#------------------------------------------------------------------------------
#$Date: 2016-04-05 21:06:25 +0300 (Tue, 05 Apr 2016) $
#$Revision: 181742 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/64/7036488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7036488
loop_
_publ_author_name
'Swarnakar, Anindya K.'
'Ferguson, Michael J.'
'McDonald, Robert'
'Rivard, Eric'
_publ_section_title
;
 Transition metal-mediated donor-acceptor coordination of low-oxidation
 state Group 14 element halides.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6071
_journal_page_last               6078
_journal_paper_doi               10.1039/c5dt03018h
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C41 H66 Cl2 Ge O5 P2 Pt W, 0.5(C6 H14)'
_chemical_formula_sum            'C44 H73 Cl2 Ge O5 P2 Pt W'
_chemical_formula_weight         1266.39
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2015-07-30 deposited with the CCDC.
2015-09-09 downloaded from the CCDC.
;
_cell_angle_alpha                105.848(2)
_cell_angle_beta                 103.959(2)
_cell_angle_gamma                93.004(3)
_cell_formula_units_Z            2
_cell_length_a                   10.172(2)
_cell_length_b                   12.807(3)
_cell_length_c                   20.478(4)
_cell_measurement_reflns_used    9783
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.52
_cell_measurement_theta_min      2.23
_cell_volume                     2470.5(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXT-2013 (Sheldrick 2013)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0148
_diffrn_reflns_av_unetI/netI     0.0222
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            22384
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.589
_diffrn_reflns_theta_min         1.072
_exptl_absorpt_coefficient_mu    5.964
_exptl_absorpt_correction_T_max  0.7960
_exptl_absorpt_correction_T_min  0.3812
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.702
_exptl_crystal_description       fragment
_exptl_crystal_F_000             1250
_exptl_crystal_size_max          0.297
_exptl_crystal_size_mid          0.099
_exptl_crystal_size_min          0.060
_refine_diff_density_max         1.248
_refine_diff_density_min         -1.042
_refine_diff_density_rms         0.128
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.117
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     534
_refine_ls_number_reflns         11338
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.118
_refine_ls_R_factor_all          0.0276
_refine_ls_R_factor_gt           0.0212
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0333P)²+0.5140P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0533
_refine_ls_wR_factor_ref         0.0603
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9930
_reflns_number_total             11338
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt03018h2.cif
_cod_data_source_block           riv13f2_cmpd_5
_cod_depositor_comments
'Adding full bibliography for 7036484--7036489.cif.'
_cod_original_cell_volume        2470.6(8)
_cod_database_code               7036488
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.270
_shelx_estimated_absorpt_t_max   0.716
_shelxl_version_number           2013-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.38138(2) 0.42202(2) 0.26899(2) 0.01895(4) Uani 1 1 d . . . . .
W W 0.33479(2) 0.18198(2) 0.04126(2) 0.02766(4) Uani 1 1 d . . . . .
Ge Ge 0.29273(3) 0.31805(2) 0.15041(2) 0.01764(7) Uani 1 1 d . . . . .
Cl1 Cl 0.48170(8) 0.51936(6) 0.39191(4) 0.02982(17) Uani 1 1 d . . . . .
Cl2 Cl 0.07760(8) 0.35748(7) 0.12046(4) 0.0374(2) Uani 1 1 d . . . . .
P1 P 0.33508(7) 0.27140(6) 0.30728(4) 0.01869(15) Uani 1 1 d . . . . .
P2 P 0.44572(8) 0.58025(6) 0.24119(4) 0.02103(15) Uani 1 1 d . . . . .
O1 O 0.3745(3) 0.0350(3) -0.10202(14) 0.0583(8) Uani 1 1 d . . . . .
O2 O 0.0118(3) 0.1176(2) -0.01439(15) 0.0546(8) Uani 1 1 d . . . . .
O3 O 0.3342(3) -0.0261(2) 0.09738(18) 0.0548(8) Uani 1 1 d . . . . .
O4 O 0.6563(3) 0.2231(2) 0.10624(16) 0.0516(7) Uani 1 1 d . . . . .
O5 O 0.3208(4) 0.3762(3) -0.02813(17) 0.0720(10) Uani 1 1 d . . . . .
C1 C 0.3609(4) 0.0873(3) -0.04894(19) 0.0392(9) Uani 1 1 d . . . . .
C2 C 0.1266(4) 0.1427(3) 0.00486(18) 0.0391(9) Uani 1 1 d . . . . .
C3 C 0.3347(3) 0.0488(3) 0.0781(2) 0.0357(8) Uani 1 1 d . . . . .
C4 C 0.5416(4) 0.2115(3) 0.08312(18) 0.0327(7) Uani 1 1 d . . . . .
C5 C 0.3272(4) 0.3080(3) -0.00164(19) 0.0424(9) Uani 1 1 d . . . . .
C11 C 0.2804(3) 0.3144(2) 0.38903(15) 0.0219(6) Uani 1 1 d . . . . .
H11 H 0.3626 0.3603 0.4248 0.026 Uiso 1 1 calc R U . . .
C12 C 0.1697(3) 0.3912(3) 0.38723(16) 0.0285(7) Uani 1 1 d . . . . .
H12A H 0.1933 0.4489 0.3667 0.034 Uiso 1 1 calc R U . . .
H12B H 0.0810 0.3495 0.3573 0.034 Uiso 1 1 calc R U . . .
C13 C 0.1585(4) 0.4434(3) 0.46199(18) 0.0399(9) Uani 1 1 d . . . . .
H13A H 0.2452 0.4897 0.4908 0.048 Uiso 1 1 calc R U . . .
H13B H 0.0847 0.4908 0.4606 0.048 Uiso 1 1 calc R U . . .
C14 C 0.1281(4) 0.3554(4) 0.49572(18) 0.0443(10) Uani 1 1 d . . . . .
H14A H 0.1273 0.3909 0.5450 0.053 Uiso 1 1 calc R U . . .
H14B H 0.0361 0.3153 0.4701 0.053 Uiso 1 1 calc R U . . .
C15 C 0.2323(4) 0.2745(3) 0.49491(17) 0.0359(8) Uani 1 1 d . . . . .
H15A H 0.2040 0.2158 0.5135 0.043 Uiso 1 1 calc R U . . .
H15B H 0.3221 0.3125 0.5260 0.043 Uiso 1 1 calc R U . . .
C16 C 0.2463(3) 0.2235(3) 0.42019(16) 0.0291(7) Uani 1 1 d . . . . .
H16A H 0.3196 0.1756 0.4217 0.035 Uiso 1 1 calc R U . . .
H16B H 0.1597 0.1783 0.3901 0.035 Uiso 1 1 calc R U . . .
C21 C 0.4922(3) 0.2080(2) 0.32981(15) 0.0217(6) Uani 1 1 d . . . . .
H21 H 0.4653 0.1383 0.3391 0.026 Uiso 1 1 calc R U . . .
C22 C 0.6013(3) 0.2775(3) 0.39554(16) 0.0283(7) Uani 1 1 d . . . . .
H22A H 0.6282 0.3484 0.3886 0.034 Uiso 1 1 calc R U . . .
H22B H 0.5628 0.2928 0.4367 0.034 Uiso 1 1 calc R U . . .
C23 C 0.7272(3) 0.2188(3) 0.41004(18) 0.0315(7) Uani 1 1 d . . . . .
H23A H 0.7969 0.2661 0.4518 0.038 Uiso 1 1 calc R U . . .
H23B H 0.7018 0.1506 0.4205 0.038 Uiso 1 1 calc R U . . .
C24 C 0.7869(3) 0.1912(3) 0.34679(19) 0.0372(8) Uani 1 1 d . . . . .
H24A H 0.8182 0.2596 0.3383 0.045 Uiso 1 1 calc R U . . .
H24B H 0.8668 0.1516 0.3568 0.045 Uiso 1 1 calc R U . . .
C25 C 0.6807(4) 0.1208(3) 0.28143(19) 0.0408(9) Uani 1 1 d . . . . .
H25A H 0.6552 0.0497 0.2884 0.049 Uiso 1 1 calc R U . . .
H25B H 0.7200 0.1063 0.2405 0.049 Uiso 1 1 calc R U . . .
C26 C 0.5536(3) 0.1780(3) 0.26655(16) 0.0314(7) Uani 1 1 d . . . . .
H26A H 0.4843 0.1292 0.2252 0.038 Uiso 1 1 calc R U . . .
H26B H 0.5778 0.2453 0.2549 0.038 Uiso 1 1 calc R U . . .
C31 C 0.2097(3) 0.1559(2) 0.24230(15) 0.0219(6) Uani 1 1 d . . . . .
H31 H 0.2316 0.1465 0.1961 0.026 Uiso 1 1 calc R U . . .
C32 C 0.2148(3) 0.0438(2) 0.25567(17) 0.0289(7) Uani 1 1 d . . . . .
H32A H 0.3077 0.0227 0.2582 0.035 Uiso 1 1 calc R U . . .
H32B H 0.1957 0.0491 0.3016 0.035 Uiso 1 1 calc R U . . .
C33 C 0.1111(4) -0.0445(3) 0.19773(19) 0.0360(8) Uani 1 1 d . . . . .
H33A H 0.1388 -0.0582 0.1533 0.043 Uiso 1 1 calc R U . . .
H33B H 0.1110 -0.1135 0.2108 0.043 Uiso 1 1 calc R U . . .
C34 C -0.0330(3) -0.0116(3) 0.1859(2) 0.0406(9) Uani 1 1 d . . . . .
H34A H -0.0656 -0.0069 0.2283 0.049 Uiso 1 1 calc R U . . .
H34B H -0.0956 -0.0683 0.1458 0.049 Uiso 1 1 calc R U . . .
C35 C -0.0352(3) 0.0988(3) 0.17055(19) 0.0377(8) Uani 1 1 d . . . . .
H35A H -0.0078 0.0932 0.1266 0.045 Uiso 1 1 calc R U . . .
H35B H -0.1289 0.1195 0.1640 0.045 Uiso 1 1 calc R U . . .
C36 C 0.0631(3) 0.1862(3) 0.23185(17) 0.0290(7) Uani 1 1 d . . . . .
H36A H 0.0341 0.1930 0.2755 0.035 Uiso 1 1 calc R U . . .
H36B H 0.0606 0.2578 0.2221 0.035 Uiso 1 1 calc R U . . .
C41 C 0.4385(3) 0.7031(2) 0.31263(15) 0.0240(6) Uani 1 1 d . . . . .
H41 H 0.5065 0.6961 0.3550 0.029 Uiso 1 1 calc R U . . .
C42 C 0.3021(3) 0.7045(3) 0.33308(17) 0.0300(7) Uani 1 1 d . . . . .
H42A H 0.2312 0.7234 0.2971 0.036 Uiso 1 1 calc R U . . .
H42B H 0.2716 0.6311 0.3352 0.036 Uiso 1 1 calc R U . . .
C43 C 0.3210(4) 0.7889(3) 0.40487(18) 0.0369(8) Uani 1 1 d . . . . .
H43A H 0.2331 0.7907 0.4176 0.044 Uiso 1 1 calc R U . . .
H43B H 0.3881 0.7674 0.4412 0.044 Uiso 1 1 calc R U . . .
C44 C 0.3710(4) 0.9022(3) 0.4032(2) 0.0418(9) Uani 1 1 d . . . . .
H44A H 0.3878 0.9547 0.4508 0.050 Uiso 1 1 calc R U . . .
H44B H 0.2995 0.9268 0.3706 0.050 Uiso 1 1 calc R U . . .
C45 C 0.5022(4) 0.9014(3) 0.37938(19) 0.0395(9) Uani 1 1 d . . . . .
H45A H 0.5765 0.8849 0.4149 0.047 Uiso 1 1 calc R U . . .
H45B H 0.5289 0.9748 0.3760 0.047 Uiso 1 1 calc R U . . .
C46 C 0.4841(4) 0.8158(3) 0.30743(18) 0.0323(7) Uani 1 1 d . . . . .
H46A H 0.4146 0.8346 0.2708 0.039 Uiso 1 1 calc R U . . .
H46B H 0.5714 0.8148 0.2941 0.039 Uiso 1 1 calc R U . . .
C51 C 0.6262(3) 0.5848(3) 0.23832(15) 0.0250(6) Uani 1 1 d . . . . .
H51 H 0.6509 0.6538 0.2277 0.030 Uiso 1 1 calc R U . . .
C52 C 0.7267(3) 0.5861(3) 0.30799(17) 0.0341(8) Uani 1 1 d . . . . .
H52A H 0.7197 0.6513 0.3457 0.041 Uiso 1 1 calc R U . . .
H52B H 0.7018 0.5203 0.3211 0.041 Uiso 1 1 calc R U . . .
C53 C 0.8736(4) 0.5882(4) 0.30225(19) 0.0480(11) Uani 1 1 d . . . . .
H53A H 0.9017 0.6576 0.2940 0.058 Uiso 1 1 calc R U . . .
H53B H 0.9347 0.5852 0.3472 0.058 Uiso 1 1 calc R U . . .
C54 C 0.8886(4) 0.4922(4) 0.2424(2) 0.0485(10) Uani 1 1 d . . . . .
H54A H 0.9837 0.4978 0.2385 0.058 Uiso 1 1 calc R U . . .
H54B H 0.8690 0.4227 0.2527 0.058 Uiso 1 1 calc R U . . .
C55 C 0.7916(4) 0.4919(4) 0.17363(19) 0.0424(9) Uani 1 1 d . . . . .
H55A H 0.7996 0.4272 0.1358 0.051 Uiso 1 1 calc R U . . .
H55B H 0.8169 0.5583 0.1613 0.051 Uiso 1 1 calc R U . . .
C56 C 0.6436(3) 0.4888(3) 0.17853(17) 0.0335(8) Uani 1 1 d . . . . .
H56A H 0.6157 0.4192 0.1866 0.040 Uiso 1 1 calc R U . . .
H56B H 0.5832 0.4915 0.1333 0.040 Uiso 1 1 calc R U . . .
C61 C 0.3533(3) 0.5966(3) 0.15506(16) 0.0272(7) Uani 1 1 d . . . . .
H61 H 0.3407 0.5227 0.1200 0.033 Uiso 1 1 calc R U . . .
C62 C 0.4274(4) 0.6749(3) 0.12649(17) 0.0357(8) Uani 1 1 d . . . . .
H62A H 0.4384 0.7506 0.1580 0.043 Uiso 1 1 calc R U . . .
H62B H 0.5195 0.6542 0.1255 0.043 Uiso 1 1 calc R U . . .
C63 C 0.3463(4) 0.6704(3) 0.05215(18) 0.0433(9) Uani 1 1 d . . . . .
H63A H 0.3924 0.7248 0.0360 0.052 Uiso 1 1 calc R U . . .
H63B H 0.3452 0.5970 0.0197 0.052 Uiso 1 1 calc R U . . .
C64 C 0.2010(4) 0.6936(3) 0.0492(2) 0.0485(10) Uani 1 1 d . . . . .
H64A H 0.2016 0.7707 0.0761 0.058 Uiso 1 1 calc R U . . .
H64B H 0.1502 0.6834 -0.0004 0.058 Uiso 1 1 calc R U . . .
C65 C 0.1288(4) 0.6190(3) 0.07903(19) 0.0446(9) Uani 1 1 d . . . . .
H65A H 0.1182 0.5426 0.0487 0.053 Uiso 1 1 calc R U . . .
H65B H 0.0365 0.6398 0.0793 0.053 Uiso 1 1 calc R U . . .
C66 C 0.2096(3) 0.6265(3) 0.15460(17) 0.0330(7) Uani 1 1 d . . . . .
H66A H 0.2155 0.7018 0.1858 0.040 Uiso 1 1 calc R U . . .
H66B H 0.1617 0.5759 0.1727 0.040 Uiso 1 1 calc R U . . .
C1SA C 0.0077(14) -0.0033(10) 0.4654(5) 0.070(3) Uani 0.6 1 d . . P A 1
H1SA H 0.1046 -0.0105 0.4666 0.084 Uiso 0.6 1 calc R U P A 1
H1SB H -0.0109 0.0674 0.4564 0.084 Uiso 0.6 1 calc R U P A 1
C2SA C -0.0770(12) -0.0915(10) 0.4046(5) 0.068(3) Uani 0.6 1 d . . P A 1
H2SA H -0.0597 -0.1621 0.4139 0.081 Uiso 0.6 1 calc R U P A 1
H2SB H -0.1740 -0.0835 0.4028 0.081 Uiso 0.6 1 calc R U P A 1
C3SA C -0.0593(14) -0.0983(8) 0.3370(6) 0.089(3) Uani 0.6 1 d . . P A 1
H3SA H -0.1367 -0.1456 0.3007 0.106 Uiso 0.6 1 calc R U P A 1
H3SB H 0.0255 -0.1291 0.3325 0.106 Uiso 0.6 1 calc R U P A 1
H3SC H -0.0544 -0.0251 0.3309 0.106 Uiso 0.6 1 calc R U P A 1
C1SB C 0.052(3) -0.0356(14) 0.4848(12) 0.119(10) Uani 0.4 1 d D . P B 2
H1SC H 0.0483 -0.1065 0.4954 0.143 Uiso 0.4 1 calc R U P B 2
H1SD H 0.1459 0.0028 0.5050 0.143 Uiso 0.4 1 calc R U P B 2
C2SB C 0.0048(16) -0.0536(16) 0.4028(10) 0.091(5) Uani 0.4 1 d D . P B 2
H2SC H 0.0289 0.0162 0.3940 0.110 Uiso 0.4 1 calc R U P B 2
H2SD H 0.0585 -0.1078 0.3803 0.110 Uiso 0.4 1 calc R U P B 2
C3SB C -0.1452(16) -0.0919(17) 0.3665(14) 0.113(8) Uani 0.4 1 d D . P B 2
H3SD H -0.1625 -0.0976 0.3163 0.136 Uiso 0.4 1 calc R U P B 2
H3SE H -0.2004 -0.0392 0.3879 0.136 Uiso 0.4 1 calc R U P B 2
H3SF H -0.1698 -0.1637 0.3716 0.136 Uiso 0.4 1 calc R U P B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
P1 Pt P2 174.18(3) .
P1 Pt Ge 91.40(2) .
P2 Pt Ge 93.82(2) .
P1 Pt Cl1 86.21(3) .
P2 Pt Cl1 88.45(3) .
Ge Pt Cl1 176.20(2) .
C1 W C5 87.70(15) .
C1 W C4 89.96(14) .
C5 W C4 94.24(16) .
C1 W C3 89.46(16) .
C5 W C3 176.23(15) .
C4 W C3 88.24(14) .
C1 W C2 91.40(14) .
C5 W C2 91.00(17) .
C4 W C2 174.64(15) .
C3 W C2 86.59(15) .
C1 W Ge 174.08(11) .
C5 W Ge 86.62(10) .
C4 W Ge 92.11(9) .
C3 W Ge 96.14(10) .
C2 W Ge 87.05(9) .
Cl2 Ge Pt 104.87(2) .
Cl2 Ge W 107.66(2) .
Pt Ge W 147.463(16) .
C11 P1 C21 105.60(13) .
C11 P1 C31 109.09(13) .
C21 P1 C31 103.99(13) .
C11 P1 Pt 110.80(10) .
C21 P1 Pt 110.10(10) .
C31 P1 Pt 116.53(10) .
C51 P2 C41 105.70(14) .
C51 P2 C61 103.93(14) .
C41 P2 C61 109.12(14) .
C51 P2 Pt 109.61(10) .
C41 P2 Pt 109.53(10) .
C61 P2 Pt 118.15(11) .
O1 C1 W 177.9(4) .
O2 C2 W 177.4(4) .
O3 C3 W 178.8(3) .
O4 C4 W 177.0(3) .
O5 C5 W 177.5(4) .
C16 C11 C12 111.0(3) .
C16 C11 P1 116.5(2) .
C12 C11 P1 114.5(2) .
C13 C12 C11 109.6(3) .
C14 C13 C12 110.6(3) .
C15 C14 C13 112.4(3) .
C14 C15 C16 111.4(3) .
C11 C16 C15 109.7(3) .
C22 C21 C26 109.8(2) .
C22 C21 P1 114.8(2) .
C26 C21 P1 109.8(2) .
C23 C22 C21 111.1(3) .
C24 C23 C22 110.8(3) .
C25 C24 C23 110.6(3) .
C24 C25 C26 110.7(3) .
C25 C26 C21 111.9(3) .
C32 C31 C36 110.2(3) .
C32 C31 P1 116.8(2) .
C36 C31 P1 111.0(2) .
C33 C32 C31 111.9(3) .
C34 C33 C32 112.0(3) .
C33 C34 C35 110.8(3) .
C36 C35 C34 109.7(3) .
C35 C36 C31 110.4(3) .
C46 C41 C42 109.9(3) .
C46 C41 P2 118.5(2) .
C42 C41 P2 114.1(2) .
C43 C42 C41 109.5(3) .
C44 C43 C42 110.6(3) .
C43 C44 C45 111.2(3) .
C44 C45 C46 111.5(3) .
C41 C46 C45 108.8(3) .
C56 C51 C52 109.7(3) .
C56 C51 P2 110.4(2) .
C52 C51 P2 113.9(2) .
C53 C52 C51 111.6(3) .
C54 C53 C52 111.5(3) .
C55 C54 C53 110.4(3) .
C54 C55 C56 111.3(3) .
C55 C56 C51 111.7(3) .
C66 C61 C62 109.7(3) .
C66 C61 P2 112.0(2) .
C62 C61 P2 116.5(2) .
C63 C62 C61 110.5(3) .
C64 C63 C62 112.1(3) .
C65 C64 C63 111.6(3) .
C64 C65 C66 111.0(3) .
C61 C66 C65 109.9(3) .
C1SA C1SA C2SA 118.5(12) 2_556
C3SA C2SA C1SA 118.0(11) .
C1SB C1SB C2SB 105(2) 2_556
C3SB C2SB C1SB 116.9(19) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt P1 2.3381(8) .
Pt P2 2.3516(9) .
Pt Ge 2.3526(5) .
Pt Cl1 2.4176(8) .
W C1 2.000(4) .
W C5 2.034(4) .
W C4 2.043(4) .
W C3 2.045(4) .
W C2 2.054(4) .
W Ge 2.5745(5) .
Ge Cl2 2.2489(9) .
P1 C11 1.842(3) .
P1 C21 1.847(3) .
P1 C31 1.869(3) .
P2 C51 1.849(3) .
P2 C41 1.852(3) .
P2 C61 1.860(3) .
O1 C1 1.155(4) .
O2 C2 1.136(4) .
O3 C3 1.133(4) .
O4 C4 1.133(4) .
O5 C5 1.144(5) .
C11 C16 1.533(4) .
C11 C12 1.533(4) .
C12 C13 1.529(4) .
C13 C14 1.528(6) .
C14 C15 1.521(5) .
C15 C16 1.535(4) .
C21 C22 1.535(4) .
C21 C26 1.536(4) .
C22 C23 1.527(4) .
C23 C24 1.524(5) .
C24 C25 1.521(5) .
C25 C26 1.527(4) .
C31 C32 1.534(4) .
C31 C36 1.541(4) .
C32 C33 1.529(4) .
C33 C34 1.528(5) .
C34 C35 1.530(5) .
C35 C36 1.530(4) .
C41 C46 1.531(4) .
C41 C42 1.542(4) .
C42 C43 1.530(5) .
C43 C44 1.525(5) .
C44 C45 1.527(5) .
C45 C46 1.540(5) .
C51 C56 1.532(4) .
C51 C52 1.537(4) .
C52 C53 1.526(5) .
C53 C54 1.525(5) .
C54 C55 1.511(5) .
C55 C56 1.532(5) .
C61 C66 1.528(5) .
C61 C62 1.540(5) .
C62 C63 1.530(5) .
C63 C64 1.513(6) .
C64 C65 1.513(6) .
C65 C66 1.542(5) .
C1SA C1SA 1.44(2) 2_556
C1SA C2SA 1.477(15) .
C2SA C3SA 1.419(14) .
C1SB C1SB 1.56(2) 2_556
C1SB C2SB 1.578(19) .
C2SB C3SB 1.516(17) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
P1 Pt Ge Cl2 97.77(3) .
P2 Pt Ge Cl2 -84.82(4) .
P1 Pt Ge W -83.04(3) .
P2 Pt Ge W 94.36(3) .
Ge Pt P1 C11 -143.60(10) .
Cl1 Pt P1 C11 39.36(10) .
Ge Pt P1 C21 99.96(10) .
Cl1 Pt P1 C21 -77.09(10) .
Ge Pt P1 C31 -18.10(11) .
Cl1 Pt P1 C31 164.86(11) .
Ge Pt P2 C51 -93.96(10) .
Cl1 Pt P2 C51 82.98(10) .
Ge Pt P2 C41 150.49(11) .
Cl1 Pt P2 C41 -32.57(11) .
Ge Pt P2 C61 24.75(12) .
Cl1 Pt P2 C61 -158.30(12) .
C21 P1 C11 C16 -60.9(2) .
C31 P1 C11 C16 50.3(3) .
Pt P1 C11 C16 179.91(19) .
C21 P1 C11 C12 167.3(2) .
C31 P1 C11 C12 -81.5(2) .
Pt P1 C11 C12 48.1(2) .
C16 C11 C12 C13 59.7(3) .
P1 C11 C12 C13 -165.9(2) .
C11 C12 C13 C14 -57.0(4) .
C12 C13 C14 C15 55.1(4) .
C13 C14 C15 C16 -54.2(4) .
C12 C11 C16 C15 -58.4(3) .
P1 C11 C16 C15 168.2(2) .
C14 C15 C16 C11 55.1(4) .
C11 P1 C21 C22 -50.8(3) .
C31 P1 C21 C22 -165.6(2) .
Pt P1 C21 C22 68.8(2) .
C11 P1 C21 C26 -175.1(2) .
C31 P1 C21 C26 70.1(2) .
Pt P1 C21 C26 -55.5(2) .
C26 C21 C22 C23 -55.6(4) .
P1 C21 C22 C23 -180.0(2) .
C21 C22 C23 C24 57.5(4) .
C22 C23 C24 C25 -57.7(4) .
C23 C24 C25 C26 56.8(4) .
C24 C25 C26 C21 -56.2(4) .
C22 C21 C26 C25 55.2(4) .
P1 C21 C26 C25 -177.6(3) .
C11 P1 C31 C32 -74.3(2) .
C21 P1 C31 C32 38.0(3) .
Pt P1 C31 C32 159.32(19) .
C11 P1 C31 C36 53.2(3) .
C21 P1 C31 C36 165.5(2) .
Pt P1 C31 C36 -73.2(2) .
C36 C31 C32 C33 54.1(4) .
P1 C31 C32 C33 -178.0(2) .
C31 C32 C33 C34 -53.1(4) .
C32 C33 C34 C35 55.0(4) .
C33 C34 C35 C36 -58.2(4) .
C34 C35 C36 C31 60.0(4) .
C32 C31 C36 C35 -57.9(4) .
P1 C31 C36 C35 171.1(2) .
C51 P2 C41 C46 58.7(3) .
C61 P2 C41 C46 -52.5(3) .
Pt P2 C41 C46 176.7(2) .
C51 P2 C41 C42 -169.5(2) .
C61 P2 C41 C42 79.3(3) .
Pt P2 C41 C42 -51.4(2) .
C46 C41 C42 C43 -60.9(3) .
P2 C41 C42 C43 163.2(2) .
C41 C42 C43 C44 58.2(4) .
C42 C43 C44 C45 -55.7(4) .
C43 C44 C45 C46 55.6(4) .
C42 C41 C46 C45 59.8(4) .
P2 C41 C46 C45 -166.5(2) .
C44 C45 C46 C41 -57.3(4) .
C41 P2 C51 C56 -177.6(2) .
C61 P2 C51 C56 -62.7(2) .
Pt P2 C51 C56 64.4(2) .
C41 P2 C51 C52 58.5(3) .
C61 P2 C51 C52 173.4(2) .
Pt P2 C51 C52 -59.5(2) .
C56 C51 C52 C53 54.9(4) .
P2 C51 C52 C53 179.2(3) .
C51 C52 C53 C54 -56.2(5) .
C52 C53 C54 C55 56.4(5) .
C53 C54 C55 C56 -56.5(5) .
C54 C55 C56 C51 56.9(4) .
C52 C51 C56 C55 -55.1(4) .
P2 C51 C56 C55 178.6(3) .
C51 P2 C61 C66 -164.2(2) .
C41 P2 C61 C66 -51.8(3) .
Pt P2 C61 C66 74.1(2) .
C51 P2 C61 C62 -36.8(3) .
C41 P2 C61 C62 75.6(3) .
Pt P2 C61 C62 -158.5(2) .
C66 C61 C62 C63 -57.6(4) .
P2 C61 C62 C63 173.8(2) .
C61 C62 C63 C64 55.1(4) .
C62 C63 C64 C65 -54.0(4) .
C63 C64 C65 C66 55.2(4) .
C62 C61 C66 C65 59.0(4) .
P2 C61 C66 C65 -170.0(2) .
C64 C65 C66 C61 -58.1(4) .
C1SA C1SA C2SA C3SA -178.9(16) 2_556
C1SB C1SB C2SB C3SB -49(3) 2_556
