#------------------------------------------------------------------------------
#$Date: 2016-08-07 11:47:08 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185340 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/94/7039452.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7039452
loop_
_publ_author_name
'Zhao, Minggang'
'Wang, Lixia'
'Zhang, Xiang'
'Zheng, Wenjun'
_publ_section_title
;
 Paddlewheel 1,2,4-diazaphospholide distibines with the shortest
 antimony-antimony single bonds.
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10505
_journal_page_last               10509
_journal_paper_doi               10.1039/c6dt02039a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C63 H96 N8 P4 Sb2'
_chemical_formula_weight         1332.86
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-05-21 deposited with the CCDC.
2016-06-03 downloaded from the CCDC.
;
_cell_angle_alpha                102.330(2)
_cell_angle_beta                 106.292(2)
_cell_angle_gamma                104.337(2)
_cell_formula_units_Z            1
_cell_length_a                   10.9130(3)
_cell_length_b                   11.8061(3)
_cell_length_c                   16.0228(4)
_cell_measurement_reflns_used    12152
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.7110
_cell_measurement_theta_min      3.1950
_cell_volume                     1828.71(9)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.0251
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0386
_diffrn_reflns_av_unetI/netI     0.0321
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            42583
_diffrn_reflns_theta_full        25.68
_diffrn_reflns_theta_max         25.68
_diffrn_reflns_theta_min         2.84
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count 1.00
_diffrn_standards_interval_time  5.93
_diffrn_standards_number         48107
_exptl_absorpt_coefficient_mu    0.865
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.64398
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.210
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             692
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.699
_refine_diff_density_min         -0.495
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     367
_refine_ls_number_reflns         6954
_refine_ls_number_restraints     80
_refine_ls_restrained_S_all      1.113
_refine_ls_R_factor_all          0.0535
_refine_ls_R_factor_gt           0.0423
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0745P)²+1.3543P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1216
_refine_ls_wR_factor_ref         0.1307
_reflns_number_gt                5862
_reflns_number_total             6954
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt02039a2.cif
_cod_data_source_block           151203-2a
_cod_depositor_comments
'Adding full bibliography for 7039448--7039452.cif.'
_cod_original_cell_volume        1828.71(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7039452
_oxdiff_exptl_absorpt_empirical_full_min 0.779
_oxdiff_exptl_absorpt_empirical_full_max 1.459
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.7852(5) 0.8062(5) 0.5823(4) 0.0767(16) Uani 1 1 d .
H1A H 0.7690 0.8461 0.5351 0.092 Uiso 1 1 calc R
H1B H 0.8772 0.8047 0.5971 0.092 Uiso 1 1 calc R
C2 C 0.7718(6) 0.8816(7) 0.6664(5) 0.098(2) Uani 1 1 d .
H2A H 0.8026 0.8501 0.7169 0.117 Uiso 1 1 calc R
H2B H 0.8295 0.9659 0.6829 0.117 Uiso 1 1 calc R
C3 C 0.6317(6) 0.8788(5) 0.6521(4) 0.0776(16) Uani 1 1 d .
H3A H 0.6059 0.9221 0.6085 0.093 Uiso 1 1 calc R
H3B H 0.6265 0.9213 0.7093 0.093 Uiso 1 1 calc R
C4 C 0.5346(7) 0.7508(6) 0.6176(5) 0.0844(18) Uani 1 1 d .
H4A H 0.4432 0.7527 0.6060 0.101 Uiso 1 1 calc R
H4B H 0.5546 0.7091 0.6632 0.101 Uiso 1 1 calc R
C5 C 0.5465(5) 0.6812(5) 0.5291(4) 0.0751(16) Uani 1 1 d .
H5A H 0.5220 0.7208 0.4827 0.090 Uiso 1 1 calc R
H5B H 0.4844 0.5978 0.5070 0.090 Uiso 1 1 calc R
C6 C 0.6918(5) 0.6791(4) 0.5458(3) 0.0518(11) Uani 1 1 d .
H6 H 0.7137 0.6382 0.5925 0.062 Uiso 1 1 calc R
C7 C 0.7065(4) 0.6081(4) 0.4608(3) 0.0461(9) Uani 1 1 d .
C8 C 0.7116(4) 0.5022(4) 0.3158(3) 0.0467(10) Uani 1 1 d .
C9 C 0.6993(5) 0.4360(4) 0.2213(3) 0.0545(11) Uani 1 1 d .
H9 H 0.7859 0.4236 0.2250 0.065 Uiso 1 1 calc R
C10 C 0.5941(10) 0.3133(6) 0.1852(5) 0.119(3) Uani 1 1 d .
H10A H 0.5082 0.3224 0.1851 0.143 Uiso 1 1 calc R
H10B H 0.6175 0.2643 0.2248 0.143 Uiso 1 1 calc R
C11 C 0.5801(12) 0.2463(7) 0.0876(6) 0.151(4) Uani 1 1 d .
H11A H 0.6605 0.2241 0.0898 0.181 Uiso 1 1 calc R
H11B H 0.5036 0.1710 0.0639 0.181 Uiso 1 1 calc R
C12 C 0.5608(8) 0.3206(9) 0.0243(5) 0.121(3) Uani 1 1 d .
H12A H 0.5642 0.2779 -0.0334 0.145 Uiso 1 1 calc R
H12B H 0.4722 0.3299 0.0128 0.145 Uiso 1 1 calc R
C13 C 0.6603(8) 0.4376(7) 0.0599(4) 0.099(2) Uani 1 1 d .
H13A H 0.6393 0.4852 0.0187 0.119 Uiso 1 1 calc R
H13B H 0.7470 0.4283 0.0625 0.119 Uiso 1 1 calc R
C14 C 0.6719(8) 0.5090(6) 0.1556(4) 0.0838(18) Uani 1 1 d .
H14A H 0.7446 0.5868 0.1774 0.101 Uiso 1 1 calc R
H14B H 0.5885 0.5262 0.1525 0.101 Uiso 1 1 calc R
C15 C 1.0634(7) 0.6512(9) 0.2409(4) 0.114(3) Uani 1 1 d .
H15A H 1.0607 0.7338 0.2463 0.137 Uiso 1 1 calc R
H15B H 0.9836 0.6046 0.2494 0.137 Uiso 1 1 calc R
C16 C 1.0606(8) 0.5917(10) 0.1443(5) 0.134(4) Uani 1 1 d .
H16A H 1.0486 0.5052 0.1355 0.160 Uiso 1 1 calc R
H16B H 0.9841 0.5981 0.0993 0.160 Uiso 1 1 calc R
C17 C 1.1825(9) 0.6491(11) 0.1305(5) 0.134(4) Uani 1 1 d .
H17A H 1.1805 0.6013 0.0725 0.161 Uiso 1 1 calc R
H17B H 1.1829 0.7297 0.1258 0.161 Uiso 1 1 calc R
C18 C 1.3059(8) 0.6629(11) 0.1993(5) 0.140(4) Uani 1 1 d .
H18A H 1.3816 0.7109 0.1875 0.168 Uiso 1 1 calc R
H18B H 1.3150 0.5828 0.1975 0.168 Uiso 1 1 calc R
C34 C 0.9045(14) 0.1212(12) 0.0002(11) 0.192(12) Uani 0.50 1 d PGD
C29 C 0.9501(18) 0.1823(14) 0.0931(11) 0.189(7) Uani 0.50 1 d PGDU
H29 H 0.8927 0.1690 0.1259 0.227 Uiso 0.50 1 calc PR
C30 C 1.0814(19) 0.2635(14) 0.1369(11) 0.192(7) Uani 0.50 1 d PGU
H30 H 1.1119 0.3044 0.1990 0.230 Uiso 0.50 1 calc PR
C31 C 1.1671(15) 0.2834(13) 0.0878(14) 0.193(6) Uani 0.50 1 d PGU
H31 H 1.2549 0.3377 0.1171 0.231 Uiso 0.50 1 calc PR
C32 C 1.1215(16) 0.2223(15) -0.0051(14) 0.193(7) Uani 0.50 1 d PGU
H32 H 1.1788 0.2357 -0.0380 0.231 Uiso 0.50 1 calc PR
C33 C 0.9902(17) 0.1412(14) -0.0489(10) 0.193(7) Uani 0.50 1 d PGDU
H33 H 0.9596 0.1003 -0.1111 0.232 Uiso 0.50 1 calc PR
C19 C 1.3084(7) 0.7287(7) 0.2966(5) 0.0935(18) Uani 1 1 d U
H19A H 1.3899 0.7327 0.3432 0.112 Uiso 1 1 calc R
H19B H 1.3083 0.8118 0.3006 0.112 Uiso 1 1 calc R
C20 C 1.1830(6) 0.6559(5) 0.3121(3) 0.0676(12) Uani 1 1 d U
H20 H 1.1842 0.5721 0.3075 0.081 Uiso 1 1 calc R
C21 C 1.1806(5) 0.7141(4) 0.4048(3) 0.0571(11) Uani 1 1 d U
C22 C 1.1803(5) 0.8275(4) 0.5487(3) 0.0507(10) Uani 1 1 d U
C23 C 1.1916(5) 0.9113(4) 0.6372(3) 0.0560(10) Uani 1 1 d U
H23 H 1.1341 0.8641 0.6636 0.067 Uiso 1 1 calc R
C24 C 1.1446(6) 1.0191(5) 0.6244(4) 0.0741(13) Uani 1 1 d U
H24A H 1.0510 0.9889 0.5838 0.089 Uiso 1 1 calc R
H24B H 1.1983 1.0654 0.5962 0.089 Uiso 1 1 calc R
C25 C 1.1575(6) 1.1034(6) 0.7154(4) 0.0868(16) Uani 1 1 d U
H25A H 1.1310 1.1734 0.7053 0.104 Uiso 1 1 calc R
H25B H 1.0969 1.0594 0.7406 0.104 Uiso 1 1 calc R
C26 C 1.3001(7) 1.1478(6) 0.7824(5) 0.0897(16) Uani 1 1 d U
H26A H 1.3592 1.2000 0.7605 0.108 Uiso 1 1 calc R
H26B H 1.3038 1.1963 0.8407 0.108 Uiso 1 1 calc R
C27 C 1.3481(7) 1.0436(6) 0.7949(4) 0.0911(16) Uani 1 1 d U
H27A H 1.2953 0.9968 0.8232 0.109 Uiso 1 1 calc R
H27B H 1.4417 1.0750 0.8354 0.109 Uiso 1 1 calc R
C28 C 1.3362(6) 0.9602(5) 0.7049(4) 0.0764(14) Uani 1 1 d U
H28A H 1.3657 0.8918 0.7155 0.092 Uiso 1 1 calc R
H28B H 1.3952 1.0052 0.6791 0.092 Uiso 1 1 calc R
C35 C 0.7645(16) 0.0305(19) -0.0464(16) 0.172(10) Uani 0.50 1 d PD
H35A H 0.7576 -0.0384 -0.0231 0.259 Uiso 0.50 1 calc PR
H35B H 0.7458 0.0029 -0.1109 0.259 Uiso 0.50 1 calc PR
H35C H 0.7003 0.0689 -0.0350 0.259 Uiso 0.50 1 calc PR
N1 N 1.1208(3) 0.7080(3) 0.5277(2) 0.0434(8) Uani 1 1 d .
N2 N 1.1203(4) 0.6433(3) 0.4457(2) 0.0454(8) Uani 1 1 d .
N3 N 0.8071(3) 0.5626(3) 0.4688(2) 0.0431(8) Uani 1 1 d .
N4 N 0.8106(3) 0.5024(3) 0.3864(2) 0.0457(8) Uani 1 1 d .
P1 P 0.60556(14) 0.57897(15) 0.34730(9) 0.0645(4) Uani 1 1 d .
P2 P 1.2442(2) 0.86974(13) 0.46687(12) 0.0815(5) Uani 1 1 d .
Sb1 Sb 0.99739(3) 0.56164(2) 0.581925(16) 0.04105(12) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C6 C1 C2 113.8(5) . .
C6 C1 H1A 108.8 . .
C2 C1 H1A 108.8 . .
C6 C1 H1B 108.8 . .
C2 C1 H1B 108.8 . .
H1A C1 H1B 107.7 . .
C3 C2 C1 112.2(5) . .
C3 C2 H2A 109.2 . .
C1 C2 H2A 109.2 . .
C3 C2 H2B 109.2 . .
C1 C2 H2B 109.2 . .
H2A C2 H2B 107.9 . .
C2 C3 C4 112.2(5) . .
C2 C3 H3A 109.2 . .
C4 C3 H3A 109.2 . .
C2 C3 H3B 109.2 . .
C4 C3 H3B 109.2 . .
H3A C3 H3B 107.9 . .
C3 C4 C5 109.5(5) . .
C3 C4 H4A 109.8 . .
C5 C4 H4A 109.8 . .
C3 C4 H4B 109.8 . .
C5 C4 H4B 109.8 . .
H4A C4 H4B 108.2 . .
C4 C5 C6 110.5(5) . .
C4 C5 H5A 109.5 . .
C6 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
C6 C5 H5B 109.5 . .
H5A C5 H5B 108.1 . .
C1 C6 C7 112.0(4) . .
C1 C6 C5 108.9(4) . .
C7 C6 C5 112.1(4) . .
C1 C6 H6 107.9 . .
C7 C6 H6 107.9 . .
C5 C6 H6 107.9 . .
N3 C7 C6 119.4(4) . .
N3 C7 P1 113.1(3) . .
C6 C7 P1 127.5(3) . .
N4 C8 C9 118.8(4) . .
N4 C8 P1 113.5(3) . .
C9 C8 P1 127.7(3) . .
C10 C9 C8 111.6(5) . .
C10 C9 C14 110.0(5) . .
C8 C9 C14 112.5(4) . .
C10 C9 H9 107.5 . .
C8 C9 H9 107.5 . .
C14 C9 H9 107.5 . .
C9 C10 C11 111.5(6) . .
C9 C10 H10A 109.3 . .
C11 C10 H10A 109.3 . .
C9 C10 H10B 109.3 . .
C11 C10 H10B 109.3 . .
H10A C10 H10B 108.0 . .
C12 C11 C10 113.3(7) . .
C12 C11 H11A 108.9 . .
C10 C11 H11A 108.9 . .
C12 C11 H11B 108.9 . .
C10 C11 H11B 108.9 . .
H11A C11 H11B 107.7 . .
C13 C12 C11 111.8(6) . .
C13 C12 H12A 109.2 . .
C11 C12 H12A 109.2 . .
C13 C12 H12B 109.2 . .
C11 C12 H12B 109.2 . .
H12A C12 H12B 107.9 . .
C12 C13 C14 113.5(6) . .
C12 C13 H13A 108.9 . .
C14 C13 H13A 108.9 . .
C12 C13 H13B 108.9 . .
C14 C13 H13B 108.9 . .
H13A C13 H13B 107.7 . .
C9 C14 C13 110.6(5) . .
C9 C14 H14A 109.5 . .
C13 C14 H14A 109.5 . .
C9 C14 H14B 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 108.1 . .
C20 C15 C16 112.3(6) . .
C20 C15 H15A 109.1 . .
C16 C15 H15A 109.1 . .
C20 C15 H15B 109.1 . .
C16 C15 H15B 109.1 . .
H15A C15 H15B 107.9 . .
C17 C16 C15 111.9(7) . .
C17 C16 H16A 109.2 . .
C15 C16 H16A 109.2 . .
C17 C16 H16B 109.2 . .
C15 C16 H16B 109.2 . .
H16A C16 H16B 107.9 . .
C18 C17 C16 116.0(8) . .
C18 C17 H17A 108.3 . .
C16 C17 H17A 108.3 . .
C18 C17 H17B 108.3 . .
C16 C17 H17B 108.3 . .
H17A C17 H17B 107.4 . .
C17 C18 C19 110.5(7) . .
C17 C18 H18A 109.6 . .
C19 C18 H18A 109.6 . .
C17 C18 H18B 109.6 . .
C19 C18 H18B 109.6 . .
H18A C18 H18B 108.1 . .
C29 C34 C33 120.0 . .
C29 C34 C35 120.0 . .
C33 C34 C35 120.0 . .
C30 C29 C34 120.0 . .
C30 C29 H29 120.0 . .
C34 C29 H29 120.0 . .
C29 C30 C31 120.0 . .
C29 C30 H30 120.0 . .
C31 C30 H30 120.0 . .
C32 C31 C30 120.0 . .
C32 C31 H31 120.0 . .
C30 C31 H31 120.0 . .
C31 C32 C33 120.0 . .
C31 C32 H32 120.0 . .
C33 C32 H32 120.0 . .
C32 C33 C34 120.0 . .
C32 C33 H33 120.0 . .
C34 C33 H33 120.0 . .
C20 C19 C18 109.1(6) . .
C20 C19 H19A 109.9 . .
C18 C19 H19A 109.9 . .
C20 C19 H19B 109.9 . .
C18 C19 H19B 109.9 . .
H19A C19 H19B 108.3 . .
C15 C20 C21 110.2(5) . .
C15 C20 C19 108.3(5) . .
C21 C20 C19 111.5(5) . .
C15 C20 H20 108.9 . .
C21 C20 H20 108.9 . .
C19 C20 H20 108.9 . .
N2 C21 C20 119.0(4) . .
N2 C21 P2 113.4(3) . .
C20 C21 P2 127.6(4) . .
N1 C22 C23 119.7(4) . .
N1 C22 P2 113.6(3) . .
C23 C22 P2 126.7(3) . .
C22 C23 C24 112.3(4) . .
C22 C23 C28 111.3(4) . .
C24 C23 C28 108.8(4) . .
C22 C23 H23 108.1 . .
C24 C23 H23 108.1 . .
C28 C23 H23 108.1 . .
C23 C24 C25 111.4(5) . .
C23 C24 H24A 109.4 . .
C25 C24 H24A 109.4 . .
C23 C24 H24B 109.4 . .
C25 C24 H24B 109.4 . .
H24A C24 H24B 108.0 . .
C26 C25 C24 111.3(5) . .
C26 C25 H25A 109.4 . .
C24 C25 H25A 109.4 . .
C26 C25 H25B 109.4 . .
C24 C25 H25B 109.4 . .
H25A C25 H25B 108.0 . .
C27 C26 C25 111.2(5) . .
C27 C26 H26A 109.4 . .
C25 C26 H26A 109.4 . .
C27 C26 H26B 109.4 . .
C25 C26 H26B 109.4 . .
H26A C26 H26B 108.0 . .
C26 C27 C28 111.7(6) . .
C26 C27 H27A 109.3 . .
C28 C27 H27A 109.3 . .
C26 C27 H27B 109.3 . .
C28 C27 H27B 109.3 . .
H27A C27 H27B 107.9 . .
C27 C28 C23 111.6(5) . .
C27 C28 H28A 109.3 . .
C23 C28 H28A 109.3 . .
C27 C28 H28B 109.3 . .
C23 C28 H28B 109.3 . .
H28A C28 H28B 108.0 . .
C34 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C34 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C22 N1 N2 113.0(3) . .
C22 N1 Sb1 140.7(3) . .
N2 N1 Sb1 106.1(2) . .
C21 N2 N1 113.1(3) . .
C21 N2 Sb1 139.1(3) . 2_766
N1 N2 Sb1 107.7(2) . 2_766
C7 N3 N4 113.5(3) . .
C7 N3 Sb1 139.8(3) . .
N4 N3 Sb1 106.5(2) . .
C8 N4 N3 112.7(3) . .
C8 N4 Sb1 140.1(3) . 2_766
N3 N4 Sb1 107.1(2) . 2_766
C7 P1 C8 87.2(2) . .
C21 P2 C22 87.0(2) . .
N2 Sb1 N3 86.25(12) 2_766 .
N2 Sb1 N4 84.12(12) 2_766 2_766
N3 Sb1 N4 146.31(11) . 2_766
N2 Sb1 N1 146.15(11) 2_766 .
N3 Sb1 N1 84.55(12) . .
N4 Sb1 N1 85.72(12) 2_766 .
N2 Sb1 Sb1 74.02(8) 2_766 2_766
N3 Sb1 Sb1 73.59(8) . 2_766
N4 Sb1 Sb1 72.73(7) 2_766 2_766
N1 Sb1 Sb1 72.13(7) . 2_766
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C6 1.472(7) .
C1 C2 1.515(8) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 C3 1.472(8) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 C4 1.495(8) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C5 1.537(8) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 C6 1.540(7) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 C7 1.511(6) .
C6 H6 0.9800 .
C7 N3 1.324(5) .
C7 P1 1.750(4) .
C8 N4 1.326(5) .
C8 C9 1.501(6) .
C8 P1 1.751(4) .
C9 C10 1.482(8) .
C9 C14 1.509(7) .
C9 H9 0.9800 .
C10 C11 1.539(10) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C12 1.481(13) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C13 1.409(11) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 C14 1.538(8) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 C20 1.451(9) .
C15 C16 1.545(10) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 C17 1.436(11) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 C18 1.427(11) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 C19 1.576(11) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C34 C29 1.3900 .
C34 C33 1.3900 .
C34 C35 1.499(10) .
C29 C30 1.3900 .
C29 H29 0.9300 .
C30 C31 1.3900 .
C30 H30 0.9300 .
C31 C32 1.3900 .
C31 H31 0.9300 .
C32 C33 1.3900 .
C32 H32 0.9300 .
C33 H33 0.9300 .
C19 C20 1.541(8) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 C21 1.508(7) .
C20 H20 0.9800 .
C21 N2 1.329(6) .
C21 P2 1.746(5) .
C22 N1 1.321(5) .
C22 C23 1.499(6) .
C22 P2 1.753(5) .
C23 C24 1.517(7) .
C23 C28 1.525(7) .
C23 H23 0.9800 .
C24 C25 1.527(8) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C25 C26 1.506(9) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 C27 1.480(9) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 C28 1.513(8) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
N1 N2 1.369(4) .
N1 Sb1 2.387(3) .
N2 Sb1 2.320(3) 2_766
N3 N4 1.376(4) .
N3 Sb1 2.346(3) .
N4 Sb1 2.360(3) 2_766
Sb1 N2 2.320(3) 2_766
Sb1 N4 2.360(3) 2_766
Sb1 Sb1 2.7399(5) 2_766
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -53.1(9) .
C1 C2 C3 C4 53.2(9) .
C2 C3 C4 C5 -56.5(8) .
C3 C4 C5 C6 58.5(7) .
C2 C1 C6 C7 178.8(5) .
C2 C1 C6 C5 54.3(7) .
C4 C5 C6 C1 -57.2(6) .
C4 C5 C6 C7 178.3(5) .
C1 C6 C7 N3 79.6(6) .
C5 C6 C7 N3 -157.6(4) .
C1 C6 C7 P1 -98.9(5) .
C5 C6 C7 P1 23.9(6) .
N4 C8 C9 C10 99.7(6) .
P1 C8 C9 C10 -78.2(7) .
N4 C8 C9 C14 -136.1(5) .
P1 C8 C9 C14 46.1(7) .
C8 C9 C10 C11 179.1(7) .
C14 C9 C10 C11 53.5(10) .
C9 C10 C11 C12 -52.0(12) .
C10 C11 C12 C13 51.7(12) .
C11 C12 C13 C14 -53.9(10) .
C10 C9 C14 C13 -55.0(8) .
C8 C9 C14 C13 179.9(5) .
C12 C13 C14 C9 56.5(9) .
C20 C15 C16 C17 -53.1(12) .
C15 C16 C17 C18 50.3(14) .
C16 C17 C18 C19 -52.5(13) .
C33 C34 C29 C30 0.0 .
C35 C34 C29 C30 177.9(14) .
C34 C29 C30 C31 0.0 .
C29 C30 C31 C32 0.0 .
C30 C31 C32 C33 0.0 .
C31 C32 C33 C34 0.0 .
C29 C34 C33 C32 0.0 .
C35 C34 C33 C32 -177.9(14) .
C17 C18 C19 C20 55.7(11) .
C16 C15 C20 C21 -179.7(7) .
C16 C15 C20 C19 58.1(9) .
C18 C19 C20 C15 -59.2(8) .
C18 C19 C20 C21 179.4(6) .
C15 C20 C21 N2 88.7(7) .
C19 C20 C21 N2 -151.0(5) .
C15 C20 C21 P2 -88.8(7) .
C19 C20 C21 P2 31.5(7) .
N1 C22 C23 C24 -130.5(5) .
P2 C22 C23 C24 51.7(6) .
N1 C22 C23 C28 107.2(5) .
P2 C22 C23 C28 -70.5(6) .
C22 C23 C24 C25 -179.8(5) .
C28 C23 C24 C25 -56.1(7) .
C23 C24 C25 C26 56.2(8) .
C24 C25 C26 C27 -55.1(9) .
C25 C26 C27 C28 55.5(9) .
C26 C27 C28 C23 -57.1(8) .
C22 C23 C28 C27 -179.3(5) .
C24 C23 C28 C27 56.5(7) .
C23 C22 N1 N2 -178.9(4) .
P2 C22 N1 N2 -0.9(5) .
C23 C22 N1 Sb1 6.2(7) .
P2 C22 N1 Sb1 -175.8(3) .
C20 C21 N2 N1 -177.6(4) .
P2 C21 N2 N1 0.2(5) .
C20 C21 N2 Sb1 -1.2(8) 2_766
P2 C21 N2 Sb1 176.7(3) 2_766
C22 N1 N2 C21 0.4(5) .
Sb1 N1 N2 C21 177.1(3) .
C22 N1 N2 Sb1 -177.2(3) 2_766
Sb1 N1 N2 Sb1 -0.5(3) 2_766
C6 C7 N3 N4 -178.7(4) .
P1 C7 N3 N4 0.0(5) .
C6 C7 N3 Sb1 -4.1(7) .
P1 C7 N3 Sb1 174.6(3) .
C9 C8 N4 N3 -177.8(4) .
P1 C8 N4 N3 0.3(5) .
C9 C8 N4 Sb1 5.7(7) 2_766
P1 C8 N4 Sb1 -176.1(3) 2_766
C7 N3 N4 C8 -0.2(5) .
Sb1 N3 N4 C8 -176.6(3) .
C7 N3 N4 Sb1 177.4(3) 2_766
Sb1 N3 N4 Sb1 1.0(3) 2_766
N3 C7 P1 C8 0.1(4) .
C6 C7 P1 C8 178.7(4) .
N4 C8 P1 C7 -0.2(4) .
C9 C8 P1 C7 177.7(4) .
N2 C21 P2 C22 -0.6(4) .
C20 C21 P2 C22 177.1(5) .
N1 C22 P2 C21 0.8(4) .
C23 C22 P2 C21 178.7(4) .
C7 N3 Sb1 N2 109.8(5) 2_766
N4 N3 Sb1 N2 -75.3(3) 2_766
C7 N3 Sb1 N4 -176.6(4) 2_766
N4 N3 Sb1 N4 -1.8(4) 2_766
C7 N3 Sb1 N1 -102.8(5) .
N4 N3 Sb1 N1 72.1(2) .
C7 N3 Sb1 Sb1 -175.7(5) 2_766
N4 N3 Sb1 Sb1 -0.9(2) 2_766
C22 N1 Sb1 N2 176.0(4) 2_766
N2 N1 Sb1 N2 0.9(4) 2_766
C22 N1 Sb1 N3 101.1(5) .
N2 N1 Sb1 N3 -74.0(2) .
C22 N1 Sb1 N4 -111.2(5) 2_766
N2 N1 Sb1 N4 73.7(2) 2_766
C22 N1 Sb1 Sb1 175.6(5) 2_766
N2 N1 Sb1 Sb1 0.4(2) 2_766
