#------------------------------------------------------------------------------
#$Date: 2018-10-05 15:19:55 +0300 (Fri, 05 Oct 2018) $
#$Revision: 211332 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/58/7035804.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035804
loop_
_publ_author_name
'Han, Min-Le'
'Bai, Liang'
'Tang, Ping'
'Wu, Xue-Qian'
'Wu, Ya-Pan'
'Zhao, Jun'
'Li, Dong-Sheng'
'Wang, Yao-Yu'
_publ_section_title
;
 Biphenyl-2,4,6,3',5'-pentacarboxylic acid as a tecton for six new Co(ii)
 coordination polymers: pH and N-donor ligand-dependent assemblies,
 structure diversities and magnetic properties.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14673
_journal_page_last               14685
_journal_paper_doi               10.1039/c5dt02147b
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C35 H29 Co2 N6 O14'
_chemical_formula_weight         875.50
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   constr
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-07-07 deposited with the CCDC.
2015-07-13 downloaded from the CCDC.
;
_cell_angle_alpha                112.206(6)
_cell_angle_beta                 90.401(5)
_cell_angle_gamma                94.839(2)
_cell_formula_units_Z            2
_cell_length_a                   10.553(4)
_cell_length_b                   12.789(6)
_cell_length_c                   14.443(6)
_cell_measurement_reflns_used    4862
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.7
_cell_volume                     1796.7(13)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean none
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0400
_diffrn_reflns_av_unetI/netI     0.0440
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            16406
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.495
_diffrn_reflns_theta_min         1.819
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    1.003
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.830
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.618
_exptl_crystal_density_meas      ?
_exptl_crystal_description       block
_exptl_crystal_F_000             894
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.220
_refine_diff_density_max         2.700
_refine_diff_density_min         -0.499
_refine_diff_density_rms         0.095
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     532
_refine_ls_number_reflns         6665
_refine_ls_number_restraints     13
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.0579
_refine_ls_R_factor_gt           0.0516
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0753P)²+3.6111P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1416
_refine_ls_wR_factor_ref         0.1465
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5826
_reflns_number_total             6665
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt02147b2.cif
_cod_data_source_block           Z
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7035800--7035805.cif.
;
_cod_database_code               7035804
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.788
_shelx_estimated_absorpt_t_max   0.809
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Co1 Co 0.26373(4) 0.42354(3) 0.22962(3) 0.01641(14) Uani 1 1 d . .
Co2 Co -0.18213(4) 0.27114(4) 0.67833(3) 0.02046(15) Uani 1 1 d . .
O1 O 0.2989(3) 0.3987(2) 0.35820(18) 0.0285(6) Uani 1 1 d . .
O2 O 0.3607(3) 0.5676(2) 0.47621(18) 0.0300(6) Uani 1 1 d . .
O3 O 0.2327(5) 0.0594(3) 0.4393(3) 0.0775(15) Uani 1 1 d . .
O4 O 0.2686(4) 0.0779(3) 0.5944(3) 0.0652(11) Uani 1 1 d . .
O5 O 0.5441(2) 0.5944(2) 0.8129(2) 0.0251(5) Uani 1 1 d . .
O6 O 0.4940(3) 0.4191(2) 0.8079(2) 0.0345(7) Uani 1 1 d . .
O7 O 0.2451(3) 0.7012(2) 1.17203(18) 0.0262(6) Uani 1 1 d . .
O8 O 0.1248(4) 0.8102(3) 1.1262(2) 0.0502(9) Uani 1 1 d . .
O9 O -0.0334(2) 0.3896(2) 0.75333(19) 0.0261(6) Uani 1 1 d . .
O10 O -0.0691(2) 0.5577(2) 0.74731(19) 0.0244(5) Uani 1 1 d . .
O11 O 0.2346(3) 0.4647(2) 0.10309(19) 0.0282(6) Uani 1 1 d D .
H11A H 0.2711 0.4221 0.0557 0.042 Uiso 1 1 calc DR U
H11B H 0.259(4) 0.5341(7) 0.117(3) 0.042 Uiso 1 1 d D U
O12 O 0.3129(2) 0.6063(2) 0.31175(18) 0.0198(5) Uani 1 1 d D .
H12A H 0.337(3) 0.602(4) 0.3660(17) 0.030 Uiso 1 1 d D U
H12B H 0.376(2) 0.612(4) 0.278(2) 0.030 Uiso 1 1 d D U
O13 O -0.0788(3) 0.1375(2) 0.6780(2) 0.0381(7) Uani 1 1 d D .
H13A H -0.0782 0.1351 0.7340 0.057 Uiso 1 1 calc DR U
H13B H -0.120(5) 0.078(3) 0.6351(13) 0.057 Uiso 1 1 d D U
O14 O -0.3359(3) 0.1466(2) 0.6061(2) 0.0383(7) Uani 1 1 d D .
H14A H -0.3963 0.1565 0.6429 0.057 Uiso 1 1 calc DR U
H14B H -0.304(4) 0.085(2) 0.596(4) 0.057 Uiso 1 1 d D U
N1 N 0.2220(3) 0.2476(2) 0.1556(2) 0.0232(6) Uani 1 1 d . .
N2 N 0.1793(3) 0.0842(2) 0.0281(2) 0.0233(6) Uani 1 1 d . .
N3 N 0.1010(3) -0.2092(3) -0.3755(2) 0.0260(7) Uani 1 1 d . .
N4 N 0.1214(3) -0.2685(3) -0.5389(2) 0.0260(7) Uani 1 1 d . .
N5 N 0.5273(3) 0.1135(3) 0.2103(2) 0.0290(7) Uani 1 1 d . .
N6 N 0.5597(4) 0.2461(3) 0.3570(3) 0.0337(8) Uani 1 1 d D .
H6A H 0.581(5) 0.310(2) 0.403(3) 0.051 Uiso 1 1 d D U
C1 C 0.3204(3) 0.4646(3) 0.4478(3) 0.0214(7) Uani 1 1 d . .
C2 C 0.2944(3) 0.4125(3) 0.5241(2) 0.0200(7) Uani 1 1 d . .
C3 C 0.2805(4) 0.2958(3) 0.4945(3) 0.0249(8) Uani 1 1 d . .
H3 H 0.2890 0.2503 0.4276 0.030 Uiso 1 1 calc R U
C4 C 0.2544(4) 0.2457(3) 0.5628(3) 0.0294(8) Uani 1 1 d . .
C5 C 0.2369(4) 0.3144(3) 0.6624(3) 0.0267(8) Uani 1 1 d . .
H5 H 0.2177 0.2814 0.7086 0.032 Uiso 1 1 calc R U
C6 C 0.2481(3) 0.4318(3) 0.6929(2) 0.0189(7) Uani 1 1 d . .
C7 C 0.2782(3) 0.4806(3) 0.6237(2) 0.0197(7) Uani 1 1 d . .
H7 H 0.2876 0.5592 0.6441 0.024 Uiso 1 1 calc R U
C8 C 0.2487(5) 0.1174(4) 0.5301(3) 0.0454(12) Uani 1 1 d . .
C9 C 0.2336(3) 0.5086(3) 0.8001(2) 0.0165(6) Uani 1 1 d . .
C10 C 0.3417(3) 0.5531(3) 0.8655(3) 0.0189(7) Uani 1 1 d . .
C11 C 0.3297(3) 0.6248(3) 0.9647(3) 0.0218(7) Uani 1 1 d . .
H11 H 0.4011 0.6500 1.0082 0.026 Uiso 1 1 calc R U
C12 C 0.2121(3) 0.6584(3) 0.9987(2) 0.0193(7) Uani 1 1 d . .
C13 C 0.1055(3) 0.6210(3) 0.9336(2) 0.0211(7) Uani 1 1 d . .
H13 H 0.0274 0.6478 0.9551 0.025 Uiso 1 1 calc R U
C14 C 0.1157(3) 0.5432(3) 0.8357(2) 0.0179(7) Uani 1 1 d . .
C15 C 0.4702(3) 0.5193(3) 0.8262(3) 0.0211(7) Uani 1 1 d . .
C16 C 0.1939(4) 0.7307(3) 1.1078(3) 0.0230(7) Uani 1 1 d . .
C17 C -0.0057(3) 0.4932(3) 0.7730(2) 0.0190(7) Uani 1 1 d . .
C18 C 0.2040(4) 0.1978(3) 0.0577(3) 0.0298(8) Uani 1 1 d . .
H18 H 0.2079 0.2362 0.0143 0.036 Uiso 1 1 calc R U
C19 C 0.2070(4) 0.1622(3) 0.1908(3) 0.0277(8) Uani 1 1 d . .
H19 H 0.2137 0.1718 0.2578 0.033 Uiso 1 1 calc R U
C20 C 0.1808(4) 0.0608(3) 0.1129(3) 0.0294(8) Uani 1 1 d . .
H20 H 0.1668 -0.0102 0.1168 0.035 Uiso 1 1 calc R U
C21 C 0.1575(4) 0.0075(3) -0.0738(3) 0.0242(8) Uani 1 1 d . .
C22 C 0.1551(6) 0.0501(4) -0.1480(3) 0.0516(14) Uani 1 1 d . .
H22 H 0.1683 0.1280 -0.1311 0.062 Uiso 1 1 calc R U
C23 C 0.1332(6) -0.0210(4) -0.2473(3) 0.0469(13) Uani 1 1 d . .
H23 H 0.1288 0.0088 -0.2967 0.056 Uiso 1 1 calc R U
C24 C 0.1181(4) -0.1368(3) -0.2722(3) 0.0253(8) Uani 1 1 d . .
C25 C 0.1189(4) -0.1800(3) -0.1984(3) 0.0316(9) Uani 1 1 d . .
H25 H 0.1059 -0.2580 -0.2154 0.038 Uiso 1 1 calc R U
C26 C 0.1390(4) -0.1081(3) -0.0985(3) 0.0296(8) Uani 1 1 d . .
H26 H 0.1401 -0.1377 -0.0488 0.036 Uiso 1 1 calc R U
C27 C 0.1453(4) -0.1830(3) -0.4528(3) 0.0287(8) Uani 1 1 d . .
H27 H 0.1871 -0.1133 -0.4458 0.034 Uiso 1 1 calc R U
C28 C 0.0449(4) -0.3191(3) -0.4161(3) 0.0327(9) Uani 1 1 d . .
H28 H 0.0059 -0.3608 -0.3818 0.039 Uiso 1 1 calc R U
C29 C 0.0580(4) -0.3536(3) -0.5157(3) 0.0344(9) Uani 1 1 d . .
H29 H 0.0285 -0.4248 -0.5622 0.041 Uiso 1 1 calc R U
C30 C 0.5060(5) 0.1172(4) 0.0429(3) 0.0410(11) Uani 1 1 d . .
H30 H 0.5096 0.1959 0.0713 0.049 Uiso 1 1 calc R U
C31 C 0.5125(4) 0.0555(3) 0.1033(3) 0.0270(8) Uani 1 1 d . .
C32 C 0.5060(5) -0.0605(3) 0.0607(3) 0.0408(11) Uani 1 1 d . .
H32 H 0.5095 -0.1019 0.1013 0.049 Uiso 1 1 calc R U
C33 C 0.5297(6) 0.0633(4) 0.2791(4) 0.0522(13) Uani 1 1 d . .
H33 H 0.5191 -0.0142 0.2653 0.063 Uiso 1 1 calc R U
C34 C 0.5499(5) 0.1464(4) 0.3702(3) 0.0454(11) Uani 1 1 d . .
H34 H 0.5560 0.1372 0.4309 0.054 Uiso 1 1 calc R U
C35 C 0.5455(4) 0.2254(3) 0.2604(3) 0.0356(9) Uani 1 1 d . .
H35 H 0.5479 0.2798 0.2321 0.043 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Co1 N1 88.86(11) . .
O1 Co1 O10 95.16(11) . 2_566
N1 Co1 O10 90.08(11) . 2_566
O1 Co1 O11 174.77(10) . .
N1 Co1 O11 96.27(11) . .
O10 Co1 O11 85.86(10) 2_566 .
O1 Co1 O5 92.53(11) . 2_666
N1 Co1 O5 89.29(11) . 2_666
O10 Co1 O5 172.27(10) 2_566 2_666
O11 Co1 O5 86.54(10) . 2_666
O1 Co1 O12 88.91(10) . .
N1 Co1 O12 177.48(10) . .
O10 Co1 O12 91.28(9) 2_566 .
O11 Co1 O12 85.94(10) . .
O5 Co1 O12 89.64(9) 2_666 .
O9 Co2 O13 91.34(12) . .
O9 Co2 N4 91.58(12) . 2
O13 Co2 N4 95.51(12) . 2
O9 Co2 O14 177.59(11) . .
O13 Co2 O14 87.43(13) . .
N4 Co2 O14 90.60(12) 2 .
O9 Co2 O12 94.98(10) . 2_566
O13 Co2 O12 170.22(11) . 2_566
N4 Co2 O12 91.78(11) 2 2_566
O14 Co2 O12 85.97(11) . 2_566
O9 Co2 O7 83.97(11) . 2_567
O13 Co2 O7 91.07(11) . 2_567
N4 Co2 O7 172.15(11) 2 2_567
O14 Co2 O7 93.98(11) . 2_567
O12 Co2 O7 82.20(9) 2_566 2_567
C1 O1 Co1 133.4(2) . .
C15 O5 Co1 125.2(2) . 2_666
C16 O7 Co2 127.3(2) . 2_567
C17 O9 Co2 135.6(2) . .
C17 O10 Co1 125.3(2) . 2_566
Co1 O11 H11A 109.5 . .
Co1 O11 H11B 110(3) . .
H11A O11 H11B 112.3 . .
Co2 O12 Co1 122.13(11) 2_566 .
Co2 O12 H12A 117(3) 2_566 .
Co1 O12 H12A 97(3) . .
Co2 O12 H12B 112(3) 2_566 .
Co1 O12 H12B 96(3) . .
H12A O12 H12B 110.9(17) . .
Co2 O13 H13A 109.5 . .
Co2 O13 H13B 104(3) . .
H13A O13 H13B 111.3 . .
Co2 O14 H14A 109.5 . .
Co2 O14 H14B 103(4) . .
H14A O14 H14B 113.5 . .
C18 N1 C19 105.5(3) . .
C18 N1 Co1 122.9(2) . .
C19 N1 Co1 131.6(2) . .
C18 N2 C20 106.6(3) . .
C18 N2 C21 124.5(3) . .
C20 N2 C21 128.9(3) . .
C27 N3 C28 106.8(3) . .
C27 N3 C24 125.2(3) . .
C28 N3 C24 127.9(3) . .
C27 N4 C29 105.3(3) . .
C27 N4 Co2 125.1(3) . 2
C29 N4 Co2 129.5(2) . 2
C35 N5 C33 107.5(3) . .
C35 N5 C31 126.3(3) . .
C33 N5 C31 126.1(3) . .
C35 N6 C34 109.0(4) . .
C35 N6 H6A 126(4) . .
C34 N6 H6A 124(4) . .
O1 C1 O2 124.9(3) . .
O1 C1 C2 115.4(3) . .
O2 C1 C2 119.7(3) . .
C3 C2 C7 119.5(3) . .
C3 C2 C1 119.8(3) . .
C7 C2 C1 120.6(3) . .
C2 C3 C4 121.0(3) . .
C2 C3 H3 119.5 . .
C4 C3 H3 119.5 . .
C3 C4 C5 119.2(3) . .
C3 C4 C8 120.1(3) . .
C5 C4 C8 120.7(3) . .
C6 C5 C4 120.4(3) . .
C6 C5 H5 119.8 . .
C4 C5 H5 119.8 . .
C5 C6 C7 119.5(3) . .
C5 C6 C9 122.0(3) . .
C7 C6 C9 118.5(3) . .
C6 C7 C2 120.3(3) . .
C6 C7 H7 119.8 . .
C2 C7 H7 119.8 . .
O4 C8 O3 124.0(4) . .
O4 C8 C4 118.2(4) . .
O3 C8 C4 117.6(4) . .
C14 C9 C10 118.3(3) . .
C14 C9 C6 121.5(3) . .
C10 C9 C6 120.1(3) . .
C11 C10 C9 120.7(3) . .
C11 C10 C15 120.8(3) . .
C9 C10 C15 118.5(3) . .
C12 C11 C10 120.2(3) . .
C12 C11 H11 119.9 . .
C10 C11 H11 119.9 . .
C11 C12 C13 119.9(3) . .
C11 C12 C16 121.7(3) . .
C13 C12 C16 118.4(3) . .
C12 C13 C14 120.1(3) . .
C12 C13 H13 119.9 . .
C14 C13 H13 119.9 . .
C9 C14 C13 120.6(3) . .
C9 C14 C17 121.5(3) . .
C13 C14 C17 117.8(3) . .
O6 C15 O5 125.4(3) . .
O6 C15 C10 118.0(3) . .
O5 C15 C10 116.6(3) . .
O8 C16 O7 125.6(3) . .
O8 C16 C12 117.7(3) . .
O7 C16 C12 116.6(3) . .
O9 C17 O10 126.9(3) . .
O9 C17 C14 114.8(3) . .
O10 C17 C14 118.3(3) . .
N1 C18 N2 111.7(3) . .
N1 C18 H18 124.1 . .
N2 C18 H18 124.1 . .
C20 C19 N1 109.8(3) . .
C20 C19 H19 125.1 . .
N1 C19 H19 125.1 . .
C19 C20 N2 106.4(3) . .
C19 C20 H20 126.8 . .
N2 C20 H20 126.8 . .
C22 C21 C26 119.7(3) . .
C22 C21 N2 119.2(3) . .
C26 C21 N2 121.1(3) . .
C21 C22 C23 121.1(4) . .
C21 C22 H22 119.5 . .
C23 C22 H22 119.5 . .
C24 C23 C22 119.1(4) . .
C24 C23 H23 120.4 . .
C22 C23 H23 120.4 . .
C25 C24 C23 120.1(3) . .
C25 C24 N3 121.5(3) . .
C23 C24 N3 118.4(3) . .
C24 C25 C26 120.5(3) . .
C24 C25 H25 119.7 . .
C26 C25 H25 119.7 . .
C21 C26 C25 119.4(3) . .
C21 C26 H26 120.3 . .
C25 C26 H26 120.3 . .
N4 C27 N3 111.5(3) . .
N4 C27 H27 124.3 . .
N3 C27 H27 124.3 . .
C29 C28 N3 105.9(3) . .
C29 C28 H28 127.1 . .
N3 C28 H28 127.1 . .
C28 C29 N4 110.5(3) . .
C28 C29 H29 124.8 . .
N4 C29 H29 124.8 . .
C31 C30 C32 119.5(4) . 2_655
C31 C30 H30 120.2 . .
C32 C30 H30 120.2 2_655 .
C32 C31 C30 119.7(4) . .
C32 C31 N5 120.4(4) . .
C30 C31 N5 119.9(3) . .
C31 C32 C30 120.7(4) . 2_655
C31 C32 H32 119.6 . .
C30 C32 H32 119.6 2_655 .
C34 C33 N5 107.6(4) . .
C34 C33 H33 126.2 . .
N5 C33 H33 126.2 . .
C33 C34 N6 107.2(4) . .
C33 C34 H34 126.4 . .
N6 C34 H34 126.4 . .
N6 C35 N5 108.7(4) . .
N6 C35 H35 125.6 . .
N5 C35 H35 125.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O1 2.036(3) .
Co1 N1 2.100(3) .
Co1 O10 2.103(3) 2_566
Co1 O11 2.112(3) .
Co1 O5 2.129(3) 2_666
Co1 O12 2.198(3) .
Co2 O9 2.066(3) .
Co2 O13 2.103(3) .
Co2 N4 2.106(3) 2
Co2 O14 2.131(3) .
Co2 O12 2.140(2) 2_566
Co2 O7 2.172(3) 2_567
O1 C1 1.256(4) .
O2 C1 1.257(4) .
O3 C8 1.240(6) .
O4 C8 1.238(6) .
O5 C15 1.258(4) .
O5 Co1 2.129(3) 2_666
O6 C15 1.254(4) .
O7 C16 1.259(4) .
O7 Co2 2.172(3) 2_567
O8 C16 1.249(5) .
O9 C17 1.253(4) .
O10 C17 1.260(4) .
O10 Co1 2.103(3) 2_566
O11 H11A 0.8200 .
O11 H11B 0.850(10) .
O12 Co2 2.140(2) 2_566
O12 H12A 0.845(10) .
O12 H12B 0.844(10) .
O13 H13A 0.8200 .
O13 H13B 0.856(10) .
O14 H14A 0.8200 .
O14 H14B 0.846(10) .
N1 C18 1.318(5) .
N1 C19 1.367(5) .
N2 C18 1.352(5) .
N2 C20 1.367(5) .
N2 C21 1.431(4) .
N3 C27 1.357(5) .
N3 C28 1.380(5) .
N3 C24 1.428(4) .
N4 C27 1.314(5) .
N4 C29 1.379(5) .
N4 Co2 2.106(3) 2
N5 C35 1.333(5) .
N5 C33 1.374(6) .
N5 C31 1.440(5) .
N6 C35 1.323(5) .
N6 C34 1.354(6) .
N6 H6A 0.849(10) .
C1 C2 1.504(5) .
C2 C3 1.382(5) .
C2 C7 1.393(5) .
C3 C4 1.383(5) .
C3 H3 0.9300 .
C4 C5 1.397(5) .
C4 C8 1.522(6) .
C5 C6 1.389(5) .
C5 H5 0.9300 .
C6 C7 1.391(5) .
C6 C9 1.505(4) .
C7 H7 0.9300 .
C9 C14 1.392(5) .
C9 C10 1.410(5) .
C10 C11 1.393(5) .
C10 C15 1.506(5) .
C11 C12 1.381(5) .
C11 H11 0.9300 .
C12 C13 1.390(5) .
C12 C16 1.519(5) .
C13 C14 1.399(5) .
C13 H13 0.9300 .
C14 C17 1.509(5) .
C18 H18 0.9300 .
C19 C20 1.361(5) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 C22 1.374(6) .
C21 C26 1.379(5) .
C22 C23 1.383(6) .
C22 H22 0.9300 .
C23 C24 1.381(6) .
C23 H23 0.9300 .
C24 C25 1.374(5) .
C25 C26 1.390(5) .
C25 H25 0.9300 .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.347(6) .
C28 H28 0.9300 .
C29 H29 0.9300 .
C30 C31 1.384(6) .
C30 C32 1.394(6) 2_655
C30 H30 0.9300 .
C31 C32 1.370(6) .
C32 C30 1.394(6) 2_655
C32 H32 0.9300 .
C33 C34 1.344(6) .
C33 H33 0.9300 .
C34 H34 0.9300 .
C35 H35 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Co1 O1 C1 O2 -21.5(6) . .
Co1 O1 C1 C2 158.4(3) . .
O1 C1 C2 C3 15.9(5) . .
O2 C1 C2 C3 -164.2(3) . .
O1 C1 C2 C7 -161.1(3) . .
O2 C1 C2 C7 18.7(5) . .
C7 C2 C3 C4 -1.8(6) . .
C1 C2 C3 C4 -178.9(3) . .
C2 C3 C4 C5 2.5(6) . .
C2 C3 C4 C8 -175.7(4) . .
C3 C4 C5 C6 -1.2(6) . .
C8 C4 C5 C6 177.0(4) . .
C4 C5 C6 C7 -0.7(6) . .
C4 C5 C6 C9 -178.3(4) . .
C5 C6 C7 C2 1.3(5) . .
C9 C6 C7 C2 179.0(3) . .
C3 C2 C7 C6 -0.1(5) . .
C1 C2 C7 C6 176.9(3) . .
C3 C4 C8 O4 155.7(5) . .
C5 C4 C8 O4 -22.4(7) . .
C3 C4 C8 O3 -19.6(7) . .
C5 C4 C8 O3 162.2(5) . .
C5 C6 C9 C14 -90.0(4) . .
C7 C6 C9 C14 92.4(4) . .
C5 C6 C9 C10 94.0(4) . .
C7 C6 C9 C10 -83.6(4) . .
C14 C9 C10 C11 3.6(5) . .
C6 C9 C10 C11 179.7(3) . .
C14 C9 C10 C15 -177.8(3) . .
C6 C9 C10 C15 -1.7(5) . .
C9 C10 C11 C12 -3.8(5) . .
C15 C10 C11 C12 177.6(3) . .
C10 C11 C12 C13 -0.3(5) . .
C10 C11 C12 C16 176.3(3) . .
C11 C12 C13 C14 4.5(5) . .
C16 C12 C13 C14 -172.2(3) . .
C10 C9 C14 C13 0.6(5) . .
C6 C9 C14 C13 -175.4(3) . .
C10 C9 C14 C17 -175.5(3) . .
C6 C9 C14 C17 8.4(5) . .
C12 C13 C14 C9 -4.7(5) . .
C12 C13 C14 C17 171.6(3) . .
Co1 O5 C15 O6 -6.7(5) 2_666 .
Co1 O5 C15 C10 174.5(2) 2_666 .
C11 C10 C15 O6 108.3(4) . .
C9 C10 C15 O6 -70.3(4) . .
C11 C10 C15 O5 -72.9(4) . .
C9 C10 C15 O5 108.5(4) . .
Co2 O7 C16 O8 24.5(6) 2_567 .
Co2 O7 C16 C12 -151.6(2) 2_567 .
C11 C12 C16 O8 137.5(4) . .
C13 C12 C16 O8 -45.8(5) . .
C11 C12 C16 O7 -46.0(5) . .
C13 C12 C16 O7 130.6(4) . .
Co2 O9 C17 O10 -1.3(6) . .
Co2 O9 C17 C14 177.6(2) . .
Co1 O10 C17 O9 51.7(5) 2_566 .
Co1 O10 C17 C14 -127.1(3) 2_566 .
C9 C14 C17 O9 64.7(4) . .
C13 C14 C17 O9 -111.5(4) . .
C9 C14 C17 O10 -116.3(4) . .
C13 C14 C17 O10 67.5(4) . .
C19 N1 C18 N2 -0.6(5) . .
Co1 N1 C18 N2 179.7(2) . .
C20 N2 C18 N1 0.5(5) . .
C21 N2 C18 N1 -179.1(3) . .
C18 N1 C19 C20 0.5(5) . .
Co1 N1 C19 C20 -179.8(3) . .
N1 C19 C20 N2 -0.2(5) . .
C18 N2 C20 C19 -0.2(5) . .
C21 N2 C20 C19 179.3(4) . .
C18 N2 C21 C22 -3.2(6) . .
C20 N2 C21 C22 177.4(4) . .
C18 N2 C21 C26 176.7(4) . .
C20 N2 C21 C26 -2.7(6) . .
C26 C21 C22 C23 0.6(8) . .
N2 C21 C22 C23 -179.4(5) . .
C21 C22 C23 C24 -2.3(9) . .
C22 C23 C24 C25 3.0(8) . .
C22 C23 C24 N3 -177.4(5) . .
C27 N3 C24 C25 -153.3(4) . .
C28 N3 C24 C25 22.6(6) . .
C27 N3 C24 C23 27.1(6) . .
C28 N3 C24 C23 -157.0(5) . .
C23 C24 C25 C26 -2.1(7) . .
N3 C24 C25 C26 178.3(4) . .
C22 C21 C26 C25 0.3(7) . .
N2 C21 C26 C25 -179.6(4) . .
C24 C25 C26 C21 0.4(7) . .
C29 N4 C27 N3 0.4(5) . .
Co2 N4 C27 N3 -175.9(3) 2 .
C28 N3 C27 N4 -0.2(5) . .
C24 N3 C27 N4 176.3(3) . .
C27 N3 C28 C29 0.0(5) . .
C24 N3 C28 C29 -176.5(4) . .
N3 C28 C29 N4 0.2(5) . .
C27 N4 C29 C28 -0.4(5) . .
Co2 N4 C29 C28 175.7(3) 2 .
C32 C30 C31 C32 -0.6(8) 2_655 .
C32 C30 C31 N5 178.8(4) 2_655 .
C35 N5 C31 C32 174.0(4) . .
C33 N5 C31 C32 -3.6(7) . .
C35 N5 C31 C30 -5.4(6) . .
C33 N5 C31 C30 177.0(5) . .
C30 C31 C32 C30 0.6(8) . 2_655
N5 C31 C32 C30 -178.8(4) . 2_655
C35 N5 C33 C34 -0.2(6) . .
C31 N5 C33 C34 177.7(4) . .
N5 C33 C34 N6 0.1(6) . .
C35 N6 C34 C33 0.2(6) . .
C34 N6 C35 N5 -0.3(5) . .
C33 N5 C35 N6 0.3(5) . .
C31 N5 C35 N6 -177.6(4) . .
