#------------------------------------------------------------------------------
#$Date: 2016-03-05 11:37:20 +0200 (Sat, 05 Mar 2016) $
#$Revision: 177793 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/77/7037759.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7037759
loop_
_publ_author_name
'Li, Jia-Jia'
'Fan, Ting-Ting'
'Qu, Xiang-Long'
'Han, Hong-Liang'
'Li, Xia'
_publ_section_title
;
 Temperature-induced 1D lanthanide polymeric frameworks based on Lnn (n =
 2, 2, 4, 6) cores: synthesis, crystal structures and luminescence
 properties.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2924
_journal_page_last               2935
_journal_paper_doi               10.1039/c5dt04262c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C66 H22 Eu2 F24 N4 O12'
_chemical_formula_weight         1822.79
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-12-21 deposited with the CCDC.
2015-12-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.900(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.7343(11)
_cell_length_b                   25.573(2)
_cell_length_c                   19.4155(16)
_cell_measurement_reflns_used    8964
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.98
_cell_measurement_theta_min      2.74
_cell_volume                     6451.6(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1245
_diffrn_reflns_av_unetI/netI     0.1459
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            35933
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.567
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    2.063
_exptl_absorpt_correction_T_max  0.646
_exptl_absorpt_correction_T_min  0.539
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.877
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             3536
_exptl_crystal_size_max          0.304
_exptl_crystal_size_mid          0.276
_exptl_crystal_size_min          0.212
_refine_diff_density_max         1.100
_refine_diff_density_min         -0.683
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     980
_refine_ls_number_reflns         11351
_refine_ls_number_restraints     609
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.1361
_refine_ls_R_factor_gt           0.0604
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0386P)²+0.0200P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1094
_refine_ls_wR_factor_ref         0.1396
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5924
_reflns_number_total             11351
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt04262c2.cif
_cod_data_source_block           10
_cod_depositor_comments
'Adding full bibliography for 7037751--7037761.cif.'
_cod_database_code               7037759
_audit_block_doi                 10.5517/cc14bpy3
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.15918(4) 0.29338(2) 0.57716(2) 0.03876(17) Uani 1 1 d . . . . .
Eu2 Eu 0.18751(4) 0.23560(2) 0.36240(2) 0.03885(17) Uani 1 1 d . . . . .
C1 C 0.3663(9) 0.3639(6) 0.6858(6) 0.070(4) Uani 1 1 d . U . . .
H1 H 0.3931 0.3302 0.6924 0.084 Uiso 1 1 calc R U . . .
C2 C 0.4343(10) 0.4054(7) 0.7119(7) 0.086(4) Uani 1 1 d . U . . .
H2 H 0.5044 0.3999 0.7344 0.103 Uiso 1 1 calc R U . . .
C3 C 0.3946(10) 0.4524(6) 0.7033(7) 0.083(4) Uani 1 1 d . U . . .
H3 H 0.4383 0.4807 0.7206 0.100 Uiso 1 1 calc R U . . .
C4 C 0.2898(10) 0.4625(6) 0.6693(6) 0.070(4) Uani 1 1 d . U . . .
C5 C 0.2373(11) 0.5120(6) 0.6581(7) 0.093(5) Uani 1 1 d . U . . .
H5 H 0.2773 0.5418 0.6728 0.112 Uiso 1 1 calc R U . . .
C6 C 0.1389(12) 0.5184(6) 0.6291(7) 0.096(5) Uani 1 1 d . U . . .
H6 H 0.1107 0.5518 0.6241 0.115 Uiso 1 1 calc R U . . .
C7 C 0.0734(10) 0.4736(6) 0.6046(6) 0.069(4) Uani 1 1 d . U . . .
C8 C -0.0328(10) 0.4758(6) 0.5715(6) 0.077(4) Uani 1 1 d . U . . .
H8 H -0.0657 0.5080 0.5653 0.092 Uiso 1 1 calc R U . . .
C9 C -0.0880(10) 0.4332(6) 0.5486(6) 0.075(4) Uani 1 1 d . U . . .
H9 H -0.1591 0.4353 0.5274 0.090 Uiso 1 1 calc R U . . .
C10 C -0.0381(9) 0.3847(5) 0.5566(6) 0.065(3) Uani 1 1 d . U . . .
H10 H -0.0775 0.3548 0.5407 0.078 Uiso 1 1 calc R U . . .
C11 C 0.1179(9) 0.4230(5) 0.6103(5) 0.048(3) Uani 1 1 d . U . . .
C12 C 0.2277(9) 0.4172(5) 0.6453(5) 0.050(3) Uani 1 1 d . U . . .
C13 C 0.4147(9) 0.1643(5) 0.3940(5) 0.060(3) Uani 1 1 d . U . . .
H13 H 0.4417 0.1980 0.4024 0.072 Uiso 1 1 calc R U . . .
C14 C 0.4838(9) 0.1225(6) 0.4133(6) 0.072(4) Uani 1 1 d . U . . .
H14 H 0.5540 0.1284 0.4345 0.087 Uiso 1 1 calc R U . . .
C15 C 0.4468(10) 0.0739(6) 0.4009(6) 0.076(4) Uani 1 1 d . U . . .
H15 H 0.4916 0.0456 0.4135 0.092 Uiso 1 1 calc R U . . .
C16 C 0.3405(9) 0.0651(6) 0.3688(6) 0.067(4) Uani 1 1 d . U . . .
C17 C 0.2931(11) 0.0155(6) 0.3538(7) 0.092(5) Uani 1 1 d . U . . .
H17 H 0.3340 -0.0142 0.3661 0.110 Uiso 1 1 calc R U . . .
C18 C 0.1932(11) 0.0100(6) 0.3231(6) 0.084(4) Uani 1 1 d . U . . .
H18 H 0.1662 -0.0236 0.3136 0.100 Uiso 1 1 calc R U . . .
C19 C 0.1264(10) 0.0522(6) 0.3044(6) 0.065(4) Uani 1 1 d . U . . .
C20 C 0.0216(10) 0.0496(6) 0.2709(6) 0.072(4) Uani 1 1 d . U . . .
H20 H -0.0091 0.0170 0.2584 0.086 Uiso 1 1 calc R U . . .
C21 C -0.0376(10) 0.0924(6) 0.2559(6) 0.075(4) Uani 1 1 d . U . . .
H21 H -0.1083 0.0898 0.2331 0.090 Uiso 1 1 calc R U . . .
C22 C 0.0094(9) 0.1403(5) 0.2750(5) 0.059(3) Uani 1 1 d . U . . .
H22 H -0.0323 0.1698 0.2664 0.071 Uiso 1 1 calc R U . . .
C23 C 0.1678(9) 0.1035(5) 0.3180(5) 0.050(3) Uani 1 1 d . U . . .
C24 C 0.2784(8) 0.1103(5) 0.3518(6) 0.052(3) Uani 1 1 d . U . . .
C25 C 0.2986(7) 0.2756(4) 0.2386(5) 0.040(3) Uani 1 1 d . U . . .
C32 C 0.1842(7) 0.3596(5) 0.4286(6) 0.044(3) Uani 1 1 d . U . . .
C34 C 0.2871(7) 0.4407(4) 0.4663(4) 0.095(5) Uani 1 1 d G U . . .
H34 H 0.3038 0.4287 0.5140 0.114 Uiso 1 1 calc R U . . .
C35 C 0.3287(7) 0.4872(4) 0.4516(6) 0.121(6) Uani 1 1 d G U . . .
C36 C 0.3037(8) 0.5051(3) 0.3804(7) 0.113(6) Uani 1 1 d G U . . .
C37 C 0.2372(8) 0.4763(4) 0.3238(5) 0.104(5) Uani 1 1 d G U . . .
C38 C 0.1956(6) 0.4297(4) 0.3385(4) 0.078(4) Uani 1 1 d G U . . .
C33 C 0.2205(6) 0.4119(3) 0.4097(5) 0.052(3) Uani 1 1 d G U . . .
C39 C 0.3726(7) 0.2762(4) 0.5192(5) 0.040(3) Uani 1 1 d . U . . .
C46 C 0.1626(8) 0.1683(5) 0.5096(5) 0.046(3) Uani 1 1 d . U . . .
C53 C 0.0188(7) 0.2532(4) 0.1819(5) 0.041(3) Uani 1 1 d . U . . .
C54 C -0.0788(5) 0.2853(3) 0.1647(4) 0.045(3) Uani 1 1 d G U . . .
C55 C -0.0902(6) 0.3209(3) 0.2157(3) 0.071(4) Uani 1 1 d G U . . .
H54 H -0.0384 0.3246 0.2603 0.085 Uiso 1 1 calc R U . . .
C56 C -0.1789(7) 0.3511(3) 0.1999(5) 0.096(5) Uani 1 1 d G U . . .
C57 C -0.2562(6) 0.3456(4) 0.1333(6) 0.094(5) Uani 1 1 d G U . . .
C58 C -0.2449(5) 0.3100(4) 0.0824(4) 0.092(5) Uani 1 1 d G U . . .
C59 C -0.1562(6) 0.2798(3) 0.0981(4) 0.062(3) Uani 1 1 d G U . . .
C60 C -0.0220(7) 0.2611(5) 0.4174(6) 0.046(3) Uani 1 1 d . U . . .
F1 F 0.3728(5) 0.3640(3) 0.3372(3) 0.079(2) Uani 1 1 d . U . . .
F2 F 0.4631(7) 0.4470(4) 0.3025(5) 0.133(3) Uani 1 1 d . U . . .
F3 F 0.4933(6) 0.4536(4) 0.1726(4) 0.123(3) Uani 1 1 d . U . . .
F4 F 0.4335(5) 0.3746(3) 0.0757(3) 0.102(3) Uani 1 1 d . U . . .
F5 F 0.3901(9) 0.5163(5) 0.5010(7) 0.218(6) Uani 1 1 d . U . . .
F6 F 0.3431(9) 0.5490(5) 0.3606(8) 0.214(6) Uani 1 1 d . U . . .
F7 F 0.2146(8) 0.4928(5) 0.2541(6) 0.180(5) Uani 1 1 d . U . . .
F8 F 0.1332(7) 0.4059(4) 0.2833(4) 0.135(4) Uani 1 1 d . U . . .
F9 F 0.5248(5) 0.2600(4) 0.6628(3) 0.111(3) Uani 1 1 d . U . . .
F10 F 0.7152(5) 0.2954(4) 0.7018(4) 0.141(4) Uani 1 1 d . U . . .
F11 F 0.7791(5) 0.3539(4) 0.6096(4) 0.132(4) Uani 1 1 d . U . . .
F12 F 0.6544(6) 0.3687(4) 0.4723(5) 0.149(4) Uani 1 1 d . U . . .
F13 F 0.0110(7) 0.1362(4) 0.5763(5) 0.146(4) Uani 1 1 d . U . . .
F14 F -0.0106(9) 0.0387(5) 0.6140(6) 0.190(5) Uani 1 1 d . U . . .
F15 F 0.1096(10) -0.0380(4) 0.5908(6) 0.193(5) Uani 1 1 d . U . . .
F16 F 0.2516(9) -0.0163(4) 0.5251(6) 0.180(5) Uani 1 1 d . U . . .
F17 F -0.1930(8) 0.3851(4) 0.2443(5) 0.161(4) Uani 1 1 d . U . . .
F18 F -0.3428(7) 0.3739(5) 0.1156(6) 0.177(5) Uani 1 1 d . U . . .
F19 F -0.3207(6) 0.3019(4) 0.0185(5) 0.156(4) Uani 1 1 d . U . . .
F20 F -0.1583(6) 0.2457(4) 0.0474(4) 0.124(3) Uani 1 1 d . U . . .
N1 N 0.2667(6) 0.3694(4) 0.6524(4) 0.048(2) Uani 1 1 d . . . . .
N2 N 0.0626(7) 0.3798(4) 0.5859(4) 0.051(2) Uani 1 1 d . . . . .
N3 N 0.3131(6) 0.1595(4) 0.3644(4) 0.046(2) Uani 1 1 d . . . . .
N4 N 0.1094(6) 0.1469(4) 0.3048(4) 0.050(2) Uani 1 1 d . . . . .
O1 O 0.2960(5) 0.2698(3) 0.3016(3) 0.051(2) Uani 1 1 d . . . . .
O2 O 0.2603(5) 0.2450(3) 0.1862(3) 0.0452(19) Uani 1 1 d . . . . .
O4 O 0.1867(5) 0.3558(3) 0.4933(3) 0.065(2) Uani 1 1 d . . . . .
O3 O 0.1590(5) 0.3254(3) 0.3806(4) 0.059(2) Uani 1 1 d . . . . .
O6 O 0.3265(4) 0.2779(3) 0.5648(3) 0.051(2) Uani 1 1 d . . . . .
O5 O 0.3380(5) 0.2632(3) 0.4554(3) 0.058(2) Uani 1 1 d . . . . .
O8 O 0.1389(5) 0.2047(3) 0.5448(4) 0.055(2) Uani 1 1 d . . . . .
O7 O 0.1987(5) 0.1745(3) 0.4591(3) 0.054(2) Uani 1 1 d . . . . .
O9 O 0.0748(5) 0.2558(3) 0.2466(3) 0.055(2) Uani 1 1 d . . . . .
O10 O 0.0360(5) 0.2274(3) 0.1327(3) 0.050(2) Uani 1 1 d . . . . .
O12 O 0.0108(5) 0.2891(3) 0.4721(3) 0.053(2) Uani 1 1 d . . . . .
O11 O 0.0249(5) 0.2365(3) 0.3833(4) 0.056(2) Uani 1 1 d . . . . .
C47 C 0.1435(7) 0.1136(3) 0.5273(4) 0.054(3) Uani 1 1 d G U . . .
C48 C 0.0717(6) 0.1014(4) 0.5615(5) 0.084(4) Uani 1 1 d G U . . .
C49 C 0.0617(7) 0.0502(5) 0.5822(5) 0.110(5) Uani 1 1 d G U . . .
C50 C 0.1235(9) 0.0111(3) 0.5688(5) 0.110(5) Uani 1 1 d G U . . .
C51 C 0.1953(8) 0.0232(4) 0.5346(5) 0.128(6) Uani 1 1 d G U . . .
C52 C 0.2053(6) 0.0745(4) 0.5139(4) 0.080(4) Uani 1 1 d G U . . .
H51 H 0.2533 0.0826 0.4910 0.096 Uiso 1 1 calc R U . . .
C26 C 0.3522(5) 0.3243(3) 0.2229(4) 0.038(2) Uani 1 1 d G U . . .
C27 C 0.3830(5) 0.3651(3) 0.2725(3) 0.055(3) Uani 1 1 d G U . . .
C28 C 0.4312(6) 0.4087(3) 0.2556(4) 0.074(4) Uani 1 1 d G U . . .
C29 C 0.4486(6) 0.4115(3) 0.1890(5) 0.077(4) Uani 1 1 d G U . . .
C30 C 0.4177(5) 0.3707(3) 0.1394(3) 0.059(3) Uani 1 1 d G U . . .
C31 C 0.3695(5) 0.3271(3) 0.1563(3) 0.059(3) Uani 1 1 d G U . . .
H31 H 0.3489 0.2998 0.1231 0.071 Uiso 1 1 calc R U . . .
C40 C 0.4847(4) 0.2946(3) 0.5443(4) 0.049(3) Uani 1 1 d G U . . .
C41 C 0.5509(6) 0.2860(3) 0.6146(3) 0.060(3) Uani 1 1 d G U . . .
C42 C 0.6504(5) 0.3058(4) 0.6358(3) 0.078(4) Uani 1 1 d G U . . .
C43 C 0.6838(4) 0.3344(4) 0.5867(5) 0.082(4) Uani 1 1 d G U . . .
C44 C 0.6176(6) 0.3430(3) 0.5165(4) 0.083(4) Uani 1 1 d G U . . .
C45 C 0.5181(5) 0.3231(3) 0.4953(3) 0.065(3) Uani 1 1 d G U . . .
H44 H 0.4738 0.3289 0.4483 0.078 Uiso 1 1 calc R U . . .
C61 C -0.1384(8) 0.2502(7) 0.3894(13) 0.058(9) Uani 0.646(13) 1 d G U P A 1
C62 C -0.1738(12) 0.1990(6) 0.3771(14) 0.072(8) Uani 0.646(13) 1 d G U P A 1
H62 H -0.1271 0.1715 0.3856 0.087 Uiso 0.646(13) 1 calc R U P A 1
C63 C -0.2789(14) 0.1890(5) 0.3520(12) 0.106(10) Uani 0.646(13) 1 d DG U P A 1
C64 C -0.3486(8) 0.2301(7) 0.3393(10) 0.068(6) Uani 0.646(13) 1 d DG U P A 1
C65 C -0.3132(11) 0.2813(6) 0.3516(10) 0.067(6) Uani 0.646(13) 1 d DG U P A 1
C66 C -0.2081(12) 0.2914(5) 0.3766(11) 0.066(6) Uani 0.646(13) 1 d DG U P A 1
F21 F -0.3112(13) 0.1387(7) 0.3423(11) 0.142(8) Uani 0.646(13) 1 d D U P A 1
F22 F -0.4493(10) 0.2180(9) 0.3131(9) 0.127(7) Uani 0.646(13) 1 d D U P A 1
F23 F -0.3822(11) 0.3187(8) 0.3336(11) 0.140(7) Uani 0.646(13) 1 d D U P A 1
F24 F -0.1733(9) 0.3422(5) 0.3872(7) 0.106(5) Uani 0.646(13) 1 d D U P A 1
C61A C -0.1378(12) 0.2616(12) 0.386(2) 0.051(15) Uani 0.354(13) 1 d G U P A 2
C62A C -0.192(2) 0.3083(9) 0.371(2) 0.059(13) Uani 0.354(13) 1 d G U P A 2
H62A H -0.1573 0.3400 0.3783 0.070 Uiso 0.354(13) 1 calc R U P A 2
C63A C -0.299(2) 0.3077(8) 0.3460(18) 0.084(15) Uani 0.354(13) 1 d DG U P A 2
C64A C -0.3518(12) 0.2603(11) 0.3354(16) 0.047(9) Uani 0.354(13) 1 d DG U P A 2
C65A C -0.2972(19) 0.2136(8) 0.3501(18) 0.052(10) Uani 0.354(13) 1 d DG U P A 2
C66A C -0.1903(19) 0.2142(9) 0.375(2) 0.055(12) Uani 0.354(13) 1 d DG U P A 2
F21A F -0.353(2) 0.3528(10) 0.3297(18) 0.109(11) Uani 0.354(13) 1 d D U P A 2
F22A F -0.4550(14) 0.2602(13) 0.3127(14) 0.087(8) Uani 0.354(13) 1 d D U P A 2
F23A F -0.353(2) 0.1691(10) 0.3362(17) 0.102(10) Uani 0.354(13) 1 d D U P A 2
F24A F -0.137(2) 0.1669(10) 0.388(2) 0.176(15) Uani 0.354(13) 1 d D U P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Eu1 O10 78.1(2) 4_566 4_566
O2 Eu1 O8 79.7(2) 4_566 .
O10 Eu1 O8 82.1(3) 4_566 .
O2 Eu1 O12 148.4(2) 4_566 .
O10 Eu1 O12 80.7(2) 4_566 .
O8 Eu1 O12 74.4(2) . .
O2 Eu1 O4 135.8(2) 4_566 .
O10 Eu1 O4 139.5(2) 4_566 .
O8 Eu1 O4 119.6(2) . .
O12 Eu1 O4 74.2(2) . .
O2 Eu1 O6 73.5(2) 4_566 .
O10 Eu1 O6 149.2(2) 4_566 .
O8 Eu1 O6 81.3(2) . .
O12 Eu1 O6 119.1(2) . .
O4 Eu1 O6 71.2(2) . .
O2 Eu1 N1 75.0(3) 4_566 .
O10 Eu1 N1 106.0(2) 4_566 .
O8 Eu1 N1 150.9(3) . .
O12 Eu1 N1 134.0(3) . .
O4 Eu1 N1 72.3(3) . .
O6 Eu1 N1 78.0(3) . .
O2 Eu1 N2 117.5(2) 4_566 .
O10 Eu1 N2 72.8(3) 4_566 .
O8 Eu1 N2 144.8(3) . .
O12 Eu1 N2 77.4(3) . .
O4 Eu1 N2 71.0(3) . .
O6 Eu1 N2 131.6(3) . .
N1 Eu1 N2 62.4(3) . .
O9 Eu2 O1 76.4(2) . .
O9 Eu2 O5 144.1(3) . .
O1 Eu2 O5 74.6(2) . .
O9 Eu2 O3 80.8(3) . .
O1 Eu2 O3 82.9(3) . .
O5 Eu2 O3 75.2(3) . .
O9 Eu2 O11 78.3(2) . .
O1 Eu2 O11 149.2(2) . .
O5 Eu2 O11 120.0(2) . .
O3 Eu2 O11 76.0(3) . .
O9 Eu2 O7 138.4(2) . .
O1 Eu2 O7 138.0(2) . .
O5 Eu2 O7 77.3(2) . .
O3 Eu2 O7 118.9(2) . .
O11 Eu2 O7 72.6(2) . .
O9 Eu2 N3 114.2(2) . .
O1 Eu2 N3 76.1(3) . .
O5 Eu2 N3 78.5(3) . .
O3 Eu2 N3 149.8(3) . .
O11 Eu2 N3 131.1(3) . .
O7 Eu2 N3 68.1(2) . .
O9 Eu2 N4 74.1(3) . .
O1 Eu2 N4 110.4(2) . .
O5 Eu2 N4 136.4(3) . .
O3 Eu2 N4 147.3(3) . .
O11 Eu2 N4 78.7(3) . .
O7 Eu2 N4 71.5(2) . .
N3 Eu2 N4 62.1(3) . .
N1 C1 C2 124.3(14) . .
N1 C1 H1 117.8 . .
C2 C1 H1 117.8 . .
C3 C2 C1 116.7(14) . .
C3 C2 H2 121.7 . .
C1 C2 H2 121.7 . .
C2 C3 C4 123.6(14) . .
C2 C3 H3 118.2 . .
C4 C3 H3 118.2 . .
C3 C4 C12 114.8(13) . .
C3 C4 C5 128.5(14) . .
C12 C4 C5 116.7(13) . .
C6 C5 C4 125.4(15) . .
C6 C5 H5 117.3 . .
C4 C5 H5 117.3 . .
C5 C6 C7 119.6(16) . .
C5 C6 H6 120.2 . .
C7 C6 H6 120.2 . .
C8 C7 C11 115.6(13) . .
C8 C7 C6 124.8(15) . .
C11 C7 C6 119.5(13) . .
C9 C8 C7 121.7(14) . .
C9 C8 H8 119.2 . .
C7 C8 H8 119.2 . .
C8 C9 C10 119.1(13) . .
C8 C9 H9 120.5 . .
C10 C9 H9 120.5 . .
N2 C10 C9 122.6(13) . .
N2 C10 H10 118.7 . .
C9 C10 H10 118.7 . .
N2 C11 C7 123.0(11) . .
N2 C11 C12 118.0(11) . .
C7 C11 C12 119.0(12) . .
N1 C12 C4 122.6(11) . .
N1 C12 C11 117.9(11) . .
C4 C12 C11 119.5(12) . .
N3 C13 C14 124.7(12) . .
N3 C13 H13 117.6 . .
C14 C13 H13 117.6 . .
C15 C14 C13 118.6(12) . .
C15 C14 H14 120.7 . .
C13 C14 H14 120.7 . .
C14 C15 C16 120.6(14) . .
C14 C15 H15 119.7 . .
C16 C15 H15 119.7 . .
C15 C16 C24 115.8(13) . .
C15 C16 C17 125.3(14) . .
C24 C16 C17 118.9(12) . .
C18 C17 C16 122.3(15) . .
C18 C17 H17 118.8 . .
C16 C17 H17 118.8 . .
C17 C18 C19 122.6(15) . .
C17 C18 H18 118.7 . .
C19 C18 H18 118.7 . .
C20 C19 C18 126.0(14) . .
C20 C19 C23 115.4(13) . .
C18 C19 C23 118.6(13) . .
C21 C20 C19 122.2(14) . .
C21 C20 H20 118.9 . .
C19 C20 H20 118.9 . .
C20 C21 C22 118.0(12) . .
C20 C21 H21 121.0 . .
C22 C21 H21 121.0 . .
N4 C22 C21 124.3(12) . .
N4 C22 H22 117.8 . .
C21 C22 H22 117.8 . .
N4 C23 C19 123.2(11) . .
N4 C23 C24 117.2(11) . .
C19 C23 C24 119.4(12) . .
N3 C24 C16 125.0(11) . .
N3 C24 C23 117.0(11) . .
C16 C24 C23 118.1(12) . .
O1 C25 O2 125.7(10) . .
O1 C25 C26 117.6(9) . .
O2 C25 C26 116.7(8) . .
O3 C32 O4 127.5(11) . .
O3 C32 C33 118.4(9) . .
O4 C32 C33 114.1(10) . .
C35 C34 C33 120.0 . .
C35 C34 H34 120.0 . .
C33 C34 H34 120.0 . .
F5 C35 C36 116.2(12) . .
F5 C35 C34 123.8(11) . .
C36 C35 C34 120.0 . .
F6 C36 C35 124.1(12) . .
F6 C36 C37 115.8(12) . .
C35 C36 C37 120.0 . .
F7 C37 C36 120.3(10) . .
F7 C37 C38 119.7(10) . .
C36 C37 C38 120.0 . .
F8 C38 C33 123.8(9) . .
F8 C38 C37 116.2(9) . .
C33 C38 C37 120.0 . .
C38 C33 C34 120.0 . .
C38 C33 C32 122.4(8) . .
C34 C33 C32 117.4(8) . .
O5 C39 O6 127.6(9) . .
O5 C39 C40 115.3(8) . .
O6 C39 C40 117.0(8) . .
O7 C46 O8 125.1(11) . .
O7 C46 C47 116.6(10) . .
O8 C46 C47 118.3(10) . .
O9 C53 O10 126.4(10) . .
O9 C53 C54 114.1(9) . .
O10 C53 C54 119.5(8) . .
C55 C54 C59 120.0 . .
C55 C54 C53 119.6(7) . .
C59 C54 C53 120.4(7) . .
C56 C55 C54 120.0 . .
C56 C55 H54 120.0 . .
C54 C55 H54 120.0 . .
F17 C56 C55 122.8(9) . .
F17 C56 C57 117.2(9) . .
C55 C56 C57 120.0 . .
F18 C57 C56 122.2(9) . .
F18 C57 C58 117.8(9) . .
C56 C57 C58 120.0 . .
F19 C58 C59 118.5(8) . .
F19 C58 C57 121.5(8) . .
C59 C58 C57 120.0 . .
F20 C59 C58 113.6(7) . .
F20 C59 C54 126.3(7) . .
C58 C59 C54 120.0 . .
O11 C60 O12 130.3(10) . .
O11 C60 C61A 116.8(18) . .
O12 C60 C61A 112.7(17) . .
O11 C60 C61 112.4(12) . .
O12 C60 C61 117.0(12) . .
C1 N1 C12 118.0(11) . .
C1 N1 Eu1 120.7(8) . .
C12 N1 Eu1 119.8(7) . .
C10 N2 C11 118.1(11) . .
C10 N2 Eu1 122.4(8) . .
C11 N2 Eu1 118.6(7) . .
C13 N3 C24 115.4(10) . .
C13 N3 Eu2 122.4(8) . .
C24 N3 Eu2 120.4(7) . .
C22 N4 C23 116.7(10) . .
C22 N4 Eu2 121.9(8) . .
C23 N4 Eu2 120.0(7) . .
C25 O1 Eu2 139.8(6) . .
C25 O2 Eu1 164.8(7) . 4_565
C32 O4 Eu1 140.9(8) . .
C32 O3 Eu2 140.7(7) . .
C39 O6 Eu1 142.6(6) . .
C39 O5 Eu2 144.3(6) . .
C46 O8 Eu1 146.2(7) . .
C46 O7 Eu2 139.1(7) . .
C53 O9 Eu2 163.7(8) . .
C53 O10 Eu1 144.9(6) . 4_565
C60 O12 Eu1 137.4(7) . .
C60 O11 Eu2 140.5(7) . .
C48 C47 C52 120.0 . .
C48 C47 C46 121.8(8) . .
C52 C47 C46 118.1(8) . .
F13 C48 C47 123.6(9) . .
F13 C48 C49 116.4(9) . .
C47 C48 C49 120.0 . .
F14 C49 C48 119.4(11) . .
F14 C49 C50 120.6(11) . .
C48 C49 C50 120.0 . .
F15 C50 C51 123.3(11) . .
F15 C50 C49 116.7(11) . .
C51 C50 C49 120.0 . .
F16 C51 C50 115.7(11) . .
F16 C51 C52 124.3(11) . .
C50 C51 C52 120.0 . .
C51 C52 C47 120.0 . .
C51 C52 H51 120.0 . .
C47 C52 H51 120.0 . .
C27 C26 C31 120.0 . .
C27 C26 C25 122.1(6) . .
C31 C26 C25 117.9(6) . .
F1 C27 C26 123.1(6) . .
F1 C27 C28 116.9(6) . .
C26 C27 C28 120.0 . .
F2 C28 C27 120.8(7) . .
F2 C28 C29 119.2(7) . .
C27 C28 C29 120.0 . .
F3 C29 C30 120.2(7) . .
F3 C29 C28 119.8(7) . .
C30 C29 C28 120.0 . .
F4 C30 C29 119.0(7) . .
F4 C30 C31 121.0(7) . .
C29 C30 C31 120.0 . .
C30 C31 C26 120.0 . .
C30 C31 H31 120.0 . .
C26 C31 H31 120.0 . .
C41 C40 C45 120.0 . .
C41 C40 C39 122.3(6) . .
C45 C40 C39 117.6(6) . .
F9 C41 C40 123.2(6) . .
F9 C41 C42 116.8(6) . .
C40 C41 C42 120.0 . .
F10 C42 C41 119.9(7) . .
F10 C42 C43 120.0(7) . .
C41 C42 C43 120.0 . .
F11 C43 C44 121.7(7) . .
F11 C43 C42 118.3(7) . .
C44 C43 C42 120.0 . .
F12 C44 C45 122.9(7) . .
F12 C44 C43 117.1(7) . .
C45 C44 C43 120.0 . .
C44 C45 C40 120.0 . .
C44 C45 H44 120.0 . .
C40 C45 H44 120.0 . .
C62 C61 C66 120.0 . .
C62 C61 C60 119.8(13) . .
C66 C61 C60 120.2(13) . .
C61 C62 C63 120.0 . .
C61 C62 H62 120.0 . .
C63 C62 H62 120.0 . .
F21 C63 C62 118.8(15) . .
F21 C63 C64 121.2(15) . .
C62 C63 C64 120.0 . .
F22 C64 C65 122.8(16) . .
F22 C64 C63 117.2(16) . .
C65 C64 C63 120.0 . .
F23 C65 C64 117.3(15) . .
F23 C65 C66 122.5(15) . .
C64 C65 C66 120.0 . .
F24 C66 C65 119.8(13) . .
F24 C66 C61 120.2(13) . .
C65 C66 C61 120.0 . .
C62A C61A C66A 120.0 . .
C62A C61A C60 121(2) . .
C66A C61A C60 119(2) . .
C63A C62A C61A 120.0 . .
C63A C62A H62A 120.0 . .
C61A C62A H62A 120.0 . .
F21A C63A C62A 120(2) . .
F21A C63A C64A 120(2) . .
C62A C63A C64A 120.0 . .
F22A C64A C63A 119(2) . .
F22A C64A C65A 121(2) . .
C63A C64A C65A 120.0 . .
F23A C65A C66A 123(2) . .
F23A C65A C64A 117(2) . .
C66A C65A C64A 120.0 . .
C65A C66A C61A 120.0 . .
C65A C66A F24A 119(2) . .
C61A C66A F24A 121(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O2 2.338(6) 4_566
Eu1 O10 2.343(6) 4_566
Eu1 O8 2.346(8) .
Eu1 O12 2.373(6) .
Eu1 O4 2.397(7) .
Eu1 O6 2.419(6) .
Eu1 N1 2.588(9) .
Eu1 N2 2.611(9) .
Eu2 O9 2.338(6) .
Eu2 O1 2.349(6) .
Eu2 O5 2.369(6) .
Eu2 O3 2.375(8) .
Eu2 O11 2.395(6) .
Eu2 O7 2.409(7) .
Eu2 N3 2.594(9) .
Eu2 N4 2.601(9) .
C1 N1 1.318(12) .
C1 C2 1.396(17) .
C1 H1 0.9300 .
C2 C3 1.309(18) .
C2 H2 0.9300 .
C3 C4 1.399(15) .
C3 H3 0.9300 .
C4 C12 1.425(16) .
C4 C5 1.436(18) .
C5 C6 1.295(16) .
C5 H5 0.9300 .
C6 C7 1.440(18) .
C6 H6 0.9300 .
C7 C8 1.392(15) .
C7 C11 1.421(16) .
C8 C9 1.319(17) .
C8 H8 0.9300 .
C9 C10 1.401(17) .
C9 H9 0.9300 .
C10 N2 1.320(12) .
C10 H10 0.9300 .
C11 N2 1.337(13) .
C11 C12 1.447(14) .
C12 N1 1.324(13) .
C13 N3 1.331(12) .
C13 C14 1.398(16) .
C13 H13 0.9300 .
C14 C15 1.334(17) .
C14 H14 0.9300 .
C15 C16 1.407(14) .
C15 H15 0.9300 .
C16 C24 1.411(16) .
C16 C17 1.412(17) .
C17 C18 1.314(15) .
C17 H17 0.9300 .
C18 C19 1.388(17) .
C18 H18 0.9300 .
C19 C20 1.376(14) .
C19 C23 1.419(16) .
C20 C21 1.336(16) .
C20 H20 0.9300 .
C21 C22 1.378(16) .
C21 H21 0.9300 .
C22 N4 1.318(11) .
C22 H22 0.9300 .
C23 N4 1.346(13) .
C23 C24 1.456(14) .
C24 N3 1.338(13) .
C25 O1 1.244(10) .
C25 O2 1.257(11) .
C25 C26 1.526(11) .
C32 O3 1.243(12) .
C32 O4 1.249(11) .
C32 C33 1.513(13) .
C34 C35 1.3900 .
C34 C33 1.3900 .
C34 H34 0.9300 .
C35 F5 1.288(12) .
C35 C36 1.3900 .
C36 F6 1.355(12) .
C36 C37 1.3900 .
C37 F7 1.354(10) .
C37 C38 1.3900 .
C38 F8 1.289(10) .
C38 C33 1.3900 .
C39 O5 1.221(10) .
C39 O6 1.245(10) .
C39 C40 1.531(10) .
C46 O7 1.244(11) .
C46 O8 1.258(12) .
C46 C47 1.486(13) .
C53 O9 1.243(10) .
C53 O10 1.246(11) .
C53 C54 1.514(11) .
C54 C55 1.3900 .
C54 C59 1.3900 .
C55 C56 1.3900 .
C55 H54 0.9300 .
C56 F17 1.283(10) .
C56 C57 1.3900 .
C57 F18 1.337(9) .
C57 C58 1.3900 .
C58 F19 1.352(9) .
C58 C59 1.3900 .
C59 F20 1.308(9) .
C60 O11 1.235(12) .
C60 O12 1.238(12) .
C60 C61A 1.509(19) .
C60 C61 1.538(14) .
F1 C27 1.309(7) .
F2 C28 1.313(9) .
F3 C29 1.327(9) .
F4 C30 1.325(7) .
F9 C41 1.291(8) .
F10 C42 1.329(8) .
F11 C43 1.335(8) .
F12 C44 1.305(9) .
F13 C48 1.312(11) .
F14 C49 1.361(10) .
F15 C50 1.361(11) .
F16 C51 1.322(12) .
O2 Eu1 2.338(6) 4_565
O10 Eu1 2.343(6) 4_565
C47 C48 1.3900 .
C47 C52 1.3900 .
C48 C49 1.3900 .
C49 C50 1.3900 .
C50 C51 1.3900 .
C51 C52 1.3900 .
C52 H51 0.9300 .
C26 C27 1.3900 .
C26 C31 1.3900 .
C27 C28 1.3900 .
C28 C29 1.3900 .
C29 C30 1.3900 .
C30 C31 1.3900 .
C31 H31 0.9300 .
C40 C41 1.3900 .
C40 C45 1.3900 .
C41 C42 1.3900 .
C42 C43 1.3900 .
C43 C44 1.3900 .
C44 C45 1.3900 .
C45 H44 0.9300 .
C61 C62 1.3900 .
C61 C66 1.3900 .
C62 C63 1.3900 .
C62 H62 0.9300 .
C63 F21 1.352(15) .
C63 C64 1.3900 .
C64 F22 1.346(12) .
C64 C65 1.3900 .
C65 F23 1.312(15) .
C65 C66 1.3900 .
C66 F24 1.378(14) .
C61A C62A 1.3900 .
C61A C66A 1.3900 .
C62A C63A 1.3900 .
C62A H62A 0.9300 .
C63A F21A 1.349(18) .
C63A C64A 1.3900 .
C64A F22A 1.342(16) .
C64A C65A 1.3900 .
C65A F23A 1.349(18) .
C65A C66A 1.3900 .
C66A F24A 1.393(19) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 1(2) .
C1 C2 C3 C4 -1(2) .
C2 C3 C4 C12 1(2) .
C2 C3 C4 C5 178.6(14) .
C3 C4 C5 C6 -176.6(14) .
C12 C4 C5 C6 1(2) .
C4 C5 C6 C7 -1(2) .
C5 C6 C7 C8 -178.7(13) .
C5 C6 C7 C11 -2(2) .
C11 C7 C8 C9 1.6(18) .
C6 C7 C8 C9 178.2(12) .
C7 C8 C9 C10 -1.3(19) .
C8 C9 C10 N2 -0.5(18) .
C8 C7 C11 N2 -0.2(16) .
C6 C7 C11 N2 -177.0(10) .
C8 C7 C11 C12 -178.8(10) .
C6 C7 C11 C12 4.3(16) .
C3 C4 C12 N1 -2.2(17) .
C5 C4 C12 N1 179.8(10) .
C3 C4 C12 C11 179.2(10) .
C5 C4 C12 C11 1.3(16) .
N2 C11 C12 N1 -1.2(14) .
C7 C11 C12 N1 177.5(9) .
N2 C11 C12 C4 177.4(9) .
C7 C11 C12 C4 -3.9(15) .
N3 C13 C14 C15 0.8(18) .
C13 C14 C15 C16 0.1(18) .
C14 C15 C16 C24 -0.3(17) .
C14 C15 C16 C17 -179.4(12) .
C15 C16 C17 C18 -179.4(12) .
C24 C16 C17 C18 1(2) .
C16 C17 C18 C19 -1(2) .
C17 C18 C19 C20 178.5(12) .
C17 C18 C19 C23 1.0(19) .
C18 C19 C20 C21 178.9(12) .
C23 C19 C20 C21 -3.5(18) .
C19 C20 C21 C22 -0.1(19) .
C20 C21 C22 N4 2.7(18) .
C20 C19 C23 N4 5.1(16) .
C18 C19 C23 N4 -177.1(10) .
C20 C19 C23 C24 -178.6(9) .
C18 C19 C23 C24 -0.8(16) .
C15 C16 C24 N3 -0.5(17) .
C17 C16 C24 N3 178.7(10) .
C15 C16 C24 C23 179.6(9) .
C17 C16 C24 C23 -1.3(16) .
N4 C23 C24 N3 -2.5(14) .
C19 C23 C24 N3 -179.0(9) .
N4 C23 C24 C16 177.5(9) .
C19 C23 C24 C16 1.0(15) .
C33 C34 C35 F5 179.3(12) .
C33 C34 C35 C36 0.0 .
F5 C35 C36 F6 2.9(13) .
C34 C35 C36 F6 -177.7(12) .
F5 C35 C36 C37 -179.3(11) .
C34 C35 C36 C37 0.0 .
F6 C36 C37 F7 -0.4(11) .
C35 C36 C37 F7 -178.3(10) .
F6 C36 C37 C38 177.9(11) .
C35 C36 C37 C38 0.0 .
F7 C37 C38 F8 -2.8(10) .
C36 C37 C38 F8 178.9(9) .
F7 C37 C38 C33 178.3(10) .
C36 C37 C38 C33 0.0 .
F8 C38 C33 C34 -178.8(10) .
C37 C38 C33 C34 0.0 .
F8 C38 C33 C32 5.9(11) .
C37 C38 C33 C32 -175.3(8) .
C35 C34 C33 C38 0.0 .
C35 C34 C33 C32 175.5(8) .
O3 C32 C33 C38 22.1(12) .
O4 C32 C33 C38 -160.3(7) .
O3 C32 C33 C34 -153.3(8) .
O4 C32 C33 C34 24.3(11) .
O9 C53 C54 C55 11.1(11) .
O10 C53 C54 C55 -169.0(8) .
O9 C53 C54 C59 -169.8(7) .
O10 C53 C54 C59 10.1(12) .
C59 C54 C55 C56 0.0 .
C53 C54 C55 C56 179.1(8) .
C54 C55 C56 F17 -178.9(11) .
C54 C55 C56 C57 0.0 .
F17 C56 C57 F18 -0.8(11) .
C55 C56 C57 F18 -179.8(11) .
F17 C56 C57 C58 179.0(10) .
C55 C56 C57 C58 0.0 .
F18 C57 C58 F19 -3.4(11) .
C56 C57 C58 F19 176.8(9) .
F18 C57 C58 C59 179.8(10) .
C56 C57 C58 C59 0.0 .
F19 C58 C59 F20 -0.8(10) .
C57 C58 C59 F20 176.0(9) .
F19 C58 C59 C54 -176.9(9) .
C57 C58 C59 C54 0.0 .
C55 C54 C59 F20 -175.5(10) .
C53 C54 C59 F20 5.5(10) .
C55 C54 C59 C58 0.0 .
C53 C54 C59 C58 -179.1(8) .
C2 C1 N1 C12 -2.5(16) .
C2 C1 N1 Eu1 163.4(9) .
C4 C12 N1 C1 3.0(15) .
C11 C12 N1 C1 -178.5(9) .
C4 C12 N1 Eu1 -163.1(8) .
C11 C12 N1 Eu1 15.5(12) .
C9 C10 N2 C11 1.8(16) .
C9 C10 N2 Eu1 -167.3(8) .
C7 C11 N2 C10 -1.5(15) .
C12 C11 N2 C10 177.2(9) .
C7 C11 N2 Eu1 168.0(8) .
C12 C11 N2 Eu1 -13.3(11) .
C14 C13 N3 C24 -1.5(15) .
C14 C13 N3 Eu2 162.9(8) .
C16 C24 N3 C13 1.3(15) .
C23 C24 N3 C13 -178.8(9) .
C16 C24 N3 Eu2 -163.5(8) .
C23 C24 N3 Eu2 16.5(12) .
C21 C22 N4 C23 -1.2(16) .
C21 C22 N4 Eu2 -167.6(9) .
C19 C23 N4 C22 -2.8(15) .
C24 C23 N4 C22 -179.2(9) .
C19 C23 N4 Eu2 163.8(8) .
C24 C23 N4 Eu2 -12.6(12) .
O2 C25 O1 Eu2 -33.3(17) .
C26 C25 O1 Eu2 146.3(7) .
O1 C25 O2 Eu1 112(2) 4_565
C26 C25 O2 Eu1 -68(3) 4_565
O3 C32 O4 Eu1 2.5(18) .
C33 C32 O4 Eu1 -174.9(6) .
O4 C32 O3 Eu2 -46.1(16) .
C33 C32 O3 Eu2 131.2(9) .
O5 C39 O6 Eu1 -32(2) .
C40 C39 O6 Eu1 145.7(8) .
O6 C39 O5 Eu2 2(2) .
C40 C39 O5 Eu2 -175.0(8) .
O7 C46 O8 Eu1 -18.5(19) .
C47 C46 O8 Eu1 163.6(7) .
O8 C46 O7 Eu2 -32.5(16) .
C47 C46 O7 Eu2 145.5(8) .
O10 C53 O9 Eu2 -37(3) .
C54 C53 O9 Eu2 142.5(19) .
O9 C53 O10 Eu1 -47.5(19) 4_565
C54 C53 O10 Eu1 132.6(9) 4_565
O11 C60 O12 Eu1 -30.8(19) .
C61A C60 O12 Eu1 154.5(16) .
C61 C60 O12 Eu1 143.1(11) .
O12 C60 O11 Eu2 -22(2) .
C61A C60 O11 Eu2 152.2(17) .
C61 C60 O11 Eu2 163.5(11) .
O7 C46 C47 C48 -156.0(7) .
O8 C46 C47 C48 22.2(11) .
O7 C46 C47 C52 28.9(11) .
O8 C46 C47 C52 -152.9(8) .
C52 C47 C48 F13 179.7(10) .
C46 C47 C48 F13 4.7(10) .
C52 C47 C48 C49 0.0 .
C46 C47 C48 C49 -175.0(8) .
F13 C48 C49 F14 1.9(10) .
C47 C48 C49 F14 -178.4(10) .
F13 C48 C49 C50 -179.7(10) .
C47 C48 C49 C50 0.0 .
F14 C49 C50 F15 -1.9(11) .
C48 C49 C50 F15 179.8(10) .
F14 C49 C50 C51 178.3(10) .
C48 C49 C50 C51 0.0 .
F15 C50 C51 F16 -0.8(11) .
C49 C50 C51 F16 179.0(10) .
F15 C50 C51 C52 -179.8(10) .
C49 C50 C51 C52 0.0 .
F16 C51 C52 C47 -178.9(11) .
C50 C51 C52 C47 0.0 .
C48 C47 C52 C51 0.0 .
C46 C47 C52 C51 175.2(8) .
O1 C25 C26 C27 -10.0(11) .
O2 C25 C26 C27 169.5(6) .
O1 C25 C26 C31 170.2(7) .
O2 C25 C26 C31 -10.2(10) .
C31 C26 C27 F1 -177.1(7) .
C25 C26 C27 F1 3.1(8) .
C31 C26 C27 C28 0.0 .
C25 C26 C27 C28 -179.7(7) .
F1 C27 C28 F2 -1.0(9) .
C26 C27 C28 F2 -178.3(9) .
F1 C27 C28 C29 177.3(7) .
C26 C27 C28 C29 0.0 .
F2 C28 C29 F3 -2.7(9) .
C27 C28 C29 F3 179.0(9) .
F2 C28 C29 C30 178.3(9) .
C27 C28 C29 C30 0.0 .
F3 C29 C30 F4 -0.1(9) .
C28 C29 C30 F4 178.9(7) .
F3 C29 C30 C31 -179.0(9) .
C28 C29 C30 C31 0.0 .
F4 C30 C31 C26 -178.9(8) .
C29 C30 C31 C26 0.0 .
C27 C26 C31 C30 0.0 .
C25 C26 C31 C30 179.8(7) .
O5 C39 C40 C41 -146.8(8) .
O6 C39 C40 C41 35.4(12) .
O5 C39 C40 C45 36.5(11) .
O6 C39 C40 C45 -141.3(8) .
C45 C40 C41 F9 179.8(10) .
C39 C40 C41 F9 3.2(10) .
C45 C40 C41 C42 0.0 .
C39 C40 C41 C42 -176.7(8) .
F9 C41 C42 F10 3.4(10) .
C40 C41 C42 F10 -176.7(9) .
F9 C41 C42 C43 -179.9(9) .
C40 C41 C42 C43 0.0 .
F10 C42 C43 F11 -4.9(10) .
C41 C42 C43 F11 178.4(9) .
F10 C42 C43 C44 176.7(9) .
C41 C42 C43 C44 0.0 .
F11 C43 C44 F12 3.7(10) .
C42 C43 C44 F12 -178.0(10) .
F11 C43 C44 C45 -178.3(10) .
C42 C43 C44 C45 0.0 .
F12 C44 C45 C40 177.9(11) .
C43 C44 C45 C40 0.0 .
C41 C40 C45 C44 0.0 .
C39 C40 C45 C44 176.8(8) .
O11 C60 C61 C62 47.0(16) .
O12 C60 C61 C62 -128.0(13) .
O11 C60 C61 C66 -133.2(13) .
O12 C60 C61 C66 51.8(19) .
C66 C61 C62 C63 0.0 .
C60 C61 C62 C63 179.8(19) .
C61 C62 C63 F21 -178(2) .
C61 C62 C63 C64 0.0 .
F21 C63 C64 F22 -4(2) .
C62 C63 C64 F22 178.2(18) .
F21 C63 C64 C65 178(2) .
C62 C63 C64 C65 0.0 .
F22 C64 C65 F23 -3(2) .
C63 C64 C65 F23 175(2) .
F22 C64 C65 C66 -178.1(19) .
C63 C64 C65 C66 0.0 .
F23 C65 C66 F24 4(2) .
C64 C65 C66 F24 178.5(17) .
F23 C65 C66 C61 -175(2) .
C64 C65 C66 C61 0.0 .
C62 C61 C66 F24 -178.5(17) .
C60 C61 C66 F24 1.7(19) .
C62 C61 C66 C65 0.0 .
C60 C61 C66 C65 -179.8(19) .
O11 C60 C61A C62A -125(2) .
O12 C60 C61A C62A 51(3) .
O11 C60 C61A C66A 59(3) .
O12 C60 C61A C66A -125.7(19) .
C66A C61A C62A C63A 0.0 .
C60 C61A C62A C63A -176(3) .
C61A C62A C63A F21A -178(4) .
C61A C62A C63A C64A 0.0 .
F21A C63A C64A F22A -4(4) .
C62A C63A C64A F22A 178(3) .
F21A C63A C64A C65A 178(4) .
C62A C63A C64A C65A 0.0 .
F22A C64A C65A F23A 4(4) .
C63A C64A C65A F23A -178(3) .
F22A C64A C65A C66A -178(3) .
C63A C64A C65A C66A 0.0 .
F23A C65A C66A C61A 178(3) .
C64A C65A C66A C61A 0.0 .
F23A C65A C66A F24A -1(4) .
C64A C65A C66A F24A -178(3) .
C62A C61A C66A C65A 0.0 .
C60 C61A C66A C65A 177(3) .
C62A C61A C66A F24A 178(3) .
C60 C61A C66A F24A -5(3) .
