#------------------------------------------------------------------------------
#$Date: 2016-04-05 20:39:47 +0300 (Tue, 05 Apr 2016) $
#$Revision: 181725 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/78/7037834.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7037834
loop_
_publ_author_name
'Roselló-Merino, Marta'
'Mansell, Stephen M.'
_publ_section_title
;
 Synthesis and reactivity of fluorenyl-tethered N-heterocyclic
 stannylenes.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6282
_journal_page_last               6293
_journal_paper_doi               10.1039/c5dt04060d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C74 H90 N4 Rh2 Sn2'
_chemical_formula_sum            'C74 H90 N4 Rh2 Sn2'
_chemical_formula_weight         1478.69
_chemical_properties_physical    'Air-sensitive, Moisture-sensitive'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2015-11-26
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2015.08.17 svn.r3210 for OlexSys, GUI svn.r5083)
;
_audit_update_record
;
2015-12-09 deposited with the CCDC.
2015-12-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 101.213(5)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   8.6300(8)
_cell_length_b                   30.633(3)
_cell_length_c                   11.9259(10)
_cell_measurement_reflns_used    2922
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      21.866
_cell_measurement_theta_min      2.191
_cell_volume                     3092.6(5)
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      100.0
_diffrn_detector_area_resol_mean 8
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.964
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1184
_diffrn_reflns_av_unetI/netI     0.1477
_diffrn_reflns_Laue_measured_fraction_full 0.969
_diffrn_reflns_Laue_measured_fraction_max 0.964
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            30195
_diffrn_reflns_point_group_measured_fraction_full 0.969
_diffrn_reflns_point_group_measured_fraction_max 0.964
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         27.557
_diffrn_reflns_theta_min         2.496
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.370
_exptl_absorpt_correction_T_max  0.6146
_exptl_absorpt_correction_T_min  0.4880
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0921 before and 0.0795 after correction.
The Ratio of minimum to maximum transmission is 0.7940.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.588
_exptl_crystal_description       block
_exptl_crystal_F_000             1504
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.04
_refine_diff_density_max         5.579
_refine_diff_density_min         -2.025
_refine_diff_density_rms         0.309
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     374
_refine_ls_number_reflns         6896
_refine_ls_number_restraints     444
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.1663
_refine_ls_R_factor_gt           0.1046
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0913P)²+88.8895P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2380
_refine_ls_wR_factor_ref         0.2656
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4279
_reflns_number_total             6896
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt04060d2.cif
_cod_data_source_block           9
_cod_depositor_comments
'Adding full bibliography for 7037826--7037834.cif.'
_cod_database_code               7037834
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.947
_shelx_estimated_absorpt_t_min   0.771
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C5) \\sim Ueq: with sigma of 0.003 and sigma for terminal atoms of 0.003
3. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4.a Ternary CH refined with riding coordinates:
 C24(H24), C27(H27), C30(H30), C31(H31), C34(H34), C35(H35)
4.b Secondary CH2 refined with riding coordinates:
 C14(H14A,H14B), C15(H15A,H15B), C16(H16A,H16B), C17(H17A,H17B), C32(H32A,
 H32B), C33(H33A,H33B), C36(H36A,H36B), C37(H37A,H37B)
4.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C9(H9), C10(H10), C11(H11), C12(H12),
 C20(H20), C21(H21), C22(H22)
4.d Idealised Me refined as rotating group:
 C25(H25A,H25B,H25C), C26(H26A,H26B,H26C), C28(H28A,H28B,H28C), C29(H29A,H29B,
 H29C)
;
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Sn1 Sn 0.66343(10) 0.51182(3) 0.44159(7) 0.0127(2) Uani 1 1 d . U
Rh1 Rh 0.89285(12) 0.32415(3) 0.33437(9) 0.0150(3) Uani 1 1 d . U
N1 N 0.4759(13) 0.4606(3) 0.4291(9) 0.014(2) Uani 1 1 d . U
N2 N 0.5073(12) 0.5329(3) 0.2957(9) 0.014(2) Uani 1 1 d . U
C1 C 0.7224(15) 0.3565(4) 0.4201(11) 0.016(2) Uani 1 1 d . U
C2 C 0.8732(16) 0.3586(4) 0.5040(11) 0.015(2) Uani 1 1 d . U
C3 C 0.9672(17) 0.3938(4) 0.5489(11) 0.019(2) Uani 1 1 d . U
H3 H 0.9357 0.4231 0.5312 0.023 Uiso 1 1 calc R .
C4 C 1.1093(17) 0.3838(5) 0.6207(11) 0.020(2) Uani 1 1 d . U
H4 H 1.1749 0.4071 0.6540 0.024 Uiso 1 1 calc R .
C5 C 1.1611(16) 0.3408(4) 0.6465(12) 0.017(2) Uani 1 1 d . U
H5 H 1.2603 0.3359 0.6955 0.020 Uiso 1 1 calc R .
C6 C 1.0730(16) 0.3068(5) 0.6031(11) 0.017(2) Uani 1 1 d . U
H6 H 1.1088 0.2778 0.6209 0.021 Uiso 1 1 calc R .
C7 C 0.9246(15) 0.3145(4) 0.5300(10) 0.014(2) Uani 1 1 d . U
C8 C 0.7963(15) 0.2851(4) 0.4771(11) 0.015(2) Uani 1 1 d . U
C9 C 0.7848(15) 0.2390(4) 0.4740(12) 0.016(2) Uani 1 1 d . U
H9 H 0.8695 0.2215 0.5126 0.020 Uiso 1 1 calc R .
C10 C 0.6528(16) 0.2204(5) 0.4158(11) 0.019(3) Uani 1 1 d . U
H10 H 0.6430 0.1895 0.4175 0.023 Uiso 1 1 calc R .
C11 C 0.5254(17) 0.2455(5) 0.3510(12) 0.022(3) Uani 1 1 d . U
H11 H 0.4361 0.2309 0.3082 0.027 Uiso 1 1 calc R .
C12 C 0.5310(15) 0.2908(4) 0.3499(11) 0.016(2) Uani 1 1 d . U
H12 H 0.4462 0.3076 0.3089 0.019 Uiso 1 1 calc R .
C13 C 0.6715(16) 0.3110(4) 0.4140(11) 0.017(2) Uani 1 1 d . U
C14 C 0.6301(18) 0.3959(4) 0.3731(12) 0.021(3) Uani 1 1 d . U
H14A H 0.5601 0.3880 0.2999 0.025 Uiso 1 1 calc R .
H14B H 0.7042 0.4186 0.3568 0.025 Uiso 1 1 calc R .
C15 C 0.5291(16) 0.4149(4) 0.4544(10) 0.014(2) Uani 1 1 d . U
H15A H 0.4348 0.3962 0.4512 0.017 Uiso 1 1 calc R .
H15B H 0.5910 0.4136 0.5335 0.017 Uiso 1 1 calc R .
C16 C 0.3728(15) 0.4647(4) 0.3133(11) 0.015(2) Uani 1 1 d . U
H16A H 0.2687 0.4512 0.3135 0.018 Uiso 1 1 calc R .
H16B H 0.4219 0.4492 0.2561 0.018 Uiso 1 1 calc R .
C17 C 0.3521(15) 0.5121(4) 0.2823(11) 0.015(2) Uani 1 1 d . U
H17A H 0.2950 0.5150 0.2022 0.018 Uiso 1 1 calc R .
H17B H 0.2889 0.5266 0.3325 0.018 Uiso 1 1 calc R .
C18 C 0.5432(15) 0.5589(4) 0.2047(10) 0.012(2) Uani 1 1 d . U
C19 C 0.4584(16) 0.5979(4) 0.1732(11) 0.016(2) Uani 1 1 d . U
C20 C 0.4984(17) 0.6228(4) 0.0848(11) 0.018(3) Uani 1 1 d . U
H20 H 0.4395 0.6485 0.0611 0.022 Uiso 1 1 calc R .
C21 C 0.6197(17) 0.6115(4) 0.0305(12) 0.020(3) Uani 1 1 d . U
H21 H 0.6472 0.6297 -0.0271 0.023 Uiso 1 1 calc R .
C22 C 0.6999(17) 0.5732(4) 0.0620(11) 0.017(3) Uani 1 1 d . U
H22 H 0.7824 0.5650 0.0238 0.020 Uiso 1 1 calc R .
C23 C 0.6649(16) 0.5459(4) 0.1481(11) 0.015(2) Uani 1 1 d . U
C24 C 0.3260(17) 0.6139(4) 0.2285(11) 0.019(2) Uani 1 1 d . U
H24 H 0.3168 0.5930 0.2915 0.023 Uiso 1 1 calc R .
C25 C 0.361(2) 0.6595(5) 0.2829(14) 0.029(3) Uani 1 1 d . U
H25A H 0.4616 0.6586 0.3382 0.044 Uiso 1 1 calc GR .
H25B H 0.2761 0.6680 0.3219 0.044 Uiso 1 1 calc GR .
H25C H 0.3692 0.6808 0.2230 0.044 Uiso 1 1 calc GR .
C26 C 0.1657(18) 0.6144(5) 0.1448(13) 0.026(3) Uani 1 1 d . U
H26A H 0.1708 0.6346 0.0820 0.039 Uiso 1 1 calc GR .
H26B H 0.0829 0.6238 0.1852 0.039 Uiso 1 1 calc GR .
H26C H 0.1414 0.5850 0.1140 0.039 Uiso 1 1 calc GR .
C27 C 0.7495(16) 0.5021(4) 0.1667(11) 0.016(2) Uani 1 1 d . U
H27 H 0.6998 0.4852 0.2222 0.020 Uiso 1 1 calc R .
C28 C 0.9268(17) 0.5077(5) 0.2209(14) 0.028(3) Uani 1 1 d . U
H28A H 0.9797 0.5238 0.1681 0.042 Uiso 1 1 calc GR .
H28B H 0.9758 0.4789 0.2360 0.042 Uiso 1 1 calc GR .
H28C H 0.9369 0.5239 0.2928 0.042 Uiso 1 1 calc GR .
C29 C 0.7299(18) 0.4755(5) 0.0586(12) 0.024(3) Uani 1 1 d . U
H29A H 0.6173 0.4706 0.0286 0.037 Uiso 1 1 calc GR .
H29B H 0.7835 0.4474 0.0751 0.037 Uiso 1 1 calc GR .
H29C H 0.7763 0.4913 0.0017 0.037 Uiso 1 1 calc GR .
C30 C 0.7998(17) 0.3285(5) 0.1577(11) 0.021(2) Uani 1 1 d . U
H30 H 0.6821 0.3310 0.1374 0.025 Uiso 1 1 calc R .
C31 C 0.8782(16) 0.3675(5) 0.1947(12) 0.021(2) Uani 1 1 d . U
H31 H 0.8053 0.3927 0.1976 0.025 Uiso 1 1 calc R .
C32 C 1.0350(17) 0.3806(5) 0.1764(13) 0.023(3) Uani 1 1 d . U
H32A H 1.0703 0.4066 0.2237 0.028 Uiso 1 1 calc R .
H32B H 1.0271 0.3888 0.0953 0.028 Uiso 1 1 calc R .
C33 C 1.1576(17) 0.3447(5) 0.2062(12) 0.024(3) Uani 1 1 d . U
H33A H 1.2632 0.3580 0.2309 0.028 Uiso 1 1 calc R .
H33B H 1.1600 0.3269 0.1372 0.028 Uiso 1 1 calc R .
C34 C 1.1213(17) 0.3147(5) 0.3030(12) 0.020(2) Uani 1 1 d . U
H34 H 1.2059 0.3143 0.3734 0.024 Uiso 1 1 calc R .
C35 C 1.0434(17) 0.2761(5) 0.2804(11) 0.021(2) Uani 1 1 d . U
H35 H 1.0793 0.2526 0.3377 0.025 Uiso 1 1 calc R .
C36 C 0.9661(19) 0.2597(5) 0.1634(12) 0.027(3) Uani 1 1 d . U
H36A H 1.0489 0.2487 0.1237 0.032 Uiso 1 1 calc R .
H36B H 0.8959 0.2349 0.1724 0.032 Uiso 1 1 calc R .
C37 C 0.8710(18) 0.2942(5) 0.0903(13) 0.026(3) Uani 1 1 d . U
H37A H 0.7846 0.2798 0.0362 0.031 Uiso 1 1 calc R .
H37B H 0.9399 0.3090 0.0447 0.031 Uiso 1 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 Sn1 N1 80.6(4) 3_666
N2 Sn1 N1 79.6(4) .
N2 Sn1 N1 96.2(4) 3_666
C1 Rh1 C2 38.3(5) .
C1 Rh1 C7 62.9(5) .
C1 Rh1 C8 61.8(5) .
C1 Rh1 C13 37.5(5) .
C2 Rh1 C8 60.4(4) .
C2 Rh1 C13 61.1(5) .
C7 Rh1 C2 36.2(4) .
C7 Rh1 C8 36.6(5) .
C7 Rh1 C13 60.8(5) .
C13 Rh1 C8 35.5(5) .
C30 Rh1 C1 106.2(5) .
C30 Rh1 C2 139.9(5) .
C30 Rh1 C7 164.4(5) .
C30 Rh1 C8 129.3(5) .
C30 Rh1 C13 103.6(5) .
C30 Rh1 C31 38.7(5) .
C30 Rh1 C35 83.1(5) .
C31 Rh1 C1 98.1(5) .
C31 Rh1 C2 113.5(5) .
C31 Rh1 C7 148.4(5) .
C31 Rh1 C8 155.6(5) .
C31 Rh1 C13 120.1(5) .
C31 Rh1 C35 98.1(5) .
C34 Rh1 C1 152.6(5) .
C34 Rh1 C2 116.7(5) .
C34 Rh1 C7 103.4(5) .
C34 Rh1 C8 122.3(5) .
C34 Rh1 C13 157.4(5) .
C34 Rh1 C30 91.1(5) .
C34 Rh1 C31 82.0(5) .
C34 Rh1 C35 37.4(5) .
C35 Rh1 C1 162.6(5) .
C35 Rh1 C2 136.6(5) .
C35 Rh1 C7 104.8(5) .
C35 Rh1 C8 100.8(5) .
C35 Rh1 C13 126.7(5) .
Sn1 N1 Sn1 99.4(4) 3_666
C15 N1 Sn1 117.1(8) .
C15 N1 Sn1 113.1(7) 3_666
C15 N1 C16 111.8(10) .
C16 N1 Sn1 107.2(7) 3_666
C16 N1 Sn1 107.1(7) .
C17 N2 Sn1 112.7(8) .
C18 N2 Sn1 127.3(8) .
C18 N2 C17 119.3(10) .
C2 C1 Rh1 75.7(7) .
C2 C1 C14 123.5(12) .
C13 C1 Rh1 76.6(7) .
C13 C1 C2 107.0(11) .
C13 C1 C14 128.3(12) .
C14 C1 Rh1 123.2(9) .
C1 C2 Rh1 66.0(7) .
C3 C2 Rh1 123.5(9) .
C3 C2 C1 131.6(12) .
C3 C2 C7 120.9(13) .
C7 C2 Rh1 71.8(7) .
C7 C2 C1 107.3(11) .
C2 C3 H3 121.8 .
C4 C3 C2 116.5(13) .
C4 C3 H3 121.8 .
C3 C4 H4 118.4 .
C3 C4 C5 123.2(13) .
C5 C4 H4 118.4 .
C4 C5 H5 119.5 .
C6 C5 C4 120.9(14) .
C6 C5 H5 119.5 .
C5 C6 H6 120.4 .
C5 C6 C7 119.1(13) .
C7 C6 H6 120.4 .
C2 C7 Rh1 72.0(7) .
C2 C7 C8 108.0(11) .
C6 C7 Rh1 123.7(9) .
C6 C7 C2 119.4(12) .
C6 C7 C8 132.5(12) .
C8 C7 Rh1 73.4(7) .
C7 C8 Rh1 69.9(7) .
C9 C8 Rh1 121.3(8) .
C9 C8 C7 131.7(12) .
C9 C8 C13 119.9(12) .
C13 C8 Rh1 71.0(7) .
C13 C8 C7 108.2(11) .
C8 C9 H9 120.5 .
C10 C9 C8 119.1(13) .
C10 C9 H9 120.5 .
C9 C10 H10 118.9 .
C9 C10 C11 122.3(14) .
C11 C10 H10 118.9 .
C10 C11 H11 119.5 .
C12 C11 C10 121.1(13) .
C12 C11 H11 119.5 .
C11 C12 H12 121.6 .
C11 C12 C13 116.9(12) .
C13 C12 H12 121.6 .
C1 C13 Rh1 65.9(7) .
C8 C13 Rh1 73.6(7) .
C8 C13 C1 108.4(12) .
C8 C13 C12 120.7(12) .
C12 C13 Rh1 122.0(9) .
C12 C13 C1 130.7(12) .
C1 C14 H14A 108.9 .
C1 C14 H14B 108.9 .
C1 C14 C15 113.2(11) .
H14A C14 H14B 107.7 .
C15 C14 H14A 108.9 .
C15 C14 H14B 108.9 .
N1 C15 C14 114.8(10) .
N1 C15 H15A 108.6 .
N1 C15 H15B 108.6 .
C14 C15 H15A 108.6 .
C14 C15 H15B 108.6 .
H15A C15 H15B 107.5 .
N1 C16 H16A 109.8 .
N1 C16 H16B 109.8 .
N1 C16 C17 109.2(10) .
H16A C16 H16B 108.3 .
C17 C16 H16A 109.8 .
C17 C16 H16B 109.8 .
N2 C17 C16 109.4(10) .
N2 C17 H17A 109.8 .
N2 C17 H17B 109.8 .
C16 C17 H17A 109.8 .
C16 C17 H17B 109.8 .
H17A C17 H17B 108.3 .
C19 C18 N2 119.7(11) .
C23 C18 N2 119.9(11) .
C23 C18 C19 120.4(11) .
C18 C19 C24 123.7(11) .
C20 C19 C18 118.0(12) .
C20 C19 C24 118.3(12) .
C19 C20 H20 118.6 .
C21 C20 C19 122.7(13) .
C21 C20 H20 118.6 .
C20 C21 H21 120.9 .
C22 C21 C20 118.3(12) .
C22 C21 H21 120.9 .
C21 C22 H22 118.7 .
C21 C22 C23 122.6(12) .
C23 C22 H22 118.7 .
C18 C23 C27 123.9(11) .
C22 C23 C18 117.9(12) .
C22 C23 C27 117.9(12) .
C19 C24 H24 107.5 .
C19 C24 C25 111.8(12) .
C19 C24 C26 112.4(12) .
C25 C24 H24 107.5 .
C26 C24 H24 107.5 .
C26 C24 C25 110.0(12) .
C24 C25 H25A 109.5 .
C24 C25 H25B 109.5 .
C24 C25 H25C 109.5 .
H25A C25 H25B 109.5 .
H25A C25 H25C 109.5 .
H25B C25 H25C 109.5 .
C24 C26 H26A 109.5 .
C24 C26 H26B 109.5 .
C24 C26 H26C 109.5 .
H26A C26 H26B 109.5 .
H26A C26 H26C 109.5 .
H26B C26 H26C 109.5 .
C23 C27 H27 107.3 .
C23 C27 C28 111.7(11) .
C28 C27 H27 107.3 .
C29 C27 C23 112.4(11) .
C29 C27 H27 107.3 .
C29 C27 C28 110.7(12) .
C27 C28 H28A 109.5 .
C27 C28 H28B 109.5 .
C27 C28 H28C 109.5 .
H28A C28 H28B 109.5 .
H28A C28 H28C 109.5 .
H28B C28 H28C 109.5 .
C27 C29 H29A 109.5 .
C27 C29 H29B 109.5 .
C27 C29 H29C 109.5 .
H29A C29 H29B 109.5 .
H29A C29 H29C 109.5 .
H29B C29 H29C 109.5 .
Rh1 C30 H30 114.7 .
C31 C30 Rh1 70.9(8) .
C31 C30 H30 114.7 .
C31 C30 C37 122.3(13) .
C37 C30 Rh1 111.6(10) .
C37 C30 H30 114.7 .
Rh1 C31 H31 113.5 .
C30 C31 Rh1 70.4(8) .
C30 C31 H31 113.5 .
C30 C31 C32 126.1(13) .
C32 C31 Rh1 111.9(10) .
C32 C31 H31 113.5 .
C31 C32 H32A 109.0 .
C31 C32 H32B 109.0 .
C31 C32 C33 112.9(12) .
H32A C32 H32B 107.8 .
C33 C32 H32A 109.0 .
C33 C32 H32B 109.0 .
C32 C33 H33A 109.3 .
C32 C33 H33B 109.3 .
C32 C33 C34 111.7(11) .
H33A C33 H33B 108.0 .
C34 C33 H33A 109.3 .
C34 C33 H33B 109.3 .
Rh1 C34 H34 114.2 .
C33 C34 Rh1 112.5(9) .
C33 C34 H34 114.2 .
C35 C34 Rh1 73.2(8) .
C35 C34 C33 122.0(13) .
C35 C34 H34 114.2 .
Rh1 C35 H35 114.5 .
C34 C35 Rh1 69.4(8) .
C34 C35 H35 114.5 .
C34 C35 C36 125.8(13) .
C36 C35 Rh1 108.7(10) .
C36 C35 H35 114.5 .
C35 C36 H36A 108.9 .
C35 C36 H36B 108.9 .
H36A C36 H36B 107.7 .
C37 C36 C35 113.2(12) .
C37 C36 H36A 108.9 .
C37 C36 H36B 108.9 .
C30 C37 H37A 108.7 .
C30 C37 H37B 108.7 .
C36 C37 C30 114.1(12) .
C36 C37 H37A 108.7 .
C36 C37 H37B 108.7 .
H37A C37 H37B 107.6 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 N1 2.239(11) .
Sn1 N1 2.293(10) 3_666
Sn1 N2 2.085(11) .
Rh1 C1 2.185(12) .
Rh1 C2 2.317(12) .
Rh1 C7 2.315(12) .
Rh1 C8 2.362(12) .
Rh1 C13 2.328(13) .
Rh1 C30 2.108(14) .
Rh1 C31 2.114(13) .
Rh1 C34 2.097(14) .
Rh1 C35 2.144(13) .
N1 Sn1 2.293(10) 3_666
N1 C15 1.486(16) .
N1 C16 1.496(17) .
N2 C17 1.464(16) .
N2 C18 1.428(16) .
C1 C2 1.481(19) .
C1 C13 1.458(19) .
C1 C14 1.494(19) .
C2 C3 1.391(19) .
C2 C7 1.438(18) .
C3 H3 0.9500 .
C3 C4 1.39(2) .
C4 H4 0.9500 .
C4 C5 1.406(19) .
C5 H5 0.9500 .
C5 C6 1.333(19) .
C6 H6 0.9500 .
C6 C7 1.422(19) .
C7 C8 1.471(19) .
C8 C9 1.415(18) .
C8 C13 1.428(19) .
C9 H9 0.9500 .
C9 C10 1.340(19) .
C10 H10 0.9500 .
C10 C11 1.439(19) .
C11 H11 0.9500 .
C11 C12 1.386(19) .
C12 H12 0.9500 .
C12 C13 1.441(19) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C14 C15 1.539(17) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C16 C17 1.501(18) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 C19 1.415(18) .
C18 C23 1.412(18) .
C19 C20 1.397(18) .
C19 C24 1.507(19) .
C20 H20 0.9500 .
C20 C21 1.377(19) .
C21 H21 0.9500 .
C21 C22 1.376(19) .
C22 H22 0.9500 .
C22 C23 1.403(17) .
C23 C27 1.523(18) .
C24 H24 1.0000 .
C24 C25 1.55(2) .
C24 C26 1.54(2) .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27 1.0000 .
C27 C28 1.550(19) .
C27 C29 1.506(19) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30 1.0000 .
C30 C31 1.40(2) .
C30 C37 1.52(2) .
C31 H31 1.0000 .
C31 C32 1.467(19) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C32 C33 1.52(2) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C33 C34 1.556(18) .
C34 H34 1.0000 .
C34 C35 1.36(2) .
C35 H35 1.0000 .
C35 C36 1.51(2) .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C36 C37 1.51(2) .
C37 H37A 0.9900 .
C37 H37B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Sn1 N1 C15 C14 -62.3(13) .
Sn1 N1 C15 C14 -177.1(9) 3_666
Sn1 N1 C16 C17 -38.2(11) .
Sn1 N1 C16 C17 67.7(10) 3_666
Sn1 N2 C17 C16 -40.7(12) .
Sn1 N2 C18 C19 -125.4(11) .
Sn1 N2 C18 C23 53.5(16) .
Rh1 C1 C2 C3 114.4(14) .
Rh1 C1 C2 C7 -60.3(8) .
Rh1 C1 C13 C8 61.6(9) .
Rh1 C1 C13 C12 -112.5(14) .
Rh1 C1 C14 C15 -174.9(9) .
Rh1 C2 C3 C4 -88.9(14) .
Rh1 C2 C7 C6 119.1(11) .
Rh1 C2 C7 C8 -65.1(8) .
Rh1 C7 C8 C9 114.5(13) .
Rh1 C7 C8 C13 -61.0(9) .
Rh1 C8 C9 C10 -88.0(14) .
Rh1 C8 C13 C1 -56.9(8) .
Rh1 C8 C13 C12 117.9(12) .
Rh1 C30 C31 C32 103.3(14) .
Rh1 C30 C37 C36 11.1(16) .
Rh1 C31 C32 C33 33.2(15) .
Rh1 C34 C35 C36 98.7(14) .
Rh1 C35 C36 C37 33.3(15) .
N1 C16 C17 N2 52.7(13) .
N2 C18 C19 C20 179.1(12) .
N2 C18 C19 C24 -2(2) .
N2 C18 C23 C22 -177.7(12) .
N2 C18 C23 C27 8.4(19) .
C1 C2 C3 C4 -175.3(13) .
C1 C2 C7 Rh1 56.6(8) .
C1 C2 C7 C6 175.8(11) .
C1 C2 C7 C8 -8.5(13) .
C1 C14 C15 N1 161.9(11) .
C2 C1 C13 Rh1 -70.2(8) .
C2 C1 C13 C8 -8.6(13) .
C2 C1 C13 C12 177.3(13) .
C2 C1 C14 C15 -80.3(16) .
C2 C3 C4 C5 1.5(19) .
C2 C7 C8 Rh1 64.2(8) .
C2 C7 C8 C9 178.7(12) .
C2 C7 C8 C13 3.2(14) .
C3 C2 C7 Rh1 -118.7(11) .
C3 C2 C7 C6 0.4(17) .
C3 C2 C7 C8 176.2(11) .
C3 C4 C5 C6 -1(2) .
C4 C5 C6 C7 -0.1(18) .
C5 C6 C7 Rh1 87.4(14) .
C5 C6 C7 C2 0.3(17) .
C5 C6 C7 C8 -174.2(13) .
C6 C7 C8 Rh1 -120.8(14) .
C6 C7 C8 C9 -6(2) .
C6 C7 C8 C13 178.2(13) .
C7 C2 C3 C4 -1.2(18) .
C7 C8 C9 C10 -178.2(13) .
C7 C8 C13 Rh1 60.3(8) .
C7 C8 C13 C1 3.4(14) .
C7 C8 C13 C12 178.2(11) .
C8 C9 C10 C11 4(2) .
C9 C8 C13 Rh1 -115.8(11) .
C9 C8 C13 C1 -172.7(11) .
C9 C8 C13 C12 2.1(18) .
C9 C10 C11 C12 -3(2) .
C10 C11 C12 C13 1.6(18) .
C11 C12 C13 Rh1 87.7(13) .
C11 C12 C13 C1 172.1(13) .
C11 C12 C13 C8 -1.3(18) .
C13 C1 C2 Rh1 70.8(8) .
C13 C1 C2 C3 -174.8(13) .
C13 C1 C2 C7 10.5(13) .
C13 C1 C14 C15 85.7(17) .
C13 C8 C9 C10 -3.2(18) .
C14 C1 C2 Rh1 -120.7(12) .
C14 C1 C2 C3 -6(2) .
C14 C1 C2 C7 179.1(11) .
C14 C1 C13 Rh1 122.0(14) .
C14 C1 C13 C8 -176.4(12) .
C14 C1 C13 C12 10(2) .
C15 N1 C16 C17 -167.8(10) .
C16 N1 C15 C14 61.8(14) .
C17 N2 C18 C19 65.2(16) .
C17 N2 C18 C23 -116.0(13) .
C18 N2 C17 C16 130.2(11) .
C18 C19 C20 C21 -2(2) .
C18 C19 C24 C25 120.9(14) .
C18 C19 C24 C26 -114.8(14) .
C18 C23 C27 C28 -115.3(15) .
C18 C23 C27 C29 119.6(14) .
C19 C18 C23 C22 1.1(19) .
C19 C18 C23 C27 -172.8(12) .
C19 C20 C21 C22 3(2) .
C20 C19 C24 C25 -60.0(17) .
C20 C19 C24 C26 64.3(16) .
C20 C21 C22 C23 -1(2) .
C21 C22 C23 C18 -1(2) .
C21 C22 C23 C27 173.6(13) .
C22 C23 C27 C28 70.8(16) .
C22 C23 C27 C29 -54.3(17) .
C23 C18 C19 C20 0.3(19) .
C23 C18 C19 C24 179.4(13) .
C24 C19 C20 C21 178.5(13) .
C30 C31 C32 C33 -48(2) .
C31 C30 C37 C36 91.6(17) .
C31 C32 C33 C34 -30.2(18) .
C32 C33 C34 Rh1 13.0(16) .
C32 C33 C34 C35 96.7(16) .
C33 C34 C35 Rh1 -106.4(13) .
C33 C34 C35 C36 -8(2) .
C34 C35 C36 C37 -44(2) .
C35 C36 C37 C30 -30.0(18) .
C37 C30 C31 Rh1 -104.0(13) .
C37 C30 C31 C32 -1(2) .
