#------------------------------------------------------------------------------
#$Date: 2016-04-05 20:48:34 +0300 (Tue, 05 Apr 2016) $
#$Revision: 181730 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/73/7037335.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7037335
loop_
_publ_author_name
'Honacker, Christian'
'Qu, Zheng-Wang'
'Tannert, Jens'
'Layh, Marcus'
'Hepp, Alexander'
'Grimme, Stefan'
'Uhl, Werner'
_publ_section_title
;
 Functionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond
 activation, Ge-H bond formation and chlorine-tert-butyl exchange via a
 transient germyl cation.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6159
_journal_page_last               6174
_journal_paper_doi               10.1039/c5dt03918e
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C52 H84 Al2 Cl2 Ge2'
_chemical_formula_weight         979.23
_chemical_name_systematic
;
 ?
;
_chemical_properties_physical    'Air-sensitive, Hygroscopic'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2015-09-30 deposited with the CCDC.
2015-11-19 downloaded from the CCDC.
;
_cell_angle_alpha                109.175(2)
_cell_angle_beta                 96.345(2)
_cell_angle_gamma                100.563(2)
_cell_formula_units_Z            1
_cell_length_a                   9.1520(3)
_cell_length_b                   11.2250(4)
_cell_length_c                   15.0549(5)
_cell_measurement_reflns_used    9079
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      30.057
_cell_measurement_theta_min      2.611
_cell_volume                     1411.56(9)
_computing_cell_refinement       'Bruker SAINT+'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0287
_diffrn_reflns_av_unetI/netI     0.0448
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            17869
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.028
_diffrn_reflns_theta_min         2.843
_diffrn_source                   microsource
_exptl_absorpt_coefficient_mu    1.220
_exptl_absorpt_correction_T_max  0.7460
_exptl_absorpt_correction_T_min  0.6762
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.152
_exptl_crystal_description       block
_exptl_crystal_F_000             520
_exptl_crystal_size_max          0.450
_exptl_crystal_size_mid          0.110
_exptl_crystal_size_min          0.040
_refine_diff_density_max         0.606
_refine_diff_density_min         -0.338
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     305
_refine_ls_number_reflns         8159
_refine_ls_number_restraints     64
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0531
_refine_ls_R_factor_gt           0.0384
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0430P)²+0.1829P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0839
_refine_ls_wR_factor_ref         0.0891
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6640
_reflns_number_total             8159
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt03918e2.cif
_cod_data_source_block           sadp-1
_cod_depositor_comments
'Adding full bibliography for 7037325--7037335.cif.'
_cod_database_code               7037335
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.610
_shelx_estimated_absorpt_t_max   0.953
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.17716(2) 0.17743(2) 0.31204(2) 0.02185(6) Uani 1 1 d . . . . .
C11 C 0.21946(19) 0.30654(17) 0.25277(13) 0.0258(4) Uani 1 1 d . . . . .
C12 C 0.2643(2) 0.39215(18) 0.22463(15) 0.0317(4) Uani 1 1 d D . . . .
C13 C 0.3288(2) 0.4986(2) 0.19196(19) 0.0439(5) Uani 1 1 d D . . . .
C14 C 0.2241(5) 0.4875(5) 0.1001(4) 0.0830(19) Uani 0.741(7) 1 d D U P A 1
H14A H 0.2132 0.4036 0.0521 0.100 Uiso 0.741(7) 1 calc R U P A 1
H14B H 0.2676 0.5535 0.0769 0.100 Uiso 0.741(7) 1 calc R U P A 1
H14C H 0.1267 0.4986 0.1143 0.100 Uiso 0.741(7) 1 calc R U P A 1
C15 C 0.4814(5) 0.4865(5) 0.1705(5) 0.0716(17) Uani 0.741(7) 1 d D U P A 1
H15A H 0.5478 0.4972 0.2279 0.086 Uiso 0.741(7) 1 calc R U P A 1
H15B H 0.5209 0.5521 0.1459 0.086 Uiso 0.741(7) 1 calc R U P A 1
H15C H 0.4740 0.4023 0.1237 0.086 Uiso 0.741(7) 1 calc R U P A 1
C16 C 0.3376(6) 0.6295(3) 0.2692(4) 0.0781(17) Uani 0.741(7) 1 d D U P A 1
H16A H 0.2386 0.6343 0.2833 0.094 Uiso 0.741(7) 1 calc R U P A 1
H16B H 0.3753 0.6979 0.2469 0.094 Uiso 0.741(7) 1 calc R U P A 1
H16C H 0.4043 0.6384 0.3261 0.094 Uiso 0.741(7) 1 calc R U P A 1
C14A C 0.361(2) 0.4405(11) 0.0905(10) 0.101(7) Uani 0.259(7) 1 d D U P A 2
H14D H 0.2680 0.4068 0.0453 0.121 Uiso 0.259(7) 1 calc R U P A 2
H14E H 0.4117 0.3717 0.0874 0.121 Uiso 0.259(7) 1 calc R U P A 2
H14F H 0.4250 0.5067 0.0755 0.121 Uiso 0.259(7) 1 calc R U P A 2
C15A C 0.2396(17) 0.5929(12) 0.2015(13) 0.081(5) Uani 0.259(7) 1 d D U P A 2
H15D H 0.1358 0.5497 0.1739 0.097 Uiso 0.259(7) 1 calc R U P A 2
H15E H 0.2757 0.6498 0.1690 0.097 Uiso 0.259(7) 1 calc R U P A 2
H15F H 0.2474 0.6425 0.2681 0.097 Uiso 0.259(7) 1 calc R U P A 2
C16A C 0.4850(17) 0.5610(18) 0.2563(16) 0.149(11) Uani 0.259(7) 1 d D U P A 2
H16D H 0.5284 0.6390 0.2461 0.178 Uiso 0.259(7) 1 calc R U P A 2
H16E H 0.5496 0.5016 0.2410 0.178 Uiso 0.259(7) 1 calc R U P A 2
H16F H 0.4747 0.5816 0.3221 0.178 Uiso 0.259(7) 1 calc R U P A 2
C21 C 0.1064(2) 0.27091(17) 0.42709(13) 0.0252(4) Uani 1 1 d . . . . .
C22 C -0.0470(2) 0.24917(18) 0.43163(13) 0.0286(4) Uani 1 1 d . . . . .
H22 H -0.1170 0.1828 0.3801 0.034 Uiso 1 1 calc R U . . .
C23 C -0.0996(2) 0.3219(2) 0.50925(14) 0.0332(4) Uani 1 1 d . . . . .
H23 H -0.2047 0.3051 0.5108 0.040 Uiso 1 1 calc R U . . .
C24 C 0.0004(2) 0.41934(19) 0.58481(14) 0.0342(4) Uani 1 1 d . . . . .
H24 H -0.0357 0.4698 0.6381 0.041 Uiso 1 1 calc R U . . .
C25 C 0.1528(2) 0.44271(19) 0.58229(14) 0.0365(5) Uani 1 1 d . . . . .
H25 H 0.2220 0.5093 0.6341 0.044 Uiso 1 1 calc R U . . .
C26 C 0.2053(2) 0.36920(19) 0.50421(14) 0.0320(4) Uani 1 1 d . . . . .
H26 H 0.3106 0.3862 0.5033 0.038 Uiso 1 1 calc R U . . .
C31 C 0.01156(18) 0.04829(16) 0.21512(12) 0.0218(3) Uani 1 1 d . . . . .
Al1 Al -0.03841(5) 0.09471(5) 0.10303(4) 0.01983(11) Uani 1 1 d . . . . .
Cl1 Cl 0.15605(4) 0.10467(4) 0.02184(3) 0.02567(10) Uani 1 1 d . . . . .
C51 C -0.1799(2) 0.20402(18) 0.09149(14) 0.0308(4) Uani 1 1 d . . . . .
C52 C -0.1490(2) 0.3281(2) 0.17894(16) 0.0418(5) Uani 1 1 d . . . . .
H52A H -0.0502 0.3828 0.1827 0.063 Uiso 1 1 calc R U . . .
H52B H -0.1491 0.3062 0.2368 0.063 Uiso 1 1 calc R U . . .
H55C H -0.2279 0.3751 0.1736 0.063 Uiso 1 1 calc R U . . .
C53 C -0.3378(2) 0.1255(3) 0.0884(3) 0.0708(9) Uani 1 1 d . . . . .
H53A H -0.4119 0.1778 0.0863 0.106 Uiso 1 1 calc R U . . .
H53B H -0.3375 0.1021 0.1456 0.106 Uiso 1 1 calc R U . . .
H53C H -0.3647 0.0464 0.0312 0.106 Uiso 1 1 calc R U . . .
C54 C -0.1799(4) 0.2382(3) 0.00177(19) 0.0710(9) Uani 1 1 d . . . . .
H54A H -0.2585 0.2856 -0.0033 0.107 Uiso 1 1 calc R U . . .
H54B H -0.2003 0.1585 -0.0546 0.107 Uiso 1 1 calc R U . . .
H54C H -0.0810 0.2926 0.0054 0.107 Uiso 1 1 calc R U . . .
C32 C -0.0828(2) -0.05856(17) 0.21561(13) 0.0268(4) Uani 1 1 d D . . . .
H32 H -0.1607 -0.0958 0.1606 0.032 Uiso 1 1 calc R U . . .
C33 C -0.0948(2) -0.13389(19) 0.28264(15) 0.0341(4) Uani 1 1 d D . . . .
C34 C -0.0982(3) -0.2750(2) 0.22191(18) 0.0480(6) Uani 1 1 d D . . . .
H34A H -0.0033 -0.2784 0.1978 0.072 Uiso 1 1 calc R U . . .
H34B H -0.1831 -0.3075 0.1678 0.072 Uiso 1 1 calc R U . . .
H34C H -0.1104 -0.3291 0.2614 0.072 Uiso 1 1 calc R U . . .
C35 C -0.2443(3) -0.1305(3) 0.3186(2) 0.0581(7) Uani 1 1 d D . . . .
H35A H -0.2600 -0.1892 0.3543 0.087 Uiso 1 1 calc R U . . .
H35B H -0.3275 -0.1582 0.2639 0.087 Uiso 1 1 calc R U . . .
H35C H -0.2412 -0.0420 0.3605 0.087 Uiso 1 1 calc R U . . .
C36 C 0.0358(3) -0.0845(2) 0.36679(16) 0.0449(5) Uani 1 1 d D . . . .
H36A H 0.0414 0.0067 0.4037 0.067 Uiso 1 1 calc R U . . .
H36B H 0.1305 -0.0922 0.3432 0.067 Uiso 1 1 calc R U . . .
H36C H 0.0199 -0.1361 0.4078 0.067 Uiso 1 1 calc R U . . .
C41 C 0.3784(2) 0.1354(2) 0.33684(14) 0.0336(4) Uani 1 1 d . . . . .
C42 C 0.4063(3) 0.1112(3) 0.43172(17) 0.0477(6) Uani 1 1 d . . . . .
H42A H 0.3305 0.0353 0.4288 0.072 Uiso 1 1 calc R U . . .
H42B H 0.3986 0.1874 0.4847 0.072 Uiso 1 1 calc R U . . .
H42C H 0.5076 0.0954 0.4419 0.072 Uiso 1 1 calc R U . . .
C43 C 0.3840(3) 0.0159(2) 0.25259(18) 0.0478(6) Uani 1 1 d . . . . .
H43A H 0.3666 0.0330 0.1930 0.072 Uiso 1 1 calc R U . . .
H43B H 0.3055 -0.0582 0.2497 0.072 Uiso 1 1 calc R U . . .
H43C H 0.4835 -0.0038 0.2610 0.072 Uiso 1 1 calc R U . . .
C44 C 0.5042(2) 0.2488(2) 0.34141(18) 0.0462(6) Uani 1 1 d . . . . .
H44A H 0.6024 0.2273 0.3509 0.069 Uiso 1 1 calc R U . . .
H44B H 0.5014 0.3265 0.3948 0.069 Uiso 1 1 calc R U . . .
H44C H 0.4895 0.2652 0.2814 0.069 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C11 Ge1 C21 102.67(8) .
C11 Ge1 C31 100.56(7) .
C21 Ge1 C31 111.97(7) .
C11 Ge1 C41 103.49(8) .
C21 Ge1 C41 114.64(8) .
C31 Ge1 C41 120.23(8) .
C12 C11 Ge1 170.97(16) .
C11 C12 C13 176.8(2) .
C15A C13 C12 113.2(5) .
C12 C13 C15 109.3(2) .
C12 C13 C16 109.7(3) .
C15 C13 C16 110.8(3) .
C15A C13 C16A 110.3(10) .
C12 C13 C16A 104.3(6) .
C15A C13 C14A 113.8(9) .
C12 C13 C14A 109.5(4) .
C16A C13 C14A 105.0(11) .
C12 C13 C14 109.0(2) .
C15 C13 C14 109.3(3) .
C16 C13 C14 108.7(3) .
C13 C14 H14A 109.5 .
C13 C14 H14B 109.5 .
H14A C14 H14B 109.5 .
C13 C14 H14C 109.5 .
H14A C14 H14C 109.5 .
H14B C14 H14C 109.5 .
C13 C15 H15A 109.5 .
C13 C15 H15B 109.5 .
H15A C15 H15B 109.5 .
C13 C15 H15C 109.5 .
H15A C15 H15C 109.5 .
H15B C15 H15C 109.5 .
C13 C16 H16A 109.5 .
C13 C16 H16B 109.5 .
H16A C16 H16B 109.5 .
C13 C16 H16C 109.5 .
H16A C16 H16C 109.5 .
H16B C16 H16C 109.5 .
C13 C14A H14D 109.5 .
C13 C14A H14E 109.5 .
H14D C14A H14E 109.5 .
C13 C14A H14F 109.5 .
H14D C14A H14F 109.5 .
H14E C14A H14F 109.5 .
C13 C15A H15D 109.5 .
C13 C15A H15E 109.5 .
H15D C15A H15E 109.5 .
C13 C15A H15F 109.5 .
H15D C15A H15F 109.5 .
H15E C15A H15F 109.5 .
C13 C16A H16D 109.5 .
C13 C16A H16E 109.5 .
H16D C16A H16E 109.5 .
C13 C16A H16F 109.5 .
H16D C16A H16F 109.5 .
H16E C16A H16F 109.5 .
C22 C21 C26 117.41(17) .
C22 C21 Ge1 120.96(13) .
C26 C21 Ge1 121.42(14) .
C23 C22 C21 121.49(17) .
C23 C22 H22 119.3 .
C21 C22 H22 119.3 .
C22 C23 C24 120.16(19) .
C22 C23 H23 119.9 .
C24 C23 H23 119.9 .
C25 C24 C23 119.56(19) .
C25 C24 H24 120.2 .
C23 C24 H24 120.2 .
C24 C25 C26 120.15(18) .
C24 C25 H25 119.9 .
C26 C25 H25 119.9 .
C25 C26 C21 121.23(18) .
C25 C26 H26 119.4 .
C21 C26 H26 119.4 .
C32 C31 Al1 114.41(13) .
C32 C31 Ge1 131.96(14) .
Al1 C31 Ge1 113.25(9) .
C31 Al1 C51 125.01(8) .
C31 Al1 Cl1 112.31(5) .
C51 Al1 Cl1 116.08(7) .
C31 Al1 Cl1 105.01(5) 2
C51 Al1 Cl1 102.04(6) 2
Cl1 Al1 Cl1 87.03(2) 2
Al1 Cl1 Al1 92.97(2) 2
C54 C51 C52 109.38(19) .
C54 C51 C53 109.4(2) .
C52 C51 C53 106.61(19) .
C54 C51 Al1 112.97(16) .
C52 C51 Al1 111.99(12) .
C53 C51 Al1 106.26(15) .
C51 C52 H52A 109.5 .
C51 C52 H52B 109.5 .
H52A C52 H52B 109.5 .
C51 C52 H55C 109.5 .
H52A C52 H55C 109.5 .
H52B C52 H55C 109.5 .
C51 C53 H53A 109.5 .
C51 C53 H53B 109.5 .
H53A C53 H53B 109.5 .
C51 C53 H53C 109.5 .
H53A C53 H53C 109.5 .
H53B C53 H53C 109.5 .
C51 C54 H54A 109.5 .
C51 C54 H54B 109.5 .
H54A C54 H54B 109.5 .
C51 C54 H54C 109.5 .
H54A C54 H54C 109.5 .
H54B C54 H54C 109.5 .
C31 C32 C33 135.50(17) .
C31 C32 H32 112.3 .
C33 C32 H32 112.3 .
C32 C33 C36 113.71(16) .
C32 C33 C35 108.90(17) .
C36 C33 C35 110.0(2) .
C32 C33 C34 106.10(17) .
C36 C33 C34 109.31(18) .
C35 C33 C34 108.66(19) .
C33 C34 H34A 109.5 .
C33 C34 H34B 109.5 .
H34A C34 H34B 109.5 .
C33 C34 H34C 109.5 .
H34A C34 H34C 109.5 .
H34B C34 H34C 109.5 .
C33 C35 H35A 109.5 .
C33 C35 H35B 109.5 .
H35A C35 H35B 109.5 .
C33 C35 H35C 109.5 .
H35A C35 H35C 109.5 .
H35B C35 H35C 109.5 .
C33 C36 H36A 109.5 .
C33 C36 H36B 109.5 .
H36A C36 H36B 109.5 .
C33 C36 H36C 109.5 .
H36A C36 H36C 109.5 .
H36B C36 H36C 109.5 .
C43 C41 C44 108.56(19) .
C43 C41 C42 110.47(19) .
C44 C41 C42 108.05(17) .
C43 C41 Ge1 107.74(12) .
C44 C41 Ge1 109.19(14) .
C42 C41 Ge1 112.76(14) .
C41 C42 H42A 109.5 .
C41 C42 H42B 109.5 .
H42A C42 H42B 109.5 .
C41 C42 H42C 109.5 .
H42A C42 H42C 109.5 .
H42B C42 H42C 109.5 .
C41 C43 H43A 109.5 .
C41 C43 H43B 109.5 .
H43A C43 H43B 109.5 .
C41 C43 H43C 109.5 .
H43A C43 H43C 109.5 .
H43B C43 H43C 109.5 .
C41 C44 H44A 109.5 .
C41 C44 H44B 109.5 .
H44A C44 H44B 109.5 .
C41 C44 H44C 109.5 .
H44A C44 H44C 109.5 .
H44B C44 H44C 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 C11 1.9408(19) .
Ge1 C21 1.9554(18) .
Ge1 C31 1.9605(16) .
Ge1 C41 2.0091(18) .
C11 C12 1.197(3) .
C12 C13 1.486(3) .
C13 C15A 1.433(9) .
C13 C15 1.488(4) .
C13 C16 1.527(5) .
C13 C16A 1.534(10) .
C13 C14A 1.538(10) .
C13 C14 1.549(5) .
C14 H14A 0.9599 .
C14 H14B 0.9599 .
C14 H14C 0.9599 .
C15 H15A 0.9599 .
C15 H15B 0.9599 .
C15 H15C 0.9599 .
C16 H16A 0.9599 .
C16 H16B 0.9599 .
C16 H16C 0.9599 .
C14A H14D 0.9599 .
C14A H14E 0.9599 .
C14A H14F 0.9599 .
C15A H15D 0.9599 .
C15A H15E 0.9599 .
C15A H15F 0.9599 .
C16A H16D 0.9599 .
C16A H16E 0.9599 .
C16A H16F 0.9599 .
C21 C22 1.393(3) .
C21 C26 1.395(2) .
C22 C23 1.380(3) .
C22 H22 0.9500 .
C23 C24 1.383(3) .
C23 H23 0.9500 .
C24 C25 1.378(3) .
C24 H24 0.9500 .
C25 C26 1.388(3) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C31 C32 1.346(2) .
C31 Al1 1.9552(18) .
Al1 C51 1.9712(18) .
Al1 Cl1 2.2741(7) .
Al1 Cl1 2.3680(6) 2
Cl1 Al1 2.3680(6) 2
C51 C54 1.521(3) .
C51 C52 1.524(3) .
C51 C53 1.536(3) .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H55C 0.9800 .
C53 H53A 0.9800 .
C53 H53B 0.9800 .
C53 H53C 0.9800 .
C54 H54A 0.9800 .
C54 H54B 0.9800 .
C54 H54C 0.9800 .
C32 C33 1.515(3) .
C32 H32 0.9500 .
C33 C36 1.517(3) .
C33 C35 1.528(3) .
C33 C34 1.540(3) .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 H35A 0.9800 .
C35 H35B 0.9800 .
C35 H35C 0.9800 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C41 C43 1.528(3) .
C41 C44 1.529(3) .
C41 C42 1.543(3) .
C42 H42A 0.9800 .
C42 H42B 0.9800 .
C42 H42C 0.9800 .
C43 H43A 0.9800 .
C43 H43B 0.9800 .
C43 H43C 0.9800 .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C26 C21 C22 C23 0.1(3)
Ge1 C21 C22 C23 -174.63(15)
C21 C22 C23 C24 0.2(3)
C22 C23 C24 C25 -0.4(3)
C23 C24 C25 C26 0.2(3)
C24 C25 C26 C21 0.0(3)
C22 C21 C26 C25 -0.2(3)
Ge1 C21 C26 C25 174.49(15)
Al1 C31 C32 C33 179.91(18)
Ge1 C31 C32 C33 -7.8(3)
C31 C32 C33 C36 -5.3(3)
C31 C32 C33 C35 117.8(3)
C31 C32 C33 C34 -125.4(2)
