#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:48:51 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180097 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/43/7054343.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7054343
loop_
_publ_author_name
'Kulikov, Vladislav'
'Meyer, Gerd'
_publ_section_title
;
 Organoamine silver(i) decatungstate structures: remarkable
 chemoselectivity and the exploration of the intramolecular redox reaction
 upon thermolysis
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              3408
_journal_paper_doi               10.1039/C4NJ00172A
_journal_volume                  38
_journal_year                    2014
_chemical_formula_moiety         '4(C14 H10 N2 Ag), W10 O32'
_chemical_formula_sum            'C56 H40 Ag4 N8 O32 W10'
_chemical_formula_weight         3606.94
_chemical_melting_point          ?
_chemical_name_common
;
Tetrakis(dibenzonitrilesiver(I))decatungstate
;
_chemical_name_systematic
; 
Tetrakis(dibenzonitrilesiver(I))di-mu5-oxo-icosa-mu-oxo-decaoxodecatungstate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.717(4)
_cell_angle_beta                 113.242(3)
_cell_angle_gamma                94.594(3)
_cell_formula_units_Z            1
_cell_length_a                   11.0972(4)
_cell_length_b                   13.3970(5)
_cell_length_c                   13.9852(7)
_cell_measurement_reflns_used    'not measured'
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      'not measured'
_cell_measurement_theta_min      'not measured'
_cell_volume                     1809.31(15)
_computing_cell_refinement       'X-Area, (Stoe, 2001)'
_computing_data_collection       'X-Area, (Stoe, 2001)'
_computing_data_reduction        'X-Area, (Stoe, 2001)'
_computing_molecular_graphics    'Diamond v3.2 (Crystal Impact 2011)'
_computing_publication_material  'Diamond v3.2 (Crystal Impact 2011)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 'not measured'
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'IPDS II (Stoe & Cie)'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0798
_diffrn_reflns_av_unetI/netI     0.0530
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            25537
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.80
_diffrn_reflns_theta_min         1.92
_diffrn_standards_decay_%        'not measured'
_diffrn_standards_interval_count 'not measured'
_diffrn_standards_interval_time  'not measured'
_diffrn_standards_number         'not measured'
_exptl_absorpt_coefficient_mu    16.963
_exptl_absorpt_correction_T_max  0.1911
_exptl_absorpt_correction_T_min  0.0469
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
The absorption correction (X-RED; Stoe & Cie, 2001) 
was performed after optimizing the crystal shape 
using X-SHAPE (Stoe & Cie, 1999).
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    3.310
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1616
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.534
_refine_diff_density_min         -2.125
_refine_diff_density_rms         0.205
_refine_ls_extinction_coef       0.00109(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.114
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     497
_refine_ls_number_reflns         7649
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.114
_refine_ls_R_factor_all          0.0345
_refine_ls_R_factor_gt           0.0301
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0211P)²+7.1758P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0742
_refine_ls_wR_factor_ref         0.0767
_reflns_number_gt                6924
_reflns_number_total             7649
_reflns_threshold_expression     >4sigma(I)
_cod_data_source_file            c4nj00172a2.cif
_cod_data_source_block           AGPhCNW
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        1809.31(14)
_cod_database_code               7054343
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
W4 W 0.10511(3) 0.06928(2) -0.14609(2) 0.02247(8) Uani 1 1 d . .
W2 W -0.05250(3) 0.19891(2) 0.11157(2) 0.02287(8) Uani 1 1 d . .
W3 W 0.24254(3) 0.17585(2) 0.11993(2) 0.02377(8) Uani 1 1 d . .
W1 W 0.05577(3) 0.30050(2) -0.03840(2) 0.02547(8) Uani 1 1 d . .
W5 W -0.19028(3) 0.09286(2) -0.15489(2) 0.02361(8) Uani 1 1 d . .
Ag2 Ag 0.04802(8) 0.50560(6) 0.20158(6) 0.04990(17) Uani 1 1 d . .
O12 O -0.3421(5) 0.0774(5) -0.2598(4) 0.0359(12) Uani 1 1 d . .
O4 O -0.0111(5) 0.3249(4) 0.0707(4) 0.0256(9) Uani 1 1 d . .
O13 O -0.0843(5) 0.0468(4) -0.2296(4) 0.0271(10) Uani 1 1 d . .
O1 O 0.0782(6) 0.4213(4) -0.0566(5) 0.0368(12) Uani 1 1 d . .
O6 O 0.0261(4) 0.1393(3) -0.0158(3) 0.0202(9) Uani 1 1 d . .
O11 O -0.2125(5) 0.1544(4) -0.0240(4) 0.0255(10) Uani 1 1 d . .
O8 O 0.4013(5) 0.2214(4) 0.2192(4) 0.0373(12) Uani 1 1 d . .
O7 O 0.2639(5) 0.1124(4) -0.0107(4) 0.0261(10) Uani 1 1 d . .
O2 O 0.1139(5) 0.2145(4) -0.1385(4) 0.0277(10) Uani 1 1 d . .
O9 O 0.1375(5) 0.2208(4) 0.1969(4) 0.0269(10) Uani 1 1 d . .
O16 O 0.0741(5) -0.0651(4) -0.1238(4) 0.0250(10) Uani 1 1 d . .
O3 O 0.2245(5) 0.3005(4) 0.0750(4) 0.0268(10) Uani 1 1 d . .
N11 N -0.0798(9) 0.5170(7) 0.2869(8) 0.062(2) Uani 1 1 d . .
N1 N 0.2450(9) 0.5563(7) 0.2096(7) 0.0534(19) Uani 1 1 d . .
C12 C -0.2041(10) 0.5024(7) 0.4041(7) 0.0452(19) Uani 1 1 d . .
C11 C -0.1367(11) 0.5107(8) 0.3361(9) 0.056(2) Uani 1 1 d . .
C2 C 0.3892(8) 0.5996(6) 0.1142(7) 0.0404(18) Uani 1 1 d . .
C1 C 0.3110(9) 0.5758(7) 0.1681(7) 0.046(2) Uani 1 1 d . .
C3 C 0.3274(9) 0.6222(7) 0.0171(8) 0.0437(19) Uani 1 1 d . .
H3 H 0.2360 0.6214 -0.0121 0.052 Uiso 1 1 calc R U
C13 C -0.1590(11) 0.5729(9) 0.5086(8) 0.059(2) Uani 1 1 d . .
H13 H -0.0840 0.6263 0.5357 0.070 Uiso 1 1 calc R U
C4 C 0.4009(11) 0.6457(7) -0.0360(9) 0.056(2) Uani 1 1 d . .
H4 H 0.3591 0.6613 -0.1010 0.067 Uiso 1 1 calc R U
C15 C -0.3304(11) 0.4839(8) 0.5337(8) 0.057(2) Uani 1 1 d . .
H15 H -0.3716 0.4758 0.5785 0.068 Uiso 1 1 calc R U
C5 C 0.5366(11) 0.6464(8) 0.0061(11) 0.062(3) Uani 1 1 d . .
H5 H 0.5852 0.6607 -0.0316 0.075 Uiso 1 1 calc R U
C6 C 0.6000(10) 0.6261(9) 0.1035(12) 0.072(3) Uani 1 1 d . .
H6 H 0.6918 0.6284 0.1325 0.087 Uiso 1 1 calc R U
C14 C -0.2247(11) 0.5641(9) 0.5722(8) 0.061(3) Uani 1 1 d . .
H14 H -0.1968 0.6130 0.6412 0.073 Uiso 1 1 calc R U
C17 C -0.3142(12) 0.4224(8) 0.3656(8) 0.060(3) Uani 1 1 d . .
H17 H -0.3449 0.3741 0.2960 0.072 Uiso 1 1 calc R U
C7 C 0.5276(9) 0.6022(7) 0.1582(9) 0.051(2) Uani 1 1 d . .
H7 H 0.5702 0.5879 0.2239 0.061 Uiso 1 1 calc R U
O15 O -0.2089(5) -0.0392(4) -0.1321(4) 0.0269(10) Uani 1 1 d . .
O10 O -0.1037(5) 0.2650(4) 0.2057(4) 0.0360(12) Uani 1 1 d . .
O14 O 0.1591(5) 0.0302(4) -0.2447(4) 0.0316(11) Uani 1 1 d . .
O5 O -0.1228(5) 0.2360(4) -0.1447(4) 0.0280(10) Uani 1 1 d . .
C16 C -0.3783(12) 0.4143(10) 0.4305(9) 0.070(3) Uani 1 1 d . .
H16 H -0.4538 0.3617 0.4043 0.084 Uiso 1 1 calc R U
C24 C -0.8404(12) 0.1122(9) -0.5355(8) 0.060(3) Uani 1 1 d . .
H24 H -0.9304 0.0837 -0.5818 0.072 Uiso 1 1 calc R U
C22 C -0.6526(9) 0.1455(6) -0.3633(6) 0.0376(17) Uani 1 1 d . .
C27 C -0.5725(10) 0.1951(8) -0.3984(8) 0.054(2) Uani 1 1 d . .
H27 H -0.4820 0.2222 -0.3529 0.065 Uiso 1 1 calc R U
C25 C -0.7630(12) 0.1604(8) -0.5707(7) 0.059(3) Uani 1 1 d . .
H25 H -0.8000 0.1645 -0.6416 0.071 Uiso 1 1 calc R U
C23 C -0.7870(9) 0.1048(8) -0.4313(7) 0.049(2) Uani 1 1 d . .
H23 H -0.8411 0.0725 -0.4066 0.059 Uiso 1 1 calc R U
C21 C -0.5946(8) 0.1342(7) -0.2561(6) 0.0396(18) Uani 1 1 d . .
N21 N -0.5489(7) 0.1201(6) -0.1739(5) 0.0396(15) Uani 1 1 d . .
Ag1 Ag -0.45778(10) 0.11569(7) -0.01358(6) 0.0691(3) Uani 1 1 d . .
C26 C -0.6290(12) 0.2040(9) -0.5030(9) 0.066(3) Uani 1 1 d . .
H26 H -0.5771 0.2390 -0.5275 0.079 Uiso 1 1 calc R U
N31 N -0.3869(7) 0.1169(6) 0.1489(6) 0.0429(16) Uani 1 1 d . .
C32 C -0.2878(8) 0.1497(6) 0.3571(6) 0.0357(16) Uani 1 1 d . .
C31 C -0.3453(8) 0.1305(6) 0.2407(6) 0.0350(16) Uani 1 1 d . .
C33 C -0.3673(10) 0.1178(8) 0.4043(8) 0.047(2) Uani 1 1 d . .
H33 H -0.4571 0.0858 0.3619 0.057 Uiso 1 1 calc R U
C37 C -0.1567(10) 0.1985(9) 0.4182(7) 0.055(2) Uani 1 1 d . .
H37 H -0.1052 0.2185 0.3849 0.066 Uiso 1 1 calc R U
C36 C -0.1009(12) 0.2179(9) 0.5307(8) 0.068(3) Uani 1 1 d . .
H36 H -0.0127 0.2540 0.5736 0.082 Uiso 1 1 calc R U
C34 C -0.3083(13) 0.1350(10) 0.5163(9) 0.069(3) Uani 1 1 d . .
H34 H -0.3587 0.1135 0.5498 0.082 Uiso 1 1 calc R U
C35 C -0.1753(13) 0.1841(9) 0.5785(7) 0.067(3) Uani 1 1 d . .
H35 H -0.1362 0.1941 0.6535 0.080 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O14 W4 O13 102.4(2) . .
O14 W4 O2 98.4(2) . .
O13 W4 O2 87.9(2) . .
O14 W4 O7 105.1(2) . .
O13 W4 O7 152.55(19) . .
O2 W4 O7 88.2(2) . .
O14 W4 O16 98.3(2) . .
O13 W4 O16 87.2(2) . .
O2 W4 O16 163.28(19) . .
O7 W4 O16 88.8(2) . .
O14 W4 O6 173.8(2) . .
O13 W4 O6 75.87(17) . .
O2 W4 O6 75.76(17) . .
O7 W4 O6 76.83(17) . .
O16 W4 O6 87.53(17) . .
O10 W2 O16 100.4(2) . 2
O10 W2 O9 102.3(2) . .
O16 W2 O9 90.3(2) 2 .
O10 W2 O11 104.0(2) . .
O16 W2 O11 89.9(2) 2 .
O9 W2 O11 153.29(19) . .
O10 W2 O4 94.7(2) . .
O16 W2 O4 165.0(2) 2 .
O9 W2 O4 85.8(2) . .
O11 W2 O4 87.11(19) . .
O10 W2 O6 169.9(2) . .
O16 W2 O6 89.68(17) 2 .
O9 W2 O6 76.25(17) . .
O11 W2 O6 77.04(17) . .
O4 W2 O6 75.28(17) . .
O8 W3 O15 99.9(2) . 2
O8 W3 O9 102.7(2) . .
O15 W3 O9 88.9(2) 2 .
O8 W3 O7 104.3(2) . .
O15 W3 O7 88.90(19) 2 .
O9 W3 O7 152.9(2) . .
O8 W3 O3 96.6(2) . .
O15 W3 O3 163.4(2) 2 .
O9 W3 O3 87.4(2) . .
O7 W3 O3 87.1(2) . .
O8 W3 O6 171.5(2) . .
O15 W3 O6 88.40(18) 2 .
O9 W3 O6 75.54(17) . .
O7 W3 O6 77.45(17) . .
O3 W3 O6 75.03(18) . .
O1 W1 O5 103.0(2) . .
O1 W1 O4 103.9(2) . .
O5 W1 O4 87.9(2) . .
O1 W1 O3 104.1(2) . .
O5 W1 O3 152.9(2) . .
O4 W1 O3 87.1(2) . .
O1 W1 O2 102.3(2) . .
O5 W1 O2 86.9(2) . .
O4 W1 O2 153.83(19) . .
O3 W1 O2 86.0(2) . .
O1 W1 O6 179.4(2) . .
O5 W1 O6 76.79(17) . .
O4 W1 O6 76.67(17) . .
O3 W1 O6 76.09(17) . .
O2 W1 O6 77.16(17) . .
O12 W5 O15 99.9(2) . .
O12 W5 O13 102.2(2) . .
O15 W5 O13 89.7(2) . .
O12 W5 O11 105.2(2) . .
O15 W5 O11 88.56(19) . .
O13 W5 O11 152.4(2) . .
O12 W5 O5 96.0(2) . .
O15 W5 O5 164.2(2) . .
O13 W5 O5 87.2(2) . .
O11 W5 O5 87.0(2) . .
O12 W5 O6 170.8(2) . .
O15 W5 O6 89.30(18) . .
O13 W5 O6 76.61(17) . .
O11 W5 O6 75.85(17) . .
O5 W5 O6 74.86(17) . .
N11 Ag2 N1 146.9(3) . .
N11 Ag2 O1 99.1(3) . 2_565
N1 Ag2 O1 96.3(3) . 2_565
N11 Ag2 O4 109.4(3) . .
N1 Ag2 O4 98.8(2) . .
O1 Ag2 O4 92.74(17) 2_565 .
W1 O4 W2 115.3(2) . .
W1 O4 Ag2 118.5(2) . .
W2 O4 Ag2 121.0(2) . .
W5 O13 W4 118.4(2) . .
W1 O1 Ag2 133.0(3) . 2_565
W2 O6 W1 92.77(15) . .
W2 O6 W3 90.92(14) . .
W1 O6 W3 91.41(15) . .
W2 O6 W5 90.69(14) . .
W1 O6 W5 91.28(14) . .
W3 O6 W5 176.8(2) . .
W2 O6 W4 177.0(2) . .
W1 O6 W4 90.18(14) . .
W3 O6 W4 89.11(14) . .
W5 O6 W4 89.14(14) . .
W2 O11 W5 116.4(2) . .
W2 O11 Ag1 117.69(19) . .
W5 O11 Ag1 122.2(2) . .
W4 O7 W3 116.6(2) . .
W4 O2 W1 116.9(2) . .
W3 O9 W2 117.2(2) . .
W2 O16 W4 174.2(3) 2 .
W1 O3 W3 117.5(2) . .
C11 N11 Ag2 169.1(9) . .
C1 N1 Ag2 150.4(8) . .
C17 C12 C13 119.2(9) . .
C17 C12 C11 119.8(9) . .
C13 C12 C11 120.9(9) . .
N11 C11 C12 177.2(12) . .
C3 C2 C7 119.6(8) . .
C3 C2 C1 119.0(8) . .
C7 C2 C1 121.4(8) . .
N1 C1 C2 178.4(10) . .
C4 C3 C2 119.9(9) . .
C4 C3 H3 120.0 . .
C2 C3 H3 120.0 . .
C14 C13 C12 120.2(10) . .
C14 C13 H13 119.9 . .
C12 C13 H13 119.9 . .
C3 C4 C5 120.6(10) . .
C3 C4 H4 119.7 . .
C5 C4 H4 119.7 . .
C14 C15 C16 121.6(10) . .
C14 C15 H15 119.2 . .
C16 C15 H15 119.2 . .
C6 C5 C4 120.2(10) . .
C6 C5 H5 119.9 . .
C4 C5 H5 119.9 . .
C5 C6 C7 120.0(9) . .
C5 C6 H6 120.0 . .
C7 C6 H6 120.0 . .
C15 C14 C13 119.4(9) . .
C15 C14 H14 120.3 . .
C13 C14 H14 120.3 . .
C16 C17 C12 119.8(9) . .
C16 C17 H17 120.1 . .
C12 C17 H17 120.1 . .
C6 C7 C2 119.6(10) . .
C6 C7 H7 120.2 . .
C2 C7 H7 120.2 . .
W5 O15 W3 175.0(3) . 2
W1 O5 W5 117.1(2) . .
C15 C16 C17 119.6(11) . .
C15 C16 H16 120.2 . .
C17 C16 H16 120.2 . .
C25 C24 C23 120.2(10) . .
C25 C24 H24 119.9 . .
C23 C24 H24 119.9 . .
C27 C22 C23 120.5(8) . .
C27 C22 C21 119.2(8) . .
C23 C22 C21 120.3(8) . .
C22 C27 C26 118.8(10) . .
C22 C27 H27 120.6 . .
C26 C27 H27 120.6 . .
C24 C25 C26 120.9(8) . .
C24 C25 H25 119.5 . .
C26 C25 H25 119.5 . .
C24 C23 C22 119.8(9) . .
C24 C23 H23 120.1 . .
C22 C23 H23 120.1 . .
N21 C21 C22 176.5(10) . .
C21 N21 Ag1 172.4(7) . .
N21 Ag1 N31 173.0(3) . .
N21 Ag1 O11 87.2(2) . .
N31 Ag1 O11 99.0(2) . .
N21 Ag1 Ag1 113.7(2) . 2_455
N31 Ag1 Ag1 66.3(2) . 2_455
O11 Ag1 Ag1 116.35(10) . 2_455
C25 C26 C27 119.7(9) . .
C25 C26 H26 120.1 . .
C27 C26 H26 120.1 . .
C31 N31 Ag1 171.7(7) . .
C37 C32 C33 121.9(8) . .
C37 C32 C31 118.9(7) . .
C33 C32 C31 119.2(8) . .
N31 C31 C32 177.8(9) . .
C34 C33 C32 117.9(10) . .
C34 C33 H33 121.0 . .
C32 C33 H33 121.0 . .
C32 C37 C36 119.2(10) . .
C32 C37 H37 120.4 . .
C36 C37 H37 120.4 . .
C35 C36 C37 120.1(11) . .
C35 C36 H36 120.0 . .
C37 C36 H36 120.0 . .
C35 C34 C33 120.4(10) . .
C35 C34 H34 119.8 . .
C33 C34 H34 119.8 . .
C36 C35 C34 120.4(9) . .
C36 C35 H35 119.8 . .
C34 C35 H35 119.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W4 O14 1.694(5) .
W4 O13 1.912(5) .
W4 O2 1.914(5) .
W4 O7 1.917(5) .
W4 O16 1.931(4) .
W4 O6 2.344(4) .
W2 O10 1.709(5) .
W2 O16 1.849(4) 2
W2 O9 1.922(5) .
W2 O11 1.924(5) .
W2 O4 1.989(4) .
W2 O6 2.277(4) .
W3 O8 1.694(5) .
W3 O15 1.902(5) 2
W3 O9 1.911(5) .
W3 O7 1.924(5) .
W3 O3 1.927(5) .
W3 O6 2.314(4) .
W1 O1 1.715(5) .
W1 O5 1.905(5) .
W1 O4 1.914(5) .
W1 O3 1.917(5) .
W1 O2 1.928(5) .
W1 O6 2.277(4) .
W5 O12 1.695(5) .
W5 O15 1.886(5) .
W5 O13 1.901(5) .
W5 O11 1.927(5) .
W5 O5 1.951(5) .
W5 O6 2.323(4) .
Ag2 N11 2.176(9) .
Ag2 N1 2.187(8) .
Ag2 O1 2.453(5) 2_565
Ag2 O4 2.488(5) .
O1 Ag2 2.453(5) 2_565
O11 Ag1 2.797(5) .
O16 W2 1.849(4) 2
N11 C11 1.116(12) .
N1 C1 1.151(12) .
C12 C17 1.383(14) .
C12 C13 1.388(13) .
C12 C11 1.441(13) .
C2 C3 1.384(12) .
C2 C7 1.405(12) .
C2 C1 1.419(12) .
C3 C4 1.368(12) .
C3 H3 0.9300 .
C13 C14 1.375(14) .
C13 H13 0.9300 .
C4 C5 1.382(14) .
C4 H4 0.9300 .
C15 C14 1.351(15) .
C15 C16 1.366(14) .
C15 H15 0.9300 .
C5 C6 1.374(17) .
C5 H5 0.9300 .
C6 C7 1.380(15) .
C6 H6 0.9300 .
C14 H14 0.9300 .
C17 C16 1.373(14) .
C17 H17 0.9300 .
C7 H7 0.9300 .
O15 W3 1.902(5) 2
C16 H16 0.9300 .
C24 C25 1.343(15) .
C24 C23 1.372(12) .
C24 H24 0.9300 .
C22 C27 1.375(12) .
C22 C23 1.383(12) .
C22 C21 1.433(10) .
C27 C26 1.386(13) .
C27 H27 0.9300 .
C25 C26 1.385(16) .
C25 H25 0.9300 .
C23 H23 0.9300 .
C21 N21 1.132(10) .
N21 Ag1 2.083(6) .
Ag1 N31 2.085(6) .
Ag1 Ag1 3.3233(18) 2_455
C26 H26 0.9300 .
N31 C31 1.138(10) .
C32 C37 1.363(13) .
C32 C33 1.392(11) .
C32 C31 1.438(10) .
C33 C34 1.385(14) .
C33 H33 0.9300 .
C37 C36 1.387(13) .
C37 H37 0.9300 .
C36 C35 1.366(17) .
C36 H36 0.9300 .
C34 C35 1.382(17) .
C34 H34 0.9300 .
C35 H35 0.9300 .
