#------------------------------------------------------------------------------
#$Date: 2015-07-11 00:13:22 +0300 (Sat, 11 Jul 2015) $
#$Revision: 143486 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/52/7035213.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035213
loop_
_publ_author_name
'Tanimoto, Hiroki'
'Nagao, Tomohiko'
'Fujiwara, Taro'
'Nishiyama, Yasuhiro'
'Morimoto, Tsumoru'
'Suzuka, Toshimasa'
'Tsutsumi, Ken'
'Kakiuchi, Kiyomi'
_publ_section_title
;
 Stepwise synthesis and characterization of germa[4], [5], [8], and
 [10]pericyclynes.
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11811
_journal_page_last               11818
_journal_paper_doi               10.1039/c5dt01411e
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C80 H140 Ge10'
_chemical_formula_sum            'C80 H140 Ge10'
_chemical_formula_weight         1827.81
_chemical_name_systematic        iPrGe10
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2015-05-12 deposited with the CCDC.
2015-05-15 downloaded from the CCDC.
;
_cell_angle_alpha                105.9307(7)
_cell_angle_beta                 96.9004(7)
_cell_angle_gamma                104.5367(7)
_cell_formula_units_Z            1
_cell_length_a                   8.62692(16)
_cell_length_b                   16.1073(3)
_cell_length_c                   18.5212(3)
_cell_measurement_reflns_used    35010
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.00
_cell_volume                     2345.65(7)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.1'
_computing_publication_material  'CrystalStructure 4.1 (Rigaku, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      123(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0162
_diffrn_reflns_av_unetI/netI     0.0133
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            40719
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.484
_diffrn_reflns_theta_min         2.995
_exptl_absorpt_coefficient_mu    3.189
_exptl_absorpt_correction_T_max  0.727
_exptl_absorpt_correction_T_min  0.659
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.294
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             940
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.110
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.652
_refine_diff_density_min         -0.216
_refine_diff_density_rms         0.064
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.123
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     426
_refine_ls_number_reflns         10722
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.123
_refine_ls_R_factor_all          0.0189
_refine_ls_R_factor_gt           0.0170
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0238P)²+0.8821P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0432
_refine_ls_wR_factor_ref         0.0490
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10056
_reflns_number_total             10722
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt01411e2.cif
_cod_data_source_block           shelxl
_cod_depositor_comments
'Adding full bibliography for 7035212--7035215.cif.'
_cod_original_cell_volume        2345.65(8)
_cod_database_code               7035213
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.701
_shelx_estimated_absorpt_t_max   0.741
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ge1 Ge 0.70966(2) 0.95066(2) 0.74862(2) 0.02068(4) Uani 1 1 d . .
Ge2 Ge 0.73297(2) 0.63799(2) 0.61901(2) 0.01543(4) Uani 1 1 d . .
Ge3 Ge 0.86774(2) 0.73351(2) 0.39798(2) 0.01786(4) Uani 1 1 d . .
Ge4 Ge 0.89386(2) 0.57332(2) 0.12914(2) 0.01630(4) Uani 1 1 d . .
Ge5 Ge 0.85432(2) 0.83092(2) 0.03234(2) 0.01833(4) Uani 1 1 d . .
C1 C 0.87860(19) 1.01698(10) 0.83787(9) 0.0267(3) Uani 1 1 d . .
C2 C 0.73723(18) 0.83468(10) 0.70462(8) 0.0237(3) Uani 1 1 d . .
C3 C 0.74244(18) 0.75955(9) 0.67370(8) 0.0215(3) Uani 1 1 d . .
C4 C 0.77744(17) 0.64739(9) 0.52232(8) 0.0196(3) Uani 1 1 d . .
C5 C 0.80781(17) 0.66619(9) 0.46562(8) 0.0210(3) Uani 1 1 d . .
C6 C 0.88755(17) 0.65920(10) 0.30150(8) 0.0208(3) Uani 1 1 d . .
C7 C 0.89319(17) 0.62500(9) 0.23557(8) 0.0201(3) Uani 1 1 d . .
C8 C 0.86713(18) 0.66369(10) 0.08395(8) 0.0220(3) Uani 1 1 d . .
C9 C 0.85912(18) 0.72542(10) 0.06050(8) 0.0226(3) Uani 1 1 d . .
C10 C 1.01747(19) 0.92717(10) 0.11023(9) 0.0271(3) Uani 1 1 d . .
C11 C 0.5000(2) 0.93309(11) 0.78176(10) 0.0305(3) Uani 1 1 d . .
H11 H 0.5040 0.9914 0.8201 0.037 Uiso 1 1 calc R U
C12 C 0.4792(2) 0.86175(13) 0.82253(11) 0.0401(4) Uani 1 1 d . .
H12A H 0.4693 0.8029 0.7858 0.048 Uiso 1 1 calc R U
H12B H 0.3803 0.8581 0.8441 0.048 Uiso 1 1 calc R U
H12C H 0.5746 0.8784 0.8639 0.048 Uiso 1 1 calc R U
C13 C 0.3539(2) 0.90958(15) 0.71707(13) 0.0471(5) Uani 1 1 d . .
H13A H 0.3521 0.8555 0.6762 0.057 Uiso 1 1 calc R U
H13B H 0.3627 0.9602 0.6966 0.057 Uiso 1 1 calc R U
H13C H 0.2528 0.8979 0.7367 0.057 Uiso 1 1 calc R U
C14 C 0.7442(2) 1.02174(10) 0.67817(9) 0.0288(3) Uani 1 1 d . .
H14 H 0.8605 1.0316 0.6722 0.035 Uiso 1 1 calc R U
C15 C 0.7240(3) 1.11478(12) 0.71513(12) 0.0408(4) Uani 1 1 d . .
H15A H 0.8019 1.1449 0.7642 0.049 Uiso 1 1 calc R U
H15B H 0.6123 1.1076 0.7239 0.049 Uiso 1 1 calc R U
H15C H 0.7449 1.1514 0.6810 0.049 Uiso 1 1 calc R U
C16 C 0.6368(3) 0.97260(15) 0.59833(11) 0.0498(5) Uani 1 1 d . .
H16A H 0.6673 1.0079 0.5640 0.060 Uiso 1 1 calc R U
H16B H 0.5218 0.9654 0.6014 0.060 Uiso 1 1 calc R U
H16C H 0.6523 0.9129 0.5784 0.060 Uiso 1 1 calc R U
C17 C 0.50973(17) 0.56315(9) 0.60744(8) 0.0215(3) Uani 1 1 d . .
H17 H 0.4964 0.5018 0.5712 0.026 Uiso 1 1 calc R U
C18 C 0.4775(2) 0.55241(12) 0.68438(10) 0.0343(4) Uani 1 1 d . .
H18A H 0.4910 0.6119 0.7210 0.041 Uiso 1 1 calc R U
H18B H 0.5552 0.5249 0.7042 0.041 Uiso 1 1 calc R U
H18C H 0.3657 0.5136 0.6772 0.041 Uiso 1 1 calc R U
C19 C 0.38720(19) 0.60274(12) 0.57304(10) 0.0314(3) Uani 1 1 d . .
H19A H 0.3952 0.6620 0.6086 0.038 Uiso 1 1 calc R U
H19B H 0.2762 0.5621 0.5642 0.038 Uiso 1 1 calc R U
H19C H 0.4115 0.6096 0.5243 0.038 Uiso 1 1 calc R U
C20 C 0.90501(18) 0.60240(10) 0.67021(8) 0.0224(3) Uani 1 1 d . .
H20 H 0.8782 0.5980 0.7203 0.027 Uiso 1 1 calc R U
C21 C 0.9102(2) 0.50935(11) 0.62311(10) 0.0339(4) Uani 1 1 d . .
H21A H 0.8024 0.4652 0.6133 0.041 Uiso 1 1 calc R U
H21B H 0.9918 0.4910 0.6516 0.041 Uiso 1 1 calc R U
H21C H 0.9398 0.5122 0.5742 0.041 Uiso 1 1 calc R U
C22 C 1.0701(2) 0.67440(12) 0.68720(11) 0.0354(4) Uani 1 1 d . .
H22A H 1.0975 0.6817 0.6390 0.042 Uiso 1 1 calc R U
H22B H 1.1547 0.6557 0.7132 0.042 Uiso 1 1 calc R U
H22C H 1.0639 0.7320 0.7203 0.042 Uiso 1 1 calc R U
C23 C 0.6938(2) 0.78581(11) 0.37434(9) 0.0302(3) Uani 1 1 d . .
H23 H 0.6773 0.8238 0.4237 0.036 Uiso 1 1 calc R U
C24 C 0.5339(2) 0.71132(14) 0.33481(13) 0.0461(5) Uani 1 1 d . .
H24A H 0.5041 0.6743 0.3680 0.055 Uiso 1 1 calc R U
H24B H 0.5474 0.6732 0.2861 0.055 Uiso 1 1 calc R U
H24C H 0.4472 0.7385 0.3249 0.055 Uiso 1 1 calc R U
C25 C 0.7455(3) 0.84674(15) 0.32596(14) 0.0509(5) Uani 1 1 d . .
H25A H 0.7644 0.8109 0.2776 0.061 Uiso 1 1 calc R U
H25B H 0.8464 0.8949 0.3540 0.061 Uiso 1 1 calc R U
H25C H 0.6589 0.8736 0.3151 0.061 Uiso 1 1 calc R U
C26 C 1.0783(2) 0.82251(11) 0.45082(9) 0.0306(3) Uani 1 1 d . .
H26 H 1.1136 0.8594 0.4169 0.037 Uiso 1 1 calc R U
C27 C 1.0616(3) 0.88649(13) 0.52561(11) 0.0451(5) Uani 1 1 d . .
H27A H 1.0294 0.8521 0.5604 0.054 Uiso 1 1 calc R U
H27B H 0.9781 0.9153 0.5146 0.054 Uiso 1 1 calc R U
H27C H 1.1666 0.9330 0.5498 0.054 Uiso 1 1 calc R U
C28 C 1.2078(2) 0.77614(15) 0.46453(12) 0.0468(5) Uani 1 1 d . .
H28A H 1.1774 0.7407 0.4988 0.056 Uiso 1 1 calc R U
H28B H 1.3138 0.8219 0.4881 0.056 Uiso 1 1 calc R U
H28C H 1.2153 0.7359 0.4155 0.056 Uiso 1 1 calc R U
C29 C 0.70311(19) 0.46619(10) 0.08549(9) 0.0277(3) Uani 1 1 d . .
H29 H 0.6960 0.4435 0.0289 0.033 Uiso 1 1 calc R U
C30 C 0.5479(2) 0.49147(14) 0.09934(11) 0.0393(4) Uani 1 1 d . .
H30A H 0.5449 0.5431 0.0815 0.047 Uiso 1 1 calc R U
H30B H 0.5471 0.5077 0.1543 0.047 Uiso 1 1 calc R U
H30C H 0.4521 0.4399 0.0711 0.047 Uiso 1 1 calc R U
C31 C 0.7183(3) 0.39084(13) 0.11828(16) 0.0583(6) Uani 1 1 d . .
H31A H 0.8113 0.3706 0.1034 0.070 Uiso 1 1 calc R U
H31B H 0.6178 0.3400 0.0982 0.070 Uiso 1 1 calc R U
H31C H 0.7357 0.4135 0.1743 0.070 Uiso 1 1 calc R U
C32 C 1.10874(18) 0.55572(10) 0.12076(8) 0.0218(3) Uani 1 1 d . .
H32 H 1.0982 0.5114 0.0693 0.026 Uiso 1 1 calc R U
C33 C 1.1633(2) 0.51610(13) 0.18210(11) 0.0365(4) Uani 1 1 d . .
H33A H 1.1736 0.5584 0.2331 0.044 Uiso 1 1 calc R U
H33B H 1.2693 0.5060 0.1766 0.044 Uiso 1 1 calc R U
H33C H 1.0821 0.4585 0.1759 0.044 Uiso 1 1 calc R U
C34 C 1.2346(2) 0.64427(12) 0.12689(11) 0.0348(4) Uani 1 1 d . .
H34A H 1.2455 0.6890 0.1768 0.042 Uiso 1 1 calc R U
H34B H 1.1985 0.6670 0.0859 0.042 Uiso 1 1 calc R U
H34C H 1.3404 0.6337 0.1220 0.042 Uiso 1 1 calc R U
C35 C 0.6425(2) 0.85202(11) 0.03775(10) 0.0304(3) Uani 1 1 d . .
H35 H 0.5632 0.8114 -0.0104 0.037 Uiso 1 1 calc R U
C36 C 0.5774(3) 0.83051(15) 0.10545(15) 0.0527(6) Uani 1 1 d . .
H36A H 0.6528 0.8703 0.1533 0.063 Uiso 1 1 calc R U
H36B H 0.5678 0.7673 0.1011 0.063 Uiso 1 1 calc R U
H36C H 0.4696 0.8401 0.1055 0.063 Uiso 1 1 calc R U
C37 C 0.6565(3) 0.94993(13) 0.04228(11) 0.0414(4) Uani 1 1 d . .
H37A H 0.7313 0.9909 0.0899 0.050 Uiso 1 1 calc R U
H37B H 0.5484 0.9592 0.0414 0.050 Uiso 1 1 calc R U
H37C H 0.6988 0.9625 -0.0017 0.050 Uiso 1 1 calc R U
C38 C 0.9159(2) 0.81655(11) -0.06744(9) 0.0328(4) Uani 1 1 d . .
H38 H 0.9124 0.8710 -0.0828 0.039 Uiso 1 1 calc R U
C39 C 0.7939(3) 0.73307(13) -0.12732(10) 0.0463(5) Uani 1 1 d . .
H39A H 0.7948 0.6793 -0.1125 0.056 Uiso 1 1 calc R U
H39B H 0.8247 0.7263 -0.1774 0.056 Uiso 1 1 calc R U
H39C H 0.6840 0.7401 -0.1305 0.056 Uiso 1 1 calc R U
C40 C 1.0894(3) 0.80958(16) -0.06169(15) 0.0603(6) Uani 1 1 d . .
H40A H 1.1642 0.8632 -0.0220 0.072 Uiso 1 1 calc R U
H40B H 1.1221 0.8058 -0.1111 0.072 Uiso 1 1 calc R U
H40C H 1.0937 0.7553 -0.0483 0.072 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C2 Ge1 C1 109.07(6) .
C2 Ge1 C11 108.34(7) .
C1 Ge1 C11 107.62(7) .
C2 Ge1 C14 109.99(7) .
C1 Ge1 C14 104.90(7) .
C11 Ge1 C14 116.66(7) .
C4 Ge2 C3 102.38(6) .
C4 Ge2 C17 110.99(6) .
C3 Ge2 C17 106.74(6) .
C4 Ge2 C20 109.73(6) .
C3 Ge2 C20 110.28(6) .
C17 Ge2 C20 115.84(6) .
C5 Ge3 C6 112.50(6) .
C5 Ge3 C26 105.62(7) .
C6 Ge3 C26 109.98(7) .
C5 Ge3 C23 108.87(7) .
C6 Ge3 C23 105.70(7) .
C26 Ge3 C23 114.32(7) .
C8 Ge4 C7 104.65(6) .
C8 Ge4 C29 108.94(7) .
C7 Ge4 C29 108.19(6) .
C8 Ge4 C32 109.03(6) .
C7 Ge4 C32 108.44(6) .
C29 Ge4 C32 116.90(6) .
C10 Ge5 C9 103.95(6) .
C10 Ge5 C35 108.57(7) .
C9 Ge5 C35 109.89(7) .
C10 Ge5 C38 110.43(7) .
C9 Ge5 C38 108.24(6) .
C35 Ge5 C38 115.16(8) .
C10 C1 Ge1 167.37(14) 2_776
C3 C2 Ge1 174.93(14) .
C2 C3 Ge2 175.11(14) .
C5 C4 Ge2 170.73(12) .
C4 C5 Ge3 161.75(12) .
C7 C6 Ge3 167.47(13) .
C6 C7 Ge4 177.07(13) .
C9 C8 Ge4 174.83(14) .
C8 C9 Ge5 174.87(13) .
C1 C10 Ge5 174.95(14) 2_776
C13 C11 C12 111.08(15) .
C13 C11 Ge1 113.61(13) .
C12 C11 Ge1 109.72(11) .
C13 C11 H11 107.4 .
C12 C11 H11 107.4 .
Ge1 C11 H11 107.4 .
C11 C12 H12A 109.5 .
C11 C12 H12B 109.5 .
H12A C12 H12B 109.5 .
C11 C12 H12C 109.5 .
H12A C12 H12C 109.5 .
H12B C12 H12C 109.5 .
C11 C13 H13A 109.5 .
C11 C13 H13B 109.5 .
H13A C13 H13B 109.5 .
C11 C13 H13C 109.5 .
H13A C13 H13C 109.5 .
H13B C13 H13C 109.5 .
C16 C14 C15 113.20(16) .
C16 C14 Ge1 112.82(12) .
C15 C14 Ge1 109.03(11) .
C16 C14 H14 107.1 .
C15 C14 H14 107.1 .
Ge1 C14 H14 107.1 .
C14 C15 H15A 109.5 .
C14 C15 H15B 109.5 .
H15A C15 H15B 109.5 .
C14 C15 H15C 109.5 .
H15A C15 H15C 109.5 .
H15B C15 H15C 109.5 .
C14 C16 H16A 109.5 .
C14 C16 H16B 109.5 .
H16A C16 H16B 109.5 .
C14 C16 H16C 109.5 .
H16A C16 H16C 109.5 .
H16B C16 H16C 109.5 .
C19 C17 C18 111.22(13) .
C19 C17 Ge2 110.54(10) .
C18 C17 Ge2 110.68(10) .
C19 C17 H17 108.1 .
C18 C17 H17 108.1 .
Ge2 C17 H17 108.1 .
C17 C18 H18A 109.5 .
C17 C18 H18B 109.5 .
H18A C18 H18B 109.5 .
C17 C18 H18C 109.5 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.5 .
C17 C19 H19A 109.5 .
C17 C19 H19B 109.5 .
H19A C19 H19B 109.5 .
C17 C19 H19C 109.5 .
H19A C19 H19C 109.5 .
H19B C19 H19C 109.5 .
C21 C20 C22 111.91(13) .
C21 C20 Ge2 110.94(10) .
C22 C20 Ge2 110.58(10) .
C21 C20 H20 107.7 .
C22 C20 H20 107.7 .
Ge2 C20 H20 107.7 .
C20 C21 H21A 109.5 .
C20 C21 H21B 109.5 .
H21A C21 H21B 109.5 .
C20 C21 H21C 109.5 .
H21A C21 H21C 109.5 .
H21B C21 H21C 109.5 .
C20 C22 H22A 109.5 .
C20 C22 H22B 109.5 .
H22A C22 H22B 109.5 .
C20 C22 H22C 109.5 .
H22A C22 H22C 109.5 .
H22B C22 H22C 109.5 .
C24 C23 C25 111.98(16) .
C24 C23 Ge3 110.42(12) .
C25 C23 Ge3 109.83(12) .
C24 C23 H23 108.2 .
C25 C23 H23 108.2 .
Ge3 C23 H23 108.2 .
C23 C24 H24A 109.5 .
C23 C24 H24B 109.5 .
H24A C24 H24B 109.5 .
C23 C24 H24C 109.5 .
H24A C24 H24C 109.5 .
H24B C24 H24C 109.5 .
C23 C25 H25A 109.5 .
C23 C25 H25B 109.5 .
H25A C25 H25B 109.5 .
C23 C25 H25C 109.5 .
H25A C25 H25C 109.5 .
H25B C25 H25C 109.5 .
C28 C26 C27 111.76(15) .
C28 C26 Ge3 110.85(12) .
C27 C26 Ge3 110.49(12) .
C28 C26 H26 107.9 .
C27 C26 H26 107.9 .
Ge3 C26 H26 107.9 .
C26 C27 H27A 109.5 .
C26 C27 H27B 109.5 .
H27A C27 H27B 109.5 .
C26 C27 H27C 109.5 .
H27A C27 H27C 109.5 .
H27B C27 H27C 109.5 .
C26 C28 H28A 109.5 .
C26 C28 H28B 109.5 .
H28A C28 H28B 109.5 .
C26 C28 H28C 109.5 .
H28A C28 H28C 109.5 .
H28B C28 H28C 109.5 .
C30 C29 C31 110.78(16) .
C30 C29 Ge4 109.88(11) .
C31 C29 Ge4 111.51(13) .
C30 C29 H29 108.2 .
C31 C29 H29 108.2 .
Ge4 C29 H29 108.2 .
C29 C30 H30A 109.5 .
C29 C30 H30B 109.5 .
H30A C30 H30B 109.5 .
C29 C30 H30C 109.5 .
H30A C30 H30C 109.5 .
H30B C30 H30C 109.5 .
C29 C31 H31A 109.5 .
C29 C31 H31B 109.5 .
H31A C31 H31B 109.5 .
C29 C31 H31C 109.5 .
H31A C31 H31C 109.5 .
H31B C31 H31C 109.5 .
C34 C32 C33 111.19(14) .
C34 C32 Ge4 110.90(10) .
C33 C32 Ge4 109.97(10) .
C34 C32 H32 108.2 .
C33 C32 H32 108.2 .
Ge4 C32 H32 108.2 .
C32 C33 H33A 109.5 .
C32 C33 H33B 109.5 .
H33A C33 H33B 109.5 .
C32 C33 H33C 109.5 .
H33A C33 H33C 109.5 .
H33B C33 H33C 109.5 .
C32 C34 H34A 109.5 .
C32 C34 H34B 109.5 .
H34A C34 H34B 109.5 .
C32 C34 H34C 109.5 .
H34A C34 H34C 109.5 .
H34B C34 H34C 109.5 .
C36 C35 C37 110.72(15) .
C36 C35 Ge5 111.71(12) .
C37 C35 Ge5 109.65(12) .
C36 C35 H35 108.2 .
C37 C35 H35 108.2 .
Ge5 C35 H35 108.2 .
C35 C36 H36A 109.5 .
C35 C36 H36B 109.5 .
H36A C36 H36B 109.5 .
C35 C36 H36C 109.5 .
H36A C36 H36C 109.5 .
H36B C36 H36C 109.5 .
C35 C37 H37A 109.5 .
C35 C37 H37B 109.5 .
H37A C37 H37B 109.5 .
C35 C37 H37C 109.5 .
H37A C37 H37C 109.5 .
H37B C37 H37C 109.5 .
C40 C38 C39 111.39(16) .
C40 C38 Ge5 109.70(14) .
C39 C38 Ge5 109.67(12) .
C40 C38 H38 108.7 .
C39 C38 H38 108.7 .
Ge5 C38 H38 108.7 .
C38 C39 H39A 109.5 .
C38 C39 H39B 109.5 .
H39A C39 H39B 109.5 .
C38 C39 H39C 109.5 .
H39A C39 H39C 109.5 .
H39B C39 H39C 109.5 .
C38 C40 H40A 109.5 .
C38 C40 H40B 109.5 .
H40A C40 H40B 109.5 .
C38 C40 H40C 109.5 .
H40A C40 H40C 109.5 .
H40B C40 H40C 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 C2 1.9091(15) .
Ge1 C1 1.9152(16) .
Ge1 C11 1.9583(16) .
Ge1 C14 1.9607(16) .
Ge2 C4 1.9137(14) .
Ge2 C3 1.9176(14) .
Ge2 C17 1.9499(14) .
Ge2 C20 1.9539(14) .
Ge3 C5 1.9058(14) .
Ge3 C6 1.9124(14) .
Ge3 C26 1.9516(16) .
Ge3 C23 1.9575(16) .
Ge4 C8 1.9141(14) .
Ge4 C7 1.9190(14) .
Ge4 C29 1.9566(15) .
Ge4 C32 1.9621(14) .
Ge5 C10 1.9117(15) .
Ge5 C9 1.9178(15) .
Ge5 C35 1.9498(16) .
Ge5 C38 1.9529(16) .
C1 C10 1.204(2) 2_776
C2 C3 1.203(2) .
C4 C5 1.210(2) .
C6 C7 1.206(2) .
C8 C9 1.203(2) .
C10 C1 1.204(2) 2_776
C11 C13 1.522(3) .
C11 C12 1.526(2) .
C11 H11 1.0000 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 C16 1.527(2) .
C14 C15 1.530(2) .
C14 H14 1.0000 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C19 1.526(2) .
C17 C18 1.531(2) .
C17 H17 1.0000 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 C21 1.528(2) .
C20 C22 1.528(2) .
C20 H20 1.0000 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C24 1.524(3) .
C23 C25 1.524(3) .
C23 H23 1.0000 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 C28 1.524(3) .
C26 C27 1.530(2) .
C26 H26 1.0000 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 C30 1.524(2) .
C29 C31 1.525(3) .
C29 H29 1.0000 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 C34 1.526(2) .
C32 C33 1.530(2) .
C32 H32 1.0000 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 C36 1.523(3) .
C35 C37 1.529(2) .
C35 H35 1.0000 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C38 C40 1.522(3) .
C38 C39 1.528(3) .
C38 H38 1.0000 .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
