#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/51/7035179.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035179
loop_
_publ_author_name
'Waitschat, Steve'
'Wharmby, Michael T.'
'Stock, Norbert'
_publ_section_title
;
 Flow-synthesis of carboxylate and phosphonate based metal-organic
 frameworks under non-solvothermal reaction conditions.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11235
_journal_page_last               11240
_journal_paper_doi               10.1039/c5dt01100k
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C3 Cd N O4 P, 2.763(O)'
_chemical_formula_sum            'C3 Cd N O6.76 P'
_chemical_formula_weight         301.63
_space_group_IT_number           148
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            18
_cell_length_a                   27.4100(8)
_cell_length_b                   27.4100(8)
_cell_length_c                   6.7279(2)
_cell_measurement_temperature    298
_cell_volume                     4377.5(2)
_diffrn_ambient_temperature      298
_diffrn_measurement_device_type  'Stoe Stadi P'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a~1~'
_diffrn_radiation_wavelength     1.540562
_exptl_crystal_density_diffrn    2.060
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'Not measured'
_pd_char_colour                  white
_pd_meas_number_of_points        5733
_pd_proc_2theta_range_inc        0.015
_pd_proc_2theta_range_max        88.98500
_pd_proc_2theta_range_min        3.005
_pd_proc_ls_prof_R_factor        0.0493
_pd_proc_ls_prof_wR_expected     0.0563
_pd_proc_ls_prof_wR_factor       0.0643
_refine_ls_goodness_of_fit_all   1.14125
_refine_ls_number_parameters     0.000000
_refine_ls_number_restraints     21
_refine_ls_R_I_factor            0.0156
_refine_ls_shift/su_max          3.5982631e-015
_reflns_d_resolution_high        1.09473
_reflns_d_resolution_low         13.70501
_reflns_limit_h_max              20
_reflns_limit_h_min              0
_reflns_limit_k_max              21
_reflns_limit_k_min              -24
_reflns_limit_l_max              6
_reflns_limit_l_min              -6
_cod_data_source_file            c5dt01100k2.cif
_cod_data_source_block           STA-12(Cd)-AP.cif
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'Not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7035179.cif.
;
_cod_original_cell_volume        4377.5(3)
_cod_original_sg_symbol_H-M      R-3
_cod_database_code               7035179
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z '
'-x+y, -x, z '
'-y, x-y, z '
'y, -x+y, -z '
'x-y, x, -z '
'-x, -y, -z '
'x-1/3, y+1/3, z+1/3 '
'-x+y-1/3, -x+1/3, z+1/3 '
'-y-1/3, x-y+1/3, z+1/3 '
'y-1/3, -x+y+1/3, -z+1/3 '
'x-y-1/3, x+1/3, -z+1/3 '
'-x-1/3, -y+1/3, -z+1/3 '
'x+1/3, y-1/3, z-1/3 '
'-x+y+1/3, -x-1/3, z-1/3 '
'-y+1/3, x-y-1/3, z-1/3 '
'y+1/3, -x+y-1/3, -z-1/3 '
'x-y+1/3, x-1/3, -z-1/3 '
'-x+1/3, -y-1/3, -z-1/3 '
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_B_iso_or_equiv
Cd1 Cd 0 0.30384(14) 0.03606(14) -0.3202(6) 1 0.92(3)
P1 P 0 0.4273(4) 0.0388(6) -0.470(2) 1 0.92(3)
O1 O 0 0.4815(9) 0.0864(11) -0.538(4) 1 0.92(3)
O2 O 0 0.3962(10) 0.0554(10) -0.322(4) 1 0.92(3)
O3 O 0 0.3901(11) 0.0074(10) -0.645(4) 1 0.92(3)
O100 O 0 0.2104(15) 0.0094(13) -0.238(4) 1 4.8(10)
N1 N 0 0.4590(14) 0.0020(13) -0.130(4) 1 0.92(3)
C1 C 0 0.4406(14) -0.0141(16) -0.344(5) 1 0.92(3)
C2 C 0 0.4510(15) -0.0538(15) -0.052(5) 1 0.92(3)
C3 C 0 0.5223(15) 0.0428(19) -0.155(5) 1 0.92(3)
O101 O 0 0.2824(21) 0.5722(14) 0.281(6) 0.73684 7.2(9)
O102 O 0 0.0835(19) 0.1747(25) 0.823(8) 0.56634 7.2(9)
O103 O 0 0.310(2) 0.592(3) 0.780(6) 0.68641 7.2(9)
O104 O 0 0.2013(16) 0.5218(19) 0.060(6) 0.77439 7.2(9)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
O3 Cd1 O2 83.2(11) 8_655 1_555 1_555
N1 Cd1 O3 156.4(10) 15_555 1_555 8_655
N1 Cd1 O2 90.5(10) 15_555 1_555 1_555
O100 Cd1 N1 99.1(11) 1_555 1_555 15_555
O100 Cd1 O3 91.8(12) 1_555 1_555 8_655
O100 Cd1 O2 166.0(10) 1_555 1_555 1_555
O3 Cd1 O100 88.5(8) 15_556 1_555 1_555
O3 Cd1 N1 108.4(12) 15_556 1_555 15_555
O3 Cd1 O3 92.6(12) 15_556 1_555 8_655
O3 Cd1 O2 78.7(8) 15_556 1_555 1_555
O2 Cd1 O3 170.8(12) 15_555 1_555 15_556
O2 Cd1 O100 91.3(8) 15_555 1_555 1_555
O2 Cd1 N1 80.7(12) 15_555 1_555 15_555
O2 Cd1 O3 78.2(10) 15_555 1_555 8_655
O2 Cd1 O2 100.5(10) 15_555 1_555 1_555
O3 P1 O1 110.9(17) 1_555 1_555 1_555
O2 P1 O3 111.1(17) 1_555 1_555 1_555
O2 P1 O1 114.0(18) 1_555 1_555 1_555
C1 P1 O2 106.9(18) 1_555 1_555 1_555
C1 P1 O3 104.4(18) 1_555 1_555 1_555
C1 P1 O1 108.9(18) 1_555 1_555 1_555
C2 N1 C1 100(3) 1_555 1_555 1_555
C3 N1 C2 108(4) 1_555 1_555 1_555
C3 N1 C1 101(3) 1_555 1_555 1_555
P1 C1 N1 112(3) 1_555 1_555 1_555
C3 C2 N1 107(3) 6_655 1_555 1_555
N1 C3 C2 107(3) 1_555 1_555 6_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
Cd1 O2 2.31(3) 1_555 1_555
Cd1 O2 2.38(3) 1_555 15_555
Cd1 O3 2.32(2) 1_555 8_655
Cd1 O3 2.36(3) 1_555 15_556
Cd1 O100 2.35(4) 1_555 1_555
Cd1 N1 2.33(4) 1_555 15_555
P1 O1 1.48(2) 1_555 1_555
P1 O2 1.52(3) 1_555 1_555
P1 O3 1.51(3) 1_555 1_555
P1 C1 1.87(5) 1_555 1_555
O1 P1 1.48(2) 1_555 1_555
N1 C1 1.52(4) 1_555 1_555
N1 C2 1.53(6) 1_555 1_555
N1 C3 1.53(5) 1_555 1_555
C2 C3 1.53(5) 1_555 6_655
loop_
_pd_proc_point_id
_pd_meas_2theta_scan
_pd_proc_intensity_total
_pd_calc_intensity_total
_pd_proc_ls_weight
1 3.00500 604.97400 575.00000 0.00174
2 3.02000 604.80791 617.00000 0.00162
3 3.03500 604.64753 616.00000 0.00162
4 3.05000 604.49275 607.00000 0.00165
5 3.06500 604.34347 603.00000 0.00166
6 3.08000 604.19957 585.00000 0.00171
7 3.09500 604.06097 601.00000 0.00166
8 3.11000 603.92755 689.00000 0.00145
9 3.12500 603.79921 654.00000 0.00153
10 3.14000 603.67587 597.00000 0.00168
11 3.15500 603.55741 647.00000 0.00155
12 3.17000 603.44376 591.00000 0.00169
13 3.18500 603.33481 567.00000 0.00176
14 3.20000 603.23047 576.00000 0.00174
15 3.21500 603.13065 611.00000 0.00164
16 3.23000 603.03527 615.00000 0.00163
17 3.24500 602.94424 587.00000 0.00170
18 3.26000 602.85747 579.00000 0.00173
19 3.27500 602.77489 609.00000 0.00164
20 3.29000 602.69640 663.00000 0.00151
21 3.30500 602.62192 623.00000 0.00161
22 3.32000 602.55139 577.00000 0.00173
23 3.33500 602.48473 580.00000 0.00172
24 3.35000 602.42185 572.00000 0.00175
25 3.36500 602.36268 575.00000 0.00174
26 3.38000 602.30716 573.00000 0.00175
27 3.39500 602.25522 646.00000 0.00155
28 3.41000 602.20678 628.00000 0.00159
29 3.42500 602.16177 624.00000 0.00160
30 3.44000 602.12015 586.00000 0.00171
31 3.45500 602.08183 583.00000 0.00172
32 3.47000 602.04676 594.00000 0.00168
33 3.48500 602.01488 618.00000 0.00162
34 3.50000 601.98614 620.00000 0.00161
35 3.51500 601.96047 622.00000 0.00161
36 3.53000 601.93783 620.00000 0.00161
37 3.54500 601.91847 567.00000 0.00176
38 3.56000 601.90254 573.00000 0.00175
39 3.57500 601.89002 614.00000 0.00163
40 3.59000 601.88091 591.00000 0.00169
41 3.60500 601.87521 606.00000 0.00165
42 3.62000 601.87292 632.00000 0.00158
43 3.63500 601.87406 626.00000 0.00160
44 3.65000 601.87867 630.00000 0.00159
45 3.66500 601.88677 618.00000 0.00162
46 3.68000 601.89843 587.00000 0.00170
47 3.69500 601.91371 572.00000 0.00175
48 3.71000 601.93272 637.00000 0.00157
49 3.72500 601.95557 642.00000 0.00156
50 3.74000 601.98242 558.00000 0.00179
51 3.75500 602.01347 606.00000 0.00165
52 3.77000 602.04901 570.00000 0.00175
53 3.78500 602.08939 614.00000 0.00163
54 3.80000 602.13511 581.00000 0.00172
55 3.81500 602.18691 589.00000 0.00170
56 3.83000 602.24588 614.00000 0.00163
57 3.84500 602.31380 575.00000 0.00174
58 3.86000 602.39403 612.00000 0.00163
59 3.87500 602.49439 604.00000 0.00166
60 3.89000 602.65212 608.00000 0.00164
61 3.90500 602.80850 577.00000 0.00173
62 3.92000 602.85395 633.00000 0.00158
63 3.93500 602.90172 598.00000 0.00167
64 3.95000 602.95181 621.00000 0.00161
65 3.96500 603.00423 600.00000 0.00167
66 3.98000 603.05898 617.00000 0.00162
67 3.99500 603.11609 640.00000 0.00156
68 4.01000 603.17556 620.00000 0.00161
69 4.02500 603.23743 624.00000 0.00160
70 4.04000 603.30171 604.00000 0.00166
71 4.05500 603.36843 589.00000 0.00170
72 4.07000 603.43761 589.00000 0.00170
73 4.08500 603.50930 600.00000 0.00167
74 4.10000 603.58353 585.00000 0.00171
75 4.11500 603.66033 623.00000 0.00161
76 4.13000 603.73976 592.00000 0.00169
77 4.14500 603.82186 607.00000 0.00165
78 4.16000 603.90669 589.00000 0.00170
79 4.17500 603.99429 605.00000 0.00165
80 4.19000 604.08473 589.00000 0.00170
81 4.20500 604.17807 566.00000 0.00177
82 4.22000 604.27439 578.00000 0.00173
83 4.23500 604.37375 603.00000 0.00166
84 4.25000 604.47624 642.00000 0.00156
85 4.26500 604.58194 631.00000 0.00158
86 4.28000 604.69094 623.00000 0.00161
87 4.29500 604.80334 615.00000 0.00163
88 4.31000 604.91923 574.00000 0.00174
89 4.32500 605.03872 635.00000 0.00157
90 4.34000 605.16192 629.00000 0.00159
91 4.35500 605.28896 619.00000 0.00162
92 4.37000 605.41995 595.00000 0.00168
93 4.38500 605.55504 612.00000 0.00163
94 4.40000 605.69436 594.00000 0.00168
95 4.41500 605.83806 588.00000 0.00170
96 4.43000 605.98630 608.00000 0.00164
97 4.44500 606.13923 634.00000 0.00158
98 4.46000 606.29704 625.00000 0.00160
99 4.47500 606.45990 626.00000 0.00160
100 4.49000 606.62801 568.00000 0.00176
101 4.50500 606.80156 627.00000 0.00159
102 4.52000 606.98078 655.00000 0.00153
103 4.53500 607.16588 595.00000 0.00168
104 4.55000 607.35709 643.00000 0.00156
105 4.56500 607.55467 650.00000 0.00154
106 4.58000 607.75888 655.00000 0.00153
107 4.59500 607.96998 649.00000 0.00154
108 4.61000 608.18827 607.00000 0.00165
109 4.62500 608.41404 577.00000 0.00173
110 4.64000 608.64762 598.00000 0.00167
111 4.65500 608.88935 610.00000 0.00164
112 4.67000 609.13956 611.00000 0.00164
113 4.68500 609.39864 645.00000 0.00155
114 4.70000 609.66698 582.00000 0.00172
115 4.71500 609.94498 588.00000 0.00170
116 4.73000 610.23309 608.00000 0.00164
117 4.74500 610.53175 613.00000 0.00163
118 4.76000 610.84145 625.00000 0.00160
119 4.77500 611.16270 628.00000 0.00159
120 4.79000 611.49604 623.00000 0.00161
121 4.80500 611.84202 601.00000 0.00166
122 4.82000 612.20125 604.00000 0.00166
123 4.83500 612.57437 610.00000 0.00164
124 4.85000 612.96202 610.00000 0.00164
125 4.86500 613.36493 601.00000 0.00166
126 4.88000 613.78384 574.00000 0.00174
127 4.89500 614.21953 623.00000 0.00161
128 4.91000 614.67285 603.00000 0.00166
129 4.92500 615.14468 603.00000 0.00166
130 4.94000 615.63596 612.00000 0.00163
131 4.95500 616.14769 556.00000 0.00180
132 4.97000 616.68093 569.00000 0.00176
133 4.98500 617.23680 621.00000 0.00161
134 5.00000 617.81651 632.00000 0.00158
135 5.01500 618.42132 637.00000 0.00157
136 5.03000 619.05260 611.00000 0.00164
137 5.04500 619.71179 657.00000 0.00152
138 5.06000 620.40044 599.00000 0.00167
139 5.07500 621.12020 609.00000 0.00164
140 5.09000 621.87282 614.00000 0.00163
141 5.10500 622.66020 609.00000 0.00164
142 5.12000 623.48436 596.00000 0.00168
143 5.13500 624.34747 566.00000 0.00177
144 5.15000 625.25186 622.00000 0.00161
145 5.16500 626.20003 615.00000 0.00163
146 5.18000 627.19468 671.00000 0.00149
147 5.19500 628.23871 623.00000 0.00161
148 5.21000 629.33526 606.00000 0.00165
149 5.22500 630.48770 624.00000 0.00160
150 5.24000 631.69970 696.00000 0.00144
151 5.25500 632.97524 653.00000 0.00153
152 5.27000 634.31863 645.00000 0.00155
153 5.28500 635.73456 587.00000 0.00170
154 5.30000 637.22814 579.00000 0.00173
155 5.31500 638.80496 603.00000 0.00166
156 5.33000 640.47112 629.00000 0.00159
157 5.34500 642.23333 671.00000 0.00149
158 5.36000 644.09895 632.00000 0.00158
159 5.37500 646.07609 640.00000 0.00156
160 5.39000 648.17374 671.00000 0.00149
161 5.40500 650.40184 654.00000 0.00153
162 5.42000 652.77149 652.00000 0.00153
163 5.43500 655.29514 683.00000 0.00146
164 5.45000 657.98740 674.00000 0.00148
165 5.46500 660.86036 664.00000 0.00151
166 5.48000 663.93357 716.00000 0.00140
167 5.49500 667.22675 685.00000 0.00146
168 5.51000 670.76232 687.00000 0.00146
169 5.52500 674.56595 712.00000 0.00140
170 5.54000 678.66714 682.00000 0.00147
171 5.55500 683.10008 718.00000 0.00139
172 5.57000 687.90461 710.00000 0.00141
173 5.58500 693.12755 678.00000 0.00147
174 5.60000 698.82435 653.00000 0.00153
175 5.61500 705.06135 684.00000 0.00146
176 5.63000 711.91866 754.00000 0.00133
177 5.64500 719.49415 773.00000 0.00129
178 5.66000 727.90880 725.00000 0.00138
179 5.67500 737.31403 786.00000 0.00127
180 5.69000 747.90170 807.00000 0.00124
181 5.70500 759.91744 835.00000 0.00120
182 5.72000 773.67773 792.00000 0.00126
183 5.73500 789.58857 798.00000 0.00125
184 5.75000 808.15814 856.00000 0.00117
185 5.76500 829.98347 848.00000 0.00118
186 5.78000 855.67874 901.00000 0.00111
187 5.79500 885.73228 923.00000 0.00108
188 5.81000 920.36044 956.00000 0.00105
189 5.82500 959.48224 959.00000 0.00104
190 5.84000 1002.83591 992.00000 0.00101
191 5.85500 1050.12592 1072.00000 0.00093
192 5.87000 1101.11237 1082.00000 0.00092
193 5.88500 1155.64016 1062.00000 0.00094
194 5.90000 1213.63708 1167.00000 0.00086
195 5.91500 1275.10248 1226.00000 0.00082
196 5.93000 1340.09582 1271.00000 0.00079
197 5.94500 1408.72798 1349.00000 0.00074
198 5.96000 1481.15570 1376.00000 0.00073
199 5.97500 1557.57859 1447.00000 0.00069
200 5.99000 1638.23827 1507.00000 0.00066
201 6.00500 1723.41937 1547.00000 0.00065
202 6.02000 1813.45195 1758.00000 0.00057
203 6.03500 1908.71549 1788.00000 0.00056
204 6.05000 2009.64422 1881.00000 0.00053
205 6.06500 2116.73401 1932.00000 0.00052
206 6.08000 2230.55095 2110.00000 0.00047
207 6.09500 2351.74188 2296.00000 0.00044
208 6.11000 2481.04713 2442.00000 0.00041
209 6.12500 2619.31620 2550.00000 0.00039
210 6.14000 2767.52528 2708.00000 0.00037
211 6.15500 2926.79594 2929.00000 0.00034
212 6.17000 3098.43173 3042.00000 0.00033
213 6.18500 3283.93891 3199.00000 0.00031
214 6.20000 3485.06413 3405.00000 0.00029
215 6.21500 3703.83229 3658.00000 0.00027
216 6.23000 3942.58453 3891.00000 0.00026
217 6.24500 4204.00877 4057.00000 0.00025
218 6.26000 4491.14661 4255.00000 0.00024
219 6.27500 4807.34279 4703.00000 0.00021
220 6.29000 5156.06819 5315.00000 0.00019
221 6.30500 5540.47705 5698.00000 0.00018
222 6.32000 5962.42111 5923.00000 0.00017
223 6.33500 6420.38383 6378.00000 0.00016
224 6.35000 6905.35986 6926.00000 0.00014
225 6.36500 7393.18541 7522.00000 0.00013
226 6.38000 7832.11897 7733.00000 0.00013
227 6.39500 8128.95289 8514.00000 0.00012
228 6.41000 8151.80339 8483.00000 0.00012
229 6.42500 7785.28293 8077.00000 0.00012
230 6.44000 7034.95239 7003.00000 0.00014
231 6.45500 6064.18721 6158.00000 0.00016
232 6.47000 5083.37112 5196.00000 0.00019
233 6.48500 4226.35504 4257.00000 0.00023
234 6.50000 3532.91552 3494.00000 0.00029
235 6.51500 2990.44225 3026.00000 0.00033
236 6.53000 2569.98182 2543.00000 0.00039
237 6.54500 2242.96943 2165.00000 0.00046
238 6.56000 1986.21731 1983.00000 0.00050
239 6.57500 1782.20881 1799.00000 0.00056
240 6.59000 1618.05591 1636.00000 0.00061
241 6.60500 1484.33272 1480.00000 0.00068
242 6.62000 1374.11899 1409.00000 0.00071
243 6.63500 1282.29033 1314.00000 0.00076
244 6.65000 1205.01113 1257.00000 0.00080
245 6.66500 1139.37707 1149.00000 0.00087
246 6.68000 1083.16319 1065.00000 0.00094
247 6.69500 1034.64553 1045.00000 0.00096
248 6.71000 992.47374 975.00000 0.00103
249 6.72500 955.57917 937.00000 0.00107
250 6.74000 923.10791 870.00000 0.00115
251 6.75500 894.37144 862.00000 0.00116
252 6.77000 868.80986 800.00000 0.00125
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1931 31.95500 216.44860 217.00000 0.00461
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1933 31.98500 218.18394 249.00000 0.00402
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1936 32.03000 222.61128 236.00000 0.00424
1937 32.04500 224.77446 232.00000 0.00431
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1940 32.09000 234.56457 260.00000 0.00385
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1945 32.16500 272.21366 265.00000 0.00377
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1949 32.22500 329.60266 326.00000 0.00307
1950 32.24000 343.24385 356.00000 0.00281
1951 32.25500 352.93294 354.00000 0.00282
1952 32.27000 356.54475 352.00000 0.00284
1953 32.28500 353.26914 345.00000 0.00290
1954 32.30000 344.37503 353.00000 0.00283
1955 32.31500 332.66128 336.00000 0.00298
1956 32.33000 321.00857 316.00000 0.00316
1957 32.34500 311.38102 314.00000 0.00318
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1960 32.39000 301.53488 332.00000 0.00301
1961 32.40500 305.11902 317.00000 0.00315
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1963 32.43500 323.48785 328.00000 0.00305
1964 32.45000 338.91111 338.00000 0.00296
1965 32.46500 358.96880 324.00000 0.00309
1966 32.48000 383.83048 389.00000 0.00257
1967 32.49500 413.24679 417.00000 0.00240
1968 32.51000 446.24958 473.00000 0.00211
1969 32.52500 480.79273 486.00000 0.00206
1970 32.54000 513.42584 493.00000 0.00203
1971 32.55500 539.34288 551.00000 0.00181
1972 32.57000 553.38362 588.00000 0.00170
1973 32.58500 552.12888 582.00000 0.00172
1974 32.60000 535.77497 519.00000 0.00193
1975 32.61500 507.88861 515.00000 0.00194
1976 32.63000 473.36526 493.00000 0.00203
1977 32.64500 436.73087 452.00000 0.00221
1978 32.66000 401.49693 423.00000 0.00236
1979 32.67500 369.92998 380.00000 0.00263
1980 32.69000 343.04786 377.00000 0.00265
1981 32.70500 320.92432 382.00000 0.00262
1982 32.72000 303.11838 311.00000 0.00322
1983 32.73500 289.01315 289.00000 0.00346
1984 32.75000 278.00451 297.00000 0.00337
1985 32.76500 269.57928 266.00000 0.00376
1986 32.78000 263.36310 248.00000 0.00403
1987 32.79500 259.07831 258.00000 0.00388
1988 32.81000 256.52179 247.00000 0.00405
1989 32.82500 255.56442 252.00000 0.00397
1990 32.84000 256.10049 260.00000 0.00385
1991 32.85500 257.99574 261.00000 0.00383
1992 32.87000 261.02249 261.00000 0.00383
1993 32.88500 264.81548 235.00000 0.00426
1994 32.90000 268.77974 248.00000 0.00403
1995 32.91500 272.08430 255.00000 0.00392
1996 32.93000 273.74624 256.00000 0.00391
1997 32.94500 272.96240 262.00000 0.00382
1998 32.96000 269.56941 259.00000 0.00386
1999 32.97500 264.23916 246.00000 0.00407
2000 32.99000 258.13684 255.00000 0.00392
2001 33.00500 252.35261 245.00000 0.00408
2002 33.02000 247.58797 236.00000 0.00424
2003 33.03500 244.17405 209.00000 0.00478
2004 33.05000 242.22437 227.00000 0.00441
2005 33.06500 241.77069 240.00000 0.00417
2006 33.08000 242.84278 253.00000 0.00395
2007 33.09500 245.50199 248.00000 0.00403
2008 33.11000 249.84163 254.00000 0.00394
2009 33.12500 255.95845 255.00000 0.00392
2010 33.14000 263.89420 276.00000 0.00362
2011 33.15500 273.54837 311.00000 0.00322
2012 33.17000 284.56828 320.00000 0.00312
2013 33.18500 296.22325 320.00000 0.00312
2014 33.20000 307.28556 342.00000 0.00292
2015 33.21500 316.01268 371.00000 0.00270
2016 33.23000 320.43460 390.00000 0.00256
2017 33.24500 319.10323 373.00000 0.00268
2018 33.26000 311.99000 319.00000 0.00313
2019 33.27500 300.69440 292.00000 0.00342
2020 33.29000 287.60346 328.00000 0.00305
2021 33.30500 274.77935 322.00000 0.00311
2022 33.32000 263.44067 292.00000 0.00342
2023 33.33500 254.05900 261.00000 0.00383
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2030 33.44000 234.95644 254.00000 0.00394
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2101 34.50500 490.54519 455.00000 0.00220
2102 34.52000 538.75399 489.00000 0.00204
2103 34.53500 585.97017 530.00000 0.00189
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2105 34.56500 652.83723 582.00000 0.00172
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2107 34.59500 642.08609 589.00000 0.00170
2108 34.61000 605.76989 566.00000 0.00177
2109 34.62500 557.78888 567.00000 0.00176
2110 34.64000 506.54289 509.00000 0.00196
2111 34.65500 458.07102 485.00000 0.00206
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2113 34.68500 379.60449 405.00000 0.00247
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2115 34.71500 326.71186 345.00000 0.00290
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