#------------------------------------------------------------------------------
#$Date: 2019-11-17 12:18:32 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229830 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/64/7046480.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7046480
loop_
_publ_author_name
'Nahra, Fady'
'Van Hecke, Kristof'
'Kennedy, Alan R.'
'Nelson, David J.'
_publ_section_title
;
 Coinage metal complexes of selenoureas derived from N-heterocyclic
 carbenes.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10671
_journal_page_last               10684
_journal_paper_doi               10.1039/c8dt01506f
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C33.5 H61 Ag1.5 Cl2.5 N6 Se3'
_chemical_formula_weight         1035.19
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-04-16 deposited with the CCDC.
2018-05-30 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90.6640(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.2390(2)
_cell_length_b                   10.43040(10)
_cell_length_c                   27.0621(3)
_cell_measurement_reflns_used    27752
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      75.2670
_cell_measurement_theta_min      3.2460
_cell_volume                     4301.20(8)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_publication_material  'SHELXL 2014'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'SuperNova with Atlas CCD'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0701
_diffrn_reflns_av_unetI/netI     0.0325
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            80612
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         75.587
_diffrn_reflns_theta_min         5.671
_diffrn_source                   microsource
_exptl_absorpt_coefficient_mu    10.089
_exptl_absorpt_correction_T_max  0.906
_exptl_absorpt_correction_T_min  0.827
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Numerical absorption correction based on gaussian integration over
            a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_description       block
_exptl_crystal_F_000             2076
_exptl_crystal_size_max          0.236
_exptl_crystal_size_mid          0.148
_exptl_crystal_size_min          0.103
_refine_diff_density_max         0.889
_refine_diff_density_min         -1.852
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     454
_refine_ls_number_reflns         8840
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0488
_refine_ls_R_factor_gt           0.0388
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0530P)²+10.2651P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1014
_refine_ls_wR_factor_ref         0.1080
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7465
_reflns_number_total             8840
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt01506f2.cif
_cod_data_source_block           fn028
_cod_depositor_comments
'Adding full bibliography for 7046473--7046483.cif.'
_cod_original_formula_sum        'C33.50 H61 Ag1.50 Cl2.50 N6 Se3'
_cod_database_code               7046480
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.51981(2) 0.49480(3) 0.33275(2) 0.02825(9) Uani 1 1 d . . . . .
Se1 Se 0.36228(3) 0.52813(4) 0.29980(2) 0.03062(11) Uani 1 1 d . . . . .
Se2 Se 0.54450(3) 0.54284(4) 0.42417(2) 0.02467(10) Uani 1 1 d . . . . .
Se3 Se 0.63960(3) 0.42017(4) 0.27316(2) 0.02605(11) Uani 1 1 d . . . . .
N1 N 0.2868(2) 0.7252(3) 0.36299(13) 0.0251(7) Uani 1 1 d . . . . .
N2 N 0.2491(2) 0.5315(3) 0.38598(13) 0.0275(7) Uani 1 1 d . . . . .
N3 N 0.7307(2) 0.6038(3) 0.42285(13) 0.0273(7) Uani 1 1 d . . . . .
N4 N 0.7065(2) 0.4018(3) 0.44029(12) 0.0230(7) Uani 1 1 d . . . . .
N5 N 0.5514(2) 0.5050(3) 0.18298(12) 0.0230(7) Uani 1 1 d . . . . .
N6 N 0.5234(2) 0.3042(3) 0.19966(13) 0.0249(7) Uani 1 1 d . . . . .
C1 C 0.2997(3) 0.5976(4) 0.35321(15) 0.0246(8) Uani 1 1 d . . . . .
C2 C 0.2268(3) 0.7371(4) 0.40058(16) 0.0283(9) Uani 1 1 d . . . . .
H2 H 0.2057 0.8151 0.4141 0.034 Uiso 1 1 calc R U . . .
C3 C 0.2036(3) 0.6180(4) 0.41457(17) 0.0297(9) Uani 1 1 d . . . . .
H3 H 0.1630 0.5972 0.4397 0.036 Uiso 1 1 calc R U . . .
C4 C 0.2433(3) 0.3873(4) 0.39352(18) 0.0322(10) Uani 1 1 d . . . . .
C5 C 0.2065(3) 0.3232(4) 0.34711(19) 0.0399(12) Uani 1 1 d . . . . .
H5A H 0.1506 0.3634 0.3378 0.060 Uiso 1 1 calc R U . . .
H5B H 0.1971 0.2318 0.3536 0.060 Uiso 1 1 calc R U . . .
H5C H 0.2483 0.3331 0.3201 0.060 Uiso 1 1 calc R U . . .
C6 C 0.1810(4) 0.3623(5) 0.4364(2) 0.0461(12) Uani 1 1 d . . . . .
H6A H 0.2058 0.3990 0.4668 0.069 Uiso 1 1 calc R U . . .
H6B H 0.1733 0.2697 0.4406 0.069 Uiso 1 1 calc R U . . .
H6C H 0.1240 0.4021 0.4292 0.069 Uiso 1 1 calc R U . . .
C7 C 0.3344(3) 0.3368(4) 0.40708(19) 0.0380(11) Uani 1 1 d . . . . .
H7A H 0.3741 0.3505 0.3793 0.057 Uiso 1 1 calc R U . . .
H7B H 0.3308 0.2449 0.4144 0.057 Uiso 1 1 calc R U . . .
H7C H 0.3568 0.3824 0.4362 0.057 Uiso 1 1 calc R U . . .
C8 C 0.3296(3) 0.8391(4) 0.33906(17) 0.0297(9) Uani 1 1 d . . . . .
C9 C 0.4286(3) 0.8288(4) 0.34580(17) 0.0316(9) Uani 1 1 d . . . . .
H9A H 0.4430 0.8198 0.3810 0.047 Uiso 1 1 calc R U . . .
H9B H 0.4566 0.9063 0.3329 0.047 Uiso 1 1 calc R U . . .
H9C H 0.4501 0.7537 0.3278 0.047 Uiso 1 1 calc R U . . .
C10 C 0.3022(4) 0.8464(5) 0.28494(19) 0.0435(12) Uani 1 1 d . . . . .
H10A H 0.2382 0.8524 0.2824 0.065 Uiso 1 1 calc R U . . .
H10B H 0.3222 0.7692 0.2677 0.065 Uiso 1 1 calc R U . . .
H10C H 0.3287 0.9222 0.2698 0.065 Uiso 1 1 calc R U . . .
C11 C 0.2994(3) 0.9609(4) 0.3651(2) 0.0428(12) Uani 1 1 d . . . . .
H11A H 0.2354 0.9677 0.3626 0.064 Uiso 1 1 calc R U . . .
H11B H 0.3263 1.0357 0.3495 0.064 Uiso 1 1 calc R U . . .
H11C H 0.3171 0.9574 0.4000 0.064 Uiso 1 1 calc R U . . .
C12 C 0.6656(3) 0.5145(4) 0.42888(14) 0.0217(7) Uani 1 1 d . . . . .
C13 C 0.8111(3) 0.5437(5) 0.42999(19) 0.0361(10) Uani 1 1 d . . . . .
H13 H 0.8671 0.5832 0.4277 0.043 Uiso 1 1 calc R U . . .
C14 C 0.7960(3) 0.4207(4) 0.44067(17) 0.0312(9) Uani 1 1 d . . . . .
H14 H 0.8394 0.3574 0.4474 0.037 Uiso 1 1 calc R U . . .
C15 C 0.6643(3) 0.2742(4) 0.45213(15) 0.0244(8) Uani 1 1 d . . . . .
C16 C 0.7372(3) 0.1788(4) 0.46483(17) 0.0321(9) Uani 1 1 d . . . . .
H16A H 0.7736 0.1648 0.4357 0.048 Uiso 1 1 calc R U . . .
H16B H 0.7111 0.0973 0.4751 0.048 Uiso 1 1 calc R U . . .
H16C H 0.7736 0.2132 0.4918 0.048 Uiso 1 1 calc R U . . .
C17 C 0.6125(3) 0.2255(4) 0.40715(16) 0.0279(9) Uani 1 1 d . . . . .
H17A H 0.5630 0.2832 0.4004 0.042 Uiso 1 1 calc R U . . .
H17B H 0.5904 0.1391 0.4138 0.042 Uiso 1 1 calc R U . . .
H17C H 0.6510 0.2232 0.3784 0.042 Uiso 1 1 calc R U . . .
C18 C 0.6059(3) 0.2894(4) 0.49706(16) 0.0311(9) Uani 1 1 d . . . . .
H18A H 0.6406 0.3241 0.5247 0.047 Uiso 1 1 calc R U . . .
H18B H 0.5820 0.2056 0.5063 0.047 Uiso 1 1 calc R U . . .
H18C H 0.5576 0.3481 0.4891 0.047 Uiso 1 1 calc R U . . .
C19 C 0.7205(3) 0.7446(4) 0.41115(17) 0.0329(10) Uani 1 1 d . . . . .
C20 C 0.6772(4) 0.7609(5) 0.36049(19) 0.0413(11) Uani 1 1 d . . . . .
H20A H 0.7122 0.7165 0.3356 0.062 Uiso 1 1 calc R U . . .
H20B H 0.6737 0.8523 0.3523 0.062 Uiso 1 1 calc R U . . .
H20C H 0.6180 0.7243 0.3610 0.062 Uiso 1 1 calc R U . . .
C21 C 0.6683(4) 0.8096(4) 0.45207(19) 0.0409(11) Uani 1 1 d . . . . .
H21A H 0.6112 0.7672 0.4552 0.061 Uiso 1 1 calc R U . . .
H21B H 0.6593 0.9001 0.4438 0.061 Uiso 1 1 calc R U . . .
H21C H 0.7008 0.8030 0.4834 0.061 Uiso 1 1 calc R U . . .
C22 C 0.8118(3) 0.8056(5) 0.4108(2) 0.0453(12) Uani 1 1 d . . . . .
H22A H 0.8414 0.7897 0.4425 0.068 Uiso 1 1 calc R U . . .
H22B H 0.8063 0.8983 0.4055 0.068 Uiso 1 1 calc R U . . .
H22C H 0.8463 0.7681 0.3841 0.068 Uiso 1 1 calc R U . . .
C23 C 0.5680(3) 0.4092(4) 0.21599(15) 0.0225(8) Uani 1 1 d . . . . .
C24 C 0.4958(3) 0.4581(4) 0.14662(16) 0.0309(9) Uani 1 1 d . . . . .
H24 H 0.4734 0.5051 0.1192 0.037 Uiso 1 1 calc R U . . .
C25 C 0.4789(3) 0.3355(5) 0.15660(16) 0.0315(9) Uani 1 1 d . . . . .
H25 H 0.4428 0.2797 0.1375 0.038 Uiso 1 1 calc R U . . .
C26 C 0.5206(3) 0.1720(4) 0.22279(18) 0.0326(10) Uani 1 1 d . . . . .
C27 C 0.4616(4) 0.0860(5) 0.1908(2) 0.0456(13) Uani 1 1 d . . . . .
H27A H 0.4013 0.1185 0.1913 0.068 Uiso 1 1 calc R U . . .
H27B H 0.4629 -0.0017 0.2038 0.068 Uiso 1 1 calc R U . . .
H27C H 0.4828 0.0861 0.1567 0.068 Uiso 1 1 calc R U . . .
C28 C 0.4814(3) 0.1812(5) 0.27398(19) 0.0420(12) Uani 1 1 d . . . . .
H28A H 0.5219 0.2275 0.2960 0.063 Uiso 1 1 calc R U . . .
H28B H 0.4715 0.0948 0.2870 0.063 Uiso 1 1 calc R U . . .
H28C H 0.4254 0.2273 0.2720 0.063 Uiso 1 1 calc R U . . .
C29 C 0.6124(3) 0.1139(4) 0.2229(2) 0.0438(12) Uani 1 1 d . . . . .
H29A H 0.6324 0.1045 0.1888 0.066 Uiso 1 1 calc R U . . .
H29B H 0.6110 0.0295 0.2388 0.066 Uiso 1 1 calc R U . . .
H29C H 0.6528 0.1702 0.2412 0.066 Uiso 1 1 calc R U . . .
C30 C 0.5864(3) 0.6399(4) 0.18301(16) 0.0300(9) Uani 1 1 d . . . . .
C31 C 0.5539(4) 0.7110(4) 0.2286(2) 0.0512(15) Uani 1 1 d . . . . .
H31A H 0.4897 0.7061 0.2298 0.077 Uiso 1 1 calc R U . . .
H31B H 0.5720 0.8010 0.2270 0.077 Uiso 1 1 calc R U . . .
H31C H 0.5791 0.6715 0.2584 0.077 Uiso 1 1 calc R U . . .
C32 C 0.6867(3) 0.6362(4) 0.18038(17) 0.0354(10) Uani 1 1 d . . . . .
H32A H 0.7105 0.5946 0.2101 0.053 Uiso 1 1 calc R U . . .
H32B H 0.7094 0.7239 0.1783 0.053 Uiso 1 1 calc R U . . .
H32C H 0.7043 0.5878 0.1511 0.053 Uiso 1 1 calc R U . . .
C33 C 0.5513(3) 0.7093(5) 0.13696(19) 0.0419(12) Uani 1 1 d . . . . .
H33A H 0.5663 0.6600 0.1074 0.063 Uiso 1 1 calc R U . . .
H33B H 0.5777 0.7948 0.1350 0.063 Uiso 1 1 calc R U . . .
H33C H 0.4874 0.7174 0.1390 0.063 Uiso 1 1 calc R U . . .
Ag2 Ag 1.00353(4) 0.88430(6) 0.49864(2) 0.02975(14) Uani 0.5 1 d . . P A 1
Cl1 Cl 1.0159(2) 0.6521(2) 0.48567(11) 0.0419(6) Uani 0.5 1 d . . P A 1
Cl2 Cl 0.87660(7) 0.97714(9) 0.53867(4) 0.0313(2) Uani 1 1 d . . . . .
Cl98 Cl 0.9602(5) 1.2136(6) 0.4893(3) 0.154(3) Uani 0.5 1 d D . P B -2
Cl99 Cl 0.9918(5) 1.4121(9) 0.5594(3) 0.153(3) Uani 0.5 1 d D . P B -2
C99 C 0.9946(11) 1.3667(11) 0.4990(4) 0.0419(6) Uani 0.5 1 d D . P B -2
H99A H 0.9570 1.4255 0.4793 0.050 Uiso 0.5 1 calc R U P B -2
H99B H 1.0554 1.3754 0.4870 0.050 Uiso 0.5 1 calc R U P B -2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.7943 1.1372 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Se2 Ag1 Se3 124.806(18) . .
Se2 Ag1 Se1 115.875(19) . .
Se3 Ag1 Se1 119.315(18) . .
C1 Se1 Ag1 105.31(11) . .
C12 Se2 Ag1 99.76(12) . .
C23 Se3 Ag1 97.17(12) . .
C1 N1 C2 109.1(3) . .
C1 N1 C8 128.2(4) . .
C2 N1 C8 122.7(3) . .
C1 N2 C3 108.9(3) . .
C1 N2 C4 128.3(4) . .
C3 N2 C4 122.7(4) . .
C12 N3 C13 108.4(4) . .
C12 N3 C19 127.8(4) . .
C13 N3 C19 123.8(4) . .
C12 N4 C14 109.1(3) . .
C12 N4 C15 127.7(3) . .
C14 N4 C15 123.2(3) . .
C23 N5 C24 108.4(3) . .
C23 N5 C30 128.5(3) . .
C24 N5 C30 123.1(3) . .
C23 N6 C25 108.8(3) . .
C23 N6 C26 127.9(3) . .
C25 N6 C26 123.3(3) . .
N2 C1 N1 106.3(4) . .
N2 C1 Se1 126.6(3) . .
N1 C1 Se1 126.6(3) . .
C3 C2 N1 107.6(4) . .
C2 C3 N2 108.1(4) . .
N2 C4 C5 110.2(3) . .
N2 C4 C7 108.7(3) . .
C5 C4 C7 111.8(4) . .
N2 C4 C6 108.0(4) . .
C5 C4 C6 108.9(4) . .
C7 C4 C6 109.2(4) . .
N1 C8 C10 109.8(3) . .
N1 C8 C9 109.1(3) . .
C10 C8 C9 112.3(4) . .
N1 C8 C11 108.9(4) . .
C10 C8 C11 108.8(4) . .
C9 C8 C11 107.9(4) . .
N4 C12 N3 106.5(3) . .
N4 C12 Se2 126.8(3) . .
N3 C12 Se2 126.7(3) . .
C14 C13 N3 108.1(4) . .
C13 C14 N4 108.0(4) . .
N4 C15 C18 109.3(3) . .
N4 C15 C16 108.1(3) . .
C18 C15 C16 108.5(3) . .
N4 C15 C17 109.9(3) . .
C18 C15 C17 111.7(3) . .
C16 C15 C17 109.3(3) . .
N3 C19 C20 109.8(4) . .
N3 C19 C21 109.4(4) . .
C20 C19 C21 112.3(4) . .
N3 C19 C22 108.3(4) . .
C20 C19 C22 109.4(4) . .
C21 C19 C22 107.5(4) . .
N6 C23 N5 106.8(3) . .
N6 C23 Se3 126.7(3) . .
N5 C23 Se3 126.5(3) . .
C25 C24 N5 108.3(4) . .
C24 C25 N6 107.7(4) . .
N6 C26 C28 109.4(4) . .
N6 C26 C29 109.5(4) . .
C28 C26 C29 113.2(4) . .
N6 C26 C27 108.5(4) . .
C28 C26 C27 108.5(4) . .
C29 C26 C27 107.5(4) . .
N5 C30 C31 109.6(4) . .
N5 C30 C32 109.3(3) . .
C31 C30 C32 112.5(4) . .
N5 C30 C33 108.7(4) . .
C31 C30 C33 108.3(4) . .
C32 C30 C33 108.3(4) . .
Ag2 Ag2 Cl2 63.41(4) 3_776 .
Ag2 Ag2 Cl1 173.23(8) 3_776 .
Cl2 Ag2 Cl1 121.33(7) . .
Ag2 Ag2 Cl2 58.52(4) 3_776 3_776
Cl2 Ag2 Cl2 121.93(4) . 3_776
Cl1 Ag2 Cl2 116.52(7) . 3_776
Ag2 Cl2 Ag2 58.06(3) . 3_776
Cl98 C99 Cl99 113.4(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 Se2 2.5478(5) .
Ag1 Se3 2.5704(6) .
Ag1 Se1 2.5748(6) .
Se1 C1 1.886(4) .
Se2 C12 1.872(4) .
Se3 C23 1.887(4) .
N1 C1 1.371(5) .
N1 C2 1.381(6) .
N1 C8 1.505(5) .
N2 C1 1.368(5) .
N2 C3 1.381(6) .
N2 C4 1.520(5) .
N3 C12 1.371(5) .
N3 C13 1.388(6) .
N3 C19 1.510(5) .
N4 C12 1.365(5) .
N4 C14 1.378(5) .
N4 C15 1.514(5) .
N5 C23 1.362(5) .
N5 C24 1.380(5) .
N5 C30 1.505(5) .
N6 C23 1.360(5) .
N6 C25 1.380(5) .
N6 C26 1.515(5) .
C2 C3 1.347(6) .
C4 C5 1.524(6) .
C4 C7 1.526(6) .
C4 C6 1.530(7) .
C8 C10 1.520(6) .
C8 C9 1.523(6) .
C8 C11 1.526(6) .
C13 C14 1.336(7) .
C15 C18 1.523(6) .
C15 C16 1.527(6) .
C15 C17 1.529(5) .
C19 C20 1.524(6) .
C19 C21 1.529(7) .
C19 C22 1.531(6) .
C24 C25 1.333(6) .
C26 C28 1.518(7) .
C26 C29 1.524(6) .
C26 C27 1.532(6) .
C30 C31 1.528(6) .
C30 C32 1.531(6) .
C30 C33 1.532(6) .
Ag2 Ag2 2.4172(12) 3_776
Ag2 Cl2 2.4292(13) .
Ag2 Cl1 2.454(3) .
Ag2 Cl2 2.5471(12) 3_776
Cl2 Ag2 2.5470(12) 3_776
Cl98 C99 1.700(9) .
Cl99 C99 1.703(9) .
