#------------------------------------------------------------------------------
#$Date: 2016-04-05 20:57:40 +0300 (Tue, 05 Apr 2016) $
#$Revision: 181736 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/84/7038488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7038488
loop_
_publ_author_name
'Hering-Junghans, Christian'
'Schulz, Axel'
'Thomas, Max'
'Villinger, Alexander'
_publ_section_title
;
 Synthesis of mono-, di-, and triaminobismuthanes and observation of C-C
 coupling of aromatic systems with bismuth(iii) chloride.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6053
_journal_page_last               6059
_journal_paper_doi               10.1039/c6dt00229c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C34 H46 Bi2 N4 Si2'
_chemical_formula_weight         984.89
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-01-15 deposited with the CCDC.
2016-02-18 downloaded from the CCDC.
;
_cell_angle_alpha                111.4350(10)
_cell_angle_beta                 95.3680(10)
_cell_angle_gamma                107.9840(10)
_cell_formula_units_Z            1
_cell_length_a                   8.7707(2)
_cell_length_b                   10.3814(3)
_cell_length_c                   11.5042(3)
_cell_measurement_reflns_used    9939
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      60.109
_cell_measurement_theta_min      4.537
_cell_volume                     901.84(4)
_computing_cell_refinement       'Bruker Apex V7.51A'
_computing_data_collection       'Bruker Apex V7.51A'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP-3v2.01 (Farrugia, 1997)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker Apex Kappa II-CCD-diffractometer'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0473
_diffrn_reflns_av_sigmaI/netI    0.0522
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            29366
_diffrn_reflns_theta_full        34.17
_diffrn_reflns_theta_max         34.17
_diffrn_reflns_theta_min         1.96
_exptl_absorpt_coefficient_mu    9.837
_exptl_absorpt_correction_T_max  0.7568
_exptl_absorpt_correction_T_min  0.1841
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.813
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             472
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.063
_refine_diff_density_min         -0.797
_refine_diff_density_rms         0.160
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     290
_refine_ls_number_reflns         7359
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.006
_refine_ls_R_factor_all          0.0410
_refine_ls_R_factor_gt           0.0285
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0134P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0454
_refine_ls_wR_factor_ref         0.0488
_reflns_number_gt                6209
_reflns_number_total             7359
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c6dt00229c2.cif
_cod_data_source_block           ch_mt25c
_cod_depositor_comments
'Adding full bibliography for 7038481--7038499.cif.'
_cod_database_code               7038488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.586823(12) -0.086020(9) 0.569874(9) 0.02197(3) Uani 1 1 d . . .
Si1 Si 0.80114(10) 0.09194(9) 0.88447(8) 0.02903(16) Uani 1 1 d . . .
N1 N 0.6408(3) 0.0621(2) 0.4761(2) 0.0256(5) Uani 1 1 d . . .
N2 N 0.6620(3) 0.0849(2) 0.7643(2) 0.0267(5) Uani 1 1 d . A .
C1 C 0.7953(3) 0.1477(3) 0.4719(3) 0.0253(5) Uani 1 1 d . . .
C2 C 0.9401(3) 0.1623(3) 0.5453(3) 0.0293(6) Uani 1 1 d . . .
H2 H 0.9337 0.1090 0.5976 0.035 Uiso 1 1 calc R . .
C3 C 1.0936(4) 0.2528(3) 0.5442(3) 0.0314(6) Uani 1 1 d . . .
H3 H 1.1897 0.2597 0.5955 0.038 Uiso 1 1 calc R . .
C4 C 1.1100(4) 0.3335(3) 0.4699(3) 0.0332(7) Uani 1 1 d . . .
C5 C 0.9681(4) 0.3167(3) 0.3945(3) 0.0407(8) Uani 1 1 d . . .
H5 H 0.9760 0.3698 0.3419 0.049 Uiso 1 1 calc R . .
C6 C 0.8122(4) 0.2239(3) 0.3924(3) 0.0343(6) Uani 1 1 d . . .
H6 H 0.7172 0.2126 0.3367 0.041 Uiso 1 1 calc R . .
C7 C 1.2779(4) 0.4370(3) 0.4740(4) 0.0473(9) Uani 1 1 d . . .
H7A H 1.3278 0.3808 0.4113 0.071 Uiso 1 1 calc R . .
H7B H 1.3489 0.4797 0.5603 0.071 Uiso 1 1 calc R . .
H7C H 1.2657 0.5172 0.4531 0.071 Uiso 1 1 calc R . .
C8A C 0.8936(8) -0.0376(6) 0.8171(5) 0.0334(13) Uani 0.509(3) 1 d P A 1
H8A H 0.8083 -0.1378 0.7732 0.050 Uiso 0.509(3) 1 calc PR A 1
H8B H 0.9718 -0.0351 0.8853 0.050 Uiso 0.509(3) 1 calc PR A 1
H8C H 0.9521 -0.0122 0.7553 0.050 Uiso 0.509(3) 1 calc PR A 1
C9A C 0.6972(10) 0.0635(8) 1.0149(6) 0.0447(17) Uani 0.509(3) 1 d P A 1
H9A H 0.6452 0.1368 1.0461 0.067 Uiso 0.509(3) 1 calc PR A 1
H9B H 0.7795 0.0762 1.0860 0.067 Uiso 0.509(3) 1 calc PR A 1
H9C H 0.6130 -0.0372 0.9800 0.067 Uiso 0.509(3) 1 calc PR A 1
C10A C 0.9566(8) 0.2924(6) 0.9644(7) 0.0411(15) Uani 0.509(3) 1 d P A 1
H10A H 1.0369 0.3034 1.0360 0.062 Uiso 0.509(3) 1 calc PR A 1
H10B H 0.8987 0.3604 0.9967 0.062 Uiso 0.509(3) 1 calc PR A 1
H10C H 1.0141 0.3162 0.9015 0.062 Uiso 0.509(3) 1 calc PR A 1
C11A C 0.5766(9) 0.1915(9) 0.7846(8) 0.0214(14) Uani 0.509(3) 1 d P A 1
C12A C 0.6531(8) 0.3225(6) 0.7716(5) 0.0287(12) Uani 0.509(3) 1 d P A 1
H12A H 0.7547 0.3391 0.7459 0.034 Uiso 0.509(3) 1 calc PR A 1
C13A C 0.5818(11) 0.4308(8) 0.7961(7) 0.0271(15) Uani 0.509(3) 1 d P A 1
H13A H 0.6374 0.5218 0.7901 0.033 Uiso 0.509(3) 1 calc PR A 1
C14A C 0.4290(8) 0.4053(7) 0.8292(6) 0.0272(12) Uani 0.509(3) 1 d P A 1
C15A C 0.3531(7) 0.2738(6) 0.8397(6) 0.0334(13) Uani 0.509(3) 1 d P A 1
H15A H 0.2500 0.2558 0.8630 0.040 Uiso 0.509(3) 1 calc PR A 1
C16A C 0.4243(7) 0.1662(6) 0.8168(6) 0.0266(12) Uani 0.509(3) 1 d P A 1
H16A H 0.3687 0.0756 0.8233 0.032 Uiso 0.509(3) 1 calc PR A 1
C17A C 0.3516(8) 0.5212(6) 0.8545(6) 0.0379(15) Uani 0.509(3) 1 d P A 1
H17A H 0.3330 0.5509 0.9416 0.057 Uiso 0.509(3) 1 calc PR A 1
H17B H 0.2460 0.4796 0.7921 0.057 Uiso 0.509(3) 1 calc PR A 1
H17C H 0.4254 0.6085 0.8463 0.057 Uiso 0.509(3) 1 calc PR A 1
C8B C 1.0280(9) 0.1483(9) 0.8714(8) 0.054(2) Uani 0.491(3) 1 d P A 2
H8D H 1.0373 0.0752 0.7921 0.081 Uiso 0.491(3) 1 calc PR A 2
H8E H 1.0967 0.1514 0.9454 0.081 Uiso 0.491(3) 1 calc PR A 2
H8F H 1.0653 0.2469 0.8701 0.081 Uiso 0.491(3) 1 calc PR A 2
C9B C 0.7423(10) -0.1178(7) 0.8568(7) 0.0507(19) Uani 0.491(3) 1 d P A 2
H9D H 0.6226 -0.1645 0.8431 0.076 Uiso 0.491(3) 1 calc PR A 2
H9E H 0.7974 -0.1227 0.9323 0.076 Uiso 0.491(3) 1 calc PR A 2
H9F H 0.7775 -0.1707 0.7811 0.076 Uiso 0.491(3) 1 calc PR A 2
C10B C 0.7909(9) 0.2007(7) 1.0412(6) 0.0403(16) Uani 0.491(3) 1 d P A 2
H10D H 0.8652 0.1921 1.1046 0.060 Uiso 0.491(3) 1 calc PR A 2
H10E H 0.6777 0.1651 1.0512 0.060 Uiso 0.491(3) 1 calc PR A 2
H10F H 0.8240 0.3052 1.0545 0.060 Uiso 0.491(3) 1 calc PR A 2
C11B C 0.6389(9) 0.2177(10) 0.7830(9) 0.0236(15) Uani 0.491(3) 1 d P A 2
C12B C 0.7552(9) 0.3456(6) 0.7850(6) 0.0307(13) Uani 0.491(3) 1 d P A 2
H12B H 0.8614 0.3472 0.7731 0.037 Uiso 0.491(3) 1 calc PR A 2
C13B C 0.7162(9) 0.4718(6) 0.8043(6) 0.0351(15) Uani 0.491(3) 1 d P A 2
H13B H 0.7966 0.5582 0.8053 0.042 Uiso 0.491(3) 1 calc PR A 2
C14B C 0.5613(13) 0.4729(9) 0.8222(8) 0.0334(18) Uani 0.491(3) 1 d P A 2
C15B C 0.4478(9) 0.3457(7) 0.8181(7) 0.0324(15) Uani 0.491(3) 1 d P A 2
H15B H 0.3410 0.3436 0.8284 0.039 Uiso 0.491(3) 1 calc PR A 2
C16B C 0.4843(9) 0.2194(7) 0.7992(6) 0.0278(12) Uani 0.491(3) 1 d P A 2
H16B H 0.4026 0.1332 0.7974 0.033 Uiso 0.491(3) 1 calc PR A 2
C17B C 0.5258(10) 0.6122(7) 0.8433(8) 0.051(2) Uani 0.491(3) 1 d P A 2
H17D H 0.4294 0.5884 0.7777 0.076 Uiso 0.491(3) 1 calc PR A 2
H17E H 0.6214 0.6871 0.8373 0.076 Uiso 0.491(3) 1 calc PR A 2
H17F H 0.5036 0.6516 0.9286 0.076 Uiso 0.491(3) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Bi1 N1 75.62(8) 2_656 .
N1 Bi1 N2 95.29(8) 2_656 .
N1 Bi1 N2 96.61(8) . .
N1 Bi1 Bi1 38.00(5) 2_656 2_656
N1 Bi1 Bi1 37.62(6) . 2_656
N2 Bi1 Bi1 97.54(6) . 2_656
N2 Si1 C8A 109.1(2) . .
N2 Si1 C10B 113.8(2) . .
C8A Si1 C10B 136.1(3) . .
N2 Si1 C9A 110.2(3) . .
C8A Si1 C9A 113.6(3) . .
C10B Si1 C9A 41.7(3) . .
N2 Si1 C10A 106.2(2) . .
C8A Si1 C10A 112.6(3) . .
C10B Si1 C10A 63.8(3) . .
C9A Si1 C10A 104.8(3) . .
N2 Si1 C8B 116.2(2) . .
C8A Si1 C8B 56.6(3) . .
C10B Si1 C8B 109.3(4) . .
C9A Si1 C8B 133.1(3) . .
C10A Si1 C8B 56.5(3) . .
N2 Si1 C9B 103.9(2) . .
C8A Si1 C9B 48.4(3) . .
C10B Si1 C9B 110.4(3) . .
C9A Si1 C9B 71.5(3) . .
C10A Si1 C9B 148.9(3) . .
C8B Si1 C9B 102.5(3) . .
C1 N1 Bi1 127.01(17) . 2_656
C1 N1 Bi1 127.25(18) . .
Bi1 N1 Bi1 104.38(8) 2_656 .
C11B N2 C11A 21.2(3) . .
C11B N2 Si1 116.3(4) . .
C11A N2 Si1 123.4(3) . .
C11B N2 Bi1 117.3(4) . .
C11A N2 Bi1 113.2(3) . .
Si1 N2 Bi1 123.32(11) . .
N1 C1 C2 122.2(2) . .
N1 C1 C6 121.1(3) . .
C2 C1 C6 116.7(2) . .
C3 C2 C1 121.7(3) . .
C3 C2 H2 119.1 . .
C1 C2 H2 119.1 . .
C2 C3 C4 121.5(3) . .
C2 C3 H3 119.2 . .
C4 C3 H3 119.2 . .
C5 C4 C3 117.2(3) . .
C5 C4 C7 121.9(3) . .
C3 C4 C7 120.9(3) . .
C4 C5 C6 122.2(3) . .
C4 C5 H5 118.9 . .
C6 C5 H5 118.9 . .
C5 C6 C1 120.5(3) . .
C5 C6 H6 119.8 . .
C1 C6 H6 119.8 . .
C4 C7 H7A 109.5 . .
C4 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C4 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
Si1 C8A H8A 109.5 . .
Si1 C8A H8B 109.5 . .
Si1 C8A H8C 109.5 . .
Si1 C9A H9A 109.5 . .
Si1 C9A H9B 109.5 . .
Si1 C9A H9C 109.5 . .
Si1 C10A H10A 109.5 . .
Si1 C10A H10B 109.5 . .
Si1 C10A H10C 109.5 . .
C12A C11A C16A 118.9(6) . .
C12A C11A N2 118.2(5) . .
C16A C11A N2 122.8(6) . .
C11A C12A C13A 120.6(6) . .
C11A C12A H12A 119.7 . .
C13A C12A H12A 119.7 . .
C14A C13A C12A 120.2(7) . .
C14A C13A H13A 119.9 . .
C12A C13A H13A 119.9 . .
C15A C14A C13A 118.5(6) . .
C15A C14A C17A 121.2(5) . .
C13A C14A C17A 120.3(6) . .
C14A C15A C16A 121.5(5) . .
C14A C15A H15A 119.2 . .
C16A C15A H15A 119.2 . .
C11A C16A C15A 120.1(6) . .
C11A C16A H16A 120.0 . .
C15A C16A H16A 120.0 . .
Si1 C8B H8D 109.5 . .
Si1 C8B H8E 109.5 . .
H8D C8B H8E 109.5 . .
Si1 C8B H8F 109.5 . .
H8D C8B H8F 109.5 . .
H8E C8B H8F 109.5 . .
Si1 C9B H9D 109.5 . .
Si1 C9B H9E 109.5 . .
H9D C9B H9E 109.5 . .
Si1 C9B H9F 109.5 . .
H9D C9B H9F 109.5 . .
H9E C9B H9F 109.5 . .
Si1 C10B H10D 109.5 . .
Si1 C10B H10E 109.5 . .
H10D C10B H10E 109.5 . .
Si1 C10B H10F 109.5 . .
H10D C10B H10F 109.5 . .
H10E C10B H10F 109.5 . .
C16B C11B C12B 118.0(8) . .
C16B C11B N2 116.0(6) . .
C12B C11B N2 125.9(6) . .
C11B C12B C13B 120.3(7) . .
C11B C12B H12B 119.8 . .
C13B C12B H12B 119.8 . .
C14B C13B C12B 121.1(6) . .
C14B C13B H13B 119.4 . .
C12B C13B H13B 119.4 . .
C15B C14B C13B 117.8(6) . .
C15B C14B C17B 123.1(8) . .
C13B C14B C17B 119.0(7) . .
C14B C15B C16B 121.9(7) . .
C14B C15B H15B 119.1 . .
C16B C15B H15B 119.1 . .
C15B C16B C11B 120.8(7) . .
C15B C16B H16B 119.6 . .
C11B C16B H16B 119.6 . .
C14B C17B H17D 109.5 . .
C14B C17B H17E 109.5 . .
H17D C17B H17E 109.5 . .
C14B C17B H17F 109.5 . .
H17D C17B H17F 109.5 . .
H17E C17B H17F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Bi1 N1 2.129(2) 2_656
Bi1 N1 2.147(2) .
Bi1 N2 2.165(2) .
Bi1 Bi1 3.37850(19) 2_656
Si1 N2 1.721(3) .
Si1 C8A 1.760(5) .
Si1 C10B 1.772(6) .
Si1 C9A 1.893(6) .
Si1 C10A 1.910(6) .
Si1 C8B 1.930(7) .
Si1 C9B 1.969(6) .
N1 C1 1.388(3) .
N1 Bi1 2.129(2) 2_656
N2 C11B 1.397(10) .
N2 C11A 1.482(8) .
C1 C2 1.392(4) .
C1 C6 1.402(4) .
C2 C3 1.388(4) .
C2 H2 0.9500 .
C3 C4 1.388(4) .
C3 H3 0.9500 .
C4 C5 1.373(5) .
C4 C7 1.516(4) .
C5 C6 1.401(4) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8A H8A 0.9800 .
C8A H8B 0.9800 .
C8A H8C 0.9800 .
C9A H9A 0.9800 .
C9A H9B 0.9800 .
C9A H9C 0.9800 .
C10A H10A 0.9800 .
C10A H10B 0.9800 .
C10A H10C 0.9800 .
C11A C12A 1.388(9) .
C11A C16A 1.392(8) .
C12A C13A 1.404(8) .
C12A H12A 0.9500 .
C13A C14A 1.401(10) .
C13A H13A 0.9500 .
C14A C15A 1.377(8) .
C14A C17A 1.510(7) .
C15A C16A 1.398(7) .
C15A H15A 0.9500 .
C16A H16A 0.9500 .
C17A H17A 0.9800 .
C17A H17B 0.9800 .
C17A H17C 0.9800 .
C8B H8D 0.9800 .
C8B H8E 0.9800 .
C8B H8F 0.9800 .
C9B H9D 0.9800 .
C9B H9E 0.9800 .
C9B H9F 0.9800 .
C10B H10D 0.9800 .
C10B H10E 0.9800 .
C10B H10F 0.9800 .
C11B C16B 1.390(9) .
C11B C12B 1.394(9) .
C12B C13B 1.400(8) .
C12B H12B 0.9500 .
C13B C14B 1.395(11) .
C13B H13B 0.9500 .
C14B C15B 1.368(12) .
C14B C17B 1.512(9) .
C15B C16B 1.390(9) .
C15B H15B 0.9500 .
C16B H16B 0.9500 .
C17B H17D 0.9800 .
C17B H17E 0.9800 .
C17B H17F 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Bi1 N1 C1 167.4(3) 2_656 .
N2 Bi1 N1 C1 73.6(2) . .
Bi1 Bi1 N1 C1 167.4(3) 2_656 .
N1 Bi1 N1 Bi1 0.0 2_656 2_656
N2 Bi1 N1 Bi1 -93.79(10) . 2_656
C8A Si1 N2 C11B -149.4(4) . .
C10B Si1 N2 C11B 40.1(4) . .
C9A Si1 N2 C11B 85.1(4) . .
C10A Si1 N2 C11B -27.9(4) . .
C8B Si1 N2 C11B -88.0(5) . .
C9B Si1 N2 C11B 160.3(4) . .
C8A Si1 N2 C11A -172.4(4) . .
C10B Si1 N2 C11A 17.1(5) . .
C9A Si1 N2 C11A 62.1(4) . .
C10A Si1 N2 C11A -50.9(4) . .
C8B Si1 N2 C11A -111.1(5) . .
C9B Si1 N2 C11A 137.2(4) . .
C8A Si1 N2 Bi1 10.1(3) . .
C10B Si1 N2 Bi1 -160.4(3) . .
C9A Si1 N2 Bi1 -115.4(2) . .
C10A Si1 N2 Bi1 131.6(2) . .
C8B Si1 N2 Bi1 71.5(3) . .
C9B Si1 N2 Bi1 -40.3(3) . .
N1 Bi1 N2 C11B -43.7(4) 2_656 .
N1 Bi1 N2 C11B 32.4(4) . .
Bi1 Bi1 N2 C11B -5.6(4) 2_656 .
N1 Bi1 N2 C11A -20.8(3) 2_656 .
N1 Bi1 N2 C11A 55.3(3) . .
Bi1 Bi1 N2 C11A 17.4(3) 2_656 .
N1 Bi1 N2 Si1 156.97(14) 2_656 .
N1 Bi1 N2 Si1 -126.94(14) . .
Bi1 Bi1 N2 Si1 -164.85(12) 2_656 .
Bi1 N1 C1 C2 155.7(2) 2_656 .
Bi1 N1 C1 C2 -8.8(3) . .
Bi1 N1 C1 C6 -24.3(3) 2_656 .
Bi1 N1 C1 C6 171.11(19) . .
N1 C1 C2 C3 -177.4(2) . .
C6 C1 C2 C3 2.6(4) . .
C1 C2 C3 C4 0.2(4) . .
C2 C3 C4 C5 -1.9(4) . .
C2 C3 C4 C7 177.4(3) . .
C3 C4 C5 C6 0.7(4) . .
C7 C4 C5 C6 -178.5(3) . .
C4 C5 C6 C1 2.1(5) . .
N1 C1 C6 C5 176.3(3) . .
C2 C1 C6 C5 -3.7(4) . .
C11B N2 C11A C12A 12.0(13) . .
Si1 N2 C11A C12A 88.3(7) . .
Bi1 N2 C11A C12A -94.0(6) . .
C11B N2 C11A C16A -168(2) . .
Si1 N2 C11A C16A -91.3(7) . .
Bi1 N2 C11A C16A 86.4(7) . .
C16A C11A C12A C13A 2.8(11) . .
N2 C11A C12A C13A -176.8(6) . .
C11A C12A C13A C14A -2.5(11) . .
C12A C13A C14A C15A 1.4(10) . .
C12A C13A C14A C17A -179.6(6) . .
C13A C14A C15A C16A -0.7(10) . .
C17A C14A C15A C16A -179.7(6) . .
C12A C11A C16A C15A -2.1(10) . .
N2 C11A C16A C15A 177.5(6) . .
C14A C15A C16A C11A 1.0(10) . .
C11A N2 C11B C16B 1.9(12) . .
Si1 N2 C11B C16B -113.4(7) . .
Bi1 N2 C11B C16B 85.8(7) . .
C11A N2 C11B C12B -177(2) . .
Si1 N2 C11B C12B 67.5(9) . .
Bi1 N2 C11B C12B -93.2(8) . .
C16B C11B C12B C13B 0.8(11) . .
N2 C11B C12B C13B 179.8(7) . .
C11B C12B C13B C14B 0.1(11) . .
C12B C13B C14B C15B -1.0(12) . .
C12B C13B C14B C17B 179.7(7) . .
C13B C14B C15B C16B 1.2(12) . .
C17B C14B C15B C16B -179.6(7) . .
C14B C15B C16B C11B -0.4(11) . .
C12B C11B C16B C15B -0.6(11) . .
N2 C11B C16B C15B -179.7(6) . .
