#------------------------------------------------------------------------------
#$Date: 2019-11-08 00:09:35 +0200 (Fri, 08 Nov 2019) $
#$Revision: 224194 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/92/7049282.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7049282
loop_
_publ_author_name
'Hong, Dongjing'
'Zhu, Xiancui'
'Wang, Shaowu'
'Wei, Yun'
'Zhou, Shuangliu'
'Huang, Zeming'
'Zhu, Shan'
'Wang, Ruru'
'Yue, Wenrun'
'Mu, Xiaolong'
_publ_section_title
;
 Synthesis, characterization, and reactivity of dinuclear
 organo-rare-earth-metal alkyl complexes supported by
 2-amidate-functionalized indolyl ligands: substituent effects on
 coordination and reactivity.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5230
_journal_page_last               5242
_journal_paper_doi               10.1039/c9dt00507b
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C62 H90 Dy2 N4 O6 Si2'
_chemical_formula_sum            'C62 H90 Dy2 N4 O6 Si2'
_chemical_formula_weight         1368.55
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2018-03-26
_audit_creation_method
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_audit_update_record
;
2018-03-27 deposited with the CCDC.    2019-03-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 118.1020(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   30.336(3)
_cell_length_b                   14.9931(15)
_cell_length_c                   22.644(2)
_cell_measurement_reflns_used    9904
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.41
_cell_measurement_theta_min      2.20
_cell_volume                     9085.0(15)
_computing_cell_refinement       'SAINT v7.34A (Bruker, 200?)'
_computing_data_collection       'SAINT v7.34A (Bruker, 200?)'
_computing_data_reduction        'SAINT v7.34A (Bruker, 200?)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      293.15
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0386
_diffrn_reflns_av_unetI/netI     0.0328
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       39
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            49894
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.480
_diffrn_reflns_theta_min         1.522
_exptl_absorpt_coefficient_mu    1.693
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.001
_exptl_crystal_description       block
_exptl_crystal_F_000             2792
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.2
_refine_diff_density_max         2.132
_refine_diff_density_min         -0.790
_refine_diff_density_rms         0.068
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         10299
_refine_ls_number_restraints     33
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.0506
_refine_ls_R_factor_gt           0.0328
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0392P)²+2.8251P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0773
_refine_ls_wR_factor_ref         0.0828
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7273
_reflns_number_total             10299
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt00507b2.cif
_cod_data_source_block           2b
_cod_depositor_comments
'Adding full bibliography for 7049263--7049284.cif.'
_cod_original_cell_volume        9085.0(16)
_cod_database_code               7049282
_shelx_shelxl_version_number     2018/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.728
_shelx_estimated_absorpt_t_min   0.697
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid bond restraints
 C24, C25, C26
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
3. Uiso/Uaniso restraints and constraints
C24 \\sim C25 \\sim C26: within 2A with sigma of 0.01 and sigma for terminal
atoms of 0.02
Uanis(C24) \\sim Ueq, Uanis(C25) \\sim Ueq, Uanis(C26) \\sim Ueq: with sigma of
0.02 and sigma for terminal atoms of 0.04
4.a Secondary CH2 refined with riding coordinates:
 C20(H20A,H20B), C24(H24A,H24B), C25(H25A,H25B), C26(H26A,H26B), C27(H27A,
 H27B), C28(H28A,H28B), C29(H29A,H29B), C30(H30A,H30B), C31(H31A,H31B)
4.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C5(H5), C6(H6), C7(H7), C12(H12), C13(H13), C14(H14), C15(H15)
4.c Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C), C18(H18A,H18B,H18C), C19(H19A,H19B,H19C), C21(H21A,H21B,
 H21C), C22(H22A,H22B,H22C), C23(H23A,H23B,H23C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Dy1 Dy 0.26087(2) 0.73255(2) 0.92311(2) 0.04575(6) Uani 1 1 d . .
Si1 Si 0.14073(4) 0.80117(7) 0.76904(5) 0.0694(3) Uani 1 1 d . .
O1 O 0.26261(8) 0.67220(12) 1.01725(10) 0.0509(5) Uani 1 1 d . .
O2 O 0.35247(9) 0.73904(16) 1.00196(12) 0.0685(6) Uani 1 1 d . .
O3 O 0.29680(9) 0.67200(16) 0.85687(11) 0.0685(6) Uani 1 1 d . .
N1 N 0.22249(10) 0.61626(16) 1.08844(11) 0.0509(6) Uani 1 1 d . .
N2 N 0.24837(11) 0.55627(15) 0.95077(13) 0.0563(7) Uani 1 1 d . .
C1 C 0.22199(12) 0.55619(19) 1.04103(15) 0.0508(7) Uani 1 1 d . .
C2 C 0.20086(13) 0.4757(2) 1.04272(16) 0.0616(9) Uani 1 1 d . .
H2 H 0.196529 0.426495 1.015537 0.074 Uiso 1 1 calc R .
C3 C 0.18711(13) 0.4828(2) 1.09377(16) 0.0595(8) Uani 1 1 d . .
C4 C 0.16353(16) 0.4246(2) 1.11955(19) 0.0769(11) Uani 1 1 d . .
H4 H 0.153195 0.368015 1.101557 0.092 Uiso 1 1 calc R .
C5 C 0.15636(17) 0.4540(3) 1.1717(2) 0.0850(12) Uani 1 1 d . .
H5 H 0.140844 0.416466 1.188979 0.102 Uiso 1 1 calc R .
C6 C 0.17173(16) 0.5390(3) 1.1998(2) 0.0804(12) Uani 1 1 d . .
H6 H 0.166749 0.556571 1.235604 0.096 Uiso 1 1 calc R .
C7 C 0.19390(15) 0.5959(2) 1.17494(17) 0.0680(9) Uani 1 1 d . .
H7 H 0.204076 0.652279 1.193588 0.082 Uiso 1 1 calc R .
C8 C 0.20119(12) 0.56883(19) 1.12119(15) 0.0533(8) Uani 1 1 d . .
C9 C 0.24408(11) 0.5901(2) 1.00012(14) 0.0497(7) Uani 1 1 d . .
C10 C 0.22493(16) 0.4733(2) 0.92185(17) 0.0673(10) Uani 1 1 d . .
C11 C 0.25257(19) 0.3936(2) 0.93147(19) 0.0794(12) Uani 1 1 d . .
C12 C 0.2243(3) 0.3188(3) 0.8980(3) 0.1119(18) Uani 1 1 d . .
H12 H 0.240937 0.264859 0.903503 0.134 Uiso 1 1 calc R .
C13 C 0.1746(3) 0.3200(4) 0.8584(3) 0.125(2) Uani 1 1 d . .
H13 H 0.158017 0.267802 0.837381 0.150 Uiso 1 1 calc R .
C14 C 0.1480(2) 0.3975(4) 0.8487(2) 0.1075(16) Uani 1 1 d . .
H14 H 0.113586 0.398813 0.821544 0.129 Uiso 1 1 calc R .
C15 C 0.17426(17) 0.4742(3) 0.88085(18) 0.0790(11) Uani 1 1 d . .
H15 H 0.156918 0.527526 0.874313 0.095 Uiso 1 1 calc R .
C16 C 0.3083(2) 0.3887(3) 0.9738(3) 0.0965(15) Uani 1 1 d . .
C17 C 0.3300(3) 0.2947(3) 0.9767(3) 0.146(3) Uani 1 1 d . .
H17A H 0.316585 0.253954 0.996837 0.219 Uiso 1 1 calc GR .
H17B H 0.365719 0.296553 1.002825 0.219 Uiso 1 1 calc GR .
H17C H 0.321137 0.274989 0.932108 0.219 Uiso 1 1 calc GR .
C18 C 0.32489(18) 0.4145(3) 1.0471(2) 0.0978(14) Uani 1 1 d . .
H18A H 0.314404 0.474460 1.048843 0.147 Uiso 1 1 calc GR .
H18B H 0.360618 0.410740 1.072506 0.147 Uiso 1 1 calc GR .
H18C H 0.309951 0.374518 1.065686 0.147 Uiso 1 1 calc GR .
C19 C 0.3345(2) 0.4500(3) 0.9447(3) 0.1178(18) Uani 1 1 d . .
H19A H 0.325761 0.431346 0.900033 0.177 Uiso 1 1 calc GR .
H19B H 0.370015 0.446260 0.972236 0.177 Uiso 1 1 calc GR .
H19C H 0.323793 0.510490 0.943974 0.177 Uiso 1 1 calc GR .
C20 C 0.17586(13) 0.7202(2) 0.83493(16) 0.0581(8) Uani 1 1 d . .
H20A H 0.174677 0.665099 0.811781 0.070 Uiso 1 1 calc R .
H20B H 0.155900 0.709988 0.857440 0.070 Uiso 1 1 calc R .
C21 C 0.07279(19) 0.7722(4) 0.7179(3) 0.132(2) Uani 1 1 d . .
H21A H 0.069685 0.716724 0.695022 0.198 Uiso 1 1 calc GR .
H21B H 0.056131 0.818439 0.685634 0.198 Uiso 1 1 calc GR .
H21C H 0.057830 0.766543 0.746774 0.198 Uiso 1 1 calc GR .
C22 C 0.16612(19) 0.8113(3) 0.7089(2) 0.1000(14) Uani 1 1 d . .
H22A H 0.199998 0.832144 0.731982 0.150 Uiso 1 1 calc GR .
H22B H 0.146223 0.852798 0.674225 0.150 Uiso 1 1 calc GR .
H22C H 0.165234 0.754009 0.689338 0.150 Uiso 1 1 calc GR .
C23 C 0.14343(18) 0.9158(3) 0.8030(2) 0.0928(13) Uani 1 1 d . .
H23A H 0.126880 0.916120 0.830168 0.139 Uiso 1 1 calc GR .
H23B H 0.127116 0.957005 0.766598 0.139 Uiso 1 1 calc GR .
H23C H 0.177695 0.933199 0.829690 0.139 Uiso 1 1 calc GR .
C24 C 0.38617(16) 0.8136(3) 1.0183(2) 0.1038(15) Uani 1 1 d . U
H24A H 0.376040 0.861480 1.038196 0.125 Uiso 1 1 calc R .
H24B H 0.386746 0.836163 0.978557 0.125 Uiso 1 1 calc R .
C25 C 0.4348(2) 0.7797(4) 1.0656(4) 0.170(3) Uani 1 1 d . U
H25A H 0.456072 0.776107 1.044503 0.204 Uiso 1 1 calc R .
H25B H 0.450300 0.819822 1.103579 0.204 Uiso 1 1 calc R .
C26 C 0.4294(2) 0.6948(5) 1.0875(4) 0.164(3) Uani 1 1 d . U
H26A H 0.436810 0.697079 1.134108 0.197 Uiso 1 1 calc R .
H26B H 0.452288 0.652999 1.083470 0.197 Uiso 1 1 calc R .
C27 C 0.37833(17) 0.6668(3) 1.0459(2) 0.0932(13) Uani 1 1 d . .
H27A H 0.377382 0.614374 1.020276 0.112 Uiso 1 1 calc R .
H27B H 0.362702 0.652214 1.073500 0.112 Uiso 1 1 calc R .
C28 C 0.34644(15) 0.6732(3) 0.8643(2) 0.0866(12) Uani 1 1 d . .
H28A H 0.367935 0.632095 0.899061 0.104 Uiso 1 1 calc R .
H28B H 0.360681 0.732588 0.875648 0.104 Uiso 1 1 calc R .
C29 C 0.3405(2) 0.6449(5) 0.7976(3) 0.147(3) Uani 1 1 d . .
H29A H 0.341113 0.696530 0.772181 0.176 Uiso 1 1 calc R .
H29B H 0.367418 0.605177 0.803287 0.176 Uiso 1 1 calc R .
C30 C 0.2948(3) 0.6014(6) 0.7642(3) 0.171(3) Uani 1 1 d . .
H30A H 0.300234 0.537764 0.763237 0.205 Uiso 1 1 calc R .
H30B H 0.277013 0.622576 0.718391 0.205 Uiso 1 1 calc R .
C31 C 0.26523(17) 0.6185(3) 0.7984(2) 0.0961(14) Uani 1 1 d . .
H31A H 0.234911 0.650620 0.769301 0.115 Uiso 1 1 calc R .
H31B H 0.256153 0.562909 0.811761 0.115 Uiso 1 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 Dy1 32.50(5) . 7_567
O1 Dy1 Dy1 32.44(5) 7_567 7_567
O1 Dy1 O1 64.95(8) . 7_567
O1 Dy1 O2 95.97(8) 7_567 .
O1 Dy1 O2 79.64(8) . .
O1 Dy1 O3 163.13(7) 7_567 .
O1 Dy1 O3 127.67(8) . .
O1 Dy1 N1 67.07(7) 7_567 7_567
O1 Dy1 N1 124.66(7) . 7_567
O1 Dy1 N2 50.36(7) . .
O1 Dy1 N2 110.19(7) 7_567 .
O1 Dy1 C9 25.77(7) . .
O1 Dy1 C9 85.11(8) 7_567 .
O1 Dy1 C20 106.66(10) . .
O1 Dy1 C20 91.59(10) 7_567 .
O2 Dy1 Dy1 87.44(6) . 7_567
O2 Dy1 N2 95.72(8) . .
O2 Dy1 C9 92.83(8) . .
O3 Dy1 Dy1 158.36(6) . 7_567
O3 Dy1 O2 77.44(9) . .
O3 Dy1 N2 86.09(8) . .
O3 Dy1 C9 110.50(8) . .
O3 Dy1 C20 94.39(10) . .
N1 Dy1 Dy1 96.06(6) 7_567 7_567
N1 Dy1 O2 79.52(8) 7_567 .
N1 Dy1 O3 96.30(8) 7_567 .
N1 Dy1 N2 174.04(8) 7_567 .
N1 Dy1 C9 149.92(8) 7_567 .
N1 Dy1 C20 100.53(10) 7_567 .
N2 Dy1 Dy1 80.04(5) . 7_567
N2 Dy1 C9 25.77(7) . .
C9 Dy1 Dy1 54.28(6) . 7_567
C20 Dy1 Dy1 100.73(8) . 7_567
C20 Dy1 O2 171.76(10) . .
C20 Dy1 N2 84.70(10) . .
C20 Dy1 C9 91.08(10) . .
C20 Si1 C21 113.5(2) . .
C20 Si1 C22 111.64(19) . .
C20 Si1 C23 112.29(17) . .
C22 Si1 C21 106.2(3) . .
C22 Si1 C23 105.9(2) . .
C23 Si1 C21 106.8(2) . .
Dy1 O1 Dy1 115.05(8) . 7_567
C9 O1 Dy1 105.78(16) . .
C9 O1 Dy1 122.69(17) . 7_567
C24 O2 Dy1 129.0(2) . .
C27 O2 Dy1 121.9(2) . .
C27 O2 C24 108.6(3) . .
C28 O3 Dy1 132.9(2) . .
C28 O3 C31 108.5(3) . .
C31 O3 Dy1 118.5(2) . .
C1 N1 Dy1 117.33(18) . 7_567
C8 N1 Dy1 136.75(19) . 7_567
C8 N1 C1 104.0(2) . .
C9 N2 Dy1 84.34(17) . .
C9 N2 C10 120.5(3) . .
C10 N2 Dy1 144.5(2) . .
N1 C1 C9 114.8(3) . .
C2 C1 N1 112.4(3) . .
C2 C1 C9 132.8(3) . .
C1 C2 H2 126.9 . .
C1 C2 C3 106.2(3) . .
C3 C2 H2 126.9 . .
C2 C3 C4 134.0(3) . .
C2 C3 C8 106.6(3) . .
C8 C3 C4 119.3(3) . .
C3 C4 H4 120.9 . .
C5 C4 C3 118.2(4) . .
C5 C4 H4 120.9 . .
C4 C5 H5 119.0 . .
C4 C5 C6 121.9(3) . .
C6 C5 H5 119.0 . .
C5 C6 H6 119.8 . .
C7 C6 C5 120.4(3) . .
C7 C6 H6 119.8 . .
C6 C7 H7 120.3 . .
C6 C7 C8 119.3(3) . .
C8 C7 H7 120.3 . .
N1 C8 C3 110.8(3) . .
N1 C8 C7 128.5(3) . .
C7 C8 C3 120.7(3) . .
O1 C9 Dy1 48.44(13) . .
O1 C9 C1 113.1(2) . .
N2 C9 Dy1 69.89(16) . .
N2 C9 O1 114.5(3) . .
N2 C9 C1 132.4(3) . .
C1 C9 Dy1 151.9(2) . .
C11 C10 N2 122.2(4) . .
C15 C10 N2 117.3(3) . .
C15 C10 C11 120.4(4) . .
C10 C11 C16 123.1(4) . .
C12 C11 C10 115.2(5) . .
C12 C11 C16 121.7(4) . .
C11 C12 H12 118.0 . .
C13 C12 C11 124.1(5) . .
C13 C12 H12 118.0 . .
C12 C13 H13 119.7 . .
C12 C13 C14 120.5(5) . .
C14 C13 H13 119.7 . .
C13 C14 H14 121.0 . .
C13 C14 C15 117.9(6) . .
C15 C14 H14 121.0 . .
C10 C15 C14 121.9(5) . .
C10 C15 H15 119.1 . .
C14 C15 H15 119.1 . .
C11 C16 C17 113.6(5) . .
C11 C16 C18 111.8(3) . .
C11 C16 C19 110.3(4) . .
C17 C16 C19 105.5(4) . .
C18 C16 C17 105.6(4) . .
C18 C16 C19 109.6(4) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17B 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C16 C18 H18A 109.5 . .
C16 C18 H18B 109.5 . .
C16 C18 H18C 109.5 . .
H18A C18 H18B 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C16 C19 H19A 109.5 . .
C16 C19 H19B 109.5 . .
C16 C19 H19C 109.5 . .
H19A C19 H19B 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
Dy1 C20 H20A 105.4 . .
Dy1 C20 H20B 105.4 . .
Si1 C20 Dy1 127.58(17) . .
Si1 C20 H20A 105.4 . .
Si1 C20 H20B 105.4 . .
H20A C20 H20B 106.0 . .
Si1 C21 H21A 109.5 . .
Si1 C21 H21B 109.5 . .
Si1 C21 H21C 109.5 . .
H21A C21 H21B 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
Si1 C22 H22A 109.5 . .
Si1 C22 H22B 109.5 . .
Si1 C22 H22C 109.5 . .
H22A C22 H22B 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
Si1 C23 H23A 109.5 . .
Si1 C23 H23B 109.5 . .
Si1 C23 H23C 109.5 . .
H23A C23 H23B 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
O2 C24 H24A 110.6 . .
O2 C24 H24B 110.6 . .
O2 C24 C25 105.6(4) . .
H24A C24 H24B 108.7 . .
C25 C24 H24A 110.6 . .
C25 C24 H24B 110.6 . .
C24 C25 H25A 109.8 . .
C24 C25 H25B 109.8 . .
H25A C25 H25B 108.2 . .
C26 C25 C24 109.5(5) . .
C26 C25 H25A 109.8 . .
C26 C25 H25B 109.8 . .
C25 C26 H26A 110.2 . .
C25 C26 H26B 110.2 . .
C25 C26 C27 107.4(5) . .
H26A C26 H26B 108.5 . .
C27 C26 H26A 110.2 . .
C27 C26 H26B 110.2 . .
O2 C27 C26 107.6(4) . .
O2 C27 H27A 110.2 . .
O2 C27 H27B 110.2 . .
C26 C27 H27A 110.2 . .
C26 C27 H27B 110.2 . .
H27A C27 H27B 108.5 . .
O3 C28 H28A 110.8 . .
O3 C28 H28B 110.8 . .
O3 C28 C29 104.9(4) . .
H28A C28 H28B 108.8 . .
C29 C28 H28A 110.8 . .
C29 C28 H28B 110.8 . .
C28 C29 H29A 110.2 . .
C28 C29 H29B 110.2 . .
H29A C29 H29B 108.5 . .
C30 C29 C28 107.4(4) . .
C30 C29 H29A 110.2 . .
C30 C29 H29B 110.2 . .
C29 C30 H30A 109.8 . .
C29 C30 H30B 109.8 . .
C29 C30 C31 109.5(5) . .
H30A C30 H30B 108.2 . .
C31 C30 H30A 109.8 . .
C31 C30 H30B 109.8 . .
O3 C31 C30 105.9(4) . .
O3 C31 H31A 110.6 . .
O3 C31 H31B 110.6 . .
C30 C31 H31A 110.6 . .
C30 C31 H31B 110.6 . .
H31A C31 H31B 108.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 Dy1 3.8728(4) 7_567
Dy1 O1 2.2973(18) 7_567
Dy1 O1 2.2933(18) .
Dy1 O2 2.499(3) .
Dy1 O3 2.409(2) .
Dy1 N1 2.364(2) 7_567
Dy1 N2 2.783(2) .
Dy1 C9 2.949(3) .
Dy1 C20 2.413(3) .
Si1 C20 1.827(3) .
Si1 C21 1.879(5) .
Si1 C22 1.860(4) .
Si1 C23 1.869(4) .
O1 C9 1.333(4) .
O2 C24 1.441(5) .
O2 C27 1.429(4) .
O3 C28 1.434(4) .
O3 C31 1.456(4) .
N1 C1 1.396(4) .
N1 C8 1.387(4) .
N2 C9 1.288(3) .
N2 C10 1.429(4) .
C1 C2 1.375(4) .
C1 C9 1.467(4) .
C2 H2 0.9300 .
C2 C3 1.406(4) .
C3 C4 1.417(4) .
C3 C8 1.407(4) .
C4 H4 0.9300 .
C4 C5 1.370(5) .
C5 H5 0.9300 .
C5 C6 1.402(6) .
C6 H6 0.9300 .
C6 C7 1.362(5) .
C7 H7 0.9300 .
C7 C8 1.396(4) .
C10 C11 1.417(5) .
C10 C15 1.371(5) .
C11 C12 1.399(6) .
C11 C16 1.503(6) .
C12 H12 0.9300 .
C12 C13 1.344(8) .
C13 H13 0.9300 .
C13 C14 1.372(8) .
C14 H14 0.9300 .
C14 C15 1.393(6) .
C15 H15 0.9300 .
C16 C17 1.544(6) .
C16 C18 1.541(6) .
C16 C19 1.548(6) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C24 C25 1.446(7) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C25 C26 1.404(8) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C26 C27 1.446(7) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C28 C29 1.496(6) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C29 C30 1.389(7) .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C30 C31 1.458(6) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
