#------------------------------------------------------------------------------
#$Date: 2016-02-05 01:07:15 +0200 (Fri, 05 Feb 2016) $
#$Revision: 176011 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/77/7037746.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7037746
loop_
_publ_author_name
'Vanicek, S.'
'Kopacka, H.'
'Wurst, K.'
'Vergeiner, S.'
'Kankowski, S.'
'Schur, J.'
'Bildstein, B.'
'Ott, I.'
_publ_section_title
;
 Cobaltoceniumethynyl gold(i) as an unusual heterodinuclear
 bioorganometallic fragment to study the biological properties of alkynyl
 gold complexes.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1345
_journal_page_last               1348
_journal_paper_doi               10.1039/c5dt04796j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C30 H24 Au Co F6 P2'
_chemical_formula_weight         816.33
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-11-10 deposited with the CCDC.
2015-12-22 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 113.927(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   17.1720(3)
_cell_length_b                   23.4197(2)
_cell_length_c                   15.6447(3)
_cell_measurement_reflns_used    20271
_cell_measurement_temperature    233(2)
_cell_measurement_theta_max      26.3
_cell_measurement_theta_min      1.0
_cell_volume                     5751.03(18)
_computing_data_collection       COLLECT
_computing_data_reduction        'DENZO and SCALEPACK'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      233(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'phi- and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0380
_diffrn_reflns_av_sigmaI/netI    0.0266
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            17453
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.25
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.842
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.886
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3152
_exptl_crystal_size_max          0.41
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.21
_refine_diff_density_max         1.597
_refine_diff_density_min         -1.408
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     412
_refine_ls_number_reflns         5016
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0421
_refine_ls_R_factor_gt           0.0335
_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0441P)²+22.5043P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0846
_refine_ls_wR_factor_ref         0.0895
_reflns_number_gt                4209
_reflns_number_total             5016
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt04796j4.cif
_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 7037746--7037747.cif.'
_cod_original_cell_volume        5751.03(16)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7037746
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.085847(12) 0.249787(7) 0.850050(14) 0.04704(10) Uani 1 1 d . . .
Co1 Co -0.17799(4) 0.12325(3) 0.93695(5) 0.05260(19) Uani 1 1 d . . .
P1 P 0.17660(8) 0.31563(5) 0.83515(8) 0.0384(3) Uani 1 1 d . . .
C6 C -0.0804(4) 0.0713(3) 0.9495(4) 0.0664(16) Uani 1 1 d . A .
H6 H -0.0296 0.0670 1.0032 0.080 Uiso 1 1 calc . . .
C7 C -0.1551(5) 0.0391(3) 0.9283(6) 0.083(2) Uani 1 1 d . A .
H7 H -0.1622 0.0093 0.9646 0.099 Uiso 1 1 calc . . .
C8 C -0.2175(5) 0.0595(3) 0.8432(5) 0.082(2) Uani 1 1 d . A .
H8 H -0.2739 0.0464 0.8134 0.098 Uiso 1 1 calc . . .
C9 C -0.1795(4) 0.1032(3) 0.8110(4) 0.0653(15) Uani 1 1 d . A .
H9 H -0.2066 0.1238 0.7551 0.078 Uiso 1 1 calc . . .
C10 C -0.0941(3) 0.1113(2) 0.8764(4) 0.0511(12) Uani 1 1 d . A .
C11 C -0.0364(3) 0.1541(2) 0.8728(4) 0.0552(13) Uani 1 1 d . . .
C12 C 0.0104(3) 0.1905(2) 0.8678(4) 0.0555(13) Uani 1 1 d . A .
C101 C 0.2097(3) 0.36764(19) 0.9287(3) 0.0401(10) Uani 1 1 d . . .
C102 C 0.1463(3) 0.4003(3) 0.9397(4) 0.0590(14) Uani 1 1 d . . .
H102 H 0.0889 0.3951 0.8987 0.071 Uiso 1 1 calc . . .
C103 C 0.1678(4) 0.4399(3) 1.0105(4) 0.0723(17) Uani 1 1 d . . .
H103 H 0.1254 0.4630 1.0160 0.087 Uiso 1 1 calc . . .
C104 C 0.2514(4) 0.4457(2) 1.0735(4) 0.0629(15) Uani 1 1 d . . .
H104 H 0.2655 0.4723 1.1225 0.076 Uiso 1 1 calc . . .
C105 C 0.3139(4) 0.4130(2) 1.0650(4) 0.0581(14) Uani 1 1 d . . .
H105 H 0.3707 0.4171 1.1082 0.070 Uiso 1 1 calc . . .
C106 C 0.2933(3) 0.3737(2) 0.9923(3) 0.0484(11) Uani 1 1 d . . .
H106 H 0.3362 0.3513 0.9865 0.058 Uiso 1 1 calc . . .
C201 C 0.1334(3) 0.35659(19) 0.7269(3) 0.0384(10) Uani 1 1 d . . .
C202 C 0.0966(3) 0.3267(2) 0.6443(3) 0.0493(12) Uani 1 1 d . . .
H202 H 0.0925 0.2867 0.6453 0.059 Uiso 1 1 calc . . .
C203 C 0.0655(3) 0.3554(3) 0.5598(3) 0.0609(14) Uani 1 1 d . . .
H203 H 0.0408 0.3347 0.5038 0.073 Uiso 1 1 calc . . .
C204 C 0.0703(4) 0.4133(3) 0.5568(4) 0.0643(16) Uani 1 1 d . . .
H204 H 0.0499 0.4325 0.4991 0.077 Uiso 1 1 calc . . .
C205 C 0.1049(5) 0.4428(3) 0.6379(4) 0.0767(19) Uani 1 1 d . . .
H205 H 0.1071 0.4828 0.6362 0.092 Uiso 1 1 calc . . .
C206 C 0.1370(4) 0.4151(2) 0.7235(4) 0.0649(16) Uani 1 1 d . . .
H206 H 0.1612 0.4363 0.7791 0.078 Uiso 1 1 calc . . .
C301 C 0.2732(3) 0.28401(19) 0.8350(3) 0.0397(10) Uani 1 1 d . . .
C302 C 0.2939(3) 0.2279(2) 0.8647(4) 0.0523(12) Uani 1 1 d . . .
H302 H 0.2589 0.2069 0.8865 0.063 Uiso 1 1 calc . . .
C303 C 0.3661(4) 0.2030(2) 0.8622(4) 0.0651(15) Uani 1 1 d . . .
H303 H 0.3799 0.1651 0.8823 0.078 Uiso 1 1 calc . . .
C304 C 0.4173(4) 0.2331(3) 0.8308(4) 0.0627(15) Uani 1 1 d . . .
H304 H 0.4658 0.2157 0.8285 0.075 Uiso 1 1 calc . . .
C305 C 0.3983(4) 0.2886(3) 0.8027(4) 0.0649(15) Uani 1 1 d . . .
H305 H 0.4344 0.3093 0.7823 0.078 Uiso 1 1 calc . . .
C306 C 0.3262(3) 0.3144(2) 0.8039(4) 0.0550(13) Uani 1 1 d . . .
H306 H 0.3132 0.3524 0.7837 0.066 Uiso 1 1 calc . . .
C1 C -0.1388(12) 0.1735(10) 1.0513(16) 0.087(7) Uiso 0.50 1 d P A 1
H1 H -0.0827 0.1783 1.0959 0.104 Uiso 0.50 1 calc P B 1
C2 C -0.1978(13) 0.1340(7) 1.0553(11) 0.072(4) Uiso 0.50 1 d P A 1
H2 H -0.1882 0.1069 1.1029 0.086 Uiso 0.50 1 calc P C 1
C3 C -0.2721(10) 0.1415(6) 0.9783(13) 0.067(3) Uiso 0.50 1 d P A 1
H3 H -0.3222 0.1202 0.9639 0.081 Uiso 0.50 1 calc P D 1
C4 C -0.2616(14) 0.1853(9) 0.9251(12) 0.084(5) Uiso 0.50 1 d P A 1
H4 H -0.3038 0.1993 0.8692 0.101 Uiso 0.50 1 calc P E 1
C5 C -0.1790(18) 0.2051(8) 0.9675(18) 0.101(6) Uiso 0.50 1 d P A 1
H5 H -0.1541 0.2339 0.9451 0.122 Uiso 0.50 1 calc P F 1
C1A C -0.1517(13) 0.1594(8) 1.0648(11) 0.069(5) Uiso 0.50 1 d P A 2
H1A H -0.1087 0.1455 1.1202 0.083 Uiso 0.50 1 calc P G 2
C2A C -0.2366(16) 0.1433(9) 1.0253(17) 0.092(6) Uiso 0.50 1 d P A 2
H2A H -0.2620 0.1192 1.0547 0.110 Uiso 0.50 1 calc P H 2
C3A C -0.2803(10) 0.1673(9) 0.9361(13) 0.076(5) Uiso 0.50 1 d P A 2
H3A H -0.3360 0.1590 0.8931 0.091 Uiso 0.50 1 calc P I 2
C4A C -0.2220(10) 0.2072(5) 0.9244(9) 0.052(3) Uiso 0.50 1 d P A 2
H4A H -0.2338 0.2323 0.8738 0.063 Uiso 0.50 1 calc P J 2
C5A C -0.1436(8) 0.2019(5) 1.0030(10) 0.048(3) Uiso 0.50 1 d P A 2
H5A H -0.0940 0.2230 1.0132 0.058 Uiso 0.50 1 calc P K 2
P2 P 0.0000 0.57334(10) 0.7500 0.0578(5) Uani 1 2 d S . .
P3 P 0.5000 0.53412(11) 1.2500 0.0850(9) Uani 1 2 d S . .
F1 F 0.0523(5) 0.5300(3) 0.8218(4) 0.161(3) Uani 1 1 d . . .
F2 F 0.0693(3) 0.5747(2) 0.7080(4) 0.1184(16) Uani 1 1 d . . .
F3 F 0.0478(4) 0.6239(2) 0.8196(4) 0.136(2) Uani 1 1 d . . .
F4 F 0.5000 0.6003(9) 1.2500 0.113(15) Uani 0.50 2 d SP L 1
F5 F 0.5000 0.4630(8) 1.2500 0.173(17) Uani 0.50 2 d SP M 1
F6 F 0.5997(18) 0.5329(16) 1.272(3) 0.178(12) Uani 0.50 1 d P L 1
F7 F 0.521(2) 0.5246(11) 1.3524(16) 0.168(13) Uani 0.50 1 d P L 1
F8 F 0.415(3) 0.532(2) 1.185(3) 0.116(18) Uani 0.25 1 d P . 2
F9 F 0.587(7) 0.538(3) 1.348(4) 0.17(4) Uani 0.25 1 d P . 2
F10 F 0.528(3) 0.571(2) 1.169(2) 0.162(17) Uani 0.25 1 d P . 2
F11 F 0.459(5) 0.529(4) 1.310(4) 0.29(4) Uani 0.25 1 d P . 2
F12 F 0.491(4) 0.592(2) 1.277(4) 0.20(3) Uani 0.25 1 d P . 2
F13 F 0.535(3) 0.4827(9) 1.225(3) 0.146(13) Uani 0.25 1 d P . 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C12 Au1 P1 177.53(16) . .
C12 Au1 Au1 75.64(16) . 2_556
P1 Au1 Au1 106.70(3) . 2_556
C5 Co1 C4 40.7(8) . .
C5 Co1 C8 149.7(9) . .
C4 Co1 C8 117.1(6) . .
C5 Co1 C9 117.7(7) . .
C4 Co1 C9 110.8(5) . .
C8 Co1 C9 41.1(3) . .
C5 Co1 C3 68.3(7) . .
C4 Co1 C3 40.1(7) . .
C8 Co1 C3 108.3(5) . .
C9 Co1 C3 132.0(6) . .
C5 Co1 C6 130.6(8) . .
C4 Co1 C6 170.5(8) . .
C8 Co1 C6 69.1(3) . .
C9 Co1 C6 68.6(3) . .
C3 Co1 C6 147.2(6) . .
C5 Co1 C1 41.6(8) . .
C4 Co1 C1 68.1(8) . .
C8 Co1 C1 167.1(8) . .
C9 Co1 C1 150.6(7) . .
C3 Co1 C1 67.3(7) . .
C6 Co1 C1 107.6(6) . .
C5 Co1 C7 168.7(9) . .
C4 Co1 C7 148.6(8) . .
C8 Co1 C7 41.0(3) . .
C9 Co1 C7 68.5(3) . .
C3 Co1 C7 115.5(5) . .
C6 Co1 C7 40.7(3) . .
C1 Co1 C7 128.6(7) . .
C5 Co1 C2 68.8(7) . .
C4 Co1 C2 67.3(7) . .
C8 Co1 C2 128.8(5) . .
C9 Co1 C2 168.6(6) . .
C3 Co1 C2 39.4(7) . .
C6 Co1 C2 115.3(5) . .
C1 Co1 C2 40.2(7) . .
C7 Co1 C2 106.9(5) . .
C5 Co1 C3A 54.4(8) . .
C4 Co1 C3A 16.9(7) . .
C8 Co1 C3A 109.7(5) . .
C9 Co1 C3A 116.3(6) . .
C3 Co1 C3A 24.7(5) . .
C6 Co1 C3A 171.7(7) . .
C1 Co1 C3A 71.7(7) . .
C7 Co1 C3A 133.2(7) . .
C2 Co1 C3A 58.6(7) . .
C5 Co1 C10 108.8(6) . .
C4 Co1 C10 132.4(7) . .
C8 Co1 C10 69.6(2) . .
C9 Co1 C10 41.0(2) . .
C3 Co1 C10 171.1(6) . .
C6 Co1 C10 41.0(2) . .
C1 Co1 C10 116.6(6) . .
C7 Co1 C10 69.0(2) . .
C2 Co1 C10 148.5(6) . .
C3A Co1 C10 146.9(7) . .
C5 Co1 C1A 51.9(8) . .
C4 Co1 C1A 69.8(7) . .
C8 Co1 C1A 153.7(7) . .
C9 Co1 C1A 164.2(7) . .
C3 Co1 C1A 59.1(6) . .
C6 Co1 C1A 108.0(5) . .
C1 Co1 C1A 13.8(7) . .
C7 Co1 C1A 119.7(6) . .
C2 Co1 C1A 27.0(5) . .
C3A Co1 C1A 69.1(7) . .
C10 Co1 C1A 126.4(6) . .
C101 P1 C301 106.7(2) . .
C101 P1 C201 105.8(2) . .
C301 P1 C201 103.9(2) . .
C101 P1 Au1 112.20(15) . .
C301 P1 Au1 112.86(15) . .
C201 P1 Au1 114.55(15) . .
C7 C6 C10 109.0(6) . .
C7 C6 Co1 70.0(4) . .
C10 C6 Co1 70.4(3) . .
C7 C6 H6 125.5 . .
C10 C6 H6 125.5 . .
Co1 C6 H6 125.7 . .
C6 C7 C8 108.2(5) . .
C6 C7 Co1 69.3(3) . .
C8 C7 Co1 68.9(4) . .
C6 C7 H7 125.9 . .
C8 C7 H7 125.9 . .
Co1 C7 H7 127.5 . .
C9 C8 C7 107.3(6) . .
C9 C8 Co1 69.7(3) . .
C7 C8 Co1 70.1(4) . .
C9 C8 H8 126.3 . .
C7 C8 H8 126.3 . .
Co1 C8 H8 125.4 . .
C8 C9 C10 109.4(5) . .
C8 C9 Co1 69.2(3) . .
C10 C9 Co1 70.4(3) . .
C8 C9 H9 125.3 . .
C10 C9 H9 125.3 . .
Co1 C9 H9 126.6 . .
C9 C10 C6 106.1(5) . .
C9 C10 C11 126.6(5) . .
C6 C10 C11 127.1(5) . .
C9 C10 Co1 68.6(3) . .
C6 C10 Co1 68.6(3) . .
C11 C10 Co1 123.7(4) . .
C12 C11 C10 178.3(6) . .
C11 C12 Au1 176.0(5) . .
C106 C101 C102 119.2(4) . .
C106 C101 P1 123.1(4) . .
C102 C101 P1 117.6(4) . .
C103 C102 C101 120.0(5) . .
C103 C102 H102 120.0 . .
C101 C102 H102 120.0 . .
C102 C103 C104 120.3(5) . .
C102 C103 H103 119.9 . .
C104 C103 H103 119.9 . .
C105 C104 C103 120.3(5) . .
C105 C104 H104 119.9 . .
C103 C104 H104 119.9 . .
C104 C105 C106 120.0(5) . .
C104 C105 H105 120.0 . .
C106 C105 H105 120.0 . .
C101 C106 C105 120.2(5) . .
C101 C106 H106 119.9 . .
C105 C106 H106 119.9 . .
C206 C201 C202 118.7(4) . .
C206 C201 P1 123.7(4) . .
C202 C201 P1 117.6(3) . .
C201 C202 C203 120.2(5) . .
C201 C202 H202 119.9 . .
C203 C202 H202 119.9 . .
C204 C203 C202 120.8(5) . .
C204 C203 H203 119.6 . .
C202 C203 H203 119.6 . .
C205 C204 C203 119.1(5) . .
C205 C204 H204 120.5 . .
C203 C204 H204 120.5 . .
C204 C205 C206 121.2(5) . .
C204 C205 H205 119.4 . .
C206 C205 H205 119.4 . .
C201 C206 C205 119.9(5) . .
C201 C206 H206 120.0 . .
C205 C206 H206 120.0 . .
C306 C301 C302 119.1(4) . .
C306 C301 P1 121.3(4) . .
C302 C301 P1 119.6(3) . .
C303 C302 C301 119.8(5) . .
C303 C302 H302 120.1 . .
C301 C302 H302 120.1 . .
C304 C303 C302 120.6(5) . .
C304 C303 H303 119.7 . .
C302 C303 H303 119.7 . .
C303 C304 C305 120.1(5) . .
C303 C304 H304 120.0 . .
C305 C304 H304 120.0 . .
C304 C305 C306 120.6(5) . .
C304 C305 H305 119.7 . .
C306 C305 H305 119.7 . .
C305 C306 C301 119.8(5) . .
C305 C306 H306 120.1 . .
C301 C306 H306 120.1 . .
C2 C1 C5 107.4(16) . .
C2 C1 Co1 70.4(10) . .
C5 C1 Co1 67.7(11) . .
C2 C1 H1 126.3 . .
C5 C1 H1 126.3 . .
Co1 C1 H1 127.0 . .
C3 C2 C1 108.2(14) . .
C3 C2 Co1 69.7(9) . .
C1 C2 Co1 69.3(9) . .
C3 C2 H2 125.9 . .
C1 C2 H2 125.9 . .
Co1 C2 H2 126.7 . .
C2 C3 C4 109.0(14) . .
C2 C3 Co1 70.9(9) . .
C4 C3 Co1 69.3(9) . .
C2 C3 H3 125.5 . .
C4 C3 H3 125.5 . .
Co1 C3 H3 125.9 . .
C3 C4 C5 108.7(16) . .
C3 C4 Co1 70.6(9) . .
C5 C4 Co1 68.8(11) . .
C3 C4 H4 125.7 . .
C5 C4 H4 125.7 . .
Co1 C4 H4 126.5 . .
C4 C5 C1 106.8(18) . .
C4 C5 Co1 70.5(11) . .
C1 C5 Co1 70.7(11) . .
C4 C5 H5 126.6 . .
C1 C5 H5 126.6 . .
Co1 C5 H5 123.8 . .
C2A C1A C5A 105.1(14) . .
C2A C1A Co1 71.1(10) . .
C5A C1A Co1 70.8(8) . .
C2A C1A H1A 127.5 . .
C5A C1A H1A 127.5 . .
Co1 C1A H1A 122.4 . .
C1A C2A C3A 112.0(18) . .
C1A C2A Co1 69.6(10) . .
C3A C2A Co1 68.6(10) . .
C1A C2A H2A 124.0 . .
C3A C2A H2A 124.0 . .
Co1 C2A H2A 129.7 . .
C2A C3A C4A 105.5(14) . .
C2A C3A Co1 71.3(11) . .
C4A C3A Co1 71.7(8) . .
C2A C3A H3A 127.2 . .
C4A C3A H3A 127.2 . .
Co1 C3A H3A 121.7 . .
C5A C4A C3A 107.4(11) . .
C5A C4A Co1 69.8(6) . .
C3A C4A Co1 67.6(8) . .
C5A C4A H4A 126.3 . .
C3A C4A H4A 126.3 . .
Co1 C4A H4A 127.9 . .
C4A C5A C1A 109.2(11) . .
C4A C5A Co1 70.5(6) . .
C1A C5A Co1 68.5(8) . .
C4A C5A H5A 125.4 . .
C1A C5A H5A 125.4 . .
Co1 C5A H5A 127.1 . .
F1 P2 F1 95.5(7) 2_556 .
F1 P2 F2 90.1(3) 2_556 2_556
F1 P2 F2 91.5(3) . 2_556
F1 P2 F2 91.5(3) 2_556 .
F1 P2 F2 90.1(3) . .
F2 P2 F2 177.7(4) 2_556 .
F1 P2 F3 173.9(4) 2_556 .
F1 P2 F3 90.3(4) . .
F2 P2 F3 88.1(3) 2_556 .
F2 P2 F3 90.2(3) . .
F1 P2 F3 90.3(4) 2_556 2_556
F1 P2 F3 173.9(4) . 2_556
F2 P2 F3 90.2(3) 2_556 2_556
F2 P2 F3 88.1(3) . 2_556
F3 P2 F3 83.9(5) . 2_556
F11 P3 F11 170(8) 2_657 .
F11 P3 F8 100(3) 2_657 .
F11 P3 F8 80(3) . .
F11 P3 F8 80(3) 2_657 2_657
F11 P3 F8 100(3) . 2_657
F8 P3 F8 176(5) . 2_657
F11 P3 F12 115(5) 2_657 .
F11 P3 F12 75(4) . .
F8 P3 F12 92(4) . .
F8 P3 F12 91(3) 2_657 .
F11 P3 F12 75(4) 2_657 2_657
F11 P3 F12 115(5) . 2_657
F8 P3 F12 91(3) . 2_657
F8 P3 F12 92(4) 2_657 2_657
F12 P3 F12 41(4) . 2_657
F11 P3 F13 119(5) 2_657 2_657
F11 P3 F13 51(3) . 2_657
F8 P3 F13 76(3) . 2_657
F8 P3 F13 101(3) 2_657 2_657
F12 P3 F13 126(3) . 2_657
F12 P3 F13 162(3) 2_657 2_657
F11 P3 F13 51(3) 2_657 .
F11 P3 F13 119(5) . .
F8 P3 F13 101(3) . .
F8 P3 F13 76(3) 2_657 .
F12 P3 F13 162(3) . .
F12 P3 F13 126(3) 2_657 .
F13 P3 F13 70(3) 2_657 .
F11 P3 F7 40(3) 2_657 2_657
F11 P3 F7 137.4(19) . 2_657
F8 P3 F7 60(2) . 2_657
F8 P3 F7 120(2) 2_657 2_657
F12 P3 F7 116(3) . 2_657
F12 P3 F7 81(2) 2_657 2_657
F13 P3 F7 102.6(18) 2_657 2_657
F13 P3 F7 62.7(17) . 2_657
F11 P3 F7 137.4(19) 2_657 .
F11 P3 F7 40(3) . .
F8 P3 F7 120(2) . .
F8 P3 F7 60(2) 2_657 .
F12 P3 F7 81(2) . .
F12 P3 F7 116(3) 2_657 .
F13 P3 F7 62.7(17) 2_657 .
F13 P3 F7 102.6(18) . .
F7 P3 F7 163(2) 2_657 .
F11 P3 F4 95(4) 2_657 .
F11 P3 F4 95(4) . .
F8 P3 F4 92(2) . .
F8 P3 F4 92(2) 2_657 .
F12 P3 F4 20(2) . .
F12 P3 F4 20(2) 2_657 .
F13 P3 F4 145.2(13) 2_657 .
F13 P3 F4 145.2(13) . .
F7 P3 F4 98.5(10) 2_657 .
F7 P3 F4 98.5(10) . .
F11 P3 F6 50(3) 2_657 .
F11 P3 F6 130(3) . .
F8 P3 F6 150(2) . .
F8 P3 F6 30(2) 2_657 .
F12 P3 F6 101(3) . .
F12 P3 F6 81(3) 2_657 .
F13 P3 F6 116(2) 2_657 .
F13 P3 F6 62.1(19) . .
F7 P3 F6 90.3(12) 2_657 .
F7 P3 F6 89.4(11) . .
F4 P3 F6 91.0(14) . .
F9 F8 P3 110(10) 2_657 .
F9 F8 F13 141(10) 2_657 2_657
P3 F8 F13 54(2) . 2_657
F8 F9 P3 53(10) 2_657 .
F11 F10 F12 106(4) 2_657 2_657
F11 F10 P3 53(3) 2_657 .
F12 F10 P3 55(3) 2_657 .
F10 F11 F13 158(7) 2_657 2_657
F10 F11 P3 91(4) 2_657 .
F13 F11 P3 68(3) 2_657 .
F10 F11 F12 39(4) 2_657 .
F13 F11 F12 121(4) 2_657 .
P3 F11 F12 54(2) . .
F12 F12 F10 154(3) 2_657 2_657
F12 F12 P3 70(2) 2_657 .
F10 F12 P3 85(4) 2_657 .
F12 F12 F11 120(4) 2_657 .
F10 F12 F11 35(3) 2_657 .
P3 F12 F11 51(3) . .
F11 F13 P3 61(2) 2_657 .
F11 F13 F13 115(3) 2_657 2_657
P3 F13 F13 55.2(13) . 2_657
F11 F13 F8 71(4) 2_657 2_657
P3 F13 F8 50.5(18) . 2_657
F13 F13 F8 80(3) 2_657 2_657
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C12 1.994(5) .
Au1 P1 2.2705(11) .
Au1 Au1 3.3175(4) 2_556
Co1 C5 1.98(2) .
Co1 C4 1.998(17) .
Co1 C8 2.008(6) .
Co1 C9 2.015(5) .
Co1 C3 2.015(14) .
Co1 C6 2.015(6) .
Co1 C1 2.015(19) .
Co1 C7 2.024(7) .
Co1 C2 2.030(14) .
Co1 C3A 2.033(16) .
Co1 C10 2.039(5) .
Co1 C1A 2.048(16) .
P1 C101 1.809(4) .
P1 C301 1.818(5) .
P1 C201 1.822(4) .
C6 C7 1.406(9) .
C6 C10 1.421(7) .
C6 H6 0.9400 .
C7 C8 1.412(10) .
C7 H7 0.9400 .
C8 C9 1.411(9) .
C8 H8 0.9400 .
C9 C10 1.420(8) .
C9 H9 0.9400 .
C10 C11 1.426(7) .
C11 C12 1.197(7) .
C101 C106 1.382(7) .
C101 C102 1.397(7) .
C102 C103 1.376(7) .
C102 H102 0.9400 .
C103 C104 1.380(9) .
C103 H103 0.9400 .
C104 C105 1.368(8) .
C104 H104 0.9400 .
C105 C106 1.392(7) .
C105 H105 0.9400 .
C106 H106 0.9400 .
C201 C206 1.373(7) .
C201 C202 1.378(6) .
C202 C203 1.382(7) .
C202 H202 0.9400 .
C203 C204 1.359(9) .
C203 H203 0.9400 .
C204 C205 1.353(9) .
C204 H204 0.9400 .
C205 C206 1.385(7) .
C205 H205 0.9400 .
C206 H206 0.9400 .
C301 C306 1.389(7) .
C301 C302 1.392(7) .
C302 C303 1.384(8) .
C302 H302 0.9400 .
C303 C304 1.366(9) .
C303 H303 0.9400 .
C304 C305 1.368(9) .
C304 H304 0.9400 .
C305 C306 1.385(8) .
C305 H305 0.9400 .
C306 H306 0.9400 .
C1 C2 1.39(3) .
C1 C5 1.42(3) .
C1 H1 0.9400 .
C2 C3 1.36(2) .
C2 H2 0.9400 .
C3 C4 1.38(3) .
C3 H3 0.9400 .
C4 C5 1.38(3) .
C4 H4 0.9400 .
C5 H5 0.9400 .
C1A C2A 1.39(3) .
C1A C5A 1.43(2) .
C1A H1A 0.9400 .
C2A C3A 1.41(3) .
C2A H2A 0.9400 .
C3A C4A 1.43(2) .
C3A H3A 0.9400 .
C4A C5A 1.413(18) .
C4A H4A 0.9400 .
C5A H5A 0.9400 .
P2 F1 1.510(5) 2_556
P2 F1 1.510(5) .
P2 F2 1.577(4) 2_556
P2 F2 1.577(4) .
P2 F3 1.594(5) .
P2 F3 1.594(5) 2_556
P3 F11 1.39(5) 2_657
P3 F11 1.39(5) .
P3 F8 1.41(5) .
P3 F8 1.41(5) 2_657
P3 F12 1.44(5) .
P3 F12 1.44(5) 2_657
P3 F13 1.47(2) 2_657
P3 F13 1.47(2) .
P3 F7 1.51(2) 2_657
P3 F7 1.51(2) .
P3 F4 1.55(2) .
P3 F6 1.60(3) .
F8 F9 0.51(8) 2_657
F8 F13 1.77(6) 2_657
F9 F8 0.51(8) 2_657
F10 F11 1.03(8) 2_657
F10 F12 1.14(8) 2_657
F11 F10 1.03(8) 2_657
F11 F13 1.24(9) 2_657
F11 F12 1.73(8) .
F12 F12 1.00(11) 2_657
F12 F10 1.14(8) 2_657
F13 F11 1.24(9) 2_657
F13 F13 1.67(7) 2_657
F13 F8 1.77(6) 2_657
