#------------------------------------------------------------------------------
#$Date: 2023-12-22 17:07:40 +0200 (Fri, 22 Dec 2023) $
#$Revision: 288505 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/50/7045029.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7045029
loop_
_publ_author_name
'Tang, Fengzhi'
'Park, Sungho V.'
'Rath, Nigam P.'
'Mirica, Liviu M.'
_publ_section_title
;
 Electronic versus steric effects of pyridinophane ligands on Pd(iii)
 complexes.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1151
_journal_page_last               1158
_journal_paper_doi               10.1039/c7dt04366j
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         ' C18 H24 Cl2 N4 O2 Pd, Cl O4, C2 H3 N'
_chemical_formula_sum            'C20 H27 Cl3 N5 O6 Pd'
_chemical_formula_weight         646.22
_space_group_IT_number           11
_space_group_name_Hall           '-P 2yb'
_space_group_name_H-M_alt        'P 1 21/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2017-10-31 deposited with the CCDC.
2017-12-12 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 102.854(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.0151(7)
_cell_length_b                   9.9646(10)
_cell_length_c                   16.2762(16)
_cell_measurement_reflns_used    9608
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.39
_cell_measurement_theta_min      2.41
_cell_volume                     1267.4(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0430
_diffrn_reflns_av_sigmaI/netI    0.0231
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            31010
_diffrn_reflns_theta_full        27.60
_diffrn_reflns_theta_max         27.60
_diffrn_reflns_theta_min         2.41
_exptl_absorpt_coefficient_mu    1.094
_exptl_absorpt_correction_T_max  0.9166
_exptl_absorpt_correction_T_min  0.7100
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'sadabs v2008/1'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.693
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             654
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.813
_refine_diff_density_min         -0.570
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     207
_refine_ls_number_reflns         3087
_refine_ls_number_restraints     43
_refine_ls_restrained_S_all      1.060
_refine_ls_R_factor_all          0.0349
_refine_ls_R_factor_gt           0.0269
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0264P)²+1.8096P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0607
_refine_ls_wR_factor_ref         0.0656
_reflns_number_gt                2693
_reflns_number_total             3087
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7dt04366j2.cif
_cod_data_source_block           l5112
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_crystal_density_meas' value 'no' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7045029--7045031.cif.

The following automatic conversions were performed:

data name '_iucr_refine_instruction_details' was replaced with
'_iucr_refine_instructions_details' as specified in the replacement
file 'data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 9268 2022-04-12 08:56:07Z antanas 
;
_cod_original_sg_symbol_H-M      P2(1)/m
_cod_database_code               7045029
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.51528(3) 0.7500 0.661882(14) 0.01483(8) Uani 1 2 d S . .
Cl1 Cl 0.65913(8) 0.91802(6) 0.60946(4) 0.02506(13) Uani 1 1 d . . .
O1 O 0.0439(3) 0.4269(3) 0.82663(14) 0.0502(6) Uani 1 1 d D . .
N3 N 0.6663(3) 0.7500 0.80026(17) 0.0185(5) Uani 1 2 d S . .
N1 N 0.3774(2) 0.61738(19) 0.71110(12) 0.0181(4) Uani 1 1 d . . .
N2 N 0.2660(4) 0.7500 0.55941(18) 0.0231(6) Uani 1 2 d S . .
C1 C 0.4280(3) 0.5881(3) 0.79347(15) 0.0232(5) Uani 1 1 d . A .
C2 C 0.3203(3) 0.5224(3) 0.83496(17) 0.0322(6) Uani 1 1 d . . .
H2 H 0.3564 0.5011 0.8931 0.039 Uiso 1 1 calc R A .
C3 C 0.1579(3) 0.4880(3) 0.79024(19) 0.0341(6) Uani 1 1 d . A .
C4 C 0.1062(3) 0.5213(3) 0.70520(18) 0.0302(6) Uani 1 1 d . . .
H4 H -0.0051 0.4982 0.6742 0.036 Uiso 1 1 calc R A .
C5 C 0.2181(3) 0.5877(2) 0.66705(15) 0.0225(5) Uani 1 1 d . A .
C6 C 0.1780(3) 0.6256(3) 0.57554(16) 0.0283(5) Uani 1 1 d . . .
H6A H 0.2127 0.5513 0.5425 0.034 Uiso 1 1 calc R A .
H6B H 0.0529 0.6380 0.5561 0.034 Uiso 1 1 calc R . .
C7 C 0.6084(3) 0.6262(3) 0.83504(16) 0.0296(6) Uani 1 1 d . . .
H7A H 0.6164 0.6386 0.8961 0.036 Uiso 1 1 calc R A .
H7B H 0.6859 0.5517 0.8282 0.036 Uiso 1 1 calc R . .
C8 C 0.2942(6) 0.7500 0.4728(2) 0.0333(9) Uani 1 2 d SD . .
H8A H 0.183(2) 0.7500 0.433(2) 0.050 Uiso 1 2 d SD . .
H8B H 0.361(3) 0.6720(19) 0.4624(17) 0.050 Uiso 1 1 d D . .
C9 C 0.8536(4) 0.7500 0.8136(2) 0.0264(7) Uani 1 2 d SD . .
H9A H 0.917(4) 0.7500 0.8726(7) 0.040 Uiso 1 2 d SD . .
H9B H 0.884(3) 0.6696(17) 0.7856(12) 0.040 Uiso 1 1 d D . .
C10 C 0.0849(7) 0.4143(6) 0.9186(3) 0.0610(14) Uani 0.716(5) 1 d PD A 1
H10A H 0.1861 0.3573 0.9363 0.091 Uiso 0.716(5) 1 calc PR A 1
H10B H -0.0123 0.3738 0.9369 0.091 Uiso 0.716(5) 1 calc PR A 1
H10C H 0.1081 0.5034 0.9441 0.091 Uiso 0.716(5) 1 calc PR A 1
C10A C -0.0972(14) 0.3510(14) 0.7728(6) 0.0610(14) Uani 0.284(5) 1 d PD A -2
H10D H -0.1809 0.4139 0.7406 0.091 Uiso 0.284(5) 1 calc PR A -2
H10E H -0.1528 0.2947 0.8081 0.091 Uiso 0.284(5) 1 calc PR A -2
H10F H -0.0515 0.2942 0.7338 0.091 Uiso 0.284(5) 1 calc PR A -2
N1S N -0.8312(6) 0.2500 0.5812(3) 0.0567(11) Uani 1 2 d S . .
C1S C -0.7005(6) 0.2500 0.6273(3) 0.0381(9) Uani 1 2 d S . .
C2S C -0.5335(6) 0.2500 0.6860(3) 0.0466(11) Uani 1 2 d S . .
H2SA H -0.4679 0.3286 0.6754 0.070 Uiso 0.50 1 calc PR B -1
H2SB H -0.4711 0.1681 0.6781 0.070 Uiso 0.50 1 calc PR B -1
H2SC H -0.5493 0.2532 0.7440 0.070 Uiso 0.50 1 calc PR B -1
Cl2 Cl 0.64297(11) 0.2500 0.96501(5) 0.02450(17) Uani 1 2 d SDU . .
O2 O 0.7916(15) 0.2500 1.0350(10) 0.036(2) Uani 0.147(19) 1 d PDU C 1
O3 O 0.470(2) 0.2500 0.9807(12) 0.0385(19) Uani 0.150(10) 1 d PDU C 1
O4 O 0.6438(6) 0.3869(5) 0.9499(4) 0.0498(10) Uani 0.461(4) 1 d PDU C 1
O2A O 0.7851(9) 0.296(2) 1.0296(4) 0.036(2) Uani 0.353(19) 1 d PDU C -2
O3A O 0.4945(8) 0.3046(14) 0.9893(5) 0.0385(19) Uani 0.350(10) 1 d PDU C -2
O4A O 0.6570(7) 0.3277(6) 0.8913(4) 0.0498(10) Uani 0.460(5) 1 d PDU C -2
O4B O 0.658(3) 0.2500 0.8814(9) 0.0498(10) Uani 0.079(5) 1 d PDU C 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Pd1 N1 82.67(11) 4_575 .
N1 Pd1 N2 79.76(8) 4_575 .
N1 Pd1 N2 79.76(8) . .
N1 Pd1 Cl1 92.00(6) 4_575 .
N1 Pd1 Cl1 174.66(6) . .
N2 Pd1 Cl1 99.04(5) . .
N1 Pd1 Cl1 174.66(6) 4_575 4_575
N1 Pd1 Cl1 92.00(6) . 4_575
N2 Pd1 Cl1 99.04(5) . 4_575
Cl1 Pd1 Cl1 93.33(3) . 4_575
N1 Pd1 N3 79.97(7) 4_575 .
N1 Pd1 N3 79.97(7) . .
N2 Pd1 N3 152.89(10) . .
Cl1 Pd1 N3 99.47(5) . .
Cl1 Pd1 N3 99.47(5) 4_575 .
C3 O1 C10 118.1(3) . .
C3 O1 C10A 118.5(5) . .
C10 O1 C10A 122.1(5) . .
C9 N3 C7 109.99(17) . .
C9 N3 C7 109.99(17) . 4_575
C7 N3 C7 113.6(3) . 4_575
C9 N3 Pd1 116.2(2) . .
C7 N3 Pd1 103.48(15) . .
C7 N3 Pd1 103.48(15) 4_575 .
C1 N1 C5 121.5(2) . .
C1 N1 Pd1 118.16(15) . .
C5 N1 Pd1 118.24(15) . .
C8 N2 C6 110.48(18) . 4_575
C8 N2 C6 110.48(18) . .
C6 N2 C6 114.0(3) 4_575 .
C8 N2 Pd1 113.6(2) . .
C6 N2 Pd1 104.06(15) 4_575 .
C6 N2 Pd1 104.06(15) . .
N1 C1 C2 120.7(2) . .
N1 C1 C7 116.2(2) . .
C2 C1 C7 123.1(2) . .
C1 C2 C3 118.6(2) . .
C1 C2 H2 120.7 . .
C3 C2 H2 120.7 . .
O1 C3 C2 122.2(3) . .
O1 C3 C4 117.7(3) . .
C2 C3 C4 120.0(2) . .
C5 C4 C3 119.0(2) . .
C5 C4 H4 120.5 . .
C3 C4 H4 120.5 . .
N1 C5 C4 120.1(2) . .
N1 C5 C6 116.1(2) . .
C4 C5 C6 123.7(2) . .
N2 C6 C5 112.4(2) . .
N2 C6 H6A 109.1 . .
C5 C6 H6A 109.1 . .
N2 C6 H6B 109.1 . .
C5 C6 H6B 109.1 . .
H6A C6 H6B 107.8 . .
N3 C7 C1 113.1(2) . .
N3 C7 H7A 109.0 . .
C1 C7 H7A 109.0 . .
N3 C7 H7B 109.0 . .
C1 C7 H7B 109.0 . .
H7A C7 H7B 107.8 . .
N2 C8 H8A 109(2) . .
N2 C8 H8B 111.8(18) . .
H8A C8 H8B 109.7(9) . .
N3 C9 H9A 116(2) . .
N3 C9 H9B 106.5(16) . .
H9A C9 H9B 109.2(9) . .
O1 C10 H10A 109.5 . .
O1 C10 H10B 109.5 . .
O1 C10 H10C 109.5 . .
O1 C10A H10D 109.5 . .
O1 C10A H10E 109.5 . .
H10D C10A H10E 109.5 . .
O1 C10A H10F 109.5 . .
H10D C10A H10F 109.5 . .
H10E C10A H10F 109.5 . .
N1S C1S C2S 180.0(5) . .
C1S C2S H2SA 109.5 . .
C1S C2S H2SB 109.5 . .
H2SA C2S H2SB 109.5 . .
C1S C2S H2SC 109.5 . .
H2SA C2S H2SC 109.5 . .
H2SB C2S H2SC 109.5 . .
O4 Cl2 O4 159.5(5) 4_565 .
O4 Cl2 O4B 79.7(2) 4_565 .
O4 Cl2 O4B 79.7(2) . .
O4 Cl2 O3A 73.4(6) 4_565 4_565
O4 Cl2 O3A 117.2(6) . 4_565
O4B Cl2 O3A 121.5(9) . 4_565
O4 Cl2 O2A 114.0(8) 4_565 .
O4 Cl2 O2A 77.5(8) . .
O4B Cl2 O2A 119.2(10) . .
O3A Cl2 O2A 119.1(5) 4_565 .
O4 Cl2 O3A 117.2(6) 4_565 .
O4 Cl2 O3A 73.4(6) . .
O4B Cl2 O3A 121.5(9) . .
O2A Cl2 O3A 104.3(6) . .
O4 Cl2 O2A 77.5(8) 4_565 4_565
O4 Cl2 O2A 114.0(8) . 4_565
O4B Cl2 O2A 119.2(9) . 4_565
O3A Cl2 O2A 104.3(6) 4_565 4_565
O3A Cl2 O2A 119.1(5) . 4_565
O4 Cl2 O4A 47.5(3) 4_565 4_565
O4 Cl2 O4A 112.0(4) . 4_565
O3A Cl2 O4A 104.2(5) 4_565 4_565
O2A Cl2 O4A 125.2(5) . 4_565
O3A Cl2 O4A 130.4(4) . 4_565
O2A Cl2 O4A 103.9(6) 4_565 4_565
O4 Cl2 O4A 112.0(4) 4_565 .
O4 Cl2 O4A 47.5(3) . .
O3A Cl2 O4A 130.4(4) 4_565 .
O2A Cl2 O4A 103.9(6) . .
O3A Cl2 O4A 104.2(5) . .
O2A Cl2 O4A 125.2(5) 4_565 .
O4A Cl2 O4A 64.4(5) 4_565 .
O4 Cl2 O2 95.9(2) 4_565 .
O4 Cl2 O2 95.9(2) . .
O4B Cl2 O2 122.3(11) . .
O3A Cl2 O2 111.6(6) 4_565 .
O3A Cl2 O2 111.6(6) . .
O4A Cl2 O2 116.5(5) 4_565 .
O4A Cl2 O2 116.5(5) . .
O4 Cl2 O3 94.2(3) 4_565 .
O4 Cl2 O3 94.2(2) . .
O4B Cl2 O3 117.4(12) . .
O2A Cl2 O3 119.9(8) . .
O2A Cl2 O3 119.9(8) 4_565 .
O4A Cl2 O3 113.2(7) 4_565 .
O4A Cl2 O3 113.2(7) . .
O2 Cl2 O3 120.3(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 N1 2.0009(18) 4_575
Pd1 N1 2.0009(19) .
Pd1 N2 2.300(3) .
Pd1 Cl1 2.3018(6) .
Pd1 Cl1 2.3018(6) 4_575
Pd1 N3 2.308(3) .
O1 C3 1.340(3) .
O1 C10 1.465(5) .
O1 C10A 1.476(7) .
N3 C9 1.468(4) .
N3 C7 1.475(3) .
N3 C7 1.475(3) 4_575
N1 C1 1.344(3) .
N1 C5 1.351(3) .
N2 C8 1.476(5) .
N2 C6 1.479(3) 4_575
N2 C6 1.479(3) .
C1 C2 1.374(3) .
C1 C7 1.503(3) .
C2 C3 1.385(4) .
C2 H2 0.9500 .
C3 C4 1.394(4) .
C4 C5 1.370(3) .
C4 H4 0.9500 .
C5 C6 1.500(3) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 H8A 0.980(3) .
C8 H8B 0.980(3) .
C9 H9A 0.980(3) .
C9 H9B 0.980(3) .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C10A H10D 0.9800 .
C10A H10E 0.9800 .
C10A H10F 0.9800 .
N1S C1S 1.145(6) .
C1S C2S 1.462(7) .
C2S H2SA 0.9800 .
C2S H2SB 0.9800 .
C2S H2SC 0.9800 .
Cl2 O4 1.387(5) 4_565
Cl2 O4 1.387(5) .
Cl2 O4B 1.391(13) .
Cl2 O3A 1.441(7) 4_565
Cl2 O2A 1.441(8) .
Cl2 O3A 1.441(7) .
Cl2 O2A 1.441(8) 4_565
Cl2 O4A 1.453(5) 4_565
Cl2 O4A 1.453(5) .
Cl2 O2 1.454(12) .
Cl2 O3 1.465(12) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Pd1 N3 C9 -137.88(6) 4_575 .
N1 Pd1 N3 C9 137.88(6) . .
N2 Pd1 N3 C9 180.000(2) . .
Cl1 Pd1 N3 C9 -47.513(19) . .
Cl1 Pd1 N3 C9 47.513(19) 4_575 .
N1 Pd1 N3 C7 101.47(17) 4_575 .
N1 Pd1 N3 C7 17.23(16) . .
N2 Pd1 N3 C7 59.35(16) . .
Cl1 Pd1 N3 C7 -168.16(15) . .
Cl1 Pd1 N3 C7 -73.14(16) 4_575 .
N1 Pd1 N3 C7 -17.23(16) 4_575 4_575
N1 Pd1 N3 C7 -101.47(17) . 4_575
N2 Pd1 N3 C7 -59.35(16) . 4_575
Cl1 Pd1 N3 C7 73.14(16) . 4_575
Cl1 Pd1 N3 C7 168.16(15) 4_575 4_575
N1 Pd1 N1 C1 -81.78(18) 4_575 .
N2 Pd1 N1 C1 -162.64(18) . .
Cl1 Pd1 N1 C1 98.54(17) 4_575 .
N3 Pd1 N1 C1 -0.73(17) . .
N1 Pd1 N1 C5 81.86(18) 4_575 .
N2 Pd1 N1 C5 1.00(17) . .
Cl1 Pd1 N1 C5 -97.83(17) 4_575 .
N3 Pd1 N1 C5 162.91(18) . .
N1 Pd1 N2 C8 137.84(6) 4_575 .
N1 Pd1 N2 C8 -137.84(6) . .
Cl1 Pd1 N2 C8 47.436(19) . .
Cl1 Pd1 N2 C8 -47.436(19) 4_575 .
N3 Pd1 N2 C8 180.000(1) . .
N1 Pd1 N2 C6 17.67(17) 4_575 4_575
N1 Pd1 N2 C6 101.98(18) . 4_575
Cl1 Pd1 N2 C6 -72.74(17) . 4_575
Cl1 Pd1 N2 C6 -167.61(16) 4_575 4_575
N3 Pd1 N2 C6 59.82(17) . 4_575
N1 Pd1 N2 C6 -101.98(18) 4_575 .
N1 Pd1 N2 C6 -17.67(17) . .
Cl1 Pd1 N2 C6 167.61(16) . .
Cl1 Pd1 N2 C6 72.74(17) 4_575 .
N3 Pd1 N2 C6 -59.82(17) . .
C5 N1 C1 C2 2.3(4) . .
Pd1 N1 C1 C2 165.4(2) . .
C5 N1 C1 C7 179.9(2) . .
Pd1 N1 C1 C7 -17.0(3) . .
N1 C1 C2 C3 -0.5(4) . .
C7 C1 C2 C3 -177.9(3) . .
C10 O1 C3 C2 8.9(5) . .
C10A O1 C3 C2 -158.3(7) . .
C10 O1 C3 C4 -168.7(4) . .
C10A O1 C3 C4 24.1(8) . .
C1 C2 C3 O1 -178.3(3) . .
C1 C2 C3 C4 -0.7(4) . .
O1 C3 C4 C5 177.9(3) . .
C2 C3 C4 C5 0.2(4) . .
C1 N1 C5 C4 -2.8(4) . .
Pd1 N1 C5 C4 -165.89(18) . .
C1 N1 C5 C6 -179.9(2) . .
Pd1 N1 C5 C6 17.0(3) . .
C3 C4 C5 N1 1.5(4) . .
C3 C4 C5 C6 178.4(2) . .
C8 N2 C6 C5 152.8(3) . .
C6 N2 C6 C5 -82.1(3) 4_575 .
Pd1 N2 C6 C5 30.5(2) . .
N1 C5 C6 N2 -33.8(3) . .
C4 C5 C6 N2 149.2(2) . .
C9 N3 C7 C1 -154.9(2) . .
C7 N3 C7 C1 81.4(3) 4_575 .
Pd1 N3 C7 C1 -30.1(2) . .
N1 C1 C7 N3 33.7(3) . .
C2 C1 C7 N3 -148.7(3) . .
