#------------------------------------------------------------------------------
#$Date: 2017-04-05 12:53:55 +0300 (Wed, 05 Apr 2017) $
#$Revision: 195111 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/19/7041982.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7041982
loop_
_publ_author_name
'Ma, Huili'
'Wang, Lu'
'Chen, Jinghuo'
'Zhang, Xuejing'
'Wang, Liang'
'Xu, Na'
'Yang, Guangming'
'Cheng, Peng'
_publ_section_title
;
 A multi-responsive luminescent sensor for organic small-molecule
 pollutants and metal ions based on a 4d-4f metal-organic framework.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3526
_journal_page_last               3534
_journal_paper_doi               10.1039/c7dt00159b
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C62 H44 Ag3 N10 O31 Tb3'
_chemical_formula_sum            'C62 H44 Ag3 N10 O31 Tb3'
_chemical_formula_weight         2225.44
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2016-07-26
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_audit_update_record
;
2017-02-07 deposited with the CCDC.
2017-02-08 downloaded from the CCDC.
;
_cell_angle_alpha                103.9950(10)
_cell_angle_beta                 102.1540(10)
_cell_angle_gamma                91.6670(10)
_cell_formula_units_Z            2
_cell_length_a                   12.6918(4)
_cell_length_b                   12.9749(4)
_cell_length_c                   23.5138(7)
_cell_measurement_reflns_used    9935
_cell_measurement_temperature    120
_cell_measurement_theta_max      27.535
_cell_measurement_theta_min      3.248
_cell_volume                     3659.9(2)
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_diffrn_ambient_temperature      120
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0759
_diffrn_reflns_av_unetI/netI     0.0636
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            56163
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.82
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    3.739
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5880
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0973 before and 0.0715 after correction.
The Ratio of minimum to maximum transmission is 0.7886.
The λ/2 correction factor is 0.00150.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.019
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2140
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.654
_refine_diff_density_min         -1.265
_refine_diff_density_rms         0.158
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     989
_refine_ls_number_reflns         12867
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0644
_refine_ls_R_factor_gt           0.0412
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0383P)²+2.4810P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0858
_refine_ls_wR_factor_ref         0.0925
_reflns_number_gt                9578
_reflns_number_total             12867
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7dt00159b2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7041981--7041982.cif.'
_cod_original_cell_volume        3659.89(19)
_cod_database_code               7041982
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2.a Rotating group:
 O31(H31A,H31B), O25(H25A,H25B), O30(H30A,H30B), O27(H27A,H27B), O29(H29A,
 H29B), O26(H26A,H26B), O28(H28A,H28B)
2.b Aromatic/amide H refined with riding coordinates:
 C34(H34), C20(H20), C40(H40), C56(H56), C53(H53), C16(H16), C3(H3), C57(H57),
 C52(H52), C21(H21), C22(H22), C9(H9), C32(H32), C28(H28), C45(H45), C29(H29),
 C46(H46), C27(H27), C58(H58), C4(H4), C51(H51), C33(H33), C44(H44), C39(H39),
 C41(H41), C17(H17), C5(H5), C10(H10), C15(H15), C8(H8)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Tb1 Tb 0.33425(3) 0.61005(3) 0.411727(15) 0.01960(9) Uani 1 d .
Tb3 Tb -0.45654(3) 1.24027(3) 0.014722(16) 0.02002(9) Uani 1 d .
Tb2 Tb 0.29563(3) 1.11162(3) 0.389041(18) 0.02776(10) Uani 1 d .
Ag3 Ag -0.16724(4) 0.81944(4) 0.18707(2) 0.01863(13) Uani 1 d .
Ag2 Ag -0.06870(4) 0.56582(4) 0.23174(2) 0.02061(13) Uani 1 d .
Ag1 Ag 0.17366(5) 0.76352(5) 0.77252(3) 0.02842(15) Uani 1 d .
O12 O 0.2824(4) 0.9930(4) 0.2862(3) 0.0364(14) Uani 1 d .
O2 O 0.4716(7) 0.8860(6) 0.6465(3) 0.068(3) Uani 1 d .
O24 O 0.6497(4) 0.7148(4) 0.5415(2) 0.0228(11) Uani 1 d .
O31 O -0.5747(4) 1.3095(4) 0.0811(2) 0.0264(12) Uani 1 d .
H31A H -0.5870 1.3750 0.0794 0.040 Uiso 1 d GR
H31B H -0.5440 1.3097 0.1182 0.040 Uiso 1 d GR
O5 O 0.1545(5) 0.2223(4) 0.3839(3) 0.053(2) Uani 1 d .
O1 O 0.6070(6) 0.7826(5) 0.6531(3) 0.074(3) Uani 1 d .
O25 O 0.2766(4) 0.4857(4) 0.4643(2) 0.0217(11) Uani 1 d .
H25A H 0.3094 0.4264 0.4563 0.033 Uiso 1 d GR
H25B H 0.2059 0.4696 0.4525 0.033 Uiso 1 d GR
O18 O -0.3780(4) 0.8634(4) 0.0436(2) 0.0184(11) Uani 1 d .
O30 O -0.3900(4) 1.0836(4) -0.0351(2) 0.0255(12) Uani 1 d .
H30A H -0.3432 1.1002 -0.0547 0.038 Uiso 1 d GR
H30B H -0.4436 1.0419 -0.0606 0.038 Uiso 1 d GR
O3 O 0.3472(4) 0.6101(4) 0.5787(2) 0.0298(13) Uani 1 d .
O27 O 0.4386(4) 0.6307(4) 0.3380(2) 0.0224(11) Uani 1 d .
H27A H 0.4419 0.6993 0.3343 0.034 Uiso 1 d GR
H27B H 0.4082 0.5878 0.3008 0.034 Uiso 1 d GR
O19 O -0.4950(4) 1.1051(4) 0.0642(2) 0.0208(11) Uani 1 d .
O4 O 0.3218(4) 0.7113(4) 0.5131(2) 0.0278(12) Uani 1 d .
O11 O 0.1418(4) 0.9805(4) 0.3264(2) 0.0241(12) Uani 1 d .
O23 O 0.5529(4) 0.8902(4) 0.5264(2) 0.0205(11) Uani 1 d .
O10 O 0.2301(4) 0.7337(4) 0.3549(2) 0.0204(11) Uani 1 d .
O6 O 0.1432(6) 0.2164(5) 0.2866(4) 0.065(2) Uani 1 d .
O14 O -0.3696(4) 0.4112(4) 0.0744(2) 0.0209(11) Uani 1 d .
O13 O -0.2690(4) 0.3165(4) 0.0186(2) 0.0213(11) Uani 1 d .
O20 O -0.3314(4) 1.1870(4) 0.1050(2) 0.0214(11) Uani 1 d .
O21 O 0.5137(4) 0.6140(4) 0.4726(2) 0.0217(11) Uani 1 d .
O8 O 0.3027(4) 0.5036(4) 0.2450(2) 0.0352(14) Uani 1 d .
O29 O 0.2099(5) 1.0940(5) 0.4711(3) 0.0445(16) Uani 1 d .
H29A H 0.2208 1.0385 0.4928 0.067 Uiso 1 d GR
H29B H 0.1590 1.1412 0.4874 0.067 Uiso 1 d GR
O15 O -0.5393(4) 0.7083(5) 0.0793(2) 0.0303(13) Uani 1 d .
O17 O -0.2695(4) 0.8385(4) -0.0214(2) 0.0265(12) Uani 1 d .
O9 O 0.1449(4) 0.6580(4) 0.4094(2) 0.0259(12) Uani 1 d .
O26 O 0.4265(4) 0.4453(4) 0.3870(2) 0.0225(11) Uani 1 d .
H26A H 0.3811 0.3882 0.3809 0.034 Uiso 1 d GR
H26B H 0.4820 0.4445 0.4170 0.034 Uiso 1 d GR
O7 O 0.2273(4) 0.4939(4) 0.3215(2) 0.0227(11) Uani 1 d .
O22 O 0.4372(4) 0.7909(4) 0.4453(2) 0.0222(11) Uani 1 d .
O28 O 0.3273(5) 0.9338(5) 0.3977(4) 0.063(2) Uani 1 d .
H28A H 0.3550 0.9344 0.4359 0.095 Uiso 1 d GR
H28B H 0.3737 0.9064 0.3757 0.095 Uiso 1 d GR
O16 O -0.4124(4) 0.6416(4) 0.0345(2) 0.0203(11) Uani 1 d .
N4 N -0.0401(5) 0.3076(5) 0.1969(3) 0.0231(14) Uani 1 d .
N7 N -0.2461(4) 0.5813(4) 0.1984(2) 0.0146(12) Uani 1 d .
N3 N -0.0400(4) 0.4823(5) 0.3061(2) 0.0177(13) Uani 1 d .
N6 N -0.0749(5) 0.8357(5) 0.2819(2) 0.0209(14) Uani 1 d .
N8 N -0.1618(5) 0.6866(5) 0.1084(3) 0.0195(13) Uani 1 d .
N5 N 0.0600(5) 0.6688(5) 0.2152(3) 0.0211(14) Uani 1 d .
N2 N 0.2010(5) 0.8398(5) 0.6924(3) 0.0288(15) Uani 1 d .
N10 N -0.1270(5) 1.0503(5) 0.1782(3) 0.0234(14) Uani 1 d .
N1 N 0.3240(5) 0.7020(5) 0.7424(3) 0.0232(14) Uani 1 d .
N9 N -0.3088(5) 0.9228(4) 0.1926(3) 0.0203(13) Uani 1 d .
C12 C 0.3138(6) 0.6903(6) 0.5617(3) 0.0231(17) Uani 1 d .
C55 C -0.2101(6) 0.9975(5) 0.1345(3) 0.0187(15) Uani 1 d .
C25 C 0.1473(6) 0.7154(5) 0.3739(3) 0.0198(16) Uani 1 d .
C34 C 0.2087(6) 0.8092(6) 0.1960(3) 0.0256(17) Uani 1 d .
H34 H 0.2592 0.8576 0.1891 0.031 Uiso 1 calc R
C20 C -0.0336(6) 0.2784(6) 0.1389(3) 0.0273(18) Uani 1 d .
H20 H -0.0942 0.2393 0.1098 0.033 Uiso 1 calc R
C18 C 0.0217(6) 0.3983(5) 0.2997(3) 0.0188(16) Uani 1 d .
C7 C 0.2684(6) 0.7840(6) 0.6625(4) 0.0259(17) Uani 1 d .
C43 C -0.2930(5) 0.6038(5) 0.1466(3) 0.0150(14) Uani 1 d .
C40 C -0.0898(6) 0.5982(6) 0.0255(3) 0.0238(17) Uani 1 d .
H40 H -0.0450 0.6019 -0.0017 0.029 Uiso 1 calc R
C56 C -0.0287(6) 1.0524(6) 0.1647(4) 0.0286(19) Uani 1 d .
H56 H 0.0314 1.0875 0.1956 0.034 Uiso 1 calc R
C53 C -0.3918(6) 0.9161(6) 0.2192(3) 0.0229(16) Uani 1 d .
H53 H -0.3902 0.8680 0.2440 0.028 Uiso 1 calc R
C16 C -0.0520(6) 0.4615(6) 0.4027(3) 0.0263(18) Uani 1 d .
H16 H -0.0805 0.4835 0.4376 0.032 Uiso 1 calc R
C3 C 0.5376(7) 0.7010(6) 0.7363(3) 0.0302(19) Uani 1 d .
H3 H 0.6116 0.7002 0.7343 0.036 Uiso 1 calc R
C49 C -0.4056(6) 1.1200(5) 0.1034(3) 0.0193(16) Uani 1 d .
C57 C -0.0109(6) 1.0060(6) 0.1084(4) 0.0286(18) Uani 1 d .
H57 H 0.0591 1.0112 0.1005 0.034 Uiso 1 calc R
C52 C -0.4788(6) 0.9760(6) 0.2120(3) 0.0223(16) Uani 1 d .
H52 H -0.5352 0.9711 0.2324 0.027 Uiso 1 calc R
C21 C 0.0581(6) 0.3030(6) 0.1201(4) 0.0291(19) Uani 1 d .
H21 H 0.0619 0.2786 0.0791 0.035 Uiso 1 calc R
C50 C -0.3977(5) 1.0532(5) 0.1473(3) 0.0169(15) Uani 1 d .
C19 C 0.0438(6) 0.3652(5) 0.2377(3) 0.0209(16) Uani 1 d .
C35 C 0.1585(6) 0.8396(6) 0.2436(3) 0.0213(16) Uani 1 d .
C22 C 0.1454(6) 0.3649(6) 0.1628(4) 0.0291(19) Uani 1 d .
H22 H 0.2091 0.3831 0.1510 0.035 Uiso 1 calc R
C9 C 0.0989(7) 0.8687(6) 0.6010(4) 0.034(2) Uani 1 d .
H9 H 0.0413 0.9013 0.5811 0.041 Uiso 1 calc R
C6 C 0.3585(6) 0.7438(5) 0.7010(3) 0.0233(17) Uani 1 d .
C62 C 0.5129(6) 0.8030(6) 0.4908(3) 0.0203(16) Uani 1 d .
C47 C -0.3974(6) 0.6393(5) 0.1373(3) 0.0174(15) Uani 1 d .
C32 C 0.1105(6) 0.6397(6) 0.1697(3) 0.0247(17) Uani 1 d .
H32 H 0.0940 0.5696 0.1442 0.030 Uiso 1 calc R
C28 C -0.1163(6) 0.8365(6) 0.3771(3) 0.0244(17) Uani 1 d .
H28 H -0.1635 0.8539 0.4039 0.029 Uiso 1 calc R
C45 C -0.4050(6) 0.6235(6) 0.2354(4) 0.0299(19) Uani 1 d .
H45 H -0.4423 0.6281 0.2668 0.036 Uiso 1 calc R
C29 C -0.1389(6) 0.8591(6) 0.3221(3) 0.0239(17) Uani 1 d .
H29 H -0.2028 0.8931 0.3115 0.029 Uiso 1 calc R
C46 C -0.4533(6) 0.6505(6) 0.1832(3) 0.0279(18) Uani 1 d .
H46 H -0.5231 0.6762 0.1787 0.033 Uiso 1 calc R
C13 C 0.1225(7) 0.2537(6) 0.3357(5) 0.037(2) Uani 1 d .
C27 C -0.0246(6) 0.7883(6) 0.3925(3) 0.0234(17) Uani 1 d .
H27 H -0.0084 0.7692 0.4298 0.028 Uiso 1 calc R
C54 C -0.3127(6) 0.9907(5) 0.1575(3) 0.0186(16) Uani 1 d .
C58 C -0.0969(6) 0.9525(6) 0.0645(3) 0.0236(17) Uani 1 d .
H58 H -0.0866 0.9196 0.0255 0.028 Uiso 1 calc R
C4 C 0.5022(6) 0.6540(7) 0.7756(3) 0.0312(19) Uani 1 d .
H4 H 0.5496 0.6186 0.8001 0.037 Uiso 1 calc R
C42 C -0.2237(5) 0.5966(6) 0.1025(3) 0.0182(15) Uani 1 d .
C38 C -0.2169(6) 0.5027(5) 0.0597(3) 0.0203(16) Uani 1 d .
C51 C -0.4824(6) 1.0438(6) 0.1742(3) 0.0205(16) Uani 1 d .
H51 H -0.5433 1.0836 0.1670 0.025 Uiso 1 calc R
C33 C 0.1842(6) 0.7061(6) 0.1583(3) 0.0279(18) Uani 1 d .
H33 H 0.2181 0.6829 0.1255 0.033 Uiso 1 calc R
C44 C -0.3011(6) 0.5895(6) 0.2415(3) 0.0242(17) Uani 1 d .
H44 H -0.2683 0.5715 0.2777 0.029 Uiso 1 calc R
C24 C 0.2316(6) 0.4703(6) 0.2669(4) 0.0263(18) Uani 1 d .
C11 C 0.2498(6) 0.7651(6) 0.5994(3) 0.0266(18) Uani 1 d .
C39 C -0.1481(6) 0.5049(6) 0.0207(3) 0.0227(17) Uani 1 d .
H39 H -0.1419 0.4424 -0.0089 0.027 Uiso 1 calc R
C61 C 0.5629(6) 0.7023(6) 0.5028(3) 0.0185(15) Uani 1 d .
C37 C -0.2883(5) 0.4040(5) 0.0517(3) 0.0170(15) Uani 1 d .
C1 C 0.5163(9) 0.8137(8) 0.6632(4) 0.049(3) Uani 1 d .
C41 C -0.0967(6) 0.6871(6) 0.0705(3) 0.0203(16) Uani 1 d .
H41 H -0.0537 0.7507 0.0746 0.024 Uiso 1 calc R
C31 C 0.0836(5) 0.7674(6) 0.2514(3) 0.0178(15) Uani 1 d .
C30 C 0.0182(6) 0.7921(5) 0.2988(3) 0.0187(16) Uani 1 d .
C17 C -0.0744(5) 0.5116(6) 0.3567(3) 0.0193(16) Uani 1 d .
H17 H -0.1172 0.5706 0.3614 0.023 Uiso 1 calc R
C36 C 0.1938(6) 0.9451(6) 0.2875(3) 0.0265(18) Uani 1 d .
C26 C 0.0450(6) 0.7671(5) 0.3540(3) 0.0189(16) Uani 1 d .
C5 C 0.3944(7) 0.6597(6) 0.7785(3) 0.0302(19) Uani 1 d .
H5 H 0.3700 0.6320 0.8078 0.036 Uiso 1 calc R
C2 C 0.4679(7) 0.7499(6) 0.6993(4) 0.029(2) Uani 1 d .
C48 C -0.4520(6) 0.6643(6) 0.0797(3) 0.0226(17) Uani 1 d .
C60 C -0.2902(6) 0.8780(5) 0.0292(3) 0.0202(16) Uani 1 d .
C23 C 0.1383(6) 0.3991(6) 0.2221(3) 0.0230(17) Uani 1 d .
C10 C 0.1660(6) 0.8083(6) 0.5694(4) 0.0275(18) Uani 1 d .
H10 H 0.1536 0.7970 0.5270 0.033 Uiso 1 calc R
C59 C -0.2000(6) 0.9460(6) 0.0767(3) 0.0211(16) Uani 1 d .
C14 C 0.0497(5) 0.3438(6) 0.3435(3) 0.0218(17) Uani 1 d .
C15 C 0.0139(6) 0.3778(6) 0.3963(3) 0.0265(18) Uani 1 d .
H15 H 0.0344 0.3439 0.4280 0.032 Uiso 1 calc R
C8 C 0.1182(7) 0.8803(7) 0.6625(4) 0.037(2) Uani 1 d .
H8 H 0.0704 0.9187 0.6843 0.045 Uiso 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8970 1.1010 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1720 4.1540 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O25 Tb1 O27 144.22(16) . .
O25 Tb1 O4 71.53(16) . .
O25 Tb1 O10 131.98(16) . .
O25 Tb1 O9 80.58(17) . .
O25 Tb1 O26 71.62(16) . .
O25 Tb1 O22 134.09(16) . .
O25 Tb1 C25 106.06(19) . .
O27 Tb1 O4 136.20(17) . .
O27 Tb1 O10 75.23(16) . .
O27 Tb1 O9 125.21(16) . .
O27 Tb1 O26 72.80(16) . .
O27 Tb1 O22 70.27(16) . .
O27 Tb1 C25 100.30(19) . .
O4 Tb1 O10 96.30(16) . .
O4 Tb1 O9 70.80(17) . .
O4 Tb1 O26 126.49(17) . .
O4 Tb1 O22 66.37(17) . .
O4 Tb1 C25 83.45(18) . .
O10 Tb1 C25 26.20(18) . .
O21 Tb1 O25 87.08(16) . .
O21 Tb1 O27 81.35(16) . .
O21 Tb1 O4 75.88(17) . .
O21 Tb1 O10 136.16(15) . .
O21 Tb1 O9 146.61(16) . .
O21 Tb1 O26 64.83(16) . .
O21 Tb1 O22 65.94(16) . .
O21 Tb1 C25 150.64(17) . .
O9 Tb1 O10 52.04(16) . .
O9 Tb1 O22 101.56(17) . .
O9 Tb1 C25 25.86(18) . .
O26 Tb1 O10 137.20(16) . .
O26 Tb1 O9 136.97(16) . .
O26 Tb1 O22 121.41(16) . .
O26 Tb1 C25 143.95(17) . .
O7 Tb1 O25 86.50(16) . .
O7 Tb1 O27 78.74(16) . .
O7 Tb1 O4 141.48(17) . .
O7 Tb1 O10 75.01(16) . .
O7 Tb1 O21 135.60(16) . .
O7 Tb1 O9 74.73(16) . .
O7 Tb1 O26 71.46(16) . .
O7 Tb1 O22 138.82(16) . .
O7 Tb1 C25 72.49(18) . .
O22 Tb1 O10 71.40(15) . .
O22 Tb1 C25 86.83(18) . .
O31 Tb3 O13 127.23(15) . 1_565
O31 Tb3 O20 88.31(17) . .
O31 Tb3 O15 122.50(18) . 2_475
O31 Tb3 O16 71.03(17) . 2_475
O31 Tb3 C49 78.59(19) . .
O31 Tb3 C37 101.16(18) . 1_565
O31 Tb3 C48 96.9(2) . 2_475
O18 Tb3 O31 81.55(16) 2_475 .
O18 Tb3 O19 71.67(16) 2_475 .
O18 Tb3 O13 148.75(15) 2_475 1_565
O18 Tb3 O20 122.92(15) 2_475 .
O18 Tb3 O15 82.31(16) 2_475 2_475
O18 Tb3 O16 69.45(15) 2_475 2_475
O18 Tb3 C49 97.59(18) 2_475 .
O18 Tb3 C37 159.01(18) 2_475 1_565
O18 Tb3 C48 71.22(18) 2_475 2_475
O30 Tb3 O31 144.42(17) . .
O30 Tb3 O18 78.41(16) . 2_475
O30 Tb3 O19 74.25(17) . .
O30 Tb3 O14 132.81(16) . 1_565
O30 Tb3 O13 81.27(16) . 1_565
O30 Tb3 O20 78.54(16) . .
O30 Tb3 O15 83.53(18) . 2_475
O30 Tb3 O16 126.68(16) . 2_475
O30 Tb3 C49 75.32(18) . .
O30 Tb3 C37 108.06(19) . 1_565
O30 Tb3 C48 104.0(2) . 2_475
O19 Tb3 O31 71.66(17) . .
O19 Tb3 O13 124.65(16) . 1_565
O19 Tb3 O20 51.97(15) . .
O19 Tb3 O15 148.49(17) . 2_475
O19 Tb3 O16 128.93(16) . 2_475
O19 Tb3 C49 26.19(17) . .
O19 Tb3 C37 129.10(18) . 1_565
O19 Tb3 C48 142.38(18) . 2_475
O14 Tb3 O31 74.76(16) 1_565 .
O14 Tb3 O18 147.64(16) 1_565 2_475
O14 Tb3 O19 119.45(16) 1_565 .
O14 Tb3 O13 53.12(15) 1_565 1_565
O14 Tb3 O20 78.55(16) 1_565 .
O14 Tb3 O15 92.04(17) 1_565 2_475
O14 Tb3 O16 82.05(16) 1_565 2_475
O14 Tb3 C49 98.94(18) 1_565 .
O14 Tb3 C37 26.42(18) 1_565 1_565
O14 Tb3 C48 89.88(18) 1_565 2_475
O13 Tb3 O20 75.10(15) 1_565 .
O13 Tb3 O16 105.59(16) 1_565 2_475
O13 Tb3 C49 99.92(19) 1_565 .
O13 Tb3 C37 26.98(17) 1_565 1_565
O13 Tb3 C48 91.20(19) 1_565 2_475
O20 Tb3 C49 25.79(17) . .
O20 Tb3 C37 78.06(17) . 1_565
O20 Tb3 C48 165.65(17) . 2_475
O15 Tb3 O13 71.99(17) 2_475 1_565
O15 Tb3 O20 144.45(16) 2_475 .
O15 Tb3 O16 51.62(16) 2_475 2_475
O15 Tb3 C49 158.38(18) 2_475 .
O15 Tb3 C37 78.73(19) 2_475 1_565
O15 Tb3 C48 26.10(19) 2_475 2_475
O16 Tb3 O20 154.77(15) 2_475 .
O16 Tb3 C49 148.25(18) 2_475 .
O16 Tb3 C37 91.55(18) 2_475 1_565
O16 Tb3 C48 25.90(18) 2_475 2_475
C37 Tb3 C49 103.4(2) 1_565 .
C37 Tb3 C48 87.8(2) 1_565 2_475
C48 Tb3 C49 168.6(2) 2_475 .
O12 Tb2 O11 52.37(16) . .
O12 Tb2 C36 26.7(2) . .
O24 Tb2 O12 148.22(17) 2_676 .
O24 Tb2 O11 146.71(16) 2_676 .
O24 Tb2 O23 66.51(16) 2_676 2_676
O24 Tb2 O29 79.47(19) 2_676 .
O24 Tb2 C36 162.9(2) 2_676 .
O5 Tb2 O12 108.1(2) 1_565 .
O5 Tb2 O24 69.11(18) 1_565 2_676
O5 Tb2 O1 90.6(3) 1_565 2_676
O5 Tb2 O11 79.29(18) 1_565 .
O5 Tb2 O23 130.1(2) 1_565 2_676
O5 Tb2 O29 75.4(2) 1_565 .
O5 Tb2 O28 139.3(2) 1_565 .
O5 Tb2 C36 96.3(2) 1_565 .
O1 Tb2 O12 78.51(19) 2_676 .
O1 Tb2 O24 69.98(19) 2_676 2_676
O1 Tb2 O11 121.9(2) 2_676 .
O1 Tb2 O23 94.8(2) 2_676 2_676
O1 Tb2 O29 149.3(2) 2_676 .
O1 Tb2 O28 127.2(3) 2_676 .
O1 Tb2 C36 102.5(2) 2_676 .
O11 Tb2 C36 25.97(19) . .
O23 Tb2 O12 121.65(18) 2_676 .
O23 Tb2 O11 134.59(16) 2_676 .
O23 Tb2 C36 130.32(19) 2_676 .
O29 Tb2 O12 131.60(19) . .
O29 Tb2 O11 82.76(19) . .
O29 Tb2 O23 75.12(18) . 2_676
O29 Tb2 C36 106.0(2) . .
O28 Tb2 O12 71.2(2) . .
O28 Tb2 O24 132.5(2) . 2_676
O28 Tb2 O11 68.52(18) . .
O28 Tb2 O23 67.98(18) . 2_676
O28 Tb2 O29 76.5(3) . .
O28 Tb2 C36 64.4(2) . .
N6 Ag3 N9 106.9(2) . .
N8 Ag3 N6 125.6(2) . .
N8 Ag3 N9 123.8(2) . .
N3 Ag2 N7 111.9(2) . .
N5 Ag2 N7 122.0(2) . .
N5 Ag2 N3 123.0(2) . .
N4 Ag1 N2 139.9(2) 2_566 .
N4 Ag1 N10 89.5(2) 2_566 2_576
N4 Ag1 N1 134.5(2) 2_566 .
N2 Ag1 N10 85.4(2) . 2_576
N1 Ag1 N2 71.1(2) . .
N1 Ag1 N10 132.7(2) . 2_576
C36 O12 Tb2 91.7(4) . .
C61 O24 Tb2 119.0(4) . 2_676
Tb3 O31 H31A 109.3 . .
Tb3 O31 H31B 110.0 . .
H31A O31 H31B 109.0 . .
C13 O5 Tb2 119.0(6) . 1_545
C1 O1 Tb2 117.0(7) . 2_676
Tb1 O25 H25A 109.8 . .
Tb1 O25 H25B 110.3 . .
H25A O25 H25B 108.6 . .
C60 O18 Tb3 130.2(4) . 2_475
Tb3 O30 H30A 109.7 . .
Tb3 O30 H30B 109.5 . .
H30A O30 H30B 109.2 . .
Tb1 O27 H27A 111.7 . .
Tb1 O27 H27B 111.3 . .
H27A O27 H27B 107.2 . .
C49 O19 Tb3 97.3(4) . .
C12 O4 Tb1 136.7(5) . .
C36 O11 Tb2 92.5(4) . .
C62 O23 Tb2 118.3(5) . 2_676
C25 O10 Tb1 90.5(4) . .
C37 O14 Tb3 94.8(4) . 1_545
C37 O13 Tb3 89.0(4) . 1_545
C49 O20 Tb3 88.6(4) . .
C61 O21 Tb1 119.3(4) . .
Tb2 O29 H29A 125.8 . .
Tb2 O29 H29B 125.8 . .
H29A O29 H29B 108.4 . .
C48 O15 Tb3 95.1(4) . 2_475
C25 O9 Tb1 93.7(4) . .
Tb1 O26 H26A 110.5 . .
Tb1 O26 H26B 110.1 . .
H26A O26 H26B 108.4 . .
C24 O7 Tb1 135.0(4) . .
C62 O22 Tb1 114.4(4) . .
Tb2 O28 H28A 110.2 . .
Tb2 O28 H28B 110.3 . .
H28A O28 H28B 108.4 . .
C48 O16 Tb3 89.4(4) . 2_475
C20 N4 Ag1 120.5(5) . 2_566
C19 N4 Ag1 119.6(5) . 2_566
C19 N4 C20 118.9(6) . .
C43 N7 Ag2 126.9(4) . .
C44 N7 Ag2 112.4(4) . .
C44 N7 C43 119.3(6) . .
C18 N3 Ag2 117.0(4) . .
C17 N3 Ag2 125.1(5) . .
C17 N3 C18 117.8(6) . .
C29 N6 Ag3 112.2(5) . .
C30 N6 Ag3 126.3(5) . .
C30 N6 C29 117.4(6) . .
C42 N8 Ag3 115.6(5) . .
C41 N8 Ag3 125.0(5) . .
C41 N8 C42 119.1(6) . .
C32 N5 Ag2 124.1(5) . .
C31 N5 Ag2 117.3(5) . .
C31 N5 C32 118.6(6) . .
C7 N2 Ag1 110.2(5) . .
C8 N2 Ag1 118.8(5) . .
C8 N2 C7 119.7(7) . .
C55 N10 Ag1 111.2(4) . 2_576
C55 N10 C56 117.2(6) . .
C56 N10 Ag1 112.0(4) . 2_576
C6 N1 Ag1 117.6(5) . .
C5 N1 Ag1 118.9(5) . .
C5 N1 C6 119.0(7) . .
C53 N9 Ag3 129.7(5) . .
C54 N9 Ag3 111.9(5) . .
C54 N9 C53 117.8(6) . .
O3 C12 O4 125.5(7) . .
O3 C12 C11 118.7(6) . .
O4 C12 C11 115.6(7) . .
N10 C55 C54 111.8(6) . .
N10 C55 C59 123.6(6) . .
C59 C55 C54 124.3(6) . .
O10 C25 Tb1 63.3(4) . .
O10 C25 C26 118.9(6) . .
O9 C25 Tb1 60.4(4) . .
O9 C25 O10 123.7(7) . .
O9 C25 C26 117.4(6) . .
C26 C25 Tb1 177.4(5) . .
C35 C34 H34 120.4 . .
C35 C34 C33 119.2(7) . .
C33 C34 H34 120.4 . .
N4 C20 H20 118.8 . .
N4 C20 C21 122.4(7) . .
C21 C20 H20 118.8 . .
N3 C18 C19 112.3(6) . .
N3 C18 C14 122.6(7) . .
C14 C18 C19 124.8(6) . .
N2 C7 C6 114.6(7) . .
N2 C7 C11 120.2(7) . .
C11 C7 C6 125.2(7) . .
N7 C43 C47 121.7(6) . .
N7 C43 C42 115.1(6) . .
C47 C43 C42 123.0(6) . .
C39 C40 H40 120.4 . .
C39 C40 C41 119.3(7) . .
C41 C40 H40 120.4 . .
N10 C56 H56 118.3 . .
N10 C56 C57 123.5(7) . .
C57 C56 H56 118.3 . .
N9 C53 H53 118.6 . .
N9 C53 C52 122.7(7) . .
C52 C53 H53 118.6 . .
C17 C16 H16 121.2 . .
C17 C16 C15 117.5(7) . .
C15 C16 H16 121.2 . .
C4 C3 H3 119.4 . .
C4 C3 C2 121.3(8) . .
C2 C3 H3 119.4 . .
O19 C49 Tb3 56.5(3) . .
O19 C49 C50 115.0(6) . .
O20 C49 Tb3 65.6(4) . .
O20 C49 O19 122.1(7) . .
O20 C49 C50 122.9(6) . .
C50 C49 Tb3 171.1(5) . .
C56 C57 H57 120.9 . .
C58 C57 C56 118.3(7) . .
C58 C57 H57 120.9 . .
C53 C52 H52 120.8 . .
C53 C52 C51 118.4(7) . .
C51 C52 H52 120.8 . .
C20 C21 H21 120.8 . .
C20 C21 C22 118.5(7) . .
C22 C21 H21 120.8 . .
C54 C50 C49 122.3(6) . .
C51 C50 C49 119.5(6) . .
C51 C50 C54 117.9(6) . .
N4 C19 C18 112.8(6) . .
N4 C19 C23 122.7(7) . .
C23 C19 C18 124.3(6) . .
C34 C35 C31 118.6(7) . .
C34 C35 C36 118.8(6) . .
C31 C35 C36 122.4(6) . .
C21 C22 H22 120.1 . .
C23 C22 C21 119.8(7) . .
C23 C22 H22 120.1 . .
C10 C9 H9 121.0 . .
C10 C9 C8 118.0(8) . .
C8 C9 H9 121.0 . .
N1 C6 C7 112.1(7) . .
N1 C6 C2 121.0(8) . .
C2 C6 C7 126.8(7) . .
O23 C62 O22 125.8(7) . .
O23 C62 C61 117.2(6) . .
O22 C62 C61 116.9(6) . .
C43 C47 C48 122.9(6) . .
C46 C47 C43 118.7(7) . .
C46 C47 C48 118.5(7) . .
N5 C32 H32 118.5 . .
N5 C32 C33 123.1(7) . .
C33 C32 H32 118.5 . .
C29 C28 H28 120.8 . .
C27 C28 H28 120.8 . .
C27 C28 C29 118.3(7) . .
C46 C45 H45 120.3 . .
C46 C45 C44 119.4(7) . .
C44 C45 H45 120.3 . .
N6 C29 C28 123.6(7) . .
N6 C29 H29 118.2 . .
C28 C29 H29 118.2 . .
C47 C46 H46 120.7 . .
C45 C46 C47 118.6(7) . .
C45 C46 H46 120.7 . .
O5 C13 C14 113.1(9) . .
O6 C13 O5 126.7(9) . .
O6 C13 C14 120.2(8) . .
C28 C27 H27 120.0 . .
C28 C27 C26 120.0(7) . .
C26 C27 H27 120.0 . .
N9 C54 C55 112.5(6) . .
N9 C54 C50 123.3(6) . .
C50 C54 C55 124.0(6) . .
C57 C58 H58 119.8 . .
C57 C58 C59 120.3(7) . .
C59 C58 H58 119.8 . .
C3 C4 H4 121.2 . .
C3 C4 C5 117.6(8) . .
C5 C4 H4 121.2 . .
N8 C42 C43 115.2(6) . .
N8 C42 C38 121.3(6) . .
C38 C42 C43 123.4(6) . .
C42 C38 C39 118.5(6) . .
C42 C38 C37 121.4(6) . .
C39 C38 C37 120.0(6) . .
C52 C51 H51 120.1 . .
C50 C51 C52 119.9(7) . .
C50 C51 H51 120.1 . .
C34 C33 H33 120.8 . .
C32 C33 C34 118.3(7) . .
C32 C33 H33 120.8 . .
N7 C44 C45 122.2(7) . .
N7 C44 H44 118.9 . .
C45 C44 H44 118.9 . .
O8 C24 O7 126.5(7) . .
O8 C24 C23 115.7(7) . .
O7 C24 C23 117.7(6) . .
C7 C11 C12 122.9(7) . .
C10 C11 C12 117.3(7) . .
C10 C11 C7 119.6(8) . .
C40 C39 C38 119.3(6) . .
C40 C39 H39 120.4 . .
C38 C39 H39 120.4 . .
O24 C61 O21 125.6(7) . .
O24 C61 C62 117.1(6) . .
O21 C61 C62 117.3(6) . .
O14 C37 Tb3 58.7(3) . 1_545
O14 C37 O13 121.8(6) . .
O14 C37 C38 119.0(6) . .
O13 C37 Tb3 64.1(3) . 1_545
O13 C37 C38 119.1(6) . .
C38 C37 Tb3 165.4(5) . 1_545
O2 C1 O1 125.1(9) . .
O2 C1 C2 122.0(10) . .
O1 C1 C2 112.9(10) . .
N8 C41 C40 122.4(6) . .
N8 C41 H41 118.8 . .
C40 C41 H41 118.8 . .
N5 C31 C35 122.2(6) . .
N5 C31 C30 113.6(6) . .
C35 C31 C30 124.2(6) . .
N6 C30 C31 114.1(6) . .
N6 C30 C26 121.3(7) . .
C26 C30 C31 124.5(6) . .
N3 C17 C16 124.0(7) . .
N3 C17 H17 118.0 . .
C16 C17 H17 118.0 . .
O12 C36 Tb2 61.6(4) . .
O12 C36 C35 117.6(7) . .
O11 C36 Tb2 61.5(4) . .
O11 C36 O12 121.9(7) . .
O11 C36 C35 120.3(7) . .
C35 C36 Tb2 164.4(5) . .
C27 C26 C25 117.9(6) . .
C27 C26 C30 119.3(7) . .
C30 C26 C25 122.8(6) . .
N1 C5 C4 123.1(8) . .
N1 C5 H5 118.5 . .
C4 C5 H5 118.5 . .
C3 C2 C6 117.6(7) . .
C3 C2 C1 117.9(8) . .
C6 C2 C1 124.3(9) . .
O15 C48 Tb3 58.8(4) . 2_475
O15 C48 C47 117.0(7) . .
O16 C48 Tb3 64.7(4) . 2_475
O16 C48 O15 122.1(7) . .
O16 C48 C47 120.9(7) . .
C47 C48 Tb3 167.3(5) . 2_475
O18 C60 O17 125.8(6) . .
O18 C60 C59 117.5(6) . .
O17 C60 C59 116.7(6) . .
C19 C23 C24 123.7(7) . .
C22 C23 C19 117.6(6) . .
C22 C23 C24 118.7(6) . .
C9 C10 H10 120.1 . .
C11 C10 C9 119.7(8) . .
C11 C10 H10 120.1 . .
C55 C59 C58 117.0(7) . .
C55 C59 C60 124.0(6) . .
C58 C59 C60 118.8(6) . .
C18 C14 C13 120.8(7) . .
C18 C14 C15 118.0(7) . .
C15 C14 C13 121.0(7) . .
C16 C15 H15 120.0 . .
C14 C15 C16 120.0(7) . .
C14 C15 H15 120.0 . .
N2 C8 C9 122.7(8) . .
N2 C8 H8 118.7 . .
C9 C8 H8 118.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 O25 2.438(5) .
Tb1 O27 2.449(5) .
Tb1 O4 2.467(5) .
Tb1 O10 2.555(5) .
Tb1 O21 2.413(5) .
Tb1 O9 2.492(5) .
Tb1 O26 2.471(5) .
Tb1 O7 2.395(5) .
Tb1 O22 2.516(5) .
Tb1 C25 2.859(7) .
Tb3 O31 2.424(5) .
Tb3 O18 2.415(4) 2_475
Tb3 O30 2.363(5) .
Tb3 O19 2.417(5) .
Tb3 O14 2.409(4) 1_565
Tb3 O13 2.526(5) 1_565
Tb3 O20 2.620(5) .
Tb3 O15 2.451(5) 2_475
Tb3 O16 2.578(5) 2_475
Tb3 C49 2.875(7) .
Tb3 C37 2.808(7) 1_565
Tb3 C48 2.853(7) 2_475
Tb2 O12 2.501(5) .
Tb2 O24 2.423(5) 2_676
Tb2 O5 2.330(6) 1_565
Tb2 O1 2.337(6) 2_676
Tb2 O11 2.502(5) .
Tb2 O23 2.462(5) 2_676
Tb2 O29 2.457(6) .
Tb2 O28 2.402(6) .
Tb2 C36 2.843(7) .
Ag3 N6 2.246(6) .
Ag3 N8 2.217(6) .
Ag3 N9 2.280(6) .
Ag2 N7 2.255(6) .
Ag2 N3 2.243(6) .
Ag2 N5 2.235(6) .
Ag1 N4 2.233(6) 2_566
Ag1 N2 2.409(6) .
Ag1 N10 2.558(6) 2_576
Ag1 N1 2.272(6) .
O12 C36 1.279(9) .
O2 C1 1.214(13) .
O24 Tb2 2.423(5) 2_676
O24 C61 1.251(8) .
O31 H31A 0.8767 .
O31 H31B 0.8767 .
O5 Tb2 2.330(6) 1_545
O5 C13 1.287(11) .
O1 Tb2 2.337(6) 2_676
O1 C1 1.281(13) .
O25 H25A 0.8846 .
O25 H25B 0.8849 .
O18 Tb3 2.415(4) 2_475
O18 C60 1.253(8) .
O30 H30A 0.8752 .
O30 H30B 0.8750 .
O3 C12 1.255(9) .
O27 H27A 0.9147 .
O27 H27B 0.9135 .
O19 C49 1.279(8) .
O4 C12 1.261(8) .
O11 C36 1.246(9) .
O23 Tb2 2.462(5) 2_676
O23 C62 1.252(8) .
O10 C25 1.262(8) .
O6 C13 1.225(11) .
O14 Tb3 2.409(4) 1_545
O14 C37 1.254(8) .
O13 Tb3 2.526(5) 1_545
O13 C37 1.274(8) .
O20 C49 1.251(8) .
O21 C61 1.259(8) .
O8 C24 1.243(9) .
O29 H29A 0.9761 .
O29 H29B 0.9767 .
O15 Tb3 2.451(5) 2_475
O15 C48 1.260(9) .
O17 C60 1.262(8) .
O9 C25 1.250(9) .
O26 H26A 0.8899 .
O26 H26B 0.8898 .
O7 C24 1.260(9) .
O22 C62 1.253(8) .
O28 H28A 0.8910 .
O28 H28B 0.8903 .
O16 Tb3 2.578(5) 2_475
O16 C48 1.246(9) .
N4 Ag1 2.233(6) 2_566
N4 C20 1.345(9) .
N4 C19 1.337(9) .
N7 C43 1.342(8) .
N7 C44 1.333(9) .
N3 C18 1.358(9) .
N3 C17 1.327(9) .
N6 C29 1.359(9) .
N6 C30 1.351(9) .
N8 C42 1.350(9) .
N8 C41 1.338(9) .
N5 C32 1.343(9) .
N5 C31 1.339(9) .
N2 C7 1.340(10) .
N2 C8 1.332(11) .
N10 Ag1 2.558(6) 2_576
N10 C55 1.340(9) .
N10 C56 1.352(9) .
N1 C6 1.362(9) .
N1 C5 1.325(10) .
N9 C53 1.345(9) .
N9 C54 1.340(9) .
C12 C11 1.524(10) .
C55 C54 1.519(9) .
C55 C59 1.397(10) .
C25 C26 1.518(10) .
C34 H34 0.9500 .
C34 C35 1.383(10) .
C34 C33 1.400(10) .
C20 H20 0.9500 .
C20 C21 1.386(11) .
C18 C19 1.505(10) .
C18 C14 1.379(10) .
C7 C6 1.492(11) .
C7 C11 1.411(11) .
C43 C47 1.407(10) .
C43 C42 1.483(9) .
C40 H40 0.9500 .
C40 C39 1.368(10) .
C40 C41 1.382(10) .
C56 H56 0.9500 .
C56 C57 1.383(11) .
C53 H53 0.9500 .
C53 C52 1.373(10) .
C16 H16 0.9500 .
C16 C17 1.377(10) .
C16 C15 1.388(11) .
C3 H3 0.9500 .
C3 C4 1.363(11) .
C3 C2 1.385(12) .
C49 C50 1.490(10) .
C57 H57 0.9500 .
C57 C58 1.370(10) .
C52 H52 0.9500 .
C52 C51 1.390(10) .
C21 H21 0.9500 .
C21 C22 1.404(10) .
C50 C54 1.384(10) .
C50 C51 1.373(10) .
C19 C23 1.414(10) .
C35 C31 1.386(10) .
C35 C36 1.492(10) .
C22 H22 0.9500 .
C22 C23 1.380(10) .
C9 H9 0.9500 .
C9 C10 1.384(11) .
C9 C8 1.386(12) .
C6 C2 1.397(11) .
C62 C61 1.529(10) .
C47 C46 1.393(10) .
C47 C48 1.499(10) .
C32 H32 0.9500 .
C32 C33 1.364(10) .
C28 H28 0.9500 .
C28 C29 1.370(10) .
C28 C27 1.361(10) .
C45 H45 0.9500 .
C45 C46 1.382(11) .
C45 C44 1.392(11) .
C29 H29 0.9500 .
C46 H46 0.9500 .
C13 C14 1.512(11) .
C27 H27 0.9500 .
C27 C26 1.380(10) .
C58 H58 0.9500 .
C58 C59 1.402(10) .
C4 H4 0.9500 .
C4 C5 1.387(11) .
C42 C38 1.397(10) .
C38 C39 1.399(10) .
C38 C37 1.497(9) .
C51 H51 0.9500 .
C33 H33 0.9500 .
C44 H44 0.9500 .
C24 C23 1.517(10) .
C11 C10 1.360(11) .
C39 H39 0.9500 .
C37 Tb3 2.808(7) 1_545
C1 C2 1.521(12) .
C41 H41 0.9500 .
C31 C30 1.505(10) .
C30 C26 1.390(10) .
C17 H17 0.9500 .
C5 H5 0.9500 .
C48 Tb3 2.853(7) 2_475
C60 C59 1.504(10) .
C10 H10 0.9500 .
C14 C15 1.388(11) .
C15 H15 0.9500 .
C8 H8 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Tb1 O4 C12 O3 27.0(12) . .
Tb1 O4 C12 C11 -147.7(5) . .
Tb1 O10 C25 O9 2.7(7) . .
Tb1 O10 C25 C26 -178.5(5) . .
Tb1 O21 C61 O24 170.8(5) . .
Tb1 O21 C61 C62 -10.0(8) . .
Tb1 O9 C25 O10 -2.8(7) . .
Tb1 O9 C25 C26 178.4(5) . .
Tb1 O7 C24 O8 2.5(13) . .
Tb1 O7 C24 C23 -173.8(5) . .
Tb1 O22 C62 O23 -156.5(6) . .
Tb1 O22 C62 C61 25.4(7) . .
Tb1 C25 C26 C27 59(11) . .
Tb1 C25 C26 C30 -120(11) . .
Tb3 O18 C60 O17 -0.6(10) 2_475 .
Tb3 O18 C60 C59 -178.7(4) 2_475 .
Tb3 O19 C49 O20 -2.1(7) . .
Tb3 O19 C49 C50 176.9(5) . .
Tb3 O14 C37 O13 -11.9(7) 1_545 .
Tb3 O14 C37 C38 163.3(5) 1_545 .
Tb3 O13 C37 O14 11.3(7) 1_545 .
Tb3 O13 C37 C38 -163.9(6) 1_545 .
Tb3 O20 C49 O19 1.9(6) . .
Tb3 O20 C49 C50 -177.0(6) . .
Tb3 O15 C48 O16 -14.2(7) 2_475 .
Tb3 O15 C48 C47 166.2(5) 2_475 .
Tb3 O16 C48 O15 13.5(7) 2_475 .
Tb3 O16 C48 C47 -167.0(6) 2_475 .
Tb3 C49 C50 C54 144(3) . .
Tb3 C49 C50 C51 -29(3) . .
Tb2 O12 C36 O11 12.6(8) . .
Tb2 O12 C36 C35 -162.3(6) . .
Tb2 O24 C61 O21 -164.5(5) 2_676 .
Tb2 O24 C61 C62 16.2(8) 2_676 .
Tb2 O5 C13 O6 15.2(11) 1_545 .
Tb2 O5 C13 C14 -166.7(4) 1_545 .
Tb2 O1 C1 O2 8.9(12) 2_676 .
Tb2 O1 C1 C2 -171.0(5) 2_676 .
Tb2 O11 C36 O12 -12.6(8) . .
Tb2 O11 C36 C35 162.2(6) . .
Tb2 O23 C62 O22 -178.6(5) 2_676 .
Tb2 O23 C62 C61 -0.5(8) 2_676 .
Ag3 N6 C29 C28 155.7(6) . .
Ag3 N6 C30 C31 23.8(8) . .
Ag3 N6 C30 C26 -152.2(5) . .
Ag3 N8 C42 C43 5.2(7) . .
Ag3 N8 C42 C38 -171.5(5) . .
Ag3 N8 C41 C40 173.9(5) . .
Ag3 N9 C53 C52 -171.3(5) . .
Ag3 N9 C54 C55 -12.3(7) . .
Ag3 N9 C54 C50 172.1(5) . .
Ag2 N7 C43 C47 -162.7(5) . .
Ag2 N7 C43 C42 12.8(8) . .
Ag2 N7 C44 C45 165.2(6) . .
Ag2 N3 C18 C19 -9.9(7) . .
Ag2 N3 C18 C14 176.6(5) . .
Ag2 N3 C17 C16 -177.2(5) . .
Ag2 N5 C32 C33 176.0(6) . .
Ag2 N5 C31 C35 -177.1(5) . .
Ag2 N5 C31 C30 0.7(7) . .
Ag1 N4 C20 C21 -166.6(6) 2_566 .
Ag1 N4 C19 C18 -15.4(8) 2_566 .
Ag1 N4 C19 C23 170.3(5) 2_566 .
Ag1 N2 C7 C6 -37.3(7) . .
Ag1 N2 C7 C11 141.1(6) . .
Ag1 N2 C8 C9 -141.2(7) . .
Ag1 N10 C55 C54 -55.9(6) 2_576 .
Ag1 N10 C55 C59 130.2(6) 2_576 .
Ag1 N10 C56 C57 -128.2(7) 2_576 .
Ag1 N1 C6 C7 -26.2(7) . .
Ag1 N1 C6 C2 151.1(5) . .
Ag1 N1 C5 C4 -157.0(6) . .
O12 Tb2 O11 C36 6.9(4) . .
O12 Tb2 C36 O11 -167.8(8) . .
O12 Tb2 C36 C35 91(2) . .
O2 C1 C2 C3 -154.6(8) . .
O2 C1 C2 C6 20.5(12) . .
O24 Tb2 O12 C36 -146.1(4) 2_676 .
O24 Tb2 O11 C36 148.3(4) 2_676 .
O24 Tb2 C36 O12 88.3(8) 2_676 .
O24 Tb2 C36 O11 -79.5(8) 2_676 .
O24 Tb2 C36 C35 179.5(16) 2_676 .
O31 Tb3 O19 C49 -101.6(4) . .
O31 Tb3 O20 C49 66.8(4) . .
O31 Tb3 C49 O19 71.5(4) . .
O31 Tb3 C49 O20 -110.4(4) . .
O31 Tb3 C49 C50 53(3) . .
O5 Tb2 O12 C36 -66.8(5) 1_565 .
O5 Tb2 O11 C36 129.9(5) 1_565 .
O5 Tb2 C36 O12 118.5(5) 1_565 .
O5 Tb2 C36 O11 -49.3(5) 1_565 .
O5 Tb2 C36 C35 -150(2) 1_565 .
O5 C13 C14 C18 169.9(6) . .
O5 C13 C14 C15 -6.7(10) . .
O1 Tb2 O12 C36 -153.7(5) 2_676 .
O1 Tb2 O11 C36 45.9(5) 2_676 .
O1 Tb2 C36 O12 26.5(5) 2_676 .
O1 Tb2 C36 O11 -141.4(5) 2_676 .
O1 Tb2 C36 C35 118(2) 2_676 .
O1 C1 C2 C3 25.4(10) . .
O1 C1 C2 C6 -159.6(7) . .
O25 Tb1 O4 C12 14.0(7) . .
O25 Tb1 O10 C25 9.7(5) . .
O25 Tb1 O21 C61 -125.9(5) . .
O25 Tb1 O9 C25 -170.2(4) . .
O25 Tb1 O7 C24 -150.8(7) . .
O25 Tb1 O22 C62 37.6(6) . .
O25 Tb1 C25 O10 -172.5(4) . .
O25 Tb1 C25 O9 10.1(4) . .
O25 Tb1 C25 C26 -22(11) . .
O18 Tb3 O19 C49 171.4(4) 2_475 .
O18 Tb3 O20 C49 -12.0(4) 2_475 .
O18 Tb3 C49 O19 -8.2(4) 2_475 .
O18 Tb3 C49 O20 169.9(4) 2_475 .
O18 Tb3 C49 C50 -27(3) 2_475 .
O18 C60 C59 C55 -3.1(10) . .
O18 C60 C59 C58 171.8(7) . .
O30 Tb3 O19 C49 88.7(4) . .
O30 Tb3 O20 C49 -79.9(4) . .
O30 Tb3 C49 O19 -84.1(4) . .
O30 Tb3 C49 O20 94.0(4) . .
O30 Tb3 C49 C50 -102(3) . .
O3 C12 C11 C7 32.3(11) . .
O3 C12 C11 C10 -142.6(8) . .
O27 Tb1 O4 C12 -138.6(7) . .
O27 Tb1 O10 C25 162.7(4) . .
O27 Tb1 O21 C61 88.1(5) . .
O27 Tb1 O9 C25 -17.4(5) . .
O27 Tb1 O7 C24 -3.6(7) . .
O27 Tb1 O22 C62 -110.9(5) . .
O27 Tb1 C25 O10 -17.0(4) . .
O27 Tb1 C25 O9 165.6(4) . .
O27 Tb1 C25 C26 133(11) . .
O19 Tb3 O20 C49 -1.1(4) . .
O19 Tb3 C49 O20 178.1(6) . .
O19 Tb3 C49 C50 -18(3) . .
O19 C49 C50 C54 126.8(7) . .
O19 C49 C50 C51 -46.2(9) . .
O4 Tb1 O10 C25 -61.0(4) . .
O4 Tb1 O21 C61 -54.2(5) . .
O4 Tb1 O9 C25 116.2(4) . .
O4 Tb1 O7 C24 155.1(6) . .
O4 Tb1 O22 C62 62.8(5) . .
O4 Tb1 C25 O10 118.9(4) . .
O4 Tb1 C25 O9 -58.5(4) . .
O4 Tb1 C25 C26 -91(11) . .
O4 C12 C11 C7 -152.5(7) . .
O4 C12 C11 C10 32.6(10) . .
O11 Tb2 O12 C36 -6.7(4) . .
O11 Tb2 C36 O12 167.8(8) . .
O11 Tb2 C36 C35 -101(2) . .
O23 Tb2 O12 C36 117.8(5) 2_676 .
O23 Tb2 O11 C36 -92.9(5) 2_676 .
O23 Tb2 C36 O12 -81.1(5) 2_676 .
O23 Tb2 C36 O11 111.1(4) 2_676 .
O23 Tb2 C36 C35 10(2) 2_676 .
O23 C62 C61 O24 -10.5(9) . .
O23 C62 C61 O21 170.2(6) . .
O10 Tb1 O4 C12 146.2(7) . .
O10 Tb1 O21 C61 30.1(6) . .
O10 Tb1 O9 C25 1.4(4) . .
O10 Tb1 O7 C24 74.0(7) . .
O10 Tb1 O22 C62 168.6(5) . .
O10 Tb1 C25 O9 -177.4(7) . .
O10 Tb1 C25 C26 150(11) . .
O10 C25 C26 C27 -151.2(6) . .
O10 C25 C26 C30 29.9(10) . .
O6 C13 C14 C18 -12.0(11) . .
O6 C13 C14 C15 171.5(7) . .
O14 Tb3 O19 C49 -42.0(4) 1_565 .
O14 Tb3 O20 C49 141.6(4) 1_565 .
O14 Tb3 C49 O19 143.9(4) 1_565 .
O14 Tb3 C49 O20 -38.0(4) 1_565 .
O14 Tb3 C49 C50 126(3) 1_565 .
O13 Tb3 O19 C49 21.4(4) 1_565 .
O13 Tb3 O20 C49 -163.8(4) 1_565 .
O13 Tb3 C49 O19 -162.2(4) 1_565 .
O13 Tb3 C49 O20 15.9(4) 1_565 .
O13 Tb3 C49 C50 179(100) 1_565 .
O20 Tb3 O19 C49 1.1(4) . .
O20 Tb3 C49 O19 -178.1(6) . .
O20 Tb3 C49 C50 164(3) . .
O20 C49 C50 C54 -54.2(9) . .
O20 C49 C50 C51 132.8(7) . .
O21 Tb1 O4 C12 -77.7(7) . .
O21 Tb1 O10 C25 -137.2(4) . .
O21 Tb1 O9 C25 120.1(4) . .
O21 Tb1 O7 C24 -68.6(7) . .
O21 Tb1 O22 C62 -21.7(5) . .
O21 Tb1 C25 O10 73.7(5) . .
O21 Tb1 C25 O9 -103.7(5) . .
O21 Tb1 C25 C26 -136(11) . .
O8 C24 C23 C19 -171.5(7) . .
O8 C24 C23 C22 8.6(11) . .
O29 Tb2 O12 C36 19.5(6) . .
O29 Tb2 O11 C36 -153.7(5) . .
O29 Tb2 C36 O12 -164.9(4) . .
O29 Tb2 C36 O11 27.3(5) . .
O29 Tb2 C36 C35 -74(2) . .
O15 Tb3 O19 C49 135.5(4) 2_475 .
O15 Tb3 O20 C49 -141.2(4) 2_475 .
O15 Tb3 C49 O19 -96.5(6) 2_475 .
O15 Tb3 C49 O20 81.6(6) 2_475 .
O15 Tb3 C49 C50 -115(3) 2_475 .
O17 C60 C59 C55 178.5(7) . .
O17 C60 C59 C58 -6.5(10) . .
O9 Tb1 O4 C12 100.2(7) . .
O9 Tb1 O10 C25 -1.4(4) . .
O9 Tb1 O21 C61 -57.9(6) . .
O9 Tb1 O7 C24 128.0(7) . .
O9 Tb1 O22 C62 125.6(5) . .
O9 Tb1 C25 O10 177.4(7) . .
O9 Tb1 C25 C26 -32(11) . .
O9 C25 C26 C27 27.7(9) . .
O9 C25 C26 C30 -151.3(7) . .
O26 Tb1 O4 C12 -34.7(8) . .
O26 Tb1 O10 C25 120.0(4) . .
O26 Tb1 O21 C61 163.1(5) . .
O26 Tb1 O9 C25 -120.4(4) . .
O26 Tb1 O7 C24 -79.0(7) . .
O26 Tb1 O22 C62 -56.8(5) . .
O26 Tb1 C25 O10 -91.8(5) . .
O26 Tb1 C25 O9 90.8(5) . .
O26 Tb1 C25 C26 58(11) . .
O7 Tb1 O4 C12 72.4(8) . .
O7 Tb1 O10 C25 80.7(4) . .
O7 Tb1 O21 C61 152.1(5) . .
O7 Tb1 O9 C25 -81.3(4) . .
O7 Tb1 O22 C62 -154.4(4) . .
O7 Tb1 C25 O10 -91.6(4) . .
O7 Tb1 C25 O9 91.0(4) . .
O7 Tb1 C25 C26 59(11) . .
O7 C24 C23 C19 5.2(11) . .
O7 C24 C23 C22 -174.7(7) . .
O22 Tb1 O4 C12 -147.3(7) . .
O22 Tb1 O10 C25 -123.5(4) . .
O22 Tb1 O21 C61 15.9(5) . .
O22 Tb1 O9 C25 56.5(4) . .
O22 Tb1 O7 C24 37.8(8) . .
O22 Tb1 C25 O10 52.3(4) . .
O22 Tb1 C25 O9 -125.1(4) . .
O22 Tb1 C25 C26 -157(11) . .
O22 C62 C61 O24 167.8(6) . .
O22 C62 C61 O21 -11.6(9) . .
O28 Tb2 O12 C36 70.2(5) . .
O28 Tb2 O11 C36 -75.4(5) . .
O28 Tb2 C36 O12 -99.0(5) . .
O28 Tb2 C36 O11 93.2(5) . .
O28 Tb2 C36 C35 -8(2) . .
O16 Tb3 O19 C49 -146.6(4) 2_475 .
O16 Tb3 O20 C49 101.2(5) 2_475 .
O16 Tb3 C49 O19 54.5(5) 2_475 .
O16 Tb3 C49 O20 -127.4(4) 2_475 .
O16 Tb3 C49 C50 36(3) 2_475 .
N4 Ag1 N2 C7 -120.6(5) 2_566 .
N4 Ag1 N2 C8 23.0(8) 2_566 .
N4 Ag1 N1 C6 148.7(5) 2_566 .
N4 Ag1 N1 C5 -55.2(6) 2_566 .
N4 C20 C21 C22 -2.9(12) . .
N4 C19 C23 C22 -4.1(11) . .
N4 C19 C23 C24 176.0(7) . .
N7 Ag2 N3 C18 128.1(5) . .
N7 Ag2 N3 C17 -55.0(6) . .
N7 Ag2 N5 C32 -96.2(6) . .
N7 Ag2 N5 C31 80.2(5) . .
N7 C43 C47 C46 -0.4(10) . .
N7 C43 C47 C48 -179.5(6) . .
N7 C43 C42 N8 -87.9(7) . .
N7 C43 C42 C38 88.7(8) . .
N3 Ag2 N7 C43 -163.5(5) . .
N3 Ag2 N7 C44 30.8(5) . .
N3 Ag2 N5 C32 105.5(6) . .
N3 Ag2 N5 C31 -78.1(5) . .
N3 C18 C19 N4 -78.3(7) . .
N3 C18 C19 C23 95.9(8) . .
N3 C18 C14 C13 -177.3(6) . .
N3 C18 C14 C15 -0.7(10) . .
N6 Ag3 N8 C42 80.3(5) . .
N6 Ag3 N8 C41 -94.1(6) . .
N6 Ag3 N9 C53 -61.3(6) . .
N6 Ag3 N9 C54 127.3(4) . .
N6 C30 C26 C25 178.3(6) . .
N6 C30 C26 C27 -0.6(10) . .
N8 Ag3 N6 C29 -131.7(5) . .
N8 Ag3 N6 C30 24.8(7) . .
N8 Ag3 N9 C53 98.2(6) . .
N8 Ag3 N9 C54 -73.3(5) . .
N8 C42 C38 C39 -3.1(10) . .
N8 C42 C38 C37 -177.7(6) . .
N5 Ag2 N7 C43 36.0(6) . .
N5 Ag2 N7 C44 -129.7(5) . .
N5 Ag2 N3 C18 -71.6(5) . .
N5 Ag2 N3 C17 105.2(5) . .
N5 C32 C33 C34 0.3(12) . .
N5 C31 C30 N6 -90.7(7) . .
N5 C31 C30 C26 85.2(8) . .
N2 Ag1 N1 C6 5.8(5) . .
N2 Ag1 N1 C5 161.9(6) . .
N2 C7 C6 N1 43.7(9) . .
N2 C7 C6 C2 -133.5(8) . .
N2 C7 C11 C12 -171.6(7) . .
N2 C7 C11 C10 3.2(11) . .
N10 Ag1 N2 C7 155.8(5) 2_576 .
N10 Ag1 N2 C8 -60.7(6) 2_576 .
N10 Ag1 N1 C6 -58.6(6) 2_576 .
N10 Ag1 N1 C5 97.5(6) 2_576 .
N10 C55 C54 N9 -72.5(7) . .
N10 C55 C54 C50 103.0(8) . .
N10 C55 C59 C58 -1.0(11) . .
N10 C55 C59 C60 174.0(7) . .
N10 C56 C57 C58 -2.0(12) . .
N1 Ag1 N2 C7 17.4(5) . .
N1 Ag1 N2 C8 161.0(6) . .
N1 C6 C2 C3 7.3(11) . .
N1 C6 C2 C1 -167.7(7) . .
N9 Ag3 N6 C29 27.3(5) . .
N9 Ag3 N6 C30 -176.2(5) . .
N9 Ag3 N8 C42 -75.2(5) . .
N9 Ag3 N8 C41 110.3(6) . .
N9 C53 C52 C51 1.9(10) . .
C12 C11 C10 C9 174.0(7) . .
C55 N10 C56 C57 2.0(11) . .
C25 Tb1 O4 C12 123.4(7) . .
C25 Tb1 O21 C61 -7.6(7) . .
C25 Tb1 O7 C24 101.1(7) . .
C25 Tb1 O22 C62 147.0(5) . .
C34 C35 C31 N5 1.4(11) . .
C34 C35 C31 C30 -176.2(7) . .
C34 C35 C36 Tb2 -96(2) . .
C34 C35 C36 O12 -13.7(11) . .
C34 C35 C36 O11 171.3(7) . .
C20 N4 C19 C18 176.0(6) . .
C20 N4 C19 C23 1.7(11) . .
C20 C21 C22 C23 0.3(12) . .
C18 N3 C17 C16 -0.4(10) . .
C18 C19 C23 C22 -177.8(7) . .
C18 C19 C23 C24 2.3(12) . .
C18 C14 C15 C16 2.7(10) . .
C7 N2 C8 C9 -1.0(12) . .
C7 C6 C2 C3 -175.7(7) . .
C7 C6 C2 C1 9.2(12) . .
C7 C11 C10 C9 -1.1(12) . .
C43 N7 C44 C45 -1.7(10) . .
C43 C47 C46 C45 -1.8(10) . .
C43 C47 C48 Tb3 -104(2) . 2_475
C43 C47 C48 O15 -171.1(6) . .
C43 C47 C48 O16 9.3(10) . .
C43 C42 C38 C39 -179.5(6) . .
C43 C42 C38 C37 5.8(10) . .
C56 N10 C55 C54 173.5(6) . .
C56 N10 C55 C59 -0.4(11) . .
C56 C57 C58 C59 0.4(11) . .
C53 N9 C54 C55 175.1(6) . .
C53 N9 C54 C50 -0.4(10) . .
C53 C52 C51 C50 -2.9(10) . .
C3 C4 C5 N1 4.6(12) . .
C49 C50 C54 N9 -173.7(6) . .
C49 C50 C54 C55 11.3(10) . .
C49 C50 C51 C52 175.6(6) . .
C57 C58 C59 C55 1.0(11) . .
C57 C58 C59 C60 -174.3(7) . .
C21 C22 C23 C19 3.0(11) . .
C21 C22 C23 C24 -177.1(7) . .
C19 N4 C20 C21 1.9(11) . .
C19 C18 C14 C13 10.0(10) . .
C19 C18 C14 C15 -173.3(6) . .
C35 C34 C33 C32 0.6(12) . .
C35 C31 C30 N6 87.0(8) . .
C35 C31 C30 C26 -97.1(9) . .
C6 N1 C5 C4 -1.2(11) . .
C6 C7 C11 C12 6.7(12) . .
C6 C7 C11 C10 -178.5(7) . .
C47 C43 C42 N8 87.5(8) . .
C47 C43 C42 C38 -95.9(9) . .
C32 N5 C31 C35 -0.5(10) . .
C32 N5 C31 C30 177.3(6) . .
C28 C27 C26 C25 178.7(7) . .
C28 C27 C26 C30 -2.3(11) . .
C29 N6 C30 C31 179.3(6) . .
C29 N6 C30 C26 3.2(10) . .
C29 C28 C27 C26 2.4(11) . .
C46 C47 C48 Tb3 77(2) . 2_475
C46 C47 C48 O15 9.7(10) . .
C46 C47 C48 O16 -169.9(6) . .
C46 C45 C44 N7 -0.4(12) . .
C13 C14 C15 C16 179.3(7) . .
C27 C28 C29 N6 0.3(11) . .
C54 N9 C53 C52 -0.3(10) . .
C54 C55 C59 C58 -174.2(7) . .
C54 C55 C59 C60 0.8(11) . .
C54 C50 C51 C52 2.3(10) . .
C4 C3 C2 C6 -3.8(11) . .
C4 C3 C2 C1 171.6(7) . .
C42 N8 C41 C40 -0.4(10) . .
C42 C43 C47 C46 -175.5(6) . .
C42 C43 C47 C48 5.3(10) . .
C42 C38 C39 C40 0.1(11) . .
C42 C38 C37 Tb3 92(2) . 1_545
C42 C38 C37 O14 14.8(10) . .
C42 C38 C37 O13 -169.9(6) . .
C51 C50 C54 N9 -0.6(10) . .
C51 C50 C54 C55 -175.6(6) . .
C33 C34 C35 C31 -1.4(11) . .
C33 C34 C35 C36 173.4(7) . .
C44 N7 C43 C47 2.1(10) . .
C44 N7 C43 C42 177.6(6) . .
C44 C45 C46 C47 2.2(11) . .
C11 C7 C6 N1 -134.7(7) . .
C11 C7 C6 C2 48.1(11) . .
C39 C40 C41 N8 -2.6(11) . .
C39 C38 C37 Tb3 -83(2) . 1_545
C39 C38 C37 O14 -159.8(7) . .
C39 C38 C37 O13 15.5(10) . .
C37 Tb3 O19 C49 -12.0(5) 1_565 .
C37 Tb3 O20 C49 168.6(4) 1_565 .
C37 Tb3 C49 O19 170.4(4) 1_565 .
C37 Tb3 C49 O20 -11.5(4) 1_565 .
C37 Tb3 C49 C50 152(3) 1_565 .
C37 C38 C39 C40 174.8(7) . .
C41 N8 C42 C43 180.0(6) . .
C41 N8 C42 C38 3.3(10) . .
C41 C40 C39 C38 2.7(11) . .
C31 N5 C32 C33 -0.4(11) . .
C31 C35 C36 Tb2 78(2) . .
C31 C35 C36 O12 161.0(7) . .
C31 C35 C36 O11 -14.1(11) . .
C31 C30 C26 C25 2.7(10) . .
C31 C30 C26 C27 -176.3(6) . .
C30 N6 C29 C28 -3.1(10) . .
C17 N3 C18 C19 173.0(6) . .
C17 N3 C18 C14 -0.5(10) . .
C17 C16 C15 C14 -3.4(10) . .
C36 C35 C31 N5 -173.2(7) . .
C36 C35 C31 C30 9.2(11) . .
C5 N1 C6 C7 177.7(6) . .
C5 N1 C6 C2 -5.0(10) . .
C2 C3 C4 C5 -1.9(12) . .
C48 Tb3 O19 C49 -178.8(4) 2_475 .
C48 Tb3 O20 C49 178.5(7) 2_475 .
C48 Tb3 C49 O19 3.8(12) 2_475 .
C48 Tb3 C49 O20 -178.1(9) 2_475 .
C48 Tb3 C49 C50 -15(4) 2_475 .
C48 C47 C46 C45 177.4(7) . .
C10 C9 C8 N2 3.0(12) . .
C59 C55 C54 N9 101.4(8) . .
C59 C55 C54 C50 -83.1(9) . .
C14 C18 C19 N4 95.0(8) . .
C14 C18 C19 C23 -90.8(9) . .
C15 C16 C17 N3 2.4(11) . .
C8 N2 C7 C6 179.4(7) . .
C8 N2 C7 C11 -2.1(11) . .
C8 C9 C10 C11 -1.9(12) . .
