#------------------------------------------------------------------------------
#$Date: 2015-10-09 12:02:05 +0300 (Fri, 09 Oct 2015) $
#$Revision: 161403 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/60/7036073.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7036073
loop_
_publ_author_name
'Carter, Korey P.'
'Zulato, Cecília H F'
'Rodrigues, Emille M.'
'Pope, Simon J. A.'
'Sigoli, Fernando A.'
'Cahill, Christopher L.'
_publ_section_title
;
 Controlling dimensionality via a dual ligand strategy in
 Ln-thiophene-2,5-dicarboxylic acid-terpyridine coordination polymers.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15843
_journal_page_last               15854
_journal_paper_doi               10.1039/c5dt02596f
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C48 H32 Eu2 N6 O14 S3'
_chemical_formula_weight         1316.89
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2015-07-02 deposited with the CCDC.
2015-08-05 downloaded from the CCDC.
;
_cell_angle_alpha                110.283(6)
_cell_angle_beta                 99.536(5)
_cell_angle_gamma                99.030(5)
_cell_formula_units_Z            2
_cell_length_a                   9.990(6)
_cell_length_b                   14.334(7)
_cell_length_c                   18.575(7)
_cell_measurement_reflns_used    31626
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      51.351
_cell_measurement_theta_min      4.358
_cell_volume                     2393(2)
_computing_cell_refinement       'SAINT, Bruker-AXS'
_computing_data_collection       'APEX, Bruker-AXS'
_computing_data_reduction        'SAINT, Bruker-AXS'
_computing_molecular_graphics    'WINGX (Farrugia, 2012)'
_computing_publication_material  'Crystal Maker (Palmer, 2009)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SIR92 (Gualardi, 1994)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX II CCD'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0447
_diffrn_reflns_av_unetI/netI     0.0532
_diffrn_reflns_laue_measured_fraction_full 1.000
_diffrn_reflns_laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            31610
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.500
_diffrn_reflns_theta_max         27.385
_diffrn_reflns_theta_min         1.203
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    2.803
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_correction_T_min  0.6607
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS, Bruker-AXS (2008)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.827
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1296
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.987
_refine_diff_density_min         -1.039
_refine_diff_density_rms         0.138
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     658
_refine_ls_number_reflns         10843
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.061
_refine_ls_R_factor_all          0.0538
_refine_ls_R_factor_gt           0.0395
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0383P)²+2.2470P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0887
_refine_ls_wR_factor_ref         0.0976
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8423
_reflns_number_total             10843
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt02596f2.cif
_cod_data_source_block           Compound_3
_cod_depositor_comments
'Adding full bibliography for 7036071--7036081.cif.'
_cod_database_code               7036073
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Eu2 Eu 0.53750(2) 0.70831(2) 0.05787(2) 0.01981(7) Uani 1 1 d . .
Eu1 Eu 0.04913(2) 0.69557(2) -0.44115(2) 0.01724(7) Uani 1 1 d . .
S2 S 0.35194(13) 0.79510(10) 0.32543(7) 0.0287(3) Uani 1 1 d . .
S1 S 0.84884(15) 0.77951(11) -0.17832(7) 0.0338(3) Uani 1 1 d . .
S3 S 0.25770(15) 0.56416(9) -0.22011(7) 0.0316(3) Uani 1 1 d . .
O11 O 0.0966(4) 0.4437(3) -0.44899(18) 0.0290(8) Uani 1 1 d . .
O3 O -0.0123(4) 0.7645(2) -0.31064(19) 0.0286(8) Uani 1 1 d . .
O5 O 0.4988(4) 0.7713(3) 0.19395(19) 0.0312(8) Uani 1 1 d . .
O4 O -0.1381(4) 0.6128(3) -0.39354(19) 0.0308(8) Uani 1 1 d . .
O7 O 0.0992(4) 0.7393(3) -0.5466(2) 0.0365(9) Uani 1 1 d . .
O9 O 0.3884(4) 0.5807(3) -0.0573(2) 0.0368(9) Uani 1 1 d . .
O12 O 0.1448(4) 0.6044(3) -0.3639(2) 0.0354(9) Uani 1 1 d . .
N2 N 0.0872(4) 0.8920(3) -0.3945(2) 0.0207(8) Uani 1 1 d . .
O10 O 0.6232(4) 0.5841(3) 0.0886(2) 0.0386(9) Uani 1 1 d . .
O6 O 0.3529(4) 0.6296(3) 0.1080(2) 0.0395(9) Uani 1 1 d . .
N3 N -0.1690(4) 0.7644(3) -0.4675(2) 0.0284(9) Uani 1 1 d . .
N5 N 0.5883(4) 0.9064(3) 0.1055(2) 0.0254(9) Uani 1 1 d . .
OW1 O 0.2163(4) 0.5950(3) -0.5133(2) 0.0431(10) Uani 1 1 d . .
O8 O 0.2687(4) 0.8760(3) -0.5244(2) 0.0349(9) Uani 1 1 d . .
N6 N 0.3288(4) 0.7851(3) 0.0305(3) 0.0363(11) Uani 1 1 d . .
N1 N 0.2969(4) 0.8017(3) -0.3662(2) 0.0281(9) Uani 1 1 d . .
C47 C 0.2014(5) 0.4808(4) -0.3156(3) 0.0256(11) Uani 1 1 d . .
N4 N 0.7889(4) 0.8081(3) 0.1330(2) 0.0299(10) Uani 1 1 d . .
C32 C 0.3442(6) 0.8882(4) 0.0538(3) 0.0347(13) Uani 1 1 d . .
C43 C 0.3606(5) 0.4909(4) -0.1064(3) 0.0243(10) Uani 1 1 d . .
C5 C 0.3290(5) 0.9050(4) -0.3392(3) 0.0253(10) Uani 1 1 d . .
C11 C -0.1598(5) 0.8657(4) -0.4477(3) 0.0282(11) Uani 1 1 d . .
C6 C 0.2163(5) 0.9530(3) -0.3608(3) 0.0248(10) Uani 1 1 d . .
C41 C 0.2202(5) 0.7365(4) 0.3546(3) 0.0290(11) Uani 1 1 d . .
C48 C 0.1425(5) 0.5116(3) -0.3814(3) 0.0208(10) Uani 1 1 d . .
C44 C 0.3026(5) 0.4710(4) -0.1890(3) 0.0278(11) Uani 1 1 d . .
O2 O 0.7692(5) 0.8609(4) -0.0285(3) 0.0652(13) Uani 1 1 d . .
C26 C 0.8267(5) 0.9115(4) 0.1606(3) 0.0302(11) Uani 1 1 d . .
C1 C 0.3982(5) 0.7557(4) -0.3486(3) 0.0378(13) Uani 1 1 d . .
H1 H 0.3776 0.6847 -0.3673 0.045 Uiso 1 1 calc R U
C10 C -0.0179(5) 0.9325(4) -0.4147(3) 0.0275(11) Uani 1 1 d . .
C42 C 0.1970(5) 0.7901(4) -0.5651(3) 0.0257(11) Uani 1 1 d . .
C21 C -0.1062(5) 0.6855(4) -0.3269(3) 0.0246(10) Uani 1 1 d . .
C24 C 1.0569(6) 0.9129(6) 0.2210(4) 0.0568(18) Uani 1 1 d . .
H24 H 1.1460 0.9482 0.2517 0.068 Uiso 1 1 calc R U
C27 C 0.7189(5) 0.9642(4) 0.1406(3) 0.0281(11) Uani 1 1 d . .
C3 C 0.5604(6) 0.9130(5) -0.2756(4) 0.0516(17) Uani 1 1 d . .
H3 H 0.6479 0.9505 -0.2437 0.062 Uiso 1 1 calc R U
O1 O 0.6331(6) 0.7161(5) -0.0429(3) 0.118(3) Uani 1 1 d . U
C19 C 0.7202(6) 0.5971(5) -0.2712(3) 0.0464(15) Uani 1 1 d . .
H19 H 0.6897 0.5354 -0.3146 0.056 Uiso 1 1 calc R U
C40 C 0.1533(6) 0.6428(4) 0.2984(3) 0.0408(14) Uani 1 1 d . .
H40 H 0.0805 0.5994 0.3046 0.049 Uiso 1 1 calc R U
OW2 O 0.8676(9) 0.5409(6) -0.0211(5) 0.185(4) Uani 1 1 d . .
C20 C 0.8171(5) 0.6774(4) -0.2670(3) 0.0276(11) Uani 1 1 d . .
C15 C -0.2977(6) 0.7023(5) -0.4958(3) 0.0401(14) Uani 1 1 d . .
H15 H -0.3058 0.6323 -0.5102 0.048 Uiso 1 1 calc R U
C25 C 0.9598(6) 0.9653(5) 0.2054(3) 0.0454(15) Uani 1 1 d . .
H25 H 0.9830 1.0364 0.2245 0.055 Uiso 1 1 calc R U
C36 C 0.2007(6) 0.7245(5) -0.0001(4) 0.0494(16) Uani 1 1 d . .
H36 H 0.1916 0.6542 -0.0166 0.059 Uiso 1 1 calc R U
C31 C 0.4873(6) 0.9520(4) 0.0871(3) 0.0302(11) Uani 1 1 d . .
C38 C 0.3148(5) 0.6943(4) 0.2354(3) 0.0288(11) Uani 1 1 d . .
C29 C 0.6473(7) 1.1135(4) 0.1366(4) 0.0491(16) Uani 1 1 d . .
H29 H 0.6672 1.1829 0.1463 0.059 Uiso 1 1 calc R U
C23 C 1.0226(6) 0.8093(6) 0.1916(4) 0.0553(18) Uani 1 1 d . .
H23 H 1.0881 0.7727 0.2005 0.066 Uiso 1 1 calc R U
C45 C 0.2721(6) 0.3797(4) -0.2523(3) 0.0391(14) Uani 1 1 d . .
H45 H 0.2868 0.3190 -0.2483 0.047 Uiso 1 1 calc R U
C37 C 0.3939(5) 0.6988(4) 0.1759(3) 0.0272(11) Uani 1 1 d . .
C39 C 0.2056(6) 0.6183(4) 0.2297(3) 0.0407(14) Uani 1 1 d . .
H39 H 0.1703 0.5578 0.1855 0.049 Uiso 1 1 calc R U
C17 C 0.7318(6) 0.7145(5) -0.1461(3) 0.0441(15) Uani 1 1 d . .
C22 C 0.8867(6) 0.7588(5) 0.1475(3) 0.0410(14) Uani 1 1 d . .
H22 H 0.8632 0.6877 0.1273 0.049 Uiso 1 1 calc R U
C8 C 0.1367(7) 1.0965(4) -0.3710(3) 0.0460(16) Uani 1 1 d . .
H8 H 0.1528 1.1652 -0.3637 0.055 Uiso 1 1 calc R U
C9 C 0.0057(7) 1.0354(4) -0.4050(3) 0.0429(15) Uani 1 1 d . .
H9 H -0.0672 1.0620 -0.4216 0.052 Uiso 1 1 calc R U
C18 C 0.6705(7) 0.6188(5) -0.2008(4) 0.0560(18) Uani 1 1 d . .
H18 H 0.6036 0.5726 -0.1931 0.067 Uiso 1 1 calc R U
C33 C 0.2276(7) 0.9276(5) 0.0455(4) 0.0519(17) Uani 1 1 d . .
H33 H 0.2374 0.9978 0.0611 0.062 Uiso 1 1 calc R U
C46 C 0.2179(6) 0.3873(4) -0.3218(3) 0.0400(14) Uani 1 1 d . .
H46 H 0.1941 0.3319 -0.3699 0.048 Uiso 1 1 calc R U
C12 C -0.2782(6) 0.9042(5) -0.4566(4) 0.0452(15) Uani 1 1 d . .
H12 H -0.2694 0.9740 -0.4434 0.054 Uiso 1 1 calc R U
C4 C 0.4603(6) 0.9629(4) -0.2938(3) 0.0390(13) Uani 1 1 d . .
H4 H 0.4804 1.0339 -0.2760 0.047 Uiso 1 1 calc R U
C7 C 0.2442(7) 1.0571(4) -0.3477(3) 0.0402(14) Uani 1 1 d . .
H7 H 0.3336 1.0984 -0.3238 0.048 Uiso 1 1 calc R U
C30 C 0.5144(7) 1.0554(4) 0.1006(3) 0.0464(15) Uani 1 1 d . .
H30 H 0.4436 1.0847 0.0856 0.056 Uiso 1 1 calc R U
C13 C -0.4086(6) 0.8388(6) -0.4852(4) 0.0532(17) Uani 1 1 d . .
H13 H -0.4886 0.8637 -0.4911 0.064 Uiso 1 1 calc R U
C16 C 0.7042(7) 0.7677(6) -0.0648(4) 0.0554(18) Uani 1 1 d . .
C2 C 0.5306(6) 0.8085(5) -0.3045(4) 0.0468(15) Uani 1 1 d . .
H2 H 0.5984 0.7740 -0.2946 0.056 Uiso 1 1 calc R U
C35 C 0.0816(7) 0.7603(6) -0.0085(4) 0.0571(18) Uani 1 1 d . .
H35 H -0.0061 0.7158 -0.0289 0.069 Uiso 1 1 calc R U
C28 C 0.7512(7) 1.0694(4) 0.1583(4) 0.0472(15) Uani 1 1 d . .
H28 H 0.8410 1.1087 0.1843 0.057 Uiso 1 1 calc R U
C14 C -0.4177(6) 0.7370(5) -0.5046(4) 0.0521(17) Uani 1 1 d . .
H14 H -0.5044 0.6913 -0.5236 0.063 Uiso 1 1 calc R U
C34 C 0.0963(7) 0.8628(6) 0.0142(4) 0.062(2) Uani 1 1 d . .
H34 H 0.0180 0.8896 0.0086 0.075 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu2 O10 103.4(2) . .
O1 Eu2 O9 74.19(17) . .
O10 Eu2 O9 89.18(13) . .
O1 Eu2 O6 150.76(16) . .
O10 Eu2 O6 75.37(14) . .
O9 Eu2 O6 76.59(13) . .
O1 Eu2 O5 156.11(17) . .
O10 Eu2 O5 86.64(13) . .
O9 Eu2 O5 128.29(13) . .
O6 Eu2 O5 52.53(11) . .
O1 Eu2 N6 98.7(2) . .
O10 Eu2 N6 148.86(14) . .
O9 Eu2 N6 75.90(13) . .
O6 Eu2 N6 74.65(15) . .
O5 Eu2 N6 81.81(13) . .
O1 Eu2 N4 78.91(17) . .
O10 Eu2 N4 79.74(14) . .
O9 Eu2 N4 147.61(13) . .
O6 Eu2 N4 128.26(13) . .
O5 Eu2 N4 81.69(12) . .
N6 Eu2 N4 126.46(14) . .
O1 Eu2 N5 84.8(2) . .
O10 Eu2 N5 139.72(13) . .
O9 Eu2 N5 130.54(12) . .
O6 Eu2 N5 115.49(12) . .
O5 Eu2 N5 74.00(12) . .
N6 Eu2 N5 63.54(14) . .
N4 Eu2 N5 62.98(13) . .
O1 Eu2 C37 174.7(2) . .
O10 Eu2 C37 80.37(14) . .
O9 Eu2 C37 102.34(14) . .
O6 Eu2 C37 26.19(12) . .
O5 Eu2 C37 26.34(12) . .
N6 Eu2 C37 76.48(15) . .
N4 Eu2 C37 105.59(14) . .
N5 Eu2 C37 94.78(13) . .
O11 Eu1 O7 78.56(12) 2_564 .
O11 Eu1 O12 99.77(12) 2_564 .
O7 Eu1 O12 136.38(13) . .
O11 Eu1 O3 123.37(12) 2_564 .
O7 Eu1 O3 143.01(12) . .
O12 Eu1 O3 73.82(12) . .
O11 Eu1 O4 72.40(11) 2_564 .
O7 Eu1 O4 144.63(12) . .
O12 Eu1 O4 69.62(12) . .
O3 Eu1 O4 52.28(11) . .
O11 Eu1 N1 148.35(13) 2_564 .
O7 Eu1 N1 85.05(13) . .
O12 Eu1 N1 74.02(13) . .
O3 Eu1 N1 85.40(13) . .
O4 Eu1 N1 129.91(12) . .
O11 Eu1 N3 78.12(13) 2_564 .
O7 Eu1 N3 83.07(13) . .
O12 Eu1 N3 139.87(13) . .
O3 Eu1 N3 74.45(12) . .
O4 Eu1 N3 71.69(13) . .
N1 Eu1 N3 126.75(13) . .
O11 Eu1 N2 134.27(12) 2_564 .
O7 Eu1 N2 73.07(12) . .
O12 Eu1 N2 125.49(12) . .
O3 Eu1 N2 70.72(11) . .
O4 Eu1 N2 114.47(11) . .
N1 Eu1 N2 63.23(12) . .
N3 Eu1 N2 63.63(13) . .
O11 Eu1 OW1 74.24(12) 2_564 .
O7 Eu1 OW1 66.33(12) . .
O12 Eu1 OW1 71.27(12) . .
O3 Eu1 OW1 143.26(12) . .
O4 Eu1 OW1 122.17(12) . .
N1 Eu1 OW1 74.41(13) . .
N3 Eu1 OW1 141.98(13) . .
N2 Eu1 OW1 122.73(12) . .
O11 Eu1 C21 98.10(14) 2_564 .
O7 Eu1 C21 154.85(13) . .
O12 Eu1 C21 68.74(13) . .
O3 Eu1 C21 26.16(12) . .
O4 Eu1 C21 26.14(12) . .
N1 Eu1 C21 107.81(14) . .
N3 Eu1 C21 71.90(13) . .
N2 Eu1 C21 93.13(13) . .
OW1 Eu1 C21 137.24(13) . .
C41 S2 C38 91.9(2) . .
C17 S1 C20 91.6(3) . .
C47 S3 C44 92.2(2) . .
C48 O11 Eu1 161.9(3) . 2_564
C21 O3 Eu1 92.9(3) . .
C37 O5 Eu2 92.5(3) . .
C21 O4 Eu1 92.8(3) . .
C42 O7 Eu1 141.5(3) . .
C43 O9 Eu2 147.9(3) . .
C48 O12 Eu1 131.5(3) . .
C10 N2 C6 119.1(4) . .
C10 N2 Eu1 119.5(3) . .
C6 N2 Eu1 120.6(3) . .
C43 O10 Eu2 165.7(3) 2_665 .
C37 O6 Eu2 92.9(3) . .
C15 N3 C11 117.3(4) . .
C15 N3 Eu1 121.5(3) . .
C11 N3 Eu1 121.1(3) . .
C31 N5 C27 118.6(4) . .
C31 N5 Eu2 120.0(3) . .
C27 N5 Eu2 120.9(3) . .
C36 N6 C32 119.0(5) . .
C36 N6 Eu2 119.7(4) . .
C32 N6 Eu2 121.0(3) . .
C1 N1 C5 117.6(4) . .
C1 N1 Eu1 120.4(3) . .
C5 N1 Eu1 121.9(3) . .
C46 C47 C48 126.9(4) . .
C46 C47 S3 110.3(4) . .
C48 C47 S3 122.8(4) . .
C22 N4 C26 117.6(5) . .
C22 N4 Eu2 120.5(4) . .
C26 N4 Eu2 121.9(3) . .
N6 C32 C33 119.5(6) . .
N6 C32 C31 117.0(4) . .
C33 C32 C31 123.5(5) . .
O9 C43 O10 123.7(4) . 2_665
O9 C43 C44 118.5(4) . .
O10 C43 C44 117.8(4) 2_665 .
N1 C5 C4 122.0(5) . .
N1 C5 C6 116.2(4) . .
C4 C5 C6 121.8(5) . .
N3 C11 C12 121.4(5) . .
N3 C11 C10 116.2(4) . .
C12 C11 C10 122.3(5) . .
N2 C6 C7 121.9(5) . .
N2 C6 C5 117.2(4) . .
C7 C6 C5 120.9(5) . .
C40 C41 C42 129.8(5) . 1_556
C40 C41 S2 111.5(4) . .
C42 C41 S2 118.7(4) 1_556 .
O11 C48 O12 125.1(4) . .
O11 C48 C47 118.1(4) . .
O12 C48 C47 116.8(4) . .
C45 C44 C43 127.7(5) . .
C45 C44 S3 109.7(4) . .
C43 C44 S3 122.6(4) . .
N4 C26 C25 121.7(5) . .
N4 C26 C27 116.7(4) . .
C25 C26 C27 121.5(5) . .
N1 C1 C2 123.3(5) . .
N1 C1 H1 118.3 . .
C2 C1 H1 118.3 . .
N2 C10 C9 121.0(5) . .
N2 C10 C11 118.3(4) . .
C9 C10 C11 120.7(5) . .
O8 C42 O7 126.5(4) . .
O8 C42 C41 118.7(4) . 1_554
O7 C42 C41 114.8(4) . 1_554
O4 C21 O3 121.8(4) . .
O4 C21 C20 118.6(5) . 1_455
O3 C21 C20 119.6(4) . 1_455
O4 C21 Eu1 61.0(2) . .
O3 C21 Eu1 60.9(2) . .
C20 C21 Eu1 177.5(3) 1_455 .
C23 C24 C25 119.8(6) . .
C23 C24 H24 120.1 . .
C25 C24 H24 120.1 . .
N5 C27 C28 121.8(5) . .
N5 C27 C26 116.9(4) . .
C28 C27 C26 121.3(5) . .
C2 C3 C4 119.9(6) . .
C2 C3 H3 120.0 . .
C4 C3 H3 120.0 . .
C16 O1 Eu2 145.7(6) . .
C20 C19 C18 111.6(5) . .
C20 C19 H19 124.2 . .
C18 C19 H19 124.2 . .
C41 C40 C39 113.2(5) . .
C41 C40 H40 123.4 . .
C39 C40 H40 123.4 . .
C19 C20 C21 128.4(5) . 1_655
C19 C20 S1 112.1(4) . .
C21 C20 S1 119.5(4) 1_655 .
N3 C15 C14 123.3(6) . .
N3 C15 H15 118.3 . .
C14 C15 H15 118.3 . .
C24 C25 C26 119.4(6) . .
C24 C25 H25 120.3 . .
C26 C25 H25 120.3 . .
N6 C36 C35 123.5(6) . .
N6 C36 H36 118.2 . .
C35 C36 H36 118.2 . .
N5 C31 C30 122.1(5) . .
N5 C31 C32 117.3(5) . .
C30 C31 C32 120.6(5) . .
C39 C38 C37 128.7(5) . .
C39 C38 S2 111.1(4) . .
C37 C38 S2 120.2(4) . .
C30 C29 C28 120.2(5) . .
C30 C29 H29 119.9 . .
C28 C29 H29 119.9 . .
C24 C23 C22 118.6(6) . .
C24 C23 H23 120.7 . .
C22 C23 H23 120.7 . .
C46 C45 C44 112.8(5) . .
C46 C45 H45 123.6 . .
C44 C45 H45 123.6 . .
O6 C37 O5 122.0(4) . .
O6 C37 C38 118.2(5) . .
O5 C37 C38 119.8(4) . .
O6 C37 Eu2 60.9(3) . .
O5 C37 Eu2 61.1(2) . .
C38 C37 Eu2 177.9(4) . .
C38 C39 C40 112.3(5) . .
C38 C39 H39 123.8 . .
C40 C39 H39 123.8 . .
C18 C17 C16 128.7(6) . .
C18 C17 S1 112.1(4) . .
C16 C17 S1 119.2(5) . .
N4 C22 C23 122.8(6) . .
N4 C22 H22 118.6 . .
C23 C22 H22 118.6 . .
C9 C8 C7 120.3(5) . .
C9 C8 H8 119.9 . .
C7 C8 H8 119.9 . .
C8 C9 C10 119.4(5) . .
C8 C9 H9 120.3 . .
C10 C9 H9 120.3 . .
C17 C18 C19 112.6(5) . .
C17 C18 H18 123.7 . .
C19 C18 H18 123.7 . .
C32 C33 C34 120.2(6) . .
C32 C33 H33 119.9 . .
C34 C33 H33 119.9 . .
C47 C46 C45 115.0(5) . .
C47 C46 H46 122.5 . .
C45 C46 H46 122.5 . .
C13 C12 C11 120.0(6) . .
C13 C12 H12 120.0 . .
C11 C12 H12 120.0 . .
C3 C4 C5 118.6(5) . .
C3 C4 H4 120.7 . .
C5 C4 H4 120.7 . .
C8 C7 C6 118.2(5) . .
C8 C7 H7 120.9 . .
C6 C7 H7 120.9 . .
C29 C30 C31 118.8(6) . .
C29 C30 H30 120.6 . .
C31 C30 H30 120.6 . .
C14 C13 C12 118.5(6) . .
C14 C13 H13 120.8 . .
C12 C13 H13 120.8 . .
O1 C16 O2 128.9(7) . .
O1 C16 C17 115.8(7) . .
O2 C16 C17 115.2(6) . .
C3 C2 C1 118.4(5) . .
C3 C2 H2 120.8 . .
C1 C2 H2 120.8 . .
C34 C35 C36 117.7(6) . .
C34 C35 H35 121.1 . .
C36 C35 H35 121.1 . .
C29 C28 C27 118.5(6) . .
C29 C28 H28 120.8 . .
C27 C28 H28 120.8 . .
C13 C14 C15 119.5(6) . .
C13 C14 H14 120.3 . .
C15 C14 H14 120.3 . .
C35 C34 C33 120.1(6) . .
C35 C34 H34 120.0 . .
C33 C34 H34 120.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu2 O1 2.265(5) .
Eu2 O10 2.291(3) .
Eu2 O9 2.350(3) .
Eu2 O6 2.487(4) .
Eu2 O5 2.491(3) .
Eu2 N6 2.565(4) .
Eu2 N4 2.575(4) .
Eu2 N5 2.600(4) .
Eu2 C37 2.841(5) .
Eu1 O11 2.356(3) 2_564
Eu1 O7 2.358(3) .
Eu1 O12 2.432(3) .
Eu1 O3 2.500(3) .
Eu1 O4 2.503(3) .
Eu1 N1 2.566(4) .
Eu1 N3 2.573(4) .
Eu1 N2 2.586(4) .
Eu1 OW1 2.612(4) .
Eu1 C21 2.858(5) .
S2 C41 1.714(5) .
S2 C38 1.724(5) .
S1 C17 1.694(6) .
S1 C20 1.722(5) .
S3 C47 1.697(5) .
S3 C44 1.719(5) .
O11 C48 1.247(5) .
O11 Eu1 2.356(3) 2_564
O3 C21 1.262(6) .
O5 C37 1.262(6) .
O4 C21 1.261(6) .
O7 C42 1.290(6) .
O9 C43 1.247(6) .
O12 C48 1.251(5) .
N2 C10 1.339(6) .
N2 C6 1.349(6) .
O10 C43 1.256(5) 2_665
O6 C37 1.256(6) .
N3 C15 1.347(7) .
N3 C11 1.353(6) .
N5 C31 1.345(6) .
N5 C27 1.348(6) .
O8 C42 1.225(6) .
N6 C36 1.335(7) .
N6 C32 1.363(7) .
N1 C1 1.348(6) .
N1 C5 1.353(6) .
C47 C46 1.344(7) .
C47 C48 1.501(6) .
N4 C22 1.338(7) .
N4 C26 1.354(6) .
C32 C33 1.380(8) .
C32 C31 1.472(8) .
C43 O10 1.256(5) 2_665
C43 C44 1.455(6) .
C5 C4 1.388(7) .
C5 C6 1.479(7) .
C11 C12 1.391(7) .
C11 C10 1.477(7) .
C6 C7 1.399(7) .
C41 C40 1.362(7) .
C41 C42 1.498(6) 1_556
C44 C45 1.370(7) .
O2 C16 1.273(8) .
C26 C25 1.387(7) .
C26 C27 1.479(7) .
C1 C2 1.375(7) .
C1 H1 0.9300 .
C10 C9 1.399(7) .
C42 C41 1.498(6) 1_554
C21 C20 1.478(6) 1_455
C24 C23 1.354(9) .
C24 C25 1.370(9) .
C24 H24 0.9300 .
C27 C28 1.398(7) .
C3 C2 1.368(9) .
C3 C4 1.381(8) .
C3 H3 0.9300 .
O1 C16 1.165(8) .
C19 C20 1.354(7) .
C19 C18 1.426(7) .
C19 H19 0.9300 .
C40 C39 1.411(7) .
C40 H40 0.9300 .
C20 C21 1.478(6) 1_655
C15 C14 1.375(8) .
C15 H15 0.9300 .
C25 H25 0.9300 .
C36 C35 1.376(8) .
C36 H36 0.9300 .
C31 C30 1.389(7) .
C38 C39 1.377(7) .
C38 C37 1.474(7) .
C29 C30 1.369(9) .
C29 C28 1.372(9) .
C29 H29 0.9300 .
C23 C22 1.396(8) .
C23 H23 0.9300 .
C45 C46 1.362(7) .
C45 H45 0.9300 .
C39 H39 0.9300 .
C17 C18 1.362(9) .
C17 C16 1.531(8) .
C22 H22 0.9300 .
C8 C9 1.364(8) .
C8 C7 1.366(8) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C18 H18 0.9300 .
C33 C34 1.382(9) .
C33 H33 0.9300 .
C46 H46 0.9300 .
C12 C13 1.378(9) .
C12 H12 0.9300 .
C4 H4 0.9300 .
C7 H7 0.9300 .
C30 H30 0.9300 .
C13 C14 1.360(9) .
C13 H13 0.9300 .
C2 H2 0.9300 .
C35 C34 1.356(9) .
C35 H35 0.9300 .
C28 H28 0.9300 .
C14 H14 0.9300 .
C34 H34 0.9300 .
