#------------------------------------------------------------------------------
#$Date: 2017-08-10 05:16:51 +0300 (Thu, 10 Aug 2017) $
#$Revision: 199689 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/39/7043939.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7043939
loop_
_publ_author_name
'Osawa, Masahisa'
'Hashimoto, Masashi'
'Kawata, Isao'
'Hoshino, Mikio'
_publ_section_title
;
 Photoluminescence properties of TADF-emitting three-coordinate silver(I)
 halide complexes with diphosphine ligands: a comparison study with
 copper(I) complexes
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT02460F
_journal_year                    2017
_chemical_formula_sum            'C68 H64 Ag2 Br2 P4'
_chemical_formula_weight         1380.64
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2017-01-27 deposited with the CCDC.
2017-08-09 downloaded from the CCDC.
;
_cell_angle_alpha                102.969(2)
_cell_angle_beta                 95.6740(10)
_cell_angle_gamma                107.632(2)
_cell_formula_units_Z            2
_cell_length_a                   13.6283(14)
_cell_length_b                   14.8803(15)
_cell_length_c                   16.1037(17)
_cell_measurement_reflns_used    12434
_cell_measurement_temperature    90
_cell_measurement_theta_max      32.59
_cell_measurement_theta_min      1.59
_cell_volume                     2983.6(5)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'ORTEP-3 for Windows'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      90
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Rigaku AFC-8 with Saturn70 CCD'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0295
_diffrn_reflns_av_sigmaI/netI    0.0242
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            80385
_diffrn_reflns_theta_full        31.00
_diffrn_reflns_theta_max         31.00
_diffrn_reflns_theta_min         1.59
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.144
_exptl_absorpt_correction_T_max  0.771
_exptl_absorpt_correction_T_min  0.581
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
; 
    Higashi, T. (1999). Program for Absorption Correction. 
    Rigaku Corporation, Tokyo, Japan. 
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.537
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1392
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.126
_refine_diff_density_min         -0.930
_refine_diff_density_rms         0.103
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.880
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     685
_refine_ls_number_reflns         18806
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.880
_refine_ls_R_factor_all          0.0393
_refine_ls_R_factor_gt           0.0345
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0566P)²+5.9704P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0868
_refine_ls_wR_factor_ref         0.0910
_reflns_number_gt                16782
_reflns_number_total             18806
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c7dt02460f2.cif
_cod_data_source_block           shelxl_CCDC1
_cod_database_code               7043939
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.567942(11) 0.126062(10) -0.019311(10) 0.01550(4) Uani 1 1 d .
Ag2 Ag 1.010172(12) 0.094340(11) 0.439515(10) 0.01789(4) Uani 1 1 d .
Br1 Br 0.433476(17) -0.048267(14) -0.116378(13) 0.01861(5) Uani 1 1 d .
Br2 Br 1.094088(17) 0.093306(15) 0.603181(13) 0.02029(5) Uani 1 1 d .
P1 P 0.72257(4) 0.22714(4) -0.07236(3) 0.01280(9) Uani 1 1 d .
P2 P 0.52783(4) 0.28443(3) 0.00382(3) 0.01118(8) Uani 1 1 d .
P3 P 1.13940(4) 0.18199(4) 0.35834(3) 0.01478(9) Uani 1 1 d .
P4 P 0.95429(4) 0.24266(4) 0.45398(3) 0.01511(9) Uani 1 1 d .
C1 C 0.85598(15) 0.22323(14) -0.05604(13) 0.0139(3) Uani 1 1 d .
C2 C 0.90294(16) 0.22390(15) 0.02630(14) 0.0173(4) Uani 1 1 d .
C3 C 1.00433(16) 0.21912(16) 0.03640(15) 0.0211(4) Uani 1 1 d .
H3 H 1.0374 0.2207 0.0917 0.025 Uiso 1 1 calc R
C4 C 1.05779(17) 0.21215(16) -0.03269(16) 0.0223(4) Uani 1 1 d .
H4 H 1.1266 0.2092 -0.0242 0.027 Uiso 1 1 calc R
C5 C 1.01080(17) 0.20957(16) -0.11375(16) 0.0206(4) Uani 1 1 d .
H5 H 1.0466 0.2036 -0.1613 0.025 Uiso 1 1 calc R
C6 C 0.91045(16) 0.21585(15) -0.12517(14) 0.0177(4) Uani 1 1 d .
H6 H 0.8786 0.2151 -0.1807 0.021 Uiso 1 1 calc R
C7 C 0.69530(16) 0.22973(17) -0.18592(14) 0.0195(4) Uani 1 1 d .
C8 C 0.65986(18) 0.14268(18) -0.25213(15) 0.0227(4) Uani 1 1 d .
C9 C 0.6316(2) 0.1451(2) -0.33781(17) 0.0307(5) Uani 1 1 d .
H9 H 0.6050 0.0858 -0.3828 0.037 Uiso 1 1 calc R
C10 C 0.6421(2) 0.2327(2) -0.35709(18) 0.0335(6) Uani 1 1 d .
H10 H 0.6236 0.2331 -0.4154 0.040 Uiso 1 1 calc R
C11 C 0.6789(2) 0.3194(2) -0.29335(19) 0.0336(6) Uani 1 1 d .
H11 H 0.6860 0.3794 -0.3075 0.040 Uiso 1 1 calc R
C12 C 0.7056(2) 0.31887(19) -0.20787(17) 0.0266(5) Uani 1 1 d .
H12 H 0.7311 0.3789 -0.1637 0.032 Uiso 1 1 calc R
C13 C 0.73997(15) 0.35398(14) -0.01511(13) 0.0139(3) Uani 1 1 d .
C14 C 0.83699(16) 0.42802(16) -0.00239(16) 0.0216(4) Uani 1 1 d .
H14 H 0.8949 0.4114 -0.0207 0.026 Uiso 1 1 calc R
C15 C 0.85006(16) 0.52521(15) 0.03649(16) 0.0212(4) Uani 1 1 d .
H15 H 0.9165 0.5744 0.0450 0.025 Uiso 1 1 calc R
C16 C 0.76541(16) 0.55001(15) 0.06279(14) 0.0171(4) Uani 1 1 d .
H16 H 0.7733 0.6165 0.0884 0.021 Uiso 1 1 calc R
C17 C 0.66915(15) 0.47734(14) 0.05158(13) 0.0143(3) Uani 1 1 d .
H17 H 0.6118 0.4947 0.0704 0.017 Uiso 1 1 calc R
C18 C 0.65492(14) 0.37886(13) 0.01308(12) 0.0118(3) Uani 1 1 d .
C19 C 0.47808(15) 0.33906(14) 0.09688(13) 0.0143(3) Uani 1 1 d .
C20 C 0.52712(17) 0.34938(15) 0.18139(13) 0.0180(4) Uani 1 1 d .
C21 C 0.4852(2) 0.38760(16) 0.25109(15) 0.0247(5) Uani 1 1 d .
H21 H 0.5180 0.3956 0.3084 0.030 Uiso 1 1 calc R
C22 C 0.3966(2) 0.41424(17) 0.23864(16) 0.0274(5) Uani 1 1 d .
H22 H 0.3692 0.4398 0.2871 0.033 Uiso 1 1 calc R
C23 C 0.34815(19) 0.40341(17) 0.15547(17) 0.0252(5) Uani 1 1 d .
H23 H 0.2873 0.4211 0.1466 0.030 Uiso 1 1 calc R
C24 C 0.38933(16) 0.36633(15) 0.08487(14) 0.0187(4) Uani 1 1 d .
H24 H 0.3566 0.3595 0.0278 0.022 Uiso 1 1 calc R
C25 C 0.44695(14) 0.29019(14) -0.09106(12) 0.0134(3) Uani 1 1 d .
C26 C 0.34717(15) 0.21806(15) -0.12289(13) 0.0162(3) Uani 1 1 d .
C27 C 0.28901(16) 0.21846(16) -0.19935(14) 0.0202(4) Uani 1 1 d .
H27 H 0.2220 0.1699 -0.2214 0.024 Uiso 1 1 calc R
C28 C 0.32640(18) 0.28755(18) -0.24360(14) 0.0231(4) Uani 1 1 d .
H28 H 0.2856 0.2861 -0.2955 0.028 Uiso 1 1 calc R
C29 C 0.42422(18) 0.35920(17) -0.21168(14) 0.0208(4) Uani 1 1 d .
H29 H 0.4501 0.4074 -0.2414 0.025 Uiso 1 1 calc R
C30 C 0.48397(16) 0.36002(15) -0.13613(13) 0.0163(3) Uani 1 1 d .
H30 H 0.5510 0.4088 -0.1148 0.020 Uiso 1 1 calc R
C31 C 0.84766(19) 0.2301(2) 0.10315(15) 0.0264(5) Uani 1 1 d .
H31A H 0.8884 0.2891 0.1492 0.032 Uiso 1 1 calc R
H31B H 0.8407 0.1722 0.1245 0.032 Uiso 1 1 calc R
H31C H 0.7780 0.2330 0.0856 0.032 Uiso 1 1 calc R
C32 C 0.6553(2) 0.04676(18) -0.23440(16) 0.0292(5) Uani 1 1 d .
H32A H 0.6090 0.0334 -0.1925 0.035 Uiso 1 1 calc R
H32B H 0.7257 0.0500 -0.2106 0.035 Uiso 1 1 calc R
H32C H 0.6282 -0.0057 -0.2885 0.035 Uiso 1 1 calc R
C33 C 0.62257(18) 0.32052(16) 0.19818(14) 0.0221(4) Uani 1 1 d .
H33A H 0.6072 0.2698 0.2293 0.027 Uiso 1 1 calc R
H33B H 0.6807 0.3779 0.2333 0.027 Uiso 1 1 calc R
H33C H 0.6419 0.2952 0.1429 0.027 Uiso 1 1 calc R
C34 C 0.30228(16) 0.14210(16) -0.07670(15) 0.0210(4) Uani 1 1 d .
H34A H 0.2883 0.0767 -0.1152 0.025 Uiso 1 1 calc R
H34B H 0.2369 0.1482 -0.0600 0.025 Uiso 1 1 calc R
H34C H 0.3524 0.1518 -0.0247 0.025 Uiso 1 1 calc R
C35 C 1.26328(16) 0.25152(17) 0.43322(14) 0.0205(4) Uani 1 1 d .
C36 C 1.31535(18) 0.1998(2) 0.47387(15) 0.0277(5) Uani 1 1 d .
C37 C 1.4030(2) 0.2542(3) 0.53822(17) 0.0413(8) Uani 1 1 d .
H37 H 1.4380 0.2207 0.5674 0.050 Uiso 1 1 calc R
C38 C 1.4403(2) 0.3553(3) 0.56066(18) 0.0450(8) Uani 1 1 d .
H38 H 1.5003 0.3901 0.6046 0.054 Uiso 1 1 calc R
C39 C 1.3909(2) 0.4057(2) 0.51963(17) 0.0380(7) Uani 1 1 d .
H39 H 1.4168 0.4752 0.5346 0.046 Uiso 1 1 calc R
C40 C 1.30203(18) 0.35340(19) 0.45556(15) 0.0264(5) Uani 1 1 d .
H40 H 1.2677 0.3878 0.4269 0.032 Uiso 1 1 calc R
C41 C 1.17839(16) 0.13561(15) 0.25605(13) 0.0166(4) Uani 1 1 d .
C42 C 1.10038(18) 0.07030(15) 0.18647(14) 0.0197(4) Uani 1 1 d .
C43 C 1.1311(2) 0.03479(16) 0.10907(15) 0.0239(4) Uani 1 1 d .
H43 H 1.0791 -0.0089 0.0614 0.029 Uiso 1 1 calc R
C44 C 1.2351(2) 0.06152(17) 0.09975(16) 0.0275(5) Uani 1 1 d .
H44 H 1.2541 0.0345 0.0470 0.033 Uiso 1 1 calc R
C45 C 1.3114(2) 0.12790(18) 0.16772(16) 0.0269(5) Uani 1 1 d .
H45 H 1.3827 0.1483 0.1612 0.032 Uiso 1 1 calc R
C46 C 1.28278(18) 0.16446(16) 0.24577(15) 0.0220(4) Uani 1 1 d .
H46 H 1.3351 0.2096 0.2925 0.026 Uiso 1 1 calc R
C47 C 1.09089(15) 0.27757(14) 0.33365(13) 0.0151(3) Uani 1 1 d .
C48 C 1.13230(16) 0.32570(15) 0.27288(14) 0.0182(4) Uani 1 1 d .
H48 H 1.1830 0.3067 0.2436 0.022 Uiso 1 1 calc R
C49 C 1.10068(19) 0.40054(17) 0.25477(15) 0.0233(4) Uani 1 1 d .
H49 H 1.1304 0.4331 0.2141 0.028 Uiso 1 1 calc R
C50 C 1.0253(2) 0.42781(18) 0.29636(16) 0.0253(4) Uani 1 1 d .
H50 H 1.0039 0.4796 0.2848 0.030 Uiso 1 1 calc R
C51 C 0.98149(19) 0.37912(17) 0.35460(15) 0.0230(4) Uani 1 1 d .
H51 H 0.9287 0.3969 0.3816 0.028 Uiso 1 1 calc R
C52 C 1.01336(16) 0.30386(15) 0.37475(13) 0.0164(3) Uani 1 1 d .
C53 C 1.02618(16) 0.32647(15) 0.55790(13) 0.0167(4) Uani 1 1 d .
C54 C 1.00202(18) 0.30119(16) 0.63449(14) 0.0195(4) Uani 1 1 d .
C55 C 1.0683(2) 0.35775(17) 0.71292(14) 0.0238(4) Uani 1 1 d .
H55 H 1.0528 0.3416 0.7651 0.029 Uiso 1 1 calc R
C56 C 1.1559(2) 0.43673(18) 0.71644(15) 0.0269(5) Uani 1 1 d .
H56 H 1.2005 0.4731 0.7704 0.032 Uiso 1 1 calc R
C57 C 1.1787(2) 0.46281(17) 0.64132(15) 0.0251(4) Uani 1 1 d .
H57 H 1.2384 0.5174 0.6435 0.030 Uiso 1 1 calc R
C58 C 1.11336(18) 0.40822(16) 0.56272(14) 0.0201(4) Uani 1 1 d .
H58 H 1.1281 0.4267 0.5113 0.024 Uiso 1 1 calc R
C59 C 0.82480(17) 0.25652(18) 0.44323(14) 0.0207(4) Uani 1 1 d .
C60 C 0.7417(2) 0.1840(2) 0.38174(16) 0.0274(5) Uani 1 1 d .
C61 C 0.6440(2) 0.1968(2) 0.37314(18) 0.0346(6) Uani 1 1 d .
H61 H 0.5870 0.1484 0.3323 0.041 Uiso 1 1 calc R
C62 C 0.6288(2) 0.2790(3) 0.42329(19) 0.0361(6) Uani 1 1 d .
H62 H 0.5619 0.2865 0.4160 0.043 Uiso 1 1 calc R
C63 C 0.7108(2) 0.3501(2) 0.48400(19) 0.0333(6) Uani 1 1 d .
H63 H 0.7004 0.4063 0.5182 0.040 Uiso 1 1 calc R
C64 C 0.8085(2) 0.33834(19) 0.49443(17) 0.0262(5) Uani 1 1 d .
H64 H 0.8645 0.3862 0.5366 0.031 Uiso 1 1 calc R
C65 C 1.2804(2) 0.0898(2) 0.45034(19) 0.0359(6) Uani 1 1 d .
H65A H 1.2633 0.0671 0.5014 0.043 Uiso 1 1 calc R
H65B H 1.3368 0.0679 0.4298 0.043 Uiso 1 1 calc R
H65C H 1.2183 0.0628 0.4045 0.043 Uiso 1 1 calc R
C66 C 0.98625(18) 0.03940(18) 0.19275(16) 0.0262(5) Uani 1 1 d .
H66A H 0.9584 -0.0319 0.1820 0.031 Uiso 1 1 calc R
H66B H 0.9480 0.0594 0.1495 0.031 Uiso 1 1 calc R
H66C H 0.9779 0.0706 0.2508 0.031 Uiso 1 1 calc R
C67 C 0.90747(19) 0.21652(19) 0.63455(15) 0.0245(4) Uani 1 1 d .
H67A H 0.8617 0.2405 0.6702 0.029 Uiso 1 1 calc R
H67B H 0.9299 0.1693 0.6584 0.029 Uiso 1 1 calc R
H67C H 0.8693 0.1846 0.5751 0.029 Uiso 1 1 calc R
C68 C 0.7558(2) 0.0947(2) 0.3250(2) 0.0406(7) Uani 1 1 d .
H68A H 0.7403 0.0939 0.2640 0.049 Uiso 1 1 calc R
H68B H 0.7082 0.0356 0.3349 0.049 Uiso 1 1 calc R
H68C H 0.8283 0.0969 0.3392 0.049 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P2 Ag1 P1 80.864(17) . .
P2 Ag1 Br1 116.304(14) . 2_655
P1 Ag1 Br1 129.179(14) . 2_655
P2 Ag1 Br1 123.701(15) . .
P1 Ag1 Br1 123.092(15) . .
Br1 Ag1 Br1 88.230(10) 2_655 .
P4 Ag2 P3 82.779(18) . .
P4 Ag2 Br2 132.810(16) . 2_756
P3 Ag2 Br2 126.086(15) . 2_756
P4 Ag2 Br2 108.313(14) . .
P3 Ag2 Br2 115.284(15) . .
Br2 Ag2 Br2 92.660(8) 2_756 .
Ag1 Br1 Ag1 91.769(10) 2_655 .
Ag2 Br2 Ag2 87.339(8) 2_756 .
C1 P1 C13 102.76(9) . .
C1 P1 C7 105.02(9) . .
C13 P1 C7 101.05(10) . .
C1 P1 Ag1 125.91(7) . .
C13 P1 Ag1 103.85(6) . .
C7 P1 Ag1 114.74(7) . .
C25 P2 C19 105.11(9) . .
C25 P2 C18 104.41(9) . .
C19 P2 C18 101.88(9) . .
C25 P2 Ag1 112.82(6) . .
C19 P2 Ag1 125.72(7) . .
C18 P2 Ag1 104.49(6) . .
C35 P3 C41 104.43(9) . .
C35 P3 C47 103.57(10) . .
C41 P3 C47 101.41(9) . .
C35 P3 Ag2 108.81(7) . .
C41 P3 Ag2 130.28(7) . .
C47 P3 Ag2 105.39(7) . .
C53 P4 C59 105.22(10) . .
C53 P4 C52 103.46(9) . .
C59 P4 C52 101.80(10) . .
C53 P4 Ag2 105.68(7) . .
C59 P4 Ag2 132.03(8) . .
C52 P4 Ag2 105.55(7) . .
C6 C1 C2 119.57(18) . .
C6 C1 P1 120.72(15) . .
C2 C1 P1 119.66(15) . .
C3 C2 C1 118.35(19) . .
C3 C2 C31 119.5(2) . .
C1 C2 C31 122.16(18) . .
C4 C3 C2 121.5(2) . .
C5 C4 C3 120.0(2) . .
C4 C5 C6 119.6(2) . .
C5 C6 C1 121.0(2) . .
C8 C7 C12 118.6(2) . .
C8 C7 P1 120.15(17) . .
C12 C7 P1 121.20(18) . .
C7 C8 C9 119.5(2) . .
C7 C8 C32 121.3(2) . .
C9 C8 C32 119.2(2) . .
C10 C9 C8 120.6(3) . .
C11 C10 C9 121.0(3) . .
C10 C11 C12 119.6(3) . .
C11 C12 C7 120.7(2) . .
C14 C13 C18 119.09(18) . .
C14 C13 P1 120.49(15) . .
C18 C13 P1 120.36(14) . .
C15 C14 C13 121.28(19) . .
C16 C15 C14 119.59(19) . .
C17 C16 C15 119.79(19) . .
C16 C17 C18 121.30(18) . .
C17 C18 C13 118.94(17) . .
C17 C18 P2 119.86(14) . .
C13 C18 P2 121.17(14) . .
C24 C19 C20 119.74(19) . .
C24 C19 P2 120.71(16) . .
C20 C19 P2 119.48(15) . .
C21 C20 C19 118.4(2) . .
C21 C20 C33 119.6(2) . .
C19 C20 C33 122.04(19) . .
C22 C21 C20 121.6(2) . .
C23 C22 C21 119.9(2) . .
C22 C23 C24 119.5(2) . .
C23 C24 C19 120.9(2) . .
C30 C25 C26 119.24(18) . .
C30 C25 P2 121.71(15) . .
C26 C25 P2 118.91(15) . .
C27 C26 C25 118.59(19) . .
C27 C26 C34 119.60(18) . .
C25 C26 C34 121.81(18) . .
C28 C27 C26 121.8(2) . .
C27 C28 C29 119.6(2) . .
C30 C29 C28 119.8(2) . .
C29 C30 C25 121.01(19) . .
C40 C35 C36 119.9(2) . .
C40 C35 P3 121.61(18) . .
C36 C35 P3 118.30(19) . .
C37 C36 C35 117.8(3) . .
C37 C36 C65 119.5(3) . .
C35 C36 C65 122.7(2) . .
C38 C37 C36 121.9(3) . .
C39 C38 C37 120.3(2) . .
C38 C39 C40 119.2(3) . .
C35 C40 C39 120.9(3) . .
C46 C41 C42 119.80(19) . .
C46 C41 P3 121.48(16) . .
C42 C41 P3 118.72(16) . .
C43 C42 C41 118.2(2) . .
C43 C42 C66 119.6(2) . .
C41 C42 C66 122.2(2) . .
C44 C43 C42 121.9(2) . .
C43 C44 C45 119.7(2) . .
C44 C45 C46 119.5(2) . .
C41 C46 C45 120.9(2) . .
C48 C47 C52 119.14(19) . .
C48 C47 P3 119.43(15) . .
C52 C47 P3 121.42(15) . .
C49 C48 C47 121.2(2) . .
C48 C49 C50 119.7(2) . .
C51 C50 C49 119.7(2) . .
C50 C51 C52 121.5(2) . .
C51 C52 C47 118.65(19) . .
C51 C52 P4 119.87(16) . .
C47 C52 P4 121.48(15) . .
C58 C53 C54 119.42(19) . .
C58 C53 P4 121.13(15) . .
C54 C53 P4 118.90(16) . .
C55 C54 C53 118.3(2) . .
C55 C54 C67 119.4(2) . .
C53 C54 C67 122.3(2) . .
C56 C55 C54 121.6(2) . .
C55 C56 C57 120.1(2) . .
C56 C57 C58 119.3(2) . .
C57 C58 C53 121.2(2) . .
C64 C59 C60 120.2(2) . .
C64 C59 P4 120.78(18) . .
C60 C59 P4 119.00(18) . .
C61 C60 C59 118.2(3) . .
C61 C60 C68 119.8(2) . .
C59 C60 C68 122.0(2) . .
C62 C61 C60 121.3(3) . .
C63 C62 C61 120.3(2) . .
C62 C63 C64 119.5(3) . .
C63 C64 C59 120.5(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P2 2.5333(6) .
Ag1 P1 2.5388(5) .
Ag1 Br1 2.6917(3) 2_655
Ag1 Br1 2.6953(3) .
Ag2 P4 2.5156(6) .
Ag2 P3 2.5180(6) .
Ag2 Br2 2.6134(4) 2_756
Ag2 Br2 2.7726(4) .
Br1 Ag1 2.6917(3) 2_655
Br2 Ag2 2.6134(4) 2_756
P1 C1 1.831(2) .
P1 C13 1.837(2) .
P1 C7 1.841(2) .
P2 C25 1.828(2) .
P2 C19 1.831(2) .
P2 C18 1.8377(19) .
P3 C35 1.831(2) .
P3 C41 1.832(2) .
P3 C47 1.841(2) .
P4 C53 1.821(2) .
P4 C59 1.834(2) .
P4 C52 1.840(2) .
C1 C6 1.400(3) .
C1 C2 1.411(3) .
C2 C3 1.400(3) .
C2 C31 1.511(3) .
C3 C4 1.391(3) .
C4 C5 1.383(3) .
C5 C6 1.396(3) .
C7 C8 1.395(3) .
C7 C12 1.418(3) .
C8 C9 1.407(3) .
C8 C32 1.502(4) .
C9 C10 1.375(4) .
C10 C11 1.372(4) .
C11 C12 1.391(4) .
C13 C14 1.402(3) .
C13 C18 1.405(3) .
C14 C15 1.390(3) .
C15 C16 1.389(3) .
C16 C17 1.389(3) .
C17 C18 1.402(3) .
C19 C24 1.397(3) .
C19 C20 1.410(3) .
C20 C21 1.395(3) .
C20 C33 1.507(3) .
C21 C22 1.391(4) .
C22 C23 1.385(4) .
C23 C24 1.394(3) .
C25 C30 1.398(3) .
C25 C26 1.412(3) .
C26 C27 1.399(3) .
C26 C34 1.501(3) .
C27 C28 1.381(3) .
C28 C29 1.391(3) .
C29 C30 1.391(3) .
C35 C40 1.392(3) .
C35 C36 1.410(3) .
C36 C37 1.396(4) .
C36 C65 1.504(4) .
C37 C38 1.382(5) .
C38 C39 1.376(5) .
C39 C40 1.399(3) .
C41 C46 1.394(3) .
C41 C42 1.407(3) .
C42 C43 1.396(3) .
C42 C66 1.503(3) .
C43 C44 1.385(4) .
C44 C45 1.387(4) .
C45 C46 1.395(3) .
C47 C48 1.403(3) .
C47 C52 1.407(3) .
C48 C49 1.387(3) .
C49 C50 1.392(3) .
C50 C51 1.384(3) .
C51 C52 1.406(3) .
C53 C58 1.401(3) .
C53 C54 1.409(3) .
C54 C55 1.399(3) .
C54 C67 1.505(3) .
C55 C56 1.385(4) .
C56 C57 1.387(3) .
C57 C58 1.390(3) .
C59 C64 1.400(3) .
C59 C60 1.409(3) .
C60 C61 1.399(4) .
C60 C68 1.510(4) .
C61 C62 1.391(5) .
C62 C63 1.388(5) .
C63 C64 1.393(3) .
