#------------------------------------------------------------------------------
#$Date: 2016-08-07 12:09:43 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185455 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/95/7039524.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7039524
loop_
_publ_author_name
'Yamada, Tomofumi'
'Ebihara, Masahiro'
'Uemura, Kazuhiro'
_publ_section_title
;
 Heterometallic one-dimensional chain with tetradeca metal repetition
 constructed by amidate bridged dirhodium and pivalate bridged diplatinum
 complexes influenced by hydrogen bonding.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12322
_journal_page_last               12328
_journal_paper_doi               10.1039/c6dt01601d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C32 H76 Cl4 N12 O32 Pt4 Rh3'
_chemical_formula_weight         2371.94
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-03-16 deposited with the CCDC.
2016-06-10 downloaded from the CCDC.
;
_cell_angle_alpha                92.394(6)
_cell_angle_beta                 113.9144(15)
_cell_angle_gamma                112.016(5)
_cell_formula_units_Z            2
_cell_length_a                   14.835(7)
_cell_length_b                   16.985(8)
_cell_length_c                   17.058(8)
_cell_measurement_reflns_used    8267
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.4846
_cell_measurement_theta_min      3.0058
_cell_volume                     3546(3)
_computing_cell_refinement       CRYSTALCLEAR
_computing_data_collection       CRYSTALCLEAR
_computing_data_reduction        CRYSTALCLEAR
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 14.6199
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.1005
_diffrn_reflns_av_sigmaI/netI    0.1739
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            28943
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    8.774
_exptl_absorpt_correction_T_max  0.8441
_exptl_absorpt_correction_T_min  0.1656
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.221
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2246
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.02
_refine_diff_density_max         3.195
_refine_diff_density_min         -3.252
_refine_diff_density_rms         0.300
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     893
_refine_ls_number_reflns         16060
_refine_ls_number_restraints     170
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.1470
_refine_ls_R_factor_gt           0.0842
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0630P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1815
_refine_ls_wR_factor_ref         0.2229
_reflns_number_gt                8434
_reflns_number_total             16060
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt01601d2.cif
_cod_data_source_block           complex4
_cod_depositor_comments          'Adding full bibliography for 7039524.cif.'
_cod_database_code               7039524
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.54055(14) 0.45052(9) 0.52405(12) 0.0556(4) Uani 1 1 d . . .
Pt1 Pt 0.62949(6) 0.32969(4) 0.58519(5) 0.0449(2) Uani 1 1 d . . .
Pt2 Pt 0.76190(6) 0.23062(4) 0.64900(5) 0.04075(19) Uani 1 1 d . . .
Rh2 Rh 0.95306(12) 0.19902(8) 0.71521(10) 0.0470(4) Uani 1 1 d . . .
Rh3 Rh 1.10236(12) 0.15809(8) 0.76980(10) 0.0458(4) Uani 1 1 d . . .
Pt3 Pt 1.27067(6) 0.10414(4) 0.82811(5) 0.0453(2) Uani 1 1 d . . .
Pt4 Pt 1.42485(6) 0.03444(4) 0.92649(5) 0.04315(19) Uani 1 1 d . . .
O1 O 0.4540(11) 0.3756(7) 0.4012(9) 0.055(4) Uani 1 1 d . . .
C1 C 0.3848(19) 0.3981(14) 0.3399(18) 0.083(8) Uani 1 1 d . . .
C2 C 0.307(3) 0.3319(15) 0.255(2) 0.118(11) Uani 1 1 d . . .
H2 H 0.2583 0.2820 0.2644 0.177 Uiso 1 1 calc R . .
H2A H 0.3474 0.3143 0.2312 0.177 Uiso 1 1 calc R . .
H2B H 0.2659 0.3570 0.2133 0.177 Uiso 1 1 calc R . .
N1 N 0.6255(17) 0.5320(9) 0.6430(12) 0.084(7) Uani 1 1 d . . .
H1 H 0.6713 0.5198 0.6848 0.101 Uiso 1 1 calc R . .
O2 O 0.4111(13) 0.3782(8) 0.5461(12) 0.080(5) Uani 1 1 d . . .
C3 C 0.3386(19) 0.4061(14) 0.5342(19) 0.074(7) Uani 1 1 d . . .
C4 C 0.2383(19) 0.3457(17) 0.542(3) 0.137(16) Uani 1 1 d . . .
H4 H 0.2086 0.2888 0.5052 0.206 Uiso 1 1 calc R . .
H4A H 0.1846 0.3685 0.5225 0.206 Uiso 1 1 calc R . .
H4B H 0.2582 0.3415 0.6018 0.206 Uiso 1 1 calc R . .
N2 N 0.6595(15) 0.5251(12) 0.4961(16) 0.090(7) Uani 1 1 d . . .
H2C H 0.7119 0.5106 0.5046 0.108 Uiso 1 1 calc R . .
O3 O 0.7060(10) 0.3534(7) 0.5088(8) 0.046(3) Uani 1 1 d . . .
C5 C 0.7620(13) 0.3152(10) 0.5015(12) 0.040(4) Uani 1 1 d . . .
C6 C 0.8118(18) 0.3406(11) 0.4396(14) 0.053(5) Uani 1 1 d . . .
C7 C 0.795(2) 0.4174(15) 0.405(2) 0.101(10) Uani 1 1 d . . .
H7 H 0.7204 0.4076 0.3876 0.151 Uiso 1 1 calc R . .
H7A H 0.8100 0.4235 0.3559 0.151 Uiso 1 1 calc R . .
H7B H 0.8428 0.4697 0.4512 0.151 Uiso 1 1 calc R . .
C8 C 0.766(3) 0.2635(15) 0.3673(19) 0.120(12) Uani 1 1 d . . .
H8 H 0.7757 0.2157 0.3921 0.180 Uiso 1 1 calc R . .
H8A H 0.8039 0.2779 0.3318 0.180 Uiso 1 1 calc R . .
H8B H 0.6900 0.2470 0.3314 0.180 Uiso 1 1 calc R . .
C9 C 0.939(2) 0.3735(16) 0.489(2) 0.116(11) Uani 1 1 d . . .
H9 H 0.9712 0.4298 0.5272 0.175 Uiso 1 1 calc R . .
H9A H 0.9667 0.3778 0.4466 0.175 Uiso 1 1 calc R . .
H9B H 0.9562 0.3331 0.5229 0.175 Uiso 1 1 calc R . .
O4 O 0.7898(10) 0.2646(7) 0.5484(8) 0.048(3) Uani 1 1 d . . .
O5 O 0.7628(10) 0.4240(7) 0.6873(9) 0.053(4) Uani 1 1 d . . .
C10 C 0.8518(17) 0.4185(10) 0.7331(13) 0.052(5) Uani 1 1 d . . .
C11 C 0.9413(17) 0.4966(12) 0.8015(16) 0.063(6) Uani 1 1 d . . .
C12 C 0.9047(19) 0.5608(11) 0.828(2) 0.094(10) Uani 1 1 d . . .
H12 H 0.8730 0.5831 0.7787 0.141 Uiso 1 1 calc R . .
H12A H 0.9665 0.6080 0.8750 0.141 Uiso 1 1 calc R . .
H12B H 0.8516 0.5318 0.8484 0.141 Uiso 1 1 calc R . .
C13 C 1.020(2) 0.5386(14) 0.762(2) 0.103(10) Uani 1 1 d . . .
H13 H 1.0372 0.4954 0.7411 0.155 Uiso 1 1 calc R . .
H13A H 1.0859 0.5850 0.8063 0.155 Uiso 1 1 calc R . .
H13B H 0.9859 0.5616 0.7137 0.155 Uiso 1 1 calc R . .
C14 C 1.007(3) 0.4682(15) 0.886(2) 0.133(13) Uani 1 1 d . . .
H14 H 0.9770 0.4663 0.9269 0.199 Uiso 1 1 calc R . .
H14A H 1.0826 0.5097 0.9144 0.199 Uiso 1 1 calc R . .
H14B H 1.0019 0.4115 0.8689 0.199 Uiso 1 1 calc R . .
O6 O 0.8679(10) 0.3511(6) 0.7246(8) 0.053(3) Uani 1 1 d . . .
N3 N 0.5490(13) 0.3150(9) 0.6571(11) 0.052(4) Uani 1 1 d . . .
H3 H 0.5944 0.3487 0.7110 0.078 Uiso 1 1 calc R . .
H3A H 0.5224 0.2594 0.6605 0.078 Uiso 1 1 calc R . .
H3B H 0.4944 0.3302 0.6319 0.078 Uiso 1 1 calc R . .
N4 N 0.7489(14) 0.1945(10) 0.7577(12) 0.065(5) Uani 1 1 d . . .
H4C H 0.7173 0.1366 0.7476 0.097 Uiso 1 1 calc R . .
H4D H 0.7086 0.2161 0.7698 0.097 Uiso 1 1 calc R . .
H4E H 0.8151 0.2151 0.8033 0.097 Uiso 1 1 calc R . .
N5 N 0.4957(11) 0.2431(8) 0.4813(9) 0.049(4) Uani 1 1 d . . .
H5 H 0.4520 0.2059 0.4997 0.074 Uiso 1 1 calc R . .
H5A H 0.5146 0.2140 0.4509 0.074 Uiso 1 1 calc R . .
H5B H 0.4608 0.2708 0.4470 0.074 Uiso 1 1 calc R . .
N6 N 0.6702(11) 0.1052(8) 0.5796(10) 0.052(4) Uani 1 1 d . . .
H6 H 0.6628 0.1020 0.5249 0.077 Uiso 1 1 calc R . .
H6A H 0.6047 0.0862 0.5780 0.077 Uiso 1 1 calc R . .
H6B H 0.7029 0.0723 0.6054 0.077 Uiso 1 1 calc R . .
O7 O 0.9767(12) 0.2299(10) 0.8415(9) 0.070(4) Uani 1 1 d . . .
C15 C 1.0666(19) 0.2330(12) 0.9038(15) 0.064(6) Uani 1 1 d . . .
C16 C 1.095(2) 0.2803(13) 0.9948(16) 0.087(8) Uani 1 1 d . . .
H16 H 1.1429 0.2621 1.0394 0.130 Uiso 1 1 calc R . .
H16A H 1.0297 0.2664 1.0007 0.130 Uiso 1 1 calc R . .
H16B H 1.1313 0.3421 1.0014 0.130 Uiso 1 1 calc R . .
N7 N 1.1250(14) 0.2002(9) 0.8918(11) 0.061(5) Uani 1 1 d . . .
H7C H 1.1758 0.1957 0.9367 0.073 Uiso 1 1 calc R . .
O8 O 0.8461(10) 0.0743(7) 0.6979(10) 0.062(4) Uani 1 1 d . . .
C17 C 0.8889(15) 0.0168(8) 0.7189(11) 0.038(4) Uani 1 1 d . . .
C18 C 0.804(2) -0.0766(10) 0.6943(19) 0.095(10) Uani 1 1 d . . .
H18 H 0.8227 -0.1142 0.6670 0.143 Uiso 1 1 calc R . .
H18A H 0.7336 -0.0807 0.6540 0.143 Uiso 1 1 calc R . .
H18B H 0.8010 -0.0940 0.7464 0.143 Uiso 1 1 calc R . .
N8 N 0.9881(12) 0.0364(9) 0.7508(10) 0.049(4) Uani 1 1 d . . .
H8C H 1.0095 -0.0037 0.7658 0.059 Uiso 1 1 calc R . .
O9 O 1.0782(11) 0.1235(8) 0.6432(10) 0.063(4) Uani 1 1 d . . .
C19 C 1.0018(19) 0.1362(12) 0.5802(17) 0.075(7) Uani 1 1 d . . .
C20 C 0.987(2) 0.1113(15) 0.4921(14) 0.087(8) Uani 1 1 d . . .
H20 H 0.9567 0.0489 0.4745 0.130 Uiso 1 1 calc R . .
H20A H 1.0569 0.1364 0.4917 0.130 Uiso 1 1 calc R . .
H20B H 0.9392 0.1323 0.4519 0.130 Uiso 1 1 calc R . .
N9 N 0.9409(13) 0.1659(9) 0.5952(10) 0.052(4) Uani 1 1 d . . .
H9C H 0.8914 0.1721 0.5508 0.063 Uiso 1 1 calc R . .
O10 O 1.2089(10) 0.2837(7) 0.7798(10) 0.060(4) Uani 1 1 d . . .
C21 C 1.1696(15) 0.3439(11) 0.7639(14) 0.057(6) Uani 1 1 d . . .
C22 C 1.2558(19) 0.4363(11) 0.7864(19) 0.098(10) Uani 1 1 d . . .
H22 H 1.2299 0.4657 0.7414 0.147 Uiso 1 1 calc R . .
H22A H 1.3215 0.4350 0.7899 0.147 Uiso 1 1 calc R . .
H22B H 1.2707 0.4669 0.8420 0.147 Uiso 1 1 calc R . .
N10 N 1.0658(12) 0.3181(7) 0.7351(11) 0.055(5) Uani 1 1 d . . .
H10 H 1.0424 0.3576 0.7229 0.065 Uiso 1 1 calc R . .
O11 O 1.3591(10) 0.1940(7) 0.9426(7) 0.045(3) Uani 1 1 d . . .
C23 C 1.4481(15) 0.2075(10) 1.0023(12) 0.043(4) Uani 1 1 d . . .
C24 C 1.514(2) 0.2884(17) 1.0800(16) 0.088(8) Uani 1 1 d . . .
C25 C 1.493(2) 0.3603(16) 1.0369(18) 0.129(13) Uani 1 1 d . . .
H25 H 1.4223 0.3356 0.9865 0.194 Uiso 1 1 calc R . .
H25A H 1.5479 0.3889 1.0186 0.194 Uiso 1 1 calc R . .
H25B H 1.4951 0.4020 1.0783 0.194 Uiso 1 1 calc R . .
C26 C 1.628(2) 0.3085(17) 1.1297(19) 0.121(12) Uani 1 1 d . . .
H26 H 1.6618 0.3590 1.1767 0.182 Uiso 1 1 calc R . .
H26A H 1.6620 0.3200 1.0918 0.182 Uiso 1 1 calc R . .
H26B H 1.6346 0.2599 1.1539 0.182 Uiso 1 1 calc R . .
C27 C 1.449(3) 0.2638(19) 1.1304(19) 0.151(15) Uani 1 1 d U . .
H27 H 1.4959 0.2667 1.1902 0.226 Uiso 1 1 calc R . .
H27A H 1.3923 0.2055 1.1036 0.226 Uiso 1 1 calc R . .
H27B H 1.4165 0.3035 1.1298 0.226 Uiso 1 1 calc R . .
O12 O 1.4936(11) 0.1530(9) 1.0098(9) 0.063(4) Uani 1 1 d . . .
O13 O 1.1877(10) 0.0194(9) 0.8824(9) 0.057(3) Uani 1 1 d . . .
C28 C 1.2310(15) -0.0097(15) 0.9464(15) 0.064(6) Uani 1 1 d . . .
C29 C 1.159(2) -0.0399(18) 1.0009(18) 0.084(9) Uani 1 1 d . . .
C30 C 1.209(2) 0.0459(19) 1.072(2) 0.134(13) Uani 1 1 d . . .
H30 H 1.2033 0.0925 1.0435 0.201 Uiso 1 1 calc R . .
H30A H 1.2840 0.0607 1.1105 0.201 Uiso 1 1 calc R . .
H30B H 1.1689 0.0368 1.1060 0.201 Uiso 1 1 calc R . .
C31 C 1.180(2) -0.111(2) 1.046(2) 0.149(16) Uani 1 1 d . . .
H31 H 1.1280 -0.1351 1.0687 0.224 Uiso 1 1 calc R . .
H31A H 1.2524 -0.0866 1.0938 0.224 Uiso 1 1 calc R . .
H31B H 1.1715 -0.1560 1.0045 0.224 Uiso 1 1 calc R . .
C32 C 1.0395(15) -0.0699(16) 0.9388(16) 0.089(8) Uani 1 1 d . . .
H32 H 1.0118 -0.1259 0.9016 0.134 Uiso 1 1 calc R . .
H32A H 1.0307 -0.0286 0.9031 0.134 Uiso 1 1 calc R . .
H32B H 0.9998 -0.0743 0.9723 0.134 Uiso 1 1 calc R . .
O14 O 1.3218(12) -0.0107(9) 0.9793(10) 0.068(4) Uani 1 1 d . . .
N11 N 1.1792(12) 0.0176(7) 0.7106(10) 0.048(4) Uani 1 1 d . . .
H11 H 1.1259 0.0312 0.6766 0.072 Uiso 1 1 calc R . .
H11A H 1.1505 -0.0358 0.7188 0.072 Uiso 1 1 calc R . .
H11B H 1.2209 0.0191 0.6846 0.072 Uiso 1 1 calc R . .
N12 N 1.3604(12) -0.0892(8) 0.8517(10) 0.059(5) Uani 1 1 d . . .
H12C H 1.3863 -0.1218 0.8854 0.088 Uiso 1 1 calc R . .
H12D H 1.3790 -0.0863 0.8081 0.088 Uiso 1 1 calc R . .
H12E H 1.2880 -0.1129 0.8294 0.088 Uiso 1 1 calc R . .
N13 N 1.3362(12) 0.1951(7) 0.7702(12) 0.056(5) Uani 1 1 d . . .
H13C H 1.3530 0.2478 0.7983 0.084 Uiso 1 1 calc R . .
H13D H 1.2880 0.1847 0.7141 0.084 Uiso 1 1 calc R . .
H13E H 1.3962 0.1929 0.7726 0.084 Uiso 1 1 calc R . .
N14 N 1.5371(14) 0.0794(10) 0.8826(13) 0.067(5) Uani 1 1 d . . .
H14C H 1.6016 0.1136 0.9275 0.100 Uiso 1 1 calc R . .
H14D H 1.5178 0.1098 0.8428 0.100 Uiso 1 1 calc R . .
H14E H 1.5416 0.0347 0.8580 0.100 Uiso 1 1 calc R . .
Cl1 Cl 1.5286(5) -0.0810(3) 0.6956(4) 0.0659(14) Uani 1 1 d . . .
O15 O 1.4741(17) -0.0765(10) 0.7473(13) 0.112(7) Uani 1 1 d . . .
O16 O 1.5684(14) -0.1455(9) 0.7164(11) 0.089(6) Uani 1 1 d . . .
O17 O 1.6160(18) 0.0033(10) 0.7176(15) 0.133(9) Uani 1 1 d . . .
O18 O 1.454(2) -0.1076(14) 0.6049(13) 0.152(10) Uani 1 1 d . . .
Cl2 Cl 1.3751(6) 0.0792(4) 0.6043(5) 0.0818(19) Uani 1 1 d . . .
O19 O 1.303(2) -0.0013(13) 0.603(3) 0.217(17) Uani 1 1 d . . .
O20 O 1.455(3) 0.1145(19) 0.6896(18) 0.229(18) Uani 1 1 d . . .
O21 O 1.428(2) 0.0768(14) 0.5547(18) 0.144(9) Uani 1 1 d . . .
O22 O 1.3266(17) 0.1394(12) 0.5834(14) 0.117(7) Uani 1 1 d . . .
Cl3 Cl 1.0355(6) -0.2119(4) 0.7307(5) 0.093(2) Uani 1 1 d D . .
O23A O 0.977(2) -0.2966(15) 0.674(2) 0.130(16) Uani 0.64(4) 1 d PDU A 1
O24A O 0.968(3) -0.168(2) 0.696(3) 0.141(18) Uani 0.64(4) 1 d PDU A 1
O25A O 1.1278(19) -0.1701(15) 0.715(2) 0.098(12) Uani 0.64(4) 1 d PDU A 1
O26A O 1.079(4) -0.226(2) 0.8171(17) 0.21(3) Uani 0.64(4) 1 d PDU A 1
O23B O 1.002(4) -0.269(3) 0.649(4) 0.14(3) Uani 0.36(4) 1 d PDU A 2
O24B O 1.006(5) -0.139(4) 0.717(4) 0.12(3) Uani 0.36(4) 1 d PDU A 2
O25B O 1.150(3) -0.185(4) 0.792(4) 0.22(4) Uani 0.36(4) 1 d PDU A 2
O26B O 0.963(6) -0.250(3) 0.771(4) 0.13(3) Uani 0.36(4) 1 d PDU A 2
Cl4A Cl 0.6603(19) 0.3375(13) 0.8912(16) 0.087(8) Uani 0.47(3) 1 d PD B 1
Cl4B Cl 0.6873(18) 0.3290(14) 0.9058(15) 0.083(7) Uani 0.53(3) 1 d PD B 2
O27A O 0.695(4) 0.307(3) 0.836(3) 0.16(2) Uani 0.47(3) 1 d PDU B 1
O28A O 0.751(3) 0.382(3) 0.975(2) 0.17(2) Uani 0.47(3) 1 d PDU B 1
O29A O 0.581(3) 0.266(2) 0.901(2) 0.096(13) Uani 0.47(3) 1 d PDU B 1
O30A O 0.616(3) 0.395(3) 0.855(3) 0.19(3) Uani 0.47(3) 1 d PDU B 1
O27B O 0.738(3) 0.352(3) 0.850(2) 0.17(2) Uani 0.53(3) 1 d PDU B 2
O28B O 0.706(4) 0.406(2) 0.958(3) 0.20(2) Uani 0.53(3) 1 d PDU B 2
O29B O 0.574(2) 0.277(2) 0.855(2) 0.117(13) Uani 0.53(3) 1 d PDU B 2
O30B O 0.735(3) 0.281(3) 0.963(2) 0.18(2) Uani 0.53(3) 1 d PDU B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Rh1 N1 87.0(9) . .
N2 Rh1 O1 91.3(8) . .
N1 Rh1 O1 176.1(5) . .
N2 Rh1 O2 175.5(6) . .
N1 Rh1 O2 94.4(8) . .
O1 Rh1 O2 87.0(7) . .
N2 Rh1 Rh1 86.6(4) . 2_666
N1 Rh1 Rh1 86.5(4) . 2_666
O1 Rh1 Rh1 89.8(3) . 2_666
O2 Rh1 Rh1 89.2(4) . 2_666
N2 Rh1 Pt1 96.3(4) . .
N1 Rh1 Pt1 92.8(4) . .
O1 Rh1 Pt1 90.9(3) . .
O2 Rh1 Pt1 88.0(3) . .
Rh1 Rh1 Pt1 177.05(12) 2_666 .
N3 Pt1 N5 91.4(7) . .
N3 Pt1 O3 174.6(5) . .
N5 Pt1 O3 88.5(6) . .
N3 Pt1 O5 89.0(6) . .
N5 Pt1 O5 176.1(5) . .
O3 Pt1 O5 90.8(5) . .
N3 Pt1 Rh1 83.8(4) . .
N5 Pt1 Rh1 84.5(4) . .
O3 Pt1 Rh1 90.8(3) . .
O5 Pt1 Rh1 91.8(3) . .
N3 Pt1 Pt2 104.8(4) . .
N5 Pt1 Pt2 102.6(4) . .
O3 Pt1 Pt2 80.5(3) . .
O5 Pt1 Pt2 81.0(3) . .
Rh1 Pt1 Pt2 168.51(5) . .
O4 Pt2 O6 90.7(5) . .
O4 Pt2 N6 90.1(6) . .
O6 Pt2 N6 173.1(5) . .
O4 Pt2 N4 173.8(6) . .
O6 Pt2 N4 88.1(6) . .
N6 Pt2 N4 90.4(7) . .
O4 Pt2 Rh2 88.9(3) . .
O6 Pt2 Rh2 83.1(3) . .
N6 Pt2 Rh2 90.0(4) . .
N4 Pt2 Rh2 84.9(4) . .
O4 Pt2 Pt1 78.7(3) . .
O6 Pt2 Pt1 78.5(3) . .
N6 Pt2 Pt1 108.4(4) . .
N4 Pt2 Pt1 107.0(4) . .
Rh2 Pt2 Pt1 157.57(4) . .
N10 Rh2 N9 90.7(7) . .
N10 Rh2 O8 176.0(5) . .
N9 Rh2 O8 88.9(6) . .
N10 Rh2 O7 88.8(7) . .
N9 Rh2 O7 175.0(6) . .
O8 Rh2 O7 91.2(6) . .
N10 Rh2 Rh3 85.6(4) . .
N9 Rh2 Rh3 85.6(4) . .
O8 Rh2 Rh3 90.4(3) . .
O7 Rh2 Rh3 89.4(4) . .
N10 Rh2 Pt2 99.9(4) . .
N9 Rh2 Pt2 94.5(4) . .
O8 Rh2 Pt2 84.1(3) . .
O7 Rh2 Pt2 90.4(4) . .
Rh3 Rh2 Pt2 174.43(7) . .
N7 Rh3 N8 94.8(7) . .
N7 Rh3 O9 175.7(5) . .
N8 Rh3 O9 88.0(6) . .
N7 Rh3 O10 87.6(6) . .
N8 Rh3 O10 175.1(6) . .
O9 Rh3 O10 89.3(6) . .
N7 Rh3 Rh2 86.7(4) . .
N8 Rh3 Rh2 86.0(4) . .
O9 Rh3 Rh2 90.4(4) . .
O10 Rh3 Rh2 89.9(4) . .
N7 Rh3 Pt3 95.0(4) . .
N8 Rh3 Pt3 92.2(4) . .
O9 Rh3 Pt3 88.1(4) . .
O10 Rh3 Pt3 91.8(4) . .
Rh2 Rh3 Pt3 177.68(7) . .
O11 Pt3 N11 177.5(5) . .
O11 Pt3 N13 88.9(6) . .
N11 Pt3 N13 89.6(6) . .
O11 Pt3 O13 90.7(5) . .
N11 Pt3 O13 90.5(5) . .
N13 Pt3 O13 171.5(5) . .
O11 Pt3 Rh3 93.5(3) . .
N11 Pt3 Rh3 84.3(4) . .
N13 Pt3 Rh3 84.1(4) . .
O13 Pt3 Rh3 87.5(3) . .
O11 Pt3 Pt4 79.9(3) . .
N11 Pt3 Pt4 102.6(4) . .
N13 Pt3 Pt4 110.4(4) . .
O13 Pt3 Pt4 77.8(3) . .
Rh3 Pt3 Pt4 163.70(5) . .
N14 Pt4 O14 175.5(6) . .
N14 Pt4 O12 90.1(7) . .
O14 Pt4 O12 88.5(6) . .
N14 Pt4 N12 91.5(7) . .
O14 Pt4 N12 89.4(7) . .
O12 Pt4 N12 175.1(6) . .
N14 Pt4 Pt3 101.8(4) . .
O14 Pt4 Pt3 82.2(4) . .
O12 Pt4 Pt3 80.1(4) . .
N12 Pt4 Pt3 104.0(4) . .
N14 Pt4 Pt4 90.9(5) . 2_857
O14 Pt4 Pt4 84.8(4) . 2_857
O12 Pt4 Pt4 91.9(4) . 2_857
N12 Pt4 Pt4 83.5(4) . 2_857
Pt3 Pt4 Pt4 164.90(4) . 2_857
C1 O1 Rh1 118.8(12) . .
N1 C1 O1 121(2) 2_666 .
N1 C1 C2 121(2) 2_666 .
O1 C1 C2 117(2) . .
C1 C2 H2 109.5 . .
C1 C2 H2A 109.5 . .
H2 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 N1 Rh1 123.4(16) 2_666 .
C1 N1 H1 118.3 2_666 .
Rh1 N1 H1 118.3 . .
C3 O2 Rh1 118.3(13) . .
O2 C3 N2 123(2) . 2_666
O2 C3 C4 116.4(18) . .
N2 C3 C4 120.2(19) 2_666 .
C3 C4 H4 109.5 . .
C3 C4 H4A 109.5 . .
H4 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 N2 Rh1 123.2(14) 2_666 .
C3 N2 H2C 118.4 2_666 .
Rh1 N2 H2C 118.4 . .
C5 O3 Pt1 124.8(11) . .
O4 C5 O3 125.8(17) . .
O4 C5 C6 116.5(15) . .
O3 C5 C6 117.2(15) . .
C8 C6 C5 109.6(16) . .
C8 C6 C7 112(2) . .
C5 C6 C7 110.6(17) . .
C8 C6 C9 108(2) . .
C5 C6 C9 111.1(19) . .
C7 C6 C9 104.8(17) . .
C6 C7 H7 109.5 . .
C6 C7 H7A 109.5 . .
H7 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C8 H8 109.5 . .
C6 C8 H8A 109.5 . .
H8 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
H8 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C6 C9 H9 109.5 . .
C6 C9 H9A 109.5 . .
H9 C9 H9A 109.5 . .
C6 C9 H9B 109.5 . .
H9 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C5 O4 Pt2 129.0(11) . .
C10 O5 Pt1 125.3(10) . .
O6 C10 O5 124.9(16) . .
O6 C10 C11 118.4(18) . .
O5 C10 C11 116.8(15) . .
C10 C11 C12 114.2(18) . .
C10 C11 C13 104.9(19) . .
C12 C11 C13 111.2(19) . .
C10 C11 C14 109.9(18) . .
C12 C11 C14 110(2) . .
C13 C11 C14 107(2) . .
C11 C12 H12 109.5 . .
C11 C12 H12A 109.5 . .
H12 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C13 H13 109.5 . .
C11 C13 H13A 109.5 . .
H13 C13 H13A 109.5 . .
C11 C13 H13B 109.5 . .
H13 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C11 C14 H14 109.5 . .
C11 C14 H14A 109.5 . .
H14 C14 H14A 109.5 . .
C11 C14 H14B 109.5 . .
H14 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C10 O6 Pt2 129.4(12) . .
Pt1 N3 H3 109.5 . .
Pt1 N3 H3A 109.5 . .
H3 N3 H3A 109.5 . .
Pt1 N3 H3B 109.5 . .
H3 N3 H3B 109.5 . .
H3A N3 H3B 109.5 . .
Pt2 N4 H4C 109.5 . .
Pt2 N4 H4D 109.5 . .
H4C N4 H4D 109.5 . .
Pt2 N4 H4E 109.5 . .
H4C N4 H4E 109.5 . .
H4D N4 H4E 109.5 . .
Pt1 N5 H5 109.5 . .
Pt1 N5 H5A 109.5 . .
H5 N5 H5A 109.5 . .
Pt1 N5 H5B 109.5 . .
H5 N5 H5B 109.5 . .
H5A N5 H5B 109.5 . .
Pt2 N6 H6 109.5 . .
Pt2 N6 H6A 109.5 . .
H6 N6 H6A 109.5 . .
Pt2 N6 H6B 109.5 . .
H6 N6 H6B 109.5 . .
H6A N6 H6B 109.5 . .
C15 O7 Rh2 116.0(12) . .
N7 C15 O7 124.4(19) . .
N7 C15 C16 122(2) . .
O7 C15 C16 113.2(17) . .
C15 C16 H16 109.5 . .
C15 C16 H16A 109.5 . .
H16 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 N7 Rh3 121.7(15) . .
C15 N7 H7C 119.1 . .
Rh3 N7 H7C 119.1 . .
C17 O8 Rh2 116.2(11) . .
N8 C17 O8 123.9(14) . .
N8 C17 C18 122.5(15) . .
O8 C17 C18 113.5(17) . .
C17 C18 H18 109.5 . .
C17 C18 H18A 109.5 . .
H18 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 N8 Rh3 123.4(11) . .
C17 N8 H8C 118.3 . .
Rh3 N8 H8C 118.3 . .
C19 O9 Rh3 117.1(14) . .
N9 C19 O9 122(2) . .
N9 C19 C20 122(2) . .
O9 C19 C20 115(2) . .
C19 C20 H20 109.5 . .
C19 C20 H20A 109.5 . .
H20 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 N9 Rh2 124.9(16) . .
C19 N9 H9C 117.6 . .
Rh2 N9 H9C 117.6 . .
C21 O10 Rh3 118.0(11) . .
N10 C21 O10 117.8(15) . .
N10 C21 C22 127.7(17) . .
O10 C21 C22 114.5(16) . .
C21 C22 H22 109.5 . .
C21 C22 H22A 109.5 . .
H22 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 N10 Rh2 128.4(12) . .
C21 N10 H10 115.8 . .
Rh2 N10 H10 115.8 . .
C23 O11 Pt3 128.6(11) . .
O11 C23 O12 123.9(15) . .
O11 C23 C24 122.2(17) . .
O12 C23 C24 113.7(18) . .
C26 C24 C27 115(3) . .
C26 C24 C25 114(3) . .
C27 C24 C25 107(3) . .
C26 C24 C23 115(2) . .
C27 C24 C23 101(2) . .
C25 C24 C23 103.4(19) . .
C24 C25 H25 109.5 . .
C24 C25 H25A 109.5 . .
H25 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C26 H26 109.5 . .
C24 C26 H26A 109.5 . .
H26 C26 H26A 109.5 . .
C24 C26 H26B 109.5 . .
H26 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C24 C27 H27 109.5 . .
C24 C27 H27A 109.5 . .
H27 C27 H27A 109.5 . .
C24 C27 H27B 109.5 . .
H27 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C23 O12 Pt4 125.1(12) . .
C28 O13 Pt3 124.4(12) . .
O14 C28 O13 131(2) . .
O14 C28 C29 116.3(18) . .
O13 C28 C29 112.6(14) . .
C32 C29 C31 111(2) . .
C32 C29 C30 113.2(19) . .
C31 C29 C30 110(3) . .
C32 C29 C28 109.5(18) . .
C31 C29 C28 110.6(17) . .
C30 C29 C28 102(2) . .
C29 C30 H30 109.5 . .
C29 C30 H30A 109.5 . .
H30 C30 H30A 109.5 . .
C29 C30 H30B 109.5 . .
H30 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C29 C31 H31 109.5 . .
C29 C31 H31A 109.5 . .
H31 C31 H31A 109.5 . .
C29 C31 H31B 109.5 . .
H31 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C29 C32 H32 109.5 . .
C29 C32 H32A 109.5 . .
H32 C32 H32A 109.5 . .
C29 C32 H32B 109.5 . .
H32 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C28 O14 Pt4 121.2(14) . .
Pt3 N11 H11 109.5 . .
Pt3 N11 H11A 109.5 . .
H11 N11 H11A 109.5 . .
Pt3 N11 H11B 109.5 . .
H11 N11 H11B 109.5 . .
H11A N11 H11B 109.5 . .
Pt4 N12 H12C 109.5 . .
Pt4 N12 H12D 109.5 . .
H12C N12 H12D 109.5 . .
Pt4 N12 H12E 109.5 . .
H12C N12 H12E 109.5 . .
H12D N12 H12E 109.5 . .
Pt3 N13 H13C 109.5 . .
Pt3 N13 H13D 109.5 . .
H13C N13 H13D 109.5 . .
Pt3 N13 H13E 109.5 . .
H13C N13 H13E 109.5 . .
H13D N13 H13E 109.5 . .
Pt4 N14 H14C 109.5 . .
Pt4 N14 H14D 109.5 . .
H14C N14 H14D 109.5 . .
Pt4 N14 H14E 109.5 . .
H14C N14 H14E 109.5 . .
H14D N14 H14E 109.5 . .
O18 Cl1 O16 107.2(11) . .
O18 Cl1 O17 112.3(14) . .
O16 Cl1 O17 111.2(12) . .
O18 Cl1 O15 110.2(14) . .
O16 Cl1 O15 108.7(11) . .
O17 Cl1 O15 107.2(11) . .
O20 Cl2 O21 105.8(19) . .
O20 Cl2 O19 107(2) . .
O21 Cl2 O19 114.4(15) . .
O20 Cl2 O22 105.1(13) . .
O21 Cl2 O22 111.2(13) . .
O19 Cl2 O22 112.5(15) . .
O26A Cl3 O24A 129(3) . .
O26A Cl3 O23A 105.3(12) . .
O24A Cl3 O23A 105.0(13) . .
O26A Cl3 O25A 105.2(14) . .
O24A Cl3 O25A 105.5(13) . .
O23A Cl3 O25A 105.0(11) . .
O26A Cl3 O23B 127(3) . .
O24A Cl3 O23B 98(4) . .
O23A Cl3 O23B 30(2) . .
O25A Cl3 O23B 79(2) . .
O26A Cl3 O24B 119(3) . .
O24A Cl3 O24B 22(3) . .
O23A Cl3 O24B 126(3) . .
O25A Cl3 O24B 92(3) . .
O23B Cl3 O24B 113.2(14) . .
O26A Cl3 O25B 52(2) . .
O24A Cl3 O25B 135(3) . .
O23A Cl3 O25B 118(3) . .
O25A Cl3 O25B 53(2) . .
O23B Cl3 O25B 112.5(12) . .
O24B Cl3 O25B 112.9(13) . .
O26A Cl3 O26B 60(3) . .
O24A Cl3 O26B 84(3) . .
O23A Cl3 O26B 83(2) . .
O25A Cl3 O26B 165(2) . .
O23B Cl3 O26B 111.9(13) . .
O24B Cl3 O26B 93(3) . .
O25B Cl3 O26B 111.6(13) . .
O30A Cl4A O27A 109.8(12) . .
O30A Cl4A O29A 110.1(12) . .
O27A Cl4A O29A 109.3(12) . .
O30A Cl4A O28A 109.1(12) . .
O27A Cl4A O28A 109.3(12) . .
O29A Cl4A O28A 109.2(12) . .
O29B Cl4B O27B 110.2(12) . .
O29B Cl4B O28B 110.6(12) . .
O27B Cl4B O28B 109.2(12) . .
O29B Cl4B O30B 108.9(12) . .
O27B Cl4B O30B 108.9(12) . .
O28B Cl4B O30B 109.1(12) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 N2 2.001(19) .
Rh1 N1 2.001(16) .
Rh1 O1 2.007(12) .
Rh1 O2 2.047(15) .
Rh1 Rh1 2.404(3) 2_666
Rh1 Pt1 2.8520(17) .
Pt1 N3 1.995(15) .
Pt1 N5 1.997(13) .
Pt1 O3 2.013(12) .
Pt1 O5 2.027(12) .
Pt1 Pt2 2.9618(13) .
Pt2 O4 1.982(13) .
Pt2 O6 2.012(10) .
Pt2 N6 2.025(12) .
Pt2 N4 2.036(17) .
Pt2 Rh2 2.864(2) .
Rh2 N10 1.988(13) .
Rh2 N9 2.017(16) .
Rh2 O8 2.035(11) .
Rh2 O7 2.047(13) .
Rh2 Rh3 2.407(2) .
Rh3 N7 2.020(16) .
Rh3 N8 2.031(15) .
Rh3 O9 2.060(15) .
Rh3 O10 2.074(11) .
Rh3 Pt3 2.8002(18) .
Pt3 O11 2.009(10) .
Pt3 N11 2.018(14) .
Pt3 N13 2.023(14) .
Pt3 O13 2.036(13) .
Pt3 Pt4 2.9212(13) .
Pt4 N14 2.005(15) .
Pt4 O14 2.009(14) .
Pt4 O12 2.040(13) .
Pt4 N12 2.057(12) .
Pt4 Pt4 3.2089(16) 2_857
O1 C1 1.32(2) .
C1 N1 1.29(2) 2_666
C1 C2 1.50(3) .
C2 H2 0.9600 .
C2 H2A 0.9600 .
C2 H2B 0.9600 .
N1 C1 1.29(2) 2_666
N1 H1 0.8600 .
O2 C3 1.28(2) .
C3 N2 1.29(2) 2_666
C3 C4 1.52(3) .
C4 H4 0.9600 .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
N2 C3 1.29(2) 2_666
N2 H2C 0.8600 .
O3 C5 1.267(18) .
C5 O4 1.266(18) .
C5 C6 1.51(2) .
C6 C8 1.49(3) .
C6 C7 1.52(2) .
C6 C9 1.57(3) .
C7 H7 0.9600 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C8 H8 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C9 H9 0.9600 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
O5 C10 1.27(2) .
C10 O6 1.268(18) .
C10 C11 1.48(3) .
C11 C12 1.51(2) .
C11 C13 1.54(3) .
C11 C14 1.60(4) .
C12 H12 0.9600 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C13 H13 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C14 H14 0.9600 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
N3 H3 0.8900 .
N3 H3A 0.8900 .
N3 H3B 0.8900 .
N4 H4C 0.8900 .
N4 H4D 0.8900 .
N4 H4E 0.8900 .
N5 H5 0.8900 .
N5 H5A 0.8900 .
N5 H5B 0.8900 .
N6 H6 0.8900 .
N6 H6A 0.8900 .
N6 H6B 0.8900 .
O7 C15 1.31(3) .
C15 N7 1.26(2) .
C15 C16 1.53(3) .
C16 H16 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
N7 H7C 0.8600 .
O8 C17 1.339(17) .
C17 N8 1.24(2) .
C17 C18 1.52(2) .
C18 H18 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
N8 H8C 0.8600 .
O9 C19 1.30(2) .
C19 N9 1.29(3) .
C19 C20 1.45(3) .
C20 H20 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
N9 H9C 0.8600 .
O10 C21 1.34(2) .
C21 N10 1.29(2) .
C21 C22 1.51(2) .
C22 H22 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
N10 H10 0.8600 .
O11 C23 1.22(2) .
C23 O12 1.319(19) .
C23 C24 1.55(3) .
C24 C26 1.44(3) .
C24 C27 1.50(4) .
C24 C25 1.52(3) .
C25 H25 0.9600 .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C26 H26 0.9600 .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C27 H27 0.9600 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
O13 C28 1.25(2) .
C28 O14 1.24(2) .
C28 C29 1.64(3) .
C29 C32 1.52(3) .
C29 C31 1.52(3) .
C29 C30 1.57(4) .
C30 H30 0.9600 .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C31 H31 0.9600 .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C32 H32 0.9600 .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
N11 H11 0.8900 .
N11 H11A 0.8900 .
N11 H11B 0.8900 .
N12 H12C 0.8900 .
N12 H12D 0.8900 .
N12 H12E 0.8900 .
N13 H13C 0.8900 .
N13 H13D 0.8900 .
N13 H13E 0.8900 .
N14 H14C 0.8900 .
N14 H14D 0.8900 .
N14 H14E 0.8900 .
Cl1 O18 1.41(2) .
Cl1 O16 1.421(13) .
Cl1 O17 1.429(16) .
Cl1 O15 1.434(17) .
Cl2 O20 1.37(3) .
Cl2 O21 1.37(2) .
Cl2 O19 1.38(2) .
Cl2 O22 1.437(16) .
Cl3 O26A 1.42(2) .
Cl3 O24A 1.42(2) .
Cl3 O23A 1.43(2) .
Cl3 O25A 1.43(2) .
Cl3 O23B 1.45(5) .
Cl3 O24B 1.45(5) .
Cl3 O25B 1.46(5) .
Cl3 O26B 1.47(5) .
Cl4A O30A 1.40(3) .
Cl4A O27A 1.41(3) .
Cl4A O29A 1.41(3) .
Cl4A O28A 1.41(3) .
Cl4B O29B 1.41(3) .
Cl4B O27B 1.42(3) .
Cl4B O28B 1.42(3) .
Cl4B O30B 1.43(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Rh1 Pt1 N3 152.6(8) . .
N1 Rh1 Pt1 N3 65.3(8) . .
O1 Rh1 Pt1 N3 -116.0(6) . .
O2 Rh1 Pt1 N3 -29.0(7) . .
Rh1 Rh1 Pt1 N3 -12(2) 2_666 .
N2 Rh1 Pt1 N5 -115.4(8) . .
N1 Rh1 Pt1 N5 157.2(8) . .
O1 Rh1 Pt1 N5 -24.1(6) . .
O2 Rh1 Pt1 N5 62.9(7) . .
Rh1 Rh1 Pt1 N5 80(2) 2_666 .
N2 Rh1 Pt1 O3 -27.0(8) . .
N1 Rh1 Pt1 O3 -114.4(7) . .
O1 Rh1 Pt1 O3 64.3(5) . .
O2 Rh1 Pt1 O3 151.3(6) . .
Rh1 Rh1 Pt1 O3 168(2) 2_666 .
N2 Rh1 Pt1 O5 63.8(8) . .
N1 Rh1 Pt1 O5 -23.5(7) . .
O1 Rh1 Pt1 O5 155.2(6) . .
O2 Rh1 Pt1 O5 -117.8(7) . .
Rh1 Rh1 Pt1 O5 -101(2) 2_666 .
N2 Rh1 Pt1 Pt2 13.3(7) . .
N1 Rh1 Pt1 Pt2 -74.0(7) . .
O1 Rh1 Pt1 Pt2 104.7(5) . .
O2 Rh1 Pt1 Pt2 -168.3(5) . .
Rh1 Rh1 Pt1 Pt2 -152(2) 2_666 .
N3 Pt1 Pt2 O4 174.0(6) . .
N5 Pt1 Pt2 O4 79.1(6) . .
O3 Pt1 Pt2 O4 -7.1(5) . .
O5 Pt1 Pt2 O4 -99.5(5) . .
Rh1 Pt1 Pt2 O4 -48.2(4) . .
N3 Pt1 Pt2 O6 -93.0(6) . .
N5 Pt1 Pt2 O6 172.2(6) . .
O3 Pt1 Pt2 O6 85.9(5) . .
O5 Pt1 Pt2 O6 -6.5(6) . .
Rh1 Pt1 Pt2 O6 44.9(5) . .
N3 Pt1 Pt2 N6 87.7(7) . .
N5 Pt1 Pt2 N6 -7.2(7) . .
O3 Pt1 Pt2 N6 -93.4(6) . .
O5 Pt1 Pt2 N6 174.2(7) . .
Rh1 Pt1 Pt2 N6 -134.5(6) . .
N3 Pt1 Pt2 N4 -8.6(7) . .
N5 Pt1 Pt2 N4 -103.4(7) . .
O3 Pt1 Pt2 N4 170.3(6) . .
O5 Pt1 Pt2 N4 77.9(7) . .
Rh1 Pt1 Pt2 N4 129.2(6) . .
N3 Pt1 Pt2 Rh2 -128.6(5) . .
N5 Pt1 Pt2 Rh2 136.6(5) . .
O3 Pt1 Pt2 Rh2 50.3(4) . .
O5 Pt1 Pt2 Rh2 -42.1(4) . .
Rh1 Pt1 Pt2 Rh2 9.3(3) . .
O4 Pt2 Rh2 N10 61.8(6) . .
O6 Pt2 Rh2 N10 -29.0(7) . .
N6 Pt2 Rh2 N10 151.9(7) . .
N4 Pt2 Rh2 N10 -117.7(7) . .
Pt1 Pt2 Rh2 N10 6.1(5) . .
O4 Pt2 Rh2 N9 -29.7(5) . .
O6 Pt2 Rh2 N9 -120.5(6) . .
N6 Pt2 Rh2 N9 60.4(7) . .
N4 Pt2 Rh2 N9 150.8(6) . .
Pt1 Pt2 Rh2 N9 -85.5(5) . .
O4 Pt2 Rh2 O8 -118.1(6) . .
O6 Pt2 Rh2 O8 151.1(6) . .
N6 Pt2 Rh2 O8 -28.0(6) . .
N4 Pt2 Rh2 O8 62.4(6) . .
Pt1 Pt2 Rh2 O8 -173.9(5) . .
O4 Pt2 Rh2 O7 150.7(6) . .
O6 Pt2 Rh2 O7 59.9(6) . .
N6 Pt2 Rh2 O7 -119.2(7) . .
N4 Pt2 Rh2 O7 -28.8(7) . .
Pt1 Pt2 Rh2 O7 94.9(5) . .
O4 Pt2 Rh2 Rh3 -120.6(9) . .
O6 Pt2 Rh2 Rh3 148.5(9) . .
N6 Pt2 Rh2 Rh3 -30.5(10) . .
N4 Pt2 Rh2 Rh3 59.9(10) . .
Pt1 Pt2 Rh2 Rh3 -176.4(8) . .
N10 Rh2 Rh3 N7 84.5(7) . .
N9 Rh2 Rh3 N7 175.5(6) . .
O8 Rh2 Rh3 N7 -95.6(6) . .
O7 Rh2 Rh3 N7 -4.4(6) . .
Pt2 Rh2 Rh3 N7 -93.1(10) . .
N10 Rh2 Rh3 N8 179.5(6) . .
N9 Rh2 Rh3 N8 -89.4(6) . .
O8 Rh2 Rh3 N8 -0.6(6) . .
O7 Rh2 Rh3 N8 90.7(6) . .
Pt2 Rh2 Rh3 N8 1.9(10) . .
N10 Rh2 Rh3 O9 -92.5(6) . .
N9 Rh2 Rh3 O9 -1.4(6) . .
O8 Rh2 Rh3 O9 87.4(6) . .
O7 Rh2 Rh3 O9 178.7(5) . .
Pt2 Rh2 Rh3 O9 89.9(9) . .
N10 Rh2 Rh3 O10 -3.1(6) . .
N9 Rh2 Rh3 O10 87.9(6) . .
O8 Rh2 Rh3 O10 176.8(6) . .
O7 Rh2 Rh3 O10 -92.0(6) . .
Pt2 Rh2 Rh3 O10 179(100) . .
N10 Rh2 Rh3 Pt3 -140(2) . .
N9 Rh2 Rh3 Pt3 -49(2) . .
O8 Rh2 Rh3 Pt3 40(2) . .
O7 Rh2 Rh3 Pt3 131(2) . .
Pt2 Rh2 Rh3 Pt3 42(3) . .
N7 Rh3 Pt3 O11 -29.6(6) . .
N8 Rh3 Pt3 O11 -124.6(6) . .
O9 Rh3 Pt3 O11 147.5(5) . .
O10 Rh3 Pt3 O11 58.2(6) . .
Rh2 Rh3 Pt3 O11 -165(2) . .
N7 Rh3 Pt3 N11 151.7(6) . .
N8 Rh3 Pt3 N11 56.7(6) . .
O9 Rh3 Pt3 N11 -31.3(5) . .
O10 Rh3 Pt3 N11 -120.5(6) . .
Rh2 Rh3 Pt3 N11 17(2) . .
N7 Rh3 Pt3 N13 -118.1(6) . .
N8 Rh3 Pt3 N13 146.9(6) . .
O9 Rh3 Pt3 N13 59.0(6) . .
O10 Rh3 Pt3 N13 -30.3(6) . .
Rh2 Rh3 Pt3 N13 107(2) . .
N7 Rh3 Pt3 O13 61.0(6) . .
N8 Rh3 Pt3 O13 -34.0(6) . .
O9 Rh3 Pt3 O13 -122.0(5) . .
O10 Rh3 Pt3 O13 148.7(6) . .
Rh2 Rh3 Pt3 O13 -74(2) . .
N7 Rh3 Pt3 Pt4 35.9(5) . .
N8 Rh3 Pt3 Pt4 -59.2(5) . .
O9 Rh3 Pt3 Pt4 -147.1(4) . .
O10 Rh3 Pt3 Pt4 123.6(4) . .
Rh2 Rh3 Pt3 Pt4 -99(2) . .
O11 Pt3 Pt4 N14 -97.7(7) . .
N11 Pt3 Pt4 N14 81.6(7) . .
N13 Pt3 Pt4 N14 -12.8(7) . .
O13 Pt3 Pt4 N14 169.3(7) . .
Rh3 Pt3 Pt4 N14 -164.9(6) . .
O11 Pt3 Pt4 O14 80.2(6) . .
N11 Pt3 Pt4 O14 -100.5(6) . .
N13 Pt3 Pt4 O14 165.2(7) . .
O13 Pt3 Pt4 O14 -12.7(6) . .
Rh3 Pt3 Pt4 O14 13.0(5) . .
O11 Pt3 Pt4 O12 -9.7(6) . .
N11 Pt3 Pt4 O12 169.7(6) . .
N13 Pt3 Pt4 O12 75.3(6) . .
O13 Pt3 Pt4 O12 -102.6(6) . .
Rh3 Pt3 Pt4 O12 -76.9(5) . .
O11 Pt3 Pt4 N12 167.7(6) . .
N11 Pt3 Pt4 N12 -13.0(7) . .
N13 Pt3 Pt4 N12 -107.4(7) . .
O13 Pt3 Pt4 N12 74.7(6) . .
Rh3 Pt3 Pt4 N12 100.5(5) . .
O11 Pt3 Pt4 Pt4 49.2(4) . 2_857
N11 Pt3 Pt4 Pt4 -131.5(4) . 2_857
N13 Pt3 Pt4 Pt4 134.2(5) . 2_857
O13 Pt3 Pt4 Pt4 -43.7(4) . 2_857
Rh3 Pt3 Pt4 Pt4 -18.0(3) . 2_857
N2 Rh1 O1 C1 -88.8(17) . .
N1 Rh1 O1 C1 -24(11) . .
O2 Rh1 O1 C1 87.0(17) . .
Rh1 Rh1 O1 C1 -2.2(17) 2_666 .
Pt1 Rh1 O1 C1 174.9(17) . .
Rh1 O1 C1 N1 2(3) . 2_666
Rh1 O1 C1 C2 -168.5(19) . .
N2 Rh1 N1 C1 88(2) . 2_666
O1 Rh1 N1 C1 23(12) . 2_666
O2 Rh1 N1 C1 -88(2) . 2_666
Rh1 Rh1 N1 C1 1(2) 2_666 2_666
Pt1 Rh1 N1 C1 -176(2) . 2_666
N2 Rh1 O2 C3 -25(11) . .
N1 Rh1 O2 C3 83(2) . .
O1 Rh1 O2 C3 -93(2) . .
Rh1 Rh1 O2 C3 -3.6(19) 2_666 .
Pt1 Rh1 O2 C3 176(2) . .
Rh1 O2 C3 N2 4(4) . 2_666
Rh1 O2 C3 C4 174(2) . .
N1 Rh1 N2 C3 -86(2) . 2_666
O1 Rh1 N2 C3 90(2) . 2_666
O2 Rh1 N2 C3 22(11) . 2_666
Rh1 Rh1 N2 C3 0(2) 2_666 2_666
Pt1 Rh1 N2 C3 -179(2) . 2_666
N3 Pt1 O3 C5 179(75) . .
N5 Pt1 O3 C5 -92.7(14) . .
O5 Pt1 O3 C5 91.1(14) . .
Rh1 Pt1 O3 C5 -177.1(13) . .
Pt2 Pt1 O3 C5 10.4(13) . .
Pt1 O3 C5 O4 -9(2) . .
Pt1 O3 C5 C6 179.0(12) . .
O4 C5 C6 C8 70(2) . .
O3 C5 C6 C8 -118(2) . .
O4 C5 C6 C7 -165.8(19) . .
O3 C5 C6 C7 7(3) . .
O4 C5 C6 C9 -50(2) . .
O3 C5 C6 C9 122.8(18) . .
O3 C5 O4 Pt2 -2(3) . .
C6 C5 O4 Pt2 169.7(12) . .
O6 Pt2 O4 C5 -70.7(15) . .
N6 Pt2 O4 C5 116.2(15) . .
N4 Pt2 O4 C5 -149(5) . .
Rh2 Pt2 O4 C5 -153.8(14) . .
Pt1 Pt2 O4 C5 7.5(14) . .
N3 Pt1 O5 C10 112.8(16) . .
N5 Pt1 O5 C10 -153(8) . .
O3 Pt1 O5 C10 -72.6(16) . .
Rh1 Pt1 O5 C10 -163.4(16) . .
Pt2 Pt1 O5 C10 7.6(15) . .
Pt1 O5 C10 O6 -4(3) . .
Pt1 O5 C10 C11 176.7(14) . .
O6 C10 C11 C12 -160(2) . .
O5 C10 C11 C12 19(3) . .
O6 C10 C11 C13 78(2) . .
O5 C10 C11 C13 -103(2) . .
O6 C10 C11 C14 -36(3) . .
O5 C10 C11 C14 143(2) . .
O5 C10 O6 Pt2 -7(3) . .
C11 C10 O6 Pt2 172.7(15) . .
O4 Pt2 O6 C10 87.2(17) . .
N6 Pt2 O6 C10 -176(5) . .
N4 Pt2 O6 C10 -98.9(17) . .
Rh2 Pt2 O6 C10 176.0(17) . .
Pt1 Pt2 O6 C10 9.0(16) . .
N10 Rh2 O7 C15 -74.2(15) . .
N9 Rh2 O7 C15 10(8) . .
O8 Rh2 O7 C15 101.8(15) . .
Rh3 Rh2 O7 C15 11.4(14) . .
Pt2 Rh2 O7 C15 -174.1(14) . .
Rh2 O7 C15 N7 -17(3) . .
Rh2 O7 C15 C16 163.8(15) . .
O7 C15 N7 Rh3 12(3) . .
C16 C15 N7 Rh3 -168.4(16) . .
N8 Rh3 N7 C15 -87.4(17) . .
O9 Rh3 N7 C15 44(9) . .
O10 Rh3 N7 C15 88.3(17) . .
Rh2 Rh3 N7 C15 -1.7(17) . .
Pt3 Rh3 N7 C15 179.9(17) . .
N10 Rh2 O8 C17 0(10) . .
N9 Rh2 O8 C17 84.7(13) . .
O7 Rh2 O8 C17 -90.3(13) . .
Rh3 Rh2 O8 C17 -0.9(12) . .
Pt2 Rh2 O8 C17 179.4(13) . .
Rh2 O8 C17 N8 3(2) . .
Rh2 O8 C17 C18 -173.1(14) . .
O8 C17 N8 Rh3 -4(3) . .
C18 C17 N8 Rh3 171.9(15) . .
N7 Rh3 N8 C17 88.8(16) . .
O9 Rh3 N8 C17 -88.0(16) . .
O10 Rh3 N8 C17 -30(8) . .
Rh2 Rh3 N8 C17 2.5(15) . .
Pt3 Rh3 N8 C17 -176.0(15) . .
N7 Rh3 O9 C19 -43(9) . .
N8 Rh3 O9 C19 88.4(15) . .
O10 Rh3 O9 C19 -87.4(14) . .
Rh2 Rh3 O9 C19 2.5(14) . .
Pt3 Rh3 O9 C19 -179.2(14) . .
Rh3 O9 C19 N9 -3(3) . .
Rh3 O9 C19 C20 179.8(16) . .
O9 C19 N9 Rh2 1(3) . .
C20 C19 N9 Rh2 178.4(17) . .
N10 Rh2 N9 C19 86.4(18) . .
O8 Rh2 N9 C19 -89.6(17) . .
O7 Rh2 N9 C19 2(8) . .
Rh3 Rh2 N9 C19 0.9(17) . .
Pt2 Rh2 N9 C19 -173.5(17) . .
N7 Rh3 O10 C21 -80.6(15) . .
N8 Rh3 O10 C21 39(7) . .
O9 Rh3 O10 C21 96.5(15) . .
Rh2 Rh3 O10 C21 6.1(15) . .
Pt3 Rh3 O10 C21 -175.5(14) . .
Rh3 O10 C21 N10 -7(3) . .
Rh3 O10 C21 C22 170.9(16) . .
O10 C21 N10 Rh2 3(3) . .
C22 C21 N10 Rh2 -174.1(18) . .
N9 Rh2 N10 C21 -84(2) . .
O8 Rh2 N10 C21 0(11) . .
O7 Rh2 N10 C21 91(2) . .
Rh3 Rh2 N10 C21 1(2) . .
Pt2 Rh2 N10 C21 -178.9(19) . .
N11 Pt3 O11 C23 -149(12) . .
N13 Pt3 O11 C23 -95.2(15) . .
O13 Pt3 O11 C23 93.3(15) . .
Rh3 Pt3 O11 C23 -179.2(15) . .
Pt4 Pt3 O11 C23 15.8(14) . .
Pt3 O11 C23 O12 -14(3) . .
Pt3 O11 C23 C24 170.2(16) . .
O11 C23 C24 C26 -163(2) . .
O12 C23 C24 C26 21(3) . .
O11 C23 C24 C27 73(3) . .
O12 C23 C24 C27 -103(2) . .
O11 C23 C24 C25 -38(3) . .
O12 C23 C24 C25 146(2) . .
O11 C23 O12 Pt4 -2(3) . .
C24 C23 O12 Pt4 174.3(15) . .
N14 Pt4 O12 C23 111.3(15) . .
O14 Pt4 O12 C23 -73.0(15) . .
N12 Pt4 O12 C23 -138(7) . .
Pt3 Pt4 O12 C23 9.3(14) . .
Pt4 Pt4 O12 C23 -157.8(15) 2_857 .
O11 Pt3 O13 C28 -61.3(18) . .
N11 Pt3 O13 C28 120.9(18) . .
N13 Pt3 O13 C28 -148(4) . .
Rh3 Pt3 O13 C28 -154.8(17) . .
Pt4 Pt3 O13 C28 18.2(17) . .
Pt3 O13 C28 O14 -16(4) . .
Pt3 O13 C28 C29 155.3(15) . .
O14 C28 C29 C32 -157(2) . .
O13 C28 C29 C32 30(3) . .
O14 C28 C29 C31 -34(3) . .
O13 C28 C29 C31 153(2) . .
O14 C28 C29 C30 82(2) . .
O13 C28 C29 C30 -91(2) . .
O13 C28 O14 Pt4 -3(4) . .
C29 C28 O14 Pt4 -174.5(15) . .
N14 Pt4 O14 C28 166(7) . .
O12 Pt4 O14 C28 92.9(18) . .
N12 Pt4 O14 C28 -91.6(18) . .
Pt3 Pt4 O14 C28 12.6(18) . .
Pt4 Pt4 O14 C28 -175.1(18) 2_857 .
