#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:31:35 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180083 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/29/7052999.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7052999
loop_
_publ_author_name
'Bo, Qi-Bing'
'Wang, Hong-Yan'
'Wang, Da-Qi'
_publ_section_title
;
 Synthesis, characterization and photoluminescent properties of Zn-based
 mono- and hetero-MOFs containing the R-isophthalate (R = methyl or
 tert-butyl) ligands
;
_journal_issue                   2
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              380
_journal_paper_doi               10.1039/c2nj40752c
_journal_volume                  37
_journal_year                    2013
_chemical_formula_sum            'C18 H22 Mg O13 Zn'
_chemical_formula_weight         536.04
_chemical_name_systematic
;
?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   22.0170(17)
_cell_length_b                   16.2879(16)
_cell_length_c                   13.7909(11)
_cell_measurement_temperature    293(2)
_cell_volume                     4945.6(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0556
_diffrn_reflns_av_sigmaI/netI    0.0676
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            16243
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.68
_exptl_absorpt_coefficient_mu    1.079
_exptl_absorpt_correction_T_max  0.8906
_exptl_absorpt_correction_T_min  0.8637
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.440
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2208
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_platon_squeeze_details
;
;
_refine_diff_density_max         0.409
_refine_diff_density_min         -0.460
_refine_diff_density_rms         0.080
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     285
_refine_ls_number_reflns         5216
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.1060
_refine_ls_R_factor_gt           0.0668
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0635P)²+5.3459P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1529
_refine_ls_wR_factor_ref         0.1735
_reflns_number_gt                3231
_reflns_number_total             5216
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2nj40752c.txt
_cod_data_source_block           ZnMg-mip
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      Pnma
_cod_database_code               7052999
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z-1/2'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.33117(2) -0.00209(3) 1.02021(4) 0.03956(19) Uani 1 1 d .
Mg1 Mg 0.25915(6) -0.05091(9) 1.27790(10) 0.0366(4) Uani 1 1 d .
O1 O 0.38959(18) 0.0145(3) 0.9177(3) 0.0804(13) Uani 1 1 d .
O2 O 0.32988(16) 0.0573(3) 0.7994(3) 0.0828(14) Uani 1 1 d .
O3 O 0.60774(16) 0.0258(3) 0.8831(3) 0.0740(12) Uani 1 1 d .
O4 O 0.65054(17) 0.0525(3) 0.7420(3) 0.1002(17) Uani 1 1 d .
O5 O 0.28827(15) 0.09998(18) 1.0500(2) 0.0465(8) Uani 1 1 d .
O6 O 0.24563(14) 0.0337(2) 1.1720(3) 0.0520(9) Uani 1 1 d .
O7 O 0.28322(15) -0.0999(2) 0.9959(2) 0.0471(8) Uani 1 1 d .
O8 O 0.23056(16) -0.0334(2) 0.8853(3) 0.0617(10) Uani 1 1 d .
O1W O 0.2524(3) -0.1461(2) 1.1802(3) 0.1006(18) Uani 1 1 d .
H1WB H 0.2135 -0.1569 1.1619 0.151 Uiso 1 1 d R
H1WA H 0.2728 -0.1358 1.1243 0.151 Uiso 1 1 d R
O2W O 0.2675(3) -0.1459(2) 1.3782(3) 0.106(2) Uani 1 1 d .
H2WA H 0.3082 -0.1581 1.3954 0.160 Uiso 1 1 d R
H2WB H 0.2484 -0.1373 1.4399 0.160 Uiso 1 1 d R
C1 C 0.3806(2) 0.0398(3) 0.8321(4) 0.0474(12) Uani 1 1 d .
C2 C 0.43585(19) 0.0509(3) 0.7693(3) 0.0411(11) Uani 1 1 d .
C3 C 0.4297(2) 0.0744(3) 0.6735(3) 0.0558(14) Uani 1 1 d .
H3 H 0.3911 0.0811 0.6473 0.067 Uiso 1 1 calc R
C4 C 0.4796(3) 0.0882(4) 0.6164(4) 0.0648(16) Uani 1 1 d .
C5 C 0.4709(4) 0.1138(6) 0.5096(4) 0.111(3) Uani 1 1 d .
H5A H 0.4315 0.0965 0.4878 0.167 Uiso 1 1 calc R
H5B H 0.5017 0.0884 0.4705 0.167 Uiso 1 1 calc R
H5C H 0.4741 0.1724 0.5042 0.167 Uiso 1 1 calc R
C6 C 0.5372(2) 0.0754(3) 0.6546(3) 0.0559(14) Uani 1 1 d .
H6 H 0.5714 0.0828 0.6159 0.067 Uiso 1 1 calc R
C7 C 0.5439(2) 0.0514(3) 0.7515(3) 0.0436(11) Uani 1 1 d .
C8 C 0.6061(2) 0.0425(3) 0.7934(4) 0.0491(12) Uani 1 1 d .
C9 C 0.49319(18) 0.0391(3) 0.8075(3) 0.0423(11) Uani 1 1 d .
H9 H 0.4975 0.0227 0.8717 0.051 Uiso 1 1 calc R
C10 C 0.25445(18) 0.0975(3) 1.1253(3) 0.0344(10) Uani 1 1 d .
C11 C 0.22494(17) 0.1761(3) 1.1548(3) 0.0337(9) Uani 1 1 d .
C12 C 0.2494(2) 0.2500 1.1219(4) 0.0320(13) Uani 1 2 d S
H12 H 0.2817 0.2500 1.0785 0.038 Uiso 1 2 calc SR
C13 C 0.1759(2) 0.1769(3) 1.2161(4) 0.0489(12) Uani 1 1 d .
H13 H 0.1595 0.1273 1.2367 0.059 Uiso 1 1 calc R
C14 C 0.1500(3) 0.2500 1.2485(5) 0.0522(19) Uani 1 2 d S
C15 C 0.0971(4) 0.2500 1.3181(8) 0.099(3) Uani 1 2 d S
H15A H 0.0828 0.3052 1.3269 0.148 Uiso 0.50 1 calc PR
H15B H 0.1099 0.2281 1.3793 0.148 Uiso 0.50 1 calc PR
H15C H 0.0650 0.2168 1.2922 0.148 Uiso 0.50 1 calc PR
C16 C 0.2436(2) -0.0973(3) 0.9277(3) 0.0426(11) Uani 1 1 d .
C17 C 0.21258(19) -0.1768(3) 0.9033(3) 0.0382(10) Uani 1 1 d .
C18 C 0.1608(2) -0.1766(3) 0.8458(4) 0.0525(13) Uani 1 1 d .
H18 H 0.1439 -0.1271 0.8260 0.063 Uiso 1 1 calc R
C19 C 0.1343(3) -0.2500 0.8180(6) 0.061(2) Uani 1 2 d S
C20 C 0.0761(4) -0.2500 0.7559(9) 0.123(5) Uani 1 2 d S
H20A H 0.0637 -0.1944 0.7439 0.185 Uiso 0.50 1 calc PR
H20B H 0.0444 -0.2785 0.7898 0.185 Uiso 0.50 1 calc PR
H20C H 0.0840 -0.2770 0.6954 0.185 Uiso 0.50 1 calc PR
C21 C 0.2374(3) -0.2500 0.9329(4) 0.0364(14) Uani 1 2 d S
H21 H 0.2713 -0.2500 0.9732 0.044 Uiso 1 2 calc SR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Zn1 O3 94.00(18) . 5_657
O1 Zn1 O7 110.55(17) . .
O3 Zn1 O7 109.45(17) 5_657 .
O1 Zn1 O5 110.89(16) . .
O3 Zn1 O5 111.19(16) 5_657 .
O7 Zn1 O5 118.14(15) . .
O2 Mg1 O4 176.2(2) 2 5_657
O2 Mg1 O6 89.91(17) 2 .
O4 Mg1 O6 93.20(17) 5_657 .
O2 Mg1 O8 92.10(17) 2 2
O4 Mg1 O8 89.86(19) 5_657 2
O6 Mg1 O8 94.72(16) . 2
O2 Mg1 O1W 89.3(2) 2 .
O4 Mg1 O1W 88.4(2) 5_657 .
O6 Mg1 O1W 91.70(16) . .
O8 Mg1 O1W 173.43(18) 2 .
O2 Mg1 O2W 87.1(2) 2 .
O4 Mg1 O2W 89.6(2) 5_657 .
O6 Mg1 O2W 174.1(2) . .
O8 Mg1 O2W 90.45(17) 2 .
O1W Mg1 O2W 83.20(17) . .
C1 O1 Zn1 128.7(4) . .
C1 O2 Mg1 158.9(4) . 2_554
C8 O3 Zn1 137.4(4) . 5_657
C8 O4 Mg1 150.7(4) . 5_657
C10 O5 Zn1 115.2(3) . .
C10 O6 Mg1 157.1(3) . .
C16 O7 Zn1 118.0(3) . .
C16 O8 Mg1 153.3(3) . 2_554
Mg1 O1W H1WB 113.2 . .
Mg1 O1W H1WA 112.3 . .
H1WB O1W H1WA 105.5 . .
Mg1 O2W H2WA 113.8 . .
Mg1 O2W H2WB 116.2 . .
H2WA O2W H2WB 102.9 . .
O2 C1 O1 123.7(5) . .
O2 C1 C2 119.5(5) . .
O1 C1 C2 116.8(4) . .
C9 C2 C3 119.5(4) . .
C9 C2 C1 120.2(4) . .
C3 C2 C1 120.3(4) . .
C4 C3 C2 121.1(4) . .
C4 C3 H3 119.5 . .
C2 C3 H3 119.5 . .
C3 C4 C6 119.3(5) . .
C3 C4 C5 119.5(5) . .
C6 C4 C5 121.1(5) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C4 C6 C7 120.1(5) . .
C4 C6 H6 120.0 . .
C7 C6 H6 120.0 . .
C9 C7 C6 119.5(4) . .
C9 C7 C8 120.9(4) . .
C6 C7 C8 119.5(4) . .
O4 C8 O3 125.1(5) . .
O4 C8 C7 119.8(5) . .
O3 C8 C7 115.1(4) . .
C7 C9 C2 120.6(4) . .
C7 C9 H9 119.7 . .
C2 C9 H9 119.7 . .
O6 C10 O5 122.7(4) . .
O6 C10 C11 120.7(4) . .
O5 C10 C11 116.7(4) . .
C13 C11 C12 119.7(4) . .
C13 C11 C10 121.3(4) . .
C12 C11 C10 118.9(4) . .
C11 C12 C11 119.4(5) 8_565 .
C11 C12 H12 120.3 8_565 .
C11 C12 H12 120.3 . .
C11 C13 C14 121.9(5) . .
C11 C13 H13 119.1 . .
C14 C13 H13 119.1 . .
C13 C14 C13 117.3(6) . 8_565
C13 C14 C15 121.3(3) . .
C13 C14 C15 121.3(3) 8_565 .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
O8 C16 O7 122.3(5) . .
O8 C16 C17 121.3(4) . .
O7 C16 C17 116.4(4) . .
C21 C17 C18 119.9(5) . .
C21 C17 C16 120.1(4) . .
C18 C17 C16 119.9(4) . .
C19 C18 C17 120.2(5) . .
C19 C18 H18 119.9 . .
C17 C18 H18 119.9 . .
C18 C19 C18 119.3(6) . 8
C18 C19 C20 120.3(3) . .
C18 C19 C20 120.3(3) 8 .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C17 C21 C17 120.4(6) 8 .
C17 C21 H21 119.8 8 .
C17 C21 H21 119.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O1 1.930(4) .
Zn1 O3 1.933(3) 5_657
Zn1 O7 1.941(3) .
Zn1 O5 1.956(3) .
Mg1 O2 1.985(4) 2
Mg1 O4 2.007(4) 5_657
Mg1 O6 2.030(4) .
Mg1 O8 2.032(4) 2
Mg1 O1W 2.060(4) .
Mg1 O2W 2.084(4) .
O1 C1 1.265(6) .
O2 C1 1.238(6) .
O2 Mg1 1.985(4) 2_554
O3 C8 1.266(6) .
O3 Zn1 1.933(3) 5_657
O4 C8 1.219(6) .
O4 Mg1 2.007(4) 5_657
O5 C10 1.278(5) .
O6 C10 1.239(5) .
O7 C16 1.285(5) .
O8 C16 1.228(5) .
O8 Mg1 2.032(4) 2_554
O1W H1WB 0.9109 .
O1W H1WA 0.9081 .
O2W H2WA 0.9488 .
O2W H2WB 0.9591 .
C1 C2 1.504(6) .
C2 C9 1.382(6) .
C2 C3 1.383(6) .
C3 C4 1.371(7) .
C3 H3 0.9300 .
C4 C6 1.389(7) .
C4 C5 1.541(7) .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 C7 1.400(6) .
C6 H6 0.9300 .
C7 C9 1.373(6) .
C7 C8 1.494(6) .
C9 H9 0.9300 .
C10 C11 1.491(6) .
C11 C13 1.371(6) .
C11 C12 1.395(5) .
C12 C11 1.395(5) 8_565
C12 H12 0.9300 .
C13 C14 1.394(6) .
C13 H13 0.9300 .
C14 C13 1.394(6) 8_565
C14 C15 1.508(9) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 C17 1.502(6) .
C17 C21 1.373(5) .
C17 C18 1.388(6) .
C18 C19 1.384(6) .
C18 H18 0.9300 .
C19 C18 1.384(6) 8
C19 C20 1.540(10) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 C17 1.373(5) 8
C21 H21 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Zn1 O1 C1 -173.2(5) 5_657 .
O7 Zn1 O1 C1 74.3(5) . .
O5 Zn1 O1 C1 -58.7(5) . .
O1 Zn1 O5 C10 -171.3(3) . .
O3 Zn1 O5 C10 -68.1(3) 5_657 .
O7 Zn1 O5 C10 59.7(3) . .
O2 Mg1 O6 C10 135.6(8) 2 .
O4 Mg1 O6 C10 -46.7(8) 5_657 .
O8 Mg1 O6 C10 43.5(8) 2 .
O1W Mg1 O6 C10 -135.2(8) . .
O2W Mg1 O6 C10 -165.3(15) . .
O1 Zn1 O7 C16 -72.2(3) . .
O3 Zn1 O7 C16 -174.4(3) 5_657 .
O5 Zn1 O7 C16 57.0(3) . .
Mg1 O2 C1 O1 -36.0(15) 2_554 .
Mg1 O2 C1 C2 146.0(10) 2_554 .
Zn1 O1 C1 O2 -1.2(8) . .
Zn1 O1 C1 C2 176.9(3) . .
O2 C1 C2 C9 173.8(5) . .
O1 C1 C2 C9 -4.4(7) . .
O2 C1 C2 C3 -5.0(7) . .
O1 C1 C2 C3 176.9(5) . .
C9 C2 C3 C4 -1.6(8) . .
C1 C2 C3 C4 177.2(5) . .
C2 C3 C4 C6 2.3(9) . .
C2 C3 C4 C5 179.5(6) . .
C3 C4 C6 C7 -2.2(9) . .
C5 C4 C6 C7 -179.3(6) . .
C4 C6 C7 C9 1.3(8) . .
C4 C6 C7 C8 -176.5(5) . .
Mg1 O4 C8 O3 5.7(14) 5_657 .
Mg1 O4 C8 C7 -175.5(7) 5_657 .
Zn1 O3 C8 O4 -4.5(10) 5_657 .
Zn1 O3 C8 C7 176.7(4) 5_657 .
C9 C7 C8 O4 178.9(5) . .
C6 C7 C8 O4 -3.4(8) . .
C9 C7 C8 O3 -2.2(7) . .
C6 C7 C8 O3 175.5(5) . .
C6 C7 C9 C2 -0.6(7) . .
C8 C7 C9 C2 177.2(5) . .
C3 C2 C9 C7 0.7(8) . .
C1 C2 C9 C7 -178.1(4) . .
Mg1 O6 C10 O5 94.0(9) . .
Mg1 O6 C10 C11 -86.6(9) . .
Zn1 O5 C10 O6 -5.3(5) . .
Zn1 O5 C10 C11 175.2(3) . .
O6 C10 C11 C13 -17.5(6) . .
O5 C10 C11 C13 162.0(4) . .
O6 C10 C11 C12 160.1(4) . .
O5 C10 C11 C12 -20.5(6) . .
C13 C11 C12 C11 2.3(8) . 8_565
C10 C11 C12 C11 -175.3(3) . 8_565
C12 C11 C13 C14 -1.2(8) . .
C10 C11 C13 C14 176.4(5) . .
C11 C13 C14 C13 0.0(10) . 8_565
C11 C13 C14 C15 -178.4(7) . .
Mg1 O8 C16 O7 90.4(9) 2_554 .
Mg1 O8 C16 C17 -90.9(8) 2_554 .
Zn1 O7 C16 O8 -8.2(6) . .
Zn1 O7 C16 C17 173.1(3) . .
O8 C16 C17 C21 163.7(5) . .
O7 C16 C17 C21 -17.5(6) . .
O8 C16 C17 C18 -12.3(6) . .
O7 C16 C17 C18 166.4(4) . .
C21 C17 C18 C19 -0.2(8) . .
C16 C17 C18 C19 175.9(5) . .
C17 C18 C19 C18 -1.8(11) . 8
C17 C18 C19 C20 178.8(7) . .
C18 C17 C21 C17 2.2(8) . 8
C16 C17 C21 C17 -173.9(3) . 8
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.017 0.250 -0.283 317 53 ' '
2 0.517 0.250 -0.218 318 53 ' '
3 0.983 0.750 0.282 317 53 ' '
4 0.483 0.750 0.217 317 53 ' '
5 0.045 0.118 0.190 8 1 ' '
6 0.045 0.382 0.190 8 1 ' '
7 0.545 0.118 0.309 7 1 ' '
8 0.545 0.382 0.309 7 1 ' '
9 0.455 0.618 0.690 8 1 ' '
10 0.455 0.882 0.690 8 1 ' '
11 0.955 0.618 0.809 8 1 ' '
12 0.955 0.882 0.809 8 1 ' '
