#------------------------------------------------------------------------------
#$Date: 2016-03-05 12:04:13 +0200 (Sat, 05 Mar 2016) $
#$Revision: 177834 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/79/7037906.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7037906
loop_
_publ_author_name
'Chen, Sheng-Chun'
'Dai, An-Qi'
'Huang, Kun-Lin'
'Zhang, Zhi-Hui'
'Cui, Ai-Jun'
'He, Ming-Yang'
'Chen, Qun'
_publ_section_title
;
 Assembly of 1D, 2D and 3D lanthanum(iii) coordination polymers with
 perchlorinated benzenedicarboxylates: positional isomeric effect,
 structural transformation and ring-opening polymerisation of glycolide.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3577
_journal_page_last               3589
_journal_paper_doi               10.1039/c5dt04687d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C20 H20 Cl6 La N2 O9, C4 H9 N O'
_chemical_formula_sum            'C24 H29 Cl6 La N3 O10'
_chemical_formula_weight         871.11
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-12-27 deposited with the CCDC.
2016-01-07 downloaded from the CCDC.
;
_cell_angle_alpha                97.0740(10)
_cell_angle_beta                 109.8430(10)
_cell_angle_gamma                95.596(2)
_cell_formula_units_Z            2
_cell_length_a                   10.1071(8)
_cell_length_b                   13.0894(10)
_cell_length_c                   13.6696(11)
_cell_measurement_reflns_used    7160
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      29.96
_cell_measurement_theta_min      2.19
_cell_volume                     1669.2(2)
_computing_cell_refinement       'Bruker APEX II'
_computing_data_collection       'Bruker APEX II'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0176
_diffrn_reflns_av_unetI/netI     0.0337
_diffrn_reflns_laue_measured_fraction_full 0.985
_diffrn_reflns_laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10048
_diffrn_reflns_point_group_measured_fraction_full 0.985
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_min         1.606
_exptl_absorpt_coefficient_mu    1.815
_exptl_absorpt_correction_T_max  0.650
_exptl_absorpt_correction_T_min  0.632
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2008'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.733
_exptl_crystal_description       block
_exptl_crystal_F_000             866
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.260
_exptl_crystal_size_min          0.260
_refine_diff_density_max         1.311
_refine_diff_density_min         -0.929
_refine_diff_density_rms         0.171
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         6439
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.0327
_refine_ls_R_factor_gt           0.0303
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.09P)²+1.88P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1172
_refine_ls_wR_factor_ref         0.1194
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6024
_reflns_number_total             6439
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt04687d2.cif
_cod_data_source_block           6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'multi-scan ' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7037901--7037908.cif.
;
_cod_database_code               7037906
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.630
_shelx_estimated_absorpt_t_max   0.650
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.9996(5) 0.2787(2) -0.0629(3) 0.0284(9) Uani 1 1 d D .
C2 C 1.0010(5) 0.3931(2) -0.0276(3) 0.0247(8) Uani 1 1 d D .
C3 C 1.1265(5) 0.4598(3) 0.0200(3) 0.0283(8) Uani 1 1 d . .
C4 C 0.8713(5) 0.4336(3) -0.0483(3) 0.0304(9) Uani 1 1 d . .
C5 C 1.2216(5) 0.0575(3) 0.3862(3) 0.0307(9) Uani 1 1 d . .
C6 C 1.3662(4) 0.0286(3) 0.4463(3) 0.0246(8) Uani 1 1 d . .
C7 C 1.4749(4) 0.1004(3) 0.5235(3) 0.0248(8) Uani 1 1 d . .
C8 C 1.6065(4) 0.0728(3) 0.5758(3) 0.0246(8) Uani 1 1 d . .
C9 C 0.7336(4) -0.0684(3) -0.0576(3) 0.0213(7) Uani 1 1 d . .
C10 C 0.6130(4) -0.0334(3) -0.0271(3) 0.0198(7) Uani 1 1 d . .
C11 C 0.5685(4) -0.0786(3) 0.0457(3) 0.0222(8) Uani 1 1 d . .
C12 C 0.5410(4) 0.0437(3) -0.0745(3) 0.0219(7) Uani 1 1 d . .
C13 C 1.1947(7) 0.3808(4) 0.2805(4) 0.0519(12) Uani 1 1 d . U
C14 C 1.3538(8) 0.3701(7) 0.3261(7) 0.082(2) Uani 1 1 d . U
H14A H 1.4066 0.4126 0.2933 0.124 Uiso 1 1 calc R U
H14B H 1.3654 0.2970 0.3114 0.124 Uiso 1 1 calc R U
H14C H 1.3904 0.3940 0.4025 0.124 Uiso 1 1 calc R U
C15 C 1.2656(12) 0.5608(5) 0.3650(7) 0.097(3) Uani 1 1 d . .
H15A H 1.2622 0.5685 0.4364 0.146 Uiso 1 1 calc R U
H15B H 1.2387 0.6229 0.3343 0.146 Uiso 1 1 calc R U
H15C H 1.3622 0.5524 0.3683 0.146 Uiso 1 1 calc R U
C16 C 1.0072(10) 0.4764(7) 0.2545(7) 0.087(2) Uani 1 1 d . U
H16A H 0.9615 0.4207 0.1936 0.131 Uiso 1 1 calc R U
H16B H 0.9929 0.5441 0.2321 0.131 Uiso 1 1 calc R U
H16C H 0.9650 0.4679 0.3084 0.131 Uiso 1 1 calc R U
C17 C 0.7423(5) 0.1901(4) 0.2183(4) 0.0379(10) Uani 1 1 d . .
C18 C 0.6669(8) 0.2744(5) 0.1693(5) 0.0595(16) Uani 1 1 d . .
H18A H 0.6865 0.2826 0.1050 0.089 Uiso 1 1 calc R U
H18B H 0.7007 0.3400 0.2193 0.089 Uiso 1 1 calc R U
H18C H 0.5642 0.2556 0.1516 0.089 Uiso 1 1 calc R U
C19 C 0.6157(9) 0.2004(7) 0.3428(6) 0.077(2) Uani 1 1 d . .
H19A H 0.5999 0.2683 0.3214 0.115 Uiso 1 1 calc R U
H19B H 0.6583 0.2093 0.4199 0.115 Uiso 1 1 calc R U
H19C H 0.5245 0.1540 0.3185 0.115 Uiso 1 1 calc R U
C20 C 0.7773(7) 0.0696(5) 0.3412(5) 0.0600(16) Uani 1 1 d . .
H20A H 0.7296 0.0037 0.2945 0.090 Uiso 1 1 calc R U
H20B H 0.7685 0.0684 0.4103 0.090 Uiso 1 1 calc R U
H20C H 0.8782 0.0792 0.3496 0.090 Uiso 1 1 calc R U
C21 C 0.3272(9) 0.3983(6) 0.7571(6) 0.084(2) Uani 1 1 d . .
H21A H 0.3744 0.3363 0.7573 0.125 Uiso 1 1 calc R U
H21B H 0.2626 0.3917 0.7964 0.125 Uiso 1 1 calc R U
H21C H 0.3989 0.4602 0.7905 0.125 Uiso 1 1 calc R U
C22 C 0.2462(8) 0.4082(6) 0.6483(6) 0.0672(18) Uani 1 1 d . .
C23 C 0.1130(9) 0.2305(6) 0.6286(6) 0.0718(19) Uani 1 1 d . .
H23A H 0.1966 0.2207 0.6873 0.108 Uiso 1 1 calc R U
H23B H 0.0898 0.1719 0.5707 0.108 Uiso 1 1 calc R U
H23C H 0.0321 0.2340 0.6524 0.108 Uiso 1 1 calc R U
C24 C 0.0620(10) 0.3342(8) 0.4827(6) 0.088(3) Uani 1 1 d . .
H24A H 0.0796 0.4055 0.4700 0.132 Uiso 1 1 calc R U
H24B H -0.0396 0.3150 0.4691 0.132 Uiso 1 1 calc R U
H24C H 0.0910 0.2863 0.4355 0.132 Uiso 1 1 calc R U
Cl1 Cl 1.28370(14) 0.40952(10) 0.04438(12) 0.0487(3) Uani 1 1 d . .
Cl2 Cl 0.71349(14) 0.35118(10) -0.10757(12) 0.0512(3) Uani 1 1 d . .
Cl3 Cl 1.43827(13) 0.22433(9) 0.55303(10) 0.0425(3) Uani 1 1 d . .
Cl4 Cl 1.73850(11) 0.16382(8) 0.66688(8) 0.0331(2) Uani 1 1 d . .
Cl5 Cl 0.64767(12) -0.17975(9) 0.09792(9) 0.0369(3) Uani 1 1 d . .
Cl6 Cl 0.59136(12) 0.09426(9) -0.16881(9) 0.0363(3) Uani 1 1 d . .
La1 La 1.03628(2) 0.11963(2) 0.13967(2) 0.01769(10) Uani 1 1 d . .
N1 N 1.1683(7) 0.4709(4) 0.3008(4) 0.0677(13) Uani 1 1 d . U
N2 N 0.7119(5) 0.1549(4) 0.2958(3) 0.0467(11) Uani 1 1 d . .
N3 N 0.1437(6) 0.3280(4) 0.5918(4) 0.0577(13) Uani 1 1 d . .
O1 O 0.9840(4) 0.2168(2) -0.0026(3) 0.0379(8) Uani 1 1 d . .
O2 O 1.0153(4) 0.2543(2) -0.1485(3) 0.0427(8) Uani 1 1 d . .
O3 O 1.2182(4) 0.1078(3) 0.3129(3) 0.0405(8) Uani 1 1 d . .
O4 O 1.1218(4) 0.0260(4) 0.4121(3) 0.0497(9) Uani 1 1 d . .
O5 O 0.8531(3) -0.0090(2) -0.0194(2) 0.0224(5) Uani 1 1 d . .
O6 O 0.7122(3) -0.1508(2) -0.1205(3) 0.0368(7) Uani 1 1 d . .
O7 O 1.1024(4) 0.3018(3) 0.2276(3) 0.0444(8) Uani 1 1 d . .
O8 O 0.8288(4) 0.1502(3) 0.1835(3) 0.0427(8) Uani 1 1 d . .
O9 O 0.9741(3) -0.0487(2) 0.1964(2) 0.0307(6) Uani 1 1 d . .
H9A H 0.9774 -0.0247 0.2557 0.037 Uiso 1 1 d R U
H9B H 0.9921 -0.1074 0.1831 0.037 Uiso 1 1 d R U
O10 O 0.2676(8) 0.4853(5) 0.6104(5) 0.104(2) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 125.8(3) . .
O2 C1 C2 116.9(3) . .
O1 C1 C2 117.3(3) . .
C3 C2 C4 119.0(3) . .
C3 C2 C1 121.0(4) . .
C4 C2 C1 119.9(4) . .
C2 C3 C4 121.4(4) . 2_765
C2 C3 Cl1 118.5(3) . .
C4 C3 Cl1 120.0(4) 2_765 .
C3 C4 C2 119.6(4) 2_765 .
C3 C4 Cl2 120.9(4) 2_765 .
C2 C4 Cl2 119.5(3) . .
O4 C5 O3 127.8(4) . .
O4 C5 C6 116.7(4) . .
O3 C5 C6 115.4(4) . .
C8 C6 C7 118.0(4) 2_856 .
C8 C6 C5 119.5(4) 2_856 .
C7 C6 C5 122.4(4) . .
C8 C7 C6 121.4(4) . .
C8 C7 Cl3 120.9(3) . .
C6 C7 Cl3 117.7(3) . .
C7 C8 C6 120.6(4) . 2_856
C7 C8 Cl4 120.0(3) . .
C6 C8 Cl4 119.4(3) 2_856 .
O6 C9 O5 122.9(4) . .
O6 C9 C10 119.6(3) . .
O5 C9 C10 117.4(3) . .
O6 C9 La1 61.3(2) . 2_755
O5 C9 La1 61.88(19) . 2_755
C10 C9 La1 172.5(3) . 2_755
C11 C10 C12 118.8(3) . .
C11 C10 C9 121.3(3) . .
C12 C10 C9 119.9(3) . .
C12 C11 C10 120.4(4) 2_655 .
C12 C11 Cl5 120.2(3) 2_655 .
C10 C11 Cl5 119.4(3) . .
C11 C12 C10 120.8(3) 2_655 .
C11 C12 Cl6 120.9(3) 2_655 .
C10 C12 Cl6 118.3(3) . .
N1 C13 O7 125.5(7) . .
N1 C13 C14 114.1(6) . .
O7 C13 C14 120.4(6) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
N1 C15 H15A 109.5 . .
N1 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
N1 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N1 C16 H16A 109.5 . .
N1 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
N1 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
O8 C17 N2 120.1(5) . .
O8 C17 C18 120.7(5) . .
N2 C17 C18 119.1(5) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N2 C19 H19A 109.5 . .
N2 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
N2 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
N2 C20 H20A 109.5 . .
N2 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
N2 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 H21A 109.5 . .
C22 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C22 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O10 C22 N3 121.3(7) . .
O10 C22 C21 122.5(8) . .
N3 C22 C21 116.3(6) . .
N3 C23 H23A 109.5 . .
N3 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
N3 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
N3 C24 H24A 109.5 . .
N3 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
N3 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
O1 La1 O8 95.36(13) . .
O1 La1 O7 75.98(12) . .
O8 La1 O7 78.14(13) . .
O1 La1 O3 143.36(11) . .
O8 La1 O3 103.36(13) . .
O7 La1 O3 77.44(12) . .
O1 La1 O9 145.15(11) . .
O8 La1 O9 77.90(11) . .
O7 La1 O9 133.79(11) . .
O3 La1 O9 70.54(10) . .
O1 La1 O5 75.70(10) . .
O8 La1 O5 83.68(11) . .
O7 La1 O5 144.52(11) . .
O3 La1 O5 136.91(10) . .
O9 La1 O5 69.61(9) . .
O1 La1 O6 79.43(12) . 2_755
O8 La1 O6 161.25(12) . 2_755
O7 La1 O6 83.12(11) . 2_755
O3 La1 O6 72.73(12) . 2_755
O9 La1 O6 116.47(10) . 2_755
O5 La1 O6 111.97(9) . 2_755
O1 La1 O5 81.81(10) . 2_755
O8 La1 O5 148.18(11) . 2_755
O7 La1 O5 130.65(11) . 2_755
O3 La1 O5 97.11(11) . 2_755
O9 La1 O5 86.46(9) . 2_755
O5 La1 O5 64.84(9) . 2_755
O6 La1 O5 49.46(9) 2_755 2_755
O1 La1 C9 80.98(11) . 2_755
O8 La1 C9 172.53(12) . 2_755
O7 La1 C9 107.05(12) . 2_755
O3 La1 C9 83.22(11) . 2_755
O9 La1 C9 101.35(10) . 2_755
O5 La1 C9 89.09(9) . 2_755
O6 La1 C9 24.44(10) 2_755 2_755
O5 La1 C9 25.09(9) 2_755 2_755
C13 N1 C15 128.0(8) . .
C13 N1 C16 111.7(6) . .
C15 N1 C16 120.1(7) . .
C17 N2 C20 120.5(5) . .
C17 N2 C19 122.9(5) . .
C20 N2 C19 116.5(5) . .
C22 N3 C24 117.9(6) . .
C22 N3 C23 125.5(6) . .
C24 N3 C23 116.4(6) . .
C1 O1 La1 161.1(3) . .
C5 O3 La1 135.0(3) . .
C9 O5 La1 147.9(2) . .
C9 O5 La1 93.0(2) . 2_755
La1 O5 La1 115.16(9) . 2_755
C9 O6 La1 94.2(2) . 2_755
C13 O7 La1 151.9(4) . .
C17 O8 La1 164.1(4) . .
La1 O9 H9A 98.3 . .
La1 O9 H9B 131.5 . .
H9A O9 H9B 121.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.241(5) .
C1 O1 1.262(5) .
C1 C2 1.5126(19) .
C2 C3 1.371(6) .
C2 C4 1.414(6) .
C3 C4 1.398(6) 2_765
C3 Cl1 1.723(4) .
C4 C3 1.398(6) 2_765
C4 Cl2 1.714(5) .
C5 O4 1.229(6) .
C5 O3 1.258(5) .
C5 C6 1.524(6) .
C6 C8 1.399(6) 2_856
C6 C7 1.404(6) .
C7 C8 1.386(6) .
C7 Cl3 1.729(4) .
C8 C6 1.399(6) 2_856
C8 Cl4 1.717(4) .
C9 O6 1.245(5) .
C9 O5 1.275(5) .
C9 C10 1.509(5) .
C9 La1 3.002(4) 2_755
C10 C11 1.393(5) .
C10 C12 1.396(5) .
C11 C12 1.392(5) 2_655
C11 Cl5 1.719(4) .
C12 C11 1.392(5) 2_655
C12 Cl6 1.718(4) .
C13 N1 1.253(8) .
C13 O7 1.278(7) .
C13 C14 1.542(10) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 N1 1.434(9) .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 N1 1.547(11) .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 O8 1.254(6) .
C17 N2 1.321(7) .
C17 C18 1.499(8) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 N2 1.468(7) .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 N2 1.450(8) .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 C22 1.463(10) .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 O10 1.224(8) .
C22 N3 1.348(10) .
C23 N3 1.471(8) .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 N3 1.457(8) .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
La1 O1 2.391(3) .
La1 O8 2.424(3) .
La1 O7 2.452(3) .
La1 O3 2.490(3) .
La1 O9 2.516(3) .
La1 O5 2.598(3) .
La1 O6 2.641(3) 2_755
La1 O5 2.651(3) 2_755
La1 C9 3.002(4) 2_755
O5 La1 2.651(3) 2_755
O6 La1 2.641(3) 2_755
O9 H9A 0.8200 .
O9 H9B 0.8200 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C1 C2 C3 -81.0(5) . .
O1 C1 C2 C3 98.4(5) . .
O2 C1 C2 C4 95.9(5) . .
O1 C1 C2 C4 -84.7(5) . .
C4 C2 C3 C4 0.0(7) . 2_765
C1 C2 C3 C4 176.9(4) . 2_765
C4 C2 C3 Cl1 -179.7(3) . .
C1 C2 C3 Cl1 -2.9(5) . .
C3 C2 C4 C3 0.0(7) . 2_765
C1 C2 C4 C3 -176.9(4) . 2_765
C3 C2 C4 Cl2 -179.9(3) . .
C1 C2 C4 Cl2 3.2(5) . .
O4 C5 C6 C8 75.7(5) . 2_856
O3 C5 C6 C8 -101.7(5) . 2_856
O4 C5 C6 C7 -104.6(5) . .
O3 C5 C6 C7 78.0(5) . .
C8 C6 C7 C8 0.8(6) 2_856 .
C5 C6 C7 C8 -178.9(4) . .
C8 C6 C7 Cl3 -178.0(3) 2_856 .
C5 C6 C7 Cl3 2.3(5) . .
C6 C7 C8 C6 -0.9(7) . 2_856
Cl3 C7 C8 C6 178.0(3) . 2_856
C6 C7 C8 Cl4 178.1(3) . .
Cl3 C7 C8 Cl4 -3.1(5) . .
O6 C9 C10 C11 77.6(5) . .
O5 C9 C10 C11 -104.7(4) . .
O6 C9 C10 C12 -100.5(5) . .
O5 C9 C10 C12 77.2(5) . .
C12 C10 C11 C12 -3.3(6) . 2_655
C9 C10 C11 C12 178.6(4) . 2_655
C12 C10 C11 Cl5 175.5(3) . .
C9 C10 C11 Cl5 -2.6(5) . .
C11 C10 C12 C11 3.3(6) . 2_655
C9 C10 C12 C11 -178.6(4) . 2_655
C11 C10 C12 Cl6 -176.9(3) . .
C9 C10 C12 Cl6 1.3(5) . .
O7 C13 N1 C15 175.6(7) . .
C14 C13 N1 C15 -4.0(10) . .
O7 C13 N1 C16 0.5(9) . .
C14 C13 N1 C16 -179.2(6) . .
O8 C17 N2 C20 -0.3(8) . .
C18 C17 N2 C20 176.8(5) . .
O8 C17 N2 C19 177.7(6) . .
C18 C17 N2 C19 -5.2(9) . .
O10 C22 N3 C24 2.1(11) . .
C21 C22 N3 C24 -179.1(7) . .
O10 C22 N3 C23 177.6(7) . .
C21 C22 N3 C23 -3.6(10) . .
O2 C1 O1 La1 98.0(9) . .
C2 C1 O1 La1 -81.4(10) . .
O4 C5 O3 La1 -28.6(8) . .
C6 C5 O3 La1 148.4(3) . .
O6 C9 O5 La1 -146.3(4) . .
C10 C9 O5 La1 36.1(6) . .
La1 C9 O5 La1 -152.4(5) 2_755 .
O6 C9 O5 La1 6.1(4) . 2_755
C10 C9 O5 La1 -171.5(3) . 2_755
O5 C9 O6 La1 -6.1(4) . 2_755
C10 C9 O6 La1 171.4(3) . 2_755
N1 C13 O7 La1 173.0(5) . .
C14 C13 O7 La1 -7.4(11) . .
N2 C17 O8 La1 -110.5(12) . .
C18 C17 O8 La1 72.4(14) . .
