#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:23:38 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180076 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/22/7052241.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7052241
loop_
_publ_author_name
'Madalan, Augustin M.'
'Avarvari, Narcis'
'Andruh, Marius'
_publ_section_title
;
 Metal complexes as second-sphere ligands
;
_journal_issue                   4
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              521
_journal_paper_doi               10.1039/b517989k
_journal_volume                  30
_journal_year                    2006
_chemical_formula_sum            'C35 H33 Cl Cu N4 O11 Pd'
_chemical_formula_weight         891.04
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.64
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.543
_cell_length_b                   35.525
_cell_length_c                   8.437
_cell_measurement_reflns_used    220
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25
_cell_measurement_theta_min      2.5
_cell_volume                     3620.249
_computing_cell_refinement
'Dirax/lsq (Duisenberg & Schreurs, 1989-2000)'
_computing_data_collection       KappaCCD
_computing_data_reduction        'Denzo and Scalepak'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.954
_diffrn_measured_fraction_theta_max 0.954
_diffrn_measurement_device_type  area_detector
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.1241
_diffrn_reflns_av_sigmaI/netI    0.2289
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       43
_diffrn_reflns_limit_k_min       -46
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            19439
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.57
_exptl_absorpt_coefficient_mu    1.224
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.770271
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.635
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    .
_exptl_crystal_description       prism
_exptl_crystal_F_000             1804
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.441
_refine_diff_density_min         -0.365
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.945
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     505
_refine_ls_number_reflns         7912
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.945
_refine_ls_R_factor_all          0.2402
_refine_ls_R_factor_gt           0.0706
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0467P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1094
_refine_ls_wR_factor_ref         0.1501
_reflns_number_gt                2946
_reflns_number_total             7912
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b517989k.txt
_cod_data_source_block           mam104
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        3620.2
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7052241
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2814(6) 0.26150(17) 0.5073(7) 0.066(2) Uani 1 1 d . . .
H1A H 0.3536 0.2662 0.5795 0.099 Uiso 1 1 calc R . .
H1B H 0.2382 0.2842 0.4941 0.099 Uiso 1 1 calc R . .
H1C H 0.2883 0.2534 0.4020 0.099 Uiso 1 1 calc R . .
C2 C 0.1236(7) 0.2220(2) 0.4923(8) 0.053(2) Uani 1 1 d . . .
C3 C 0.0603(8) 0.2411(2) 0.3603(9) 0.068(2) Uani 1 1 d . . .
H3 H 0.0871 0.2629 0.3229 0.081 Uiso 1 1 calc R . .
C4 C -0.0430(9) 0.2280(3) 0.2834(10) 0.094(3) Uani 1 1 d . . .
H4 H -0.0867 0.2408 0.1929 0.113 Uiso 1 1 calc R . .
C5 C -0.0833(7) 0.1957(3) 0.3395(11) 0.089(3) Uani 1 1 d . . .
H5 H -0.1538 0.1873 0.2845 0.107 Uiso 1 1 calc R . .
C6 C -0.0215(7) 0.1752(3) 0.4768(9) 0.065(2) Uani 1 1 d . . .
C7 C 0.0857(7) 0.18885(19) 0.5562(8) 0.0481(18) Uani 1 1 d . . .
C8 C -0.0665(7) 0.1413(3) 0.5226(11) 0.077(2) Uani 1 1 d . . .
H8 H -0.1382 0.1351 0.4632 0.093 Uiso 1 1 calc R . .
C9 C -0.0802(9) 0.0872(3) 0.6770(12) 0.119(4) Uani 1 1 d . . .
H9A H -0.1240 0.0956 0.7491 0.143 Uiso 1 1 calc R . .
H9B H -0.1301 0.0772 0.5774 0.143 Uiso 1 1 calc R . .
C10 C -0.0055(9) 0.0588(3) 0.7560(15) 0.125(4) Uani 1 1 d . . .
H10A H 0.0083 0.0420 0.6730 0.151 Uiso 1 1 calc R . .
H10B H -0.0397 0.0442 0.8260 0.151 Uiso 1 1 calc R . .
C11 C 0.1729(11) 0.0556(2) 0.9724(13) 0.089(3) Uani 1 1 d . . .
H11 H 0.1498 0.0321 0.9994 0.107 Uiso 1 1 calc R . .
C12 C 0.2815(10) 0.0672(2) 1.0623(10) 0.070(2) Uani 1 1 d . . .
C13 C 0.3429(10) 0.0423(2) 1.1872(12) 0.090(3) Uani 1 1 d . . .
H13 H 0.3114 0.0198 1.2088 0.108 Uiso 1 1 calc R . .
C14 C 0.4472(11) 0.0515(3) 1.2741(12) 0.106(4) Uani 1 1 d . . .
H14 H 0.4861 0.0352 1.3556 0.127 Uiso 1 1 calc R . .
C15 C 0.4964(8) 0.0840(3) 1.2451(9) 0.081(3) Uani 1 1 d . . .
H15 H 0.5683 0.0897 1.3051 0.098 Uiso 1 1 calc R . .
C16 C 0.4386(9) 0.1081(2) 1.1265(9) 0.068(2) Uani 1 1 d . . .
C17 C 0.3301(8) 0.1011(2) 1.0313(10) 0.060(2) Uani 1 1 d . . .
C18 C 0.5968(8) 0.1477(2) 1.1582(8) 0.092(3) Uani 1 1 d . . .
H18A H 0.6158 0.1716 1.1210 0.138 Uiso 1 1 calc R . .
H18B H 0.6396 0.1283 1.1250 0.138 Uiso 1 1 calc R . .
H18C H 0.6124 0.1478 1.2760 0.138 Uiso 1 1 calc R . .
C19 C 0.2719(6) 0.16453(19) 1.3202(8) 0.0517(19) Uani 1 1 d . . .
H19 H 0.3013 0.1875 1.3000 0.062 Uiso 1 1 calc R . .
C20 C 0.1680(7) 0.1543(2) 1.2259(8) 0.064(2) Uani 1 1 d . . .
H20 H 0.1286 0.1701 1.1428 0.077 Uiso 1 1 calc R . .
C21 C 0.1239(6) 0.1212(2) 1.2548(8) 0.061(2) Uani 1 1 d . . .
H21 H 0.0536 0.1144 1.1918 0.073 Uiso 1 1 calc R . .
C22 C 0.1826(6) 0.0969(2) 1.3787(8) 0.0474(18) Uani 1 1 d . . .
C23 C 0.2850(6) 0.10877(19) 1.4677(7) 0.0467(18) Uani 1 1 d . . .
C24 C 0.3519(6) 0.08556(18) 1.5949(7) 0.0452(17) Uani 1 1 d . . .
C25 C 0.3154(6) 0.05037(18) 1.6299(8) 0.0481(18) Uani 1 1 d . . .
C26 C 0.3868(7) 0.02929(17) 1.7534(8) 0.056(2) Uani 1 1 d . . .
H26 H 0.3661 0.0055 1.7801 0.067 Uiso 1 1 calc R . .
C27 C 0.4858(7) 0.04369(19) 1.8333(8) 0.063(2) Uani 1 1 d . . .
H27 H 0.5332 0.0299 1.9168 0.075 Uiso 1 1 calc R . .
C28 C 0.5182(6) 0.07930(18) 1.7923(8) 0.0498(18) Uani 1 1 d . . .
H28 H 0.5872 0.0886 1.8492 0.060 Uiso 1 1 calc R . .
C29 C 0.1453(6) 0.0606(2) 1.4160(9) 0.067(2) Uani 1 1 d . . .
H29 H 0.0758 0.0521 1.3568 0.080 Uiso 1 1 calc R . .
C30 C 0.2082(7) 0.03857(19) 1.5345(9) 0.062(2) Uani 1 1 d . . .
H30 H 0.1815 0.0152 1.5548 0.075 Uiso 1 1 calc R . .
C31 C 0.8128(6) 0.1710(2) 1.8588(8) 0.077(2) Uani 1 1 d . . .
H31A H 0.8075 0.1514 1.9349 0.116 Uiso 1 1 calc R . .
H31B H 0.8292 0.1945 1.9165 0.116 Uiso 1 1 calc R . .
H31C H 0.8708 0.1650 1.8084 0.116 Uiso 1 1 calc R . .
C32 C 0.7041(6) 0.1742(2) 1.7273(8) 0.0531(19) Uani 1 1 d . . .
C33 C 0.6926(7) 0.20116(19) 1.6040(9) 0.062(2) Uani 1 1 d . . .
H33 H 0.7564 0.2138 1.5979 0.075 Uiso 1 1 calc R . .
C34 C 0.5953(8) 0.21086(19) 1.4903(9) 0.056(2) Uani 1 1 d . . .
C35 C 0.5943(7) 0.24258(19) 1.3741(9) 0.090(3) Uani 1 1 d . . .
H35A H 0.5210 0.2456 1.3029 0.136 Uiso 1 1 calc R . .
H35B H 0.6448 0.2372 1.3093 0.136 Uiso 1 1 calc R . .
H35C H 0.6167 0.2654 1.4354 0.136 Uiso 1 1 calc R . .
N1 N -0.0185(6) 0.1188(2) 0.6362(8) 0.081(2) Uani 1 1 d . . .
N2 N 0.1034(7) 0.07385(17) 0.8584(10) 0.079(2) Uani 1 1 d . . .
N3 N 0.3313(4) 0.14250(15) 1.4390(6) 0.0455(14) Uani 1 1 d . . .
N4 N 0.4538(5) 0.10009(13) 1.6752(6) 0.0429(14) Uani 1 1 d . . .
O1 O 0.2278(4) 0.23283(12) 0.5763(5) 0.0594(13) Uani 1 1 d . . .
O2 O 0.1554(4) 0.17331(11) 0.6838(5) 0.0565(13) Uani 1 1 d . . .
O1W O 0.3982(3) 0.18204(10) 1.7800(4) 0.0495(12) Uani 1 1 d . . .
O3 O 0.4826(5) 0.14058(16) 1.0884(5) 0.0759(16) Uani 1 1 d . . .
O4 O 0.2842(4) 0.12643(12) 0.9216(5) 0.0620(13) Uani 1 1 d . . .
O5 O 0.6267(4) 0.15295(12) 1.7430(5) 0.0606(13) Uani 1 1 d . . .
O6 O 0.5024(4) 0.19552(12) 1.4774(5) 0.0604(13) Uani 1 1 d . . .
O7 O 0.9142(16) 0.0387(6) 2.102(3) 0.155(6) Uani 0.60 1 d P . .
O7A O 0.785(3) 0.0496(7) 1.970(2) 0.144(10) Uani 0.40 1 d P . .
O8 O 0.842(3) 0.0487(9) 2.307(2) 0.232(13) Uani 0.60 1 d P . .
O8A O 0.8927(19) 0.0282(5) 2.220(4) 0.096(7) Uani 0.40 1 d P . .
O9 O 0.8508(6) 0.09350(17) 2.1509(10) 0.176(3) Uani 1 1 d . . .
O10 O 0.7298(16) 0.0430(5) 2.061(3) 0.146(8) Uani 0.60 1 d P . .
O10A O 0.734(3) 0.0554(7) 2.214(6) 0.165(14) Uani 0.40 1 d P . .
Cu1 Cu 0.47870(7) 0.15224(2) 1.60168(9) 0.0512(3) Uani 1 1 d . . .
Cl1 Cl 0.8245(2) 0.05646(6) 2.1449(4) 0.0799(7) Uani 1 1 d . . .
Pd1 Pd 0.13167(5) 0.123337(14) 0.77581(6) 0.0602(2) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C3 C2 O1 123.4(7) . . ?
C3 C2 C7 122.6(8) . . ?
O1 C2 C7 114.0(6) . . ?
C2 C3 C4 119.2(8) . . ?
C3 C4 C5 120.4(8) . . ?
C4 C5 C6 122.5(8) . . ?
C5 C6 C7 117.0(8) . . ?
C5 C6 C8 119.2(9) . . ?
C7 C6 C8 123.7(7) . . ?
O2 C7 C6 125.6(7) . . ?
O2 C7 C2 116.1(7) . . ?
C6 C7 C2 118.3(7) . . ?
N1 C8 C6 126.5(8) . . ?
C10 C9 N1 109.5(9) . . ?
C9 C10 N2 113.7(8) . . ?
N2 C11 C12 127.5(9) . . ?
C17 C12 C11 123.1(8) . . ?
C17 C12 C13 119.5(10) . . ?
C11 C12 C13 117.4(9) . . ?
C14 C13 C12 119.9(10) . . ?
C13 C14 C15 121.7(10) . . ?
C14 C15 C16 119.1(10) . . ?
O3 C16 C15 122.5(10) . . ?
O3 C16 C17 114.2(7) . . ?
C15 C16 C17 123.2(9) . . ?
O4 C17 C16 117.2(7) . . ?
O4 C17 C12 126.2(9) . . ?
C16 C17 C12 116.6(8) . . ?
N3 C19 C20 121.9(7) . . ?
C21 C20 C19 119.7(7) . . ?
C20 C21 C22 120.9(7) . . ?
C23 C22 C21 116.4(7) . . ?
C23 C22 C29 118.1(6) . . ?
C21 C22 C29 125.4(7) . . ?
C22 C23 N3 123.3(6) . . ?
C22 C23 C24 120.4(7) . . ?
N3 C23 C24 116.3(6) . . ?
N4 C24 C25 123.3(6) . . ?
N4 C24 C23 115.6(6) . . ?
C25 C24 C23 121.1(7) . . ?
C24 C25 C26 117.3(7) . . ?
C24 C25 C30 117.2(7) . . ?
C26 C25 C30 125.4(7) . . ?
C27 C26 C25 119.4(6) . . ?
C26 C27 C28 120.7(7) . . ?
N4 C28 C27 122.0(7) . . ?
C30 C29 C22 121.6(7) . . ?
C29 C30 C25 121.4(7) . . ?
O5 C32 C33 124.1(7) . . ?
O5 C32 C31 116.3(7) . . ?
C33 C32 C31 119.4(7) . . ?
C34 C33 C32 125.9(7) . . ?
O6 C34 C33 125.1(7) . . ?
O6 C34 C35 115.2(7) . . ?
C33 C34 C35 119.7(7) . . ?
C8 N1 C9 119.3(8) . . ?
C8 N1 Pd1 126.3(6) . . ?
C9 N1 Pd1 114.2(6) . . ?
C11 N2 C10 125.3(9) . . ?
C11 N2 Pd1 124.6(7) . . ?
C10 N2 Pd1 109.7(6) . . ?
C19 N3 C23 117.8(6) . . ?
C19 N3 Cu1 129.6(5) . . ?
C23 N3 Cu1 112.4(4) . . ?
C28 N4 C24 117.3(5) . . ?
C28 N4 Cu1 129.3(5) . . ?
C24 N4 Cu1 113.3(4) . . ?
C2 O1 C1 118.7(5) . . ?
C7 O2 Pd1 123.9(4) . . ?
C16 O3 C18 118.9(7) . . ?
C17 O4 Pd1 124.7(5) . . ?
C32 O5 Cu1 125.8(4) . . ?
C34 O6 Cu1 124.8(5) . . ?
O8A O7 Cl1 62.6(14) . . ?
O8A O7 O7A 103(2) . . ?
Cl1 O7 O7A 53.1(11) . . ?
O10 O7A Cl1 58.1(11) . . ?
O10 O7A O7 98.4(17) . . ?
Cl1 O7A O7 51.8(9) . . ?
O8A O8 Cl1 61.2(11) . . ?
O8A O8 O10A 109(3) . . ?
Cl1 O8 O10A 61.6(16) . . ?
O7 O8A O8 124(2) . . ?
O7 O8A Cl1 68.0(14) . . ?
O8 O8A Cl1 60.9(13) . . ?
O7A O10 Cl1 71.0(16) . . ?
O7A O10 O10A 133(3) . . ?
Cl1 O10 O10A 64.4(16) . . ?
O10 O10A O8 105(3) . . ?
O10 O10A Cl1 56.1(16) . . ?
O8 O10A Cl1 57.8(17) . . ?
O5 Cu1 O6 93.6(2) . . ?
O5 Cu1 N4 91.4(2) . . ?
O6 Cu1 N4 164.72(18) . . ?
O5 Cu1 N3 169.61(19) . . ?
O6 Cu1 N3 90.8(2) . . ?
N4 Cu1 N3 82.0(2) . . ?
O5 Cu1 O1W 96.31(17) . . ?
O6 Cu1 O1W 98.56(16) . . ?
N4 Cu1 O1W 95.21(17) . . ?
N3 Cu1 O1W 92.32(16) . . ?
O10 Cl1 O9 123.8(8) . . ?
O10 Cl1 O8 110.6(14) . . ?
O9 Cl1 O8 100.8(12) . . ?
O10 Cl1 O8A 110.5(11) . . ?
O9 Cl1 O8A 125.7(9) . . ?
O8 Cl1 O8A 57.9(13) . . ?
O10 Cl1 O10A 59.5(16) . . ?
O9 Cl1 O10A 103.1(13) . . ?
O8 Cl1 O10A 60.6(15) . . ?
O8A Cl1 O10A 105.3(17) . . ?
O10 Cl1 O7 111.6(14) . . ?
O9 Cl1 O7 103.9(9) . . ?
O8 Cl1 O7 104.1(17) . . ?
O8A Cl1 O7 49.4(10) . . ?
O10A Cl1 O7 151.1(14) . . ?
O10 Cl1 O7A 50.8(11) . . ?
O9 Cl1 O7A 102.5(12) . . ?
O8 Cl1 O7A 156.2(16) . . ?
O8A Cl1 O7A 110.6(16) . . ?
O10A Cl1 O7A 109(2) . . ?
O7 Cl1 O7A 75.1(14) . . ?
N1 Pd1 N2 84.4(3) . . ?
N1 Pd1 O4 178.2(3) . . ?
N2 Pd1 O4 93.8(3) . . ?
N1 Pd1 O2 93.4(3) . . ?
N2 Pd1 O2 177.7(3) . . ?
O4 Pd1 O2 88.37(18) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.428(7) . ?
C2 C3 1.362(8) . ?
C2 O1 1.362(8) . ?
C2 C7 1.430(8) . ?
C3 C4 1.364(11) . ?
C4 C5 1.387(11) . ?
C5 C6 1.411(10) . ?
C6 C7 1.415(9) . ?
C6 C8 1.427(10) . ?
C7 O2 1.312(7) . ?
C8 N1 1.269(9) . ?
C9 C10 1.415(11) . ?
C9 N1 1.458(10) . ?
C10 N2 1.504(10) . ?
C11 N2 1.286(10) . ?
C11 C12 1.429(11) . ?
C12 C17 1.407(10) . ?
C12 C13 1.431(11) . ?
C13 C14 1.355(12) . ?
C14 C15 1.362(12) . ?
C15 C16 1.368(10) . ?
C16 O3 1.354(9) . ?
C16 C17 1.403(10) . ?
C17 O4 1.308(8) . ?
C18 O3 1.416(8) . ?
C19 N3 1.330(7) . ?
C19 C20 1.380(9) . ?
C20 C21 1.349(9) . ?
C21 C22 1.402(9) . ?
C22 C23 1.369(8) . ?
C22 C29 1.434(9) . ?
C23 N3 1.380(8) . ?
C23 C24 1.432(8) . ?
C24 N4 1.375(7) . ?
C24 C25 1.390(8) . ?
C25 C26 1.395(8) . ?
C25 C30 1.431(9) . ?
C26 C27 1.344(9) . ?
C27 C28 1.401(8) . ?
C28 N4 1.320(7) . ?
C29 C30 1.346(8) . ?
C31 C32 1.512(8) . ?
C32 O5 1.265(7) . ?
C32 C33 1.393(9) . ?
C33 C34 1.377(9) . ?
C34 O6 1.265(8) . ?
C34 C35 1.491(8) . ?
N1 Pd1 1.940(7) . ?
N2 Pd1 1.958(6) . ?
N3 Cu1 2.014(5) . ?
N4 Cu1 2.005(5) . ?
O2 Pd1 1.992(4) . ?
O1W Cu1 2.285(4) . ?
O4 Pd1 1.979(5) . ?
O5 Cu1 1.917(5) . ?
O6 Cu1 1.928(4) . ?
O7 O8A 1.16(2) . ?
O7 Cl1 1.421(18) . ?
O7 O7A 1.75(3) . ?
O7A O10 1.18(2) . ?
O7A Cl1 1.446(19) . ?
O8 O8A 1.31(3) . ?
O8 Cl1 1.356(18) . ?
O8 O10A 1.40(4) . ?
O8A Cl1 1.361(17) . ?
O9 Cl1 1.354(6) . ?
O10 Cl1 1.299(15) . ?
O10 O10A 1.35(4) . ?
O10A Cl1 1.41(3) . ?
