#------------------------------------------------------------------------------
#$Date: 2016-04-05 20:57:40 +0300 (Tue, 05 Apr 2016) $
#$Revision: 181736 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/84/7038484.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7038484
loop_
_publ_author_name
'Hering-Junghans, Christian'
'Schulz, Axel'
'Thomas, Max'
'Villinger, Alexander'
_publ_section_title
;
 Synthesis of mono-, di-, and triaminobismuthanes and observation of C-C
 coupling of aromatic systems with bismuth(iii) chloride.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6053
_journal_page_last               6059
_journal_paper_doi               10.1039/c6dt00229c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C15 H26 Bi Cl2 N Si'
_chemical_formula_sum            'C15 H26 Bi Cl2 N Si'
_chemical_formula_weight         528.34
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2016-01-15 deposited with the CCDC.
2016-02-18 downloaded from the CCDC.
;
_cell_angle_alpha                107.659(4)
_cell_angle_beta                 102.886(4)
_cell_angle_gamma                101.754(4)
_cell_formula_units_Z            8
_cell_length_a                   14.3834(12)
_cell_length_b                   16.6481(15)
_cell_length_c                   19.0847(17)
_cell_measurement_reflns_used    9890
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      31.36
_cell_measurement_theta_min      2.67
_cell_volume                     4059.8(6)
_computing_cell_refinement       'Bruker Apex V7.51A'
_computing_data_collection       'Bruker Apex V7.51A'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP-3v2.01 (Farrugia, 1997)'
_computing_publication_material  SHELXL-2013
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker-Nonius Apex X8-CCD-diffractometer'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0469
_diffrn_reflns_av_unetI/netI     0.0645
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            98637
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.999
_diffrn_reflns_theta_min         2.671
_exptl_absorpt_coefficient_mu    9.000
_exptl_absorpt_correction_T_max  0.7464
_exptl_absorpt_correction_T_min  0.5020
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.729
_exptl_crystal_description       block
_exptl_crystal_F_000             2032
_exptl_crystal_size_max          0.270
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.140
_refine_diff_density_max         1.264
_refine_diff_density_min         -0.994
_refine_diff_density_rms         0.144
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.001
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     749
_refine_ls_number_reflns         25805
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.0659
_refine_ls_R_factor_gt           0.0324
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0203P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0532
_refine_ls_wR_factor_ref         0.0607
_reflns_Friedel_coverage         0.000
_reflns_number_gt                18083
_reflns_number_total             25805
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6dt00229c2.cif
_cod_data_source_block           av667b
_cod_depositor_comments
'Adding full bibliography for 7038481--7038499.cif.'
_cod_database_code               7038484
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.195
_shelx_estimated_absorpt_t_max   0.366
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Bi1 Bi 0.40163(2) 0.53757(2) 0.24064(2) 0.02955(3) Uani 1 1 d . .
Cl1 Cl 0.52546(7) 0.68061(7) 0.27249(6) 0.0489(3) Uani 1 1 d . .
Cl2 Cl 0.40389(6) 0.56281(6) 0.37773(5) 0.0371(2) Uani 1 1 d . .
Si1 Si 0.16013(7) 0.51546(6) 0.21377(6) 0.0314(2) Uani 1 1 d . .
N1 N 0.27377(18) 0.58189(17) 0.21692(15) 0.0270(6) Uani 1 1 d . .
C1 C 0.2811(2) 0.6593(2) 0.1974(2) 0.0360(8) Uani 1 1 d . .
C2 C 0.2899(3) 0.7413(2) 0.2535(3) 0.0464(10) Uani 1 1 d . .
C3 C 0.2900(3) 0.8128(3) 0.2303(3) 0.0602(13) Uani 1 1 d . .
H3 H 0.2947 0.8678 0.2672 0.072 Uiso 1 1 calc R U
C4 C 0.2835(3) 0.8063(3) 0.1564(3) 0.0664(14) Uani 1 1 d . .
H4 H 0.2824 0.8559 0.1419 0.080 Uiso 1 1 calc R U
C5 C 0.2784(3) 0.7266(3) 0.1027(3) 0.0647(14) Uani 1 1 d . .
H5 H 0.2757 0.7233 0.0517 0.078 Uiso 1 1 calc R U
C6 C 0.2772(3) 0.6513(3) 0.1204(2) 0.0447(10) Uani 1 1 d . .
C7 C 0.3006(3) 0.7527(3) 0.3375(2) 0.0491(10) Uani 1 1 d . .
H7 H 0.2963 0.6941 0.3425 0.059 Uiso 1 1 calc R U
C8 C 0.4008(3) 0.8168(3) 0.3914(3) 0.0716(14) Uani 1 1 d . .
H8A H 0.4547 0.7962 0.3755 0.107 Uiso 1 1 calc R U
H8B H 0.4068 0.8201 0.4444 0.107 Uiso 1 1 calc R U
H8C H 0.4054 0.8754 0.3888 0.107 Uiso 1 1 calc R U
C9 C 0.2163(3) 0.7858(3) 0.3637(3) 0.0724(14) Uani 1 1 d . .
H9A H 0.2185 0.7827 0.4145 0.109 Uiso 1 1 calc R U
H9B H 0.1516 0.7486 0.3262 0.109 Uiso 1 1 calc R U
H9C H 0.2255 0.8469 0.3670 0.109 Uiso 1 1 calc R U
C10 C 0.2764(3) 0.5679(3) 0.0611(2) 0.0520(11) Uani 1 1 d . .
H10 H 0.2643 0.5201 0.0825 0.062 Uiso 1 1 calc R U
C11 C 0.3782(3) 0.5763(3) 0.0468(3) 0.0707(15) Uani 1 1 d . .
H11A H 0.3918 0.6222 0.0251 0.106 Uiso 1 1 calc R U
H11B H 0.3774 0.5199 0.0104 0.106 Uiso 1 1 calc R U
H11C H 0.4303 0.5921 0.0957 0.106 Uiso 1 1 calc R U
C12 C 0.1940(4) 0.5389(4) -0.0158(3) 0.091(2) Uani 1 1 d . .
H12A H 0.1294 0.5350 -0.0063 0.136 Uiso 1 1 calc R U
H12B H 0.1931 0.4811 -0.0498 0.136 Uiso 1 1 calc R U
H12C H 0.2070 0.5820 -0.0404 0.136 Uiso 1 1 calc R U
C13 C 0.1241(3) 0.5508(3) 0.3040(2) 0.0565(12) Uani 1 1 d . .
H13A H 0.1790 0.5572 0.3482 0.085 Uiso 1 1 calc R U
H13B H 0.0646 0.5064 0.2996 0.085 Uiso 1 1 calc R U
H13C H 0.1099 0.6075 0.3115 0.085 Uiso 1 1 calc R U
C14 C 0.0589(3) 0.5130(3) 0.1327(3) 0.0659(13) Uani 1 1 d . .
H14A H 0.0580 0.5733 0.1386 0.099 Uiso 1 1 calc R U
H14B H -0.0053 0.4794 0.1331 0.099 Uiso 1 1 calc R U
H14C H 0.0707 0.4848 0.0837 0.099 Uiso 1 1 calc R U
C15 C 0.1740(3) 0.4035(2) 0.1996(3) 0.0484(10) Uani 1 1 d . .
H15A H 0.1982 0.3838 0.1551 0.073 Uiso 1 1 calc R U
H15B H 0.1092 0.3624 0.1904 0.073 Uiso 1 1 calc R U
H15C H 0.2218 0.4053 0.2459 0.073 Uiso 1 1 calc R U
Bi2 Bi 0.36197(2) 0.32146(2) 0.53225(2) 0.02357(3) Uani 1 1 d . .
Cl3 Cl 0.37144(6) 0.43069(5) 0.46889(5) 0.03002(18) Uani 1 1 d . .
Cl4 Cl 0.37083(6) 0.48801(5) 0.65986(5) 0.0354(2) Uani 1 1 d . .
Si2 Si 0.13011(6) 0.25748(7) 0.38961(6) 0.0326(2) Uani 1 1 d . .
N2 N 0.20701(17) 0.25812(17) 0.47538(15) 0.0272(6) Uani 1 1 d . .
C16 C 0.1714(2) 0.2025(2) 0.5154(2) 0.0329(8) Uani 1 1 d . .
C17 C 0.1264(2) 0.2358(3) 0.5725(2) 0.0401(10) Uani 1 1 d . .
C18 C 0.0880(3) 0.1787(3) 0.6062(2) 0.0608(14) Uani 1 1 d . .
H18 H 0.0558 0.1988 0.6436 0.073 Uiso 1 1 calc R U
C19 C 0.0953(4) 0.0936(4) 0.5867(3) 0.0737(16) Uani 1 1 d . .
H19 H 0.0687 0.0562 0.6110 0.088 Uiso 1 1 calc R U
C20 C 0.1410(3) 0.0631(3) 0.5324(3) 0.0635(13) Uani 1 1 d . .
H20 H 0.1466 0.0050 0.5201 0.076 Uiso 1 1 calc R U
C21 C 0.1798(3) 0.1164(3) 0.4943(2) 0.0444(10) Uani 1 1 d . .
C22 C 0.1163(3) 0.3269(3) 0.5956(2) 0.0477(11) Uani 1 1 d . .
H22 H 0.1594 0.3611 0.5737 0.057 Uiso 1 1 calc R U
C23 C 0.0083(3) 0.3276(3) 0.5631(3) 0.0688(14) Uani 1 1 d . .
H23A H -0.0132 0.3004 0.5067 0.103 Uiso 1 1 calc R U
H23B H 0.0053 0.3886 0.5785 0.103 Uiso 1 1 calc R U
H23C H -0.0357 0.2943 0.5836 0.103 Uiso 1 1 calc R U
C24 C 0.1518(3) 0.3756(3) 0.6845(2) 0.0664(14) Uani 1 1 d . .
H24A H 0.1044 0.3490 0.7068 0.100 Uiso 1 1 calc R U
H24B H 0.1554 0.4379 0.6967 0.100 Uiso 1 1 calc R U
H24C H 0.2178 0.3705 0.7062 0.100 Uiso 1 1 calc R U
C25 C 0.2285(3) 0.0779(3) 0.4351(3) 0.0543(11) Uani 1 1 d . .
H25 H 0.2521 0.1250 0.4153 0.065 Uiso 1 1 calc R U
C26 C 0.3198(3) 0.0539(3) 0.4693(3) 0.0815(17) Uani 1 1 d . .
H26A H 0.3641 0.1040 0.5152 0.122 Uiso 1 1 calc R U
H26B H 0.3552 0.0392 0.4310 0.122 Uiso 1 1 calc R U
H26C H 0.2991 0.0030 0.4838 0.122 Uiso 1 1 calc R U
C27 C 0.1541(3) -0.0006(3) 0.3650(3) 0.0709(14) Uani 1 1 d . .
H27A H 0.1297 -0.0489 0.3817 0.106 Uiso 1 1 calc R U
H27B H 0.1875 -0.0206 0.3263 0.106 Uiso 1 1 calc R U
H27C H 0.0978 0.0178 0.3424 0.106 Uiso 1 1 calc R U
C28 C 0.0082(2) 0.1715(3) 0.3620(2) 0.0493(11) Uani 1 1 d . .
H28A H 0.0175 0.1128 0.3442 0.074 Uiso 1 1 calc R U
H28B H -0.0404 0.1777 0.3204 0.074 Uiso 1 1 calc R U
H28C H -0.0162 0.1791 0.4069 0.074 Uiso 1 1 calc R U
C29 C 0.1094(3) 0.3677(3) 0.4029(2) 0.0497(10) Uani 1 1 d . .
H29A H 0.0882 0.3874 0.4490 0.075 Uiso 1 1 calc R U
H29B H 0.0576 0.3632 0.3575 0.075 Uiso 1 1 calc R U
H29C H 0.1716 0.4103 0.4091 0.075 Uiso 1 1 calc R U
C30 C 0.1868(3) 0.2293(3) 0.3103(2) 0.0441(10) Uani 1 1 d . .
H30A H 0.2463 0.2775 0.3211 0.066 Uiso 1 1 calc R U
H30B H 0.1385 0.2205 0.2614 0.066 Uiso 1 1 calc R U
H30C H 0.2054 0.1750 0.3065 0.066 Uiso 1 1 calc R U
Bi3 Bi 0.46376(2) 0.62804(2) 0.63618(2) 0.02454(3) Uani 1 1 d . .
Cl5 Cl 0.60106(6) 0.67455(5) 0.75680(5) 0.03391(19) Uani 1 1 d . .
Cl6 Cl 0.44236(6) 0.24132(6) 0.43009(5) 0.0370(2) Uani 1 1 d . .
Si3 Si 0.27461(6) 0.70749(7) 0.62342(5) 0.0329(2) Uani 1 1 d . .
N3 N 0.38608(17) 0.71412(17) 0.68869(15) 0.0267(6) Uani 1 1 d . .
C31 C 0.4189(2) 0.7710(2) 0.76897(18) 0.0263(7) Uani 1 1 d . .
C32 C 0.3864(2) 0.7409(2) 0.82445(19) 0.0303(8) Uani 1 1 d . .
C33 C 0.4162(2) 0.7986(2) 0.90062(19) 0.0366(8) Uani 1 1 d . .
H33 H 0.3946 0.7788 0.9377 0.044 Uiso 1 1 calc R U
C34 C 0.4765(3) 0.8843(2) 0.9241(2) 0.0419(9) Uani 1 1 d . .
H34 H 0.4951 0.9229 0.9764 0.050 Uiso 1 1 calc R U
C35 C 0.5091(2) 0.9128(2) 0.8713(2) 0.0394(9) Uani 1 1 d . .
H35 H 0.5517 0.9711 0.8878 0.047 Uiso 1 1 calc R U
C36 C 0.4812(2) 0.8578(2) 0.79292(19) 0.0317(8) Uani 1 1 d . .
C37 C 0.3227(2) 0.6477(2) 0.8056(2) 0.0354(8) Uani 1 1 d . .
H37 H 0.3036 0.6160 0.7485 0.042 Uiso 1 1 calc R U
C38 C 0.2261(3) 0.6471(3) 0.8277(2) 0.0562(12) Uani 1 1 d . .
H38A H 0.2427 0.6765 0.8837 0.084 Uiso 1 1 calc R U
H38B H 0.1853 0.5860 0.8120 0.084 Uiso 1 1 calc R U
H38C H 0.1887 0.6782 0.8014 0.084 Uiso 1 1 calc R U
C39 C 0.3830(3) 0.5986(3) 0.8448(2) 0.0497(10) Uani 1 1 d . .
H39A H 0.4440 0.6001 0.8297 0.075 Uiso 1 1 calc R U
H39B H 0.3430 0.5373 0.8287 0.075 Uiso 1 1 calc R U
H39C H 0.4006 0.6272 0.9010 0.075 Uiso 1 1 calc R U
C40 C 0.5225(2) 0.8956(2) 0.7397(2) 0.0373(9) Uani 1 1 d . .
H40 H 0.4922 0.8509 0.6860 0.045 Uiso 1 1 calc R U
C41 C 0.4966(3) 0.9806(3) 0.7400(3) 0.0552(11) Uani 1 1 d . .
H41A H 0.4245 0.9705 0.7301 0.083 Uiso 1 1 calc R U
H41B H 0.5168 0.9981 0.6998 0.083 Uiso 1 1 calc R U
H41C H 0.5319 1.0276 0.7905 0.083 Uiso 1 1 calc R U
C42 C 0.6364(2) 0.9129(3) 0.7607(2) 0.0471(10) Uani 1 1 d . .
H42A H 0.6681 0.9575 0.8128 0.071 Uiso 1 1 calc R U
H42B H 0.6609 0.9340 0.7236 0.071 Uiso 1 1 calc R U
H42C H 0.6526 0.8581 0.7590 0.071 Uiso 1 1 calc R U
C43 C 0.1624(3) 0.6556(5) 0.6429(3) 0.110(3) Uani 1 1 d . .
H43A H 0.1574 0.5934 0.6334 0.165 Uiso 1 1 calc R U
H43B H 0.1032 0.6600 0.6087 0.165 Uiso 1 1 calc R U
H43C H 0.1668 0.6858 0.6968 0.165 Uiso 1 1 calc R U
C44 C 0.2727(3) 0.6408(3) 0.5258(2) 0.0657(14) Uani 1 1 d . .
H44A H 0.3306 0.6693 0.5138 0.099 Uiso 1 1 calc R U
H44B H 0.2114 0.6360 0.4878 0.099 Uiso 1 1 calc R U
H44C H 0.2751 0.5818 0.5240 0.099 Uiso 1 1 calc R U
C45 C 0.2680(4) 0.8177(3) 0.6224(3) 0.0853(17) Uani 1 1 d . .
H45A H 0.2645 0.8536 0.6725 0.128 Uiso 1 1 calc R U
H45B H 0.2084 0.8105 0.5816 0.128 Uiso 1 1 calc R U
H45C H 0.3276 0.8468 0.6127 0.128 Uiso 1 1 calc R U
Bi4 Bi 0.67637(2) 0.78966(2) 0.95533(2) 0.03341(4) Uani 1 1 d . .
Cl7 Cl 0.82197(7) 0.82058(6) 0.91177(5) 0.0433(2) Uani 1 1 d . .
Cl8 Cl 0.66496(8) 0.63233(6) 0.94055(6) 0.0508(3) Uani 1 1 d . .
Si4 Si 0.69934(7) 0.82711(8) 1.14168(6) 0.0456(3) Uani 1 1 d . .
N4 N 0.75898(18) 0.84521(19) 1.07465(15) 0.0328(7) Uani 1 1 d . .
C46 C 0.8611(2) 0.8993(2) 1.09757(18) 0.0308(8) Uani 1 1 d . .
C47 C 0.8794(3) 0.9887(2) 1.1049(2) 0.0385(9) Uani 1 1 d . .
C48 C 0.9777(3) 1.0399(3) 1.1264(2) 0.0486(10) Uani 1 1 d . .
H48 H 0.9910 1.1000 1.1313 0.058 Uiso 1 1 calc R U
C49 C 1.0565(3) 1.0052(3) 1.1409(2) 0.0501(11) Uani 1 1 d . .
H49 H 1.1233 1.0413 1.1557 0.060 Uiso 1 1 calc R U
C50 C 1.0375(3) 0.9183(3) 1.1335(2) 0.0414(9) Uani 1 1 d . .
H50 H 1.0919 0.8949 1.1439 0.050 Uiso 1 1 calc R U
C51 C 0.9410(2) 0.8638(2) 1.11145(19) 0.0342(8) Uani 1 1 d . .
C52 C 0.7970(3) 1.0313(2) 1.0887(2) 0.0474(10) Uani 1 1 d . .
H52 H 0.7327 0.9880 1.0812 0.057 Uiso 1 1 calc R U
C53 C 0.7877(3) 1.0505(3) 1.0151(3) 0.0670(13) Uani 1 1 d . .
H53A H 0.8506 1.0911 1.0198 0.100 Uiso 1 1 calc R U
H53B H 0.7338 1.0775 1.0068 0.100 Uiso 1 1 calc R U
H53C H 0.7728 0.9954 0.9714 0.100 Uiso 1 1 calc R U
C54 C 0.8101(4) 1.1152(3) 1.1569(3) 0.0762(15) Uani 1 1 d . .
H54A H 0.8149 1.1015 1.2038 0.114 Uiso 1 1 calc R U
H54B H 0.7526 1.1374 1.1459 0.114 Uiso 1 1 calc R U
H54C H 0.8711 1.1601 1.1645 0.114 Uiso 1 1 calc R U
C55 C 0.9259(3) 0.7678(2) 1.1026(2) 0.0403(9) Uani 1 1 d . .
H55 H 0.8526 0.7386 1.0869 0.048 Uiso 1 1 calc R U
C56 C 0.9662(3) 0.7190(3) 1.0405(3) 0.0568(11) Uani 1 1 d . .
H56A H 1.0391 0.7423 1.0572 0.085 Uiso 1 1 calc R U
H56B H 0.9383 0.7274 0.9924 0.085 Uiso 1 1 calc R U
H56C H 0.9473 0.6560 1.0319 0.085 Uiso 1 1 calc R U
C57 C 0.9739(3) 0.7595(3) 1.1787(2) 0.0605(12) Uani 1 1 d . .
H57A H 0.9554 0.6974 1.1732 0.091 Uiso 1 1 calc R U
H57B H 0.9505 0.7936 1.2192 0.091 Uiso 1 1 calc R U
H57C H 1.0465 0.7823 1.1927 0.091 Uiso 1 1 calc R U
C58 C 0.7517(3) 0.9238(4) 1.2326(2) 0.0849(19) Uani 1 1 d . .
H58A H 0.8247 0.9392 1.2483 0.127 Uiso 1 1 calc R U
H58B H 0.7277 0.9099 1.2729 0.127 Uiso 1 1 calc R U
H58C H 0.7306 0.9737 1.2249 0.127 Uiso 1 1 calc R U
C59 C 0.7087(4) 0.7265(4) 1.1612(3) 0.0900(19) Uani 1 1 d . .
H59A H 0.6816 0.6754 1.1126 0.135 Uiso 1 1 calc R U
H59B H 0.6708 0.7184 1.1965 0.135 Uiso 1 1 calc R U
H59C H 0.7789 0.7324 1.1848 0.135 Uiso 1 1 calc R U
C60 C 0.5646(3) 0.8129(3) 1.0981(2) 0.0671(14) Uani 1 1 d . .
H60A H 0.5574 0.8642 1.0848 0.101 Uiso 1 1 calc R U
H60B H 0.5287 0.8075 1.1353 0.101 Uiso 1 1 calc R U
H60C H 0.5368 0.7595 1.0514 0.101 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Bi1 Cl1 95.99(7) . .
N1 Bi1 Cl2 92.50(7) . .
Cl1 Bi1 Cl2 94.90(3) . .
N1 Si1 C14 109.25(16) . .
N1 Si1 C15 107.05(15) . .
C14 Si1 C15 111.1(2) . .
N1 Si1 C13 114.92(15) . .
C14 Si1 C13 108.2(2) . .
C15 Si1 C13 106.3(2) . .
C1 N1 Si1 122.6(2) . .
C1 N1 Bi1 119.66(19) . .
Si1 N1 Bi1 117.48(14) . .
C2 C1 C6 120.9(3) . .
C2 C1 N1 120.5(3) . .
C6 C1 N1 118.5(3) . .
C3 C2 C1 118.2(4) . .
C3 C2 C7 120.0(4) . .
C1 C2 C7 121.8(4) . .
C4 C3 C2 122.0(4) . .
C4 C3 H3 119.0 . .
C2 C3 H3 119.0 . .
C3 C4 C5 119.4(4) . .
C3 C4 H4 120.3 . .
C5 C4 H4 120.3 . .
C4 C5 C6 122.7(5) . .
C4 C5 H5 118.6 . .
C6 C5 H5 118.6 . .
C5 C6 C1 116.7(4) . .
C5 C6 C10 120.5(4) . .
C1 C6 C10 122.7(3) . .
C8 C7 C2 111.6(3) . .
C8 C7 C9 108.8(4) . .
C2 C7 C9 111.6(4) . .
C8 C7 H7 108.2 . .
C2 C7 H7 108.2 . .
C9 C7 H7 108.2 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C7 C9 H9A 109.5 . .
C7 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C7 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C6 C10 C12 113.7(4) . .
C6 C10 C11 110.8(3) . .
C12 C10 C11 109.7(4) . .
C6 C10 H10 107.5 . .
C12 C10 H10 107.5 . .
C11 C10 H10 107.5 . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C10 C12 H12A 109.5 . .
C10 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C10 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
Si1 C13 H13A 109.5 . .
Si1 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
Si1 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
Si1 C14 H14A 109.5 . .
Si1 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
Si1 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
Si1 C15 H15A 109.5 . .
Si1 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
Si1 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N2 Bi2 Cl3 94.48(7) . .
N2 Bi2 Cl6 101.95(7) . .
Cl3 Bi2 Cl6 84.24(3) . .
N2 Bi2 Cl4 104.60(7) . .
Cl3 Bi2 Cl4 77.51(3) . .
Cl6 Bi2 Cl4 148.71(2) . .
Bi3 Cl4 Bi2 109.22(3) . .
N2 Si2 C30 110.90(15) . .
N2 Si2 C29 110.96(16) . .
C30 Si2 C29 108.28(19) . .
N2 Si2 C28 107.89(16) . .
C30 Si2 C28 108.73(17) . .
C29 Si2 C28 110.06(18) . .
C16 N2 Si2 121.64(19) . .
C16 N2 Bi2 107.99(19) . .
Si2 N2 Bi2 130.04(13) . .
C21 C16 C17 122.2(3) . .
C21 C16 N2 118.8(3) . .
C17 C16 N2 119.0(3) . .
C18 C17 C16 117.2(4) . .
C18 C17 C22 119.6(4) . .
C16 C17 C22 123.2(3) . .
C19 C18 C17 122.0(4) . .
C19 C18 H18 119.0 . .
C17 C18 H18 119.0 . .
C20 C19 C18 119.9(4) . .
C20 C19 H19 120.0 . .
C18 C19 H19 120.0 . .
C19 C20 C21 121.5(5) . .
C19 C20 H20 119.3 . .
C21 C20 H20 119.3 . .
C16 C21 C20 117.3(4) . .
C16 C21 C25 124.6(3) . .
C20 C21 C25 118.2(4) . .
C17 C22 C23 112.1(3) . .
C17 C22 C24 112.5(4) . .
C23 C22 C24 108.9(3) . .
C17 C22 H22 107.7 . .
C23 C22 H22 107.7 . .
C24 C22 H22 107.7 . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C22 C24 H24A 109.5 . .
C22 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C22 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C21 C25 C26 112.8(4) . .
C21 C25 C27 112.2(3) . .
C26 C25 C27 111.3(4) . .
C21 C25 H25 106.7 . .
C26 C25 H25 106.7 . .
C27 C25 H25 106.7 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C25 C27 H27A 109.5 . .
C25 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C25 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
Si2 C28 H28A 109.5 . .
Si2 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
Si2 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
Si2 C29 H29A 109.5 . .
Si2 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
Si2 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
Si2 C30 H30A 109.5 . .
Si2 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
Si2 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
N3 Bi3 Cl5 93.19(7) . .
N3 Bi3 Cl4 96.16(7) . .
Cl5 Bi3 Cl4 92.16(3) . .
N3 Bi3 Cl6 92.51(7) . 2_666
Cl5 Bi3 Cl6 97.67(3) . 2_666
Cl4 Bi3 Cl6 166.51(2) . 2_666
N3 Bi3 Si3 29.91(7) . .
Cl5 Bi3 Si3 123.10(3) . .
Cl4 Bi3 Si3 94.25(3) . .
Cl6 Bi3 Si3 88.12(2) 2_666 .
Bi2 Cl6 Bi3 109.25(3) . 2_666
N3 Si3 C43 113.20(18) . .
N3 Si3 C44 107.36(16) . .
C43 Si3 C44 108.7(3) . .
N3 Si3 C45 112.08(18) . .
C43 Si3 C45 108.0(3) . .
C44 Si3 C45 107.2(2) . .
N3 Si3 Bi3 37.42(8) . .
C43 Si3 Bi3 120.6(2) . .
C44 Si3 Bi3 70.41(14) . .
C45 Si3 Bi3 129.60(16) . .
C31 N3 Si3 122.5(2) . .
C31 N3 Bi3 124.84(19) . .
Si3 N3 Bi3 112.67(13) . .
C36 C31 C32 119.4(3) . .
C36 C31 N3 120.1(3) . .
C32 C31 N3 120.4(3) . .
C33 C32 C31 118.8(3) . .
C33 C32 C37 117.4(3) . .
C31 C32 C37 123.7(3) . .
C34 C33 C32 121.8(3) . .
C34 C33 H33 119.1 . .
C32 C33 H33 119.1 . .
C35 C34 C33 119.4(3) . .
C35 C34 H34 120.3 . .
C33 C34 H34 120.3 . .
C34 C35 C36 121.7(3) . .
C34 C35 H35 119.1 . .
C36 C35 H35 119.1 . .
C35 C36 C31 118.8(3) . .
C35 C36 C40 117.3(3) . .
C31 C36 C40 123.9(3) . .
C32 C37 C39 110.4(3) . .
C32 C37 C38 111.8(3) . .
C39 C37 C38 111.2(3) . .
C32 C37 H37 107.8 . .
C39 C37 H37 107.8 . .
C38 C37 H37 107.8 . .
C37 C38 H38A 109.5 . .
C37 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
C37 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C37 C39 H39A 109.5 . .
C37 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C37 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
C36 C40 C41 112.5(3) . .
C36 C40 C42 111.0(3) . .
C41 C40 C42 109.6(3) . .
C36 C40 H40 107.9 . .
C41 C40 H40 107.9 . .
C42 C40 H40 107.9 . .
C40 C41 H41A 109.5 . .
C40 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
C40 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C40 C42 H42A 109.5 . .
C40 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
C40 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
Si3 C43 H43A 109.5 . .
Si3 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
Si3 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
Si3 C44 H44A 109.5 . .
Si3 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
Si3 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
Si3 C45 H45A 109.5 . .
Si3 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
Si3 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
N4 Bi4 Cl7 94.58(7) . .
N4 Bi4 Cl8 95.89(8) . .
Cl7 Bi4 Cl8 97.86(3) . .
N4 Si4 C58 109.26(18) . .
N4 Si4 C59 113.60(18) . .
C58 Si4 C59 109.7(3) . .
N4 Si4 C60 106.33(17) . .
C58 Si4 C60 110.3(2) . .
C59 Si4 C60 107.6(2) . .
C46 N4 Si4 122.6(2) . .
C46 N4 Bi4 118.59(19) . .
Si4 N4 Bi4 118.76(13) . .
C51 C46 C47 120.3(3) . .
C51 C46 N4 120.9(3) . .
C47 C46 N4 118.8(3) . .
C48 C47 C46 118.3(3) . .
C48 C47 C52 118.2(3) . .
C46 C47 C52 123.5(3) . .
C49 C48 C47 121.4(4) . .
C49 C48 H48 119.3 . .
C47 C48 H48 119.3 . .
C50 C49 C48 119.5(3) . .
C50 C49 H49 120.3 . .
C48 C49 H49 120.3 . .
C49 C50 C51 121.6(4) . .
C49 C50 H50 119.2 . .
C51 C50 H50 119.2 . .
C50 C51 C46 118.8(3) . .
C50 C51 C55 118.5(3) . .
C46 C51 C55 122.7(3) . .
C53 C52 C47 112.1(3) . .
C53 C52 C54 110.4(4) . .
C47 C52 C54 112.2(3) . .
C53 C52 H52 107.3 . .
C47 C52 H52 107.3 . .
C54 C52 H52 107.3 . .
C52 C53 H53A 109.5 . .
C52 C53 H53B 109.5 . .
H53A C53 H53B 109.5 . .
C52 C53 H53C 109.5 . .
H53A C53 H53C 109.5 . .
H53B C53 H53C 109.5 . .
C52 C54 H54A 109.5 . .
C52 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C52 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C56 C55 C51 112.2(3) . .
C56 C55 C57 109.6(3) . .
C51 C55 C57 111.2(3) . .
C56 C55 H55 107.9 . .
C51 C55 H55 107.9 . .
C57 C55 H55 107.9 . .
C55 C56 H56A 109.5 . .
C55 C56 H56B 109.5 . .
H56A C56 H56B 109.5 . .
C55 C56 H56C 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
C55 C57 H57A 109.5 . .
C55 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
C55 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
Si4 C58 H58A 109.5 . .
Si4 C58 H58B 109.5 . .
H58A C58 H58B 109.5 . .
Si4 C58 H58C 109.5 . .
H58A C58 H58C 109.5 . .
H58B C58 H58C 109.5 . .
Si4 C59 H59A 109.5 . .
Si4 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
Si4 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
Si4 C60 H60A 109.5 . .
Si4 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
Si4 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Bi1 N1 2.125(3) .
Bi1 Cl1 2.4746(9) .
Bi1 Cl2 2.5124(9) .
Si1 N1 1.754(3) .
Si1 C14 1.856(4) .
Si1 C15 1.859(4) .
Si1 C13 1.867(4) .
N1 C1 1.436(4) .
C1 C2 1.417(5) .
C1 C6 1.422(5) .
C2 C3 1.389(6) .
C2 C7 1.525(6) .
C3 C4 1.362(7) .
C3 H3 0.9500 .
C4 C5 1.384(7) .
C4 H4 0.9500 .
C5 C6 1.392(5) .
C5 H5 0.9500 .
C6 C10 1.497(6) .
C7 C8 1.523(5) .
C7 C9 1.548(5) .
C7 H7 1.0000 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 C12 1.534(6) .
C10 C11 1.536(6) .
C10 H10 1.0000 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
Bi2 N2 2.128(2) .
Bi2 Cl3 2.4687(8) .
Bi2 Cl6 2.6409(8) .
Bi2 Cl4 3.0423(9) .
Cl4 Bi3 2.6580(8) .
Si2 N2 1.755(3) .
Si2 C30 1.857(3) .
Si2 C29 1.870(4) .
Si2 C28 1.872(3) .
N2 C16 1.454(4) .
C16 C21 1.404(5) .
C16 C17 1.416(5) .
C17 C18 1.392(5) .
C17 C22 1.493(6) .
C18 C19 1.384(7) .
C18 H18 0.9500 .
C19 C20 1.373(7) .
C19 H19 0.9500 .
C20 C21 1.413(5) .
C20 H20 0.9500 .
C21 C25 1.510(6) .
C22 C23 1.542(6) .
C22 C24 1.551(5) .
C22 H22 1.0000 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 C26 1.516(6) .
C25 C27 1.540(6) .
C25 H25 1.0000 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
Bi3 N3 2.142(2) .
Bi3 Cl5 2.4631(8) .
Bi3 Cl6 3.0638(9) 2_666
Bi3 Si3 3.2522(10) .
Cl6 Bi3 3.0639(9) 2_666
Si3 N3 1.757(3) .
Si3 C43 1.839(4) .
Si3 C44 1.847(4) .
Si3 C45 1.861(5) .
N3 C31 1.443(4) .
C31 C36 1.411(4) .
C31 C32 1.427(4) .
C32 C33 1.388(4) .
C32 C37 1.520(5) .
C33 C34 1.387(5) .
C33 H33 0.9500 .
C34 C35 1.368(5) .
C34 H34 0.9500 .
C35 C36 1.409(5) .
C35 H35 0.9500 .
C36 C40 1.512(5) .
C37 C39 1.532(5) .
C37 C38 1.540(5) .
C37 H37 1.0000 .
C38 H38A 0.9800 .
C38 H38B 0.9800 .
C38 H38C 0.9800 .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
C40 C41 1.534(5) .
C40 C42 1.540(5) .
C40 H40 1.0000 .
C41 H41A 0.9800 .
C41 H41B 0.9800 .
C41 H41C 0.9800 .
C42 H42A 0.9800 .
C42 H42B 0.9800 .
C42 H42C 0.9800 .
C43 H43A 0.9800 .
C43 H43B 0.9800 .
C43 H43C 0.9800 .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
C45 H45A 0.9800 .
C45 H45B 0.9800 .
C45 H45C 0.9800 .
Bi4 N4 2.126(3) .
Bi4 Cl7 2.4369(9) .
Bi4 Cl8 2.5145(11) .
Si4 N4 1.755(3) .
Si4 C58 1.843(5) .
Si4 C59 1.847(5) .
Si4 C60 1.865(4) .
N4 C46 1.448(4) .
C46 C51 1.405(5) .
C46 C47 1.415(5) .
C47 C48 1.390(5) .
C47 C52 1.521(5) .
C48 C49 1.386(6) .
C48 H48 0.9500 .
C49 C50 1.375(5) .
C49 H49 0.9500 .
C50 C51 1.386(5) .
C50 H50 0.9500 .
C51 C55 1.521(5) .
C52 C53 1.516(6) .
C52 C54 1.536(6) .
C52 H52 1.0000 .
C53 H53A 0.9800 .
C53 H53B 0.9800 .
C53 H53C 0.9800 .
C54 H54A 0.9800 .
C54 H54B 0.9800 .
C54 H54C 0.9800 .
C55 C56 1.521(5) .
C55 C57 1.523(5) .
C55 H55 1.0000 .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
C57 H57A 0.9800 .
C57 H57B 0.9800 .
C57 H57C 0.9800 .
C58 H58A 0.9800 .
C58 H58B 0.9800 .
C58 H58C 0.9800 .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C14 Si1 N1 C1 34.8(3)
C15 Si1 N1 C1 155.2(3)
C13 Si1 N1 C1 -87.0(3)
C14 Si1 N1 Bi1 -139.4(2)
C15 Si1 N1 Bi1 -19.0(2)
C13 Si1 N1 Bi1 98.7(2)
Si1 N1 C1 C2 85.0(3)
Bi1 N1 C1 C2 -100.9(3)
Si1 N1 C1 C6 -93.7(4)
Bi1 N1 C1 C6 80.5(3)
C6 C1 C2 C3 3.0(5)
N1 C1 C2 C3 -175.7(3)
C6 C1 C2 C7 -176.2(3)
N1 C1 C2 C7 5.1(5)
C1 C2 C3 C4 -1.1(6)
C7 C2 C3 C4 178.1(4)
C2 C3 C4 C5 -1.2(7)
C3 C4 C5 C6 1.6(7)
C4 C5 C6 C1 0.2(6)
C4 C5 C6 C10 -177.2(4)
C2 C1 C6 C5 -2.5(5)
N1 C1 C6 C5 176.2(3)
C2 C1 C6 C10 174.8(3)
N1 C1 C6 C10 -6.5(5)
C3 C2 C7 C8 -63.2(5)
C1 C2 C7 C8 116.0(4)
C3 C2 C7 C9 58.8(5)
C1 C2 C7 C9 -122.0(4)
C5 C6 C10 C12 -52.1(5)
C1 C6 C10 C12 130.7(4)
C5 C6 C10 C11 71.9(5)
C1 C6 C10 C11 -105.3(4)
C30 Si2 N2 C16 -122.6(3)
C29 Si2 N2 C16 117.0(3)
C28 Si2 N2 C16 -3.6(3)
C30 Si2 N2 Bi2 50.0(2)
C29 Si2 N2 Bi2 -70.4(2)
C28 Si2 N2 Bi2 168.9(2)
Si2 N2 C16 C21 87.7(4)
Bi2 N2 C16 C21 -86.3(3)
Si2 N2 C16 C17 -90.2(3)
Bi2 N2 C16 C17 95.7(3)
C21 C16 C17 C18 -1.6(5)
N2 C16 C17 C18 176.3(3)
C21 C16 C17 C22 -179.8(3)
N2 C16 C17 C22 -1.8(5)
C16 C17 C18 C19 1.7(6)
C22 C17 C18 C19 179.9(4)
C17 C18 C19 C20 -0.4(7)
C18 C19 C20 C21 -1.1(7)
C17 C16 C21 C20 0.2(5)
N2 C16 C21 C20 -177.7(3)
C17 C16 C21 C25 -178.8(3)
N2 C16 C21 C25 3.3(5)
C19 C20 C21 C16 1.2(6)
C19 C20 C21 C25 -179.8(4)
C18 C17 C22 C23 -72.7(5)
C16 C17 C22 C23 105.4(4)
C18 C17 C22 C24 50.5(4)
C16 C17 C22 C24 -131.4(3)
C16 C21 C25 C26 116.8(4)
C20 C21 C25 C26 -62.2(5)
C16 C21 C25 C27 -116.5(4)
C20 C21 C25 C27 64.5(5)
C43 Si3 N3 C31 -68.5(4)
C44 Si3 N3 C31 171.5(3)
C45 Si3 N3 C31 54.0(3)
Bi3 Si3 N3 C31 -179.0(3)
C43 Si3 N3 Bi3 110.5(3)
C44 Si3 N3 Bi3 -9.5(2)
C45 Si3 N3 Bi3 -127.0(2)
Si3 N3 C31 C36 -91.0(3)
Bi3 N3 C31 C36 90.1(3)
Si3 N3 C31 C32 87.2(3)
Bi3 N3 C31 C32 -91.7(3)
C36 C31 C32 C33 0.8(5)
N3 C31 C32 C33 -177.4(3)
C36 C31 C32 C37 -177.5(3)
N3 C31 C32 C37 4.3(5)
C31 C32 C33 C34 -0.1(5)
C37 C32 C33 C34 178.2(3)
C32 C33 C34 C35 -1.0(6)
C33 C34 C35 C36 1.4(6)
C34 C35 C36 C31 -0.7(5)
C34 C35 C36 C40 -179.3(3)
C32 C31 C36 C35 -0.4(5)
N3 C31 C36 C35 177.8(3)
C32 C31 C36 C40 178.0(3)
N3 C31 C36 C40 -3.8(5)
C33 C32 C37 C39 -66.5(4)
C31 C32 C37 C39 111.8(4)
C33 C32 C37 C38 57.8(4)
C31 C32 C37 C38 -123.9(4)
C35 C36 C40 C41 -56.9(4)
C31 C36 C40 C41 124.6(4)
C35 C36 C40 C42 66.3(4)
C31 C36 C40 C42 -112.2(4)
C58 Si4 N4 C46 29.9(4)
C59 Si4 N4 C46 -93.0(3)
C60 Si4 N4 C46 148.9(3)
C58 Si4 N4 Bi4 -147.7(2)
C59 Si4 N4 Bi4 89.4(3)
C60 Si4 N4 Bi4 -28.7(3)
Si4 N4 C46 C51 84.9(3)
Bi4 N4 C46 C51 -97.5(3)
Si4 N4 C46 C47 -95.9(3)
Bi4 N4 C46 C47 81.7(3)
C51 C46 C47 C48 -0.3(5)
N4 C46 C47 C48 -179.6(3)
C51 C46 C47 C52 178.2(3)
N4 C46 C47 C52 -1.0(5)
C46 C47 C48 C49 -0.3(6)
C52 C47 C48 C49 -179.0(4)
C47 C48 C49 C50 0.3(6)
C48 C49 C50 C51 0.5(6)
C49 C50 C51 C46 -1.1(5)
C49 C50 C51 C55 178.4(3)
C47 C46 C51 C50 1.0(5)
N4 C46 C51 C50 -179.8(3)
C47 C46 C51 C55 -178.4(3)
N4 C46 C51 C55 0.8(5)
C48 C47 C52 C53 69.9(4)
C46 C47 C52 C53 -108.7(4)
C48 C47 C52 C54 -55.0(5)
C46 C47 C52 C54 126.4(4)
C50 C51 C55 C56 -61.7(4)
C46 C51 C55 C56 117.8(4)
C50 C51 C55 C57 61.5(4)
C46 C51 C55 C57 -119.0(4)
