#------------------------------------------------------------------------------
#$Date: 2015-07-11 00:13:22 +0300 (Sat, 11 Jul 2015) $
#$Revision: 143486 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/52/7035212.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035212
loop_
_publ_author_name
'Tanimoto, Hiroki'
'Nagao, Tomohiko'
'Fujiwara, Taro'
'Nishiyama, Yasuhiro'
'Morimoto, Tsumoru'
'Suzuka, Toshimasa'
'Tsutsumi, Ken'
'Kakiuchi, Kiyomi'
_publ_section_title
;
 Stepwise synthesis and characterization of germa[4], [5], [8], and
 [10]pericyclynes.
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11811
_journal_page_last               11818
_journal_paper_doi               10.1039/c5dt01411e
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C40 H70 Ge5'
_chemical_formula_sum            'C40 H70 Ge5'
_chemical_formula_weight         913.91
_chemical_name_systematic        iPrGe5
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2015-05-12 deposited with the CCDC.
2015-05-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   11.2890(2)
_cell_length_b                   49.9471(9)
_cell_length_c                   16.5855(3)
_cell_measurement_reflns_used    110205
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      3.05
_cell_volume                     9351.8(3)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.1'
_computing_publication_material  'CrystalStructure 4.1 (Rigaku, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      123(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.1049
_diffrn_reflns_av_unetI/netI     0.0411
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       64
_diffrn_reflns_limit_k_min       -64
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            152447
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_min         3.048
_exptl_absorpt_coefficient_mu    3.200
_exptl_absorpt_correction_T_max  0.681
_exptl_absorpt_correction_T_min  0.667
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.298
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3760
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.120
_refine_diff_density_max         0.699
_refine_diff_density_min         -0.669
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     426
_refine_ls_number_reflns         10726
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.128
_refine_ls_R_factor_all          0.0734
_refine_ls_R_factor_gt           0.0639
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+43.0176P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0942
_refine_ls_wR_factor_ref         0.0971
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9182
_reflns_number_total             10726
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt01411e2.cif
_cod_data_source_block           shelxl
_cod_depositor_comments
'Adding full bibliography for 7035212--7035215.cif.'
_cod_database_code               7035212
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.612
_shelx_estimated_absorpt_t_max   0.700
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, z'
'x, -y+1/2, z+1/2'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, -z'
'-x, y-1/2, -z-1/2'
'x-1/2, y, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ge1 Ge 0.79705(4) 0.06577(2) 0.54488(3) 0.02200(10) Uani 1 1 d . .
Ge2 Ge 0.38889(4) 0.05249(2) 0.43152(3) 0.02100(9) Uani 1 1 d . .
Ge3 Ge 0.22077(4) 0.13960(2) 0.33251(3) 0.02180(10) Uani 1 1 d . .
Ge4 Ge 0.50543(4) 0.21126(2) 0.41380(3) 0.02534(10) Uani 1 1 d . .
Ge5 Ge 0.70213(4) 0.15822(2) 0.62895(3) 0.02580(10) Uani 1 1 d . .
C1 C 0.6472(4) 0.06020(8) 0.4931(3) 0.0255(9) Uani 1 1 d . .
C2 C 0.5485(4) 0.05749(8) 0.4671(3) 0.0259(9) Uani 1 1 d . .
C3 C 0.3328(4) 0.08576(8) 0.3892(2) 0.0237(8) Uani 1 1 d . .
C4 C 0.2923(4) 0.10646(8) 0.3652(2) 0.0248(8) Uani 1 1 d . .
C5 C 0.3396(4) 0.16662(8) 0.3482(3) 0.0238(8) Uani 1 1 d . .
C6 C 0.4077(4) 0.18413(8) 0.3670(2) 0.0243(9) Uani 1 1 d . .
C7 C 0.6060(5) 0.19220(9) 0.4869(3) 0.0352(11) Uani 1 1 d . .
C8 C 0.6538(4) 0.17898(9) 0.5379(3) 0.0325(10) Uani 1 1 d . .
C9 C 0.7723(4) 0.12570(8) 0.5919(3) 0.0269(9) Uani 1 1 d . .
C10 C 0.7938(4) 0.10286(8) 0.5735(3) 0.0268(9) Uani 1 1 d . .
C11 C 0.7985(4) 0.04432(8) 0.6432(3) 0.0300(10) Uani 1 1 d . .
H11 H 0.7976 0.0251 0.6267 0.036 Uiso 1 1 calc R U
C12 C 0.6869(4) 0.04935(10) 0.6933(3) 0.0361(11) Uani 1 1 d . .
H12A H 0.6861 0.0680 0.7118 0.043 Uiso 1 1 calc R U
H12B H 0.6865 0.0374 0.7400 0.043 Uiso 1 1 calc R U
H12C H 0.6166 0.0459 0.6602 0.043 Uiso 1 1 calc R U
C13 C 0.9098(5) 0.04889(13) 0.6917(3) 0.0526(15) Uani 1 1 d . .
H13A H 0.9103 0.0369 0.7384 0.063 Uiso 1 1 calc R U
H13B H 0.9121 0.0675 0.7102 0.063 Uiso 1 1 calc R U
H13C H 0.9792 0.0453 0.6579 0.063 Uiso 1 1 calc R U
C14 C 0.9296(4) 0.05686(9) 0.4748(3) 0.0350(11) Uani 1 1 d . .
H14 H 1.0026 0.0576 0.5089 0.042 Uiso 1 1 calc R U
C15 C 0.9473(6) 0.07613(11) 0.4082(4) 0.0631(19) Uani 1 1 d . .
H15A H 0.9581 0.0941 0.4304 0.076 Uiso 1 1 calc R U
H15B H 0.8777 0.0760 0.3728 0.076 Uiso 1 1 calc R U
H15C H 1.0177 0.0711 0.3772 0.076 Uiso 1 1 calc R U
C16 C 0.9192(5) 0.02833(9) 0.4446(3) 0.0443(13) Uani 1 1 d . .
H16A H 0.9891 0.0238 0.4123 0.053 Uiso 1 1 calc R U
H16B H 0.8479 0.0266 0.4114 0.053 Uiso 1 1 calc R U
H16C H 0.9139 0.0161 0.4907 0.053 Uiso 1 1 calc R U
C17 C 0.2921(4) 0.04338(8) 0.5256(3) 0.0291(9) Uani 1 1 d . .
H17 H 0.2122 0.0379 0.5056 0.035 Uiso 1 1 calc R U
C18 C 0.2752(6) 0.06721(10) 0.5810(3) 0.0500(15) Uani 1 1 d . .
H18A H 0.2230 0.0622 0.6257 0.060 Uiso 1 1 calc R U
H18B H 0.2393 0.0820 0.5507 0.060 Uiso 1 1 calc R U
H18C H 0.3521 0.0729 0.6023 0.060 Uiso 1 1 calc R U
C19 C 0.3454(5) 0.01958(9) 0.5706(3) 0.0350(11) Uani 1 1 d . .
H19A H 0.3541 0.0044 0.5335 0.042 Uiso 1 1 calc R U
H19B H 0.2931 0.0145 0.6152 0.042 Uiso 1 1 calc R U
H19C H 0.4233 0.0246 0.5920 0.042 Uiso 1 1 calc R U
C20 C 0.3836(4) 0.02548(8) 0.3466(3) 0.0247(9) Uani 1 1 d . .
H20 H 0.3879 0.0075 0.3730 0.030 Uiso 1 1 calc R U
C21 C 0.4890(4) 0.02787(10) 0.2899(3) 0.0357(11) Uani 1 1 d . .
H21A H 0.5626 0.0265 0.3210 0.043 Uiso 1 1 calc R U
H21B H 0.4863 0.0452 0.2623 0.043 Uiso 1 1 calc R U
H21C H 0.4860 0.0134 0.2500 0.043 Uiso 1 1 calc R U
C22 C 0.2660(4) 0.02702(9) 0.3013(3) 0.0320(10) Uani 1 1 d . .
H22A H 0.2595 0.0444 0.2744 0.038 Uiso 1 1 calc R U
H22B H 0.2004 0.0249 0.3395 0.038 Uiso 1 1 calc R U
H22C H 0.2626 0.0127 0.2610 0.038 Uiso 1 1 calc R U
C23 C 0.0924(4) 0.14764(8) 0.4077(3) 0.0304(10) Uani 1 1 d . .
H23 H 0.0259 0.1350 0.3960 0.036 Uiso 1 1 calc R U
C24 C 0.1310(6) 0.14311(12) 0.4951(3) 0.0540(16) Uani 1 1 d . .
H24A H 0.0624 0.1450 0.5308 0.065 Uiso 1 1 calc R U
H24B H 0.1911 0.1564 0.5098 0.065 Uiso 1 1 calc R U
H24C H 0.1643 0.1251 0.5006 0.065 Uiso 1 1 calc R U
C25 C 0.0459(4) 0.17601(9) 0.3954(3) 0.0381(11) Uani 1 1 d . .
H25A H -0.0201 0.1793 0.4325 0.046 Uiso 1 1 calc R U
H25B H 0.0183 0.1781 0.3397 0.046 Uiso 1 1 calc R U
H25C H 0.1095 0.1889 0.4061 0.046 Uiso 1 1 calc R U
C26 C 0.1708(4) 0.13660(9) 0.2203(3) 0.0291(9) Uani 1 1 d . .
H26 H 0.1159 0.1518 0.2084 0.035 Uiso 1 1 calc R U
C27 C 0.1028(5) 0.11053(10) 0.2079(3) 0.0451(13) Uani 1 1 d . .
H27A H 0.0348 0.1100 0.2446 0.054 Uiso 1 1 calc R U
H27B H 0.1551 0.0953 0.2191 0.054 Uiso 1 1 calc R U
H27C H 0.0748 0.1095 0.1520 0.054 Uiso 1 1 calc R U
C28 C 0.2755(5) 0.13856(11) 0.1632(3) 0.0466(13) Uani 1 1 d . .
H28A H 0.3322 0.1243 0.1754 0.056 Uiso 1 1 calc R U
H28B H 0.3141 0.1560 0.1700 0.056 Uiso 1 1 calc R U
H28C H 0.2478 0.1367 0.1075 0.056 Uiso 1 1 calc R U
C29 C 0.4062(5) 0.23457(9) 0.4801(3) 0.0380(11) Uani 1 1 d . .
H29 H 0.3502 0.2443 0.4436 0.046 Uiso 1 1 calc R U
C30 C 0.3337(6) 0.21834(12) 0.5397(4) 0.0587(17) Uani 1 1 d . .
H30A H 0.2843 0.2304 0.5719 0.070 Uiso 1 1 calc R U
H30B H 0.3871 0.2084 0.5754 0.070 Uiso 1 1 calc R U
H30C H 0.2831 0.2057 0.5103 0.070 Uiso 1 1 calc R U
C31 C 0.4825(6) 0.25538(10) 0.5232(3) 0.0538(16) Uani 1 1 d . .
H31A H 0.4317 0.2672 0.5553 0.065 Uiso 1 1 calc R U
H31B H 0.5258 0.2660 0.4833 0.065 Uiso 1 1 calc R U
H31C H 0.5391 0.2463 0.5587 0.065 Uiso 1 1 calc R U
C32 C 0.5928(4) 0.23096(8) 0.3314(3) 0.0323(10) Uani 1 1 d . .
H32 H 0.6230 0.2478 0.3566 0.039 Uiso 1 1 calc R U
C33 C 0.5102(5) 0.23888(9) 0.2632(3) 0.0389(11) Uani 1 1 d . .
H33A H 0.4815 0.2227 0.2359 0.047 Uiso 1 1 calc R U
H33B H 0.5529 0.2502 0.2246 0.047 Uiso 1 1 calc R U
H33C H 0.4427 0.2489 0.2852 0.047 Uiso 1 1 calc R U
C34 C 0.6990(5) 0.21539(11) 0.3005(4) 0.0499(14) Uani 1 1 d . .
H34A H 0.6723 0.1984 0.2769 0.060 Uiso 1 1 calc R U
H34B H 0.7533 0.2117 0.3453 0.060 Uiso 1 1 calc R U
H34C H 0.7401 0.2260 0.2593 0.060 Uiso 1 1 calc R U
C35 C 0.5603(5) 0.14761(10) 0.6869(3) 0.0428(13) Uani 1 1 d . .
H35 H 0.5180 0.1643 0.7034 0.051 Uiso 1 1 calc R U
C36 C 0.4763(6) 0.13164(13) 0.6330(5) 0.072(2) Uani 1 1 d . .
H36A H 0.4599 0.1418 0.5838 0.087 Uiso 1 1 calc R U
H36B H 0.4020 0.1283 0.6619 0.087 Uiso 1 1 calc R U
H36C H 0.5131 0.1145 0.6188 0.087 Uiso 1 1 calc R U
C37 C 0.5907(6) 0.13223(12) 0.7637(4) 0.0627(18) Uani 1 1 d . .
H37A H 0.6349 0.1160 0.7497 0.075 Uiso 1 1 calc R U
H37B H 0.5175 0.1273 0.7917 0.075 Uiso 1 1 calc R U
H37C H 0.6392 0.1435 0.7989 0.075 Uiso 1 1 calc R U
C38 C 0.8110(4) 0.17986(8) 0.6928(3) 0.0275(9) Uani 1 1 d . .
H38 H 0.8423 0.1685 0.7377 0.033 Uiso 1 1 calc R U
C39 C 0.9147(4) 0.18926(10) 0.6426(3) 0.0386(11) Uani 1 1 d . .
H39A H 0.8856 0.2001 0.5975 0.046 Uiso 1 1 calc R U
H39B H 0.9577 0.1737 0.6217 0.046 Uiso 1 1 calc R U
H39C H 0.9679 0.2001 0.6761 0.046 Uiso 1 1 calc R U
C40 C 0.7443(5) 0.20347(10) 0.7300(3) 0.0451(14) Uani 1 1 d . .
H40A H 0.7998 0.2147 0.7605 0.054 Uiso 1 1 calc R U
H40B H 0.6826 0.1967 0.7664 0.054 Uiso 1 1 calc R U
H40C H 0.7077 0.2141 0.6871 0.054 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C10 Ge1 C1 103.58(18)
C10 Ge1 C14 112.61(19)
C1 Ge1 C14 112.16(19)
C10 Ge1 C11 108.95(18)
C1 Ge1 C11 107.56(19)
C14 Ge1 C11 111.6(2)
C3 Ge2 C2 108.16(17)
C3 Ge2 C20 109.00(17)
C2 Ge2 C20 110.00(18)
C3 Ge2 C17 108.07(18)
C2 Ge2 C17 108.06(19)
C20 Ge2 C17 113.41(18)
C4 Ge3 C5 105.90(18)
C4 Ge3 C26 108.96(18)
C5 Ge3 C26 112.66(18)
C4 Ge3 C23 107.99(18)
C5 Ge3 C23 106.70(19)
C26 Ge3 C23 114.2(2)
C6 Ge4 C7 104.30(18)
C6 Ge4 C32 111.37(18)
C7 Ge4 C32 113.2(2)
C6 Ge4 C29 108.7(2)
C7 Ge4 C29 106.3(2)
C32 Ge4 C29 112.5(2)
C9 Ge5 C8 109.00(19)
C9 Ge5 C35 105.6(2)
C8 Ge5 C35 107.7(2)
C9 Ge5 C38 112.64(19)
C8 Ge5 C38 108.00(19)
C35 Ge5 C38 113.7(2)
C2 C1 Ge1 174.0(4)
C1 C2 Ge2 176.8(4)
C4 C3 Ge2 176.4(4)
C3 C4 Ge3 176.4(4)
C6 C5 Ge3 172.0(4)
C5 C6 Ge4 170.8(4)
C8 C7 Ge4 170.3(5)
C7 C8 Ge5 169.4(5)
C10 C9 Ge5 166.0(4)
C9 C10 Ge1 169.5(4)
C13 C11 C12 111.8(4)
C13 C11 Ge1 111.6(3)
C12 C11 Ge1 110.9(3)
C13 C11 H11 107.4
C12 C11 H11 107.4
Ge1 C11 H11 107.4
C11 C12 H12A 109.5
C11 C12 H12B 109.5
H12A C12 H12B 109.5
C11 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
C11 C13 H13A 109.5
C11 C13 H13B 109.5
H13A C13 H13B 109.5
C11 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
C15 C14 C16 112.1(4)
C15 C14 Ge1 113.6(4)
C16 C14 Ge1 110.7(3)
C15 C14 H14 106.6
C16 C14 H14 106.6
Ge1 C14 H14 106.6
C14 C15 H15A 109.5
C14 C15 H15B 109.5
H15A C15 H15B 109.5
C14 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C14 C16 H16A 109.5
C14 C16 H16B 109.5
H16A C16 H16B 109.5
C14 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C18 C17 C19 111.4(4)
C18 C17 Ge2 111.8(3)
C19 C17 Ge2 110.5(3)
C18 C17 H17 107.7
C19 C17 H17 107.7
Ge2 C17 H17 107.7
C17 C18 H18A 109.5
C17 C18 H18B 109.5
H18A C18 H18B 109.5
C17 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C17 C19 H19A 109.5
C17 C19 H19B 109.5
H19A C19 H19B 109.5
C17 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C21 C20 C22 111.9(4)
C21 C20 Ge2 111.6(3)
C22 C20 Ge2 110.3(3)
C21 C20 H20 107.6
C22 C20 H20 107.6
Ge2 C20 H20 107.6
C20 C21 H21A 109.5
C20 C21 H21B 109.5
H21A C21 H21B 109.5
C20 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
C20 C22 H22A 109.5
C20 C22 H22B 109.5
H22A C22 H22B 109.5
C20 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C25 C23 C24 111.2(4)
C25 C23 Ge3 111.2(3)
C24 C23 Ge3 111.3(3)
C25 C23 H23 107.7
C24 C23 H23 107.7
Ge3 C23 H23 107.7
C23 C24 H24A 109.5
C23 C24 H24B 109.5
H24A C24 H24B 109.5
C23 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
C23 C25 H25A 109.5
C23 C25 H25B 109.5
H25A C25 H25B 109.5
C23 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
C28 C26 C27 111.3(4)
C28 C26 Ge3 111.4(3)
C27 C26 Ge3 109.9(3)
C28 C26 H26 108.1
C27 C26 H26 108.1
Ge3 C26 H26 108.1
C26 C27 H27A 109.5
C26 C27 H27B 109.5
H27A C27 H27B 109.5
C26 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
C26 C28 H28A 109.5
C26 C28 H28B 109.5
H28A C28 H28B 109.5
C26 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C30 C29 C31 111.2(4)
C30 C29 Ge4 110.9(3)
C31 C29 Ge4 110.2(4)
C30 C29 H29 108.1
C31 C29 H29 108.1
Ge4 C29 H29 108.1
C29 C30 H30A 109.5
C29 C30 H30B 109.5
H30A C30 H30B 109.5
C29 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
C29 C31 H31A 109.5
C29 C31 H31B 109.5
H31A C31 H31B 109.5
C29 C31 H31C 109.5
H31A C31 H31C 109.5
H31B C31 H31C 109.5
C33 C32 C34 111.6(4)
C33 C32 Ge4 110.0(3)
C34 C32 Ge4 112.2(3)
C33 C32 H32 107.6
C34 C32 H32 107.6
Ge4 C32 H32 107.6
C32 C33 H33A 109.5
C32 C33 H33B 109.5
H33A C33 H33B 109.5
C32 C33 H33C 109.5
H33A C33 H33C 109.5
H33B C33 H33C 109.5
C32 C34 H34A 109.5
C32 C34 H34B 109.5
H34A C34 H34B 109.5
C32 C34 H34C 109.5
H34A C34 H34C 109.5
H34B C34 H34C 109.5
C37 C35 C36 111.4(5)
C37 C35 Ge5 111.4(4)
C36 C35 Ge5 111.4(4)
C37 C35 H35 107.5
C36 C35 H35 107.5
Ge5 C35 H35 107.5
C35 C36 H36A 109.5
C35 C36 H36B 109.5
H36A C36 H36B 109.5
C35 C36 H36C 109.5
H36A C36 H36C 109.5
H36B C36 H36C 109.5
C35 C37 H37A 109.5
C35 C37 H37B 109.5
H37A C37 H37B 109.5
C35 C37 H37C 109.5
H37A C37 H37C 109.5
H37B C37 H37C 109.5
C39 C38 C40 111.4(4)
C39 C38 Ge5 111.2(3)
C40 C38 Ge5 109.6(3)
C39 C38 H38 108.2
C40 C38 H38 108.2
Ge5 C38 H38 108.2
C38 C39 H39A 109.5
C38 C39 H39B 109.5
H39A C39 H39B 109.5
C38 C39 H39C 109.5
H39A C39 H39C 109.5
H39B C39 H39C 109.5
C38 C40 H40A 109.5
C38 C40 H40B 109.5
H40A C40 H40B 109.5
C38 C40 H40C 109.5
H40A C40 H40C 109.5
H40B C40 H40C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ge1 C10 1.912(4)
Ge1 C1 1.917(4)
Ge1 C14 1.947(5)
Ge1 C11 1.951(4)
Ge2 C3 1.912(4)
Ge2 C2 1.913(5)
Ge2 C20 1.951(4)
Ge2 C17 1.958(4)
Ge3 C4 1.920(4)
Ge3 C5 1.920(4)
Ge3 C26 1.950(4)
Ge3 C23 1.953(4)
Ge4 C6 1.912(4)
Ge4 C7 1.914(5)
Ge4 C32 1.952(5)
Ge4 C29 1.954(5)
Ge5 C9 1.909(4)
Ge5 C8 1.911(5)
Ge5 C35 1.942(5)
Ge5 C38 1.950(4)
C1 C2 1.203(6)
C3 C4 1.199(6)
C5 C6 1.206(6)
C7 C8 1.201(6)
C9 C10 1.206(6)
C11 C13 1.509(7)
C11 C12 1.529(6)
C11 H11 1.0000
C12 H12A 0.9800
C12 H12B 0.9800
C12 H12C 0.9800
C13 H13A 0.9800
C13 H13B 0.9800
C13 H13C 0.9800
C14 C15 1.478(7)
C14 C16 1.514(6)
C14 H14 1.0000
C15 H15A 0.9800
C15 H15B 0.9800
C15 H15C 0.9800
C16 H16A 0.9800
C16 H16B 0.9800
C16 H16C 0.9800
C17 C18 1.516(6)
C17 C19 1.527(6)
C17 H17 1.0000
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C19 H19A 0.9800
C19 H19B 0.9800
C19 H19C 0.9800
C20 C21 1.521(6)
C20 C22 1.527(6)
C20 H20 1.0000
C21 H21A 0.9800
C21 H21B 0.9800
C21 H21C 0.9800
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 C25 1.525(6)
C23 C24 1.531(7)
C23 H23 1.0000
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
C25 H25A 0.9800
C25 H25B 0.9800
C25 H25C 0.9800
C26 C28 1.517(7)
C26 C27 1.526(6)
C26 H26 1.0000
C27 H27A 0.9800
C27 H27B 0.9800
C27 H27C 0.9800
C28 H28A 0.9800
C28 H28B 0.9800
C28 H28C 0.9800
C29 C30 1.518(8)
C29 C31 1.528(7)
C29 H29 1.0000
C30 H30A 0.9800
C30 H30B 0.9800
C30 H30C 0.9800
C31 H31A 0.9800
C31 H31B 0.9800
C31 H31C 0.9800
C32 C33 1.518(6)
C32 C34 1.519(7)
C32 H32 1.0000
C33 H33A 0.9800
C33 H33B 0.9800
C33 H33C 0.9800
C34 H34A 0.9800
C34 H34B 0.9800
C34 H34C 0.9800
C35 C37 1.526(8)
C35 C36 1.527(8)
C35 H35 1.0000
C36 H36A 0.9800
C36 H36B 0.9800
C36 H36C 0.9800
C37 H37A 0.9800
C37 H37B 0.9800
C37 H37C 0.9800
C38 C39 1.511(6)
C38 C40 1.530(6)
C38 H38 1.0000
C39 H39A 0.9800
C39 H39B 0.9800
C39 H39C 0.9800
C40 H40A 0.9800
C40 H40B 0.9800
C40 H40C 0.9800
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
Ge5 C9 C10 Ge1 19(4)
