#------------------------------------------------------------------------------
#$Date: 2016-03-05 12:16:54 +0200 (Sat, 05 Mar 2016) $
#$Revision: 177859 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/80/7038023.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7038023
loop_
_publ_author_name
'Zhang, Wan-Ying'
'Tian, Yong-Mei'
'Li, Hong-Feng'
'Chen, Peng'
'Sun, Wen-Bin'
'Zhang, Yi-Quan'
'Yan, Peng-Fei'
_publ_section_title
;
 A series of dinuclear Dy(iii) complexes bridged by
 2-methyl-8-hydroxylquinoline: replacement on the periphery coordinated
 β-diketonate terminal leads to different single-molecule magnetic
 properties.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3863
_journal_page_last               3873
_journal_paper_doi               10.1039/c5dt04449a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C50 H24 Dy2 F36 N2 O14'
_chemical_formula_sum            'C50 H24 Dy2 F36 N2 O14'
_chemical_formula_weight         1885.71
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-12-16 deposited with the CCDC.
2016-01-15 downloaded from the CCDC.
;
_cell_angle_alpha                105.245(4)
_cell_angle_beta                 112.104(4)
_cell_angle_gamma                106.283(4)
_cell_formula_units_Z            1
_cell_length_a                   12.0760(6)
_cell_length_b                   12.7204(6)
_cell_length_c                   12.9553(6)
_cell_measurement_reflns_used    6052
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.9437
_cell_measurement_theta_min      2.9203
_cell_volume                     1610.82(17)
_computing_cell_refinement       'CrysAlis PRO (Agilent, 2011)'
_computing_data_collection       'CrysAlis PRO (Agilent, 2011)'
_computing_data_reduction        'CrysAlis PRO (Agilent, 2011)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.847
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_av_unetI/netI     0.0447
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.847
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            13290
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.847
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         29.008
_diffrn_reflns_theta_min         2.926
_exptl_absorpt_coefficient_mu    2.467
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_diffrn    1.944
_exptl_crystal_description       block
_exptl_crystal_F_000             906
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.169
_refine_diff_density_min         -0.570
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     524
_refine_ls_number_reflns         7259
_refine_ls_number_restraints     301
_refine_ls_restrained_S_all      1.094
_refine_ls_R_factor_all          0.0503
_refine_ls_R_factor_gt           0.0403
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0506P)²+1.9614P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0967
_refine_ls_wR_factor_ref         0.1054
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6283
_reflns_number_total             7259
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt04449a2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7038020--7038023.cif.'
_cod_original_cell_volume        1610.80(15)
_cod_database_code               7038023
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C19 C 0.2399(7) 0.9215(5) 0.3785(5) 0.0642(16) Uani 1 1 d . . . . .
C15 C -0.1171(7) 0.6105(6) 0.3821(7) 0.0776(19) Uani 1 1 d D . . . .
C10 C 0.0711(5) 0.6956(4) -0.1546(4) 0.0446(11) Uani 1 1 d . . . . .
C1 C -0.0192(5) 0.6410(4) -0.1198(4) 0.0397(10) Uani 1 1 d . . . . .
C25 C 0.3824(9) 0.6186(8) 0.5028(7) 0.087(2) Uani 1 1 d D . . . .
C2 C -0.1319(5) 0.6585(4) -0.1531(5) 0.0476(12) Uani 1 1 d . . . . .
H2 H -0.1919 0.6258 -0.1291 0.057 Uiso 1 1 calc R U . . .
C16 C 0.3281(8) 0.9926(5) 0.1465(7) 0.088(2) Uani 1 1 d D . . . .
C5 C 0.0434(6) 0.7610(5) -0.2270(5) 0.0559(14) Uani 1 1 d . . . . .
C6 C 0.1403(8) 0.8119(6) -0.2564(6) 0.0717(19) Uani 1 1 d . . . . .
H6 H 0.1248 0.8546 -0.3045 0.086 Uiso 1 1 calc R U . . .
C11 C -0.1691(7) 0.8429(6) 0.1263(8) 0.084(2) Uani 1 1 d D . . . .
C8 C 0.2798(7) 0.7370(6) -0.1460(6) 0.0659(16) Uani 1 1 d . . . . .
C20 C 0.2645(9) 0.9958(6) 0.5024(8) 0.106(3) Uani 1 1 d D . . . .
C17 C 0.2727(6) 0.9215(5) 0.2055(5) 0.0561(14) Uani 1 1 d . . . . .
C21 C 0.4585(7) 0.5802(8) 0.1458(8) 0.093(3) Uani 1 1 d D . . . .
C4 C -0.0754(7) 0.7739(5) -0.2605(6) 0.0671(17) Uani 1 1 d . . . . .
H4 H -0.0961 0.8160 -0.3083 0.081 Uiso 1 1 calc R U . . .
C24 C 0.3346(6) 0.6156(5) 0.3736(5) 0.0568(14) Uani 1 1 d . . . . .
C9 C 0.4058(8) 0.7269(9) -0.0957(10) 0.105(3) Uani 1 1 d . . . . .
H9A H 0.4638 0.7884 -0.0140 0.158 Uiso 1 1 calc R U . . .
H9B H 0.4457 0.7365 -0.1462 0.158 Uiso 1 1 calc R U . . .
H9C H 0.3900 0.6492 -0.0941 0.158 Uiso 1 1 calc R U . . .
C12 C -0.1138(6) 0.7593(5) 0.1675(6) 0.0552(13) Uani 1 1 d . . . . .
C3 C -0.1591(7) 0.7251(5) -0.2233(6) 0.0636(16) Uani 1 1 d . . . . .
H3 H -0.2366 0.7356 -0.2443 0.076 Uiso 1 1 calc R U . . .
C13 C -0.1293(6) 0.7293(5) 0.2566(6) 0.0598(15) Uani 1 1 d . . . . .
H13 H -0.1653 0.7675 0.2976 0.072 Uiso 1 1 calc R U . . .
C14 C -0.0925(5) 0.6433(5) 0.2872(5) 0.0520(12) Uani 1 1 d . . . . .
C22 C 0.3735(5) 0.6020(5) 0.2033(6) 0.0578(14) Uani 1 1 d . . . . .
C18 C 0.2866(7) 0.9824(5) 0.3174(6) 0.075(2) Uani 1 1 d . . . . .
H18 H 0.3281 1.0661 0.3534 0.090 Uiso 1 1 calc R U . . .
C7 C 0.2534(8) 0.8010(6) -0.2178(7) 0.076(2) Uani 1 1 d . . . . .
H7 H 0.3155 0.8362 -0.2387 0.091 Uiso 1 1 calc R U . . .
C23 C 0.4140(6) 0.6099(6) 0.3203(6) 0.0647(16) Uani 1 1 d . . . . .
H23 H 0.4960 0.6114 0.3644 0.078 Uiso 1 1 calc R U . . .
N1 N 0.1884(5) 0.6887(4) -0.1176(4) 0.0505(10) Uani 1 1 d . . . . .
H1A H 0.2054 0.6503 -0.0724 0.061 Uiso 1 1 calc R U . . .
O4 O 0.2170(4) 0.8105(3) 0.1425(3) 0.0501(8) Uani 1 1 d . . . . .
O5 O 0.1816(4) 0.8116(3) 0.3412(4) 0.0608(10) Uani 1 1 d . . . . .
O6 O 0.2728(4) 0.6085(3) 0.1336(4) 0.0536(9) Uani 1 1 d . . . . .
O3 O -0.0422(4) 0.5851(3) 0.2404(3) 0.0481(8) Uani 1 1 d . . . . .
O2 O -0.0553(4) 0.7242(3) 0.1118(4) 0.0541(9) Uani 1 1 d . . . . .
O1 O 0.0082(3) 0.5743(3) -0.0561(3) 0.0366(7) Uani 1 1 d . . . . .
O7 O 0.2232(4) 0.6129(3) 0.3264(3) 0.0559(9) Uani 1 1 d . . . . .
F1 F -0.210(3) 0.9064(17) 0.189(3) 0.131(4) Uani 0.5 1 d D U P A 1
F2 F -0.2801(19) 0.773(2) 0.0176(15) 0.121(4) Uani 0.5 1 d D U P A 1
F3 F -0.096(3) 0.916(2) 0.099(2) 0.118(6) Uani 0.5 1 d D U P A 1
F4 F -0.2275(16) 0.5072(14) 0.3209(17) 0.121(5) Uani 0.5 1 d D U P B 1
F5 F -0.135(2) 0.6955(16) 0.448(3) 0.121(5) Uani 0.5 1 d D U P B 1
F6 F -0.022(2) 0.5907(18) 0.457(2) 0.134(6) Uani 0.5 1 d D U P B 1
F7 F 0.2120(15) 0.9374(10) 0.5534(10) 0.131(4) Uani 0.5 1 d D U P C 1
F8 F 0.2161(15) 1.0797(14) 0.4977(14) 0.150(4) Uani 0.5 1 d D U P C 1
F9 F 0.3960(12) 1.0641(11) 0.5815(10) 0.140(4) Uani 0.5 1 d D U P C 1
F10 F 0.398(4) 1.1078(17) 0.219(4) 0.142(6) Uani 0.5 1 d D U P D 1
F11 F 0.401(2) 0.952(4) 0.104(2) 0.144(6) Uani 0.5 1 d D U P D 1
F12 F 0.226(3) 0.980(3) 0.0476(11) 0.125(6) Uani 0.5 1 d D U P D 1
F13 F 0.381(2) 0.5287(19) 0.0227(12) 0.108(3) Uani 0.5 1 d D U P E 1
F14 F 0.5606(12) 0.6762(17) 0.170(3) 0.125(4) Uani 0.5 1 d D U P E 1
F15 F 0.5006(13) 0.4959(12) 0.1678(15) 0.129(4) Uani 0.5 1 d D U P E 1
F16 F 0.3661(13) 0.5091(10) 0.5004(15) 0.124(4) Uani 0.5 1 d D U P F 1
F17 F 0.3239(12) 0.6569(11) 0.5636(11) 0.111(3) Uani 0.5 1 d D U P F 1
F18 F 0.5124(11) 0.6886(10) 0.5694(14) 0.112(3) Uani 0.5 1 d D U P F 1
F16' F 0.3061(13) 0.5190(10) 0.5002(15) 0.124(4) Uani 0.5 1 d D U P F 2
F17' F 0.3783(12) 0.7146(10) 0.5709(11) 0.111(3) Uani 0.5 1 d D U P F 2
F18' F 0.5075(11) 0.6331(10) 0.5618(14) 0.112(3) Uani 0.5 1 d D U P F 2
F1' F -0.230(3) 0.8695(17) 0.188(3) 0.131(4) Uani 0.5 1 d D U P A 2
F2' F -0.2539(19) 0.798(2) 0.0083(14) 0.121(4) Uani 0.5 1 d D U P A 2
F3' F -0.071(3) 0.943(2) 0.152(2) 0.118(6) Uani 0.5 1 d D U P A 2
F4' F -0.1706(17) 0.4952(13) 0.3574(17) 0.121(5) Uani 0.5 1 d D U P B 2
F5' F -0.180(2) 0.6573(17) 0.430(3) 0.121(5) Uani 0.5 1 d D U P B 2
F6' F 0.002(2) 0.6502(18) 0.477(2) 0.134(6) Uani 0.5 1 d D U P B 2
F7' F 0.3224(14) 0.9582(11) 0.5854(10) 0.131(4) Uani 0.5 1 d D U P C 2
F8' F 0.1446(13) 0.9766(13) 0.4998(14) 0.150(4) Uani 0.5 1 d D U P C 2
F9' F 0.3224(15) 1.1123(8) 0.5425(11) 0.140(4) Uani 0.5 1 d D U P C 2
F10' F 0.369(4) 1.1093(16) 0.195(4) 0.142(6) Uani 0.5 1 d D U P D 2
F11' F 0.436(2) 0.975(4) 0.157(2) 0.144(6) Uani 0.5 1 d D U P D 2
F12' F 0.259(3) 0.957(3) 0.0271(10) 0.125(6) Uani 0.5 1 d D U P D 2
F13' F 0.401(2) 0.5028(19) 0.0315(12) 0.108(3) Uani 0.5 1 d D U P E 2
F14' F 0.5200(12) 0.6898(16) 0.147(3) 0.125(4) Uani 0.5 1 d D U P E 2
F15' F 0.5619(13) 0.5647(13) 0.2180(15) 0.129(4) Uani 0.5 1 d D U P E 2
Dy1 Dy 0.09453(2) 0.63880(2) 0.15597(2) 0.03646(8) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 C19 C18 126.4(5) . .
O5 C19 C20 116.0(6) . .
C18 C19 C20 117.5(5) . .
F5' C15 F4' 104.6(13) . .
F5' C15 F6' 104.0(15) . .
F4' C15 F6' 102.8(11) . .
F5 C15 F6 109.0(14) . .
F5 C15 F4 109.7(12) . .
F6 C15 F4 107.1(11) . .
F5' C15 C14 120.2(16) . .
F5 C15 C14 109.8(14) . .
F4' C15 C14 117.5(11) . .
F6' C15 C14 105.5(16) . .
F6 C15 C14 114.7(17) . .
F4 C15 C14 106.4(10) . .
N1 C10 C1 120.4(5) . .
N1 C10 C5 118.0(5) . .
C1 C10 C5 121.5(5) . .
O1 C1 C2 123.0(4) . .
O1 C1 C10 119.6(4) . .
C2 C1 C10 117.4(5) . .
F16' C25 F17' 110.7(10) . .
F17 C25 F18 108.5(9) . .
F17 C25 F16 105.3(10) . .
F18 C25 F16 106.5(9) . .
F16' C25 F18' 107.2(9) . .
F17' C25 F18' 105.1(9) . .
F16' C25 C24 110.8(9) . .
F17 C25 C24 116.5(8) . .
F17' C25 C24 106.8(8) . .
F18 C25 C24 108.3(10) . .
F16 C25 C24 111.4(9) . .
F18' C25 C24 116.0(10) . .
C1 C2 C3 121.4(5) . .
C1 C2 H2 119.3 . .
C3 C2 H2 119.3 . .
F10' C16 F12' 106(2) . .
F10 C16 F12 108.8(18) . .
F10 C16 F11 109(2) . .
F12 C16 F11 104.9(15) . .
F10' C16 F11' 105.6(19) . .
F12' C16 F11' 101.3(15) . .
F10' C16 C17 118(3) . .
F10 C16 C17 113(3) . .
F12' C16 C17 118.3(17) . .
F12 C16 C17 107.0(16) . .
F11 C16 C17 114.3(19) . .
F11' C16 C17 105.7(18) . .
C4 C5 C6 124.7(6) . .
C4 C5 C10 118.4(5) . .
C6 C5 C10 116.9(6) . .
C7 C6 C5 122.1(6) . .
C7 C6 H6 119.0 . .
C5 C6 H6 119.0 . .
F3 C11 F1 106.9(16) . .
F2' C11 F1' 108.1(14) . .
F2' C11 F3' 107.2(14) . .
F1' C11 F3' 109.6(13) . .
F3 C11 F2 102.8(15) . .
F1 C11 F2 102.6(15) . .
F3 C11 C12 114(2) . .
F1 C11 C12 121.4(13) . .
F2' C11 C12 115.3(14) . .
F1' C11 C12 106.9(11) . .
F3' C11 C12 110(2) . .
F2 C11 C12 106.4(13) . .
N1 C8 C7 117.7(6) . .
N1 C8 C9 119.3(6) . .
C7 C8 C9 122.9(6) . .
F9' C20 F7' 111.4(9) . .
F7 C20 F8 105.1(10) . .
F7 C20 F9 109.4(10) . .
F8 C20 F9 102.7(8) . .
F9' C20 F8' 103.0(9) . .
F7' C20 F8' 103.1(9) . .
F9' C20 C19 117.4(9) . .
F7 C20 C19 116.1(7) . .
F7' C20 C19 111.5(8) . .
F8 C20 C19 111.0(9) . .
F9 C20 C19 111.5(8) . .
F8' C20 C19 109.1(9) . .
O4 C17 C18 128.0(5) . .
O4 C17 C16 113.3(5) . .
C18 C17 C16 118.6(5) . .
F13' C21 F15' 111.6(10) . .
F14 C21 F13 106.0(12) . .
F14 C21 F15 109.1(9) . .
F13 C21 F15 103.1(10) . .
F13' C21 F14' 105.3(12) . .
F15' C21 F14' 102.0(9) . .
F13' C21 C22 118.9(11) . .
F14 C21 C22 117.1(13) . .
F15' C21 C22 113.3(10) . .
F13 C21 C22 107.7(10) . .
F15 C21 C22 112.7(10) . .
F14' C21 C22 103.6(12) . .
C3 C4 C5 119.8(5) . .
C3 C4 H4 120.1 . .
C5 C4 H4 120.1 . .
O7 C24 C23 127.0(6) . .
O7 C24 C25 114.2(6) . .
C23 C24 C25 118.7(6) . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
O2 C12 C13 126.7(5) . .
O2 C12 C11 113.2(5) . .
C13 C12 C11 120.1(5) . .
C4 C3 C2 121.5(6) . .
C4 C3 H3 119.3 . .
C2 C3 H3 119.3 . .
C12 C13 C14 121.5(5) . .
C12 C13 H13 119.3 . .
C14 C13 H13 119.3 . .
O3 C14 C13 126.4(5) . .
O3 C14 C15 114.6(5) . .
C13 C14 C15 119.0(5) . .
O6 C22 C23 129.0(5) . .
O6 C22 C21 113.5(6) . .
C23 C22 C21 117.5(5) . .
C17 C18 C19 121.5(5) . .
C17 C18 H18 119.3 . .
C19 C18 H18 119.3 . .
C6 C7 C8 120.5(6) . .
C6 C7 H7 119.7 . .
C8 C7 H7 119.7 . .
C22 C23 C24 120.9(5) . .
C22 C23 H23 119.5 . .
C24 C23 H23 119.5 . .
C8 N1 C10 124.8(5) . .
C8 N1 H1A 117.6 . .
C10 N1 H1A 117.6 . .
C17 O4 Dy1 136.1(4) . .
C19 O5 Dy1 136.4(4) . .
C22 O6 Dy1 133.2(4) . .
C14 O3 Dy1 130.4(3) . .
C12 O2 Dy1 132.4(4) . .
C1 O1 Dy1 125.9(3) . .
C1 O1 Dy1 120.4(3) . 2_565
Dy1 O1 Dy1 110.75(11) . 2_565
C24 O7 Dy1 136.4(4) . .
O2 Dy1 O7 135.85(13) . .
O2 Dy1 O1 79.08(12) . .
O7 Dy1 O1 144.07(12) . .
O2 Dy1 O3 71.33(12) . .
O7 Dy1 O3 74.79(13) . .
O1 Dy1 O3 121.08(12) . .
O2 Dy1 O4 79.19(13) . .
O7 Dy1 O4 111.56(14) . .
O1 Dy1 O4 78.26(11) . .
O3 Dy1 O4 139.41(12) . .
O2 Dy1 O1 112.83(12) . 2_565
O7 Dy1 O1 85.61(12) . 2_565
O1 Dy1 O1 69.25(12) . 2_565
O3 Dy1 O1 77.08(11) . 2_565
O4 Dy1 O1 141.62(11) . 2_565
O2 Dy1 O5 75.32(14) . .
O7 Dy1 O5 69.07(14) . .
O1 Dy1 O5 142.97(12) . .
O3 Dy1 O5 74.87(13) . .
O4 Dy1 O5 71.04(12) . .
O1 Dy1 O5 146.15(12) 2_565 .
O2 Dy1 O6 147.47(13) . .
O7 Dy1 O6 71.51(13) . .
O1 Dy1 O6 79.53(12) . .
O3 Dy1 O6 141.17(12) . .
O4 Dy1 O6 72.65(12) . .
O1 Dy1 O6 81.64(11) 2_565 .
O5 Dy1 O6 109.47(14) . .
O2 Dy1 Dy1 97.05(10) . 2_565
O7 Dy1 Dy1 116.25(9) . 2_565
O1 Dy1 Dy1 34.87(7) . 2_565
O3 Dy1 Dy1 100.08(9) . 2_565
O4 Dy1 Dy1 110.88(8) . 2_565
O1 Dy1 Dy1 34.38(7) 2_565 2_565
O5 Dy1 Dy1 171.82(11) . 2_565
O6 Dy1 Dy1 78.54(10) . 2_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C19 O5 1.234(6) .
C19 C18 1.399(9) .
C19 C20 1.498(9) .
C15 F5' 1.316(12) .
C15 F5 1.317(12) .
C15 F4' 1.318(14) .
C15 F6' 1.335(16) .
C15 F6 1.336(15) .
C15 F4 1.344(15) .
C15 C14 1.500(8) .
C10 N1 1.351(7) .
C10 C1 1.409(7) .
C10 C5 1.418(7) .
C1 O1 1.353(5) .
C1 C2 1.366(7) .
C25 F16' 1.325(12) .
C25 F17 1.329(13) .
C25 F17' 1.331(13) .
C25 F18 1.340(14) .
C25 F16 1.341(15) .
C25 F18' 1.342(13) .
C25 C24 1.537(10) .
C2 C3 1.410(8) .
C2 H2 0.9300 .
C16 F10' 1.308(17) .
C16 F10 1.314(16) .
C16 F12' 1.319(12) .
C16 F12 1.333(13) .
C16 F11 1.344(16) .
C16 F11' 1.350(17) .
C16 C17 1.504(9) .
C5 C4 1.405(9) .
C5 C6 1.406(9) .
C6 C7 1.328(10) .
C6 H6 0.9300 .
C11 F3 1.307(16) .
C11 F1 1.317(15) .
C11 F2' 1.322(15) .
C11 F1' 1.321(15) .
C11 F3' 1.333(13) .
C11 F2 1.350(15) .
C11 C12 1.514(9) .
C8 N1 1.332(7) .
C8 C7 1.396(10) .
C8 C9 1.471(10) .
C20 F9' 1.302(10) .
C20 F7 1.304(10) .
C20 F7' 1.330(13) .
C20 F8 1.357(13) .
C20 F9 1.364(13) .
C20 F8' 1.385(13) .
C17 O4 1.250(6) .
C17 C18 1.371(8) .
C21 F13' 1.311(12) .
C21 F14 1.331(14) .
C21 F15' 1.352(13) .
C21 F13 1.355(14) .
C21 F15 1.358(13) .
C21 F14' 1.375(12) .
C21 C22 1.521(9) .
C4 C3 1.347(9) .
C4 H4 0.9300 .
C24 O7 1.237(7) .
C24 C23 1.382(9) .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C12 O2 1.270(6) .
C12 C13 1.365(8) .
C3 H3 0.9300 .
C13 C14 1.386(8) .
C13 H13 0.9300 .
C14 O3 1.255(6) .
C22 O6 1.253(7) .
C22 C23 1.372(9) .
C18 H18 0.9300 .
C7 H7 0.9300 .
C23 H23 0.9300 .
N1 H1A 0.8600 .
O4 Dy1 2.360(3) .
O5 Dy1 2.393(4) .
O6 Dy1 2.397(3) .
O3 Dy1 2.347(3) .
O2 Dy1 2.330(3) .
O1 Dy1 2.342(3) .
O1 Dy1 2.371(3) 2_565
O7 Dy1 2.342(4) .
Dy1 O1 2.371(3) 2_565
Dy1 Dy1 3.8787(5) 2_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N1 C10 C1 O1 -4.6(7) .
C5 C10 C1 O1 176.6(4) .
N1 C10 C1 C2 175.5(4) .
C5 C10 C1 C2 -3.2(7) .
O1 C1 C2 C3 -177.7(5) .
C10 C1 C2 C3 2.1(7) .
N1 C10 C5 C4 -176.8(5) .
C1 C10 C5 C4 2.0(8) .
N1 C10 C5 C6 1.2(7) .
C1 C10 C5 C6 179.9(5) .
C4 C5 C6 C7 177.1(6) .
C10 C5 C6 C7 -0.7(9) .
O5 C19 C20 F9' -178.0(10) .
C18 C19 C20 F9' 3.0(14) .
O5 C19 C20 F7 -5.6(14) .
C18 C19 C20 F7 175.4(11) .
O5 C19 C20 F7' 51.8(11) .
C18 C19 C20 F7' -127.2(9) .
O5 C19 C20 F8 -125.5(10) .
C18 C19 C20 F8 55.5(12) .
O5 C19 C20 F9 120.6(9) .
C18 C19 C20 F9 -58.4(11) .
O5 C19 C20 F8' -61.5(11) .
C18 C19 C20 F8' 119.6(10) .
F10' C16 C17 O4 169.0(18) .
F10 C16 C17 O4 -173.5(17) .
F12' C16 C17 O4 38.9(14) .
F12 C16 C17 O4 67.1(11) .
F11 C16 C17 O4 -48.5(15) .
F11' C16 C17 O4 -73.5(14) .
F10' C16 C17 C18 -10(2) .
F10 C16 C17 C18 7.1(19) .
F12' C16 C17 C18 -140.5(12) .
F12 C16 C17 C18 -112.3(11) .
F11 C16 C17 C18 132.0(14) .
F11' C16 C17 C18 107.0(14) .
C6 C5 C4 C3 -177.4(6) .
C10 C5 C4 C3 0.3(9) .
F16' C25 C24 O7 63.6(10) .
F17 C25 C24 O7 -21.2(11) .
F17' C25 C24 O7 -57.1(9) .
F18 C25 C24 O7 -143.7(8) .
F16 C25 C24 O7 99.5(9) .
F18' C25 C24 O7 -173.9(7) .
F16' C25 C24 C23 -113.2(9) .
F17 C25 C24 C23 162.0(8) .
F17' C25 C24 C23 126.1(8) .
F18 C25 C24 C23 39.5(10) .
F16 C25 C24 C23 -77.2(10) .
F18' C25 C24 C23 9.3(10) .
F3 C11 C12 O2 -35.8(13) .
F1 C11 C12 O2 -166.5(16) .
F2' C11 C12 O2 57.9(13) .
F1' C11 C12 O2 178.2(14) .
F3' C11 C12 O2 -63.0(13) .
F2 C11 C12 O2 76.9(12) .
F3 C11 C12 C13 144.0(12) .
F1 C11 C12 C13 13.3(18) .
F2' C11 C12 C13 -122.2(13) .
F1' C11 C12 C13 -2.0(15) .
F3' C11 C12 C13 116.8(12) .
F2 C11 C12 C13 -103.2(13) .
C5 C4 C3 C2 -1.5(9) .
C1 C2 C3 C4 0.2(9) .
O2 C12 C13 C14 -7.2(10) .
C11 C12 C13 C14 173.0(6) .
C12 C13 C14 O3 0.4(10) .
C12 C13 C14 C15 -177.5(6) .
F5' C15 C14 O3 -173.8(14) .
F5 C15 C14 O3 163.2(13) .
F4' C15 C14 O3 -44.5(12) .
F6' C15 C14 O3 69.3(12) .
F6 C15 C14 O3 40.1(13) .
F4 C15 C14 O3 -78.1(10) .
F5' C15 C14 C13 4.3(16) .
F5 C15 C14 C13 -18.7(14) .
F4' C15 C14 C13 133.6(11) .
F6' C15 C14 C13 -112.6(12) .
F6 C15 C14 C13 -141.8(11) .
F4 C15 C14 C13 100.0(10) .
F13' C21 C22 O6 -41.6(14) .
F14 C21 C22 O6 96.1(12) .
F15' C21 C22 O6 -175.6(8) .
F13 C21 C22 O6 -23.0(13) .
F15 C21 C22 O6 -136.0(8) .
F14' C21 C22 O6 74.7(11) .
F13' C21 C22 C23 137.4(13) .
F14 C21 C22 C23 -84.8(12) .
F15' C21 C22 C23 3.4(11) .
F13 C21 C22 C23 156.0(12) .
F15 C21 C22 C23 43.0(11) .
F14' C21 C22 C23 -106.3(11) .
O4 C17 C18 C19 2.1(12) .
C16 C17 C18 C19 -178.5(7) .
O5 C19 C18 C17 -1.1(13) .
C20 C19 C18 C17 177.7(7) .
C5 C6 C7 C8 0.3(11) .
N1 C8 C7 C6 -0.4(10) .
C9 C8 C7 C6 -176.9(7) .
O6 C22 C23 C24 6.4(10) .
C21 C22 C23 C24 -172.4(6) .
O7 C24 C23 C22 1.0(10) .
C25 C24 C23 C22 177.3(6) .
C7 C8 N1 C10 1.0(9) .
C9 C8 N1 C10 177.6(6) .
C1 C10 N1 C8 179.8(5) .
C5 C10 N1 C8 -1.4(8) .
C18 C17 O4 Dy1 4.5(11) .
C16 C17 O4 Dy1 -174.8(5) .
C18 C19 O5 Dy1 -6.4(12) .
C20 C19 O5 Dy1 174.7(5) .
C23 C22 O6 Dy1 0.5(9) .
C21 C22 O6 Dy1 179.4(4) .
C13 C14 O3 Dy1 30.2(8) .
C15 C14 O3 Dy1 -151.8(4) .
C13 C12 O2 Dy1 -17.6(9) .
C11 C12 O2 Dy1 162.2(4) .
C2 C1 O1 Dy1 -80.6(5) .
C10 C1 O1 Dy1 99.6(4) .
C2 C1 O1 Dy1 78.1(5) 2_565
C10 C1 O1 Dy1 -101.8(4) 2_565
C23 C24 O7 Dy1 -16.1(9) .
C25 C24 O7 Dy1 167.5(4) .
