#------------------------------------------------------------------------------
#$Date: 2015-10-09 14:36:09 +0300 (Fri, 09 Oct 2015) $
#$Revision: 161812 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/58/7035856.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035856
loop_
_publ_author_name
'Hu, Yang-Yang'
'Xiao-Zhang, ?'
'Zhao, De-Chuan'
'Guo, Hai-Yang'
'Fu, Li-Wei'
'Guo, Lan-Lan'
'Cui, Xiao-Bing'
'Huo, Qi-Sheng'
'Xu, Ji-Qing'
_publ_section_title
;
 Tuning the structures based on polyoxometalates from 1-D to 2-D by using
 different secondary organic ligands.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14830
_journal_page_last               14841
_journal_paper_doi               10.1039/c5dt02060c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C32 H36 Cu Ge N10 O44 W12'
_chemical_formula_weight         3606.95
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-07-14 deposited with the CCDC.
2015-07-17 downloaded from the CCDC.
;
_cell_angle_alpha                110.394(3)
_cell_angle_beta                 97.412(3)
_cell_angle_gamma                111.891(2)
_cell_formula_units_Z            1
_cell_length_a                   11.110(2)
_cell_length_b                   12.786(3)
_cell_length_c                   13.191(3)
_cell_measurement_reflns_used    5357
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.0990
_cell_measurement_theta_min      3.4100
_cell_volume                     1555.8(6)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_molecular_graphics    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 15.9737
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.858
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0432
_diffrn_reflns_av_unetI/netI     0.0682
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.858
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            13888
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.858
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.091
_diffrn_reflns_theta_min         3.064
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    22.996
_exptl_absorpt_correction_T_max  0.093
_exptl_absorpt_correction_T_min  0.038
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
Analytical numeric absorption correction using a multifaceted crystal
            model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            dark_green
_exptl_crystal_density_diffrn    3.850
_exptl_crystal_description       block
_exptl_crystal_F_000             1598
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.190
_refine_diff_density_max         2.395
_refine_diff_density_min         -2.889
_refine_diff_density_rms         0.314
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     436
_refine_ls_number_reflns         7152
_refine_ls_number_restraints     462
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.0759
_refine_ls_R_factor_gt           0.0557
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0251P)²+27.8761P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1103
_refine_ls_wR_factor_ref         0.1238
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5491
_reflns_number_total             7152
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt02060c2.cif
_cod_data_source_block           shelx_2
_cod_depositor_comments
'Adding full bibliography for 7035855--7035860.cif.'
_cod_database_code               7035856
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.055
_shelx_estimated_absorpt_t_max   0.097
_exptl_absorpt_special_details
;
R(int) was 0.0456 before and 0.0430 after correction. The Ratio of minimum to 
maximum transmission is 0.4086.   
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
W1 W 1.80211(6) 0.70692(5) 0.47908(5) 0.03574(15) Uani 1 1 d . . .
W2 W 1.24274(7) 0.59341(7) 0.55260(6) 0.0493(2) Uani 1 1 d . . .
W3 W 1.54643(7) 0.80120(6) 0.53354(6) 0.0534(2) Uani 1 1 d . . .
W4 W 1.18956(6) 0.36198(5) 0.28348(5) 0.03341(15) Uani 1 1 d . . .
W5 W 1.49227(7) 0.57086(5) 0.26362(5) 0.03733(16) Uani 1 1 d . . .
W6 W 1.55087(7) 0.72905(6) 0.76817(5) 0.0480(2) Uani 1 1 d . . .
Ge1 Ge 1.5000 0.5000 0.5000 0.0235(4) Uani 1 2 d S . P
O1 O 1.420(2) 0.4461(18) 0.3624(17) 0.039(3) Uani 0.5 1 d . U P
O2 O 1.331(2) 0.445(2) 0.4674(18) 0.044(4) Uani 0.5 1 d . U P
O3 O 1.426(2) 0.3914(19) 0.5521(16) 0.038(4) Uani 0.5 1 d . U P
O4 O 1.464(2) 0.630(2) 0.5773(18) 0.046(4) Uani 0.5 1 d . U P
O5 O 1.8609(16) 0.7299(12) 0.6315(11) 0.071(3) Uani 1 1 d . U .
O6 O 1.4898(13) 0.6040(14) 0.1526(11) 0.070(4) Uani 1 1 d . U .
O7 O 1.0464(13) 0.2975(11) 0.1789(11) 0.073(4) Uani 1 1 d . U .
O8 O 1.6837(15) 0.6458(13) 0.3313(12) 0.082(3) Uani 1 1 d . U .
O9 O 1.2686(13) 0.2588(11) 0.2144(12) 0.067(3) Uani 1 1 d . U .
O10 O 1.7211(15) 0.8109(14) 0.5336(12) 0.085(4) Uani 1 1 d . U .
O11 O 1.5778(13) 0.8339(11) 0.8959(10) 0.056(3) Uani 1 1 d . U .
O12 O 1.4878(14) 0.7110(13) 0.3729(12) 0.078(3) Uani 1 1 d . U .
O13 O 1.9466(13) 0.8047(12) 0.4701(9) 0.074(4) Uani 1 1 d . U .
O14 O 1.8185(16) 0.5560(12) 0.4286(10) 0.069(3) Uani 1 1 d . U .
O15 O 1.1721(14) 0.4953(11) 0.3914(11) 0.064(3) Uani 1 1 d . U .
O16 O 1.4998(14) 0.4168(11) 0.2057(13) 0.073(3) Uani 1 1 d . U .
O17 O 1.5765(12) 0.9437(10) 0.5499(10) 0.054(3) Uani 1 1 d . U .
O18 O 1.3569(15) 0.7277(14) 0.5262(12) 0.093(4) Uani 1 1 d . U .
O19 O 1.3037(15) 0.4836(12) 0.2405(12) 0.075(3) Uani 1 1 d . U .
O20 O 1.5922(15) 0.8312(15) 0.6888(12) 0.095(4) Uani 1 1 d . U .
O21 O 1.3661(15) 0.6721(14) 0.7008(12) 0.091(4) Uani 1 1 d . U .
O22 O 1.1209(14) 0.6357(11) 0.5763(10) 0.061(3) Uani 1 1 d . U .
Cu1 Cu 1.5000 1.0000 1.0000 0.0407(6) Uani 1 2 d S . P
O23 O 1.7031(13) 1.1887(12) 0.8467(11) 0.066(4) Uani 1 1 d . U .
O24 O 1.6521(11) 1.1159(10) 0.9724(9) 0.051(3) Uani 1 1 d . U .
N1 N 1.3963(8) 0.9823(8) 0.8604(6) 0.033(3) Uani 1 1 d G . .
C1 C 1.2576(8) 0.9107(8) 0.8059(8) 0.049(4) Uani 1 1 d G . .
H1A H 1.2030 0.8624 0.8362 0.059 Uiso 1 1 calc R U .
C2 C 1.2005(8) 0.9114(9) 0.7061(8) 0.053(4) Uani 1 1 d G . .
H2A H 1.1077 0.8636 0.6697 0.064 Uiso 1 1 calc R U .
C3 C 1.2820(11) 0.9837(10) 0.6608(7) 0.058(5) Uani 1 1 d G . .
H3A H 1.2438 0.9842 0.5941 0.070 Uiso 1 1 calc R U .
C4 C 1.4207(11) 1.0553(9) 0.7153(8) 0.049(4) Uani 1 1 d G . .
H4A H 1.4752 1.1036 0.6850 0.058 Uiso 1 1 calc R U .
C5 C 1.4778(7) 1.0546(8) 0.8151(7) 0.040(4) Uani 1 1 d G . .
C6 C 1.6203(17) 1.1260(15) 0.8830(13) 0.047(4) Uani 1 1 d . . .
N5 N 1.183(2) 0.696(2) 0.2885(18) 0.110(8) Uani 1 1 d . . .
H5A H 1.1999 0.6899 0.3510 0.132 Uiso 1 1 calc R U .
H5B H 1.2456 0.7480 0.2740 0.132 Uiso 1 1 calc R U .
N2 N 0.318(2) 0.271(2) 0.9380(18) 0.103(7) Uani 1 1 d . . .
H2B H 0.3691 0.3108 0.9068 0.124 Uiso 1 1 calc R U .
H2C H 0.3512 0.2825 1.0058 0.124 Uiso 1 1 calc R U .
C7 C 0.1120(14) 0.1435(13) 0.9432(9) 0.068(6) Uani 1 1 d G . .
H7A H 0.1527 0.1593 1.0165 0.082 Uiso 1 1 calc R U .
C8 C -0.0274(13) 0.0703(13) 0.8943(14) 0.118(11) Uani 1 1 d G . .
H8A H -0.0801 0.0372 0.9350 0.141 Uiso 1 1 calc R U .
C9 C -0.0881(11) 0.0467(13) 0.7846(14) 0.090(8) Uani 1 1 d G . .
H9A H -0.1814 -0.0022 0.7519 0.108 Uiso 1 1 calc R U .
C10 C -0.0094(16) 0.0963(13) 0.7238(9) 0.096(9) Uani 1 1 d G . .
H10A H -0.0501 0.0805 0.6504 0.115 Uiso 1 1 calc R U .
N3 N 0.1300(15) 0.1694(12) 0.7726(9) 0.074(5) Uani 1 1 d G . .
C11 C 0.1908(11) 0.1930(11) 0.8823(10) 0.059(5) Uani 1 1 d G . .
C12 C 1.0583(10) 0.6249(12) 0.2134(9) 0.068(6) Uani 1 1 d G . .
C13 C 0.9504(14) 0.5386(13) 0.2290(11) 0.067(6) Uani 1 1 d G . .
H13A H 0.9635 0.5239 0.2928 0.080 Uiso 1 1 calc R U .
C14 C 0.8231(11) 0.4742(12) 0.1491(14) 0.085(7) Uani 1 1 d G . .
H14A H 0.7509 0.4165 0.1595 0.103 Uiso 1 1 calc R U .
C15 C 0.8036(11) 0.4962(12) 0.0537(11) 0.091(8) Uani 1 1 d G . .
H15A H 0.7184 0.4531 0.0002 0.109 Uiso 1 1 calc R U .
C16 C 0.9115(15) 0.5825(13) 0.0381(8) 0.064(5) Uani 1 1 d G . .
H16A H 0.8985 0.5972 -0.0258 0.077 Uiso 1 1 calc R U .
N4 N 1.0388(12) 0.6469(10) 0.1180(10) 0.062(4) Uani 1 1 d G . .
H4B H 1.1056 0.7003 0.1083 0.075 Uiso 1 1 calc R U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O13 W1 O10 102.2(8) . .
O13 W1 O14 101.2(7) . .
O10 W1 O14 156.5(7) . .
O13 W1 O8 100.4(7) . .
O10 W1 O8 87.9(6) . .
O14 W1 O8 88.2(5) . .
O13 W1 O5 100.3(6) . .
O10 W1 O5 87.0(6) . .
O14 W1 O5 88.6(5) . .
O8 W1 O5 159.3(7) . .
O13 W1 O3 156.1(6) . 2_866
O10 W1 O3 64.3(7) . 2_866
O14 W1 O3 93.7(7) . 2_866
O8 W1 O3 61.2(7) . 2_866
O5 W1 O3 98.6(7) . 2_866
O13 W1 O2 155.6(7) . 2_866
O10 W1 O2 93.7(8) . 2_866
O14 W1 O2 64.1(7) . 2_866
O8 W1 O2 98.6(7) . 2_866
O5 W1 O2 61.8(7) . 2_866
O3 W1 O2 48.3(7) 2_866 2_866
O22 W2 O14 101.5(6) . 2_866
O22 W2 O18 99.5(7) . .
O14 W2 O18 158.9(7) 2_866 .
O22 W2 O21 102.1(7) . .
O14 W2 O21 86.7(6) 2_866 .
O18 W2 O21 88.0(6) . .
O22 W2 O15 100.1(6) . .
O14 W2 O15 89.1(5) 2_866 .
O18 W2 O15 88.1(6) . .
O21 W2 O15 157.9(7) . .
O22 W2 O4 153.4(7) . .
O14 W2 O4 96.5(7) 2_866 .
O18 W2 O4 63.4(7) . .
O21 W2 O4 59.5(8) . .
O15 W2 O4 99.5(7) . .
O22 W2 O2 154.6(7) . .
O14 W2 O2 62.0(6) 2_866 .
O18 W2 O2 98.4(8) . .
O21 W2 O2 96.4(8) . .
O15 W2 O2 62.7(6) . .
O4 W2 O2 52.0(8) . .
O17 W3 O10 99.6(6) . .
O17 W3 O12 101.9(6) . .
O10 W3 O12 88.7(6) . .
O17 W3 O20 99.4(6) . .
O10 W3 O20 87.9(7) . .
O12 W3 O20 158.7(7) . .
O17 W3 O18 102.5(7) . .
O10 W3 O18 157.9(7) . .
O12 W3 O18 86.7(6) . .
O20 W3 O18 88.5(6) . .
O17 W3 O4 153.9(7) . .
O10 W3 O4 97.6(7) . .
O12 W3 O4 97.9(7) . .
O20 W3 O4 61.8(7) . .
O18 W3 O4 61.7(7) . .
O17 W3 O3 151.1(6) . 2_866
O10 W3 O3 59.6(6) . 2_866
O12 W3 O3 61.0(5) . 2_866
O20 W3 O3 99.5(7) . 2_866
O18 W3 O3 99.6(7) . 2_866
O4 W3 O3 54.8(7) . 2_866
O7 W4 O5 102.3(6) . 2_866
O7 W4 O9 98.9(7) . .
O5 W4 O9 88.5(6) 2_866 .
O7 W4 O15 101.4(7) . .
O5 W4 O15 89.6(5) 2_866 .
O9 W4 O15 159.5(6) . .
O7 W4 O19 99.2(6) . .
O5 W4 O19 158.5(7) 2_866 .
O9 W4 O19 87.8(5) . .
O15 W4 O19 86.5(5) . .
O7 W4 O1 155.6(8) . .
O5 W4 O1 96.3(6) 2_866 .
O9 W4 O1 65.7(7) . .
O15 W4 O1 94.3(7) . .
O19 W4 O1 63.0(6) . .
O7 W4 O2 158.7(8) . .
O5 W4 O2 62.6(6) 2_866 .
O9 W4 O2 95.7(7) . .
O15 W4 O2 65.5(7) . .
O19 W4 O2 96.8(7) . .
O1 W4 O2 45.7(7) . .
O6 W5 O16 101.6(7) . .
O6 W5 O12 101.5(7) . .
O16 W5 O12 156.9(6) . .
O6 W5 O19 100.5(6) . .
O16 W5 O19 89.3(6) . .
O12 W5 O19 87.1(6) . .
O6 W5 O8 99.5(7) . .
O16 W5 O8 86.7(6) . .
O12 W5 O8 88.9(6) . .
O19 W5 O8 160.0(7) . .
O6 W5 O3 155.2(7) . 2_866
O16 W5 O3 93.0(7) . 2_866
O12 W5 O3 65.2(6) . 2_866
O19 W5 O3 99.7(7) . 2_866
O8 W5 O3 61.0(7) . 2_866
O6 W5 O1 156.0(7) . .
O16 W5 O1 64.7(6) . .
O12 W5 O1 93.7(7) . .
O19 W5 O1 61.5(7) . .
O8 W5 O1 99.2(7) . .
O3 W5 O1 48.8(7) 2_866 .
O11 W6 O21 102.3(7) . .
O11 W6 O16 100.1(6) . 2_866
O21 W6 O16 87.4(6) . 2_866
O11 W6 O20 100.8(7) . .
O21 W6 O20 88.8(6) . .
O16 W6 O20 159.0(7) 2_866 .
O11 W6 O9 98.4(6) . 2_866
O21 W6 O9 159.2(7) . 2_866
O16 W6 O9 87.7(5) 2_866 2_866
O20 W6 O9 88.6(6) . 2_866
O11 W6 O4 154.9(7) . .
O21 W6 O4 60.2(8) . .
O16 W6 O4 97.0(7) 2_866 .
O20 W6 O4 63.4(7) . .
O9 W6 O4 100.4(7) 2_866 .
O11 W6 O1 152.3(6) . 2_866
O21 W6 O1 98.5(7) . 2_866
O16 W6 O1 62.6(6) 2_866 2_866
O20 W6 O1 97.7(7) . 2_866
O9 W6 O1 61.5(6) 2_866 2_866
O4 W6 O1 52.8(7) . 2_866
O2 Ge1 O2 180.0(17) 2_866 .
O2 Ge1 O1 65.1(10) 2_866 2_866
O2 Ge1 O1 114.9(10) . 2_866
O2 Ge1 O1 114.9(10) 2_866 .
O2 Ge1 O1 65.1(10) . .
O1 Ge1 O1 180.0(16) 2_866 .
O2 Ge1 O3 112.4(9) 2_866 .
O2 Ge1 O3 67.6(9) . .
O1 Ge1 O3 68.7(9) 2_866 .
O1 Ge1 O3 111.3(9) . .
O2 Ge1 O3 67.6(9) 2_866 2_866
O2 Ge1 O3 112.4(9) . 2_866
O1 Ge1 O3 111.3(9) 2_866 2_866
O1 Ge1 O3 68.7(9) . 2_866
O3 Ge1 O3 180.0 . 2_866
O2 Ge1 O4 107.5(10) 2_866 .
O2 Ge1 O4 72.5(10) . .
O1 Ge1 O4 73.6(9) 2_866 .
O1 Ge1 O4 106.4(9) . .
O3 Ge1 O4 103.4(9) . .
O3 Ge1 O4 76.6(9) 2_866 .
O2 Ge1 O4 72.5(10) 2_866 2_866
O2 Ge1 O4 107.5(10) . 2_866
O1 Ge1 O4 106.4(9) 2_866 2_866
O1 Ge1 O4 73.6(9) . 2_866
O3 Ge1 O4 76.6(9) . 2_866
O3 Ge1 O4 103.4(9) 2_866 2_866
O4 Ge1 O4 180.0(12) . 2_866
Ge1 O1 O2 57.3(9) . .
Ge1 O1 W4 125.6(11) . .
O2 O1 W4 68.4(10) . .
Ge1 O1 W5 120.4(10) . .
O2 O1 W5 136.6(12) . .
W4 O1 W5 98.5(7) . .
Ge1 O1 W6 115.3(8) . 2_866
O2 O1 W6 127.4(11) . 2_866
W4 O1 W6 96.3(8) . 2_866
W5 O1 W6 94.1(7) . 2_866
Ge1 O2 O1 57.6(10) . .
Ge1 O2 W4 123.6(11) . .
O1 O2 W4 65.9(9) . .
Ge1 O2 W1 121.6(10) . 2_866
O1 O2 W1 135.7(13) . 2_866
W4 O2 W1 97.8(8) . 2_866
Ge1 O2 W2 117.2(11) . .
O1 O2 W2 126.0(11) . .
W4 O2 W2 95.3(7) . .
W1 O2 W2 95.0(8) 2_866 .
Ge1 O3 W1 122.4(8) . 2_866
Ge1 O3 W5 122.0(10) . 2_866
W1 O3 W5 101.5(8) 2_866 2_866
Ge1 O3 W3 113.2(10) . 2_866
W1 O3 W3 96.1(7) 2_866 2_866
W5 O3 W3 95.8(6) 2_866 2_866
Ge1 O4 W6 118.3(9) . .
Ge1 O4 W2 118.3(11) . .
W6 O4 W2 101.9(9) . .
Ge1 O4 W3 115.5(11) . .
W6 O4 W3 99.9(8) . .
W2 O4 W3 99.8(7) . .
W4 O5 W1 137.4(8) 2_866 .
W5 O8 W1 136.0(10) . .
W4 O9 W6 136.5(7) . 2_866
W1 O10 W3 139.9(8) . .
W6 O11 Cu1 141.1(6) . .
W5 O12 W3 137.8(7) . .
W2 O14 W1 138.7(8) 2_866 .
W4 O15 W2 136.2(7) . .
W5 O16 W6 138.4(8) . 2_866
W2 O18 W3 135.1(9) . .
W5 O19 W4 136.6(8) . .
W3 O20 W6 134.9(8) . .
W6 O21 W2 138.4(10) . .
N1 Cu1 N1 180.0 2_877 .
N1 Cu1 O24 96.6(4) 2_877 .
N1 Cu1 O24 83.4(4) . .
N1 Cu1 O24 83.4(4) 2_877 2_877
N1 Cu1 O24 96.6(4) . 2_877
O24 Cu1 O24 180.0 . 2_877
N1 Cu1 O11 93.4(4) 2_877 2_877
N1 Cu1 O11 86.6(4) . 2_877
O24 Cu1 O11 95.1(4) . 2_877
O24 Cu1 O11 84.9(4) 2_877 2_877
N1 Cu1 O11 86.6(4) 2_877 .
N1 Cu1 O11 93.4(4) . .
O24 Cu1 O11 84.9(4) . .
O24 Cu1 O11 95.1(5) 2_877 .
O11 Cu1 O11 180.0 2_877 .
C6 O24 Cu1 114.1(10) . .
C1 N1 C5 120.0 . .
C1 N1 Cu1 128.3(5) . .
C5 N1 Cu1 111.7(5) . .
C2 C1 N1 120.0 . .
C2 C1 H1A 120.0 . .
N1 C1 H1A 120.0 . .
C1 C2 C3 120.0 . .
C1 C2 H2A 120.0 . .
C3 C2 H2A 120.0 . .
C4 C3 C2 120.0 . .
C4 C3 H3A 120.0 . .
C2 C3 H3A 120.0 . .
C5 C4 C3 120.0 . .
C5 C4 H4A 120.0 . .
C3 C4 H4A 120.0 . .
C4 C5 N1 120.0 . .
C4 C5 C6 126.5(9) . .
N1 C5 C6 113.5(9) . .
O23 C6 O24 124.1(16) . .
O23 C6 C5 118.6(14) . .
O24 C6 C5 117.3(14) . .
C12 N5 H5A 120.0 . .
C12 N5 H5B 120.0 . .
H5A N5 H5B 120.0 . .
C11 N2 H2B 120.0 . .
C11 N2 H2C 120.0 . .
H2B N2 H2C 120.0 . .
C8 C7 C11 120.0 . .
C8 C7 H7A 120.0 . .
C11 C7 H7A 120.0 . .
C7 C8 C9 120.0 . .
C7 C8 H8A 120.0 . .
C9 C8 H8A 120.0 . .
C8 C9 C10 120.0 . .
C8 C9 H9A 120.0 . .
C10 C9 H9A 120.0 . .
C9 C10 N3 120.0 . .
C9 C10 H10A 120.0 . .
N3 C10 H10A 120.0 . .
C11 N3 C10 120.0 . .
N2 C11 N3 123.4(13) . .
N2 C11 C7 116.2(13) . .
N3 C11 C7 120.0 . .
N5 C12 C13 124.3(12) . .
N5 C12 N4 115.6(12) . .
C13 C12 N4 120.0 . .
C14 C13 C12 120.0 . .
C14 C13 H13A 120.0 . .
C12 C13 H13A 120.0 . .
C13 C14 C15 120.0 . .
C13 C14 H14A 120.0 . .
C15 C14 H14A 120.0 . .
C16 C15 C14 120.0 . .
C16 C15 H15A 120.0 . .
C14 C15 H15A 120.0 . .
N4 C16 C15 120.0 . .
N4 C16 H16A 120.0 . .
C15 C16 H16A 120.0 . .
C16 N4 C12 120.0 . .
C16 N4 H4B 120.0 . .
C12 N4 H4B 120.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O13 1.677(11) .
W1 O10 1.867(14) .
W1 O14 1.897(12) .
W1 O8 1.911(13) .
W1 O5 1.914(12) .
W1 O3 2.28(2) 2_866
W1 O2 2.36(2) 2_866
W2 O22 1.662(12) .
W2 O14 1.892(12) 2_866
W2 O18 1.894(13) .
W2 O21 1.903(12) .
W2 O15 1.920(13) .
W2 O4 2.28(2) .
W2 O2 2.45(2) .
W3 O17 1.653(10) .
W3 O10 1.898(15) .
W3 O12 1.904(14) .
W3 O20 1.907(14) .
W3 O18 1.933(16) .
W3 O4 2.341(19) .
W3 O3 2.48(2) 2_866
W4 O7 1.666(11) .
W4 O5 1.882(13) 2_866
W4 O9 1.891(12) .
W4 O15 1.897(13) .
W4 O19 1.917(13) .
W4 O1 2.30(2) .
W4 O2 2.34(2) .
W5 O6 1.661(11) .
W5 O16 1.887(12) .
W5 O12 1.890(13) .
W5 O19 1.893(14) .
W5 O8 1.906(14) .
W5 O3 2.291(18) 2_866
W5 O1 2.378(18) .
W6 O11 1.650(12) .
W6 O21 1.870(15) .
W6 O16 1.905(13) 2_866
W6 O20 1.909(14) .
W6 O9 1.930(13) 2_866
W6 O4 2.26(2) .
W6 O1 2.47(2) 2_866
Ge1 O2 1.67(2) 2_866
Ge1 O2 1.67(2) .
Ge1 O1 1.68(2) 2_866
Ge1 O1 1.68(2) .
Ge1 O3 1.741(18) .
Ge1 O3 1.741(18) 2_866
Ge1 O4 1.84(2) .
Ge1 O4 1.84(2) 2_866
O1 O2 1.80(3) .
O1 W6 2.47(2) 2_866
O2 W1 2.355(19) 2_866
O3 W1 2.28(2) 2_866
O3 W5 2.291(18) 2_866
O3 W3 2.48(2) 2_866
O5 W4 1.882(12) 2_866
O9 W6 1.930(13) 2_866
O11 Cu1 2.605(12) .
O14 W2 1.892(12) 2_866
O16 W6 1.905(13) 2_866
Cu1 N1 1.934(6) 2_877
Cu1 N1 1.934(6) .
Cu1 O24 1.963(11) .
Cu1 O24 1.963(11) 2_877
Cu1 O11 2.605(12) 2_877
O23 C6 1.244(19) .
O24 C6 1.251(18) .
N1 C1 1.3900 .
N1 C5 1.3900 .
C1 C2 1.3900 .
C1 H1A 0.9300 .
C2 C3 1.3900 .
C2 H2A 0.9300 .
C3 C4 1.3900 .
C3 H3A 0.9300 .
C4 C5 1.3900 .
C4 H4A 0.9300 .
C5 C6 1.459(18) .
N5 C12 1.34(2) .
N5 H5A 0.8600 .
N5 H5B 0.8600 .
N2 C11 1.31(2) .
N2 H2B 0.8600 .
N2 H2C 0.8600 .
C7 C8 1.3900 .
C7 C11 1.3900 .
C7 H7A 0.9300 .
C8 C9 1.3900 .
C8 H8A 0.9300 .
C9 C10 1.3900 .
C9 H9A 0.9300 .
C10 N3 1.3900 .
C10 H10A 0.9300 .
N3 C11 1.3900 .
C12 C13 1.3900 .
C12 N4 1.3900 .
C13 C14 1.3900 .
C13 H13A 0.9300 .
C14 C15 1.3900 .
C14 H14A 0.9300 .
C15 C16 1.3900 .
C15 H15A 0.9300 .
C16 N4 1.3900 .
C16 H16A 0.9300 .
N4 H4B 0.8600 .
