#------------------------------------------------------------------------------
#$Date: 2016-08-07 11:39:41 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185301 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/91/7039185.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7039185
loop_
_publ_author_name
'Wang, Jian-Feng'
'Liu, Shi-Yuan'
'Liu, Chun-Yu'
'Ren, Zhi-Gang'
'Lang, Jian-Ping'
_publ_section_title
;
 Silver(i) complexes with a P-N hybrid ligand and oxyanions: synthesis,
 structures, photocatalysis and photocurrent responses.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9294
_journal_page_last               9306
_journal_paper_doi               10.1039/c6dt01211f
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C90 H80 Ag4 N4 O10 P4'
_chemical_formula_sum            'C90 H80 Ag4 N4 O10 P4'
_chemical_formula_weight         1932.94
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_update_record
;
2016-01-31 deposited with the CCDC.
2016-05-03 downloaded from the CCDC.
;
_cell_angle_alpha                90.780(3)
_cell_angle_beta                 92.476(3)
_cell_angle_gamma                108.267(3)
_cell_formula_units_Z            1
_cell_length_a                   11.0884(4)
_cell_length_b                   13.1145(5)
_cell_length_c                   14.8180(5)
_cell_measurement_reflns_used    6979
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      28.7430
_cell_measurement_theta_min      3.1450
_cell_volume                     2043.48(13)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 10.4471
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.863
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_unetI/netI     0.0642
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.863
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            21287
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.863
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.290
_diffrn_reflns_theta_min         2.902
_exptl_absorpt_coefficient_mu    1.085
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.94509
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.571
_exptl_crystal_description       prism
_exptl_crystal_F_000             976
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.632
_refine_diff_density_min         -0.570
_refine_diff_density_rms         0.092
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     507
_refine_ls_number_reflns         10572
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0734
_refine_ls_R_factor_gt           0.0423
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0254P)²+0.1656P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0700
_refine_ls_wR_factor_ref         0.0833
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7487
_reflns_number_total             10572
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6dt01211f2.cif
_cod_data_source_block           4
_cod_depositor_comments
'Adding full bibliography for 7039182--7039188.cif.'
_cod_database_code               7039185
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.737
_shelx_estimated_absorpt_t_max   0.812
_shelxl_version_number           2013-2
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ag1 Ag 0.76997(2) 0.33890(2) 0.40155(2) 0.03531(8) Uani 1 1 d . .
Ag2 Ag 0.70114(2) 0.43550(2) 0.68545(2) 0.03430(8) Uani 1 1 d . .
P1 P 0.61912(6) 0.34710(6) 0.28749(5) 0.02449(17) Uani 1 1 d . .
P2 P 0.48721(6) 0.68819(6) 0.26550(5) 0.02474(17) Uani 1 1 d . .
O1 O 0.82554(18) 0.34831(17) 0.56845(16) 0.0381(5) Uani 1 1 d . .
O2 O 0.8402(2) 0.21403(18) 0.48289(17) 0.0437(6) Uani 1 1 d . .
O3 O 0.88440(18) 0.55597(17) 0.75513(15) 0.0376(5) Uani 1 1 d . .
O4 O 0.73138(19) 0.59263(18) 0.82876(16) 0.0413(6) Uani 1 1 d . .
O5 O 0.9791(2) 0.45599(19) 0.39395(18) 0.0553(7) Uani 1 1 d . .
H5O1 H 1.0329 0.4601 0.3539 0.063(13) Uiso 1 1 d R .
H5O2 H 1.0373 0.5019 0.4258 0.078(14) Uiso 1 1 d R .
N1 N 0.6143(2) 0.54980(18) 0.32732(18) 0.0283(6) Uani 1 1 d . .
N2 N 0.7209(2) 0.55356(19) 0.56669(17) 0.0277(6) Uani 1 1 d . .
C1 C 0.5283(2) 0.4396(2) 0.3151(2) 0.0274(7) Uani 1 1 d . .
H1A H 0.4648 0.4364 0.2661 0.033 Uiso 1 1 calc R U
H1B H 0.4834 0.4172 0.3706 0.033 Uiso 1 1 calc R U
C2 C 0.6132(3) 0.6220(2) 0.2550(2) 0.0278(7) Uani 1 1 d . .
H2A H 0.5991 0.5818 0.1971 0.033 Uiso 1 1 calc R U
H2B H 0.6965 0.6774 0.2548 0.033 Uiso 1 1 calc R U
C3 C 0.6783(2) 0.5860(2) 0.4103(2) 0.0251(6) Uani 1 1 d . .
C4 C 0.7637(2) 0.6907(2) 0.4223(2) 0.0309(7) Uani 1 1 d . .
H4 H 0.7817 0.7372 0.3734 0.037 Uiso 1 1 calc R U
C5 C 0.8205(3) 0.7241(3) 0.5067(2) 0.0369(8) Uani 1 1 d . .
H5 H 0.8760 0.7945 0.5160 0.044 Uiso 1 1 calc R U
C6 C 0.7965(3) 0.6552(2) 0.5769(2) 0.0347(7) Uani 1 1 d . .
H6 H 0.8345 0.6802 0.6343 0.042 Uiso 1 1 calc R U
C7 C 0.6638(2) 0.5209(2) 0.4851(2) 0.0272(7) Uani 1 1 d . .
H7 H 0.6106 0.4494 0.4779 0.033 Uiso 1 1 calc R U
C8 C 0.6820(3) 0.3980(2) 0.1799(2) 0.0272(7) Uani 1 1 d . .
C9 C 0.6038(3) 0.4047(2) 0.1062(2) 0.0343(7) Uani 1 1 d . .
H9 H 0.5150 0.3796 0.1101 0.041 Uiso 1 1 calc R U
C10 C 0.6563(3) 0.4484(3) 0.0265(3) 0.0455(9) Uani 1 1 d . .
H10 H 0.6032 0.4539 -0.0232 0.055 Uiso 1 1 calc R U
C11 C 0.7861(4) 0.4835(3) 0.0207(3) 0.0557(10) Uani 1 1 d . .
H11 H 0.8216 0.5122 -0.0335 0.067 Uiso 1 1 calc R U
C12 C 0.8642(4) 0.4772(3) 0.0928(3) 0.0583(11) Uani 1 1 d . .
H12 H 0.9529 0.5014 0.0881 0.070 Uiso 1 1 calc R U
C13 C 0.8126(3) 0.4354(3) 0.1724(3) 0.0427(9) Uani 1 1 d . .
H13 H 0.8666 0.4322 0.2222 0.051 Uiso 1 1 calc R U
C14 C 0.4969(2) 0.2193(2) 0.2615(2) 0.0264(7) Uani 1 1 d . .
C15 C 0.5305(3) 0.1264(2) 0.2708(2) 0.0348(8) Uani 1 1 d . .
H15 H 0.6142 0.1316 0.2899 0.042 Uiso 1 1 calc R U
C16 C 0.4428(3) 0.0263(3) 0.2526(3) 0.0457(9) Uani 1 1 d . .
H16 H 0.4673 -0.0358 0.2589 0.055 Uiso 1 1 calc R U
C17 C 0.3196(3) 0.0175(3) 0.2252(3) 0.0427(9) Uani 1 1 d . .
H17 H 0.2597 -0.0506 0.2131 0.051 Uiso 1 1 calc R U
C18 C 0.2848(3) 0.1081(3) 0.2156(3) 0.0446(9) Uani 1 1 d . .
H18 H 0.2006 0.1021 0.1971 0.054 Uiso 1 1 calc R U
C19 C 0.3726(3) 0.2089(2) 0.2329(2) 0.0365(8) Uani 1 1 d . .
H19 H 0.3477 0.2706 0.2252 0.044 Uiso 1 1 calc R U
C20 C 0.5554(2) 0.8001(2) 0.3457(2) 0.0250(6) Uani 1 1 d . .
C21 C 0.4986(3) 0.7969(3) 0.4275(2) 0.0373(8) Uani 1 1 d . .
H21 H 0.4260 0.7391 0.4389 0.045 Uiso 1 1 calc R U
C22 C 0.5472(3) 0.8775(3) 0.4926(3) 0.0518(10) Uani 1 1 d . .
H22 H 0.5086 0.8742 0.5482 0.062 Uiso 1 1 calc R U
C23 C 0.6520(3) 0.9624(3) 0.4755(3) 0.0498(10) Uani 1 1 d . .
H23 H 0.6848 1.0178 0.5194 0.060 Uiso 1 1 calc R U
C24 C 0.7097(3) 0.9673(2) 0.3949(3) 0.0386(8) Uani 1 1 d . .
H24 H 0.7821 1.0256 0.3842 0.046 Uiso 1 1 calc R U
C25 C 0.6620(3) 0.8872(2) 0.3294(2) 0.0309(7) Uani 1 1 d . .
H25 H 0.7012 0.8913 0.2740 0.037 Uiso 1 1 calc R U
C26 C 0.4854(3) 0.7510(2) 0.1569(2) 0.0338(7) Uani 1 1 d . .
C27 C 0.5899(4) 0.7838(3) 0.1025(3) 0.0525(10) Uani 1 1 d . .
H27 H 0.6664 0.7716 0.1205 0.063 Uiso 1 1 calc R U
C28 C 0.5811(5) 0.8335(3) 0.0231(3) 0.0717(14) Uani 1 1 d . .
H28 H 0.6524 0.8558 -0.0125 0.086 Uiso 1 1 calc R U
C29 C 0.4730(7) 0.8514(3) -0.0053(3) 0.0853(17) Uani 1 1 d . .
H29 H 0.4690 0.8854 -0.0603 0.102 Uiso 1 1 calc R U
C30 C 0.3682(6) 0.8198(4) 0.0464(3) 0.0837(16) Uani 1 1 d . .
H30 H 0.2927 0.8330 0.0270 0.100 Uiso 1 1 calc R U
C31 C 0.3738(4) 0.7686(3) 0.1270(3) 0.0532(10) Uani 1 1 d . .
H31 H 0.3015 0.7457 0.1615 0.064 Uiso 1 1 calc R U
C32 C 0.8557(3) 0.2635(2) 0.5577(2) 0.0331(8) Uani 1 1 d . .
C33 C 0.9144(3) 0.2212(3) 0.6362(2) 0.0347(8) Uani 1 1 d . .
C34 C 0.9471(3) 0.2788(3) 0.7172(3) 0.0447(9) Uani 1 1 d . .
H34 H 0.9300 0.3441 0.7245 0.054 Uiso 1 1 calc R U
C35 C 1.0052(3) 0.2402(3) 0.7877(3) 0.0563(10) Uani 1 1 d . .
H35 H 1.0287 0.2798 0.8425 0.068 Uiso 1 1 calc R U
C36 C 1.0281(3) 0.1440(4) 0.7771(3) 0.0575(11) Uani 1 1 d . .
H36 H 1.0671 0.1179 0.8251 0.069 Uiso 1 1 calc R U
C37 C 0.9952(3) 0.0855(3) 0.6977(3) 0.0494(10) Uani 1 1 d . .
H37 H 1.0110 0.0195 0.6913 0.059 Uiso 1 1 calc R U
C38 C 0.9384(3) 0.1241(3) 0.6269(3) 0.0392(8) Uani 1 1 d . .
H38 H 0.9159 0.0842 0.5722 0.047 Uiso 1 1 calc R U
C39 C 0.8431(3) 0.6142(2) 0.8068(2) 0.0312(7) Uani 1 1 d . .
C40 C 0.9391(3) 0.7182(3) 0.8429(2) 0.0349(8) Uani 1 1 d . .
C41 C 1.0460(3) 0.7691(3) 0.7965(3) 0.0498(10) Uani 1 1 d . .
H41 H 1.0611 0.7384 0.7422 0.060 Uiso 1 1 calc R U
C42 C 1.1316(3) 0.8660(3) 0.8301(4) 0.0655(13) Uani 1 1 d . .
H42 H 1.2035 0.9008 0.7978 0.079 Uiso 1 1 calc R U
C43 C 1.1115(4) 0.9107(3) 0.9096(4) 0.0694(14) Uani 1 1 d . .
H43 H 1.1698 0.9754 0.9326 0.083 Uiso 1 1 calc R U
C44 C 1.0056(5) 0.8603(3) 0.9553(3) 0.0733(14) Uani 1 1 d . .
H44 H 0.9915 0.8908 1.0100 0.088 Uiso 1 1 calc R U
C45 C 0.9187(4) 0.7649(3) 0.9222(3) 0.0536(10) Uani 1 1 d . .
H45 H 0.8457 0.7319 0.9540 0.064 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
O2 Ag1 P1 141.03(6) .
O2 Ag1 O5 91.79(9) .
P1 Ag1 O5 117.98(7) .
O2 Ag1 O1 53.86(8) .
P1 Ag1 O1 146.42(5) .
O5 Ag1 O1 83.62(8) .
N2 Ag2 O3 88.52(8) .
N2 Ag2 P2 127.44(6) 2_666
O3 Ag2 P2 135.87(6) 2_666
C14 P1 C8 106.07(13) .
C14 P1 C1 104.01(12) .
C8 P1 C1 101.21(14) .
C14 P1 Ag1 113.95(10) .
C8 P1 Ag1 116.08(10) .
C1 P1 Ag1 114.04(10) .
C26 P2 C20 104.56(13) .
C26 P2 C2 103.21(15) .
C20 P2 C2 105.14(13) .
C26 P2 Ag2 119.63(10) 2_666
C20 P2 Ag2 112.66(10) 2_666
C2 P2 Ag2 110.33(9) 2_666
C32 O1 Ag1 87.9(2) .
C32 O2 Ag1 95.92(19) .
C39 O3 Ag2 104.30(17) .
Ag1 O5 H5O1 129.8 .
Ag1 O5 H5O2 141.4 .
H5O1 O5 H5O2 88.2 .
C3 N1 C2 121.9(2) .
C3 N1 C1 120.7(3) .
C2 N1 C1 116.6(2) .
C6 N2 C7 117.8(3) .
C6 N2 Ag2 120.4(2) .
C7 N2 Ag2 121.70(19) .
N1 C1 P1 110.24(18) .
N1 C1 H1A 109.6 .
P1 C1 H1A 109.6 .
N1 C1 H1B 109.6 .
P1 C1 H1B 109.6 .
H1A C1 H1B 108.1 .
N1 C2 P2 112.55(19) .
N1 C2 H2A 109.1 .
P2 C2 H2A 109.1 .
N1 C2 H2B 109.1 .
P2 C2 H2B 109.1 .
H2A C2 H2B 107.8 .
N1 C3 C7 122.4(3) .
N1 C3 C4 121.3(3) .
C7 C3 C4 116.3(3) .
C5 C4 C3 119.0(3) .
C5 C4 H4 120.5 .
C3 C4 H4 120.5 .
C6 C5 C4 120.2(3) .
C6 C5 H5 119.9 .
C4 C5 H5 119.9 .
N2 C6 C5 122.3(3) .
N2 C6 H6 118.9 .
C5 C6 H6 118.9 .
N2 C7 C3 124.3(3) .
N2 C7 H7 117.9 .
C3 C7 H7 117.9 .
C9 C8 C13 118.8(3) .
C9 C8 P1 122.2(2) .
C13 C8 P1 118.9(2) .
C8 C9 C10 120.2(3) .
C8 C9 H9 119.9 .
C10 C9 H9 119.9 .
C11 C10 C9 119.6(3) .
C11 C10 H10 120.2 .
C9 C10 H10 120.2 .
C12 C11 C10 120.8(4) .
C12 C11 H11 119.6 .
C10 C11 H11 119.6 .
C11 C12 C13 119.8(4) .
C11 C12 H12 120.1 .
C13 C12 H12 120.1 .
C12 C13 C8 120.8(3) .
C12 C13 H13 119.6 .
C8 C13 H13 119.6 .
C15 C14 C19 118.1(3) .
C15 C14 P1 117.7(2) .
C19 C14 P1 124.2(2) .
C16 C15 C14 121.1(3) .
C16 C15 H15 119.4 .
C14 C15 H15 119.4 .
C17 C16 C15 120.0(3) .
C17 C16 H16 120.0 .
C15 C16 H16 120.0 .
C18 C17 C16 119.7(3) .
C18 C17 H17 120.2 .
C16 C17 H17 120.2 .
C17 C18 C19 120.6(3) .
C17 C18 H18 119.7 .
C19 C18 H18 119.7 .
C18 C19 C14 120.5(3) .
C18 C19 H19 119.8 .
C14 C19 H19 119.8 .
C21 C20 C25 118.8(3) .
C21 C20 P2 117.7(2) .
C25 C20 P2 123.5(2) .
C22 C21 C20 120.9(3) .
C22 C21 H21 119.5 .
C20 C21 H21 119.5 .
C23 C22 C21 119.5(3) .
C23 C22 H22 120.3 .
C21 C22 H22 120.3 .
C22 C23 C24 120.6(3) .
C22 C23 H23 119.7 .
C24 C23 H23 119.7 .
C23 C24 C25 120.4(3) .
C23 C24 H24 119.8 .
C25 C24 H24 119.8 .
C24 C25 C20 119.8(3) .
C24 C25 H25 120.1 .
C20 C25 H25 120.1 .
C31 C26 C27 118.1(3) .
C31 C26 P2 117.7(3) .
C27 C26 P2 124.2(3) .
C28 C27 C26 120.2(4) .
C28 C27 H27 119.9 .
C26 C27 H27 119.9 .
C29 C28 C27 121.6(5) .
C29 C28 H28 119.2 .
C27 C28 H28 119.2 .
C28 C29 C30 119.8(4) .
C28 C29 H29 120.1 .
C30 C29 H29 120.1 .
C29 C30 C31 120.1(5) .
C29 C30 H30 120.0 .
C31 C30 H30 120.0 .
C26 C31 C30 120.3(4) .
C26 C31 H31 119.8 .
C30 C31 H31 119.8 .
O2 C32 O1 122.2(3) .
O2 C32 C33 118.4(3) .
O1 C32 C33 119.5(3) .
C34 C33 C38 119.3(3) .
C34 C33 C32 120.9(3) .
C38 C33 C32 119.8(3) .
C33 C34 C35 120.0(4) .
C33 C34 H34 120.0 .
C35 C34 H34 120.0 .
C36 C35 C34 119.7(4) .
C36 C35 H35 120.1 .
C34 C35 H35 120.1 .
C37 C36 C35 121.0(4) .
C37 C36 H36 119.5 .
C35 C36 H36 119.5 .
C36 C37 C38 119.6(4) .
C36 C37 H37 120.2 .
C38 C37 H37 120.2 .
C37 C38 C33 120.4(4) .
C37 C38 H38 119.8 .
C33 C38 H38 119.8 .
O4 C39 O3 125.0(3) .
O4 C39 C40 118.5(3) .
O3 C39 C40 116.5(3) .
C45 C40 C41 118.9(3) .
C45 C40 C39 119.9(3) .
C41 C40 C39 121.2(3) .
C40 C41 C42 120.2(4) .
C40 C41 H41 119.9 .
C42 C41 H41 119.9 .
C43 C42 C41 120.4(4) .
C43 C42 H42 119.8 .
C41 C42 H42 119.8 .
C44 C43 C42 119.3(4) .
C44 C43 H43 120.4 .
C42 C43 H43 120.4 .
C43 C44 C45 121.0(4) .
C43 C44 H44 119.5 .
C45 C44 H44 119.5 .
C40 C45 C44 120.2(4) .
C40 C45 H45 119.9 .
C44 C45 H45 119.9 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O2 2.348(2) .
Ag1 P1 2.3535(8) .
Ag1 O5 2.355(2) .
Ag1 O1 2.515(2) .
Ag2 N2 2.332(3) .
Ag2 O3 2.335(2) .
Ag2 P2 2.3582(7) 2_666
P1 C14 1.819(3) .
P1 C8 1.819(3) .
P1 C1 1.855(3) .
P2 C26 1.820(3) .
P2 C20 1.821(3) .
P2 C2 1.873(3) .
P2 Ag2 2.3582(7) 2_666
O1 C32 1.267(4) .
O2 C32 1.254(4) .
O3 C39 1.270(4) .
O4 C39 1.240(3) .
O5 H5O1 0.8500 .
O5 H5O2 0.8500 .
N1 C3 1.392(4) .
N1 C2 1.442(4) .
N1 C1 1.465(3) .
N2 C6 1.337(4) .
N2 C7 1.340(4) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C3 C7 1.392(4) .
C3 C4 1.407(4) .
C4 C5 1.377(4) .
C4 H4 0.9400 .
C5 C6 1.366(4) .
C5 H5 0.9400 .
C6 H6 0.9400 .
C7 H7 0.9400 .
C8 C9 1.385(4) .
C8 C13 1.386(4) .
C9 C10 1.389(5) .
C9 H9 0.9400 .
C10 C11 1.374(5) .
C10 H10 0.9400 .
C11 C12 1.366(5) .
C11 H11 0.9400 .
C12 C13 1.378(5) .
C12 H12 0.9400 .
C13 H13 0.9400 .
C14 C15 1.387(4) .
C14 C19 1.390(4) .
C15 C16 1.381(4) .
C15 H15 0.9400 .
C16 C17 1.377(4) .
C16 H16 0.9400 .
C17 C18 1.368(5) .
C17 H17 0.9400 .
C18 C19 1.386(4) .
C18 H18 0.9400 .
C19 H19 0.9400 .
C20 C21 1.385(4) .
C20 C25 1.395(4) .
C21 C22 1.382(4) .
C21 H21 0.9400 .
C22 C23 1.371(5) .
C22 H22 0.9400 .
C23 C24 1.372(5) .
C23 H23 0.9400 .
C24 C25 1.380(4) .
C24 H24 0.9400 .
C25 H25 0.9400 .
C26 C31 1.383(4) .
C26 C27 1.399(5) .
C27 C28 1.368(5) .
C27 H27 0.9400 .
C28 C29 1.343(6) .
C28 H28 0.9400 .
C29 C30 1.375(7) .
C29 H29 0.9400 .
C30 C31 1.388(6) .
C30 H30 0.9400 .
C31 H31 0.9400 .
C32 C33 1.505(4) .
C33 C34 1.381(5) .
C33 C38 1.387(4) .
C34 C35 1.386(5) .
C34 H34 0.9400 .
C35 C36 1.372(5) .
C35 H35 0.9400 .
C36 C37 1.366(5) .
C36 H36 0.9400 .
C37 C38 1.382(5) .
C37 H37 0.9400 .
C38 H38 0.9400 .
C39 C40 1.517(4) .
C40 C45 1.377(5) .
C40 C41 1.382(5) .
C41 C42 1.396(5) .
C41 H41 0.9400 .
C42 C43 1.366(6) .
C42 H42 0.9400 .
C43 C44 1.366(6) .
C43 H43 0.9400 .
C44 C45 1.386(5) .
C44 H44 0.9400 .
C45 H45 0.9400 .
