#------------------------------------------------------------------------------
#$Date: 2015-12-09 17:17:59 +0200 (Wed, 09 Dec 2015) $
#$Revision: 171288 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/67/7036702.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7036702
loop_
_publ_author_name
'Chen, Chia-Hsiang'
'Aghabali, Amineh'
'Metta-Magana, Alejandro J'
'Olmstead, Marilyn M.'
'Balch, Alan L.'
'Echegoyen, Luis'
_publ_section_title
;
 Synthesis and characterization of a trans-1 hexakis-fullerene linker that
 forms crystalline polymers with silver salts.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18487
_journal_page_last               18491
_journal_paper_doi               10.1039/c5dt03054d
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C118 H64 Ag2 F3 N4 O30 P2, 2(C H1.5 N0.5)'
_chemical_formula_sum            'C120 H67 Ag2 F3 N5 O30 P2'
_chemical_formula_weight         2393.46
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-09-15 deposited with the CCDC.
2015-09-29 downloaded from the CCDC.
;
_cell_angle_alpha                105.067(3)
_cell_angle_beta                 94.215(4)
_cell_angle_gamma                93.227(3)
_cell_formula_units_Z            1
_cell_length_a                   10.0910(6)
_cell_length_b                   14.7707(9)
_cell_length_c                   16.9006(11)
_cell_measurement_reflns_used    9857
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      38.5
_cell_measurement_theta_min      5.9
_cell_volume                     2418.4(3)
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_collection       'Apex 2 (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'XT (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.42
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'Bruker D8 with Photon 100 CMOS detector'
_diffrn_measurement_method       'ω and φ'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     1.0333
_diffrn_reflns_av_R_equivalents  0.0658
_diffrn_reflns_av_unetI/netI     0.0605
_diffrn_reflns_laue_measured_fraction_full 0.976
_diffrn_reflns_laue_measured_fraction_max 0.968
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            32870
_diffrn_reflns_point_group_measured_fraction_full 0.976
_diffrn_reflns_point_group_measured_fraction_max 0.968
_diffrn_reflns_theta_full        38.315
_diffrn_reflns_theta_max         38.640
_diffrn_reflns_theta_min         2.952
_diffrn_source                   'Advanced Light Source, beamline 11.3.1'
_exptl_absorpt_coefficient_mu    1.447
_exptl_absorpt_correction_T_max  0.748
_exptl_absorpt_correction_T_min  0.594
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2012)'
_exptl_crystal_colour            yellow-green
_exptl_crystal_density_diffrn    1.643
_exptl_crystal_description       block
_exptl_crystal_F_000             1213
_exptl_crystal_size_max          0.094
_exptl_crystal_size_mid          0.047
_exptl_crystal_size_min          0.019
_refine_diff_density_max         1.655
_refine_diff_density_min         -1.202
_refine_diff_density_rms         0.135
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.182
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     760
_refine_ls_number_reflns         8653
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.185
_refine_ls_R_factor_all          0.1396
_refine_ls_R_factor_gt           0.1057
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+36.1713P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2214
_refine_ls_wR_factor_ref         0.2400
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6518
_reflns_number_total             8653
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt03054d2.cif
_cod_data_source_block           5
_cod_depositor_comments
'Adding full bibliography for 7036700--7036702.cif.'
_cod_database_code               7036702
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.876
_shelx_estimated_absorpt_t_max   0.973
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.09962(8) 0.11367(6) 0.00644(5) 0.0523(3) Uani 1 1 d . . . . .
P1 P -0.0178(3) 0.0008(2) 0.18538(18) 0.0489(7) Uani 1 1 d D . . . .
O13 O -0.1161(18) -0.0533(11) 0.2120(10) 0.102(5) Uani 0.75 1 d . . P A 1
O14 O 0.1170(13) -0.0302(11) 0.2060(7) 0.080(4) Uani 0.75 1 d . . P A 1
O15 O -0.0059(15) 0.0985(7) 0.2434(6) 0.070(4) Uani 0.75 1 d . . P A 1
O16 O -0.0272(9) 0.0157(7) 0.1020(5) 0.081(3) Uani 0.75 1 d . . P A 1
F1 F 0.046(3) -0.0945(14) 0.1610(18) 0.062(7) Uiso 0.25 1 d D . P A 2
F2 F 0.117(2) 0.062(2) 0.2297(17) 0.072(8) Uiso 0.25 1 d D . P A 2
F3 F -0.093(3) 0.019(3) 0.2636(16) 0.087(10) Uiso 0.25 1 d D . P A 2
F4 F -0.160(2) -0.053(3) 0.153(3) 0.104(12) Uiso 0.25 1 d D . P A 2
F5 F -0.074(5) 0.099(2) 0.212(3) 0.133(19) Uiso 0.25 1 d D . P A 2
F6 F -0.0272(9) 0.0157(7) 0.1020(5) 0.081(3) Uani 0.25 1 d D . P A 2
O1 O 0.8004(7) 0.8799(4) 0.4626(4) 0.0370(15) Uani 1 1 d . . . . .
O2 O 0.8585(6) 0.9431(4) 0.5979(4) 0.0352(15) Uani 1 1 d . . . . .
O3 O 0.6170(7) 0.7665(5) 0.6620(4) 0.0417(16) Uani 1 1 d . . . . .
O4 O 0.5787(6) 0.8755(4) 0.5936(4) 0.0323(14) Uani 1 1 d . . . . .
O5 O 0.7617(7) 0.4480(4) 0.8154(4) 0.0394(16) Uani 1 1 d . . . . .
O6 O 0.8062(8) 0.2975(5) 0.7712(4) 0.0491(19) Uani 1 1 d . . . . .
O7 O 0.5317(6) 0.2817(4) 0.5746(4) 0.0350(15) Uani 1 1 d . . . . .
O8 O 0.5307(6) 0.2863(5) 0.7086(4) 0.0407(16) Uani 1 1 d . . . . .
O9 O 0.5277(6) 0.4776(5) 0.2582(4) 0.0415(16) Uani 1 1 d . . . . .
O10 O 0.5347(6) 0.3599(4) 0.1427(4) 0.0393(16) Uani 1 1 d . . . . .
O11 O 0.7823(7) 0.2554(4) 0.1411(4) 0.0402(16) Uani 1 1 d . . . . .
O12 O 0.6427(6) 0.1972(4) 0.2183(4) 0.0312(14) Uani 1 1 d . . . . .
N1 N 0.0776(8) 0.2113(6) 0.0377(5) 0.040(2) Uani 1 1 d . . . . .
N2 N 0.2968(8) -0.0462(5) 0.0473(5) 0.0381(19) Uani 1 1 d . . . . .
N3 N 0.727(3) 0.5245(17) 0.0882(18) 0.087(8) Uani 0.5 1 d . . P . .
C1 C 0.6926(8) 0.5683(5) 0.5730(5) 0.0250(18) Uani 1 1 d . . . . .
C2 C 0.6739(8) 0.4679(6) 0.5625(5) 0.0238(18) Uani 1 1 d . . . . .
C3 C 0.7452(8) 0.4452(6) 0.6339(5) 0.0239(17) Uani 1 1 d . . . . .
C4 C 0.8271(8) 0.5323(5) 0.6783(5) 0.0249(18) Uani 1 1 d . . . . .
C5 C 0.7865(8) 0.6073(5) 0.6467(5) 0.0225(17) Uani 1 1 d . . . . .
C6 C 0.8765(8) 0.6842(5) 0.6506(5) 0.0225(17) Uani 1 1 d . . . . .
C7 C 0.8747(8) 0.7357(5) 0.5871(5) 0.0240(18) Uani 1 1 d . . . . .
C8 C 0.7720(8) 0.6931(5) 0.5064(5) 0.0253(18) Uani 1 1 d . . . . .
C9 C 0.6904(8) 0.6057(6) 0.5071(5) 0.0242(18) Uani 1 1 d . . . . .
C10 C 0.6810(7) 0.5438(6) 0.4248(5) 0.0239(18) Uani 1 1 d . . . . .
C11 C 0.6628(8) 0.4462(5) 0.4134(5) 0.0235(18) Uani 1 1 d . . . . .
C12 C 0.6655(8) 0.4094(5) 0.4826(5) 0.0254(18) Uani 1 1 d . . . . .
C13 C 0.7366(8) 0.3228(5) 0.4639(5) 0.0233(18) Uani 1 1 d . . . . .
C14 C 0.8148(8) 0.2979(5) 0.5250(5) 0.0241(18) Uani 1 1 d . . . . .
C15 C 0.8227(8) 0.3512(6) 0.6133(5) 0.0265(18) Uani 1 1 d . . . . .
C16 C 0.9666(8) 0.3624(5) 0.6428(5) 0.0232(17) Uani 1 1 d . . . . .
C17 C 1.0296(8) 0.4467(5) 0.6924(5) 0.0220(17) Uani 1 1 d . . . . .
C18 C 0.9577(8) 0.5325(5) 0.7103(5) 0.0223(17) Uani 1 1 d . . . . .
C19 C 0.7196(8) 0.3789(5) 0.3448(5) 0.0239(18) Uani 1 1 d . . . . .
C20 C 0.7777(8) 0.3091(5) 0.3839(5) 0.0255(18) Uani 1 1 d . . . . .
C21 C 0.9018(8) 0.2750(5) 0.3672(5) 0.0246(18) Uani 1 1 d . . . . .
C22 C 0.9841(8) 0.2498(5) 0.4293(5) 0.0237(18) Uani 1 1 d . . . . .
C23 C 0.9426(8) 0.2649(5) 0.5074(5) 0.0251(18) Uani 1 1 d . . . . .
C24 C 1.0371(8) 0.3041(5) 0.5815(5) 0.0239(18) Uani 1 1 d . . . . .
C25 C 1.1704(8) 0.3292(5) 0.5727(5) 0.0238(18) Uani 1 1 d . . . . .
C26 C 1.2328(8) 0.4158(5) 0.6244(5) 0.0229(17) Uani 1 1 d . . . . .
C27 C 1.1656(8) 0.4718(5) 0.6852(5) 0.0248(18) Uani 1 1 d . . . . .
C28 C 1.1871(8) 0.5772(5) 0.7082(5) 0.0248(18) Uani 1 1 d . . . . .
C29 C 1.0505(8) 0.6105(5) 0.7145(5) 0.0245(18) Uani 1 1 d . . . . .
C30 C 1.0110(8) 0.6831(5) 0.6823(5) 0.0224(17) Uani 1 1 d . . . . .
C31 C 0.7635(8) 0.7910(5) 0.5619(5) 0.0261(18) Uani 1 1 d . . . . .
C32 C 0.8081(8) 0.8755(6) 0.5322(6) 0.0289(19) Uani 1 1 d . . . . .
C33 C 0.8869(10) 1.0380(6) 0.5873(6) 0.040(2) Uani 1 1 d . . . . .
H33A H 0.8833 1.0355 0.5281 0.048 Uiso 1 1 calc R U . . .
H33B H 0.9769 1.0640 0.6133 0.048 Uiso 1 1 calc R U . . .
C34 C 0.7840(14) 1.0980(8) 0.6273(8) 0.064(3) Uani 1 1 d . . . . .
H34A H 0.6959 1.0739 0.5989 0.095 Uiso 1 1 calc R U . . .
H34B H 0.8033 1.1627 0.6243 0.095 Uiso 1 1 calc R U . . .
H34C H 0.7850 1.0970 0.6851 0.095 Uiso 1 1 calc R U . . .
C35 C 0.6461(8) 0.8090(6) 0.6123(5) 0.0286(19) Uani 1 1 d . . . . .
C36 C 0.4639(9) 0.9037(7) 0.6401(6) 0.036(2) Uani 1 1 d . . . . .
H36A H 0.4935 0.9510 0.6926 0.043 Uiso 1 1 calc R U . . .
H36B H 0.4191 0.8484 0.6528 0.043 Uiso 1 1 calc R U . . .
C37 C 0.3708(10) 0.9440(8) 0.5885(7) 0.051(3) Uani 1 1 d . . . . .
H37A H 0.4188 0.9941 0.5713 0.076 Uiso 1 1 calc R U . . .
H37B H 0.2980 0.9699 0.6205 0.076 Uiso 1 1 calc R U . . .
H37C H 0.3341 0.8946 0.5398 0.076 Uiso 1 1 calc R U . . .
C38 C 0.7135(8) 0.3636(6) 0.6716(5) 0.0274(19) Uani 1 1 d . . . . .
C39 C 0.7610(8) 0.3769(6) 0.7618(6) 0.033(2) Uani 1 1 d . . . . .
C40 C 0.8513(13) 0.2967(9) 0.8554(7) 0.070(4) Uani 1 1 d D . . . .
H40A H 0.9166 0.3510 0.8808 0.084 Uiso 1 1 calc R U . B 1
H40B H 0.8945 0.2382 0.8553 0.084 Uiso 1 1 calc R U . B 1
C41A C 0.724(3) 0.303(3) 0.906(2) 0.078(10) Uiso 0.5 1 d D . P C 1
H41A H 0.7501 0.3025 0.9625 0.117 Uiso 0.5 1 calc R U P C 1
H41B H 0.6817 0.3611 0.9053 0.117 Uiso 0.5 1 calc R U P C 1
H41C H 0.6598 0.2488 0.8799 0.117 Uiso 0.5 1 calc R U P C 1
C41B C 0.741(3) 0.267(2) 0.8990(19) 0.067(8) Uiso 0.5 1 d D . P C 2
H41D H 0.7755 0.2672 0.9549 0.100 Uiso 0.5 1 calc R U P C 2
H41E H 0.6709 0.3103 0.9017 0.100 Uiso 0.5 1 calc R U P C 2
H41F H 0.7049 0.2031 0.8692 0.100 Uiso 0.5 1 calc R U P C 2
C42 C 0.5807(9) 0.3059(6) 0.6434(6) 0.030(2) Uani 1 1 d . . . . .
C43 C 0.4051(11) 0.2259(8) 0.6906(7) 0.055(3) Uani 1 1 d . . . . .
H43A H 0.3462 0.2444 0.6490 0.066 Uiso 1 1 calc R U . D 1
H43B H 0.4239 0.1595 0.6680 0.066 Uiso 1 1 calc R U . D 1
C44A C 0.339(4) 0.235(3) 0.765(2) 0.076(10) Uiso 0.4 1 d . . P E 1
H44A H 0.2556 0.1950 0.7532 0.114 Uiso 0.4 1 calc R U P E 1
H44B H 0.3973 0.2162 0.8063 0.114 Uiso 0.4 1 calc R U P E 1
H44C H 0.3197 0.3009 0.7873 0.114 Uiso 0.4 1 calc R U P E 1
C44B C 0.401(2) 0.1758(17) 0.7570(14) 0.070(6) Uiso 0.6 1 d . . P E 2
H44D H 0.3186 0.1344 0.7476 0.105 Uiso 0.6 1 calc R U P E 2
H44E H 0.4780 0.1381 0.7562 0.105 Uiso 0.6 1 calc R U P E 2
H44F H 0.4033 0.2219 0.8106 0.105 Uiso 0.6 1 calc R U P E 2
C45 C 0.6863(8) 0.3618(6) 0.2527(5) 0.0247(18) Uani 1 1 d . . . . .
C46 C 0.5733(9) 0.4084(6) 0.2213(6) 0.034(2) Uani 1 1 d . . . . .
C47 C 0.4346(10) 0.3987(7) 0.0964(6) 0.039(2) Uani 1 1 d . . . . .
H47A H 0.4693 0.4065 0.0451 0.047 Uiso 1 1 calc R U . . .
H47B H 0.4135 0.4610 0.1296 0.047 Uiso 1 1 calc R U . . .
C48 C 0.3100(10) 0.3314(6) 0.0760(6) 0.037(2) Uani 1 1 d . . . . .
C49 C 0.2630(11) 0.2916(8) -0.0041(7) 0.051(3) Uani 1 1 d . . . . .
H49 H 0.3087 0.3050 -0.0475 0.062 Uiso 1 1 calc R U . . .
C50 C 0.1472(11) 0.2312(9) -0.0216(7) 0.057(3) Uani 1 1 d . . . . .
H50 H 0.1162 0.2028 -0.0775 0.068 Uiso 1 1 calc R U . . .
C51 C 0.1272(10) 0.2513(8) 0.1141(7) 0.049(3) Uani 1 1 d . . . . .
H51 H 0.0800 0.2385 0.1571 0.059 Uiso 1 1 calc R U . . .
C52 C 0.2418(10) 0.3099(7) 0.1361(6) 0.045(3) Uani 1 1 d . . . . .
H52 H 0.2731 0.3351 0.1924 0.054 Uiso 1 1 calc R U . . .
C53 C 0.7110(8) 0.2662(6) 0.1959(5) 0.0276(19) Uani 1 1 d . . . . .
C54 C 0.6617(9) 0.1011(6) 0.1753(6) 0.035(2) Uani 1 1 d . . . . .
H54A H 0.6966 0.0676 0.2151 0.042 Uiso 1 1 calc R U . . .
H54B H 0.7278 0.1007 0.1348 0.042 Uiso 1 1 calc R U . . .
C55 C 0.5316(10) 0.0513(6) 0.1315(5) 0.032(2) Uani 1 1 d . . . . .
C56 C 0.4146(10) 0.0943(7) 0.1340(6) 0.040(2) Uani 1 1 d . . . . .
H56 H 0.4118 0.1580 0.1642 0.048 Uiso 1 1 calc R U . . .
C57 C 0.3003(10) 0.0429(7) 0.0914(7) 0.045(3) Uani 1 1 d . . . . .
H57 H 0.2194 0.0731 0.0938 0.054 Uiso 1 1 calc R U . . .
C58 C 0.4114(10) -0.0879(6) 0.0462(6) 0.040(2) Uani 1 1 d . . . . .
H58 H 0.4108 -0.1517 0.0152 0.048 Uiso 1 1 calc R U . . .
C59 C 0.5308(10) -0.0433(6) 0.0877(6) 0.037(2) Uani 1 1 d . . . . .
H59 H 0.6095 -0.0759 0.0864 0.044 Uiso 1 1 calc R U . . .
C60 C 0.821(3) 0.4842(14) 0.0842(12) 0.045(5) Uani 0.5 1 d . . P . .
C61 C 0.939(2) 0.4388(12) 0.0805(10) 0.035(5) Uani 0.5 1 d . . P . .
H61A H 0.9819 0.4442 0.0316 0.052 Uiso 0.5 1 calc R U P . .
H61B H 0.9189 0.3723 0.0775 0.052 Uiso 0.5 1 calc R U P . .
H61C H 0.9992 0.4682 0.1299 0.052 Uiso 0.5 1 calc R U P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0080 0.0038 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0145 0.0076 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0240 0.0138 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.2293 2.1516 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1820 0.2009 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0370 0.0231 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N2 161.9(3) . 2
N1 Ag1 F6 95.1(3) . .
N2 Ag1 F6 102.9(3) 2 .
N1 Ag1 O16 95.1(3) . .
N2 Ag1 O16 102.9(3) 2 .
O13 P1 O16 122.7(8) . .
O13 P1 O14 108.8(9) . .
O16 P1 O14 110.7(6) . .
O13 P1 O15 107.6(9) . .
O16 P1 O15 105.0(6) . .
O14 P1 O15 99.6(8) . .
F6 P1 F3 140.8(14) . .
F6 P1 F1 95.8(11) . .
F3 P1 F1 116.1(18) . .
F6 P1 F5 85(2) . .
F3 P1 F5 64(2) . .
F1 P1 F5 177(2) . .
F6 P1 F4 81.6(17) . .
F3 P1 F4 77(2) . .
F1 P1 F4 89.6(19) . .
F5 P1 F4 94(3) . .
F6 P1 F2 103.8(12) . .
F3 P1 F2 95.4(18) . .
F1 P1 F2 95.7(16) . .
F5 P1 F2 81(2) . .
F4 P1 F2 172(2) . .
P1 O16 Ag1 149.3(6) . .
P1 F3 F5 58.4(14) . .
P1 F5 F3 57.3(14) . .
P1 F6 Ag1 149.3(6) . .
C32 O2 C33 117.9(7) . .
C35 O4 C36 116.8(7) . .
C39 O6 C40 116.2(8) . .
C42 O8 C43 115.3(7) . .
C46 O10 C47 117.9(7) . .
C53 O12 C54 117.5(7) . .
C51 N1 C50 115.8(9) . .
C51 N1 Ag1 123.2(7) . .
C50 N1 Ag1 120.9(6) . .
C57 N2 C58 116.9(8) . .
C57 N2 Ag1 116.3(7) . 2
C58 N2 Ag1 126.5(6) . 2
C9 C1 C2 121.5(7) . .
C9 C1 C5 121.5(7) . .
C2 C1 C5 107.3(7) . .
C12 C2 C1 117.8(8) . .
C12 C2 C3 123.3(7) . .
C1 C2 C3 108.5(7) . .
C4 C3 C2 105.3(7) . .
C4 C3 C38 123.7(7) . .
C2 C3 C38 128.5(7) . .
C4 C3 C15 115.7(7) . .
C2 C3 C15 115.8(7) . .
C38 C3 C15 57.9(5) . .
C18 C4 C5 120.4(7) . .
C18 C4 C3 123.0(7) . .
C5 C4 C3 109.0(7) . .
C6 C5 C4 120.3(7) . .
C6 C5 C1 120.3(7) . .
C4 C5 C1 108.6(7) . .
C5 C6 C30 118.9(7) . .
C5 C6 C7 123.0(7) . .
C30 C6 C7 108.8(7) . .
C6 C7 C22 106.0(7) . 2_766
C6 C7 C31 127.8(7) . .
C22 C7 C31 123.6(7) 2_766 .
C6 C7 C8 116.5(7) . .
C22 C7 C8 115.2(7) 2_766 .
C31 C7 C8 57.7(5) . .
C25 C8 C9 105.1(7) 2_766 .
C25 C8 C31 125.7(7) 2_766 .
C9 C8 C31 126.8(7) . .
C25 C8 C7 116.4(7) 2_766 .
C9 C8 C7 114.7(7) . .
C31 C8 C7 58.2(5) . .
C1 C9 C10 119.5(7) . .
C1 C9 C8 123.5(7) . .
C10 C9 C8 107.4(7) . .
C11 C10 C9 119.5(8) . .
C11 C10 C26 121.5(7) . 2_766
C9 C10 C26 108.8(7) . 2_766
C10 C11 C12 119.6(7) . .
C10 C11 C19 121.5(7) . .
C12 C11 C19 109.1(7) . .
C2 C12 C11 121.6(7) . .
C2 C12 C13 120.6(7) . .
C11 C12 C13 108.2(7) . .
C14 C13 C20 120.8(7) . .
C14 C13 C12 121.1(7) . .
C20 C13 C12 107.9(7) . .
C13 C14 C23 118.9(8) . .
C13 C14 C15 122.8(7) . .
C23 C14 C15 108.3(7) . .
C16 C15 C14 105.6(7) . .
C16 C15 C38 122.6(7) . .
C14 C15 C38 128.8(7) . .
C16 C15 C3 116.0(6) . .
C14 C15 C3 116.1(7) . .
C38 C15 C3 58.7(5) . .
C17 C16 C24 119.5(7) . .
C17 C16 C15 122.9(7) . .
C24 C16 C15 108.7(7) . .
C16 C17 C27 120.3(7) . .
C16 C17 C18 120.3(7) . .
C27 C17 C18 108.7(7) . .
C4 C18 C29 119.9(7) . .
C4 C18 C17 121.3(7) . .
C29 C18 C17 108.1(7) . .
C20 C19 C11 104.2(7) . .
C20 C19 C45 124.1(7) . .
C11 C19 C45 128.6(7) . .
C20 C19 C28 116.3(7) . 2_766
C11 C19 C28 116.6(6) . 2_766
C45 C19 C28 59.0(5) . 2_766
C21 C20 C13 119.6(8) . .
C21 C20 C19 122.6(8) . .
C13 C20 C19 109.5(7) . .
C20 C21 C22 120.5(8) . .
C20 C21 C30 120.3(7) . 2_766
C22 C21 C30 108.1(7) . 2_766
C23 C22 C21 118.9(7) . .
C23 C22 C7 123.4(7) . 2_766
C21 C22 C7 108.0(7) . 2_766
C22 C23 C14 121.1(7) . .
C22 C23 C24 121.2(7) . .
C14 C23 C24 108.3(7) . .
C25 C24 C16 120.6(7) . .
C25 C24 C23 119.8(8) . .
C16 C24 C23 107.9(7) . .
C24 C25 C26 118.8(7) . .
C24 C25 C8 123.2(7) . 2_766
C26 C25 C8 109.9(7) . 2_766
C27 C26 C25 120.8(7) . .
C27 C26 C10 121.7(7) . 2_766
C25 C26 C10 107.5(7) . 2_766
C26 C27 C17 119.8(7) . .
C26 C27 C28 121.6(8) . .
C17 C27 C28 108.4(7) . .
C29 C28 C27 104.7(7) . .
C29 C28 C45 123.9(7) . 2_766
C27 C28 C45 128.0(7) . 2_766
C29 C28 C19 116.7(7) . 2_766
C27 C28 C19 116.7(7) . 2_766
C45 C28 C19 58.8(5) 2_766 2_766
C30 C29 C18 119.6(7) . .
C30 C29 C28 122.1(8) . .
C18 C29 C28 109.1(7) . .
C29 C30 C6 120.8(7) . .
C29 C30 C21 121.2(7) . 2_766
C6 C30 C21 108.0(7) . 2_766
C35 C31 C8 118.3(7) . .
C35 C31 C32 112.3(7) . .
C8 C31 C32 119.0(7) . .
C35 C31 C7 119.7(7) . .
C8 C31 C7 64.1(5) . .
C32 C31 C7 115.7(7) . .
O1 C32 O2 126.3(8) . .
O1 C32 C31 126.1(8) . .
O2 C32 C31 107.6(8) . .
O2 C33 C34 107.5(8) . .
O2 C33 H33A 110.2 . .
C34 C33 H33A 110.2 . .
O2 C33 H33B 110.2 . .
C34 C33 H33B 110.2 . .
H33A C33 H33B 108.5 . .
C33 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C33 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
O3 C35 O4 125.2(8) . .
O3 C35 C31 124.4(8) . .
O4 C35 C31 110.4(8) . .
O4 C36 C37 107.7(8) . .
O4 C36 H36A 110.2 . .
C37 C36 H36A 110.2 . .
O4 C36 H36B 110.2 . .
C37 C36 H36B 110.2 . .
H36A C36 H36B 108.5 . .
C36 C37 H37A 109.5 . .
C36 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C36 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C15 C38 C42 118.8(7) . .
C15 C38 C39 115.2(7) . .
C42 C38 C39 114.7(7) . .
C15 C38 C3 63.5(6) . .
C42 C38 C3 117.9(7) . .
C39 C38 C3 117.5(7) . .
O5 C39 O6 125.1(9) . .
O5 C39 C38 125.9(8) . .
O6 C39 C38 109.0(8) . .
O6 C40 C41B 112.0(15) . .
O6 C40 C41A 107.2(15) . .
O6 C40 H40A 110.3 . .
C41A C40 H40A 110.3 . .
O6 C40 H40B 110.3 . .
C41A C40 H40B 110.3 . .
H40A C40 H40B 108.5 . .
C40 C41A H41A 109.5 . .
C40 C41A H41B 109.5 . .
H41A C41A H41B 109.5 . .
C40 C41A H41C 109.5 . .
H41A C41A H41C 109.5 . .
H41B C41A H41C 109.5 . .
C40 C41B H41D 109.5 . .
C40 C41B H41E 109.5 . .
H41D C41B H41E 109.5 . .
C40 C41B H41F 109.5 . .
H41D C41B H41F 109.5 . .
H41E C41B H41F 109.5 . .
O7 C42 O8 126.2(8) . .
O7 C42 C38 125.1(8) . .
O8 C42 C38 108.7(7) . .
C44A C43 O8 109.7(17) . .
O8 C43 C44B 106.4(12) . .
C44A C43 H43A 109.7 . .
O8 C43 H43A 109.7 . .
C44A C43 H43B 109.7 . .
O8 C43 H43B 109.7 . .
H43A C43 H43B 108.2 . .
C43 C44A H44A 109.5 . .
C43 C44A H44B 109.5 . .
H44A C44A H44B 109.5 . .
C43 C44A H44C 109.5 . .
H44A C44A H44C 109.5 . .
H44B C44A H44C 109.5 . .
C43 C44B H44D 109.5 . .
C43 C44B H44E 109.5 . .
H44D C44B H44E 109.5 . .
C43 C44B H44F 109.5 . .
H44D C44B H44F 109.5 . .
H44E C44B H44F 109.5 . .
C46 C45 C19 119.8(7) . .
C46 C45 C28 117.9(7) . 2_766
C19 C45 C28 62.2(5) . 2_766
C46 C45 C53 114.1(7) . .
C19 C45 C53 118.7(7) . .
C28 C45 C53 114.1(7) 2_766 .
O9 C46 O10 125.7(8) . .
O9 C46 C45 125.9(8) . .
O10 C46 C45 108.4(7) . .
O10 C47 C48 108.6(8) . .
O10 C47 H47A 110.0 . .
C48 C47 H47A 110.0 . .
O10 C47 H47B 110.0 . .
C48 C47 H47B 110.0 . .
H47A C47 H47B 108.4 . .
C52 C48 C49 118.4(10) . .
C52 C48 C47 121.5(9) . .
C49 C48 C47 120.1(10) . .
C48 C49 C50 119.2(11) . .
C48 C49 H49 120.4 . .
C50 C49 H49 120.4 . .
N1 C50 C49 122.6(10) . .
N1 C50 H50 118.7 . .
C49 C50 H50 118.7 . .
N1 C51 C52 124.9(11) . .
N1 C51 H51 117.6 . .
C52 C51 H51 117.6 . .
C48 C52 C51 119.0(9) . .
C48 C52 H52 120.5 . .
C51 C52 H52 120.5 . .
O11 C53 O12 125.8(8) . .
O11 C53 C45 124.6(8) . .
O12 C53 C45 109.5(7) . .
O12 C54 C55 110.4(7) . .
O12 C54 H54A 109.6 . .
C55 C54 H54A 109.6 . .
O12 C54 H54B 109.6 . .
C55 C54 H54B 109.6 . .
H54A C54 H54B 108.1 . .
C56 C55 C59 119.0(9) . .
C56 C55 C54 122.8(8) . .
C59 C55 C54 118.3(8) . .
C55 C56 C57 118.6(9) . .
C55 C56 H56 120.7 . .
C57 C56 H56 120.7 . .
N2 C57 C56 124.0(10) . .
N2 C57 H57 118.0 . .
C56 C57 H57 118.0 . .
N2 C58 C59 123.6(9) . .
N2 C58 H58 118.2 . .
C59 C58 H58 118.2 . .
C58 C59 C55 117.8(9) . .
C58 C59 H59 121.1 . .
C55 C59 H59 121.1 . .
N3 C60 C61 178(2) . .
C60 C61 H61A 109.5 . .
C60 C61 H61B 109.5 . .
H61A C61 H61B 109.5 . .
C60 C61 H61C 109.5 . .
H61A C61 H61C 109.5 . .
H61B C61 H61C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.175(8) .
Ag1 N2 2.195(8) 2
Ag1 F6 2.530(8) .
Ag1 O16 2.530(8) .
P1 O13 1.410(14) .
P1 F6 1.479(8) .
P1 O16 1.479(8) .
P1 O14 1.505(11) .
P1 O15 1.511(9) .
P1 F3 1.543(18) .
P1 F1 1.553(17) .
P1 F5 1.56(2) .
P1 F4 1.591(19) .
P1 F2 1.604(17) .
F3 F5 1.65(6) .
O1 C32 1.193(11) .
O2 C32 1.331(10) .
O2 C33 1.473(10) .
O3 C35 1.214(11) .
O4 C35 1.318(10) .
O4 C36 1.467(10) .
O5 C39 1.195(11) .
O6 C39 1.325(11) .
O6 C40 1.465(13) .
O7 C42 1.185(10) .
O8 C42 1.336(11) .
O8 C43 1.473(11) .
O9 C46 1.188(11) .
O10 C46 1.350(11) .
O10 C47 1.463(11) .
O11 C53 1.196(10) .
O12 C53 1.349(10) .
O12 C54 1.446(9) .
N1 C51 1.320(13) .
N1 C50 1.348(14) .
N2 C57 1.329(12) .
N2 C58 1.340(13) .
N2 Ag1 2.195(8) 2
N3 C60 1.15(3) .
C1 C9 1.367(12) .
C1 C2 1.447(11) .
C1 C5 1.474(11) .
C2 C12 1.395(12) .
C2 C3 1.483(12) .
C3 C4 1.479(10) .
C3 C38 1.531(12) .
C3 C15 1.604(11) .
C4 C18 1.387(11) .
C4 C5 1.417(12) .
C5 C6 1.399(11) .
C6 C30 1.425(11) .
C6 C7 1.467(12) .
C7 C22 1.485(11) 2_766
C7 C31 1.524(11) .
C7 C8 1.613(11) .
C8 C25 1.463(12) 2_766
C8 C9 1.494(11) .
C8 C31 1.517(11) .
C9 C10 1.445(11) .
C10 C11 1.405(11) .
C10 C26 1.452(12) 2_766
C11 C12 1.410(12) .
C11 C19 1.491(11) .
C12 C13 1.475(11) .
C13 C14 1.391(11) .
C13 C20 1.410(12) .
C14 C23 1.429(11) .
C14 C15 1.490(11) .
C15 C16 1.485(11) .
C15 C38 1.518(12) .
C16 C17 1.396(11) .
C16 C24 1.426(11) .
C17 C27 1.424(11) .
C17 C18 1.470(11) .
C18 C29 1.426(11) .
C19 C20 1.487(12) .
C19 C45 1.519(11) .
C19 C28 1.571(12) 2_766
C20 C21 1.396(12) .
C21 C22 1.428(12) .
C21 C30 1.474(12) 2_766
C22 C23 1.381(12) .
C22 C7 1.485(11) 2_766
C23 C24 1.483(11) .
C24 C25 1.404(11) .
C25 C26 1.429(10) .
C25 C8 1.463(12) 2_766
C26 C27 1.387(11) .
C26 C10 1.452(12) 2_766
C27 C28 1.503(11) .
C28 C29 1.491(11) .
C28 C45 1.522(11) 2_766
C28 C19 1.571(12) 2_766
C29 C30 1.388(12) .
C30 C21 1.474(12) 2_766
C31 C35 1.505(12) .
C31 C32 1.518(12) .
C33 C34 1.489(15) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C36 C37 1.488(14) .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C38 C42 1.522(11) .
C38 C39 1.523(12) .
C40 C41B 1.485(18) .
C40 C41A 1.589(18) .
C40 H40A 0.9900 .
C40 H40B 0.9900 .
C41A H41A 0.9800 .
C41A H41B 0.9800 .
C41A H41C 0.9800 .
C41B H41D 0.9800 .
C41B H41E 0.9800 .
C41B H41F 0.9800 .
C43 C44A 1.45(4) .
C43 C44B 1.50(2) .
C43 H43A 0.9900 .
C43 H43B 0.9900 .
C44A H44A 0.9800 .
C44A H44B 0.9800 .
C44A H44C 0.9800 .
C44B H44D 0.9800 .
C44B H44E 0.9800 .
C44B H44F 0.9800 .
C45 C46 1.499(12) .
C45 C28 1.522(11) 2_766
C45 C53 1.532(11) .
C47 C48 1.518(13) .
C47 H47A 0.9900 .
C47 H47B 0.9900 .
C48 C52 1.360(14) .
C48 C49 1.366(14) .
C49 C50 1.394(14) .
C49 H49 0.9500 .
C50 H50 0.9500 .
C51 C52 1.371(14) .
C51 H51 0.9500 .
C52 H52 0.9500 .
C54 C55 1.509(12) .
C54 H54A 0.9900 .
C54 H54B 0.9900 .
C55 C56 1.370(13) .
C55 C59 1.401(12) .
C56 C57 1.386(13) .
C56 H56 0.9500 .
C57 H57 0.9500 .
C58 C59 1.387(13) .
C58 H58 0.9500 .
C59 H59 0.9500 .
C60 C61 1.40(3) .
C61 H61A 0.9800 .
C61 H61B 0.9800 .
C61 H61C 0.9800 .
