O26 Zn1 N2 133.2(12) . .
C64 O26 Zn1 O1 -41.1(13) . .
C64 O26 Zn1 O2 40.7(13) . .
C65 C64 O25 Eu1 -176.3(12) . .
C65 C64 O26 Zn1 -178.6(11) . .
C66 O27 Zn2 N3 -129.7(10) . .
C66 O27 Zn2 N4 132.0(10) . .
C66 O27 Zn2 O17 43.6(10) . .
C66 O27 Zn2 O18 -40.6(10) . .
C67 C66 O27 Zn2 179.7(9) . .
C67 C66 O28 Eu2 178.1(10) . .
C68 O29 Zn3 N5 128.7(9) . .
C68 O29 Zn3 N6 -135.0(9) . .
C68 O29 Zn3 O21 37.3(9) . .
C68 O29 Zn3 O22 -44.5(9) . .
C69 C68 O29 Zn3 -175.8(7) . .
C69 C68 O30 Eu3 176.0(7) . .
Eu1 O1 Zn1 N1 -173.9(4) . .
Eu1 O1 Zn1 N2 -89.0(9) . .
Eu1 O1 Zn1 O2 -21.6(3) . .
Eu1 O1 Zn1 O26 79.1(4) . .
Eu1 O2 Zn1 N1 88.2(8) . .
Eu1 O2 Zn1 N2 176.7(4) . .
Eu1 O2 Zn1 O1 22.1(3) . .
Eu1 O2 Zn1 O26 -78.2(4) . .
Eu2 C21 O6 Eu1 142(3) . .
Eu2 O17 Zn2 N3 84.5(9) . .
Eu2 O17 Zn2 N4 179.2(4) . .
Eu2 O17 Zn2 O18 19.9(3) . .
Eu2 O17 Zn2 O27 -80.2(3) . .
Eu2 O18 Zn2 N3 -177.1(4) . .
Eu2 O18 Zn2 N4 -85.4(9) . .
Eu2 O18 Zn2 O17 -19.8(3) . .
Eu2 O18 Zn2 O27 75.6(3) . .
Eu3 C24 C25 O14 177.3(12) 3_766 .
Eu3 C24 C25 O15 4.4(9) 3_766 3_766
Eu3 C24 O13 Eu2 -159(4) 3_766 .
Eu3 C25 O14 Eu2 163(3) 3_766 .
Eu3 O21 Zn3 N5 174.1(3) . .
Eu3 O21 Zn3 N6 83.8(9) . .
Eu3 O21 Zn3 O22 22.9(3) . .
Eu3 O21 Zn3 O29 -77.9(3) . .
Eu3 O22 Zn3 N5 -91.4(7) . .
Eu3 O22 Zn3 N6 179.5(3) . .
Eu3 O22 Zn3 O21 -22.0(3) . .
Eu3 O22 Zn3 O29 76.0(3) . .
N1 C9 C10 C11 73.9(14) . .
N2 C12 C13 C14 -167.8(14) . .
N2 C12 C13 C18 19.0(19) . .
N3 C34 C35 C36 71.4(16) . .
N4 C37 C38 C43 11(2) . .
N4 C37 C38 C39 -174.9(11) . .
N5 C53 C54 C55 -75.7(13) . .
N6 C56 C57 C62 1.8(17) . .
N6 C56 C57 C58 -175.6(11) . .
O1 C7 C2 C3 176.3(8) . .
O1 C7 C2 O3 -7.4(8) . .
O1 Eu1 O2 C18 149.8(8) . .
O1 Eu1 O2 Zn1 -20.3(3) . .
O1 Eu1 O3 C1 162.8(8) . .
O1 Eu1 O3 C2 -19.1(5) . .
O1 Eu1 O4 C17 -13.7(7) . .
O1 Eu1 O4 C19 161.0(6) . .
O1 Eu1 O5 C20 137.1(8) . .
O1 Eu1 O6 C21 -44.9(9) . .
O1 Eu1 O9 C22 147.2(7) . .
O1 Eu1 O10 C23 -59.1(10) . .
O1 Eu1 O25 C64 29.7(18) . .
O2 C18 C13 C12 -8.6(10) . .
O2 C18 C13 C14 178.3(9) . .
O2 Eu1 O1 C7 -136.3(7) . .
O2 Eu1 O1 Zn1 20.3(3) . .
O2 Eu1 O3 C1 -165.8(7) . .
O2 Eu1 O3 C2 12.2(6) . .
O2 Eu1 O4 C17 10.9(6) . .
O2 Eu1 O4 C19 -174.4(8) . .
O2 Eu1 O5 C20 -151.9(8) . .
O2 Eu1 O6 C21 50.5(9) . .
O2 Eu1 O9 C22 84.1(8) . .
O2 Eu1 O10 C23 -136.7(7) . .
O2 Eu1 O25 C64 -42.7(18) . .
O3 C2 C3 C4 -175.8(8) . .
O3 Eu1 O1 C7 16.6(6) . .
O3 Eu1 O1 Zn1 173.2(4) . .
O3 Eu1 O2 C18 120.0(8) . .
O3 Eu1 O2 Zn1 -50.1(4) . .
O3 Eu1 O4 C17 -102.3(6) . .
O3 Eu1 O4 C19 72.4(8) . .
O3 Eu1 O5 C20 71.8(8) . .
O3 Eu1 O6 C21 -71.4(8) . .
O3 Eu1 O9 C22 -157.0(7) . .
O3 Eu1 O10 C23 40.3(8) . .
O3 Eu1 O25 C64 79.0(18) . .
O4 C17 C18 C13 -176.5(8) . .
O4 C17 C18 O2 5.1(8) . .
O4 Eu1 O1 C7 -113.1(7) . .
O4 Eu1 O1 Zn1 43.5(4) . .
O4 Eu1 O2 C18 -9.4(7) . .
O4 Eu1 O2 Zn1 -179.5(4) . .
O4 Eu1 O3 C1 -80.4(8) . .
O4 Eu1 O3 C2 97.6(6) . .
O4 Eu1 O5 C20 -87.1(8) . .
O4 Eu1 O6 C21 80.7(8) . .
O4 Eu1 O9 C22 -24.0(8) . .
O4 Eu1 O10 C23 173.5(8) . .
O4 Eu1 O25 C64 -95.0(18) . .
O5 C20 C21 Eu2 -177.0(9) . .
O5 C20 C21 O6 -6.2(14) . .
O5 C20 C21 O8 172.8(10) . .
O5 C20 O7 Eu2 176.0(9) . .
O5 Eu1 O1 C7 -56.6(7) . .
O5 Eu1 O1 Zn1 100.0(3) . .
O5 Eu1 O2 C18 67.5(8) . .
O5 Eu1 O2 Zn1 -102.7(3) . .
O5 Eu1 O3 C1 -110.5(8) . .
O5 Eu1 O3 C2 67.5(5) . .
O5 Eu1 O4 C17 -72.7(6) . .
O5 Eu1 O4 C19 102.0(7) . .
O5 Eu1 O6 C21 3.5(7) . .
O5 Eu1 O9 C22 -131.7(7) . .
O5 Eu1 O10 C23 136.5(7) . .
O5 Eu1 O25 C64 -11(2) . .
O6 C21 Eu2 O7 -147(3) . .
O6 C21 Eu2 O8 48(3) . .
O6 C21 Eu2 O13 -57(3) . .
O6 C21 Eu2 O14 -34(3) . .
O6 C21 Eu2 O17 69(3) . .
O6 C21 Eu2 O18 168(3) . .
O6 C21 Eu2 O19 17(3) . .
O6 C21 Eu2 O20 -121(3) . .
O6 C21 Eu2 O28 132(3) . .
O6 C21 O8 Eu2 -166.5(8) . .
O6 Eu1 O1 C7 -12.0(8) . .
O6 Eu1 O1 Zn1 144.7(3) . .
O6 Eu1 O2 C18 23.7(9) . .
O6 Eu1 O2 Zn1 -146.5(3) . .
O6 Eu1 O3 C1 -39.4(7) . .
O6 Eu1 O3 C2 138.6(6) . .
O6 Eu1 O4 C17 -143.0(6) . .
O6 Eu1 O4 C19 31.6(7) . .
O6 Eu1 O5 C20 -7.5(8) . .
O6 Eu1 O9 C22 -82.5(7) . .
O6 Eu1 O10 C23 95.9(8) . .
O6 Eu1 O25 C64 176.7(16) . .
O7 C20 C21 Eu2 1.9(9) . .
O7 C20 C21 O6 172.7(10) . .
O7 C20 C21 O8 -8.3(15) . .
O7 C20 O5 Eu1 -169.0(9) . .
O7 Eu2 O8 C21 -11.5(7) . .
O7 Eu2 O13 C24 -155.5(9) . .
O7 Eu2 O14 C25 50.9(10) . .
O7 Eu2 O17 C43 -136.5(7) . .
O7 Eu2 O17 Zn2 69.4(5) . .
O7 Eu2 O18 C32 66.4(8) . .
O7 Eu2 O18 Zn2 -129.5(3) . .
O7 Eu2 O19 C42 158.9(6) . .
O7 Eu2 O19 C44 -22.0(10) . .
O7 Eu2 O20 C26 50.3(9) . .
O7 Eu2 O20 C27 -140.8(7) . .
O7 Eu2 O28 C66 148.6(17) . .
O8 C21 Eu2 O7 165.6(9) . .
O8 C21 Eu2 O13 -105.2(8) . .
O8 C21 Eu2 O14 -81.7(8) . .
O8 C21 Eu2 O17 21.7(8) . .
O8 C21 Eu2 O18 120.5(8) . .
O8 C21 Eu2 O19 -30.5(8) . .
O8 C21 Eu2 O20 -169.2(7) . .
O8 C21 Eu2 O28 84.4(8) . .
O8 C21 O6 Eu1 -179.3(8) . .
O8 Eu2 O7 C20 7.0(8) . .
O8 Eu2 O13 C24 134.6(9) . .
O8 Eu2 O14 C25 -43.6(10) . .
O8 Eu2 O17 C43 -70.8(7) . .
O8 Eu2 O17 Zn2 135.0(3) . .
O8 Eu2 O18 C32 140.1(7) . .
O8 Eu2 O18 Zn2 -55.8(6) . .
O8 Eu2 O19 C42 132.3(7) . .
O8 Eu2 O19 C44 -48.6(8) . .
O8 Eu2 O20 C26 25.3(11) . .
O8 Eu2 O20 C27 -165.8(6) . .
O8 Eu2 O28 C66 -141.0(17) . .
O9 C22 C23 O10 7.8(13) . .
O9 C22 C23 O12 -175.5(8) . .
O9 C22 O11 Eu3 -167.2(7) . .
O9 Eu1 O1 C7 74.7(7) . .
O9 Eu1 O1 Zn1 -128.6(3) . .
O9 Eu1 O2 C18 -139.1(7) . .
O9 Eu1 O2 Zn1 50.8(6) . .
O9 Eu1 O3 C1 49.7(7) . .
O9 Eu1 O3 C2 -132.3(6) . .
O9 Eu1 O4 C17 155.4(5) . .
O9 Eu1 O4 C19 -30.0(8) . .
O9 Eu1 O5 C20 47.1(9) . .
O9 Eu1 O6 C21 -138.8(8) . .
O9 Eu1 O10 C23 8.9(7) . .
O9 Eu1 O25 C64 132.8(18) . .
O10 C23 O12 Eu3 155.4(9) . .
O10 Eu1 O1 C7 135.1(6) . .
O10 Eu1 O1 Zn1 -68.2(6) . .
O10 Eu1 O2 C18 -62.9(8) . .
O10 Eu1 O2 Zn1 126.9(3) . .
O10 Eu1 O3 C1 17.8(8) . .
O10 Eu1 O3 C2 -164.2(5) . .
O10 Eu1 O4 C17 135.2(6) . .
O10 Eu1 O4 C19 -50.1(7) . .
O10 Eu1 O5 C20 -51.1(9) . .
O10 Eu1 O6 C21 151.9(8) . .
O10 Eu1 O9 C22 -3.8(6) . .
O10 Eu1 O25 C64 -156.1(19) . .
O11 C22 C23 O10 -172.2(9) . .
O11 C22 C23 O12 4.5(13) . .
O11 C22 O9 Eu1 179.8(8) . .
O11 Eu3 O12 C23 20.0(7) . .
O11 Eu3 O15 C25 -84.0(8) . 3_766
O11 Eu3 O16 C24 78.2(9) . 3_766
O11 Eu3 O21 C51 8.8(8) . .
O11 Eu3 O21 Zn3 -146.7(3) . .
O11 Eu3 O22 C62 -33.4(8) . .
O11 Eu3 O22 Zn3 147.2(3) . .
O11 Eu3 O23 C45 34.1(7) . .
O11 Eu3 O23 C46 -138.3(5) . .
O11 Eu3 O24 C61 154.0(7) . .
O11 Eu3 O24 C63 -31.0(8) . .
O11 Eu3 O30 C68 -177.8(11) . .
O12 C23 O10 Eu1 172.3(8) . .
O12 Eu3 O11 C22 -16.3(7) . .
O12 Eu3 O15 C25 -125.2(8) . 3_766
O12 Eu3 O16 C24 124.6(8) . 3_766
O12 Eu3 O21 C51 54.0(7) . .
O12 Eu3 O21 Zn3 -101.5(3) . .
O12 Eu3 O22 C62 -76.9(7) . .
O12 Eu3 O22 Zn3 103.8(3) . .
O12 Eu3 O23 C45 105.3(7) . .
O12 Eu3 O23 C46 -67.0(5) . .
O12 Eu3 O24 C61 84.3(7) . .
O12 Eu3 O24 C63 -100.7(9) . .
O12 Eu3 O30 C68 -0.1(14) . .
O13 C24 C25 Eu3 -177.0(10) . 3_766
O13 C24 C25 O14 0.3(17) . .
O13 C24 C25 O15 -172.6(10) . 3_766
O13 Eu2 O7 C20 -74.8(8) . .
O13 Eu2 O8 C21 69.3(7) . .
O13 Eu2 O14 C25 6.9(8) . .
O13 Eu2 O17 C43 12.4(9) . .
O13 Eu2 O17 Zn2 -141.7(3) . .
O13 Eu2 O18 C32 -19.9(8) . .
O13 Eu2 O18 Zn2 144.3(3) . .
O13 Eu2 O19 C42 -144.1(7) . .
O13 Eu2 O19 C44 35.0(8) . .
O13 Eu2 O20 C26 -31.5(9) . .
O13 Eu2 O20 C27 137.4(7) . .
O13 Eu2 O28 C66 -179.1(14) . .
O14 Eu2 O7 C20 -115.8(8) . .
O14 Eu2 O8 C21 115.9(8) . .
O14 Eu2 O13 C24 -7.3(8) . .
O14 Eu2 O17 C43 56.6(7) . .
O14 Eu2 O17 Zn2 -97.6(3) . .
O14 Eu2 O18 C32 -64.2(7) . .
O14 Eu2 O18 Zn2 99.9(3) . .
O14 Eu2 O19 C42 -73.0(6) . .
O14 Eu2 O19 C44 106.1(9) . .
O14 Eu2 O20 C26 -101.6(9) . .
O14 Eu2 O20 C27 67.2(6) . .
O14 Eu2 O28 C66 0(2) . .
O15 C25 O14 Eu2 165.5(9) 3_766 .
O15 Eu3 O11 C22 -164.8(7) . .
O15 Eu3 O12 C23 64.2(8) . .
O15 Eu3 O16 C24 -3.2(8) . 3_766
O15 Eu3 O21 C51 -138.2(6) . .
O15 Eu3 O21 Zn3 66.3(5) . .
O15 Eu3 O22 C62 54.7(7) . .
O15 Eu3 O22 Zn3 -124.7(3) . .
O15 Eu3 O23 C45 -24.0(8) . .
O15 Eu3 O23 C46 163.6(5) . .
O15 Eu3 O24 C61 -124.5(7) . .
O15 Eu3 O24 C63 50.5(8) . .
O15 Eu3 O30 C68 148.6(12) . .
O16 C24 C25 Eu3 5.5(10) 3_766 3_766
O16 C24 C25 O14 -177.2(12) 3_766 .
O16 C24 C25 O15 9.9(17) 3_766 3_766
O16 C24 O13 Eu2 -176.0(9) 3_766 .
O16 Eu3 O11 C22 125.9(7) . .
O16 Eu3 O12 C23 -30.1(9) . .
O16 Eu3 O15 C25 -2.4(8) . 3_766
O16 Eu3 O21 C51 -73.9(7) . .
O16 Eu3 O21 Zn3 130.6(3) . .
O16 Eu3 O22 C62 128.8(7) . .
O16 Eu3 O22 Zn3 -50.6(6) . .
O16 Eu3 O23 C45 -49.3(7) . .
O16 Eu3 O23 C46 138.4(6) . .
O16 Eu3 O24 C61 -147.0(7) . .
O16 Eu3 O24 C63 27.9(10) . .
O16 Eu3 O30 C68 -140.8(12) . .
O17 C43 C42 C41 178.6(8) . .
O17 C43 C42 O19 0.1(8) . .
O17 Eu2 O7 C20 81.6(9) . .
O17 Eu2 O8 C21 -161.1(7) . .
O17 Eu2 O13 C24 40.4(9) . .
O17 Eu2 O14 C25 -138.1(9) . .
O17 Eu2 O18 C32 -146.0(8) . .
O17 Eu2 O18 Zn2 18.1(3) . .
O17 Eu2 O19 C42 13.9(6) . .
O17 Eu2 O19 C44 -167.0(9) . .
O17 Eu2 O20 C26 -161.2(9) . .
O17 Eu2 O20 C27 7.6(8) . .
O17 Eu2 O28 C66 -35.0(16) . .
O18 C32 C31 C30 -175.6(9) . .
O18 C32 C31 C33 6.6(10) . .
O18 Eu2 O7 C20 158.2(8) . .
O18 Eu2 O8 C21 -94.8(8) . .
O18 Eu2 O13 C24 -54.8(9) . .
O18 Eu2 O14 C25 150.5(9) . .
O18 Eu2 O17 C43 136.2(8) . .
O18 Eu2 O17 Zn2 -17.9(3) . .
O18 Eu2 O19 C42 -18.1(7) . .
O18 Eu2 O19 C44 161.0(8) . .
O18 Eu2 O20 C26 175.0(10) . .
O18 Eu2 O20 C27 -16.2(6) . .
O18 Eu2 O28 C66 37.1(17) . .
O19 C42 C41 C40 178.4(8) . .
O19 Eu2 O7 C20 -19.2(10) . .
O19 Eu2 O8 C21 146.5(8) . .
O19 Eu2 O13 C24 66.3(8) . .
O19 Eu2 O14 C25 -73.5(9) . .
O19 Eu2 O17 C43 -15.9(7) . .
O19 Eu2 O17 Zn2 -170.0(4) . .
O19 Eu2 O18 C32 -116.0(7) . .
O19 Eu2 O18 Zn2 48.1(4) . .
O19 Eu2 O20 C26 -74.7(10) . .
O19 Eu2 O20 C27 94.1(7) . .
O19 Eu2 O28 C66 -84.6(17) . .
O20 C27 C32 C31 176.5(7) . .
O20 C27 C32 O18 -7.6(8) . .
O20 Eu2 O7 C20 -153.3(9) . .
O20 Eu2 O8 C21 13.6(9) . .
O20 Eu2 O13 C24 -84.7(8) . .
O20 Eu2 O14 C25 87.3(9) . .
O20 Eu2 O17 C43 114.1(7) . .
O20 Eu2 O17 Zn2 -40.1(4) . .
O20 Eu2 O18 C32 13.5(7) . .
O20 Eu2 O18 Zn2 177.7(4) . .
O20 Eu2 O19 C42 -100.5(7) . .
O20 Eu2 O19 C44 78.6(9) . .
O20 Eu2 O28 C66 88.4(17) . .
O21 C51 C46 C47 -173.9(7) . .
O21 C51 C46 O23 10.8(7) . .
O21 C51 C50 C49 173.1(7) . .
O21 C51 C50 C52 -9.8(9) . .
O21 Eu3 O11 C22 32.7(8) . .
O21 Eu3 O12 C23 -124.8(8) . .
O21 Eu3 O15 C25 71.4(10) . 3_766
O21 Eu3 O16 C24 -151.3(9) . 3_766
O21 Eu3 O22 C62 -159.7(8) . .
O21 Eu3 O22 Zn3 20.9(3) . .
O21 Eu3 O23 C45 -166.9(8) . .
O21 Eu3 O23 C46 20.7(5) . .
O21 Eu3 O24 C61 21.8(8) . .
O21 Eu3 O24 C63 -163.3(8) . .
O21 Eu3 O30 C68 -34.6(12) . .
O22 C62 C57 C56 -1.6(11) . .
O22 C62 C57 C58 175.7(8) . .
O22 C62 C61 C60 -175.6(8) . .
O22 C62 C61 O24 2.7(9) . .
O22 Eu3 O11 C22 -63.1(8) . .
O22 Eu3 O12 C23 166.1(8) . .
O22 Eu3 O15 C25 146.0(8) . 3_766
O22 Eu3 O16 C24 -88.3(10) . 3_766
O22 Eu3 O21 C51 135.2(7) . .
O22 Eu3 O21 Zn3 -20.3(3) . .
O22 Eu3 O23 C45 163.7(6) . .
O22 Eu3 O23 C46 -8.7(6) . .
O22 Eu3 O24 C61 0.1(6) . .
O22 Eu3 O24 C63 175.1(9) . .
O22 Eu3 O30 C68 35.5(12) . .
O23 C46 C47 C48 175.2(7) . .
O23 Eu3 O11 C22 57.8(7) . .
O23 Eu3 O12 C23 -60.3(7) . .
O23 Eu3 O15 C25 -27.3(9) . 3_766
O23 Eu3 O16 C24 155.7(9) . 3_766
O23 Eu3 O21 C51 -18.5(6) . .
O23 Eu3 O21 Zn3 -174.1(4) . .
O23 Eu3 O22 C62 -131.6(6) . .
O23 Eu3 O22 Zn3 49.1(4) . .
O23 Eu3 O24 C61 110.4(7) . .
O23 Eu3 O24 C63 -74.7(10) . .
O23 Eu3 O30 C68 -85.6(12) . .
O24 Eu3 O11 C22 -94.4(7) . .
O24 Eu3 O12 C23 102.0(8) . .
O24 Eu3 O15 C25 -164.5(9) . 3_766
O24 Eu3 O16 C24 19.6(10) . 3_766
O24 Eu3 O21 C51 114.5(6) . .
O24 Eu3 O21 Zn3 -41.0(4) . .
O24 Eu3 O22 C62 1.5(6) . .
O24 Eu3 O22 Zn3 -177.9(4) . .
O24 Eu3 O23 C45 78.6(8) . .
O24 Eu3 O23 C46 -93.8(6) . .
O24 Eu3 O30 C68 89.1(12) . .
O25 C64 O26 Zn1 -4(2) . .
O25 Eu1 O1 C7 146.1(8) . .
O25 Eu1 O1 Zn1 -57.2(3) . .
O25 Eu1 O2 C18 -131.1(8) . .
O25 Eu1 O2 Zn1 58.7(3) . .
O25 Eu1 O3 C1 108.0(7) . .
O25 Eu1 O3 C2 -74.0(6) . .
O25 Eu1 O4 C17 69.7(6) . .
O25 Eu1 O4 C19 -115.7(7) . .
O25 Eu1 O5 C20 176.6(7) . .
O25 Eu1 O6 C21 178.8(7) . .
O25 Eu1 O9 C22 76.2(7) . .
O25 Eu1 O10 C23 -70.0(7) . .
O26 C64 O25 Eu1 9(3) . .
O27 C66 O28 Eu2 -2(3) . .
O28 C66 O27 Zn2 0(2) . .
O28 Eu2 O7 C20 88.1(9) . .
O28 Eu2 O8 C21 -90.9(8) . .
O28 Eu2 O13 C24 172.4(8) . .
O28 Eu2 O14 C25 -172.9(8) . .
O28 Eu2 O17 C43 -143.1(8) . .
O28 Eu2 O17 Zn2 62.8(3) . .
O28 Eu2 O18 C32 136.2(8) . .
O28 Eu2 O18 Zn2 -59.7(3) . .
O28 Eu2 O19 C42 69.8(7) . .
O28 Eu2 O19 C44 -111.1(8) . .
O28 Eu2 O20 C26 114.8(9) . .
O28 Eu2 O20 C27 -76.4(7) . .
O29 C68 O30 Eu3 -5(2) . .
O30 C68 O29 Zn3 5.1(18) . .
O30 Eu3 O11 C22 162.3(6) . .
O30 Eu3 O12 C23 -158.5(7) . .
O30 Eu3 O15 C25 77.1(9) . 3_766
O30 Eu3 O16 C24 -81.2(9) . 3_766
O30 Eu3 O21 C51 -143.9(7) . .
O30 Eu3 O21 Zn3 60.6(3) . .
O30 Eu3 O22 C62 121.7(7) . .
O30 Eu3 O22 Zn3 -57.7(3) . .
O30 Eu3 O23 C45 -109.3(7) . .
O30 Eu3 O23 C46 78.4(5) . .
O30 Eu3 O24 C61 -62.0(7) . .
O30 Eu3 O24 C63 113.0(8) . .
#BEGIN Loops that were not found in dictionaries:
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
1 -0.493 0.000 0.500 1823.7 906.8
2 -0.544 0.500 0.000 1823.7 906.8
#END Loops that were not found in dictionaries
