#------------------------------------------------------------------------------
#$Date: 2018-07-10 12:13:45 +0300 (Tue, 10 Jul 2018) $
#$Revision: 208944 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/51/7055167.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7055167
loop_
_publ_author_name
'Kalinowska-Lis, Urszula'
'Felczak, Aleksandra'
'Chęcińska, Lilianna'
'Małecka, Magdalena'
'Lisowska, Katarzyna'
'Ochocki, Justyn'
_publ_section_title
;
 Influence of selected inorganic counter-ions on the structure and
 antimicrobial properties of silver(i) complexes with imidazole-containing
 ligands
;
_journal_issue                   1
_journal_name_full               'New J. Chem.'
_journal_page_first              694
_journal_paper_doi               10.1039/C5NJ02514A
_journal_volume                  40
_journal_year                    2016
_chemical_formula_moiety
'C16 H24 Ag2 N8 O4, 2(Cl O4)'
_chemical_formula_sum            'C16 H24 Ag2 Cl2 N8 O12'
_chemical_formula_weight         807.07
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-11-04 deposited with the CCDC.
2015-11-16 downloaded from the CCDC.
;
_cell_angle_alpha                106.201(2)
_cell_angle_beta                 95.799(2)
_cell_angle_gamma                119.067(2)
_cell_formula_units_Z            2
_cell_length_a                   10.6600(2)
_cell_length_b                   10.7580(2)
_cell_length_c                   13.6855(3)
_cell_measurement_reflns_used    13559
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      36.1760
_cell_measurement_theta_min      2.2370
_cell_volume                     1263.90(6)
_computing_cell_refinement       'CrysAlisPro (Agilent Technologies)'
_computing_data_collection       'CrysAlisPro (Agilent Technologies)'
_computing_data_reduction        'CrysAlisPro (Agilent Technologies)'
_computing_molecular_graphics
; 
C. F. Macrae, I. J. Bruno, J. A. Chisholm, P. R. Edgington, P. McCabe, E.
Pidcock, L. Rodriguez-Monge, R. Taylor, J. van de Streek and P. A. Wood
(2008). J. Appl. Cryst. 41, 466--470.
A. L. Spek (2009). Acta Cryst. D65, 148--155.
;
_computing_publication_material
;
Sheldrick, G. M. (2015). Acta Cryst. C71, 3--8.
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920--925.
;
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2015)'
_computing_structure_solution
;
Sheldrick, G. M. (2015). Acta Cryst. A71, 3--8.
;
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4498
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0138
_diffrn_reflns_av_unetI/netI     0.0133
_diffrn_reflns_laue_measured_fraction_full 1.000
_diffrn_reflns_laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            16910
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.999
_diffrn_reflns_theta_min         2.220
_exptl_absorpt_coefficient_mu    1.839
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.58945
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.121
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             800
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.130
_exptl_crystal_size_min          0.040
_refine_diff_density_max         0.605
_refine_diff_density_min         -0.508
_refine_diff_density_rms         0.078
_refine_ls_extinction_coef       0.0065(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2015)'
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     394
_refine_ls_number_reflns         7321
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.0179
_refine_ls_R_factor_gt           0.0169
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0225P)²+0.6374P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0456
_refine_ls_wR_factor_ref         0.0463
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7007
_reflns_number_total             7321
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5nj02514a3.cif
_cod_data_source_block           complex2
_cod_depositor_comments
;
Adding full bibliography for 7055167--7055169.cif.

2018-06-13
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C32 H48 Ag4 Cl4 N16 O24'
_cod_original_formula_weight         1614.14
_cod_original_formula_moiety
'C16 H24 Ag2 N8 O4, 2(C8 H12 Ag N4 O2), 4(Cl O4)'
_cod_original_formula_units_Z            1
_cod_database_code               7055167
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.745
_shelx_estimated_absorpt_t_max   0.930
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ag1 Ag 0.45432(2) 0.07893(2) 0.43142(2) 0.01351(3) Uani 1 1 d . .
O1 O 0.47351(11) -0.23189(11) 0.25009(8) 0.01852(18) Uani 1 1 d . .
O2 O 0.71914(10) 0.01410(10) 0.42280(8) 0.01776(18) Uani 1 1 d . .
N1 N 0.26097(12) -0.11346(12) 0.31508(8) 0.01377(19) Uani 1 1 d . .
N2 N 0.02816(12) -0.28723(13) 0.22102(9) 0.0176(2) Uani 1 1 d . .
N3 N 0.66941(11) 0.27062(12) 0.51674(8) 0.01271(18) Uani 1 1 d . .
N4 N 0.85802(12) 0.48640(12) 0.63837(9) 0.01448(19) Uani 1 1 d . .
C1 C 0.26047(14) -0.20447(14) 0.22060(10) 0.0147(2) Uani 1 1 d . .
C2 C 0.11567(14) -0.31289(14) 0.16184(10) 0.0176(2) Uani 1 1 d . .
H2 H 0.0823 -0.3904 0.0937 0.021 Uiso 1 1 calc R U
C3 C 0.11914(13) -0.16700(14) 0.31257(10) 0.0155(2) Uani 1 1 d . .
H3 H 0.0861 -0.1263 0.3676 0.019 Uiso 1 1 calc R U
C4 C 0.40068(14) -0.17962(15) 0.19368(10) 0.0173(2) Uani 1 1 d . .
H41 H 0.3768 -0.2345 0.1165 0.021 Uiso 1 1 calc R U
H42 H 0.4703 -0.0687 0.2103 0.021 Uiso 1 1 calc R U
C5 C 0.80186(13) 0.28203(14) 0.50442(10) 0.0127(2) Uani 1 1 d . .
C6 C 0.91890(13) 0.41537(14) 0.57987(10) 0.0135(2) Uani 1 1 d . .
H6 H 1.0221 0.4521 0.5901 0.016 Uiso 1 1 calc R U
C7 C 0.70852(13) 0.39604(14) 0.59812(10) 0.0148(2) Uani 1 1 d . .
H7 H 0.6401 0.4190 0.6245 0.018 Uiso 1 1 calc R U
C8 C 0.80434(15) 0.16399(14) 0.41773(11) 0.0177(2) Uani 1 1 d . .
H8A H 0.7623 0.1603 0.3483 0.021 Uiso 1 1 calc R U
H8B H 0.9091 0.1932 0.4234 0.021 Uiso 1 1 calc R U
H1A H 0.540(2) -0.159(2) 0.3025(17) 0.031(5) Uiso 1 1 d . .
H2A H 0.772(2) -0.016(2) 0.4299(17) 0.035(6) Uiso 1 1 d . .
H20 H -0.069(2) -0.340(2) 0.2034(15) 0.023(4) Uiso 1 1 d . .
H40 H 0.906(2) 0.576(2) 0.6856(15) 0.022(4) Uiso 1 1 d . .
Ag2 Ag 1.04367(2) 0.91783(2) 0.07726(2) 0.01296(3) Uani 1 1 d . .
O3 O 1.05779(11) 1.21103(11) 0.25262(8) 0.01734(18) Uani 1 1 d . .
O4 O 0.79474(11) 0.92891(11) 0.18802(8) 0.0219(2) Uani 1 1 d . .
N5 N 1.25443(11) 1.09368(12) 0.18229(8) 0.01299(18) Uani 1 1 d . .
N6 N 1.49654(12) 1.25361(13) 0.25404(9) 0.0169(2) Uani 1 1 d . .
N7 N 0.82291(11) 0.74521(12) -0.01122(8) 0.01289(18) Uani 1 1 d . .
N8 N 0.62203(12) 0.53015(13) -0.12301(9) 0.0156(2) Uani 1 1 d . .
C9 C 1.27897(13) 1.20028(14) 0.27891(10) 0.0137(2) Uani 1 1 d . .
C10 C 1.42940(14) 1.30032(14) 0.32368(10) 0.0171(2) Uani 1 1 d . .
H10 H 1.4780 1.3851 0.3896 0.020 Uiso 1 1 calc R U
C11 C 1.38783(13) 1.12967(14) 0.17006(10) 0.0150(2) Uani 1 1 d . .
H11 H 1.4047 1.0757 0.1104 0.018 Uiso 1 1 calc R U
C12 C 1.15404(14) 1.19435(15) 0.32179(10) 0.0169(2) Uani 1 1 d . .
H12A H 1.0953 1.0951 0.3303 0.020 Uiso 1 1 calc R U
H12B H 1.1955 1.2776 0.3926 0.020 Uiso 1 1 calc R U
C13 C 0.69783(13) 0.74816(14) 0.00481(10) 0.0129(2) Uani 1 1 d . .
C14 C 0.57258(13) 0.61456(14) -0.06454(10) 0.0139(2) Uani 1 1 d . .
H14 H 0.4717 0.5858 -0.0710 0.017 Uiso 1 1 calc R U
C15 C 0.77224(14) 0.61182(15) -0.08856(10) 0.0158(2) Uani 1 1 d . .
H15 H 0.8337 0.5784 -0.1160 0.019 Uiso 1 1 calc R U
C16 C 0.71103(14) 0.88488(15) 0.08253(11) 0.0178(2) Uani 1 1 d . .
H16A H 0.7601 0.9721 0.0592 0.021 Uiso 1 1 calc R U
H16B H 0.6095 0.8625 0.0832 0.021 Uiso 1 1 calc R U
H3A H 0.980(3) 1.138(3) 0.232(2) 0.046(7) Uiso 1 1 d . .
H4A H 0.761(3) 0.858(3) 0.2052(18) 0.042(6) Uiso 1 1 d . .
H60 H 1.588(2) 1.296(2) 0.2618(16) 0.033(5) Uiso 1 1 d . .
H80 H 0.567(2) 0.437(2) -0.1714(15) 0.020(4) Uiso 1 1 d . .
Cl1 Cl 0.74605(3) 0.69937(3) 0.37454(2) 0.01425(6) Uani 1 1 d . .
O5 O 0.61403(11) 0.68157(12) 0.40329(9) 0.0223(2) Uani 1 1 d . .
O6 O 0.87013(10) 0.85626(11) 0.43328(9) 0.0223(2) Uani 1 1 d . .
O7 O 0.77911(11) 0.59521(12) 0.39908(9) 0.0237(2) Uani 1 1 d . .
O8 O 0.72370(12) 0.66917(13) 0.26197(8) 0.0252(2) Uani 1 1 d . .
Cl2 Cl 0.77493(3) 0.29439(3) 0.10896(2) 0.01341(6) Uani 1 1 d . .
O9 O 0.77025(11) 0.41217(11) 0.08066(9) 0.0234(2) Uani 1 1 d . .
O10 O 0.78923(12) 0.32966(14) 0.22121(8) 0.0261(2) Uani 1 1 d . .
O11 O 0.90200(11) 0.28966(12) 0.08664(9) 0.0231(2) Uani 1 1 d . .
O12 O 0.63902(11) 0.14845(11) 0.04888(8) 0.02050(19) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N3 Ag1 N1 166.21(4) .
N3 Ag1 Ag1 83.52(3) 2_656
N1 Ag1 Ag1 101.29(3) 2_656
C4 O1 H1A 109.7(14) .
C8 O2 H2A 109.1(16) .
C3 N1 C1 106.45(10) .
C3 N1 Ag1 128.71(9) .
C1 N1 Ag1 124.73(8) .
C3 N2 C2 108.08(11) .
C3 N2 H20 125.9(13) .
C2 N2 H20 126.0(13) .
C7 N3 C5 106.10(10) .
C7 N3 Ag1 128.53(8) .
C5 N3 Ag1 125.06(8) .
C7 N4 C6 107.73(10) .
C7 N4 H40 125.4(13) .
C6 N4 H40 126.4(13) .
C2 C1 N1 108.82(11) .
C2 C1 C4 128.65(12) .
N1 C1 C4 122.53(11) .
C1 C2 N2 106.15(11) .
C1 C2 H2 126.9 .
N2 C2 H2 126.9 .
N1 C3 N2 110.50(12) .
N1 C3 H3 124.8 .
N2 C3 H3 124.8 .
O1 C4 C1 112.84(11) .
O1 C4 H41 109.0 .
C1 C4 H41 109.0 .
O1 C4 H42 109.0 .
C1 C4 H42 109.0 .
H41 C4 H42 107.8 .
C6 C5 N3 108.86(10) .
C6 C5 C8 128.93(11) .
N3 C5 C8 122.18(11) .
C5 C6 N4 106.39(10) .
C5 C6 H6 126.8 .
N4 C6 H6 126.8 .
N3 C7 N4 110.92(11) .
N3 C7 H7 124.5 .
N4 C7 H7 124.5 .
O2 C8 C5 111.38(10) .
O2 C8 H8A 109.4 .
C5 C8 H8A 109.4 .
O2 C8 H8B 109.4 .
C5 C8 H8B 109.4 .
H8A C8 H8B 108.0 .
N7 Ag2 N5 172.87(4) .
C12 O3 H3A 109.0(18) .
C16 O4 H4A 109.6(16) .
C11 N5 C9 106.52(10) .
C11 N5 Ag2 128.40(9) .
C9 N5 Ag2 125.04(8) .
C11 N6 C10 107.99(11) .
C11 N6 H60 126.0(15) .
C10 N6 H60 126.0(15) .
C15 N7 C13 106.19(10) .
C15 N7 Ag2 128.86(8) .
C13 N7 Ag2 124.90(8) .
C15 N8 C14 107.98(10) .
C15 N8 H80 124.9(12) .
C14 N8 H80 127.0(12) .
C10 C9 N5 108.80(11) .
C10 C9 C12 128.92(12) .
N5 C9 C12 122.26(11) .
C9 C10 N6 106.16(11) .
C9 C10 H10 126.9 .
N6 C10 H10 126.9 .
N5 C11 N6 110.53(11) .
N5 C11 H11 124.7 .
N6 C11 H11 124.7 .
O3 C12 C9 111.15(10) .
O3 C12 H12A 109.4 .
C9 C12 H12A 109.4 .
O3 C12 H12B 109.4 .
C9 C12 H12B 109.4 .
H12A C12 H12B 108.0 .
C14 C13 N7 108.90(11) .
C14 C13 C16 129.28(11) .
N7 C13 C16 121.71(10) .
C13 C14 N8 106.12(10) .
C13 C14 H14 126.9 .
N8 C14 H14 126.9 .
N7 C15 N8 110.81(11) .
N7 C15 H15 124.6 .
N8 C15 H15 124.6 .
O4 C16 C13 113.18(11) .
O4 C16 H16A 108.9 .
C13 C16 H16A 108.9 .
O4 C16 H16B 108.9 .
C13 C16 H16B 108.9 .
H16A C16 H16B 107.8 .
O7 Cl1 O5 110.07(6) .
O7 Cl1 O6 109.77(6) .
O5 Cl1 O6 108.81(6) .
O7 Cl1 O8 109.61(7) .
O5 Cl1 O8 109.88(7) .
O6 Cl1 O8 108.68(7) .
O12 Cl2 O11 110.10(6) .
O12 Cl2 O9 109.23(6) .
O11 Cl2 O9 109.51(7) .
O12 Cl2 O10 109.59(6) .
O11 Cl2 O10 109.01(6) .
O9 Cl2 O10 109.38(7) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.0963(10) .
Ag1 N1 2.1024(11) .
Ag1 Ag1 3.22054(19) 2_656
O1 C4 1.4354(15) .
O1 H1A 0.82(2) .
O2 C8 1.4429(15) .
O2 H2A 0.79(2) .
N1 C3 1.3233(16) .
N1 C1 1.3846(16) .
N2 C3 1.3471(16) .
N2 C2 1.3712(18) .
N2 H20 0.865(19) .
N3 C7 1.3251(16) .
N3 C5 1.3885(15) .
N4 C7 1.3441(15) .
N4 C6 1.3753(15) .
N4 H40 0.85(2) .
C1 C2 1.3660(17) .
C1 C4 1.4897(17) .
C2 H2 0.9500 .
C3 H3 0.9500 .
C4 H41 0.9900 .
C4 H42 0.9900 .
C5 C6 1.3619(16) .
C5 C8 1.4897(17) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
Ag2 N7 2.0919(10) .
Ag2 N5 2.0959(10) .
O3 C12 1.4347(16) .
O3 H3A 0.76(3) .
O4 C16 1.4325(16) .
O4 H4A 0.79(2) .
N5 C11 1.3227(15) .
N5 C9 1.3873(15) .
N6 C11 1.3476(16) .
N6 C10 1.3758(17) .
N6 H60 0.83(2) .
N7 C15 1.3248(16) .
N7 C13 1.3869(15) .
N8 C15 1.3445(16) .
N8 C14 1.3739(16) .
N8 H80 0.877(19) .
C9 C10 1.3645(17) .
C9 C12 1.4894(17) .
C10 H10 0.9500 .
C11 H11 0.9500 .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.3665(16) .
C13 C16 1.4866(17) .
C14 H14 0.9500 .
C15 H15 0.9500 .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
Cl1 O7 1.4361(10) .
Cl1 O5 1.4368(10) .
Cl1 O6 1.4503(10) .
Cl1 O8 1.4515(11) .
Cl2 O12 1.4383(9) .
Cl2 O11 1.4397(10) .
Cl2 O9 1.4454(10) .
Cl2 O10 1.4486(10) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2A O6 0.79(2) 2.10(2) 2.8704(14) 168(2) 1_545
N2 H20 O8 0.865(19) 2.468(19) 3.1785(16) 139.9(16) 1_445
N2 H20 O9 0.865(19) 2.311(19) 2.9213(15) 127.7(16) 1_445
N4 H40 O3 0.85(2) 2.02(2) 2.7943(14) 151.1(17) 2_776
O1 H1A O2 0.82(2) 2.01(2) 2.8234(13) 173(2) .
O3 H3A O4 0.76(3) 2.00(3) 2.7547(14) 169(3) .
O4 H4A O8 0.79(2) 2.25(2) 3.0138(16) 165(2) .
N6 H60 O10 0.83(2) 2.15(2) 2.9350(15) 157(2) 1_665
N8 H80 O1 0.877(19) 1.966(19) 2.7767(14) 153.2(17) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C3 N1 C1 C2 0.11(14)
Ag1 N1 C1 C2 -176.42(8)
C3 N1 C1 C4 179.92(11)
Ag1 N1 C1 C4 3.39(16)
N1 C1 C2 N2 0.07(14)
C4 C1 C2 N2 -179.72(12)
C3 N2 C2 C1 -0.22(14)
C1 N1 C3 N2 -0.25(14)
Ag1 N1 C3 N2 176.09(8)
C2 N2 C3 N1 0.30(15)
C2 C1 C4 O1 -104.82(15)
N1 C1 C4 O1 75.41(15)
C7 N3 C5 C6 0.24(14)
Ag1 N3 C5 C6 -173.84(8)
C7 N3 C5 C8 -177.86(11)
Ag1 N3 C5 C8 8.06(16)
N3 C5 C6 N4 -0.29(14)
C8 C5 C6 N4 177.64(12)
C7 N4 C6 C5 0.23(14)
C5 N3 C7 N4 -0.09(14)
Ag1 N3 C7 N4 173.71(8)
C6 N4 C7 N3 -0.09(15)
C6 C5 C8 O2 123.78(14)
N3 C5 C8 O2 -58.53(16)
C11 N5 C9 C10 0.11(14)
Ag2 N5 C9 C10 -177.76(8)
C11 N5 C9 C12 -178.27(11)
Ag2 N5 C9 C12 3.85(16)
N5 C9 C10 N6 -0.33(14)
C12 C9 C10 N6 177.92(12)
C11 N6 C10 C9 0.42(14)
C9 N5 C11 N6 0.16(14)
Ag2 N5 C11 N6 177.94(8)
C10 N6 C11 N5 -0.36(15)
C10 C9 C12 O3 120.51(14)
N5 C9 C12 O3 -61.45(15)
C15 N7 C13 C14 -0.19(14)
Ag2 N7 C13 C14 -177.76(8)
C15 N7 C13 C16 -176.75(12)
Ag2 N7 C13 C16 5.67(16)
N7 C13 C14 N8 -0.03(14)
C16 C13 C14 N8 176.19(12)
C15 N8 C14 C13 0.24(14)
C13 N7 C15 N8 0.34(15)
Ag2 N7 C15 N8 177.79(8)
C14 N8 C15 N7 -0.37(15)
C14 C13 C16 O4 127.07(14)
N7 C13 C16 O4 -57.14(16)
