#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/58/7035879.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035879
loop_
_publ_author_name
'Weiss, Daniel T.'
'Altmann, Philipp J.'
'Haslinger, Stefan'
'Jandl, Christian'
'Pöthig, Alexander'
'Cokoja, Mirza'
'Kühn, Fritz E'
_publ_section_title
;
 Structural diversity of late transition metal complexes with flexible
 tetra-NHC ligands.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18329
_journal_page_last               18339
_journal_paper_doi               10.1039/c5dt02386f
_journal_volume                  44
_journal_year                    2015
_chemical_compound_source        'see text'
_chemical_formula_moiety         'C19 H24 Cu2 N8, 2(F6 P)'
_chemical_formula_sum            'C19 H24 Cu2 F12 N8 P2'
_chemical_formula_weight         781.50
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_update_record
;
2015-06-22 deposited with the CCDC.
2015-07-20 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 91.55(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   20.099(9)
_cell_length_b                   10.385(4)
_cell_length_c                   13.286(5)
_cell_measurement_reflns_used    9979
_cell_measurement_temperature    123
_cell_measurement_theta_max      26.2802
_cell_measurement_theta_min      2.2035
_cell_volume                     2772.1(19)
_computing_cell_refinement       'SAINT (Bruker, 2012)'
_computing_data_collection       'APEX II Control Software (Bruker, 2013)'
_computing_data_reduction        'SAINT (Bruker, 2012)'
_computing_molecular_graphics    'PLATON (Spek, 2011)'
_computing_publication_material  'PLATON (Spek, 2011), enCIFer (Allen, 2004)'
_computing_structure_refinement
'SHELXL2013 (Sheldrick, 2013), SHELXLE (Huebschle, 2011)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      123
_diffrn_detector                 ' CCD plate '
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       ' κ-geometry diffractometer '
_diffrn_measurement_device_type  ' Bruker APEX-II CCD '
_diffrn_measurement_method       ' phi- and omega-rotation '
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0443
_diffrn_reflns_av_sigmaI/netI    0.0325
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            29604
_diffrn_reflns_reduction_process
;
;
_diffrn_reflns_theta_full        25.24
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         2.03
_exptl_absorpt_coefficient_mu    1.759
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.6259
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker, 2008b'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.872
_exptl_crystal_density_method    'Not Measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             1560
_exptl_crystal_size_max          0.388
_exptl_crystal_size_mid          0.330
_exptl_crystal_size_min          0.298
_refine_diff_density_max         0.769
_refine_diff_density_min         -0.407
_refine_diff_density_rms         0.067
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     390
_refine_ls_number_reflns         5083
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0370
_refine_ls_R_factor_gt           0.0281
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'W=1/[Σ²(FO²)+(0.0268P)²+2.6753P] WHERE P=(FO²+2FC²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0640
_refine_ls_wR_factor_ref         0.0677
_reflns_number_gt                4323
_reflns_number_total             5083
_reflns_threshold_expression     i>2σ(i)
_cod_data_source_file            c5dt02386f2.cif
_cod_data_source_block           compound_5
_cod_depositor_comments
'Adding full bibliography for 7035878--7035886.cif.'
_cod_original_cell_volume        2772.2(19)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7035879
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 x,y,z
2 -x,1/2+y,1/2-z
3 -x,-y,-z
4 x,1/2-y,1/2+z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_thermal_displace_type
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu Uani 0.26427(2) 0.07995(3) 0.43789(2) 1.000 0.0169(1) d .
Cu2 Cu Uani 0.24747(2) 0.29975(3) 0.53652(2) 1.000 0.0161(1) d .
P1 P Uani 0.39814(3) 0.69164(7) 0.46019(5) 1.000 0.0241(2) d .
P2 P Uani 0.08592(3) 0.85030(7) 0.28383(5) 1.000 0.0209(2) d .
N1 N Uani 0.36125(10) 0.0328(2) 0.28218(15) 1.000 0.0199(7) d .
F1 F Uani 0.36042(8) 0.55565(15) 0.45909(14) 1.000 0.0405(6) d .
N2 N Uani 0.40069(10) 0.1628(2) 0.39226(15) 1.000 0.0186(6) d .
F2 F Uani 0.43619(8) 0.82609(17) 0.46171(14) 1.000 0.0424(6) d .
N3 N Uani 0.38459(10) 0.2015(2) 0.56825(15) 1.000 0.0184(6) d .
F3 F Uani 0.45800(9) 0.6291(2) 0.40236(16) 1.000 0.0573(8) d .
N4 N Uani 0.32199(10) 0.1429(2) 0.68640(15) 1.000 0.0189(6) d .
F4 F Uani 0.43456(9) 0.6543(2) 0.56366(13) 1.000 0.0524(7) d .
N5 N Uani 0.17455(10) -0.0075(2) 0.59512(15) 1.000 0.0183(6) d .
F5 F Uani 0.33951(8) 0.75250(18) 0.52076(17) 1.000 0.0576(8) d .
F6 F Uani 0.36229(11) 0.7276(2) 0.35784(16) 1.000 0.0714(9) d .
N6 N Uani 0.12329(10) 0.1108(2) 0.48759(15) 1.000 0.0186(6) d .
N7 N Uani 0.11637(10) 0.3301(2) 0.43347(15) 1.000 0.0194(6) d .
N8 N Uani 0.15466(10) 0.5105(2) 0.48314(15) 1.000 0.0186(6) d .
C1 C Uani 0.31600(13) -0.0504(3) 0.2245(2) 1.000 0.0281(9) d .
C2 C Uani 0.34515(12) 0.0953(2) 0.36674(18) 1.000 0.0191(8) d .
C3 C Uani 0.42506(13) 0.0610(3) 0.25512(19) 1.000 0.0256(9) d .
C4 C Uani 0.45010(12) 0.1422(3) 0.32426(19) 1.000 0.0243(8) d .
C5 C Uani 0.40532(12) 0.2566(3) 0.47391(18) 1.000 0.0211(8) d .
C6 C Uani 0.32191(12) 0.2159(2) 0.60232(18) 1.000 0.0182(8) d .
C7 C Uani 0.42202(12) 0.1204(3) 0.62896(19) 1.000 0.0229(8) d .
C8 C Uani 0.38260(12) 0.0830(3) 0.70372(19) 1.000 0.0235(8) d .
C9 C Uani 0.26381(13) 0.1235(3) 0.74822(19) 1.000 0.0235(8) d .
C10 C Uani 0.24266(13) -0.0165(3) 0.75196(19) 1.000 0.0236(8) d .
C11 C Uani 0.22781(12) -0.0764(2) 0.64935(19) 1.000 0.0201(8) d .
C12 C Uani 0.18371(12) 0.0578(2) 0.50893(18) 1.000 0.0187(8) d .
C13 C Uani 0.10986(12) 0.0046(3) 0.6268(2) 1.000 0.0224(8) d .
C14 C Uani 0.07806(12) 0.0788(3) 0.5598(2) 1.000 0.0232(8) d .
C15 C Uani 0.11115(12) 0.1953(2) 0.40383(19) 1.000 0.0221(8) d .
C16 C Uani 0.17085(12) 0.3851(2) 0.47821(18) 1.000 0.0184(8) d .
C17 C Uani 0.06768(12) 0.4201(3) 0.4124(2) 1.000 0.0251(8) d .
C18 C Uani 0.09149(12) 0.5333(3) 0.4443(2) 1.000 0.0245(8) d .
C19 C Uani 0.19853(13) 0.6116(3) 0.5221(2) 1.000 0.0246(8) d .
F7 F Uani 0.13658(8) 0.73218(16) 0.28478(12) 1.000 0.0365(6) d .
F8 F Uani 0.03577(7) 0.96913(15) 0.28381(12) 1.000 0.0312(5) d .
F9 F Uani 0.14709(7) 0.94795(16) 0.28088(12) 1.000 0.0343(6) d .
F10 F Uani 0.08855(8) 0.85160(15) 0.40417(11) 1.000 0.0292(5) d .
F11 F Uani 0.02467(7) 0.75279(15) 0.28599(12) 1.000 0.0322(5) d .
F12 F Uani 0.08268(8) 0.84634(17) 0.16361(11) 1.000 0.0351(6) d .
H1A H Uiso 0.30340 -0.00840 0.16070 1.000 0.0420 c RU
H1B H Uiso 0.27600 -0.06630 0.26320 1.000 0.0420 c RU
H1C H Uiso 0.33810 -0.13240 0.21080 1.000 0.0420 c RU
H3 H Uiso 0.44720 0.02880 0.19810 1.000 0.0310 c RU
H4 H Uiso 0.49350 0.17860 0.32620 1.000 0.0290 c RU
H5A H Uiso 0.45180 0.28720 0.48150 1.000 0.0250 c RU
H5B H Uiso 0.37690 0.33170 0.45690 1.000 0.0250 c RU
H7 H Uiso 0.46700 0.09570 0.61990 1.000 0.0270 c RU
H8 H Uiso 0.39410 0.02660 0.75770 1.000 0.0280 c RU
H9A H Uiso 0.22640 0.17580 0.72070 1.000 0.0280 c RU
H9B H Uiso 0.27410 0.15390 0.81750 1.000 0.0280 c RU
H10A H Uiso 0.20240 -0.02330 0.79290 1.000 0.0280 c RU
H10B H Uiso 0.27840 -0.06680 0.78640 1.000 0.0280 c RU
H11A H Uiso 0.26860 -0.07460 0.60920 1.000 0.0240 c RU
H11B H Uiso 0.21460 -0.16740 0.65810 1.000 0.0240 c RU
H13 H Uiso 0.09170 -0.03300 0.68520 1.000 0.0270 c RU
H14 H Uiso 0.03280 0.10500 0.56130 1.000 0.0280 c RU
H15A H Uiso 0.06610 0.17870 0.37490 1.000 0.0270 c RU
H15B H Uiso 0.14370 0.17710 0.35110 1.000 0.0270 c RU
H17 H Uiso 0.02530 0.40460 0.38120 1.000 0.0300 c RU
H18 H Uiso 0.06920 0.61400 0.44080 1.000 0.0290 c RU
H19A H Uiso 0.24470 0.59060 0.50680 1.000 0.0370 c RU
H19B H Uiso 0.19410 0.61840 0.59520 1.000 0.0370 c RU
H19C H Uiso 0.18630 0.69380 0.49050 1.000 0.0370 c RU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C2 Cu1 C12 177.87(10) yes
C6 Cu2 C16 176.69(11) yes
F2 P1 F5 90.42(11) yes
F2 P1 F6 90.66(11) yes
F3 P1 F4 88.93(11) yes
F3 P1 F5 178.32(12) yes
F3 P1 F6 90.82(12) yes
F4 P1 F5 89.39(11) yes
F4 P1 F6 179.64(12) yes
F5 P1 F6 90.85(12) yes
F1 P1 F2 179.48(11) yes
F1 P1 F3 89.98(11) yes
F1 P1 F4 89.98(11) yes
F1 P1 F5 89.89(10) yes
F1 P1 F6 89.76(11) yes
F2 P1 F3 89.71(11) yes
F2 P1 F4 89.61(11) yes
F9 P2 F11 179.62(10) yes
F9 P2 F12 90.14(10) yes
F10 P2 F11 89.54(10) yes
F10 P2 F12 178.92(11) yes
F11 P2 F12 89.49(10) yes
F7 P2 F12 89.82(10) yes
F8 P2 F9 89.75(9) yes
F8 P2 F10 89.85(10) yes
F7 P2 F8 179.37(10) yes
F7 P2 F9 89.82(10) yes
F7 P2 F10 89.70(10) yes
F7 P2 F11 90.26(10) yes
F8 P2 F11 90.18(9) yes
F8 P2 F12 90.64(10) yes
F9 P2 F10 90.83(10) yes
C2 N1 C3 111.3(2) yes
C1 N1 C3 124.3(2) yes
C1 N1 C2 124.4(2) yes
C2 N2 C4 111.1(2) yes
C2 N2 C5 124.6(2) yes
C4 N2 C5 124.0(2) yes
C5 N3 C7 125.7(2) yes
C5 N3 C6 122.4(2) yes
C6 N3 C7 111.7(2) yes
C6 N4 C9 124.0(2) yes
C6 N4 C8 111.8(2) yes
C8 N4 C9 124.0(2) yes
C12 N5 C13 111.3(2) yes
C11 N5 C12 123.4(2) yes
C11 N5 C13 125.2(2) yes
C14 N6 C15 125.9(2) yes
C12 N6 C14 111.1(2) yes
C12 N6 C15 122.9(2) yes
C16 N7 C17 111.3(2) yes
C15 N7 C16 125.0(2) yes
C15 N7 C17 123.5(2) yes
C16 N8 C19 124.8(2) yes
C16 N8 C18 111.7(2) yes
C18 N8 C19 123.5(2) yes
Cu1 C2 N2 128.81(18) yes
Cu1 C2 N1 126.93(18) yes
N1 C2 N2 104.1(2) yes
N1 C3 C4 107.0(2) yes
N2 C4 C3 106.5(2) yes
N2 C5 N3 111.4(2) yes
N3 C6 N4 103.5(2) yes
Cu2 C6 N3 128.04(18) yes
Cu2 C6 N4 127.92(18) yes
N3 C7 C8 106.6(2) yes
N4 C8 C7 106.4(2) yes
N4 C9 C10 112.3(2) yes
C9 C10 C11 114.3(2) no
N5 C11 C10 111.4(2) yes
Cu1 C12 N5 128.14(18) yes
N5 C12 N6 103.9(2) yes
Cu1 C12 N6 127.88(18) yes
N5 C13 C14 106.7(2) yes
N6 C14 C13 107.0(2) yes
N6 C15 N7 111.7(2) yes
Cu2 C16 N8 128.28(18) yes
Cu2 C16 N7 127.63(17) yes
N7 C16 N8 103.6(2) yes
N7 C17 C18 106.7(2) yes
N8 C18 C17 106.7(2) yes
H1A C1 H1B 109.00 no
H1A C1 H1C 110.00 no
N1 C1 H1A 110.00 no
N1 C1 H1B 109.00 no
N1 C1 H1C 109.00 no
H1B C1 H1C 109.00 no
N1 C3 H3 127.00 no
C4 C3 H3 127.00 no
C3 C4 H4 127.00 no
N2 C4 H4 127.00 no
N2 C5 H5B 109.00 no
N2 C5 H5A 109.00 no
N3 C5 H5B 109.00 no
H5A C5 H5B 108.00 no
N3 C5 H5A 109.00 no
C8 C7 H7 127.00 no
N3 C7 H7 127.00 no
N4 C8 H8 127.00 no
C7 C8 H8 127.00 no
C10 C9 H9A 109.00 no
N4 C9 H9B 109.00 no
N4 C9 H9A 109.00 no
C10 C9 H9B 109.00 no
H9A C9 H9B 108.00 no
H10A C10 H10B 108.00 no
C9 C10 H10A 109.00 no
C9 C10 H10B 109.00 no
C11 C10 H10A 109.00 no
C11 C10 H10B 109.00 no
C10 C11 H11A 109.00 no
N5 C11 H11A 109.00 no
N5 C11 H11B 109.00 no
C10 C11 H11B 109.00 no
H11A C11 H11B 108.00 no
C14 C13 H13 127.00 no
N5 C13 H13 127.00 no
N6 C14 H14 126.00 no
C13 C14 H14 127.00 no
N6 C15 H15B 109.00 no
N6 C15 H15A 109.00 no
H15A C15 H15B 108.00 no
N7 C15 H15A 109.00 no
N7 C15 H15B 109.00 no
N7 C17 H17 127.00 no
C18 C17 H17 127.00 no
C17 C18 H18 127.00 no
N8 C18 H18 127.00 no
H19B C19 H19C 109.00 no
N8 C19 H19A 109.00 no
N8 C19 H19B 109.00 no
N8 C19 H19C 109.00 no
H19A C19 H19B 109.00 no
H19A C19 H19C 109.00 no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 C2 1.909(3) yes
Cu1 C12 1.910(3) yes
Cu2 C6 1.921(3) yes
Cu2 C16 1.922(3) yes
P1 F3 1.584(2) yes
P1 F1 1.6028(19) yes
P1 F2 1.592(2) yes
P1 F6 1.567(2) yes
P1 F4 1.588(2) yes
P1 F5 1.577(2) yes
P2 F10 1.5983(18) yes
P2 F7 1.5940(19) yes
P2 F11 1.5949(18) yes
P2 F12 1.5973(18) yes
P2 F9 1.5950(18) yes
P2 F8 1.5934(18) yes
N1 C2 1.345(3) yes
N1 C3 1.373(3) yes
N1 C1 1.457(4) yes
N2 C5 1.459(3) yes
N2 C2 1.354(3) yes
N2 C4 1.377(3) yes
N3 C6 1.358(3) yes
N3 C5 1.449(3) yes
N3 C7 1.376(3) yes
N4 C6 1.350(3) yes
N4 C8 1.382(3) yes
N4 C9 1.461(3) yes
N5 C12 1.348(3) yes
N5 C13 1.383(3) yes
N5 C11 1.461(3) yes
N6 C12 1.356(3) yes
N6 C14 1.380(3) yes
N6 C15 1.433(3) yes
N7 C17 1.377(3) yes
N7 C16 1.358(3) yes
N7 C15 1.457(3) yes
N8 C18 1.378(3) yes
N8 C16 1.344(3) yes
N8 C19 1.457(4) yes
C3 C4 1.335(4) no
C7 C8 1.345(4) no
C9 C10 1.516(4) no
C10 C11 1.521(4) no
C13 C14 1.328(4) no
C17 C18 1.334(4) no
C1 H1C 0.9800 no
C1 H1A 0.9800 no
C1 H1B 0.9800 no
C3 H3 0.9500 no
C4 H4 0.9500 no
C5 H5A 0.9900 no
C5 H5B 0.9900 no
C7 H7 0.9500 no
C8 H8 0.9500 no
C9 H9A 0.9900 no
C9 H9B 0.9900 no
C10 H10A 0.9900 no
C10 H10B 0.9900 no
C11 H11B 0.9900 no
C11 H11A 0.9900 no
C13 H13 0.9500 no
C14 H14 0.9500 no
C15 H15A 0.9900 no
C15 H15B 0.9900 no
C17 H17 0.9500 no
C18 H18 0.9500 no
C19 H19B 0.9800 no
C19 H19C 0.9800 no
C19 H19A 0.9800 no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
C1 N1 C2 Cu1 5.9(3) no
C1 N1 C2 N2 -178.2(2) no
C3 N1 C2 Cu1 -176.21(19) no
C3 N1 C2 N2 -0.4(3) no
C1 N1 C3 C4 178.3(2) no
C2 N1 C3 C4 0.5(3) no
C4 N2 C2 Cu1 175.87(19) no
C4 N2 C2 N1 0.1(3) no
C5 N2 C2 Cu1 -10.8(3) no
C5 N2 C2 N1 173.4(2) no
C2 N2 C4 C3 0.2(3) no
C5 N2 C4 C3 -173.2(2) no
C2 N2 C5 N3 54.1(3) no
C4 N2 C5 N3 -133.5(2) no
C6 N3 C5 N2 -96.2(3) no
C7 N3 C5 N2 77.6(3) no
C5 N3 C6 Cu2 3.2(3) no
C5 N3 C6 N4 175.3(2) no
C7 N3 C6 Cu2 -171.28(19) no
C7 N3 C6 N4 0.8(3) no
C5 N3 C7 C8 -174.7(2) no
C6 N3 C7 C8 -0.5(3) no
C8 N4 C6 Cu2 171.22(19) no
C8 N4 C6 N3 -0.9(3) no
C9 N4 C6 Cu2 -5.4(3) no
C9 N4 C6 N3 -177.5(2) no
C6 N4 C8 C7 0.6(3) no
C9 N4 C8 C7 177.2(2) no
C6 N4 C9 C10 117.9(3) no
C8 N4 C9 C10 -58.3(3) no
C12 N5 C11 C10 114.9(3) no
C13 N5 C11 C10 -62.0(3) no
C11 N5 C12 Cu1 -0.9(3) no
C11 N5 C12 N6 -177.3(2) no
C13 N5 C12 Cu1 176.36(19) no
C13 N5 C12 N6 0.0(3) no
C11 N5 C13 C14 177.0(2) no
C12 N5 C13 C14 -0.2(3) no
C14 N6 C12 Cu1 -176.16(19) no
C14 N6 C12 N5 0.2(3) no
C15 N6 C12 Cu1 0.1(3) no
C15 N6 C12 N5 176.5(2) no
C12 N6 C14 C13 -0.4(3) no
C15 N6 C14 C13 -176.5(2) no
C12 N6 C15 N7 -95.5(3) no
C14 N6 C15 N7 80.2(3) no
C16 N7 C15 N6 57.2(3) no
C17 N7 C15 N6 -127.8(2) no
C15 N7 C16 Cu2 -12.5(3) no
C15 N7 C16 N8 175.0(2) no
C17 N7 C16 Cu2 172.02(19) no
C17 N7 C16 N8 -0.6(3) no
C15 N7 C17 C18 -175.7(2) no
C16 N7 C17 C18 -0.1(3) no
C18 N8 C16 Cu2 -171.47(19) no
C18 N8 C16 N7 1.0(3) no
C19 N8 C16 Cu2 10.0(4) no
C19 N8 C16 N7 -177.5(2) no
C16 N8 C18 C17 -1.1(3) no
C19 N8 C18 C17 177.4(2) no
N1 C3 C4 N2 -0.4(3) no
N3 C7 C8 N4 -0.1(3) no
N4 C9 C10 C11 -56.7(3) no
C9 C10 C11 N5 -59.3(3) no
N5 C13 C14 N6 0.3(3) no
N7 C17 C18 N8 0.7(3) no
