#------------------------------------------------------------------------------
#$Date: 2019-11-17 10:16:30 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229300 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/73/7047343.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7047343
loop_
_publ_author_name
'Jin, Jun-Ling'
'Xie, Yun-Peng'
'Lu, Xing'
_publ_section_title
;
 High-nuclearity silver ethynide clusters containing polynucleating oxygen
 donor ligands.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12972
_journal_page_last               12978
_journal_paper_doi               10.1039/c8dt02700e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C44 H104 O20 P4 Sn6'
_chemical_formula_weight         1789.29
_chemical_name_systematic        Complex1
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-08-16 deposited with the CCDC.
2018-08-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 93.564(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.6070(13)
_cell_length_b                   16.984(2)
_cell_length_c                   19.941(2)
_cell_measurement_reflns_used    9057
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.4413
_cell_measurement_theta_min      2.9735
_cell_volume                     3585.4(7)
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_collection       'Apex2 (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL (Sheldrick, 2014)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0242
_diffrn_reflns_av_unetI/netI     0.0215
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            20980
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        24.257
_diffrn_reflns_theta_max         24.257
_diffrn_reflns_theta_min         2.973
_exptl_absorpt_coefficient_mu    2.204
_exptl_absorpt_correction_T_max  0.806
_exptl_absorpt_correction_T_min  0.739
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2014/2 (Bruker,2014)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.657
_exptl_crystal_description       block
_exptl_crystal_F_000             1776
_exptl_crystal_size_max          0.146
_exptl_crystal_size_mid          0.115
_exptl_crystal_size_min          0.102
_exptl_transmission_factor_max   0.0917
_exptl_transmission_factor_min   0.0622
_refine_diff_density_max         1.033
_refine_diff_density_min         -0.751
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.179
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     340
_refine_ls_number_reflns         5753
_refine_ls_number_restraints     296
_refine_ls_restrained_S_all      1.181
_refine_ls_R_factor_all          0.0621
_refine_ls_R_factor_gt           0.0522
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0218P)²+22.9111P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1079
_refine_ls_wR_factor_ref         0.1156
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4948
_reflns_number_total             5753
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt02700e2.cif
_cod_data_source_block           Complex1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7047343--7047346.cif.
;
_cod_original_cell_volume        3585.6(7)
_cod_database_code               7047343
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.739
_shelx_estimated_absorpt_t_max   0.806
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.34811(5) 0.42824(3) 0.59102(2) 0.05260(16) Uani 1 1 d . U . . .
Sn2 Sn 0.59372(5) 0.34873(3) 0.47948(3) 0.05547(16) Uani 1 1 d . U . . .
Sn3 Sn 0.28750(6) 0.36695(3) 0.43413(3) 0.06072(18) Uani 1 1 d . U . . .
P1 P 0.66084(19) 0.44463(12) 0.62494(10) 0.0537(5) Uani 1 1 d . U . . .
P2 P 0.3863(2) 0.24710(13) 0.55088(11) 0.0664(6) Uani 1 1 d . U . . .
O1 O 0.6848(5) 0.3885(3) 0.5681(3) 0.0642(13) Uani 1 1 d . U . . .
O2 O 0.5208(5) 0.4540(3) 0.6365(2) 0.0601(12) Uani 1 1 d . U . . .
O3 O 0.7229(5) 0.5240(3) 0.6150(3) 0.0670(14) Uani 1 1 d . U . . .
O4 O 0.5227(6) 0.2524(3) 0.5309(3) 0.0703(14) Uani 1 1 d . U . . .
O5 O 0.3607(6) 0.3055(3) 0.6066(3) 0.0680(14) Uani 1 1 d . U . . .
O6 O 0.2939(6) 0.2592(3) 0.4899(3) 0.0767(16) Uani 1 1 d . U . . .
O7 O 0.4298(4) 0.4058(3) 0.5019(2) 0.0485(10) Uani 1 1 d . U . . .
O8 O 0.6708(5) 0.4523(3) 0.4394(3) 0.0670(14) Uani 1 1 d . U . . .
O101 O 0.4605(6) 0.3341(3) 0.3944(3) 0.0666(13) Uani 1 1 d . U . . .
O102 O 0.1923(5) 0.4141(4) 0.5152(3) 0.0678(14) Uani 1 1 d . U . . .
C1 C 0.7350(8) 0.4013(5) 0.7007(4) 0.0631(19) Uani 1 1 d . U . . .
C2 C 0.8775(8) 0.3922(6) 0.6924(5) 0.087(3) Uani 1 1 d . U . . .
H2A H 0.9142 0.4431 0.6858 0.130 Uiso 1 1 calc R U . . .
H2B H 0.9169 0.3685 0.7321 0.130 Uiso 1 1 calc R U . . .
H2C H 0.8905 0.3594 0.6543 0.130 Uiso 1 1 calc R U . . .
C3 C 0.7141(11) 0.4562(7) 0.7602(4) 0.097(3) Uani 1 1 d . U . . .
H3A H 0.7526 0.5063 0.7526 0.145 Uiso 1 1 calc R U . . .
H3B H 0.6251 0.4633 0.7644 0.145 Uiso 1 1 calc R U . . .
H3C H 0.7514 0.4334 0.8008 0.145 Uiso 1 1 calc R U . . .
C4 C 0.6748(10) 0.3213(6) 0.7114(5) 0.087(3) Uani 1 1 d . U . . .
H4A H 0.6888 0.2878 0.6738 0.130 Uiso 1 1 calc R U . . .
H4B H 0.7120 0.2978 0.7517 0.130 Uiso 1 1 calc R U . . .
H4C H 0.5857 0.3277 0.7153 0.130 Uiso 1 1 calc R U . . .
C5 C 0.3652(11) 0.1489(5) 0.5851(5) 0.088(3) Uani 1 1 d . U . . .
C6 C 0.4594(14) 0.1384(7) 0.6451(6) 0.122(4) Uani 1 1 d . U . . .
H6A H 0.4432 0.1769 0.6788 0.183 Uiso 1 1 calc R U . . .
H6B H 0.4509 0.0866 0.6634 0.183 Uiso 1 1 calc R U . . .
H6C H 0.5436 0.1453 0.6310 0.183 Uiso 1 1 calc R U . . .
C7 C 0.3902(17) 0.0889(6) 0.5322(6) 0.144(5) Uani 1 1 d . U . . .
H7A H 0.4756 0.0941 0.5196 0.216 Uiso 1 1 calc R U . . .
H7B H 0.3777 0.0370 0.5498 0.216 Uiso 1 1 calc R U . . .
H7C H 0.3331 0.0972 0.4936 0.216 Uiso 1 1 calc R U . . .
C8 C 0.2303(13) 0.1419(8) 0.6060(8) 0.150(5) Uani 1 1 d . U . . .
H8A H 0.2158 0.1806 0.6397 0.226 Uiso 1 1 calc R U . . .
H8B H 0.1727 0.1504 0.5676 0.226 Uiso 1 1 calc R U . . .
H8C H 0.2172 0.0902 0.6238 0.226 Uiso 1 1 calc R U . . .
C9 C 0.1479(11) 0.3162(7) 0.3671(5) 0.101(3) Uani 1 1 d D U . . .
H9A H 0.1916 0.2789 0.3399 0.121 Uiso 1 1 calc R U . . .
H9B H 0.0938 0.2854 0.3945 0.121 Uiso 1 1 calc R U . . .
C10 C 0.0661(15) 0.3594(9) 0.3219(8) 0.171(7) Uani 1 1 d D U . . .
H10A H 0.1179 0.3919 0.2945 0.205 Uiso 1 1 calc R U . . .
H10B H 0.0167 0.3947 0.3481 0.205 Uiso 1 1 calc R U . . .
C11 C -0.0217(17) 0.3145(10) 0.2766(8) 0.170(7) Uani 1 1 d D U . . .
C12A C -0.061(3) 0.3526(13) 0.2141(11) 0.188(12) Uani 0.82(3) 1 d D U P A 1
H12A H -0.1175 0.3188 0.1882 0.282 Uiso 0.82(3) 1 calc R U P A 1
H12B H -0.1025 0.4012 0.2232 0.282 Uiso 0.82(3) 1 calc R U P A 1
H12C H 0.0122 0.3632 0.1893 0.282 Uiso 0.82(3) 1 calc R U P A 1
C12B C -0.140(4) 0.364(3) 0.266(4) 0.138(19) Uani 0.18(3) 1 d D U P A 2
H12D H -0.2003 0.3372 0.2364 0.207 Uiso 0.18(3) 1 calc R U P A 2
H12E H -0.1754 0.3734 0.3083 0.207 Uiso 0.18(3) 1 calc R U P A 2
H12F H -0.1187 0.4137 0.2462 0.207 Uiso 0.18(3) 1 calc R U P A 2
C13 C 0.2430(10) 0.4459(7) 0.6786(5) 0.091(3) Uani 1 1 d D U . . .
H13A H 0.2387 0.5022 0.6862 0.109 Uiso 1 1 calc R U . . .
H13B H 0.1573 0.4282 0.6675 0.109 Uiso 1 1 calc R U . . .
C14 C 0.2821(19) 0.4119(13) 0.7380(5) 0.207(8) Uani 1 1 d D U . . .
H14A H 0.3694 0.4275 0.7473 0.248 Uiso 1 1 calc R U . . .
H14B H 0.2825 0.3555 0.7303 0.248 Uiso 1 1 calc R U . . .
C15 C 0.222(2) 0.4240(18) 0.7962(7) 0.289(9) Uani 1 1 d D U . . .
H15A H 0.1640 0.4678 0.7890 0.346 Uiso 1 1 calc R U . . .
H15B H 0.1714 0.3777 0.8044 0.346 Uiso 1 1 calc R U . . .
C16 C 0.296(2) 0.4387(18) 0.8518(8) 0.289(9) Uani 1 1 d D U . . .
H16A H 0.2438 0.4461 0.8892 0.433 Uiso 1 1 calc R U . . .
H16B H 0.3516 0.3950 0.8608 0.433 Uiso 1 1 calc R U . . .
H16C H 0.3441 0.4854 0.8454 0.433 Uiso 1 1 calc R U . . .
C17 C 0.7472(10) 0.2807(6) 0.4452(6) 0.096(3) Uani 1 1 d D U . . .
H17A H 0.7305 0.2722 0.3973 0.115 Uiso 1 1 calc R U . . .
H17B H 0.8226 0.3130 0.4505 0.115 Uiso 1 1 calc R U . . .
C18 C 0.7764(15) 0.2066(8) 0.4747(11) 0.199(7) Uani 1 1 d D U . . .
H18A H 0.7028 0.1735 0.4656 0.238 Uiso 1 1 calc R U . . .
H18B H 0.7837 0.2150 0.5229 0.238 Uiso 1 1 calc R U . . .
C19 C 0.8825(18) 0.1612(11) 0.4589(14) 0.250(10) Uani 1 1 d D U . . .
H19A H 0.8795 0.1553 0.4105 0.300 Uiso 1 1 calc R U . . .
H19B H 0.9575 0.1918 0.4717 0.300 Uiso 1 1 calc R U . . .
C20 C 0.900(2) 0.0859(12) 0.4871(18) 0.357(18) Uani 1 1 d D U . . .
H20A H 0.9751 0.0628 0.4717 0.535 Uiso 1 1 calc R U . . .
H20B H 0.9068 0.0900 0.5352 0.535 Uiso 1 1 calc R U . . .
H20C H 0.8284 0.0533 0.4737 0.535 Uiso 1 1 calc R U . . .
C101 C 0.4844(14) 0.3215(12) 0.3285(6) 0.179(8) Uani 1 1 d . U . . .
H10C H 0.4309 0.3549 0.3002 0.268 Uiso 1 1 calc R U . . .
H10D H 0.4677 0.2674 0.3172 0.268 Uiso 1 1 calc R U . . .
H10E H 0.5713 0.3334 0.3220 0.268 Uiso 1 1 calc R U . . .
C102 C 0.0692(10) 0.3887(10) 0.5303(7) 0.146(6) Uani 1 1 d . U . . .
H10F H 0.0193 0.4335 0.5412 0.219 Uiso 1 1 calc R U . . .
H10G H 0.0756 0.3532 0.5678 0.219 Uiso 1 1 calc R U . . .
H10H H 0.0298 0.3623 0.4919 0.219 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Sn1 O7 90.50(19) . .
O2 Sn1 O5 95.7(2) . .
O7 Sn1 O5 85.30(19) . .
O2 Sn1 O8 89.3(2) . 3_666
O7 Sn1 O8 88.10(19) . 3_666
O5 Sn1 O8 171.7(2) . 3_666
O2 Sn1 C13 96.1(3) . .
O7 Sn1 C13 173.3(3) . .
O5 Sn1 C13 92.9(3) . .
O8 Sn1 C13 93.1(3) 3_666 .
O2 Sn1 O102 162.1(2) . .
O7 Sn1 O102 73.94(19) . .
O5 Sn1 O102 91.8(2) . .
O8 Sn1 O102 81.5(2) 3_666 .
C13 Sn1 O102 99.7(3) . .
O7 Sn2 O1 91.0(2) . .
O7 Sn2 O4 85.8(2) . .
O1 Sn2 O4 90.0(2) . .
O7 Sn2 O8 92.35(19) . .
O1 Sn2 O8 83.1(2) . .
O4 Sn2 O8 172.8(2) . .
O7 Sn2 C17 171.7(4) . .
O1 Sn2 C17 97.2(4) . .
O4 Sn2 C17 92.2(3) . .
O8 Sn2 C17 90.5(3) . .
O7 Sn2 O101 72.8(2) . .
O1 Sn2 O101 163.1(2) . .
O4 Sn2 O101 93.3(2) . .
O8 Sn2 O101 92.8(2) . .
C17 Sn2 O101 99.2(4) . .
O7 Sn3 O3 92.19(19) . 3_666
O7 Sn3 C9 174.6(3) . .
O3 Sn3 C9 92.9(3) 3_666 .
O7 Sn3 O102 75.18(19) . .
O3 Sn3 O102 90.5(2) 3_666 .
C9 Sn3 O102 106.8(4) . .
O7 Sn3 O101 73.42(19) . .
O3 Sn3 O101 94.6(2) 3_666 .
C9 Sn3 O101 104.2(4) . .
O102 Sn3 O101 148.3(2) . .
O7 Sn3 O6 86.3(2) . .
O3 Sn3 O6 176.3(2) 3_666 .
C9 Sn3 O6 88.8(3) . .
O102 Sn3 O6 85.9(2) . .
O101 Sn3 O6 88.2(2) . .
O1 P1 O3 111.5(3) . .
O1 P1 O2 112.9(3) . .
O3 P1 O2 111.2(3) . .
O1 P1 C1 106.5(4) . .
O3 P1 C1 107.4(4) . .
O2 P1 C1 107.0(3) . .
O5 P2 O4 111.4(3) . .
O5 P2 O6 110.9(4) . .
O4 P2 O6 110.9(3) . .
O5 P2 C5 106.9(4) . .
O4 P2 C5 107.0(5) . .
O6 P2 C5 109.5(4) . .
P1 O1 Sn2 138.8(3) . .
P1 O2 Sn1 140.0(3) . .
P1 O3 Sn3 146.6(3) . 3_666
P2 O4 Sn2 123.3(3) . .
P2 O5 Sn1 123.2(3) . .
P2 O6 Sn3 121.8(3) . .
Sn1 O7 Sn2 132.7(2) . .
Sn1 O7 Sn3 107.0(2) . .
Sn2 O7 Sn3 107.4(2) . .
Sn2 O8 Sn1 150.5(3) . 3_666
C101 O101 Sn3 128.0(8) . .
C101 O101 Sn2 128.5(7) . .
Sn3 O101 Sn2 102.5(2) . .
C102 O102 Sn3 122.2(7) . .
C102 O102 Sn1 123.5(6) . .
Sn3 O102 Sn1 101.2(2) . .
C4 C1 C3 110.6(8) . .
C4 C1 C2 110.4(8) . .
C3 C1 C2 109.5(8) . .
C4 C1 P1 108.3(6) . .
C3 C1 P1 108.7(6) . .
C2 C1 P1 109.2(6) . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
C1 C3 H3A 109.5 . .
C1 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
C1 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C1 C4 H4A 109.5 . .
C1 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C1 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C7 C5 C8 110.4(11) . .
C7 C5 C6 109.7(11) . .
C8 C5 C6 111.0(11) . .
C7 C5 P2 109.1(7) . .
C8 C5 P2 108.3(8) . .
C6 C5 P2 108.2(7) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C5 C7 H7A 109.5 . .
C5 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C5 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C5 C8 H8A 109.5 . .
C5 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C5 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 Sn3 124.6(8) . .
C10 C9 H9A 106.2 . .
Sn3 C9 H9A 106.2 . .
C10 C9 H9B 106.2 . .
Sn3 C9 H9B 106.2 . .
H9A C9 H9B 106.4 . .
C9 C10 C11 117.5(13) . .
C9 C10 H10A 107.9 . .
C11 C10 H10A 107.9 . .
C9 C10 H10B 107.9 . .
C11 C10 H10B 107.9 . .
H10A C10 H10B 107.2 . .
C12A C11 C10 115.8(14) . .
C10 C11 C12B 107(3) . .
C11 C12A H12A 109.5 . .
C11 C12A H12B 109.5 . .
H12A C12A H12B 109.5 . .
C11 C12A H12C 109.5 . .
H12A C12A H12C 109.5 . .
H12B C12A H12C 109.5 . .
C11 C12B H12D 109.5 . .
C11 C12B H12E 109.5 . .
H12D C12B H12E 109.5 . .
C11 C12B H12F 109.5 . .
H12D C12B H12F 109.5 . .
H12E C12B H12F 109.5 . .
C14 C13 Sn1 120.2(9) . .
C14 C13 H13A 107.3 . .
Sn1 C13 H13A 107.3 . .
C14 C13 H13B 107.3 . .
Sn1 C13 H13B 107.3 . .
H13A C13 H13B 106.9 . .
C13 C14 C15 122.7(19) . .
C13 C14 H14A 106.7 . .
C15 C14 H14A 106.7 . .
C13 C14 H14B 106.7 . .
C15 C14 H14B 106.7 . .
H14A C14 H14B 106.6 . .
C16 C15 C14 117(2) . .
C16 C15 H15A 108.1 . .
C14 C15 H15A 108.1 . .
C16 C15 H15B 108.1 . .
C14 C15 H15B 108.1 . .
H15A C15 H15B 107.3 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 Sn2 119.8(9) . .
C18 C17 H17A 107.4 . .
Sn2 C17 H17A 107.4 . .
C18 C17 H17B 107.4 . .
Sn2 C17 H17B 107.4 . .
H17A C17 H17B 106.9 . .
C17 C18 C19 123.2(16) . .
C17 C18 H18A 106.5 . .
C19 C18 H18A 106.5 . .
C17 C18 H18B 106.5 . .
C19 C18 H18B 106.5 . .
H18A C18 H18B 106.5 . .
C20 C19 C18 119(2) . .
C20 C19 H19A 107.5 . .
C18 C19 H19A 107.5 . .
C20 C19 H19B 107.5 . .
C18 C19 H19B 107.5 . .
H19A C19 H19B 107.0 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O101 C101 H10C 109.5 . .
O101 C101 H10D 109.5 . .
H10C C101 H10D 109.5 . .
O101 C101 H10E 109.5 . .
H10C C101 H10E 109.5 . .
H10D C101 H10E 109.5 . .
O102 C102 H10F 109.5 . .
O102 C102 H10G 109.5 . .
H10F C102 H10G 109.5 . .
O102 C102 H10H 109.5 . .
H10F C102 H10H 109.5 . .
H10G C102 H10H 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 O2 2.040(5) .
Sn1 O7 2.061(4) .
Sn1 O5 2.110(6) .
Sn1 O8 2.123(5) 3_666
Sn1 C13 2.150(8) .
Sn1 O102 2.182(5) .
Sn2 O7 2.063(5) .
Sn2 O1 2.073(5) .
Sn2 O4 2.096(5) .
Sn2 O8 2.117(5) .
Sn2 C17 2.142(9) .
Sn2 O101 2.154(6) .
Sn3 O7 2.070(5) .
Sn3 O3 2.095(5) 3_666
Sn3 C9 2.116(9) .
Sn3 O102 2.117(6) .
Sn3 O101 2.119(6) .
Sn3 O6 2.140(6) .
P1 O1 1.515(6) .
P1 O3 1.519(6) .
P1 O2 1.526(5) .
P1 C1 1.816(8) .
P2 O5 1.526(6) .
P2 O4 1.527(6) .
P2 O6 1.528(6) .
P2 C5 1.821(9) .
O3 Sn3 2.095(5) 3_666
O8 Sn1 2.123(5) 3_666
O101 C101 1.370(11) .
O102 C102 1.424(11) .
C1 C4 1.523(12) .
C1 C3 1.536(12) .
C1 C2 1.538(12) .
C2 H2A 0.9600 .
C2 H2B 0.9600 .
C2 H2C 0.9600 .
C3 H3A 0.9600 .
C3 H3B 0.9600 .
C3 H3C 0.9600 .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 C7 1.501(15) .
C5 C8 1.520(16) .
C5 C6 1.521(15) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 C10 1.416(13) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C11 1.471(12) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C12A 1.441(12) .
C11 C12B 1.52(2) .
C12A H12A 0.9600 .
C12A H12B 0.9600 .
C12A H12C 0.9600 .
C12B H12D 0.9600 .
C12B H12E 0.9600 .
C12B H12F 0.9600 .
C13 C14 1.359(13) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 C15 1.375(16) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 C16 1.341(18) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C18 1.416(13) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 C19 1.416(15) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C20 1.405(17) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C101 H10C 0.9600 .
C101 H10D 0.9600 .
C101 H10E 0.9600 .
C102 H10F 0.9600 .
C102 H10G 0.9600 .
C102 H10H 0.9600 .
