#------------------------------------------------------------------------------
#$Date: 2017-10-24 05:23:56 +0300 (Tue, 24 Oct 2017) $
#$Revision: 202262 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/45/7044515.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7044515
loop_
_publ_author_name
'Bertrand, Benoît'
'Romanov, Alexander S.'
'Brooks, Mark'
'Schmidt, Claudia'
'Ott, Ingo'
'O'Connell, Maria Anne'
'Bochmann, Manfred'
_publ_section_title
;
 Synthesis, Structure and Cytotoxicity of Cyclic (Alkyl)(Amino) Carbene
 and Acyclic Carbene Complexes of Group 11 metals
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT03189K
_journal_year                    2017
_chemical_formula_moiety         'C19 H30 Au N5 P, F6 P, C H2 Cl2'
_chemical_formula_sum            'C20 H32 Au Cl2 F6 N5 P2'
_chemical_formula_weight         786.31
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2017-08-10 deposited with the CCDC.
2017-10-23 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 106.059(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.6153(2)
_cell_length_b                   12.5760(2)
_cell_length_c                   16.6816(3)
_cell_measurement_reflns_used    14929
_cell_measurement_temperature    140.0(8)
_cell_measurement_theta_max      32.1620
_cell_measurement_theta_min      3.4220
_cell_volume                     2744.86(8)
_computing_cell_refinement
;                                                                         
CrysAlisPro, Agilent Technologies,                                        
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)                 
(compiled Sep 14 2012,17:21:16)                                           
;
_computing_data_collection
;                                                                         
CrysAlisPro, Agilent Technologies,                                        
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)                 
(compiled Sep 14 2012,17:21:16)                                           
;
_computing_data_reduction
;                                                                         
CrysAlisPro, Agilent Technologies,                                        
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)                 
(compiled Sep 14 2012,17:21:16)                                           
;
_computing_molecular_graphics    'ORTEP (Johnson, 1976 and Farrugia, 1997)'
_computing_publication_material
'SHELXL-97 (Sheldrick, 2008) and WINGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      140.0(8)
_diffrn_detector_area_resol_mean 16.0050
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur 3/Sapphire3 CCD'
_diffrn_measurement_method       'Thin slice ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0270
_diffrn_reflns_av_sigmaI/netI    0.0226
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            28505
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         3.43
_exptl_absorpt_coefficient_mu    5.732
_exptl_absorpt_correction_T_max  0.7249
_exptl_absorpt_correction_T_min  0.4252
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;                                                             
 CrysAlisPro RED, Oxford Diffraction Ltd., Version 1.171.33.66
 Empirical absorption correction using spherical harmonics,   
  implemented in SCALE3 ABSPACK scaling algorithm.            
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.903
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1536
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CH2Cl2, hexane'
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.927
_refine_diff_density_min         -0.829
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     355
_refine_ls_number_reflns         6603
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0264
_refine_ls_R_factor_gt           0.0234
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0300P)²+2.5000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0579
_refine_ls_wR_factor_ref         0.0596
_reflns_number_gt                6075
_reflns_number_total             6603
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            c7dt03189k2.cif
_cod_data_source_block           11a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7044515
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.420104(8) 0.281635(8) 0.566535(6) 0.02543(5) Uani 1 1 d . . .
P2 P 0.01986(6) 0.80143(6) 0.21373(5) 0.02515(15) Uani 1 1 d . . .
F4 F -0.00526(19) 0.71212(16) 0.27226(15) 0.0528(6) Uani 1 1 d . . .
F3 F -0.08228(17) 0.77222(19) 0.14281(14) 0.0517(6) Uani 1 1 d . . .
F6 F 0.08312(18) 0.71814(17) 0.17649(16) 0.0524(6) Uani 1 1 d . . .
F5 F -0.04406(17) 0.88601(16) 0.25048(14) 0.0487(5) Uani 1 1 d . . .
F2 F 0.04542(19) 0.8922(2) 0.15541(16) 0.0633(7) Uani 1 1 d . . .
F1 F 0.12021(17) 0.8309(2) 0.28403(16) 0.0650(7) Uani 1 1 d . . .
P1 P 0.31265(5) 0.41015(6) 0.49680(4) 0.02377(15) Uani 1 1 d . . .
N5 N 0.16233(17) 0.47027(17) 0.35700(13) 0.0217(5) Uani 1 1 d . . .
N2 N 0.58136(17) 0.11496(18) 0.59880(14) 0.0240(5) Uani 1 1 d . . .
N1 N 0.52259(17) 0.14778(18) 0.71156(14) 0.0229(5) Uani 1 1 d . . .
N4 N 0.28671(17) 0.60835(18) 0.42612(15) 0.0246(5) Uani 1 1 d . . .
C16 C 0.2259(2) 0.3779(2) 0.39353(16) 0.0220(5) Uani 1 1 d . . .
H16A H 0.2658 0.3557 0.3565 0.026 Uiso 1 1 calc R . .
H16B H 0.1820 0.3192 0.3990 0.026 Uiso 1 1 calc R . .
C19 C 0.2268(2) 0.5615(2) 0.34728(17) 0.0243(6) Uani 1 1 d . . .
H19A H 0.2733 0.5383 0.3160 0.029 Uiso 1 1 calc R . .
H19B H 0.1832 0.6162 0.3148 0.029 Uiso 1 1 calc R . .
N3 N 0.15474(19) 0.5483(2) 0.49178(15) 0.0290(5) Uani 1 1 d . . .
C2 C 0.4548(2) 0.1998(2) 0.75104(17) 0.0222(5) Uani 1 1 d . . .
C15 C 0.3673(2) 0.5354(2) 0.47114(17) 0.0256(6) Uani 1 1 d . . .
H15A H 0.4070 0.5691 0.5221 0.031 Uiso 1 1 calc R . .
H15B H 0.4129 0.5201 0.4370 0.031 Uiso 1 1 calc R . .
C1 C 0.5200(2) 0.1681(2) 0.63220(17) 0.0228(5) Uani 1 1 d . . .
C18 C 0.0979(2) 0.5038(2) 0.41092(18) 0.0262(6) Uani 1 1 d . . .
H18A H 0.0494 0.5567 0.3813 0.031 Uiso 1 1 calc R . .
H18B H 0.0591 0.4429 0.4207 0.031 Uiso 1 1 calc R . .
C17 C 0.2177(2) 0.6370(2) 0.47606(19) 0.0300(6) Uani 1 1 d . . .
H17A H 0.1727 0.6934 0.4477 0.036 Uiso 1 1 calc R . .
H17B H 0.2580 0.6649 0.5292 0.036 Uiso 1 1 calc R . .
C7 C 0.3708(2) 0.1439(2) 0.76182(18) 0.0281(6) Uani 1 1 d . . .
C10 C 0.6549(2) 0.0332(2) 0.64241(17) 0.0263(6) Uani 1 1 d . . .
H10A H 0.6207 -0.0224 0.6648 0.032 Uiso 1 1 calc R . .
H10B H 0.7079 0.0643 0.6876 0.032 Uiso 1 1 calc R . .
C13 C 0.5910(2) 0.1345(3) 0.51401(18) 0.0316(6) Uani 1 1 d . . .
H13A H 0.5935 0.2101 0.5031 0.038 Uiso 1 1 calc R . .
H13B H 0.5345 0.1031 0.4721 0.038 Uiso 1 1 calc R . .
C3 C 0.4742(3) 0.3059(2) 0.77707(19) 0.0319(7) Uani 1 1 d . . .
C14 C 0.2179(2) 0.4667(3) 0.54539(18) 0.0313(6) Uani 1 1 d . . .
H14A H 0.1741 0.4104 0.5555 0.038 Uiso 1 1 calc R . .
H14B H 0.2531 0.4981 0.5987 0.038 Uiso 1 1 calc R . .
C6 C 0.3040(3) 0.1957(3) 0.7978(2) 0.0402(8) Uani 1 1 d . . .
H6A H 0.2477 0.1596 0.8054 0.048 Uiso 1 1 calc R . .
C11 C 0.6993(3) -0.0103(3) 0.5748(2) 0.0384(7) Uani 1 1 d . . .
H11A H 0.7700 -0.0314 0.5979 0.046 Uiso 1 1 calc R . .
H11B H 0.6604 -0.0711 0.5472 0.046 Uiso 1 1 calc R . .
C8 C 0.5661(3) 0.3651(3) 0.7670(2) 0.0410(8) Uani 1 1 d . . .
H8A H 0.6263 0.3229 0.7890 0.062 Uiso 1 1 calc R . .
H8B H 0.5728 0.4312 0.7968 0.062 Uiso 1 1 calc R . .
H8C H 0.5579 0.3789 0.7089 0.062 Uiso 1 1 calc R . .
C4 C 0.4040(3) 0.3546(3) 0.8120(2) 0.0471(9) Uani 1 1 d . . .
H4A H 0.4139 0.4252 0.8288 0.057 Uiso 1 1 calc R . .
C9 C 0.3516(3) 0.0305(3) 0.7340(2) 0.0397(8) Uani 1 1 d . . .
H9A H 0.3481 0.0252 0.6759 0.060 Uiso 1 1 calc R . .
H9B H 0.2882 0.0069 0.7425 0.060 Uiso 1 1 calc R . .
H9C H 0.4063 -0.0134 0.7658 0.060 Uiso 1 1 calc R . .
C12 C 0.6909(3) 0.0812(3) 0.5152(2) 0.0449(8) Uani 1 1 d . . .
H12A H 0.6898 0.0560 0.4600 0.054 Uiso 1 1 calc R . .
H12B H 0.7477 0.1300 0.5346 0.054 Uiso 1 1 calc R . .
C5 C 0.3204(3) 0.3012(3) 0.8225(3) 0.0502(10) Uani 1 1 d . . .
H5A H 0.2747 0.3356 0.8462 0.060 Uiso 1 1 calc R . .
Cl2 Cl -0.19478(18) 0.84668(18) 0.45114(15) 0.0588(5) Uani 0.60 1 d PD A 1
Cl1 Cl -0.00534(15) 0.7400(2) 0.48398(15) 0.0713(6) Uani 0.60 1 d PD A 1
C1S C -0.0912(6) 0.8182(7) 0.4147(5) 0.074(3) Uani 0.60 1 d PD A 1
H1SA H -0.1142 0.7818 0.3615 0.088 Uiso 0.60 1 calc PR A 1
H1SB H -0.0583 0.8839 0.4059 0.088 Uiso 0.60 1 calc PR A 1
Cl1' Cl 0.03955(18) 0.9336(2) 0.46735(14) 0.0513(6) Uani 0.40 1 d PD . 2
Cl2' Cl -0.1497(2) 0.8293(3) 0.4647(3) 0.0608(9) Uani 0.40 1 d PD B 2
C1S' C -0.0270(5) 0.8169(5) 0.4567(5) 0.0319(17) Uani 0.40 1 d PD B 2
H1SC H 0.0100 0.7677 0.4991 0.038 Uiso 0.40 1 calc PR B 2
H1SD H -0.0296 0.7864 0.4027 0.038 Uiso 0.40 1 calc PR B 2
H1A H 0.5668 0.1035 0.7381 0.038(10) Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C1 Au1 P1 178.38(8) .
F1 P2 F4 89.94(14) .
F1 P2 F6 89.66(14) .
F4 P2 F6 90.36(13) .
F1 P2 F2 89.70(15) .
F4 P2 F2 179.49(15) .
F6 P2 F2 90.00(13) .
F1 P2 F5 90.56(14) .
F4 P2 F5 90.12(13) .
F6 P2 F5 179.47(13) .
F2 P2 F5 89.52(12) .
F1 P2 F3 179.54(15) .
F4 P2 F3 90.07(14) .
F6 P2 F3 90.80(13) .
F2 P2 F3 90.28(14) .
F5 P2 F3 88.98(12) .
C15 P1 C16 99.58(12) .
C15 P1 C14 98.56(14) .
C16 P1 C14 98.64(13) .
C15 P1 Au1 118.86(9) .
C16 P1 Au1 118.48(9) .
C14 P1 Au1 118.61(10) .
C16 N5 C19 110.9(2) .
C16 N5 C18 110.6(2) .
C19 N5 C18 108.3(2) .
C1 N2 C13 124.0(2) .
C1 N2 C10 124.8(2) .
C13 N2 C10 111.1(2) .
C1 N1 C2 121.6(2) .
C17 N4 C19 108.9(2) .
C17 N4 C15 111.7(2) .
C19 N4 C15 111.1(2) .
N5 C16 P1 111.30(17) .
N5 C16 H16A 109.4 .
P1 C16 H16A 109.4 .
N5 C16 H16B 109.4 .
P1 C16 H16B 109.4 .
H16A C16 H16B 108.0 .
N4 C19 N5 114.4(2) .
N4 C19 H19A 108.7 .
N5 C19 H19A 108.7 .
N4 C19 H19B 108.7 .
N5 C19 H19B 108.7 .
H19A C19 H19B 107.6 .
C18 N3 C14 111.3(2) .
C18 N3 C17 108.0(2) .
C14 N3 C17 111.4(2) .
C7 C2 C3 121.9(3) .
C7 C2 N1 119.0(2) .
C3 C2 N1 119.1(3) .
N4 C15 P1 111.13(19) .
N4 C15 H15A 109.4 .
P1 C15 H15A 109.4 .
N4 C15 H15B 109.4 .
P1 C15 H15B 109.4 .
H15A C15 H15B 108.0 .
N2 C1 N1 118.6(2) .
N2 C1 Au1 122.12(19) .
N1 C1 Au1 119.3(2) .
N3 C18 N5 114.6(2) .
N3 C18 H18A 108.6 .
N5 C18 H18A 108.6 .
N3 C18 H18B 108.6 .
N5 C18 H18B 108.6 .
H18A C18 H18B 107.6 .
N4 C17 N3 114.3(2) .
N4 C17 H17A 108.7 .
N3 C17 H17A 108.7 .
N4 C17 H17B 108.7 .
N3 C17 H17B 108.7 .
H17A C17 H17B 107.6 .
C6 C7 C2 118.6(3) .
C6 C7 C9 120.2(3) .
C2 C7 C9 121.1(3) .
N2 C10 C11 103.8(2) .
N2 C10 H10A 111.0 .
C11 C10 H10A 111.0 .
N2 C10 H10B 111.0 .
C11 C10 H10B 111.0 .
H10A C10 H10B 109.0 .
N2 C13 C12 103.4(2) .
N2 C13 H13A 111.1 .
C12 C13 H13A 111.1 .
N2 C13 H13B 111.1 .
C12 C13 H13B 111.1 .
H13A C13 H13B 109.0 .
C4 C3 C2 117.1(3) .
C4 C3 C8 121.2(3) .
C2 C3 C8 121.7(3) .
N3 C14 P1 111.3(2) .
N3 C14 H14A 109.4 .
P1 C14 H14A 109.4 .
N3 C14 H14B 109.4 .
P1 C14 H14B 109.4 .
H14A C14 H14B 108.0 .
C7 C6 C5 120.6(3) .
C7 C6 H6A 119.7 .
C5 C6 H6A 119.7 .
C12 C11 C10 104.0(3) .
C12 C11 H11A 111.0 .
C10 C11 H11A 111.0 .
C12 C11 H11B 111.0 .
C10 C11 H11B 111.0 .
H11A C11 H11B 109.0 .
C3 C8 H8A 109.5 .
C3 C8 H8B 109.5 .
H8A C8 H8B 109.5 .
C3 C8 H8C 109.5 .
H8A C8 H8C 109.5 .
H8B C8 H8C 109.5 .
C5 C4 C3 121.8(3) .
C5 C4 H4A 119.1 .
C3 C4 H4A 119.1 .
C7 C9 H9A 109.5 .
C7 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
C7 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
C11 C12 C13 104.6(3) .
C11 C12 H12A 110.8 .
C13 C12 H12A 110.8 .
C11 C12 H12B 110.8 .
C13 C12 H12B 110.8 .
H12A C12 H12B 108.9 .
C4 C5 C6 119.9(3) .
C4 C5 H5A 120.0 .
C6 C5 H5A 120.0 .
Cl1 C1S Cl2 110.8(4) .
Cl1 C1S H1SA 109.5 .
Cl2 C1S H1SA 109.5 .
Cl1 C1S H1SB 109.5 .
Cl2 C1S H1SB 109.5 .
H1SA C1S H1SB 108.1 .
C1S' Cl1' Cl1' 110.7(3) 3_576
Cl1' C1S' Cl2' 114.4(4) .
Cl1' C1S' H1SC 108.7 .
Cl2' C1S' H1SC 108.7 .
Cl1' C1S' H1SD 108.7 .
Cl2' C1S' H1SD 108.7 .
H1SC C1S' H1SD 107.6 .
Cl1' C1S' H1A 108.5 .
Cl2' C1S' H1A 126.5 .
H1SC C1S' H1A 24.3 .
H1SD C1S' H1A 85.2 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C1 2.065(3) .
Au1 P1 2.2725(7) .
P2 F1 1.579(2) .
P2 F4 1.586(2) .
P2 F6 1.588(2) .
P2 F2 1.599(2) .
P2 F5 1.600(2) .
P2 F3 1.599(2) .
P1 C15 1.842(3) .
P1 C16 1.844(3) .
P1 C14 1.846(3) .
N5 C16 1.476(3) .
N5 C19 1.481(3) .
N5 C18 1.481(4) .
N2 C1 1.308(4) .
N2 C13 1.477(4) .
N2 C10 1.479(3) .
N1 C1 1.339(3) .
N1 C2 1.431(4) .
N4 C17 1.463(4) .
N4 C19 1.466(3) .
N4 C15 1.468(3) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
N3 C18 1.468(4) .
N3 C14 1.471(4) .
N3 C17 1.474(4) .
C2 C7 1.397(4) .
C2 C3 1.406(4) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C7 C6 1.382(5) .
C7 C9 1.500(4) .
C10 C11 1.521(4) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C13 C12 1.511(5) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C3 C4 1.392(5) .
C3 C8 1.505(5) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C6 C5 1.389(5) .
C6 H6A 0.9300 .
C11 C12 1.505(5) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C4 C5 1.374(6) .
C4 H4A 0.9300 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C5 H5A 0.9300 .
Cl2 C1S 1.720(6) .
Cl1 C1S 1.710(6) .
C1S H1SA 0.9700 .
C1S H1SB 0.9700 .
Cl1' C1S' 1.707(6) .
Cl1' Cl1' 2.406(6) 3_576
Cl2' C1S' 1.719(6) .
C1S' H1SC 0.9700 .
C1S' H1SD 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C1 Au1 P1 C15 46(3) .
C1 Au1 P1 C16 167(3) .
C1 Au1 P1 C14 -74(3) .
C19 N5 C16 P1 59.3(3) .
C18 N5 C16 P1 -60.9(2) .
C15 P1 C16 N5 -49.2(2) .
C14 P1 C16 N5 51.1(2) .
Au1 P1 C16 N5 -179.58(15) .
C17 N4 C19 N5 -54.6(3) .
C15 N4 C19 N5 68.8(3) .
C16 N5 C19 N4 -68.0(3) .
C18 N5 C19 N4 53.6(3) .
C1 N1 C2 C7 103.2(3) .
C1 N1 C2 C3 -76.1(3) .
C17 N4 C15 P1 61.1(3) .
C19 N4 C15 P1 -60.8(3) .
C16 P1 C15 N4 49.7(2) .
C14 P1 C15 N4 -50.7(2) .
Au1 P1 C15 N4 179.85(15) .
C13 N2 C1 N1 -175.8(3) .
C10 N2 C1 N1 -0.2(4) .
C13 N2 C1 Au1 4.1(4) .
C10 N2 C1 Au1 179.7(2) .
C2 N1 C1 N2 -177.5(2) .
C2 N1 C1 Au1 2.6(3) .
P1 Au1 C1 N2 -115(3) .
P1 Au1 C1 N1 64(3) .
C14 N3 C18 N5 -67.4(3) .
C17 N3 C18 N5 55.3(3) .
C16 N5 C18 N3 67.5(3) .
C19 N5 C18 N3 -54.3(3) .
C19 N4 C17 N3 55.8(3) .
C15 N4 C17 N3 -67.3(3) .
C18 N3 C17 N4 -55.9(3) .
C14 N3 C17 N4 66.7(3) .
C3 C2 C7 C6 1.2(4) .
N1 C2 C7 C6 -178.1(3) .
C3 C2 C7 C9 -179.7(3) .
N1 C2 C7 C9 1.0(4) .
C1 N2 C10 C11 175.0(3) .
C13 N2 C10 C11 -9.0(3) .
C1 N2 C13 C12 162.6(3) .
C10 N2 C13 C12 -13.5(3) .
C7 C2 C3 C4 -1.9(4) .
N1 C2 C3 C4 177.4(3) .
C7 C2 C3 C8 178.7(3) .
N1 C2 C3 C8 -2.0(4) .
C18 N3 C14 P1 60.4(3) .
C17 N3 C14 P1 -60.2(3) .
C15 P1 C14 N3 50.5(2) .
C16 P1 C14 N3 -50.6(2) .
Au1 P1 C14 N3 -179.83(16) .
C2 C7 C6 C5 0.1(5) .
C9 C7 C6 C5 -179.0(3) .
N2 C10 C11 C12 27.9(3) .
C2 C3 C4 C5 1.3(5) .
C8 C3 C4 C5 -179.2(3) .
C10 C11 C12 C13 -36.9(4) .
N2 C13 C12 C11 30.9(4) .
C3 C4 C5 C6 -0.2(6) .
C7 C6 C5 C4 -0.6(6) .
Cl1' Cl1' C1S' Cl2' 18.1(6) 3_576
