#------------------------------------------------------------------------------
#$Date: 2015-12-09 16:29:51 +0200 (Wed, 09 Dec 2015) $
#$Revision: 171207 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/67/7036791.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7036791
loop_
_publ_author_name
'Chan, Chung Ying'
'Barnard, Peter J.'
_publ_section_title
;
 Rhenium complexes of bidentate, bis-bidentate and tridentate
 N-heterocyclic carbene ligands.
;
_journal_issue                   44
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              19126
_journal_page_last               19140
_journal_paper_doi               10.1039/c5dt03295d
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         '2(C15 H13 Cl N4 O3 Re), C3 H6 O, C H4 O'
_chemical_formula_sum            'C34 H36 Cl2 N8 O8 Re2'
_chemical_formula_weight         1128.01
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_date             2015-07-07
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_audit_update_record
;
2015-08-20 deposited with the CCDC.
2015-10-07 downloaded from the CCDC.
;
_cell_angle_alpha                96.224(3)
_cell_angle_beta                 93.276(3)
_cell_angle_gamma                100.399(2)
_cell_formula_units_Z            2
_cell_length_a                   9.4195(3)
_cell_length_b                   13.0035(3)
_cell_length_c                   16.2478(6)
_cell_measurement_temperature    172.9
_cell_volume                     1939.91(11)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      172.9
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.876
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0268
_diffrn_reflns_av_unetI/netI     0.0420
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.876
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            20675
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.876
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.298
_diffrn_reflns_theta_min         2.827
_exptl_absorpt_coefficient_mu    6.432
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.38332
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.931
_exptl_crystal_description       plate
_exptl_crystal_F_000             1088
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.174
_refine_diff_density_min         -1.264
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     495
_refine_ls_number_reflns         10178
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0403
_refine_ls_R_factor_gt           0.0284
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0255P)²+0.7181P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0591
_refine_ls_wR_factor_ref         0.0648
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8363
_reflns_number_total             10178
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt03295d2.cif
_cod_data_source_block           trans-trans-16
_cod_depositor_comments
'Adding full bibliography for 7036787--7036794.cif.'
_cod_original_cell_volume        1939.91(10)
_cod_database_code               7036791
_shelxl_version_number           2013-2
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Ternary CH refined with riding coordinates:
 C24(H24), C23(H23)
2.b Aromatic/amide H refined with riding coordinates:
 C9(H9), C17(H17), C26(H26), C30(H30), C27(H27), C29(H29), C20(H20), C10(H10),
 C5(H5), C21(H21), C16(H16), C6(H6)
2.c Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C7(H7A,H7B,H7C), C18(H18A,H18B,H18C), C22(H22A,H22B,
 H22C), C32(H32A,H32B,H32C), C33(H33A,H33B,H33C), C34(H34A,H34B,H34C)
2.d Idealised tetrahedral OH refined as rotating group:
 O8(H8)
;
_olex2_date_sample_data_collection 2013-10-28
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Re1 Re 0.68145(2) 0.26386(2) 0.33487(2) 0.02130(4) Uani 1 1 d .
Re2 Re 0.76288(2) 0.24841(2) 0.91047(2) 0.02319(5) Uani 1 1 d .
Cl1 Cl 0.62867(11) 0.43239(7) 0.28651(6) 0.0326(2) Uani 1 1 d .
Cl2 Cl 0.83541(14) 0.15312(9) 0.78005(7) 0.0457(3) Uani 1 1 d .
O3 O 0.7594(3) 0.0635(2) 0.39042(19) 0.0377(7) Uani 1 1 d .
N5 N 0.5098(3) 0.3191(2) 0.80749(19) 0.0235(6) Uani 1 1 d .
C8 C 0.6099(4) 0.3261(3) 0.4507(2) 0.0245(8) Uani 1 1 d .
C3 C 0.7249(4) 0.1377(3) 0.3710(2) 0.0248(8) Uani 1 1 d .
C14 C 0.7111(4) 0.3211(3) 1.0079(3) 0.0291(8) Uani 1 1 d .
C1 C 0.8843(5) 0.3196(3) 0.3633(3) 0.0319(9) Uani 1 1 d .
C12 C 0.9491(5) 0.2601(3) 0.9714(3) 0.0368(10) Uani 1 1 d .
N1 N 0.3539(3) 0.1832(2) 0.3669(2) 0.0309(8) Uani 1 1 d .
N6 N 0.4631(4) 0.1523(2) 0.7991(2) 0.0296(7) Uani 1 1 d .
C13 C 0.7008(5) 0.1176(3) 0.9565(3) 0.0340(9) Uani 1 1 d .
C28 C 0.5365(4) 0.4635(3) 0.9221(2) 0.0223(7) Uani 1 1 d .
N2 N 0.3634(4) 0.1939(2) 0.2372(2) 0.0351(8) Uani 1 1 d .
O6 O 0.6862(4) 0.3628(2) 1.07096(19) 0.0417(8) Uani 1 1 d .
N8 N 0.9501(4) 0.4405(3) 0.8297(2) 0.0342(8) Uani 1 1 d .
N7 N 0.7265(3) 0.4489(2) 0.8234(2) 0.0248(7) Uani 1 1 d .
N4 N 0.6609(4) 0.4176(2) 0.5005(2) 0.0291(7) Uani 1 1 d .
N3 N 0.4886(3) 0.2846(2) 0.4863(2) 0.0277(7) Uani 1 1 d .
C15 C 0.5612(4) 0.2371(3) 0.8357(2) 0.0233(8) Uani 1 1 d .
O5 O 0.6666(4) 0.0404(2) 0.9849(2) 0.0571(9) Uani 1 1 d .
C2 C 0.7385(5) 0.2178(3) 0.2253(3) 0.0330(9) Uani 1 1 d .
C24 C 0.5721(4) 0.4289(3) 0.8342(2) 0.0243(8) Uani 1 1 d .
H24 H 0.5263 0.4715 0.7964 0.029 Uiso 1 1 calc R
C9 C 0.4672(5) 0.3496(3) 0.5564(3) 0.0388(11) Uani 1 1 d .
H9 H 0.3902 0.3374 0.5915 0.047 Uiso 1 1 calc R
C19 C 0.8217(4) 0.3909(3) 0.8513(2) 0.0256(8) Uani 1 1 d .
C17 C 0.3552(5) 0.1815(3) 0.7502(3) 0.0346(9) Uani 1 1 d .
H17 H 0.2763 0.1357 0.7185 0.041 Uiso 1 1 calc R
C25 C 0.4538(4) 0.0897(3) 0.4768(3) 0.0290(9) Uani 1 1 d .
O2 O 0.7794(4) 0.1906(2) 0.1631(2) 0.0521(9) Uani 1 1 d .
C26 C 0.4194(4) -0.0050(3) 0.4250(3) 0.0316(9) Uani 1 1 d .
H26 H 0.3635 -0.0094 0.3738 0.038 Uiso 1 1 calc R
C30 C 0.5325(4) 0.0940(3) 0.5513(3) 0.0320(9) Uani 1 1 d .
H30 H 0.5546 0.1584 0.5873 0.038 Uiso 1 1 calc R
C4 C 0.4495(4) 0.2065(3) 0.3085(3) 0.0278(8) Uani 1 1 d .
C27 C 0.4189(4) 0.4107(3) 0.9561(2) 0.0245(8) Uani 1 1 d .
H27 H 0.3624 0.3487 0.9259 0.029 Uiso 1 1 calc R
O4 O 1.0568(4) 0.2644(3) 1.0099(3) 0.0596(10) Uani 1 1 d .
C29 C 0.6183(4) 0.5537(3) 0.9666(2) 0.0240(8) Uani 1 1 d .
H29 H 0.7002 0.5910 0.9439 0.029 Uiso 1 1 calc R
C23 C 0.3933(4) 0.1854(3) 0.4552(3) 0.0300(9) Uani 1 1 d .
H23 H 0.3021 0.1843 0.4840 0.036 Uiso 1 1 calc R
C11 C 0.7882(5) 0.4946(3) 0.4879(3) 0.0399(11) Uani 1 1 d .
H11A H 0.8758 0.4683 0.5037 0.060 Uiso 1 1 calc GR
H11B H 0.7871 0.5611 0.5223 0.060 Uiso 1 1 calc GR
H11C H 0.7873 0.5061 0.4293 0.060 Uiso 1 1 calc GR
C20 C 0.7961(5) 0.5320(3) 0.7852(3) 0.0340(10) Uani 1 1 d .
H20 H 0.7527 0.5831 0.7608 0.041 Uiso 1 1 calc R
O1 O 1.0069(3) 0.3447(3) 0.3795(2) 0.0536(9) Uani 1 1 d .
C10 C 0.5758(5) 0.4325(3) 0.5649(3) 0.0400(11) Uani 1 1 d .
H10 H 0.5912 0.4906 0.6073 0.048 Uiso 1 1 calc R
C5 C 0.2130(5) 0.1560(3) 0.3309(4) 0.0470(12) Uani 1 1 d .
H5 H 0.1279 0.1363 0.3585 0.056 Uiso 1 1 calc R
C21 C 0.9356(5) 0.5261(3) 0.7896(3) 0.0421(11) Uani 1 1 d .
H21 H 1.0113 0.5724 0.7688 0.051 Uiso 1 1 calc R
C16 C 0.3840(4) 0.2873(3) 0.7565(2) 0.0298(9) Uani 1 1 d .
H16 H 0.3288 0.3312 0.7310 0.036 Uiso 1 1 calc R
C7 C 0.4131(6) 0.2115(4) 0.1551(3) 0.0470(12) Uani 1 1 d .
H7A H 0.4825 0.2782 0.1596 0.070 Uiso 1 1 calc GR
H7B H 0.3300 0.2146 0.1169 0.070 Uiso 1 1 calc GR
H7C H 0.4599 0.1536 0.1340 0.070 Uiso 1 1 calc GR
C18 C 0.4684(5) 0.0424(3) 0.8077(3) 0.0458(12) Uani 1 1 d .
H18A H 0.5663 0.0297 0.7993 0.069 Uiso 1 1 calc GR
H18B H 0.3993 -0.0037 0.7661 0.069 Uiso 1 1 calc GR
H18C H 0.4432 0.0273 0.8634 0.069 Uiso 1 1 calc GR
C6 C 0.2202(5) 0.1629(3) 0.2502(4) 0.0474(12) Uani 1 1 d .
H6 H 0.1410 0.1489 0.2091 0.057 Uiso 1 1 calc R
C22 C 1.0887(5) 0.4083(4) 0.8447(4) 0.0500(13) Uani 1 1 d .
H22A H 1.1210 0.4248 0.9038 0.075 Uiso 1 1 calc GR
H22B H 1.1605 0.4462 0.8119 0.075 Uiso 1 1 calc GR
H22C H 1.0778 0.3324 0.8283 0.075 Uiso 1 1 calc GR
C32 C 0.9764(6) 0.1079(4) 0.5817(4) 0.0600(15) Uani 1 1 d .
H32A H 0.9086 0.0857 0.5323 0.090 Uiso 1 1 calc GR
H32B H 0.9286 0.0867 0.6309 0.090 Uiso 1 1 calc GR
H32C H 1.0611 0.0744 0.5755 0.090 Uiso 1 1 calc GR
C31 C 1.0223(5) 0.2220(4) 0.5913(3) 0.0493(12) Uani 1 1 d .
O7 O 1.1483(5) 0.2605(4) 0.5892(4) 0.1028(18) Uani 1 1 d .
C33 C 0.9115(6) 0.2884(4) 0.6031(4) 0.0626(15) Uani 1 1 d .
H33A H 0.8464 0.2787 0.5525 0.094 Uiso 1 1 calc GR
H33B H 0.9590 0.3626 0.6148 0.094 Uiso 1 1 calc GR
H33C H 0.8557 0.2681 0.6497 0.094 Uiso 1 1 calc GR
O8 O 0.9291(5) 0.9877(4) 0.1962(4) 0.0932(16) Uani 1 1 d .
H8 H 0.9835 0.9488 0.2134 0.140 Uiso 1 1 calc GR
C34 C 0.9181(12) 0.9755(8) 0.1073(6) 0.165(5) Uani 1 1 d .
H34A H 0.8586 1.0236 0.0873 0.248 Uiso 1 1 calc GR
H34B H 0.8732 0.9027 0.0862 0.248 Uiso 1 1 calc GR
H34C H 1.0150 0.9918 0.0875 0.248 Uiso 1 1 calc GR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C8 Re1 Cl1 83.55(9) . .
C8 Re1 C4 81.48(14) . .
C3 Re1 Cl1 178.96(11) . .
C3 Re1 C8 96.91(14) . .
C3 Re1 C1 84.75(16) . .
C3 Re1 C2 88.38(15) . .
C3 Re1 C4 96.34(14) . .
C1 Re1 Cl1 94.28(12) . .
C1 Re1 C8 95.51(15) . .
C1 Re1 C2 86.07(18) . .
C1 Re1 C4 176.89(15) . .
C2 Re1 Cl1 91.18(11) . .
C2 Re1 C8 174.59(15) . .
C2 Re1 C4 96.86(17) . .
C4 Re1 Cl1 84.65(9) . .
C14 Re2 Cl2 179.18(13) . .
C14 Re2 C12 85.14(18) . .
C14 Re2 C13 88.46(17) . .
C14 Re2 C15 97.49(15) . .
C14 Re2 C19 93.73(15) . .
C12 Re2 Cl2 94.37(13) . .
C12 Re2 C13 87.86(18) . .
C12 Re2 C15 176.61(16) . .
C12 Re2 C19 95.71(16) . .
C13 Re2 Cl2 92.17(13) . .
C13 Re2 C15 94.34(16) . .
C13 Re2 C19 175.95(16) . .
C15 Re2 Cl2 82.98(9) . .
C15 Re2 C19 82.01(14) . .
C19 Re2 Cl2 85.66(9) . .
C15 N5 C24 123.9(3) . .
C15 N5 C16 112.8(3) . .
C16 N5 C24 123.1(3) . .
N4 C8 Re1 130.5(3) . .
N4 C8 N3 103.2(3) . .
N3 C8 Re1 126.0(3) . .
O3 C3 Re1 175.5(3) . .
O6 C14 Re2 175.2(4) . .
O1 C1 Re1 174.6(3) . .
O4 C12 Re2 177.1(4) . .
C4 N1 C23 125.0(3) . .
C4 N1 C5 110.8(4) . .
C5 N1 C23 124.2(4) . .
C15 N6 C17 112.0(3) . .
C15 N6 C18 125.4(3) . .
C17 N6 C18 122.6(3) . .
O5 C13 Re2 178.5(4) . .
C27 C28 C24 121.1(3) . .
C27 C28 C29 119.1(3) . .
C29 C28 C24 119.7(3) . .
C4 N2 C7 125.4(4) . .
C4 N2 C6 111.8(4) . .
C6 N2 C7 122.7(4) . .
C19 N8 C21 111.7(3) . .
C19 N8 C22 125.5(4) . .
C21 N8 C22 122.8(4) . .
C19 N7 C24 124.7(3) . .
C19 N7 C20 111.3(3) . .
C20 N7 C24 123.9(3) . .
C8 N4 C11 125.5(3) . .
C8 N4 C10 112.2(3) . .
C10 N4 C11 122.3(3) . .
C8 N3 C9 111.1(3) . .
C8 N3 C23 124.7(3) . .
C9 N3 C23 124.2(3) . .
N5 C15 Re2 125.8(3) . .
N5 C15 N6 102.5(3) . .
N6 C15 Re2 131.5(3) . .
O2 C2 Re1 176.2(4) . .
N5 C24 C28 111.8(3) . .
N5 C24 N7 110.3(3) . .
N7 C24 C28 113.3(3) . .
C10 C9 N3 106.8(4) . .
N8 C19 Re2 131.6(3) . .
N8 C19 N7 103.4(3) . .
N7 C19 Re2 125.0(3) . .
C16 C17 N6 106.6(4) . .
C26 C25 C23 120.5(4) . .
C30 C25 C26 119.3(3) . .
C30 C25 C23 120.0(3) . .
C25 C26 C30 119.7(4) . 2_656
C25 C30 C26 121.0(4) . 2_656
N1 C4 Re1 124.9(3) . .
N2 C4 Re1 131.5(3) . .
N2 C4 N1 103.4(3) . .
C28 C27 C29 120.9(3) . 2_667
C27 C29 C28 120.0(3) 2_667 .
N1 C23 C25 113.9(3) . .
N3 C23 N1 109.7(3) . .
N3 C23 C25 112.9(3) . .
C21 C20 N7 106.3(4) . .
C9 C10 N4 106.7(4) . .
C6 C5 N1 106.7(4) . .
C20 C21 N8 107.3(4) . .
C17 C16 N5 106.0(4) . .
C5 C6 N2 107.2(4) . .
C32 C31 C33 118.6(5) . .
O7 C31 C32 120.1(5) . .
O7 C31 C33 121.3(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Re1 Cl1 2.5277(9) .
Re1 C8 2.159(4) .
Re1 C3 1.905(4) .
Re1 C1 1.928(4) .
Re1 C2 1.952(4) .
Re1 C4 2.179(4) .
Re2 Cl2 2.5287(10) .
Re2 C14 1.888(4) .
Re2 C12 1.937(5) .
Re2 C13 1.940(4) .
Re2 C15 2.169(4) .
Re2 C19 2.178(4) .
O3 C3 1.141(4) .
N5 C15 1.359(4) .
N5 C24 1.451(4) .
N5 C16 1.378(5) .
C8 N4 1.357(5) .
C8 N3 1.361(5) .
C14 O6 1.163(5) .
C1 O1 1.149(5) .
C12 O4 1.150(5) .
N1 C4 1.367(5) .
N1 C23 1.457(5) .
N1 C5 1.388(5) .
N6 C15 1.362(5) .
N6 C17 1.385(5) .
N6 C18 1.460(5) .
C13 O5 1.151(5) .
C28 C24 1.524(5) .
C28 C27 1.372(5) .
C28 C29 1.386(5) .
N2 C4 1.353(5) .
N2 C7 1.466(6) .
N2 C6 1.371(6) .
N8 C19 1.348(5) .
N8 C21 1.373(5) .
N8 C22 1.456(5) .
N7 C24 1.455(5) .
N7 C19 1.360(5) .
N7 C20 1.384(5) .
N4 C11 1.456(5) .
N4 C10 1.372(5) .
N3 C9 1.391(5) .
N3 C23 1.453(5) .
C2 O2 1.145(5) .
C9 C10 1.334(6) .
C17 C16 1.345(5) .
C25 C26 1.390(5) .
C25 C30 1.373(6) .
C25 C23 1.524(5) .
C26 C30 1.399(5) 2_656
C30 C26 1.399(5) 2_656
C27 C29 1.378(5) 2_667
C29 C27 1.378(5) 2_667
C20 C21 1.329(6) .
C5 C6 1.328(7) .
C32 C31 1.458(7) .
C31 O7 1.205(6) .
C31 C33 1.478(7) .
O8 C34 1.433(9) .
