#------------------------------------------------------------------------------
#$Date: 2016-02-05 01:07:15 +0200 (Fri, 05 Feb 2016) $
#$Revision: 176011 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/77/7037747.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7037747
loop_
_publ_author_name
'Vanicek, S.'
'Kopacka, H.'
'Wurst, K.'
'Vergeiner, S.'
'Kankowski, S.'
'Schur, J.'
'Bildstein, B.'
'Ott, I.'
_publ_section_title
;
 Cobaltoceniumethynyl gold(i) as an unusual heterodinuclear
 bioorganometallic fragment to study the biological properties of alkynyl
 gold complexes.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1345
_journal_page_last               1348
_journal_paper_doi               10.1039/c5dt04796j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C24 H18 Au Co2 F6 P'
_chemical_formula_weight         766.18
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-11-10 deposited with the CCDC.
2015-12-22 downloaded from the CCDC.
;
_cell_angle_alpha                117.297(3)
_cell_angle_beta                 92.968(4)
_cell_angle_gamma                106.865(3)
_cell_formula_units_Z            4
_cell_length_a                   13.3787(6)
_cell_length_b                   13.9151(6)
_cell_length_c                   15.1660(7)
_cell_measurement_reflns_used    68650
_cell_measurement_temperature    233(2)
_cell_measurement_theta_max      26.0
_cell_measurement_theta_min      1.0
_cell_volume                     2343.7(2)
_computing_cell_refinement       'DENZO and SCALEPACK'
_computing_data_collection       COLLECT
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      233(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'phi- and omega-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_sigmaI/netI    0.0429
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            16455
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.93
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    7.770
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.171
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1456
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.716
_refine_diff_density_min         -1.918
_refine_diff_density_rms         0.143
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     616
_refine_ls_number_reflns         8596
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0491
_refine_ls_R_factor_gt           0.0387
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0579P)²+4.8109P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1001
_refine_ls_wR_factor_ref         0.1057
_reflns_number_gt                7215
_reflns_number_total             8596
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt04796j4.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 7037746--7037747.cif.'
_cod_original_cell_volume        2343.68(18)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7037747
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.08676(2) 0.23460(2) 0.47595(2) 0.04686(10) Uani 1 1 d .
Au2 Au 0.252609(18) 0.46128(2) 0.930091(19) 0.03926(9) Uani 1 1 d .
Co1 Co 0.29405(6) 0.09498(7) 0.74124(6) 0.03543(19) Uani 1 1 d .
Co2 Co -0.12915(7) 0.42414(7) 0.27008(6) 0.0375(2) Uani 1 1 d .
Co3 Co 0.65623(7) 0.64598(7) 0.79175(7) 0.0407(2) Uani 1 1 d .
Co4 Co -0.21133(7) 0.15024(8) 0.77566(7) 0.0419(2) Uani 1 1 d .
P3 P 0.5000 0.0000 1.0000 0.0369(5) Uani 1 2 d S
C1 C 0.4166(6) 0.1020(7) 0.6706(6) 0.060(2) Uani 1 1 d .
H1 H 0.4109 0.0573 0.6004 0.072 Uiso 1 1 calc .
C2 C 0.4370(6) 0.0709(6) 0.7436(6) 0.0538(18) Uani 1 1 d .
H2 H 0.4475 0.0020 0.7306 0.065 Uiso 1 1 calc .
C3 C 0.4392(5) 0.1599(7) 0.8393(5) 0.0509(17) Uani 1 1 d .
H3 H 0.4519 0.1610 0.9014 0.061 Uiso 1 1 calc .
C4 C 0.4188(5) 0.2491(6) 0.8262(5) 0.0466(16) Uani 1 1 d .
H4 H 0.4146 0.3184 0.8773 0.056 Uiso 1 1 calc .
C5 C 0.4062(6) 0.2115(7) 0.7200(6) 0.060(2) Uani 1 1 d .
H5 H 0.3932 0.2526 0.6886 0.072 Uiso 1 1 calc .
C6 C 0.1632(5) -0.0328(6) 0.6317(5) 0.0477(16) Uani 1 1 d .
H6 H 0.1623 -0.0820 0.5635 0.057 Uiso 1 1 calc .
C7 C 0.1797(6) -0.0541(6) 0.7123(6) 0.0555(19) Uani 1 1 d .
H7 H 0.1922 -0.1193 0.7073 0.067 Uiso 1 1 calc .
C8 C 0.1742(6) 0.0386(7) 0.8016(6) 0.0541(19) Uani 1 1 d .
H8 H 0.1811 0.0453 0.8663 0.065 Uiso 1 1 calc .
C9 C 0.1568(5) 0.1192(6) 0.7783(5) 0.0470(16) Uani 1 1 d .
H9 H 0.1517 0.1902 0.8247 0.056 Uiso 1 1 calc .
C10 C 0.1481(5) 0.0745(6) 0.6697(5) 0.0445(15) Uani 1 1 d .
C11 C 0.1339(5) 0.1285(6) 0.6134(6) 0.0510(17) Uani 1 1 d .
C12 C 0.1171(5) 0.1684(6) 0.5609(5) 0.0488(17) Uani 1 1 d .
C21 C -0.2608(6) 0.2808(6) 0.2203(6) 0.0565(19) Uani 1 1 d .
H21 H -0.2658 0.2045 0.1759 0.068 Uiso 1 1 calc .
C22 C -0.2818(6) 0.3572(7) 0.1914(6) 0.059(2) Uani 1 1 d .
H22 H -0.3037 0.3404 0.1244 0.071 Uiso 1 1 calc .
C23 C -0.2642(6) 0.4632(7) 0.2802(6) 0.0578(19) Uani 1 1 d .
H23 H -0.2722 0.5294 0.2829 0.069 Uiso 1 1 calc .
C24 C -0.2328(6) 0.4521(6) 0.3637(5) 0.0522(17) Uani 1 1 d .
H24 H -0.2158 0.5101 0.4322 0.063 Uiso 1 1 calc .
C25 C -0.2307(6) 0.3391(6) 0.3280(6) 0.0535(18) Uani 1 1 d .
H25 H -0.2129 0.3087 0.3680 0.064 Uiso 1 1 calc .
C26 C -0.0129(5) 0.3748(6) 0.2001(5) 0.0472(16) Uani 1 1 d .
H26 H -0.0206 0.2999 0.1493 0.057 Uiso 1 1 calc .
C27 C -0.0315(6) 0.4597(7) 0.1826(6) 0.0534(18) Uani 1 1 d .
H27 H -0.0539 0.4515 0.1190 0.064 Uiso 1 1 calc .
C28 C -0.0104(5) 0.5591(6) 0.2780(6) 0.0510(17) Uani 1 1 d .
H28 H -0.0154 0.6296 0.2891 0.061 Uiso 1 1 calc .
C29 C 0.0194(5) 0.5350(6) 0.3538(5) 0.0482(16) Uani 1 1 d .
H29 H 0.0365 0.5863 0.4243 0.058 Uiso 1 1 calc .
C30 C 0.0192(5) 0.4192(6) 0.3060(5) 0.0419(15) Uani 1 1 d .
C31 C 0.0398(5) 0.3583(6) 0.3550(5) 0.0491(17) Uani 1 1 d .
C32 C 0.0564(5) 0.3058(6) 0.3954(5) 0.0480(16) Uani 1 1 d .
C41 C 0.5584(9) 0.6124(9) 0.6673(7) 0.083(3) Uani 1 1 d .
H41 H 0.5001 0.5436 0.6259 0.099 Uiso 1 1 calc .
C42 C 0.6663(9) 0.6360(9) 0.6554(7) 0.078(3) Uani 1 1 d .
H42 H 0.6926 0.5857 0.6047 0.094 Uiso 1 1 calc .
C43 C 0.7258(7) 0.7488(8) 0.7338(7) 0.068(2) Uani 1 1 d .
H43 H 0.7994 0.7876 0.7439 0.081 Uiso 1 1 calc .
C44 C 0.6584(8) 0.7933(7) 0.7934(7) 0.068(2) Uani 1 1 d .
H44 H 0.6783 0.8666 0.8517 0.082 Uiso 1 1 calc .
C45 C 0.5558(7) 0.7105(9) 0.7520(8) 0.075(3) Uani 1 1 d .
H45 H 0.4944 0.7194 0.7771 0.090 Uiso 1 1 calc .
C46 C 0.6264(6) 0.4989(5) 0.8007(6) 0.0504(17) Uani 1 1 d .
H46 H 0.5821 0.4242 0.7503 0.061 Uiso 1 1 calc .
C47 C 0.7355(6) 0.5495(7) 0.8075(6) 0.0584(19) Uani 1 1 d .
H47 H 0.7768 0.5149 0.7633 0.070 Uiso 1 1 calc .
C48 C 0.7728(5) 0.6629(7) 0.8934(6) 0.0538(18) Uani 1 1 d .
H48 H 0.8430 0.7166 0.9161 0.065 Uiso 1 1 calc .
C49 C 0.6858(6) 0.6800(6) 0.9381(5) 0.0490(17) Uani 1 1 d .
H49 H 0.6881 0.7479 0.9961 0.059 Uiso 1 1 calc .
C50 C 0.5930(5) 0.5781(5) 0.8816(5) 0.0422(15) Uani 1 1 d .
C51 C 0.4884(5) 0.5556(6) 0.9022(5) 0.0431(15) Uani 1 1 d .
C52 C 0.4013(5) 0.5265(6) 0.9195(5) 0.0410(14) Uani 1 1 d .
C61 C -0.1729(9) 0.0107(9) 0.6927(8) 0.086(3) Uani 1 1 d .
H61 H -0.1370 -0.0214 0.7205 0.103 Uiso 1 1 calc .
C62 C -0.2846(9) -0.0195(8) 0.6677(7) 0.084(3) Uani 1 1 d .
H62 H -0.3365 -0.0769 0.6739 0.101 Uiso 1 1 calc .
C63 C -0.3049(7) 0.0523(9) 0.6314(6) 0.073(3) Uani 1 1 d .
H63 H -0.3726 0.0512 0.6097 0.088 Uiso 1 1 calc .
C64 C -0.2045(7) 0.1260(8) 0.6338(6) 0.068(2) Uani 1 1 d .
H64 H -0.1935 0.1836 0.6153 0.081 Uiso 1 1 calc .
C65 C -0.1246(7) 0.0973(8) 0.6689(7) 0.072(3) Uani 1 1 d .
H65 H -0.0507 0.1306 0.6753 0.086 Uiso 1 1 calc .
C66 C -0.1632(7) 0.2019(8) 0.9240(6) 0.069(2) Uani 1 1 d .
H66 H -0.1336 0.1629 0.9486 0.082 Uiso 1 1 calc .
C67 C -0.2752(6) 0.1824(9) 0.8984(6) 0.082(3) Uani 1 1 d .
H67 H -0.3318 0.1285 0.9044 0.099 Uiso 1 1 calc .
C68 C -0.2859(6) 0.2569(8) 0.8633(7) 0.075(3) Uani 1 1 d .
H68 H -0.3503 0.2626 0.8423 0.090 Uiso 1 1 calc .
C69 C -0.1836(6) 0.3206(6) 0.8652(6) 0.0560(19) Uani 1 1 d .
H69 H -0.1680 0.3753 0.8432 0.067 Uiso 1 1 calc .
C70 C -0.1061(5) 0.2918(6) 0.9049(5) 0.0484(17) Uani 1 1 d .
C71 C 0.0066(5) 0.3406(6) 0.9189(5) 0.0463(16) Uani 1 1 d .
C72 C 0.1004(5) 0.3885(5) 0.9291(5) 0.0402(14) Uani 1 1 d .
P1 P 0.61593(19) 0.25155(17) 0.51212(16) 0.0586(5) Uani 1 1 d .
P2 P 1.0000 1.0000 1.0000 0.0502(6) Uani 1 2 d S
F1 F 0.6664(5) 0.2878(5) 0.6264(4) 0.0949(18) Uani 1 1 d .
F2 F 0.5687(5) 0.2139(5) 0.4012(4) 0.1002(19) Uani 1 1 d .
F3 F 0.6793(6) 0.3757(4) 0.5320(5) 0.113(2) Uani 1 1 d .
F4 F 0.5522(5) 0.1269(4) 0.4948(5) 0.104(2) Uani 1 1 d .
F5 F 0.5212(5) 0.2949(6) 0.5528(5) 0.111(2) Uani 1 1 d .
F6 F 0.7125(5) 0.2101(5) 0.4758(4) 0.0902(16) Uani 1 1 d .
F7 F 1.0108(7) 1.0996(7) 1.1050(6) 0.186(5) Uani 1 1 d .
F8 F 1.1235(4) 1.0327(6) 1.0143(5) 0.112(2) Uani 1 1 d .
F9 F 0.9866(7) 0.9174(9) 1.0438(8) 0.170(4) Uani 1 1 d .
F10 F 0.5022(5) 0.0360(4) 1.1155(3) 0.0768(15) Uani 1 1 d .
F11 F 0.6218(4) 0.0142(5) 1.0192(4) 0.0833(15) Uani 1 1 d .
F12 F 0.5337(4) 0.1323(3) 1.0290(3) 0.0681(13) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C12 Au1 C32 177.9(3) . .
C52 Au2 C72 175.6(3) . .
C1 Co1 C7 123.8(3) . .
C1 Co1 C9 155.5(3) . .
C7 Co1 C9 68.3(3) . .
C1 Co1 C8 161.6(4) . .
C7 Co1 C8 40.5(3) . .
C9 Co1 C8 40.3(3) . .
C1 Co1 C5 40.9(3) . .
C7 Co1 C5 160.7(4) . .
C9 Co1 C5 121.0(3) . .
C8 Co1 C5 156.8(4) . .
C1 Co1 C2 40.5(3) . .
C7 Co1 C2 107.4(3) . .
C9 Co1 C2 163.1(3) . .
C8 Co1 C2 126.0(3) . .
C5 Co1 C2 68.5(3) . .
C1 Co1 C6 105.9(3) . .
C7 Co1 C6 40.4(3) . .
C9 Co1 C6 68.5(3) . .
C8 Co1 C6 68.0(3) . .
C5 Co1 C6 123.9(3) . .
C2 Co1 C6 119.6(3) . .
C1 Co1 C4 69.0(3) . .
C7 Co1 C4 156.8(3) . .
C9 Co1 C4 108.5(3) . .
C8 Co1 C4 122.1(3) . .
C5 Co1 C4 41.0(3) . .
C2 Co1 C4 68.6(3) . .
C6 Co1 C4 161.8(3) . .
C1 Co1 C10 118.7(3) . .
C7 Co1 C10 68.4(3) . .
C9 Co1 C10 41.7(3) . .
C8 Co1 C10 68.7(3) . .
C5 Co1 C10 106.5(3) . .
C2 Co1 C10 153.7(3) . .
C6 Co1 C10 40.3(3) . .
C4 Co1 C10 125.5(3) . .
C1 Co1 C3 68.0(3) . .
C7 Co1 C3 121.3(3) . .
C9 Co1 C3 127.0(3) . .
C8 Co1 C3 109.7(3) . .
C5 Co1 C3 68.4(3) . .
C2 Co1 C3 40.0(3) . .
C6 Co1 C3 154.9(3) . .
C4 Co1 C3 41.0(3) . .
C10 Co1 C3 164.2(3) . .
C22 Co2 C21 40.8(3) . .
C22 Co2 C24 68.3(3) . .
C21 Co2 C24 68.5(3) . .
C22 Co2 C29 163.0(3) . .
C21 Co2 C29 154.8(3) . .
C24 Co2 C29 107.6(3) . .
C22 Co2 C28 125.9(3) . .
C21 Co2 C28 163.1(3) . .
C24 Co2 C28 120.4(3) . .
C29 Co2 C28 40.6(3) . .
C22 Co2 C23 40.8(3) . .
C21 Co2 C23 68.8(3) . .
C24 Co2 C23 40.5(3) . .
C29 Co2 C23 125.5(3) . .
C28 Co2 C23 107.9(3) . .
C22 Co2 C27 107.8(3) . .
C21 Co2 C27 125.6(3) . .
C24 Co2 C27 155.1(3) . .
C29 Co2 C27 68.5(3) . .
C28 Co2 C27 40.6(3) . .
C23 Co2 C27 120.4(3) . .
C22 Co2 C26 120.7(3) . .
C21 Co2 C26 107.9(3) . .
C24 Co2 C26 162.8(3) . .
C29 Co2 C26 68.0(3) . .
C28 Co2 C26 67.9(3) . .
C23 Co2 C26 155.5(3) . .
C27 Co2 C26 40.5(3) . .
C22 Co2 C25 68.7(3) . .
C21 Co2 C25 40.9(3) . .
C24 Co2 C25 40.8(3) . .
C29 Co2 C25 119.8(3) . .
C28 Co2 C25 154.9(3) . .
C23 Co2 C25 68.8(3) . .
C27 Co2 C25 162.8(3) . .
C26 Co2 C25 125.6(3) . .
C22 Co2 C30 154.8(3) . .
C21 Co2 C30 119.5(3) . .
C24 Co2 C30 125.4(3) . .
C29 Co2 C30 41.0(3) . .
C28 Co2 C30 68.7(3) . .
C23 Co2 C30 162.7(3) . .
C27 Co2 C30 68.8(3) . .
C26 Co2 C30 40.5(3) . .
C25 Co2 C30 106.8(3) . .
C48 Co3 C41 167.1(4) . .
C48 Co3 C47 41.3(3) . .
C41 Co3 C47 129.1(4) . .
C48 Co3 C45 150.3(4) . .
C41 Co3 C45 40.3(4) . .
C47 Co3 C45 168.0(4) . .
C48 Co3 C42 127.5(4) . .
C41 Co3 C42 41.3(4) . .
C47 Co3 C42 107.3(4) . .
C45 Co3 C42 68.1(4) . .
C48 Co3 C44 116.4(4) . .
C41 Co3 C44 68.2(4) . .
C47 Co3 C44 149.9(4) . .
C45 Co3 C44 40.1(4) . .
C42 Co3 C44 68.0(4) . .
C48 Co3 C49 40.5(3) . .
C41 Co3 C49 151.8(4) . .
C47 Co3 C49 68.5(3) . .
C45 Co3 C49 118.7(4) . .
C42 Co3 C49 165.6(4) . .
C44 Co3 C49 108.3(3) . .
C48 Co3 C46 68.4(3) . .
C41 Co3 C46 109.6(4) . .
C47 Co3 C46 40.4(3) . .
C45 Co3 C46 131.0(4) . .
C42 Co3 C46 118.4(4) . .
C44 Co3 C46 168.4(3) . .
C49 Co3 C46 67.9(3) . .
C48 Co3 C43 107.0(3) . .
C41 Co3 C43 68.3(4) . .
C47 Co3 C43 117.2(3) . .
C45 Co3 C43 67.0(4) . .
C42 Co3 C43 40.5(4) . .
C44 Co3 C43 39.7(4) . .
C49 Co3 C43 128.0(3) . .
C46 Co3 C43 151.2(3) . .
C48 Co3 C50 68.6(3) . .
C41 Co3 C50 118.7(4) . .
C47 Co3 C50 68.5(3) . .
C45 Co3 C50 110.0(3) . .
C42 Co3 C50 152.1(4) . .
C44 Co3 C50 129.6(3) . .
C49 Co3 C50 40.7(3) . .
C46 Co3 C50 40.5(3) . .
C43 Co3 C50 166.5(3) . .
C67 Co4 C61 126.4(5) . .
C67 Co4 C69 67.7(4) . .
C61 Co4 C69 155.9(4) . .
C67 Co4 C66 41.9(4) . .
C61 Co4 C66 107.8(4) . .
C69 Co4 C66 68.5(4) . .
C67 Co4 C65 163.3(5) . .
C61 Co4 C65 40.8(4) . .
C69 Co4 C65 120.3(4) . .
C66 Co4 C65 124.4(4) . .
C67 Co4 C64 155.5(4) . .
C61 Co4 C64 69.0(4) . .
C69 Co4 C64 106.0(4) . .
C66 Co4 C64 160.1(3) . .
C65 Co4 C64 40.5(4) . .
C67 Co4 C68 40.6(4) . .
C61 Co4 C68 163.1(4) . .
C69 Co4 C68 40.0(3) . .
C66 Co4 C68 69.4(4) . .
C65 Co4 C68 154.5(5) . .
C64 Co4 C68 119.4(4) . .
C67 Co4 C62 109.3(4) . .
C61 Co4 C62 40.7(4) . .
C69 Co4 C62 161.3(4) . .
C66 Co4 C62 122.6(4) . .
C65 Co4 C62 68.0(4) . .
C64 Co4 C62 68.6(4) . .
C68 Co4 C62 125.7(4) . .
C67 Co4 C63 121.6(4) . .
C61 Co4 C63 68.7(4) . .
C69 Co4 C63 123.7(4) . .
C66 Co4 C63 158.0(4) . .
C65 Co4 C63 67.9(4) . .
C64 Co4 C63 40.8(3) . .
C68 Co4 C63 107.3(4) . .
C62 Co4 C63 40.7(4) . .
C67 Co4 C70 68.8(3) . .
C61 Co4 C70 121.2(4) . .
C69 Co4 C70 40.4(3) . .
C66 Co4 C70 40.9(3) . .
C65 Co4 C70 107.1(3) . .
C64 Co4 C70 122.8(3) . .
C68 Co4 C70 68.3(3) . .
C62 Co4 C70 157.6(4) . .
C63 Co4 C70 159.8(4) . .
F11 P3 F11 180.000(1) . 2_657
F11 P3 F10 91.0(3) . 2_657
F11 P3 F10 89.0(3) 2_657 2_657
F11 P3 F10 89.0(3) . .
F11 P3 F10 91.0(3) 2_657 .
F10 P3 F10 180.000(2) 2_657 .
F11 P3 F12 90.0(3) . 2_657
F11 P3 F12 90.0(3) 2_657 2_657
F10 P3 F12 89.9(2) 2_657 2_657
F10 P3 F12 90.1(2) . 2_657
F11 P3 F12 90.0(3) . .
F11 P3 F12 90.0(3) 2_657 .
F10 P3 F12 90.1(2) 2_657 .
F10 P3 F12 89.9(2) . .
F12 P3 F12 180.000(1) 2_657 .
C2 C1 C5 108.7(6) . .
C2 C1 Co1 70.8(4) . .
C5 C1 Co1 70.2(4) . .
C1 C2 C3 108.5(7) . .
C1 C2 Co1 68.6(4) . .
C3 C2 Co1 71.0(4) . .
C2 C3 C4 108.3(6) . .
C2 C3 Co1 69.0(4) . .
C4 C3 Co1 69.1(4) . .
C5 C4 C3 106.4(6) . .
C5 C4 Co1 68.5(4) . .
C3 C4 Co1 69.9(4) . .
C1 C5 C4 108.1(7) . .
C1 C5 Co1 68.9(4) . .
C4 C5 Co1 70.5(4) . .
C7 C6 C10 109.0(6) . .
C7 C6 Co1 69.0(4) . .
C10 C6 Co1 70.5(4) . .
C8 C7 C6 108.3(6) . .
C8 C7 Co1 69.9(4) . .
C6 C7 Co1 70.5(4) . .
C9 C8 C7 108.6(6) . .
C9 C8 Co1 69.7(4) . .
C7 C8 Co1 69.6(4) . .
C8 C9 C10 108.1(6) . .
C8 C9 Co1 70.0(4) . .
C10 C9 Co1 70.6(4) . .
C11 C10 C6 126.2(6) . .
C11 C10 C9 127.8(7) . .
C6 C10 C9 105.9(6) . .
C11 C10 Co1 124.9(5) . .
C6 C10 Co1 69.1(4) . .
C9 C10 Co1 67.8(4) . .
C12 C11 C10 176.1(8) . .
C11 C12 Au1 178.7(7) . .
C22 C21 C25 108.2(7) . .
C22 C21 Co2 69.5(4) . .
C25 C21 Co2 70.2(4) . .
C23 C22 C21 108.3(7) . .
C23 C22 Co2 69.8(4) . .
C21 C22 Co2 69.6(4) . .
C24 C23 C22 107.7(7) . .
C24 C23 Co2 69.6(4) . .
C22 C23 Co2 69.4(4) . .
C23 C24 C25 109.0(7) . .
C23 C24 Co2 69.9(4) . .
C25 C24 Co2 70.2(4) . .
C24 C25 C21 106.8(6) . .
C24 C25 Co2 69.0(4) . .
C21 C25 Co2 68.9(4) . .
C27 C26 C30 109.8(6) . .
C27 C26 Co2 69.5(4) . .
C30 C26 Co2 70.7(4) . .
C26 C27 C28 107.3(6) . .
C26 C27 Co2 69.9(4) . .
C28 C27 Co2 69.6(4) . .
C29 C28 C27 108.4(6) . .
C29 C28 Co2 69.7(4) . .
C27 C28 Co2 69.8(4) . .
C28 C29 C30 108.7(6) . .
C28 C29 Co2 69.7(4) . .
C30 C29 Co2 70.8(4) . .
C26 C30 C31 127.0(6) . .
C26 C30 C29 105.8(6) . .
C31 C30 C29 127.0(6) . .
C26 C30 Co2 68.8(4) . .
C31 C30 Co2 124.2(5) . .
C29 C30 Co2 68.2(4) . .
C32 C31 C30 179.3(8) . .
C31 C32 Au1 173.9(7) . .
C45 C41 C42 106.9(8) . .
C45 C41 Co3 70.0(5) . .
C42 C41 Co3 69.5(5) . .
C43 C42 C41 107.1(8) . .
C43 C42 Co3 70.3(5) . .
C41 C42 Co3 69.2(5) . .
C44 C43 C42 108.8(8) . .
C44 C43 Co3 69.8(5) . .
C42 C43 Co3 69.2(5) . .
C43 C44 C45 107.9(9) . .
C43 C44 Co3 70.4(5) . .
C45 C44 Co3 69.6(5) . .
C44 C45 C41 109.3(9) . .
C44 C45 Co3 70.3(5) . .
C41 C45 Co3 69.7(5) . .
C47 C46 C50 109.5(6) . .
C47 C46 Co3 69.1(4) . .
C50 C46 Co3 71.2(4) . .
C46 C47 C48 107.7(7) . .
C46 C47 Co3 70.5(4) . .
C48 C47 Co3 69.3(4) . .
C49 C48 C47 107.7(6) . .
C49 C48 Co3 70.5(4) . .
C47 C48 Co3 69.4(4) . .
C48 C49 C50 109.2(6) . .
C48 C49 Co3 69.0(4) . .
C50 C49 Co3 71.1(4) . .
C46 C50 C51 125.7(6) . .
C46 C50 C49 105.9(6) . .
C51 C50 C49 128.3(6) . .
C46 C50 Co3 68.4(4) . .
C51 C50 Co3 129.6(5) . .
C49 C50 Co3 68.2(4) . .
C52 C51 C50 173.1(7) . .
C51 C52 Au2 172.7(6) . .
C65 C61 C62 107.9(10) . .
C65 C61 Co4 70.4(5) . .
C62 C61 Co4 70.9(6) . .
C61 C62 C63 107.9(9) . .
C61 C62 Co4 68.3(5) . .
C63 C62 Co4 70.1(5) . .
C64 C63 C62 107.6(8) . .
C64 C63 Co4 68.9(4) . .
C62 C63 Co4 69.3(5) . .
C65 C64 C63 107.5(8) . .
C65 C64 Co4 69.6(5) . .
C63 C64 Co4 70.4(5) . .
C64 C65 C61 109.0(8) . .
C64 C65 Co4 69.9(5) . .
C61 C65 Co4 68.8(5) . .
C70 C66 C67 106.6(8) . .
C70 C66 Co4 71.2(4) . .
C67 C66 Co4 68.4(5) . .
C68 C67 C66 108.9(7) . .
C68 C67 Co4 71.0(5) . .
C66 C67 Co4 69.7(4) . .
C69 C68 C67 107.1(8) . .
C69 C68 Co4 69.4(5) . .
C67 C68 Co4 68.5(5) . .
C68 C69 C70 110.7(8) . .
C68 C69 Co4 70.6(5) . .
C70 C69 Co4 71.5(4) . .
C69 C70 C71 126.2(7) . .
C69 C70 C66 106.6(7) . .
C71 C70 C66 127.2(8) . .
C69 C70 Co4 68.1(4) . .
C71 C70 Co4 127.0(5) . .
C66 C70 Co4 68.0(4) . .
C72 C71 C70 174.6(8) . .
C71 C72 Au2 173.9(6) . .
F2 P1 F3 90.3(4) . .
F2 P1 F4 91.0(4) . .
F3 P1 F4 178.6(4) . .
F2 P1 F6 89.5(3) . .
F3 P1 F6 91.2(4) . .
F4 P1 F6 89.2(3) . .
F2 P1 F5 92.6(4) . .
F3 P1 F5 88.6(4) . .
F4 P1 F5 90.9(4) . .
F6 P1 F5 177.9(4) . .
F2 P1 F1 178.4(4) . .
F3 P1 F1 90.6(4) . .
F4 P1 F1 88.1(3) . .
F6 P1 F1 89.1(3) . .
F5 P1 F1 88.7(3) . .
F7 P2 F7 180.000(4) 2_777 .
F7 P2 F9 89.7(6) 2_777 .
F7 P2 F9 90.3(6) . .
F7 P2 F9 90.3(6) 2_777 2_777
F7 P2 F9 89.7(6) . 2_777
F9 P2 F9 180.000(5) . 2_777
F7 P2 F8 91.9(4) 2_777 2_777
F7 P2 F8 88.1(4) . 2_777
F9 P2 F8 85.7(4) . 2_777
F9 P2 F8 94.3(4) 2_777 2_777
F7 P2 F8 88.1(4) 2_777 .
F7 P2 F8 91.9(4) . .
F9 P2 F8 94.3(4) . .
F9 P2 F8 85.7(4) 2_777 .
F8 P2 F8 180.000(2) 2_777 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C12 1.981(7) .
Au1 C32 1.982(7) .
Au2 C52 1.981(6) .
Au2 C72 1.990(6) .
Co1 C1 2.008(7) .
Co1 C7 2.023(7) .
Co1 C9 2.023(6) .
Co1 C8 2.025(7) .
Co1 C5 2.026(7) .
Co1 C2 2.037(7) .
Co1 C6 2.042(6) .
Co1 C4 2.052(6) .
Co1 C10 2.060(7) .
Co1 C3 2.062(7) .
Co2 C22 2.021(7) .
Co2 C21 2.023(7) .
Co2 C24 2.024(7) .
Co2 C29 2.026(6) .
Co2 C28 2.026(6) .
Co2 C23 2.027(8) .
Co2 C27 2.029(7) .
Co2 C26 2.034(7) .
Co2 C25 2.040(7) .
Co2 C30 2.060(7) .
Co3 C48 2.017(7) .
Co3 C41 2.018(9) .
Co3 C47 2.019(8) .
Co3 C45 2.022(8) .
Co3 C42 2.023(8) .
Co3 C44 2.031(8) .
Co3 C49 2.035(7) .
Co3 C46 2.037(7) .
Co3 C43 2.038(8) .
Co3 C50 2.074(6) .
Co4 C67 2.005(8) .
Co4 C61 2.006(10) .
Co4 C69 2.021(8) .
Co4 C66 2.023(8) .
Co4 C65 2.027(8) .
Co4 C64 2.031(7) .
Co4 C68 2.038(9) .
Co4 C62 2.040(9) .
Co4 C63 2.051(8) .
Co4 C70 2.066(7) .
P3 F11 1.578(5) .
P3 F11 1.578(5) 2_657
P3 F10 1.582(4) 2_657
P3 F10 1.582(4) .
P3 F12 1.595(4) 2_657
P3 F12 1.595(4) .
C1 C2 1.401(11) .
C1 C5 1.411(12) .
C2 C3 1.403(10) .
C3 C4 1.441(10) .
C4 C5 1.430(11) .
C6 C7 1.405(10) .
C6 C10 1.414(10) .
C7 C8 1.401(11) .
C8 C9 1.395(10) .
C9 C10 1.452(10) .
C10 C11 1.409(10) .
C11 C12 1.205(10) .
C21 C22 1.411(11) .
C21 C25 1.420(10) .
C22 C23 1.410(11) .
C23 C24 1.403(11) .
C24 C25 1.418(11) .
C26 C27 1.407(10) .
C26 C30 1.417(9) .
C27 C28 1.408(11) .
C28 C29 1.407(10) .
C29 C30 1.431(10) .
C30 C31 1.427(10) .
C31 C32 1.205(10) .
C41 C45 1.392(14) .
C41 C42 1.424(14) .
C42 C43 1.406(13) .
C43 C44 1.382(12) .
C44 C45 1.391(13) .
C46 C47 1.399(10) .
C46 C50 1.423(10) .
C47 C48 1.423(11) .
C48 C49 1.402(11) .
C49 C50 1.428(9) .
C50 C51 1.426(9) .
C51 C52 1.203(9) .
C61 C65 1.405(14) .
C61 C62 1.409(15) .
C62 C63 1.422(14) .
C63 C64 1.421(12) .
C64 C65 1.403(13) .
C66 C70 1.428(10) .
C66 C67 1.440(13) .
C67 C68 1.402(14) .
C68 C69 1.389(11) .
C69 C70 1.412(11) .
C70 C71 1.421(9) .
C71 C72 1.200(9) .
P1 F2 1.548(6) .
P1 F3 1.562(5) .
P1 F4 1.583(5) .
P1 F6 1.588(6) .
P1 F5 1.592(6) .
P1 F1 1.610(6) .
P2 F7 1.521(6) 2_777
P2 F7 1.521(6) .
P2 F9 1.545(7) .
P2 F9 1.545(7) 2_777
P2 F8 1.555(6) 2_777
P2 F8 1.555(6) .
