#------------------------------------------------------------------------------
#$Date: 2018-10-05 15:19:55 +0300 (Fri, 05 Oct 2018) $
#$Revision: 211332 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/58/7035801.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035801
loop_
_publ_author_name
'Han, Min-Le'
'Bai, Liang'
'Tang, Ping'
'Wu, Xue-Qian'
'Wu, Ya-Pan'
'Zhao, Jun'
'Li, Dong-Sheng'
'Wang, Yao-Yu'
_publ_section_title
;
 Biphenyl-2,4,6,3',5'-pentacarboxylic acid as a tecton for six new Co(ii)
 coordination polymers: pH and N-donor ligand-dependent assemblies,
 structure diversities and magnetic properties.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14673
_journal_page_last               14685
_journal_paper_doi               10.1039/c5dt02147b
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C37 H24 Co2 N4 O11'
_chemical_formula_weight         818.46
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   constr
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-07-07 deposited with the CCDC.
2015-07-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 101.498(8)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.610(7)
_cell_length_b                   15.935(9)
_cell_length_c                   17.477(10)
_cell_measurement_reflns_used    6770
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      2.1
_cell_volume                     3441(3)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean none
_diffrn_measured_fraction_theta_full 0.960
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0962
_diffrn_reflns_av_unetI/netI     0.0715
_diffrn_reflns_Laue_measured_fraction_full 0.960
_diffrn_reflns_Laue_measured_fraction_max 0.960
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            29445
_diffrn_reflns_point_group_measured_fraction_full 0.960
_diffrn_reflns_point_group_measured_fraction_max 0.960
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.499
_diffrn_reflns_theta_min         2.700
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    1.034
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.706
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            violet
_exptl_crystal_density_diffrn    1.580
_exptl_crystal_density_meas      ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1664
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.210
_refine_diff_density_max         0.903
_refine_diff_density_min         -1.187
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     490
_refine_ls_number_reflns         6167
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.1078
_refine_ls_R_factor_gt           0.0810
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1253P)²+1.9704P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2013
_refine_ls_wR_factor_ref         0.2250
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4633
_reflns_number_total             6167
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt02147b2.cif
_cod_data_source_block           Z
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7035800--7035805.cif.
;
_cod_database_code               7035801
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.789
_shelx_estimated_absorpt_t_max   0.812
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Co1 Co 0.50108(6) 0.37334(5) 0.06782(4) 0.0300(2) Uani 1 1 d . .
Co2 Co 0.32850(7) 0.33817(6) 0.44337(5) 0.0471(3) Uani 1 1 d . .
O1 O 0.5054(3) 0.4979(2) 0.1011(2) 0.0341(9) Uani 1 1 d . .
O2 O 0.5811(3) 0.6043(3) 0.0485(2) 0.0361(9) Uani 1 1 d . .
O3 O 0.9913(3) 0.5426(4) 0.1985(3) 0.0581(14) Uani 1 1 d . .
O4 O 1.0108(3) 0.5522(4) 0.3279(3) 0.0639(16) Uani 1 1 d . .
H4A H 1.0687 0.5287 0.3281 0.096 Uiso 1 1 calc R U
O5 O 0.7070(4) 0.6186(4) 0.4557(3) 0.0633(15) Uani 1 1 d . .
O6 O 0.5779(4) 0.6911(4) 0.3806(3) 0.0661(15) Uani 1 1 d . .
O7 O 0.3654(4) 0.4309(3) 0.3863(3) 0.0560(13) Uani 1 1 d . .
O8 O 0.1994(3) 0.4835(3) 0.3545(3) 0.0501(12) Uani 1 1 d . .
O9 O 0.1526(4) 0.7333(4) 0.1669(3) 0.0693(17) Uani 1 1 d . .
O10 O 0.2870(4) 0.7643(3) 0.1086(3) 0.0546(13) Uani 1 1 d . .
O11 O 0.4743(4) 0.2848(4) 0.4872(3) 0.0688(15) Uani 1 1 d D .
H11A H 0.4839 0.2833 0.5349 0.103 Uiso 1 1 calc DR U
H11B H 0.506(7) 0.244(4) 0.4686(13) 0.103 Uiso 1 1 d D U
N1 N 0.3479(4) 0.3510(3) 0.0966(3) 0.0341(11) Uani 1 1 d . .
N2 N 0.4674(5) 0.2462(3) 0.0334(3) 0.0422(12) Uani 1 1 d . .
N3 N 0.6675(4) 0.3810(3) 0.0579(3) 0.0368(11) Uani 1 1 d . .
N4 N 0.5890(4) 0.3345(3) 0.1814(3) 0.0426(12) Uani 1 1 d . .
C1 C 0.5727(4) 0.5555(3) 0.1040(3) 0.0260(11) Uani 1 1 d . .
C2 C 0.6503(4) 0.5719(3) 0.1807(3) 0.0249(10) Uani 1 1 d . .
C3 C 0.7621(4) 0.5639(4) 0.1835(3) 0.0303(11) Uani 1 1 d . .
H3 H 0.7868 0.5539 0.1377 0.036 Uiso 1 1 calc R U
C4 C 0.8361(4) 0.5706(3) 0.2538(3) 0.0274(11) Uani 1 1 d . .
C5 C 0.7996(4) 0.5916(4) 0.3213(3) 0.0324(12) Uani 1 1 d . .
H5 H 0.8489 0.5978 0.3682 0.039 Uiso 1 1 calc R U
C6 C 0.6893(4) 0.6034(4) 0.3191(3) 0.0312(12) Uani 1 1 d . .
C7 C 0.6129(4) 0.5903(3) 0.2492(3) 0.0265(11) Uani 1 1 d . .
C8 C 0.9535(5) 0.5540(4) 0.2564(4) 0.0394(14) Uani 1 1 d . .
C9 C 0.6542(5) 0.6385(4) 0.3911(3) 0.0420(15) Uani 1 1 d . .
C10 C 0.4951(4) 0.5958(3) 0.2488(3) 0.0266(11) Uani 1 1 d . .
C11 C 0.4504(4) 0.5405(4) 0.2961(3) 0.0287(11) Uani 1 1 d . .
H11 H 0.4944 0.5007 0.3258 0.034 Uiso 1 1 calc R U
C12 C 0.3402(4) 0.5442(3) 0.2991(3) 0.0278(11) Uani 1 1 d . .
C13 C 0.2739(4) 0.6035(4) 0.2530(3) 0.0334(12) Uani 1 1 d . .
H13 H 0.2007 0.6063 0.2548 0.040 Uiso 1 1 calc R U
C14 C 0.3161(4) 0.6575(4) 0.2054(3) 0.0335(12) Uani 1 1 d . .
C15 C 0.4282(4) 0.6537(4) 0.2020(3) 0.0315(12) Uani 1 1 d . .
H15 H 0.4565 0.6893 0.1690 0.038 Uiso 1 1 calc R U
C16 C 0.2964(4) 0.4827(4) 0.3489(3) 0.0351(13) Uani 1 1 d . .
C17 C 0.2463(5) 0.7218(4) 0.1590(4) 0.0424(14) Uani 1 1 d . .
C18 C 0.2953(5) 0.4070(5) 0.1347(4) 0.0415(14) Uani 1 1 d . .
H18 H 0.3243 0.4605 0.1448 0.050 Uiso 1 1 calc R U
C19 C 0.1997(6) 0.3872(5) 0.1591(4) 0.0535(18) Uani 1 1 d . .
H19 H 0.1647 0.4264 0.1846 0.064 Uiso 1 1 calc R U
C20 C 0.1591(6) 0.3080(6) 0.1442(5) 0.064(2) Uani 1 1 d . .
H20 H 0.0962 0.2925 0.1608 0.077 Uiso 1 1 calc R U
C21 C 0.2097(6) 0.2515(5) 0.1051(5) 0.0573(19) Uani 1 1 d . .
H21 H 0.1805 0.1982 0.0941 0.069 Uiso 1 1 calc R U
C22 C 0.3056(5) 0.2739(4) 0.0816(3) 0.0399(14) Uani 1 1 d . .
C23 C 0.3694(5) 0.2169(4) 0.0403(4) 0.0446(15) Uani 1 1 d . .
C24 C 0.3320(8) 0.1394(5) 0.0113(5) 0.066(2) Uani 1 1 d . .
H24 H 0.2651 0.1192 0.0177 0.079 Uiso 1 1 calc R U
C25 C 0.3986(10) 0.0917(6) -0.0283(6) 0.084(3) Uani 1 1 d . .
H25 H 0.3754 0.0398 -0.0497 0.101 Uiso 1 1 calc R U
C26 C 0.4964(10) 0.1223(6) -0.0347(5) 0.077(3) Uani 1 1 d . .
H26 H 0.5407 0.0916 -0.0610 0.092 Uiso 1 1 calc R U
C27 C 0.5298(7) 0.1977(5) -0.0029(5) 0.062(2) Uani 1 1 d . .
H27 H 0.5984 0.2168 -0.0062 0.075 Uiso 1 1 calc R U
C28 C 0.7023(5) 0.4101(5) -0.0058(4) 0.0437(15) Uani 1 1 d . .
H28 H 0.6517 0.4227 -0.0508 0.052 Uiso 1 1 calc R U
C29 C 0.8110(5) 0.4215(5) -0.0056(4) 0.0492(16) Uani 1 1 d . .
H29 H 0.8331 0.4411 -0.0500 0.059 Uiso 1 1 calc R U
C30 C 0.8870(5) 0.4035(5) 0.0614(5) 0.0589(19) Uani 1 1 d . .
H30 H 0.9605 0.4110 0.0628 0.071 Uiso 1 1 calc R U
C31 C 0.8510(5) 0.3743(5) 0.1258(4) 0.0524(17) Uani 1 1 d . .
H31 H 0.9007 0.3627 0.1714 0.063 Uiso 1 1 calc R U
C32 C 0.7414(5) 0.3620(4) 0.1235(4) 0.0415(14) Uani 1 1 d . .
C33 C 0.6975(5) 0.3321(4) 0.1902(4) 0.0375(13) Uani 1 1 d . .
C34 C 0.7617(6) 0.3047(5) 0.2601(4) 0.0526(17) Uani 1 1 d . .
H34 H 0.8366 0.3038 0.2657 0.063 Uiso 1 1 calc R U
C35 C 0.7152(8) 0.2792(5) 0.3202(4) 0.066(2) Uani 1 1 d . .
H35 H 0.7576 0.2585 0.3660 0.080 Uiso 1 1 calc R U
C36 C 0.6048(8) 0.2846(6) 0.3119(5) 0.071(2) Uani 1 1 d . .
H36 H 0.5720 0.2699 0.3531 0.085 Uiso 1 1 calc R U
C37 C 0.5431(6) 0.3117(5) 0.2426(4) 0.0529(17) Uani 1 1 d . .
H37 H 0.4683 0.3146 0.2373 0.064 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Co1 O2 95.08(16) . 3_665
O1 Co1 N1 93.92(17) . .
O2 Co1 N1 87.78(17) 3_665 .
O1 Co1 N2 170.07(19) . .
O2 Co1 N2 81.79(18) 3_665 .
N1 Co1 N2 76.6(2) . .
O1 Co1 N3 89.82(17) . .
O2 Co1 N3 102.26(17) 3_665 .
N1 Co1 N3 168.94(19) . .
N2 Co1 N3 100.0(2) . .
O1 Co1 N4 92.13(19) . .
O2 Co1 N4 172.60(19) 3_665 .
N1 Co1 N4 93.4(2) . .
N2 Co1 N4 91.4(2) . .
N3 Co1 N4 76.1(2) . .
O7 Co2 O10 117.7(2) . 2_545
O7 Co2 O5 108.3(3) . 3_666
O10 Co2 O5 109.7(2) 2_545 3_666
O7 Co2 O11 103.1(2) . .
O10 Co2 O11 117.3(2) 2_545 .
O5 Co2 O11 98.9(2) 3_666 .
C1 O1 Co1 134.4(3) . .
C1 O2 Co1 137.7(3) . 3_665
C8 O4 H4A 109.5 . .
C9 O5 Co2 122.5(5) . 3_666
C16 O7 Co2 124.0(4) . .
C17 O10 Co2 105.8(4) . 2
Co2 O11 H11A 109.5 . .
Co2 O11 H11B 129(5) . .
H11A O11 H11B 112.4 . .
C22 N1 C18 118.8(5) . .
C22 N1 Co1 116.8(4) . .
C18 N1 Co1 124.1(4) . .
C27 N2 C23 118.4(6) . .
C27 N2 Co1 125.1(5) . .
C23 N2 Co1 116.0(4) . .
C28 N3 C32 119.3(5) . .
C28 N3 Co1 124.6(4) . .
C32 N3 Co1 115.9(4) . .
C33 N4 C37 118.9(6) . .
C33 N4 Co1 115.9(4) . .
C37 N4 Co1 125.2(5) . .
O1 C1 O2 125.6(5) . .
O1 C1 C2 118.6(5) . .
O2 C1 C2 115.8(4) . .
C7 C2 C3 119.7(5) . .
C7 C2 C1 121.5(4) . .
C3 C2 C1 118.7(4) . .
C4 C3 C2 121.0(5) . .
C4 C3 H3 119.5 . .
C2 C3 H3 119.5 . .
C5 C4 C3 119.3(5) . .
C5 C4 C8 120.6(5) . .
C3 C4 C8 120.0(5) . .
C4 C5 C6 120.4(5) . .
C4 C5 H5 119.8 . .
C6 C5 H5 119.8 . .
C5 C6 C7 120.5(5) . .
C5 C6 C9 118.7(5) . .
C7 C6 C9 120.6(5) . .
C2 C7 C6 118.8(4) . .
C2 C7 C10 121.0(4) . .
C6 C7 C10 120.2(4) . .
O3 C8 O4 123.8(5) . .
O3 C8 C4 123.4(5) . .
O4 C8 C4 112.8(5) . .
O5 C9 O6 124.2(6) . .
O5 C9 C6 118.0(6) . .
O6 C9 C6 117.5(6) . .
C11 C10 C15 119.6(5) . .
C11 C10 C7 118.7(5) . .
C15 C10 C7 121.8(5) . .
C10 C11 C12 120.9(5) . .
C10 C11 H11 119.5 . .
C12 C11 H11 119.5 . .
C13 C12 C11 119.3(5) . .
C13 C12 C16 122.0(5) . .
C11 C12 C16 118.6(5) . .
C14 C13 C12 120.6(5) . .
C14 C13 H13 119.7 . .
C12 C13 H13 119.7 . .
C13 C14 C15 120.3(5) . .
C13 C14 C17 120.2(5) . .
C15 C14 C17 119.5(5) . .
C10 C15 C14 119.3(5) . .
C10 C15 H15 120.3 . .
C14 C15 H15 120.3 . .
O8 C16 O7 122.9(6) . .
O8 C16 C12 121.5(5) . .
O7 C16 C12 115.5(5) . .
O9 C17 O10 121.3(6) . .
O9 C17 C14 121.3(6) . .
O10 C17 C14 117.4(5) . .
N1 C18 C19 122.4(7) . .
N1 C18 H18 118.8 . .
C19 C18 H18 118.8 . .
C20 C19 C18 117.8(7) . .
C20 C19 H19 121.1 . .
C18 C19 H19 121.1 . .
C21 C20 C19 120.6(6) . .
C21 C20 H20 119.7 . .
C19 C20 H20 119.7 . .
C20 C21 C22 119.8(7) . .
C20 C21 H21 120.1 . .
C22 C21 H21 120.1 . .
N1 C22 C21 120.6(6) . .
N1 C22 C23 114.8(5) . .
C21 C22 C23 124.6(6) . .
N2 C23 C24 121.9(7) . .
N2 C23 C22 115.2(6) . .
C24 C23 C22 122.9(7) . .
C23 C24 C25 117.9(9) . .
C23 C24 H24 121.0 . .
C25 C24 H24 121.0 . .
C26 C25 C24 119.2(8) . .
C26 C25 H25 120.4 . .
C24 C25 H25 120.4 . .
C25 C26 C27 120.0(9) . .
C25 C26 H26 120.0 . .
C27 C26 H26 120.0 . .
N2 C27 C26 122.6(9) . .
N2 C27 H27 118.7 . .
C26 C27 H27 118.7 . .
N3 C28 C29 121.7(6) . .
N3 C28 H28 119.2 . .
C29 C28 H28 119.2 . .
C28 C29 C30 119.6(6) . .
C28 C29 H29 120.2 . .
C30 C29 H29 120.2 . .
C31 C30 C29 118.3(6) . .
C31 C30 H30 120.8 . .
C29 C30 H30 120.8 . .
C30 C31 C32 120.9(7) . .
C30 C31 H31 119.5 . .
C32 C31 H31 119.5 . .
N3 C32 C31 120.2(6) . .
N3 C32 C33 116.1(5) . .
C31 C32 C33 123.7(6) . .
N4 C33 C34 120.6(6) . .
N4 C33 C32 115.8(5) . .
C34 C33 C32 123.6(6) . .
C35 C34 C33 120.3(7) . .
C35 C34 H34 119.8 . .
C33 C34 H34 119.8 . .
C34 C35 C36 118.8(7) . .
C34 C35 H35 120.6 . .
C36 C35 H35 120.6 . .
C35 C36 C37 119.9(7) . .
C35 C36 H36 120.1 . .
C37 C36 H36 120.1 . .
N4 C37 C36 121.4(7) . .
N4 C37 H37 119.3 . .
C36 C37 H37 119.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O1 2.066(4) .
Co1 O2 2.120(4) 3_665
Co1 N1 2.121(5) .
Co1 N2 2.132(5) .
Co1 N3 2.143(5) .
Co1 N4 2.162(5) .
Co2 O7 1.892(5) .
Co2 O10 1.951(5) 2_545
Co2 O5 2.025(5) 3_666
Co2 O11 2.032(6) .
O1 C1 1.244(6) .
O2 C1 1.265(7) .
O2 Co1 2.120(4) 3_665
O3 C8 1.215(7) .
O4 C8 1.313(8) .
O4 H4A 0.8200 .
O5 C9 1.232(8) .
O5 Co2 2.025(5) 3_666
O6 C9 1.262(9) .
O7 C16 1.280(7) .
O8 C16 1.247(7) .
O9 C17 1.230(8) .
O10 C17 1.295(8) .
O10 Co2 1.951(5) 2
O11 H11A 0.8200 .
O11 H11B 0.851(10) .
N1 C22 1.345(8) .
N1 C18 1.362(8) .
N2 C27 1.347(9) .
N2 C23 1.349(9) .
N3 C28 1.358(8) .
N3 C32 1.360(8) .
N4 C33 1.347(8) .
N4 C37 1.364(8) .
C1 C2 1.516(7) .
C2 C7 1.401(7) .
C2 C3 1.406(7) .
C3 C4 1.391(8) .
C3 H3 0.9300 .
C4 C5 1.390(8) .
C4 C8 1.495(7) .
C5 C6 1.397(7) .
C5 H5 0.9300 .
C6 C7 1.413(7) .
C6 C9 1.522(8) .
C7 C10 1.487(7) .
C10 C11 1.400(8) .
C10 C15 1.400(8) .
C11 C12 1.403(7) .
C11 H11 0.9300 .
C12 C13 1.403(8) .
C12 C16 1.489(8) .
C13 C14 1.377(8) .
C13 H13 0.9300 .
C14 C15 1.427(7) .
C14 C17 1.483(8) .
C15 H15 0.9300 .
C18 C19 1.393(9) .
C18 H18 0.9300 .
C19 C20 1.368(12) .
C19 H19 0.9300 .
C20 C21 1.363(12) .
C20 H20 0.9300 .
C21 C22 1.399(9) .
C21 H21 0.9300 .
C22 C23 1.491(10) .
C23 C24 1.383(10) .
C24 C25 1.412(14) .
C24 H24 0.9300 .
C25 C26 1.352(15) .
C25 H25 0.9300 .
C26 C27 1.356(13) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.382(9) .
C28 H28 0.9300 .
C29 C30 1.387(10) .
C29 H29 0.9300 .
C30 C31 1.375(11) .
C30 H30 0.9300 .
C31 C32 1.389(9) .
C31 H31 0.9300 .
C32 C33 1.466(9) .
C33 C34 1.393(9) .
C34 C35 1.362(11) .
C34 H34 0.9300 .
C35 C36 1.374(13) .
C35 H35 0.9300 .
C36 C37 1.372(11) .
C36 H36 0.9300 .
C37 H37 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O10 Co2 O7 C16 49.5(6) 2_545
O5 Co2 O7 C16 -75.6(6) 3_666
O11 Co2 O7 C16 -179.7(5) .
Co1 O1 C1 O2 86.9(7) .
Co1 O1 C1 C2 -95.0(6) .
Co1 O2 C1 O1 3.6(9) 3_665
Co1 O2 C1 C2 -174.5(4) 3_665
O1 C1 C2 C7 -57.4(7) .
O2 C1 C2 C7 120.8(6) .
O1 C1 C2 C3 119.1(5) .
O2 C1 C2 C3 -62.6(7) .
C7 C2 C3 C4 2.6(8) .
C1 C2 C3 C4 -174.0(5) .
C2 C3 C4 C5 -4.7(8) .
C2 C3 C4 C8 174.4(5) .
C3 C4 C5 C6 1.9(9) .
C8 C4 C5 C6 -177.2(6) .
C4 C5 C6 C7 3.1(9) .
C4 C5 C6 C9 -171.3(6) .
C3 C2 C7 C6 2.3(8) .
C1 C2 C7 C6 178.8(5) .
C3 C2 C7 C10 -177.5(5) .
C1 C2 C7 C10 -1.0(8) .
C5 C6 C7 C2 -5.1(8) .
C9 C6 C7 C2 169.1(5) .
C5 C6 C7 C10 174.7(5) .
C9 C6 C7 C10 -11.1(8) .
C5 C4 C8 O3 -173.4(7) .
C3 C4 C8 O3 7.6(10) .
C5 C4 C8 O4 7.3(8) .
C3 C4 C8 O4 -171.8(6) .
Co2 O5 C9 O6 4.7(10) 3_666
Co2 O5 C9 C6 179.0(4) 3_666
C5 C6 C9 O5 -34.4(9) .
C7 C6 C9 O5 151.3(6) .
C5 C6 C9 O6 140.2(6) .
C7 C6 C9 O6 -34.1(9) .
C2 C7 C10 C11 119.3(6) .
C6 C7 C10 C11 -60.5(7) .
C2 C7 C10 C15 -59.8(7) .
C6 C7 C10 C15 120.4(6) .
C15 C10 C11 C12 -2.2(8) .
C7 C10 C11 C12 178.7(5) .
C10 C11 C12 C13 1.0(8) .
C10 C11 C12 C16 178.6(5) .
C11 C12 C13 C14 0.0(8) .
C16 C12 C13 C14 -177.5(5) .
C12 C13 C14 C15 0.2(9) .
C12 C13 C14 C17 -177.9(6) .
C11 C10 C15 C14 2.3(8) .
C7 C10 C15 C14 -178.6(5) .
C13 C14 C15 C10 -1.3(9) .
C17 C14 C15 C10 176.7(5) .
Co2 O7 C16 O8 9.5(9) .
Co2 O7 C16 C12 -172.1(4) .
C13 C12 C16 O8 -3.3(9) .
C11 C12 C16 O8 179.2(6) .
C13 C12 C16 O7 178.3(6) .
C11 C12 C16 O7 0.8(8) .
Co2 O10 C17 O9 -0.9(8) 2
Co2 O10 C17 C14 177.6(5) 2
C13 C14 C17 O9 6.3(10) .
C15 C14 C17 O9 -171.8(7) .
C13 C14 C17 O10 -172.3(6) .
C15 C14 C17 O10 9.7(9) .
C22 N1 C18 C19 0.3(9) .
Co1 N1 C18 C19 -173.8(5) .
N1 C18 C19 C20 0.5(10) .
C18 C19 C20 C21 -1.5(11) .
C19 C20 C21 C22 1.6(12) .
C18 N1 C22 C21 -0.3(9) .
Co1 N1 C22 C21 174.3(5) .
C18 N1 C22 C23 -179.5(5) .
Co1 N1 C22 C23 -4.9(6) .
C20 C21 C22 N1 -0.7(10) .
C20 C21 C22 C23 178.5(7) .
C27 N2 C23 C24 -0.1(9) .
Co1 N2 C23 C24 171.9(5) .
C27 N2 C23 C22 179.6(6) .
Co1 N2 C23 C22 -8.4(7) .
N1 C22 C23 N2 8.8(8) .
C21 C22 C23 N2 -170.4(6) .
N1 C22 C23 C24 -171.5(6) .
C21 C22 C23 C24 9.3(10) .
N2 C23 C24 C25 -1.8(10) .
C22 C23 C24 C25 178.6(7) .
C23 C24 C25 C26 1.6(12) .
C24 C25 C26 C27 0.4(14) .
C23 N2 C27 C26 2.2(11) .
Co1 N2 C27 C26 -169.0(6) .
C25 C26 C27 N2 -2.4(14) .
C32 N3 C28 C29 -0.5(10) .
Co1 N3 C28 C29 173.2(5) .
N3 C28 C29 C30 -0.5(12) .
C28 C29 C30 C31 0.3(12) .
C29 C30 C31 C32 0.9(12) .
C28 N3 C32 C31 1.6(9) .
Co1 N3 C32 C31 -172.6(5) .
C28 N3 C32 C33 179.2(6) .
Co1 N3 C32 C33 4.9(7) .
C30 C31 C32 N3 -1.8(11) .
C30 C31 C32 C33 -179.2(7) .
C37 N4 C33 C34 1.6(10) .
Co1 N4 C33 C34 -177.4(5) .
C37 N4 C33 C32 -176.6(6) .
Co1 N4 C33 C32 4.3(7) .
N3 C32 C33 N4 -6.2(8) .
C31 C32 C33 N4 171.3(6) .
N3 C32 C33 C34 175.7(6) .
C31 C32 C33 C34 -6.9(10) .
N4 C33 C34 C35 0.6(11) .
C32 C33 C34 C35 178.7(7) .
C33 C34 C35 C36 -2.9(12) .
C34 C35 C36 C37 2.9(13) .
C33 N4 C37 C36 -1.6(11) .
Co1 N4 C37 C36 177.4(6) .
C35 C36 C37 N4 -0.7(13) .
