#------------------------------------------------------------------------------
#$Date: 2016-04-05 19:07:58 +0300 (Tue, 05 Apr 2016) $
#$Revision: 181657 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/78/7037814.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7037814
loop_
_publ_author_name
'Bortoluzzi, Marco'
'Ceriotti, Alessandro'
'Ciabatti, Iacopo'
'Della Pergola, Roberto'
'Femoni, Cristina'
'Carmela Iapalucci, Maria'
'Storione, Alba'
'Zacchini, Stefano'
_publ_section_title
;
 Platinum carbonyl clusters stabilized by Sn(ii)-based fragments:
 syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4](4-),
 [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) and
 [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2.).
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5001
_journal_page_last               5013
_journal_paper_doi               10.1039/c5dt04696c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C110 H92 Cl16 N4 O6 P4 Pt6 Sn6'
_chemical_formula_weight         4139.64
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-12-25 deposited with the CCDC.
2016-01-04 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 91.697(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.0696(5)
_cell_length_b                   18.9114(7)
_cell_length_c                   26.3812(10)
_cell_measurement_reflns_used    9917
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.646
_cell_measurement_theta_min      2.154
_cell_volume                     6517.6(4)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0984
_diffrn_reflns_av_unetI/netI     0.0535
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            100318
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    7.964
_exptl_absorpt_correction_T_max  0.4483
_exptl_absorpt_correction_T_min  0.2856
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1734 (selected reflections only, before parameter refinement)
 R(int) = 0.0762 (selected reflections only, after parameter refinement)
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    2.109
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3856
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         2.632
_refine_diff_density_min         -1.590
_refine_diff_density_rms         0.177
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     685
_refine_ls_number_reflns         12808
_refine_ls_number_restraints     373
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0702
_refine_ls_R_factor_gt           0.0399
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0338P)²+29.7216P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0855
_refine_ls_wR_factor_ref         0.1038
_reflns_number_gt                9356
_reflns_number_total             12808
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt04696c1.cif
_cod_data_source_block           3_4MeCN_1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7037810--7037817.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7037814
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.08262(3) 0.624867(17) 0.497137(13) 0.03843(9) Uani 1 1 d .
Pt2 Pt 0.04096(3) 0.478280(17) 0.457458(12) 0.03661(9) Uani 1 1 d .
Pt3 Pt -0.10092(3) 0.601819(17) 0.451451(14) 0.04079(9) Uani 1 1 d .
Sn1 Sn 0.18056(5) 0.52338(3) 0.54365(2) 0.04431(16) Uani 1 1 d .
Sn2 Sn 0.08668(5) 0.58731(3) 0.39495(2) 0.04312(15) Uani 1 1 d .
Sn3 Sn -0.05172(5) 0.73495(3) 0.47764(3) 0.04814(17) Uani 1 1 d .
Cl1 Cl 0.3493(2) 0.51166(16) 0.51380(11) 0.0659(7) Uani 1 1 d .
Cl2 Cl 0.2268(2) 0.56485(16) 0.62686(10) 0.0656(7) Uani 1 1 d .
Cl3 Cl 0.0958(2) 0.70841(14) 0.36633(11) 0.0691(8) Uani 1 1 d .
Cl4 Cl 0.0167(2) 0.54545(16) 0.31595(10) 0.0698(8) Uani 1 1 d .
Cl5 Cl 0.2617(2) 0.56393(16) 0.37675(11) 0.0664(7) Uani 1 1 d .
Cl6 Cl 0.0667(3) 0.82885(14) 0.49278(15) 0.0853(10) Uani 1 1 d U
Cl7 Cl -0.1390(3) 0.80182(16) 0.41187(13) 0.0853(10) Uani 1 1 d .
Cl8 Cl -0.1624(3) 0.76814(18) 0.54297(15) 0.1060(13) Uani 1 1 d U
C1 C 0.1942(8) 0.6851(5) 0.5072(4) 0.061(3) Uani 1 1 d .
C2 C 0.0772(8) 0.4163(5) 0.4069(4) 0.055(3) Uani 1 1 d .
C3 C -0.2057(8) 0.6288(5) 0.4061(5) 0.063(3) Uani 1 1 d .
O1 O 0.2643(7) 0.7200(5) 0.5126(4) 0.107(3) Uani 1 1 d .
O2 O 0.0963(7) 0.3784(4) 0.3743(3) 0.077(2) Uani 1 1 d .
O3 O -0.2675(7) 0.6450(5) 0.3770(4) 0.110(4) Uani 1 1 d .
P1 P 0.3797(2) 0.30081(13) 0.28080(9) 0.0479(6) Uani 1 1 d .
C101 C 0.3357(8) 0.3770(5) 0.2462(4) 0.056(2) Uani 1 1 d U
C102 C 0.2887(9) 0.4319(6) 0.2710(4) 0.063(2) Uani 1 1 d U
H102 H 0.2870 0.4321 0.3062 0.075 Uiso 1 1 calc R
C103 C 0.2441(9) 0.4866(6) 0.2432(4) 0.069(3) Uani 1 1 d U
H103 H 0.2144 0.5247 0.2596 0.083 Uiso 1 1 calc R
C104 C 0.2443(10) 0.4839(6) 0.1917(4) 0.074(3) Uani 1 1 d U
H104 H 0.2122 0.5199 0.1732 0.089 Uiso 1 1 calc R
C105 C 0.2901(10) 0.4301(6) 0.1662(4) 0.073(3) Uani 1 1 d U
H105 H 0.2892 0.4293 0.1309 0.087 Uiso 1 1 calc R
C106 C 0.3373(9) 0.3775(6) 0.1939(4) 0.065(2) Uani 1 1 d U
H106 H 0.3710 0.3414 0.1771 0.078 Uiso 1 1 calc R
C107 C 0.4137(8) 0.3234(5) 0.3454(4) 0.048(2) Uani 1 1 d U
C108 C 0.5143(8) 0.3294(5) 0.3620(4) 0.058(2) Uani 1 1 d U
H108 H 0.5669 0.3208 0.3398 0.069 Uiso 1 1 calc R
C109 C 0.5369(10) 0.3482(6) 0.4112(4) 0.068(3) Uani 1 1 d U
H109 H 0.6048 0.3521 0.4224 0.081 Uiso 1 1 calc R
C110 C 0.4600(10) 0.3612(6) 0.4438(4) 0.071(3) Uani 1 1 d U
H110 H 0.4766 0.3742 0.4771 0.085 Uiso 1 1 calc R
C111 C 0.3595(10) 0.3558(6) 0.4288(4) 0.069(3) Uani 1 1 d U
H111 H 0.3075 0.3647 0.4512 0.083 Uiso 1 1 calc R
C112 C 0.3377(9) 0.3365(6) 0.3792(4) 0.062(2) Uani 1 1 d U
H112 H 0.2697 0.3322 0.3683 0.074 Uiso 1 1 calc R
C113 C 0.4906(8) 0.2655(5) 0.2510(4) 0.055(2) Uani 1 1 d U
C114 C 0.5022(9) 0.1932(5) 0.2453(4) 0.061(2) Uani 1 1 d U
H114 H 0.4495 0.1628 0.2538 0.073 Uiso 1 1 calc R
C115 C 0.5919(9) 0.1666(6) 0.2272(4) 0.069(3) Uani 1 1 d U
H115 H 0.5993 0.1182 0.2226 0.083 Uiso 1 1 calc R
C116 C 0.6701(10) 0.2113(6) 0.2159(4) 0.073(3) Uani 1 1 d U
H116 H 0.7314 0.1929 0.2047 0.087 Uiso 1 1 calc R
C117 C 0.6594(10) 0.2826(6) 0.2208(4) 0.072(3) Uani 1 1 d U
H117 H 0.7127 0.3127 0.2127 0.087 Uiso 1 1 calc R
C118 C 0.5682(9) 0.3103(6) 0.2382(4) 0.064(2) Uani 1 1 d U
H118 H 0.5599 0.3589 0.2410 0.077 Uiso 1 1 calc R
C119 C 0.2777(8) 0.2384(6) 0.2809(4) 0.059(2) Uani 1 1 d U
C120 C 0.2664(9) 0.1922(6) 0.3207(4) 0.068(3) Uani 1 1 d U
H120 H 0.3138 0.1920 0.3477 0.082 Uiso 1 1 calc R
C121 C 0.1832(10) 0.1455(6) 0.3203(5) 0.079(3) Uani 1 1 d U
H121 H 0.1744 0.1151 0.3475 0.094 Uiso 1 1 calc R
C122 C 0.1152(11) 0.1447(7) 0.2803(5) 0.085(3) Uani 1 1 d U
H122 H 0.0597 0.1139 0.2802 0.102 Uiso 1 1 calc R
C123 C 0.1283(11) 0.1885(7) 0.2407(5) 0.088(3) Uani 1 1 d U
H123 H 0.0831 0.1861 0.2128 0.106 Uiso 1 1 calc R
C124 C 0.2072(10) 0.2365(6) 0.2408(4) 0.075(3) Uani 1 1 d U
H124 H 0.2133 0.2678 0.2138 0.090 Uiso 1 1 calc R
P2 P 0.3243(2) 0.95530(14) 0.41050(10) 0.0551(7) Uani 1 1 d .
C201 C 0.4039(10) 0.8784(6) 0.4166(4) 0.067(3) Uani 1 1 d U
C202 C 0.5064(11) 0.8843(7) 0.4314(4) 0.078(3) Uani 1 1 d U
H202 H 0.5351 0.9286 0.4375 0.094 Uiso 1 1 calc R
C203 C 0.5660(12) 0.8236(8) 0.4372(5) 0.092(3) Uani 1 1 d U
H203 H 0.6348 0.8273 0.4468 0.110 Uiso 1 1 calc R
C204 C 0.5242(12) 0.7601(8) 0.4288(5) 0.094(3) Uani 1 1 d U
H204 H 0.5652 0.7201 0.4323 0.113 Uiso 1 1 calc R
C205 C 0.4225(12) 0.7520(7) 0.4151(5) 0.091(3) Uani 1 1 d U
H205 H 0.3944 0.7072 0.4102 0.109 Uiso 1 1 calc R
C206 C 0.3636(11) 0.8116(6) 0.4088(5) 0.079(3) Uani 1 1 d U
H206 H 0.2949 0.8069 0.3990 0.095 Uiso 1 1 calc R
C207 C 0.4050(9) 1.0304(6) 0.4004(4) 0.063(2) Uani 1 1 d U
C208 C 0.3986(9) 1.0903(6) 0.4308(4) 0.067(3) Uani 1 1 d U
H208 H 0.3505 1.0925 0.4561 0.080 Uiso 1 1 calc R
C209 C 0.4640(10) 1.1466(6) 0.4233(5) 0.077(3) Uani 1 1 d U
H209 H 0.4604 1.1866 0.4436 0.093 Uiso 1 1 calc R
C210 C 0.5338(11) 1.1434(7) 0.3860(5) 0.082(3) Uani 1 1 d U
H210 H 0.5773 1.1816 0.3811 0.098 Uiso 1 1 calc R
C211 C 0.5412(10) 1.0853(7) 0.3556(5) 0.080(3) Uani 1 1 d U
H211 H 0.5898 1.0838 0.3306 0.096 Uiso 1 1 calc R
C212 C 0.4760(10) 1.0287(6) 0.3623(5) 0.074(3) Uani 1 1 d U
H212 H 0.4796 0.9894 0.3412 0.089 Uiso 1 1 calc R
C213 C 0.2561(8) 0.9680(5) 0.4674(4) 0.053(2) Uani 1 1 d U
C214 C 0.2852(9) 0.9330(5) 0.5112(4) 0.059(2) Uani 1 1 d U
H214 H 0.3399 0.9015 0.5114 0.071 Uiso 1 1 calc R
C215 C 0.2321(9) 0.9452(6) 0.5553(4) 0.069(3) Uani 1 1 d U
H215 H 0.2486 0.9198 0.5846 0.082 Uiso 1 1 calc R
C216 C 0.1557(10) 0.9945(6) 0.5554(5) 0.072(3) Uani 1 1 d U
H216 H 0.1226 1.0046 0.5853 0.087 Uiso 1 1 calc R
C217 C 0.1282(10) 1.0284(6) 0.5123(5) 0.071(3) Uani 1 1 d U
H217 H 0.0745 1.0606 0.5125 0.085 Uiso 1 1 calc R
C218 C 0.1776(9) 1.0165(6) 0.4684(4) 0.065(2) Uani 1 1 d U
H218 H 0.1584 1.0410 0.4391 0.078 Uiso 1 1 calc R
C219 C 0.2323(9) 0.9446(5) 0.3595(4) 0.063(2) Uani 1 1 d U
C220 C 0.1410(10) 0.9098(6) 0.3680(5) 0.075(3) Uani 1 1 d U
H220 H 0.1271 0.8943 0.4006 0.089 Uiso 1 1 calc R
C221 C 0.0711(11) 0.8980(7) 0.3296(5) 0.083(3) Uani 1 1 d U
H221 H 0.0112 0.8733 0.3356 0.100 Uiso 1 1 calc R
C222 C 0.0900(11) 0.9226(7) 0.2820(5) 0.085(3) Uani 1 1 d U
H222 H 0.0411 0.9161 0.2560 0.102 Uiso 1 1 calc R
C223 C 0.1791(11) 0.9566(6) 0.2719(4) 0.078(3) Uani 1 1 d U
H223 H 0.1916 0.9721 0.2393 0.094 Uiso 1 1 calc R
C224 C 0.2505(10) 0.9676(6) 0.3105(4) 0.068(3) Uani 1 1 d U
H224 H 0.3115 0.9907 0.3037 0.082 Uiso 1 1 calc R
N1 N 0.7854(18) 0.1691(12) 0.3369(9) 0.212(8) Uani 1 1 d DU
C301 C 0.844(2) 0.2106(14) 0.3423(11) 0.199(8) Uani 1 1 d DU
C302 C 0.9202(19) 0.2654(13) 0.3461(10) 0.214(9) Uani 1 1 d DU
H30A H 0.9777 0.2488 0.3663 0.322 Uiso 1 1 calc R
H30B H 0.8916 0.3064 0.3618 0.322 Uiso 1 1 calc R
H30C H 0.9422 0.2774 0.3128 0.322 Uiso 1 1 calc R
N2 N 0.4480(11) -0.0024(7) 0.2299(5) 0.110(4) Uani 1 1 d DU
C401 C 0.4570(11) 0.0119(7) 0.1893(5) 0.083(3) Uani 1 1 d DU
C402 C 0.4752(11) 0.0300(7) 0.1374(5) 0.092(4) Uani 1 1 d DU
H40A H 0.4685 0.0802 0.1330 0.137 Uiso 1 1 calc R
H40B H 0.4263 0.0062 0.1156 0.137 Uiso 1 1 calc R
H40C H 0.5431 0.0157 0.1290 0.137 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 Sn1 90.7(3) . .
C1 Pt1 Pt3 147.9(3) . .
Sn1 Pt1 Pt3 120.877(19) . .
C1 Pt1 Sn3 93.2(3) . .
Sn1 Pt1 Sn3 161.35(3) . .
Pt3 Pt1 Sn3 58.986(17) . .
C1 Pt1 Sn2 104.8(4) . .
Sn1 Pt1 Sn2 104.20(2) . .
Pt3 Pt1 Sn2 64.388(17) . .
Sn3 Pt1 Sn2 92.41(2) . .
C1 Pt1 Pt2 144.8(3) . 3_566
Sn1 Pt1 Pt2 64.442(17) . 3_566
Pt3 Pt1 Pt2 64.142(13) . 3_566
Sn3 Pt1 Pt2 103.380(19) . 3_566
Sn2 Pt1 Pt2 105.170(18) . 3_566
C1 Pt1 Pt2 138.2(3) . .
Sn1 Pt1 Pt2 64.183(17) . .
Pt3 Pt1 Pt2 62.901(12) . .
Sn3 Pt1 Pt2 121.497(19) . .
Sn2 Pt1 Pt2 55.762(15) . .
Pt2 Pt1 Pt2 53.880(13) 3_566 .
C2 Pt2 Pt2 158.1(3) . 3_566
C2 Pt2 Sn2 88.7(3) . .
Pt2 Pt2 Sn2 112.39(2) 3_566 .
C2 Pt2 Pt1 91.7(3) . 3_566
Pt2 Pt2 Pt1 66.639(15) 3_566 3_566
Sn2 Pt2 Pt1 157.06(2) . 3_566
C2 Pt2 Sn1 105.3(3) . 3_566
Pt2 Pt2 Sn1 65.305(19) 3_566 3_566
Sn2 Pt2 Sn1 103.88(2) . 3_566
Pt1 Pt2 Sn1 53.978(15) 3_566 3_566
C2 Pt2 Pt3 101.3(3) . 3_566
Pt2 Pt2 Pt3 64.504(15) 3_566 3_566
Sn2 Pt2 Pt3 146.33(2) . 3_566
Pt1 Pt2 Pt3 55.708(12) 3_566 3_566
Sn1 Pt2 Pt3 104.238(18) 3_566 3_566
C2 Pt2 Pt3 129.1(3) . .
Pt2 Pt2 Pt3 62.327(14) 3_566 .
Sn2 Pt2 Pt3 61.396(17) . .
Pt1 Pt2 Pt3 101.606(14) 3_566 .
Sn1 Pt2 Pt3 52.280(15) 3_566 .
Pt3 Pt2 Pt3 126.831(13) 3_566 .
C2 Pt2 Sn1 124.4(3) . .
Pt2 Pt2 Sn1 61.352(18) 3_566 .
Sn2 Pt2 Sn1 96.00(2) . .
Pt1 Pt2 Sn1 102.588(17) 3_566 .
Sn1 Pt2 Sn1 126.657(16) 3_566 .
Pt3 Pt2 Sn1 51.855(15) 3_566 .
Pt3 Pt2 Sn1 100.421(17) . .
C2 Pt2 Pt1 142.0(3) . .
Pt2 Pt2 Pt1 59.481(14) 3_566 .
Sn2 Pt2 Pt1 58.066(16) . .
Pt1 Pt2 Pt1 126.120(13) 3_566 .
Sn1 Pt2 Pt1 100.617(17) 3_566 .
Pt3 Pt2 Pt1 98.623(14) 3_566 .
Pt3 Pt2 Pt1 53.314(11) . .
Sn1 Pt2 Pt1 51.217(14) . .
C3 Pt3 Sn1 89.6(3) . 3_566
C3 Pt3 Sn3 94.3(3) . .
Sn1 Pt3 Sn3 159.70(3) 3_566 .
C3 Pt3 Pt1 150.8(3) . .
Sn1 Pt3 Pt1 118.70(2) 3_566 .
Sn3 Pt3 Pt1 61.878(18) . .
C3 Pt3 Sn2 108.1(4) . .
Sn1 Pt3 Sn2 106.51(2) 3_566 .
Sn3 Pt3 Sn2 91.21(2) . .
Pt1 Pt3 Sn2 59.498(16) . .
C3 Pt3 Pt2 147.4(3) . 3_566
Sn1 Pt3 Pt2 65.444(17) 3_566 3_566
Sn3 Pt3 Pt2 102.581(19) . 3_566
Pt1 Pt3 Pt2 60.150(12) . 3_566
Sn2 Pt3 Pt2 99.323(17) . 3_566
C3 Pt3 Pt2 133.8(3) . .
Sn1 Pt3 Pt2 62.086(17) 3_566 .
Sn3 Pt3 Pt2 125.24(2) . .
Pt1 Pt3 Pt2 63.785(12) . .
Sn2 Pt3 Pt2 54.805(15) . .
Pt2 Pt3 Pt2 53.169(13) 3_566 .
Cl1 Sn1 Cl2 97.08(10) . .
Cl1 Sn1 Pt3 108.04(7) . 3_566
Cl2 Sn1 Pt3 110.16(8) . 3_566
Cl1 Sn1 Pt1 111.24(8) . .
Cl2 Sn1 Pt1 107.40(7) . .
Pt3 Sn1 Pt1 120.41(3) 3_566 .
Cl1 Sn1 Pt2 159.13(7) . 3_566
Cl2 Sn1 Pt2 103.77(7) . 3_566
Pt3 Sn1 Pt2 65.634(17) 3_566 3_566
Pt1 Sn1 Pt2 61.580(17) . 3_566
Cl1 Sn1 Pt2 105.81(7) . .
Cl2 Sn1 Pt2 157.11(7) . .
Pt3 Sn1 Pt2 62.701(16) 3_566 .
Pt1 Sn1 Pt2 64.599(17) . .
Pt2 Sn1 Pt2 53.343(16) 3_566 .
Cl4 Sn2 Cl5 96.18(11) . .
Cl4 Sn2 Cl3 93.60(10) . .
Cl5 Sn2 Cl3 93.22(10) . .
Cl4 Sn2 Pt2 101.11(8) . .
Cl5 Sn2 Pt2 102.14(7) . .
Cl3 Sn2 Pt2 157.33(7) . .
Cl4 Sn2 Pt1 155.59(8) . .
Cl5 Sn2 Pt1 106.66(7) . .
Cl3 Sn2 Pt1 93.62(7) . .
Pt2 Sn2 Pt1 66.172(17) . .
Cl4 Sn2 Pt3 99.84(8) . .
Cl5 Sn2 Pt3 160.42(7) . .
Cl3 Sn2 Pt3 96.92(7) . .
Pt2 Sn2 Pt3 63.799(16) . .
Pt1 Sn2 Pt3 56.115(15) . .
Cl8 Sn3 Cl6 95.06(14) . .
Cl8 Sn3 Cl7 95.66(14) . .
Cl6 Sn3 Cl7 91.19(12) . .
Cl8 Sn3 Pt3 106.81(10) . .
Cl6 Sn3 Pt3 153.16(9) . .
Cl7 Sn3 Pt3 101.69(8) . .
Cl8 Sn3 Pt1 117.59(10) . .
Cl6 Sn3 Pt1 97.15(8) . .
Cl7 Sn3 Pt1 144.63(9) . .
Pt3 Sn3 Pt1 59.136(16) . .
O1 C1 Pt1 177.6(12) . .
O2 C2 Pt2 177.3(10) . .
O3 C3 Pt3 177.6(12) . .
C119 P1 C101 107.8(5) . .
C119 P1 C113 111.6(5) . .
C101 P1 C113 109.1(5) . .
C119 P1 C107 108.6(5) . .
C101 P1 C107 111.0(5) . .
C113 P1 C107 108.8(5) . .
C102 C101 C106 119.2(10) . .
C102 C101 P1 120.3(8) . .
C106 C101 P1 120.0(8) . .
C101 C102 C103 119.8(10) . .
C101 C102 H102 120.1 . .
C103 C102 H102 120.1 . .
C104 C103 C102 119.1(11) . .
C104 C103 H103 120.4 . .
C102 C103 H103 120.4 . .
C103 C104 C105 122.3(11) . .
C103 C104 H104 118.9 . .
C105 C104 H104 118.9 . .
C104 C105 C106 118.3(11) . .
C104 C105 H105 120.9 . .
C106 C105 H105 120.9 . .
C105 C106 C101 121.2(11) . .
C105 C106 H106 119.4 . .
C101 C106 H106 119.4 . .
C112 C107 C108 118.6(9) . .
C112 C107 P1 119.6(8) . .
C108 C107 P1 121.8(8) . .
C109 C108 C107 119.9(10) . .
C109 C108 H108 120.0 . .
C107 C108 H108 120.0 . .
C110 C109 C108 120.2(11) . .
C110 C109 H109 119.9 . .
C108 C109 H109 119.9 . .
C109 C110 C111 121.6(11) . .
C109 C110 H110 119.2 . .
C111 C110 H110 119.2 . .
C110 C111 C112 117.7(11) . .
C110 C111 H111 121.2 . .
C112 C111 H111 121.2 . .
C107 C112 C111 121.9(11) . .
C107 C112 H112 119.0 . .
C111 C112 H112 119.0 . .
C118 C113 C114 120.0(10) . .
C118 C113 P1 119.3(8) . .
C114 C113 P1 120.4(8) . .
C115 C114 C113 119.7(11) . .
C115 C114 H114 120.1 . .
C113 C114 H114 120.1 . .
C116 C115 C114 120.1(11) . .
C116 C115 H115 120.0 . .
C114 C115 H115 120.0 . .
C117 C116 C115 120.8(12) . .
C117 C116 H116 119.6 . .
C115 C116 H116 119.6 . .
C116 C117 C118 119.7(12) . .
C116 C117 H117 120.2 . .
C118 C117 H117 120.2 . .
C113 C118 C117 119.7(10) . .
C113 C118 H118 120.1 . .
C117 C118 H118 120.1 . .
C120 C119 C124 118.9(11) . .
C120 C119 P1 121.3(8) . .
C124 C119 P1 119.8(9) . .
C119 C120 C121 119.7(11) . .
C119 C120 H120 120.1 . .
C121 C120 H120 120.1 . .
C122 C121 C120 120.2(12) . .
C122 C121 H121 119.9 . .
C120 C121 H121 119.9 . .
C123 C122 C121 120.0(13) . .
C123 C122 H122 120.0 . .
C121 C122 H122 120.0 . .
C122 C123 C124 121.1(12) . .
C122 C123 H123 119.4 . .
C124 C123 H123 119.4 . .
C123 C124 C119 120.0(12) . .
C123 C124 H124 120.0 . .
C119 C124 H124 120.0 . .
C213 P2 C219 107.9(5) . .
C213 P2 C201 109.6(5) . .
C219 P2 C201 110.6(5) . .
C213 P2 C207 109.2(5) . .
C219 P2 C207 111.3(5) . .
C201 P2 C207 108.3(6) . .
C206 C201 C202 118.4(11) . .
C206 C201 P2 120.7(10) . .
C202 C201 P2 120.8(10) . .
C201 C202 C203 119.7(13) . .
C201 C202 H202 120.2 . .
C203 C202 H202 120.2 . .
C204 C203 C202 119.9(15) . .
C204 C203 H203 120.1 . .
C202 C203 H203 120.1 . .
C203 C204 C205 122.2(14) . .
C203 C204 H204 118.9 . .
C205 C204 H204 118.9 . .
C206 C205 C204 118.3(14) . .
C206 C205 H205 120.9 . .
C204 C205 H205 120.9 . .
C205 C206 C201 121.5(14) . .
C205 C206 H206 119.2 . .
C201 C206 H206 119.2 . .
C212 C207 C208 119.4(11) . .
C212 C207 P2 119.8(9) . .
C208 C207 P2 120.8(9) . .
C209 C208 C207 119.7(12) . .
C209 C208 H208 120.2 . .
C207 C208 H208 120.2 . .
C210 C209 C208 119.9(13) . .
C210 C209 H209 120.0 . .
C208 C209 H209 120.0 . .
C209 C210 C211 121.4(13) . .
C209 C210 H210 119.3 . .
C211 C210 H210 119.3 . .
C210 C211 C212 119.6(13) . .
C210 C211 H211 120.2 . .
C212 C211 H211 120.2 . .
C211 C212 C207 120.0(12) . .
C211 C212 H212 120.0 . .
C207 C212 H212 120.0 . .
C214 C213 C218 119.5(10) . .
C214 C213 P2 120.7(8) . .
C218 C213 P2 119.7(8) . .
C213 C214 C215 119.4(10) . .
C213 C214 H214 120.3 . .
C215 C214 H214 120.3 . .
C216 C215 C214 119.9(11) . .
C216 C215 H215 120.1 . .
C214 C215 H215 120.1 . .
C217 C216 C215 120.0(11) . .
C217 C216 H216 120.0 . .
C215 C216 H216 120.0 . .
C216 C217 C218 121.2(12) . .
C216 C217 H217 119.4 . .
C218 C217 H217 119.4 . .
C217 C218 C213 119.9(11) . .
C217 C218 H218 120.0 . .
C213 C218 H218 120.0 . .
C220 C219 C224 118.0(11) . .
C220 C219 P2 119.6(8) . .
C224 C219 P2 122.3(10) . .
C221 C220 C219 121.2(12) . .
C221 C220 H220 119.4 . .
C219 C220 H220 119.4 . .
C220 C221 C222 119.5(14) . .
C220 C221 H221 120.3 . .
C222 C221 H221 120.3 . .
C223 C222 C221 121.1(13) . .
C223 C222 H222 119.5 . .
C221 C222 H222 119.5 . .
C222 C223 C224 119.6(12) . .
C222 C223 H223 120.2 . .
C224 C223 H223 120.2 . .
C223 C224 C219 120.5(12) . .
C223 C224 H224 119.7 . .
C219 C224 H224 119.7 . .
N1 C301 C302 177(4) . .
C301 C302 H30A 109.5 . .
C301 C302 H30B 109.5 . .
H30A C302 H30B 109.5 . .
C301 C302 H30C 109.5 . .
H30A C302 H30C 109.5 . .
H30B C302 H30C 109.5 . .
N2 C401 C402 176.5(17) . .
C401 C402 H40A 109.5 . .
C401 C402 H40B 109.5 . .
H40A C402 H40B 109.5 . .
C401 C402 H40C 109.5 . .
H40A C402 H40C 109.5 . .
H40B C402 H40C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 1.863(11) .
Pt1 Sn1 2.5951(7) .
Pt1 Pt3 2.6880(5) .
Pt1 Sn3 2.7618(7) .
Pt1 Sn2 2.7899(7) .
Pt1 Pt2 2.8219(5) 3_566
Pt1 Pt2 3.0072(5) .
Pt2 C2 1.847(11) .
Pt2 Pt2 2.6461(7) 3_566
Pt2 Sn2 2.7178(7) .
Pt2 Pt1 2.8219(5) 3_566
Pt2 Sn1 2.8946(7) 3_566
Pt2 Pt3 2.9278(5) 3_566
Pt2 Pt3 2.9840(5) .
Pt2 Sn1 2.9968(7) .
Pt3 C3 1.864(11) .
Pt3 Sn1 2.5912(7) 3_566
Pt3 Sn3 2.6838(7) .
Pt3 Sn2 2.9198(7) .
Pt3 Pt2 2.9278(5) 3_566
Sn1 Cl1 2.374(3) .
Sn1 Cl2 2.392(3) .
Sn1 Pt3 2.5912(7) 3_566
Sn1 Pt2 2.8946(7) 3_566
Sn2 Cl4 2.386(3) .
Sn2 Cl5 2.392(3) .
Sn2 Cl3 2.416(3) .
Sn3 Cl8 2.368(3) .
Sn3 Cl6 2.381(3) .
Sn3 Cl7 2.407(3) .
C1 O1 1.135(12) .
C2 O2 1.154(11) .
C3 O3 1.140(12) .
P1 C119 1.781(11) .
P1 C101 1.790(10) .
P1 C113 1.798(11) .
P1 C107 1.800(9) .
C101 C102 1.381(14) .
C101 C106 1.382(14) .
C102 C103 1.388(15) .
C102 H102 0.9300 .
C103 C104 1.359(15) .
C103 H103 0.9300 .
C104 C105 1.369(16) .
C104 H104 0.9300 .
C105 C106 1.371(15) .
C105 H105 0.9300 .
C106 H106 0.9300 .
C107 C112 1.376(14) .
C107 C108 1.379(13) .
C108 C109 1.368(14) .
C108 H108 0.9300 .
C109 C110 1.364(16) .
C109 H109 0.9300 .
C110 C111 1.365(16) .
C110 H110 0.9300 .
C111 C112 1.380(14) .
C111 H111 0.9300 .
C112 H112 0.9300 .
C113 C118 1.371(14) .
C113 C114 1.384(13) .
C114 C115 1.374(15) .
C114 H114 0.9300 .
C115 C116 1.367(16) .
C115 H115 0.9300 .
C116 C117 1.362(15) .
C116 H116 0.9300 .
C117 C118 1.391(15) .
C117 H117 0.9300 .
C118 H118 0.9300 .
C119 C120 1.376(14) .
C119 C124 1.383(14) .
C120 C121 1.400(15) .
C120 H120 0.9300 .
C121 C122 1.360(17) .
C121 H121 0.9300 .
C122 C123 1.348(17) .
C122 H122 0.9300 .
C123 C124 1.375(16) .
C123 H123 0.9300 .
C124 H124 0.9300 .
P2 C213 1.785(10) .
P2 C219 1.788(11) .
P2 C201 1.792(11) .
P2 C207 1.795(11) .
C201 C206 1.382(16) .
C201 C202 1.390(17) .
C202 C203 1.394(17) .
C202 H202 0.9300 .
C203 C204 1.334(19) .
C203 H203 0.9300 .
C204 C205 1.38(2) .
C204 H204 0.9300 .
C205 C206 1.372(16) .
C205 H205 0.9300 .
C206 H206 0.9300 .
C207 C212 1.388(16) .
C207 C208 1.392(15) .
C208 C209 1.384(16) .
C208 H208 0.9300 .
C209 C210 1.362(18) .
C209 H209 0.9300 .
C210 C211 1.366(18) .
C210 H210 0.9300 .
C211 C212 1.383(16) .
C211 H211 0.9300 .
C212 H212 0.9300 .
C213 C214 1.375(13) .
C213 C218 1.377(14) .
C214 C215 1.390(15) .
C214 H214 0.9300 .
C215 C216 1.366(16) .
C215 H215 0.9300 .
C216 C217 1.346(16) .
C216 H216 0.9300 .
C217 C218 1.361(15) .
C217 H217 0.9300 .
C218 H218 0.9300 .
C219 C220 1.387(16) .
C219 C224 1.392(14) .
C220 C221 1.363(16) .
C220 H220 0.9300 .
C221 C222 1.368(17) .
C221 H221 0.9300 .
C222 C223 1.363(18) .
C222 H222 0.9300 .
C223 C224 1.376(16) .
C223 H223 0.9300 .
C224 H224 0.9300 .
N1 C301 1.103(13) .
C301 C302 1.439(14) .
C302 H30A 0.9600 .
C302 H30B 0.9600 .
C302 H30C 0.9600 .
N2 C401 1.115(11) .
C401 C402 1.437(12) .
C402 H40A 0.9600 .
C402 H40B 0.9600 .
C402 H40C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Pt1 Pt2 C2 -40.0(7) . .
Sn1 Pt1 Pt2 C2 -98.5(5) . .
Pt3 Pt1 Pt2 C2 108.9(5) . .
Sn3 Pt1 Pt2 C2 101.8(5) . .
Sn2 Pt1 Pt2 C2 32.7(5) . .
Pt2 Pt1 Pt2 C2 -174.6(5) 3_566 .
C1 Pt1 Pt2 Pt2 134.6(5) . 3_566
Sn1 Pt1 Pt2 Pt2 76.10(2) . 3_566
Pt3 Pt1 Pt2 Pt2 -76.521(16) . 3_566
Sn3 Pt1 Pt2 Pt2 -83.62(3) . 3_566
Sn2 Pt1 Pt2 Pt2 -152.69(2) . 3_566
C1 Pt1 Pt2 Sn2 -72.7(5) . .
Sn1 Pt1 Pt2 Sn2 -131.22(3) . .
Pt3 Pt1 Pt2 Sn2 76.17(2) . .
Sn3 Pt1 Pt2 Sn2 69.07(3) . .
Pt2 Pt1 Pt2 Sn2 152.69(2) 3_566 .
C1 Pt1 Pt2 Pt1 134.6(5) . 3_566
Sn1 Pt1 Pt2 Pt1 76.10(2) . 3_566
Pt3 Pt1 Pt2 Pt1 -76.520(16) . 3_566
Sn3 Pt1 Pt2 Pt1 -83.62(3) . 3_566
Sn2 Pt1 Pt2 Pt1 -152.69(2) . 3_566
Pt2 Pt1 Pt2 Pt1 0.0 3_566 3_566
C1 Pt1 Pt2 Sn1 -172.6(5) . 3_566
Sn1 Pt1 Pt2 Sn1 128.946(16) . 3_566
Pt3 Pt1 Pt2 Sn1 -23.672(18) . 3_566
Sn3 Pt1 Pt2 Sn1 -30.77(3) . 3_566
Sn2 Pt1 Pt2 Sn1 -99.84(2) . 3_566
Pt2 Pt1 Pt2 Sn1 52.848(17) 3_566 3_566
C1 Pt1 Pt2 Pt3 81.1(5) . 3_566
Sn1 Pt1 Pt2 Pt3 22.59(2) . 3_566
Pt3 Pt1 Pt2 Pt3 -130.023(13) . 3_566
Sn3 Pt1 Pt2 Pt3 -137.12(2) . 3_566
Sn2 Pt1 Pt2 Pt3 153.81(2) . 3_566
Pt2 Pt1 Pt2 Pt3 -53.503(14) 3_566 3_566
C1 Pt1 Pt2 Pt3 -148.9(5) . .
Sn1 Pt1 Pt2 Pt3 152.62(2) . .
Sn3 Pt1 Pt2 Pt3 -7.10(2) . .
Sn2 Pt1 Pt2 Pt3 -76.17(2) . .
Pt2 Pt1 Pt2 Pt3 76.521(16) 3_566 .
C1 Pt1 Pt2 Sn1 58.5(5) . .
Pt3 Pt1 Pt2 Sn1 -152.62(2) . .
Sn3 Pt1 Pt2 Sn1 -159.72(3) . .
Sn2 Pt1 Pt2 Sn1 131.22(3) . .
Pt2 Pt1 Pt2 Sn1 -76.10(2) 3_566 .
C1 Pt1 Pt3 C3 5.1(10) . .
Sn1 Pt1 Pt3 C3 -163.3(8) . .
Sn3 Pt1 Pt3 C3 38.5(8) . .
Sn2 Pt1 Pt3 C3 -71.6(8) . .
Pt2 Pt1 Pt3 C3 164.7(8) 3_566 .
Pt2 Pt1 Pt3 C3 -134.5(8) . .
C1 Pt1 Pt3 Sn1 169.8(7) . 3_566
Sn1 Pt1 Pt3 Sn1 1.33(4) . 3_566
Sn3 Pt1 Pt3 Sn1 -156.89(3) . 3_566
Sn2 Pt1 Pt3 Sn1 93.07(3) . 3_566
Pt2 Pt1 Pt3 Sn1 -30.63(2) 3_566 3_566
Pt2 Pt1 Pt3 Sn1 30.17(2) . 3_566
C1 Pt1 Pt3 Sn3 -33.3(7) . .
Sn1 Pt1 Pt3 Sn3 158.22(3) . .
Sn2 Pt1 Pt3 Sn3 -110.04(2) . .
Pt2 Pt1 Pt3 Sn3 126.26(2) 3_566 .
Pt2 Pt1 Pt3 Sn3 -172.94(2) . .
C1 Pt1 Pt3 Sn2 76.7(7) . .
Sn1 Pt1 Pt3 Sn2 -91.74(3) . .
Sn3 Pt1 Pt3 Sn2 110.04(2) . .
Pt2 Pt1 Pt3 Sn2 -123.700(18) 3_566 .
Pt2 Pt1 Pt3 Sn2 -62.898(17) . .
C1 Pt1 Pt3 Pt2 -159.6(7) . 3_566
Sn1 Pt1 Pt3 Pt2 31.96(2) . 3_566
Sn3 Pt1 Pt3 Pt2 -126.26(2) . 3_566
Sn2 Pt1 Pt3 Pt2 123.700(18) . 3_566
Pt2 Pt1 Pt3 Pt2 60.802(14) . 3_566
C1 Pt1 Pt3 Pt2 139.6(7) . .
Sn1 Pt1 Pt3 Pt2 -28.84(2) . .
Sn3 Pt1 Pt3 Pt2 172.94(2) . .
Sn2 Pt1 Pt3 Pt2 62.898(17) . .
Pt2 Pt1 Pt3 Pt2 -60.802(14) 3_566 .
C2 Pt2 Pt3 C3 19.7(6) . .
Pt2 Pt2 Pt3 C3 -137.8(5) 3_566 .
Sn2 Pt2 Pt3 C3 81.3(5) . .
Pt1 Pt2 Pt3 C3 -82.2(5) 3_566 .
Sn1 Pt2 Pt3 C3 -58.8(5) 3_566 .
Pt3 Pt2 Pt3 C3 -137.8(5) 3_566 .
Sn1 Pt2 Pt3 C3 172.5(5) . .
Pt1 Pt2 Pt3 C3 151.1(5) . .
C2 Pt2 Pt3 Sn1 78.5(4) . 3_566
Pt2 Pt2 Pt3 Sn1 -79.00(2) 3_566 3_566
Sn2 Pt2 Pt3 Sn1 140.11(3) . 3_566
Pt1 Pt2 Pt3 Sn1 -23.39(2) 3_566 3_566
Pt3 Pt2 Pt3 Sn1 -79.00(2) 3_566 3_566
Sn1 Pt2 Pt3 Sn1 -128.694(16) . 3_566
Pt1 Pt2 Pt3 Sn1 -150.07(2) . 3_566
C2 Pt2 Pt3 Sn3 -123.8(4) . .
Pt2 Pt2 Pt3 Sn3 78.70(3) 3_566 .
Sn2 Pt2 Pt3 Sn3 -62.19(3) . .
Pt1 Pt2 Pt3 Sn3 134.31(2) 3_566 .
Sn1 Pt2 Pt3 Sn3 157.70(3) 3_566 .
Pt3 Pt2 Pt3 Sn3 78.70(3) 3_566 .
Sn1 Pt2 Pt3 Sn3 29.01(3) . .
Pt1 Pt2 Pt3 Sn3 7.63(2) . .
C2 Pt2 Pt3 Pt1 -131.4(4) . .
Pt2 Pt2 Pt3 Pt1 71.072(16) 3_566 .
Sn2 Pt2 Pt3 Pt1 -69.815(19) . .
Pt1 Pt2 Pt3 Pt1 126.685(13) 3_566 .
Sn1 Pt2 Pt3 Pt1 150.07(2) 3_566 .
Pt3 Pt2 Pt3 Pt1 71.072(16) 3_566 .
Sn1 Pt2 Pt3 Pt1 21.379(17) . .
C2 Pt2 Pt3 Sn2 -61.6(4) . .
Pt2 Pt2 Pt3 Sn2 140.89(2) 3_566 .
Pt1 Pt2 Pt3 Sn2 -163.50(2) 3_566 .
Sn1 Pt2 Pt3 Sn2 -140.11(3) 3_566 .
Pt3 Pt2 Pt3 Sn2 140.89(2) 3_566 .
Sn1 Pt2 Pt3 Sn2 91.19(2) . .
Pt1 Pt2 Pt3 Sn2 69.815(19) . .
C2 Pt2 Pt3 Pt2 157.5(4) . 3_566
Sn2 Pt2 Pt3 Pt2 -140.89(2) . 3_566
Pt1 Pt2 Pt3 Pt2 55.613(13) 3_566 3_566
Sn1 Pt2 Pt3 Pt2 79.00(2) 3_566 3_566
Pt3 Pt2 Pt3 Pt2 0.0 3_566 3_566
Sn1 Pt2 Pt3 Pt2 -49.694(17) . 3_566
Pt1 Pt2 Pt3 Pt2 -71.072(16) . 3_566
C1 Pt1 Sn1 Cl1 -47.4(4) . .
Pt3 Pt1 Sn1 Cl1 126.49(7) . .
Sn3 Pt1 Sn1 Cl1 -149.58(9) . .
Sn2 Pt1 Sn1 Cl1 58.09(7) . .
Pt2 Pt1 Sn1 Cl1 158.36(7) 3_566 .
Pt2 Pt1 Sn1 Cl1 97.99(7) . .
C1 Pt1 Sn1 Cl2 57.7(4) . .
Pt3 Pt1 Sn1 Cl2 -128.42(8) . .
Sn3 Pt1 Sn1 Cl2 -44.49(11) . .
Sn2 Pt1 Sn1 Cl2 163.19(8) . .
Pt2 Pt1 Sn1 Cl2 -96.55(8) 3_566 .
Pt2 Pt1 Sn1 Cl2 -156.91(8) . .
C1 Pt1 Sn1 Pt3 -175.2(4) . 3_566
Pt3 Pt1 Sn1 Pt3 -1.35(4) . 3_566
Sn3 Pt1 Sn1 Pt3 82.58(8) . 3_566
Sn2 Pt1 Sn1 Pt3 -69.75(3) . 3_566
Pt2 Pt1 Sn1 Pt3 30.52(3) 3_566 3_566
Pt2 Pt1 Sn1 Pt3 -29.85(2) . 3_566
C1 Pt1 Sn1 Pt2 154.2(4) . 3_566
Pt3 Pt1 Sn1 Pt2 -31.87(2) . 3_566
Sn3 Pt1 Sn1 Pt2 52.06(7) . 3_566
Sn2 Pt1 Sn1 Pt2 -100.26(2) . 3_566
Pt2 Pt1 Sn1 Pt2 -60.363(15) . 3_566
C1 Pt1 Sn1 Pt2 -145.4(4) . .
Pt3 Pt1 Sn1 Pt2 28.49(2) . .
Sn3 Pt1 Sn1 Pt2 112.43(7) . .
Sn2 Pt1 Sn1 Pt2 -39.902(19) . .
Pt2 Pt1 Sn1 Pt2 60.363(15) 3_566 .
C2 Pt2 Sn1 Cl1 26.1(4) . .
Pt2 Pt2 Sn1 Cl1 -178.74(8) 3_566 .
Sn2 Pt2 Sn1 Cl1 -66.47(8) . .
Pt1 Pt2 Sn1 Cl1 127.06(8) 3_566 .
Sn1 Pt2 Sn1 Cl1 -178.74(8) 3_566 .
Pt3 Pt2 Sn1 Cl1 102.48(8) 3_566 .
Pt3 Pt2 Sn1 Cl1 -128.43(8) . .
Pt1 Pt2 Sn1 Cl1 -106.40(8) . .
C2 Pt2 Sn1 Cl2 -153.4(4) . .
Pt2 Pt2 Sn1 Cl2 1.79(19) 3_566 .
Sn2 Pt2 Sn1 Cl2 114.1(2) . .
Pt1 Pt2 Sn1 Cl2 -52.4(2) 3_566 .
Sn1 Pt2 Sn1 Cl2 1.79(19) 3_566 .
Pt3 Pt2 Sn1 Cl2 -77.0(2) 3_566 .
Pt3 Pt2 Sn1 Cl2 52.1(2) . .
Pt1 Pt2 Sn1 Cl2 74.13(19) . .
C2 Pt2 Sn1 Pt3 -76.4(4) . 3_566
Pt2 Pt2 Sn1 Pt3 78.777(19) 3_566 3_566
Sn2 Pt2 Sn1 Pt3 -168.95(2) . 3_566
Pt1 Pt2 Sn1 Pt3 24.577(18) 3_566 3_566
Sn1 Pt2 Sn1 Pt3 78.777(19) 3_566 3_566
Pt3 Pt2 Sn1 Pt3 129.093(15) . 3_566
Pt1 Pt2 Sn1 Pt3 151.12(2) . 3_566
C2 Pt2 Sn1 Pt1 132.5(4) . .
Pt2 Pt2 Sn1 Pt1 -72.341(18) 3_566 .
Sn2 Pt2 Sn1 Pt1 39.93(2) . .
Pt1 Pt2 Sn1 Pt1 -126.541(15) 3_566 .
Sn1 Pt2 Sn1 Pt1 -72.341(18) 3_566 .
Pt3 Pt2 Sn1 Pt1 -151.12(2) 3_566 .
Pt3 Pt2 Sn1 Pt1 -22.025(17) . .
C2 Pt2 Sn1 Pt2 -155.1(4) . 3_566
Sn2 Pt2 Sn1 Pt2 112.27(2) . 3_566
Pt1 Pt2 Sn1 Pt2 -54.200(15) 3_566 3_566
Sn1 Pt2 Sn1 Pt2 0.0 3_566 3_566
Pt3 Pt2 Sn1 Pt2 -78.777(19) 3_566 3_566
Pt3 Pt2 Sn1 Pt2 50.316(14) . 3_566
Pt1 Pt2 Sn1 Pt2 72.341(18) . 3_566
C2 Pt2 Sn2 Cl4 41.3(3) . .
Pt2 Pt2 Sn2 Cl4 -132.77(8) 3_566 .
Pt1 Pt2 Sn2 Cl4 -50.06(10) 3_566 .
Sn1 Pt2 Sn2 Cl4 -64.09(8) 3_566 .
Pt3 Pt2 Sn2 Cl4 150.01(8) 3_566 .
Pt3 Pt2 Sn2 Cl4 -95.60(8) . .
Sn1 Pt2 Sn2 Cl4 165.79(8) . .
Pt1 Pt2 Sn2 Cl4 -158.08(8) . .
C2 Pt2 Sn2 Cl5 -57.6(3) . .
Pt2 Pt2 Sn2 Cl5 128.35(8) 3_566 .
Pt1 Pt2 Sn2 Cl5 -148.94(8) 3_566 .
Sn1 Pt2 Sn2 Cl5 -162.98(8) 3_566 .
Pt3 Pt2 Sn2 Cl5 51.13(9) 3_566 .
Pt3 Pt2 Sn2 Cl5 165.52(8) . .
Sn1 Pt2 Sn2 Cl5 66.90(8) . .
Pt1 Pt2 Sn2 Cl5 103.03(8) . .
C2 Pt2 Sn2 Cl3 170.8(4) . .
Pt2 Pt2 Sn2 Cl3 -3.3(2) 3_566 .
Pt1 Pt2 Sn2 Cl3 79.5(2) 3_566 .
Sn1 Pt2 Sn2 Cl3 65.4(2) 3_566 .
Pt3 Pt2 Sn2 Cl3 -80.5(2) 3_566 .
Pt3 Pt2 Sn2 Cl3 33.9(2) . .
Sn1 Pt2 Sn2 Cl3 -64.7(2) . .
Pt1 Pt2 Sn2 Cl3 -28.6(2) . .
C2 Pt2 Sn2 Pt1 -160.6(3) . .
Pt2 Pt2 Sn2 Pt1 25.31(2) 3_566 .
Pt1 Pt2 Sn2 Pt1 108.03(5) 3_566 .
Sn1 Pt2 Sn2 Pt1 93.99(2) 3_566 .
Pt3 Pt2 Sn2 Pt1 -51.91(4) 3_566 .
Pt3 Pt2 Sn2 Pt1 62.486(14) . .
Sn1 Pt2 Sn2 Pt1 -36.129(18) . .
C2 Pt2 Sn2 Pt3 136.9(3) . .
Pt2 Pt2 Sn2 Pt3 -37.17(2) 3_566 .
Pt1 Pt2 Sn2 Pt3 45.54(5) 3_566 .
Sn1 Pt2 Sn2 Pt3 31.503(19) 3_566 .
Pt3 Pt2 Sn2 Pt3 -114.39(3) 3_566 .
Sn1 Pt2 Sn2 Pt3 -98.616(19) . .
Pt1 Pt2 Sn2 Pt3 -62.486(14) . .
C1 Pt1 Sn2 Cl4 -158.7(4) . .
Sn1 Pt1 Sn2 Cl4 106.71(18) . .
Pt3 Pt1 Sn2 Cl4 -11.05(18) . .
Sn3 Pt1 Sn2 Cl4 -64.74(18) . .
Pt2 Pt1 Sn2 Cl4 39.82(18) 3_566 .
Pt2 Pt1 Sn2 Cl4 62.40(18) . .
C1 Pt1 Sn2 Cl5 42.7(3) . .
Sn1 Pt1 Sn2 Cl5 -51.88(8) . .
Pt3 Pt1 Sn2 Cl5 -169.64(8) . .
Sn3 Pt1 Sn2 Cl5 136.66(8) . .
Pt2 Pt1 Sn2 Cl5 -118.77(8) 3_566 .
Pt2 Pt1 Sn2 Cl5 -96.19(8) . .
C1 Pt1 Sn2 Cl3 -51.8(3) . .
Sn1 Pt1 Sn2 Cl3 -146.34(8) . .
Pt3 Pt1 Sn2 Cl3 95.90(8) . .
Sn3 Pt1 Sn2 Cl3 42.21(8) . .
Pt2 Pt1 Sn2 Cl3 146.77(8) 3_566 .
Pt2 Pt1 Sn2 Cl3 169.36(8) . .
C1 Pt1 Sn2 Pt2 138.9(3) . .
Sn1 Pt1 Sn2 Pt2 44.31(2) . .
Pt3 Pt1 Sn2 Pt2 -73.452(15) . .
Sn3 Pt1 Sn2 Pt2 -127.15(2) . .
Pt2 Pt1 Sn2 Pt2 -22.59(2) 3_566 .
C1 Pt1 Sn2 Pt3 -147.7(3) . .
Sn1 Pt1 Sn2 Pt3 117.76(2) . .
Sn3 Pt1 Sn2 Pt3 -53.693(18) . .
Pt2 Pt1 Sn2 Pt3 50.867(15) 3_566 .
Pt2 Pt1 Sn2 Pt3 73.452(15) . .
C3 Pt3 Sn2 Cl4 -33.8(3) . .
Sn1 Pt3 Sn2 Cl4 61.39(8) 3_566 .
Sn3 Pt3 Sn2 Cl4 -128.64(7) . .
Pt1 Pt3 Sn2 Cl4 175.39(8) . .
Pt2 Pt3 Sn2 Cl4 128.40(7) 3_566 .
Pt2 Pt3 Sn2 Cl4 97.62(7) . .
C3 Pt3 Sn2 Cl5 -178.2(4) . .
Sn1 Pt3 Sn2 Cl5 -83.1(2) 3_566 .
Sn3 Pt3 Sn2 Cl5 86.9(2) . .
Pt1 Pt3 Sn2 Cl5 30.9(2) . .
Pt2 Pt3 Sn2 Cl5 -16.1(2) 3_566 .
Pt2 Pt3 Sn2 Cl5 -46.8(2) . .
C3 Pt3 Sn2 Cl3 61.1(3) . .
Sn1 Pt3 Sn2 Cl3 156.28(8) 3_566 .
Sn3 Pt3 Sn2 Cl3 -33.75(8) . .
Pt1 Pt3 Sn2 Cl3 -89.72(8) . .
Pt2 Pt3 Sn2 Cl3 -136.71(8) 3_566 .
Pt2 Pt3 Sn2 Cl3 -167.49(8) . .
C3 Pt3 Sn2 Pt2 -131.4(3) . .
Sn1 Pt3 Sn2 Pt2 -36.23(2) 3_566 .
Sn3 Pt3 Sn2 Pt2 133.74(2) . .
Pt1 Pt3 Sn2 Pt2 77.767(16) . .
Pt2 Pt3 Sn2 Pt2 30.776(18) 3_566 .
C3 Pt3 Sn2 Pt1 150.9(3) . .
Sn1 Pt3 Sn2 Pt1 -114.00(2) 3_566 .
Sn3 Pt3 Sn2 Pt1 55.969(19) . .
Pt2 Pt3 Sn2 Pt1 -46.990(15) 3_566 .
Pt2 Pt3 Sn2 Pt1 -77.767(16) . .
C3 Pt3 Sn3 Cl8 85.2(4) . .
Sn1 Pt3 Sn3 Cl8 -15.35(15) 3_566 .
Pt1 Pt3 Sn3 Cl8 -112.52(12) . .
Sn2 Pt3 Sn3 Cl8 -166.58(12) . .
Pt2 Pt3 Sn3 Cl8 -66.75(12) 3_566 .
Pt2 Pt3 Sn3 Cl8 -120.28(12) . .
C3 Pt3 Sn3 Cl6 -131.6(4) . .
Sn1 Pt3 Sn3 Cl6 127.9(2) 3_566 .
Pt1 Pt3 Sn3 Cl6 30.7(2) . .
Sn2 Pt3 Sn3 Cl6 -23.4(2) . .
Pt2 Pt3 Sn3 Cl6 76.5(2) 3_566 .
Pt2 Pt3 Sn3 Cl6 22.9(2) . .
C3 Pt3 Sn3 Cl7 -14.4(4) . .
Sn1 Pt3 Sn3 Cl7 -115.01(11) 3_566 .
Pt1 Pt3 Sn3 Cl7 147.82(10) . .
Sn2 Pt3 Sn3 Cl7 93.76(10) . .
Pt2 Pt3 Sn3 Cl7 -166.41(10) 3_566 .
Pt2 Pt3 Sn3 Cl7 140.06(10) . .
C3 Pt3 Sn3 Pt1 -162.3(4) . .
Sn1 Pt3 Sn3 Pt1 97.17(7) 3_566 .
Sn2 Pt3 Sn3 Pt1 -54.059(18) . .
Pt2 Pt3 Sn3 Pt1 45.773(16) 3_566 .
Pt2 Pt3 Sn3 Pt1 -7.76(2) . .
C1 Pt1 Sn3 Cl8 -103.1(4) . .
Sn1 Pt1 Sn3 Cl8 -1.35(15) . .
Pt3 Pt1 Sn3 Cl8 93.89(13) . .
Sn2 Pt1 Sn3 Cl8 151.87(13) . .
Pt2 Pt1 Sn3 Cl8 45.65(13) 3_566 .
Pt2 Pt1 Sn3 Cl8 101.26(13) . .
C1 Pt1 Sn3 Cl6 -3.6(4) . .
Sn1 Pt1 Sn3 Cl6 98.20(12) . .
Pt3 Pt1 Sn3 Cl6 -166.57(10) . .
Sn2 Pt1 Sn3 Cl6 -108.58(10) . .
Pt2 Pt1 Sn3 Cl6 145.20(10) 3_566 .
Pt2 Pt1 Sn3 Cl6 -159.19(10) . .
C1 Pt1 Sn3 Cl7 98.7(4) . .
Sn1 Pt1 Sn3 Cl7 -159.51(16) . .
Pt3 Pt1 Sn3 Cl7 -64.28(16) . .
Sn2 Pt1 Sn3 Cl7 -6.29(16) . .
Pt2 Pt1 Sn3 Cl7 -112.51(16) 3_566 .
Pt2 Pt1 Sn3 Cl7 -56.90(16) . .
C1 Pt1 Sn3 Pt3 163.0(4) . .
Sn1 Pt1 Sn3 Pt3 -95.24(7) . .
Sn2 Pt1 Sn3 Pt3 57.983(19) . .
Pt2 Pt1 Sn3 Pt3 -48.233(17) 3_566 .
Pt2 Pt1 Sn3 Pt3 7.37(2) . .
Sn1 Pt1 C1 O1 52(27) . .
Pt3 Pt1 C1 O1 -118(27) . .
Sn3 Pt1 C1 O1 -146(27) . .
Sn2 Pt1 C1 O1 -52(27) . .
Pt2 Pt1 C1 O1 95(27) 3_566 .
Pt2 Pt1 C1 O1 2(28) . .
Pt2 Pt2 C2 O2 94(20) 3_566 .
Sn2 Pt2 C2 O2 -71(20) . .
Pt1 Pt2 C2 O2 86(20) 3_566 .
Sn1 Pt2 C2 O2 33(21) 3_566 .
Pt3 Pt2 C2 O2 142(20) 3_566 .
Pt3 Pt2 C2 O2 -20(21) . .
Sn1 Pt2 C2 O2 -167(20) . .
Pt1 Pt2 C2 O2 -98(20) . .
Sn1 Pt3 C3 O3 -101(24) 3_566 .
Sn3 Pt3 C3 O3 99(24) . .
Pt1 Pt3 C3 O3 65(24) . .
Sn2 Pt3 C3 O3 6(24) . .
Pt2 Pt3 C3 O3 -140(24) 3_566 .
Pt2 Pt3 C3 O3 -52(24) . .
C119 P1 C101 C102 90.0(10) . .
C113 P1 C101 C102 -148.7(9) . .
C107 P1 C101 C102 -28.8(11) . .
C119 P1 C101 C106 -82.1(10) . .
C113 P1 C101 C106 39.2(11) . .
C107 P1 C101 C106 159.1(9) . .
C106 C101 C102 C103 -0.2(17) . .
P1 C101 C102 C103 -172.3(9) . .
C101 C102 C103 C104 2.3(18) . .
C102 C103 C104 C105 -2(2) . .
C103 C104 C105 C106 0(2) . .
C104 C105 C106 C101 2.4(19) . .
C102 C101 C106 C105 -2.3(18) . .
P1 C101 C106 C105 169.9(10) . .
C119 P1 C107 C112 -43.9(10) . .
C101 P1 C107 C112 74.4(9) . .
C113 P1 C107 C112 -165.6(8) . .
C119 P1 C107 C108 137.5(9) . .
C101 P1 C107 C108 -104.2(9) . .
C113 P1 C107 C108 15.8(10) . .
C112 C107 C108 C109 -0.1(16) . .
P1 C107 C108 C109 178.5(8) . .
C107 C108 C109 C110 -0.2(17) . .
C108 C109 C110 C111 0.3(19) . .
C109 C110 C111 C112 0.0(18) . .
C108 C107 C112 C111 0.4(16) . .
P1 C107 C112 C111 -178.3(9) . .
C110 C111 C112 C107 -0.3(18) . .
C119 P1 C113 C118 166.7(9) . .
C101 P1 C113 C118 47.7(10) . .
C107 P1 C113 C118 -73.5(10) . .
C119 P1 C113 C114 -19.4(10) . .
C101 P1 C113 C114 -138.3(9) . .
C107 P1 C113 C114 100.4(9) . .
C118 C113 C114 C115 0.5(17) . .
P1 C113 C114 C115 -173.4(9) . .
C113 C114 C115 C116 1.5(18) . .
C114 C115 C116 C117 -2.1(19) . .
C115 C116 C117 C118 0.8(19) . .
C114 C113 C118 C117 -1.8(17) . .
P1 C113 C118 C117 172.2(9) . .
C116 C117 C118 C113 1.2(18) . .
C101 P1 C119 C120 -149.4(9) . .
C113 P1 C119 C120 90.9(10) . .
C107 P1 C119 C120 -29.1(11) . .
C101 P1 C119 C124 29.8(11) . .
C113 P1 C119 C124 -90.0(10) . .
C107 P1 C119 C124 150.1(9) . .
C124 C119 C120 C121 -1.4(18) . .
P1 C119 C120 C121 177.8(9) . .
C119 C120 C121 C122 2(2) . .
C120 C121 C122 C123 0(2) . .
C121 C122 C123 C124 -3(2) . .
C122 C123 C124 C119 3(2) . .
C120 C119 C124 C123 -0.8(19) . .
P1 C119 C124 C123 -180.0(10) . .
C213 P2 C201 C206 81.4(10) . .
C219 P2 C201 C206 -37.4(11) . .
C207 P2 C201 C206 -159.5(9) . .
C213 P2 C201 C202 -95.8(10) . .
C219 P2 C201 C202 145.4(9) . .
C207 P2 C201 C202 23.3(11) . .
C206 C201 C202 C203 1.1(17) . .
P2 C201 C202 C203 178.3(9) . .
C201 C202 C203 C204 -0.5(19) . .
C202 C203 C204 C205 -1(2) . .
C203 C204 C205 C206 2(2) . .
C204 C205 C206 C201 -1(2) . .
C202 C201 C206 C205 -0.3(18) . .
P2 C201 C206 C205 -177.6(10) . .
C213 P2 C207 C212 171.2(9) . .
C219 P2 C207 C212 -69.8(11) . .
C201 P2 C207 C212 51.9(11) . .
C213 P2 C207 C208 -7.8(11) . .
C219 P2 C207 C208 111.1(10) . .
C201 P2 C207 C208 -127.2(9) . .
C212 C207 C208 C209 -1.1(17) . .
P2 C207 C208 C209 177.9(9) . .
C207 C208 C209 C210 0.5(18) . .
C208 C209 C210 C211 -0.3(19) . .
C209 C210 C211 C212 0.7(19) . .
C210 C211 C212 C207 -1.4(19) . .
C208 C207 C212 C211 1.6(18) . .
P2 C207 C212 C211 -177.4(9) . .
C219 P2 C213 C214 135.5(9) . .
C201 P2 C213 C214 15.1(11) . .
C207 P2 C213 C214 -103.4(9) . .
C219 P2 C213 C218 -48.5(10) . .
C201 P2 C213 C218 -169.0(9) . .
C207 P2 C213 C218 72.5(10) . .
C218 C213 C214 C215 2.6(16) . .
P2 C213 C214 C215 178.5(8) . .
C213 C214 C215 C216 -3.7(17) . .
C214 C215 C216 C217 3.6(18) . .
C215 C216 C217 C218 -2.3(19) . .
C216 C217 C218 C213 1.2(18) . .
C214 C213 C218 C217 -1.3(17) . .
P2 C213 C218 C217 -177.3(9) . .
C213 P2 C219 C220 -35.0(11) . .
C201 P2 C219 C220 84.8(11) . .
C207 P2 C219 C220 -154.8(10) . .
C213 P2 C219 C224 147.6(9) . .
C201 P2 C219 C224 -92.5(10) . .
C207 P2 C219 C224 27.9(11) . .
C224 C219 C220 C221 0.4(19) . .
P2 C219 C220 C221 -177.0(10) . .
C219 C220 C221 C222 -2(2) . .
C220 C221 C222 C223 2(2) . .
C221 C222 C223 C224 -1(2) . .
C222 C223 C224 C219 -0.2(19) . .
C220 C219 C224 C223 0.7(17) . .
P2 C219 C224 C223 178.0(9) . .
