#------------------------------------------------------------------------------
#$Date: 2016-08-07 11:39:41 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185301 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/91/7039188.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7039188
loop_
_publ_author_name
'Wang, Jian-Feng'
'Liu, Shi-Yuan'
'Liu, Chun-Yu'
'Ren, Zhi-Gang'
'Lang, Jian-Ping'
_publ_section_title
;
 Silver(i) complexes with a P-N hybrid ligand and oxyanions: synthesis,
 structures, photocatalysis and photocurrent responses.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9294
_journal_page_last               9306
_journal_paper_doi               10.1039/c6dt01211f
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C90 H76 Ag4 N4 O12 P4'
_chemical_formula_sum            'C90 H76 Ag4 N4 O12 P4'
_chemical_formula_weight         1960.90
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_update_record
;
2016-01-31 deposited with the CCDC.
2016-05-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 92.366(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.1121(3)
_cell_length_b                   14.2728(5)
_cell_length_c                   28.6382(11)
_cell_measurement_reflns_used    8242
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      29.5180
_cell_measurement_theta_min      3.3900
_cell_volume                     4129.8(2)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 10.4471
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.876
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0361
_diffrn_reflns_av_unetI/netI     0.0467
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.876
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            32135
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.876
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.353
_diffrn_reflns_theta_min         2.809
_exptl_absorpt_coefficient_mu    1.077
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.79292
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.577
_exptl_crystal_description       block
_exptl_crystal_F_000             1976
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.425
_refine_diff_density_min         -0.505
_refine_diff_density_rms         0.083
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         10909
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.0947
_refine_ls_R_factor_gt           0.0529
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0581P)²+4.0441P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1214
_refine_ls_wR_factor_ref         0.1448
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6841
_reflns_number_total             10909
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6dt01211f2.cif
_cod_data_source_block           7
_cod_depositor_comments
'Adding full bibliography for 7039182--7039188.cif.'
_cod_database_code               7039188
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.738
_shelx_estimated_absorpt_t_max   0.813
_shelxl_version_number           2013-2
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ag1 Ag 0.91979(3) 0.60539(3) 0.54879(2) 0.06140(13) Uani 1 1 d . .
Ag2 Ag 0.74016(3) 0.47388(3) 0.41065(2) 0.05412(12) Uani 1 1 d . .
P1 P 0.74526(9) 0.66618(7) 0.59325(4) 0.0415(2) Uani 1 1 d . .
P2 P 0.38442(10) 0.43719(8) 0.64444(4) 0.0475(3) Uani 1 1 d . .
N1 N 0.6051(3) 0.5017(3) 0.59846(13) 0.0490(8) Uani 1 1 d . .
N2 N 0.6947(3) 0.4152(2) 0.48321(13) 0.0494(8) Uani 1 1 d . .
O1 O 0.9865(3) 0.6703(2) 0.48025(12) 0.0638(8) Uani 1 1 d . .
O2 O 0.9565(3) 0.5327(2) 0.44661(13) 0.0642(9) Uani 1 1 d . .
O3 O 1.0606(4) 0.8122(3) 0.4355(2) 0.1028(15) Uani 1 1 d . .
H3O H 1.0295 0.7825 0.4574 0.154 Uiso 1 1 calc R U
O4 O 0.8427(4) 0.3299(3) 0.39949(15) 0.0836(11) Uani 1 1 d . .
O5 O 0.6806(4) 0.3168(3) 0.34388(17) 0.0992(13) Uani 1 1 d . .
O6 O 0.6901(5) 0.1860(4) 0.2863(2) 0.1203(17) Uani 1 1 d . .
H6O H 0.6763 0.2398 0.2958 0.180 Uiso 1 1 calc R U
C1 C 0.5876(4) 0.6003(3) 0.58856(16) 0.0463(9) Uani 1 1 d . .
H1A H 0.5258 0.6269 0.6105 0.056 Uiso 1 1 calc R U
H1B H 0.5483 0.6077 0.5569 0.056 Uiso 1 1 calc R U
C2 C 0.5637(4) 0.4691(3) 0.64347(16) 0.0545(11) Uani 1 1 d . .
H2A H 0.5821 0.5183 0.6667 0.065 Uiso 1 1 calc R U
H2B H 0.6168 0.4142 0.6527 0.065 Uiso 1 1 calc R U
C3 C 0.6319(3) 0.4400(3) 0.56294(15) 0.0455(10) Uani 1 1 d . .
C4 C 0.6306(4) 0.3430(3) 0.56890(19) 0.0577(12) Uani 1 1 d . .
H4 H 0.6108 0.3171 0.5980 0.069 Uiso 1 1 calc R U
C5 C 0.6579(4) 0.2861(3) 0.5326(2) 0.0635(13) Uani 1 1 d . .
H5 H 0.6544 0.2208 0.5366 0.076 Uiso 1 1 calc R U
C6 C 0.6905(4) 0.3220(3) 0.49020(19) 0.0587(12) Uani 1 1 d . .
H6 H 0.7101 0.2811 0.4657 0.070 Uiso 1 1 calc R U
C7 C 0.6648(4) 0.4717(3) 0.51825(15) 0.0435(9) Uani 1 1 d . .
H7 H 0.6656 0.5367 0.5129 0.052 Uiso 1 1 calc R U
C8 C 0.6897(5) 0.7825(3) 0.57590(17) 0.0585(12) Uani 1 1 d . .
C9 C 0.5654(8) 0.8173(5) 0.5858(3) 0.109(2) Uani 1 1 d . .
H9 H 0.5057 0.7796 0.6017 0.131 Uiso 1 1 calc R U
C10 C 0.5286(12) 0.9083(7) 0.5721(4) 0.143(4) Uani 1 1 d . .
H10 H 0.4438 0.9309 0.5784 0.172 Uiso 1 1 calc R U
C11 C 0.6126(13) 0.9626(6) 0.5504(4) 0.142(4) Uani 1 1 d . .
H11 H 0.5874 1.0241 0.5424 0.171 Uiso 1 1 calc R U
C12 C 0.7309(14) 0.9324(9) 0.5396(4) 0.175(4) Uani 1 1 d . U
H12 H 0.7891 0.9722 0.5243 0.210 Uiso 1 1 calc R U
C13 C 0.7704(10) 0.8382(6) 0.5516(3) 0.142(3) Uani 1 1 d . .
H13 H 0.8526 0.8153 0.5424 0.171 Uiso 1 1 calc R U
C14 C 0.7801(4) 0.6748(3) 0.65566(15) 0.0509(10) Uani 1 1 d . .
C15 C 0.6839(6) 0.6954(5) 0.6872(2) 0.0905(19) Uani 1 1 d . .
H15 H 0.5951 0.7030 0.6769 0.109 Uiso 1 1 calc R U
C16 C 0.7204(10) 0.7047(6) 0.7346(2) 0.116(3) Uani 1 1 d . .
H16 H 0.6555 0.7185 0.7561 0.139 Uiso 1 1 calc R U
C17 C 0.8486(10) 0.6941(5) 0.7501(2) 0.106(2) Uani 1 1 d . .
H17 H 0.8718 0.7000 0.7821 0.127 Uiso 1 1 calc R U
C18 C 0.9405(8) 0.6754(6) 0.7199(2) 0.106(2) Uani 1 1 d . .
H18 H 1.0292 0.6695 0.7307 0.127 Uiso 1 1 calc R U
C19 C 0.9088(5) 0.6643(4) 0.67252(19) 0.0734(15) Uani 1 1 d . .
H19 H 0.9756 0.6495 0.6519 0.088 Uiso 1 1 calc R U
C20 C 0.3819(4) 0.3107(3) 0.6367(2) 0.0619(13) Uani 1 1 d . .
C21 C 0.3009(6) 0.2744(5) 0.6012(3) 0.110(3) Uani 1 1 d . .
H21 H 0.2478 0.3147 0.5825 0.132 Uiso 1 1 calc R U
C22 C 0.2976(9) 0.1781(7) 0.5931(5) 0.179(6) Uani 1 1 d . .
H22 H 0.2433 0.1529 0.5688 0.215 Uiso 1 1 calc R U
C23 C 0.3758(12) 0.1208(6) 0.6216(6) 0.173(6) Uani 1 1 d . .
H23 H 0.3714 0.0555 0.6175 0.207 Uiso 1 1 calc R U
C24 C 0.4576(11) 0.1564(6) 0.6548(4) 0.138(4) Uani 1 1 d . .
H24 H 0.5146 0.1167 0.6725 0.166 Uiso 1 1 calc R U
C25 C 0.4582(7) 0.2511(4) 0.6630(2) 0.0901(19) Uani 1 1 d . .
H25 H 0.5129 0.2753 0.6875 0.108 Uiso 1 1 calc R U
C26 C 0.3475(4) 0.4506(3) 0.70562(16) 0.0558(11) Uani 1 1 d . .
C27 C 0.2222(6) 0.4681(5) 0.7176(2) 0.096(2) Uani 1 1 d . .
H27 H 0.1570 0.4793 0.6939 0.115 Uiso 1 1 calc R U
C28 C 0.1870(7) 0.4700(7) 0.7638(3) 0.118(3) Uani 1 1 d . .
H28 H 0.0977 0.4786 0.7707 0.142 Uiso 1 1 calc R U
C29 C 0.2750(8) 0.4601(6) 0.7978(2) 0.106(2) Uani 1 1 d . .
H29 H 0.2500 0.4671 0.8288 0.128 Uiso 1 1 calc R U
C30 C 0.4059(8) 0.4392(5) 0.7887(2) 0.095(2) Uani 1 1 d . .
H30 H 0.4683 0.4283 0.8133 0.114 Uiso 1 1 calc R U
C31 C 0.4422(6) 0.4347(4) 0.7428(2) 0.0759(15) Uani 1 1 d . .
H31 H 0.5303 0.4210 0.7362 0.091 Uiso 1 1 calc R U
C32 C 0.9931(4) 0.6155(4) 0.44556(16) 0.0508(11) Uani 1 1 d . .
C33 C 1.0457(4) 0.6584(4) 0.40220(17) 0.0615(13) Uani 1 1 d . .
C34 C 1.0778(5) 0.7545(5) 0.3996(2) 0.0791(18) Uani 1 1 d . .
C35 C 1.1292(6) 0.7889(7) 0.3586(4) 0.130(4) Uani 1 1 d . .
H35 H 1.1506 0.8528 0.3563 0.156 Uiso 1 1 calc R U
C36 C 1.1491(8) 0.7303(12) 0.3215(4) 0.167(7) Uani 1 1 d . .
H36 H 1.1860 0.7543 0.2944 0.200 Uiso 1 1 calc R U
C37 C 1.1164(7) 0.6386(10) 0.3234(3) 0.139(5) Uani 1 1 d . .
H37 H 1.1282 0.5999 0.2974 0.167 Uiso 1 1 calc R U
C38 C 1.0660(5) 0.6018(6) 0.36315(19) 0.090(2) Uani 1 1 d . .
H38 H 1.0448 0.5377 0.3642 0.107 Uiso 1 1 calc R U
C39 C 0.7797(6) 0.2861(4) 0.3682(2) 0.0772(16) Uani 1 1 d . .
C40 C 0.8188(6) 0.1861(4) 0.3582(3) 0.0849(18) Uani 1 1 d . .
C41 C 0.7723(7) 0.1404(5) 0.3174(3) 0.094(2) Uani 1 1 d . .
C42 C 0.8085(8) 0.0471(5) 0.3079(3) 0.109(2) Uani 1 1 d . .
H42 H 0.7756 0.0160 0.2809 0.131 Uiso 1 1 calc R U
C43 C 0.8903(10) 0.0047(6) 0.3384(5) 0.133(3) Uani 1 1 d . .
H43 H 0.9180 -0.0565 0.3317 0.160 Uiso 1 1 calc R U
C44 C 0.9370(10) 0.0453(7) 0.3794(5) 0.159(4) Uani 1 1 d . .
H44 H 0.9932 0.0120 0.4004 0.191 Uiso 1 1 calc R U
C45 C 0.8989(8) 0.1379(6) 0.3892(4) 0.123(3) Uani 1 1 d . .
H45 H 0.9288 0.1665 0.4172 0.148 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Ag1 O2 102.29(12) . 3_766
O1 Ag1 P1 124.07(9) . .
O2 Ag1 P1 133.18(9) 3_766 .
N2 Ag2 O4 84.81(14) . .
N2 Ag2 P2 132.86(9) . 3_666
O4 Ag2 P2 127.84(12) . 3_666
N2 Ag2 O2 87.42(12) . .
O4 Ag2 O2 88.08(13) . .
P2 Ag2 O2 121.73(8) 3_666 .
C14 P1 C8 104.7(2) . .
C14 P1 C1 103.8(2) . .
C8 P1 C1 100.9(2) . .
C14 P1 Ag1 115.69(15) . .
C8 P1 Ag1 114.48(17) . .
C1 P1 Ag1 115.55(14) . .
C26 P2 C20 102.7(2) . .
C26 P2 C2 103.1(2) . .
C20 P2 C2 104.4(2) . .
C26 P2 Ag2 117.70(16) . 3_666
C20 P2 Ag2 116.74(19) . 3_666
C2 P2 Ag2 110.56(14) . 3_666
C3 N1 C1 120.2(3) . .
C3 N1 C2 121.6(4) . .
C1 N1 C2 116.7(4) . .
C7 N2 C6 118.5(4) . .
C7 N2 Ag2 121.3(3) . .
C6 N2 Ag2 120.1(3) . .
C32 O1 Ag1 116.6(3) . .
C32 O2 Ag1 130.3(3) . 3_766
C32 O2 Ag2 124.2(3) . .
Ag1 O2 Ag2 101.27(12) 3_766 .
C34 O3 H3O 109.5 . .
C39 O4 Ag2 108.9(4) . .
C41 O6 H6O 109.5 . .
N1 C1 P1 112.5(3) . .
N1 C1 H1A 109.1 . .
P1 C1 H1A 109.1 . .
N1 C1 H1B 109.1 . .
P1 C1 H1B 109.1 . .
H1A C1 H1B 107.8 . .
N1 C2 P2 114.0(3) . .
N1 C2 H2A 108.7 . .
P2 C2 H2A 108.7 . .
N1 C2 H2B 108.7 . .
P2 C2 H2B 108.7 . .
H2A C2 H2B 107.6 . .
N1 C3 C4 122.6(4) . .
N1 C3 C7 121.7(4) . .
C4 C3 C7 115.7(4) . .
C5 C4 C3 119.8(5) . .
C5 C4 H4 120.1 . .
C3 C4 H4 120.1 . .
C4 C5 C6 121.2(4) . .
C4 C5 H5 119.4 . .
C6 C5 H5 119.4 . .
N2 C6 C5 120.8(5) . .
N2 C6 H6 119.6 . .
C5 C6 H6 119.6 . .
N2 C7 C3 124.0(4) . .
N2 C7 H7 118.0 . .
C3 C7 H7 118.0 . .
C13 C8 C9 117.6(6) . .
C13 C8 P1 119.5(5) . .
C9 C8 P1 122.9(5) . .
C8 C9 C10 120.4(8) . .
C8 C9 H9 119.8 . .
C10 C9 H9 119.8 . .
C11 C10 C9 120.3(10) . .
C11 C10 H10 119.8 . .
C9 C10 H10 119.8 . .
C12 C11 C10 121.6(9) . .
C12 C11 H11 119.2 . .
C10 C11 H11 119.2 . .
C11 C12 C13 119.7(10) . .
C11 C12 H12 120.2 . .
C13 C12 H12 120.2 . .
C8 C13 C12 120.2(9) . .
C8 C13 H13 119.9 . .
C12 C13 H13 119.9 . .
C19 C14 C15 118.2(5) . .
C19 C14 P1 118.8(4) . .
C15 C14 P1 123.0(4) . .
C14 C15 C16 119.2(6) . .
C14 C15 H15 120.4 . .
C16 C15 H15 120.4 . .
C17 C16 C15 121.0(7) . .
C17 C16 H16 119.5 . .
C15 C16 H16 119.5 . .
C18 C17 C16 119.7(6) . .
C18 C17 H17 120.1 . .
C16 C17 H17 120.1 . .
C17 C18 C19 121.4(7) . .
C17 C18 H18 119.3 . .
C19 C18 H18 119.3 . .
C14 C19 C18 120.4(6) . .
C14 C19 H19 119.8 . .
C18 C19 H19 119.8 . .
C25 C20 C21 118.7(6) . .
C25 C20 P2 123.4(5) . .
C21 C20 P2 117.9(5) . .
C20 C21 C22 120.3(9) . .
C20 C21 H21 119.9 . .
C22 C21 H21 119.9 . .
C23 C22 C21 118.4(10) . .
C23 C22 H22 120.8 . .
C21 C22 H22 120.8 . .
C24 C23 C22 121.2(9) . .
C24 C23 H23 119.4 . .
C22 C23 H23 119.4 . .
C23 C24 C25 119.7(10) . .
C23 C24 H24 120.2 . .
C25 C24 H24 120.2 . .
C20 C25 C24 121.6(9) . .
C20 C25 H25 119.2 . .
C24 C25 H25 119.2 . .
C27 C26 C31 116.7(5) . .
C27 C26 P2 119.8(4) . .
C31 C26 P2 123.2(4) . .
C26 C27 C28 121.9(6) . .
C26 C27 H27 119.1 . .
C28 C27 H27 119.1 . .
C29 C28 C27 121.2(7) . .
C29 C28 H28 119.4 . .
C27 C28 H28 119.4 . .
C28 C29 C30 120.7(6) . .
C28 C29 H29 119.6 . .
C30 C29 H29 119.6 . .
C31 C30 C29 118.7(6) . .
C31 C30 H30 120.6 . .
C29 C30 H30 120.6 . .
C30 C31 C26 120.6(6) . .
C30 C31 H31 119.7 . .
C26 C31 H31 119.7 . .
O2 C32 O1 122.9(4) . .
O2 C32 C33 121.7(5) . .
O1 C32 C33 115.3(5) . .
C38 C33 C34 118.4(6) . .
C38 C33 C32 119.5(6) . .
C34 C33 C32 122.1(5) . .
O3 C34 C35 119.8(8) . .
O3 C34 C33 121.3(5) . .
C35 C34 C33 118.8(8) . .
C36 C35 C34 120.5(10) . .
C36 C35 H35 119.7 . .
C34 C35 H35 119.7 . .
C37 C36 C35 121.0(9) . .
C37 C36 H36 119.5 . .
C35 C36 H36 119.5 . .
C36 C37 C38 120.3(11) . .
C36 C37 H37 119.8 . .
C38 C37 H37 119.8 . .
C37 C38 C33 120.8(9) . .
C37 C38 H38 119.6 . .
C33 C38 H38 119.6 . .
O4 C39 O5 126.1(5) . .
O4 C39 C40 118.6(6) . .
O5 C39 C40 115.3(6) . .
C45 C40 C41 118.5(7) . .
C45 C40 C39 120.5(7) . .
C41 C40 C39 121.0(7) . .
O6 C41 C40 120.0(6) . .
O6 C41 C42 118.8(8) . .
C40 C41 C42 121.2(8) . .
C43 C42 C41 117.7(9) . .
C43 C42 H42 121.2 . .
C41 C42 H42 121.2 . .
C42 C43 C44 123.6(9) . .
C42 C43 H43 118.2 . .
C44 C43 H43 118.2 . .
C43 C44 C45 118.6(10) . .
C43 C44 H44 120.7 . .
C45 C44 H44 120.7 . .
C40 C45 C44 120.3(9) . .
C40 C45 H45 119.8 . .
C44 C45 H45 119.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O1 2.297(3) .
Ag1 O2 2.336(3) 3_766
Ag1 P1 2.3820(10) .
Ag2 N2 2.304(4) .
Ag2 O4 2.330(4) .
Ag2 P2 2.3502(12) 3_666
Ag2 O2 2.523(3) .
P1 C14 1.812(4) .
P1 C8 1.815(5) .
P1 C1 1.851(4) .
P2 C26 1.816(5) .
P2 C20 1.818(5) .
P2 C2 1.871(4) .
P2 Ag2 2.3503(12) 3_666
N1 C3 1.381(6) .
N1 C1 1.445(5) .
N1 C2 1.448(5) .
N2 C7 1.332(5) .
N2 C6 1.346(6) .
O1 C32 1.269(5) .
O2 C32 1.238(5) .
O2 Ag1 2.336(3) 3_766
O3 C34 1.335(8) .
O3 H3O 0.8300 .
O4 C39 1.245(7) .
O5 C39 1.274(7) .
O6 C41 1.359(9) .
O6 H6O 0.8300 .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C3 C4 1.395(6) .
C3 C7 1.410(6) .
C4 C5 1.357(7) .
C4 H4 0.9400 .
C5 C6 1.371(7) .
C5 H5 0.9400 .
C6 H6 0.9400 .
C7 H7 0.9400 .
C8 C13 1.353(9) .
C8 C9 1.392(8) .
C9 C10 1.402(10) .
C9 H9 0.9400 .
C10 C11 1.324(14) .
C10 H10 0.9400 .
C11 C12 1.319(14) .
C11 H11 0.9400 .
C12 C13 1.440(13) .
C12 H12 0.9400 .
C13 H13 0.9400 .
C14 C19 1.377(7) .
C14 C15 1.387(7) .
C15 C16 1.398(9) .
C15 H15 0.9400 .
C16 C17 1.361(10) .
C16 H16 0.9400 .
C17 C18 1.323(10) .
C17 H17 0.9400 .
C18 C19 1.389(8) .
C18 H18 0.9400 .
C19 H19 0.9400 .
C20 C25 1.356(8) .
C20 C21 1.380(9) .
C21 C22 1.393(11) .
C21 H21 0.9400 .
C22 C23 1.382(17) .
C22 H22 0.9400 .
C23 C24 1.335(16) .
C23 H23 0.9400 .
C24 C25 1.373(11) .
C24 H24 0.9400 .
C25 H25 0.9400 .
C26 C27 1.349(7) .
C26 C31 1.421(7) .
C27 C28 1.385(9) .
C27 H27 0.9400 .
C28 C29 1.299(10) .
C28 H28 0.9400 .
C29 C30 1.392(10) .
C29 H29 0.9400 .
C30 C31 1.379(8) .
C30 H30 0.9400 .
C31 H31 0.9400 .
C32 C33 1.502(6) .
C33 C38 1.402(8) .
C33 C34 1.412(8) .
C34 C35 1.393(9) .
C35 C36 1.373(16) .
C35 H35 0.9400 .
C36 C37 1.352(17) .
C36 H36 0.9400 .
C37 C38 1.370(11) .
C37 H37 0.9400 .
C38 H38 0.9400 .
C39 C40 1.512(8) .
C40 C45 1.362(10) .
C40 C41 1.403(9) .
C41 C42 1.411(10) .
C42 C43 1.324(12) .
C42 H42 0.9400 .
C43 C44 1.375(14) .
C43 H43 0.9400 .
C44 C45 1.408(11) .
C44 H44 0.9400 .
C45 H45 0.9400 .
